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來源(yuan):行業動態 閱讀:109402 發布時間:2019-07-05
導讀:由于生(sheng)產銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)兩者的(de)(de)(de)(de)工藝(yi)不(bu)同,所生(sheng)產的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)含(han)氧(yang)量及外觀就(jiu)不(bu)同。上(shang)引生(sheng)產的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan),工藝(yi)得當氧(yang)含(han)量在(zai)10ppm以(yi)下,叫無氧(yang)銅(tong)(tong)(tong)桿(gan)(gan);連鑄(zhu)連鑄(zhu)生(sheng)產的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan) 是在(zai)保護(hu)條件下的(de)(de)(de)(de)熱軋(ya),氧(yang)含(han)量在(zai)200-500ppm范圍內,但有(you)時也(ye)高達700ppm以(yi)上(shang),一般情況下,此種方法生(sheng)產的(de)(de)(de)(de)銅(tong)(tong)(tong)外表光亮,低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)(gan),有(you)時也(ye)叫光桿(gan)(gan)。
銅(tong)(tong)桿(gan)(gan)是(shi)電纜行(xing)業的(de)主(zhu)(zhu)要(yao)原料,生產(chan)的(de)方(fang)式(shi)主(zhu)(zhu)要(yao)有兩種(zhong)——連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)法(fa)和(he)上引連(lian)(lian)鑄(zhu)法(fa)。連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)低(di)(di)氧銅(tong)(tong)桿(gan)(gan)的(de)生產(chan)方(fang)法(fa)較多,其(qi)特點是(shi)金(jin)屬在(zai)豎爐(lu)中融化(hua)后(hou)(hou),銅(tong)(tong)液(ye)通過(guo)保溫爐(lu)、溜(liu)槽、中間(jian)包,從澆管(guan)進(jin)入(ru)封閉(bi)的(de)模(mo)腔(qiang)內,采(cai)用(yong)較大的(de)冷(leng)(leng)(leng)卻強(qiang)度進(jin)行(xing)冷(leng)(leng)(leng)卻,形(xing)(xing)成鑄(zhu)坯,然后(hou)(hou)進(jin)行(xing)多道次(ci)軋(ya)制,生產(chan)的(de)低(di)(di)氧銅(tong)(tong)桿(gan)(gan)為熱加工(gong)組織(zhi),原來的(de)鑄(zhu)造(zao)(zao)組織(zhi)已(yi)經(jing)破碎,含氧量(liang)(liang)一般為200~400ppm之間(jian)。無氧銅(tong)(tong)桿(gan)(gan)國內基本全部(bu)采(cai)用(yong)上引連(lian)(lian)鑄(zhu)法(fa)生產(chan),金(jin)屬在(zai)感應電爐(lu)中融化(hua)后(hou)(hou)通過(guo)石墨模(mo)進(jin)行(xing)上引連(lian)(lian)續鑄(zhu)造(zao)(zao),之后(hou)(hou)進(jin)行(xing)冷(leng)(leng)(leng)軋(ya)或(huo)冷(leng)(leng)(leng)加工(gong),生產(chan)的(de)無氧銅(tong)(tong)桿(gan)(gan)為鑄(zhu)造(zao)(zao)組織(zhi),含氧量(liang)(liang)一般在(zai)20ppm以下。由于制造(zao)(zao)工(gong)藝(yi)的(de)不同,所以在(zai)組織(zhi)結構、氧含量(liang)(liang)分(fen)布(bu)、雜質的(de)形(xing)(xing)式(shi)及分(fen)布(bu)等諸(zhu)多方(fang)面有較大差別。
一、拉制性能
銅桿(gan)的(de)(de)拉(la)制性能跟很(hen)多因素有關,如雜質的(de)(de)含量、氧含量及分(fen)布、工藝控制等。下面分(fen)別從以上幾個方(fang)面對銅桿(gan)的(de)(de)拉(la)制性能進行分(fen)析。
1、熔化方(fang)式對S等雜質(zhi)的影響
連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)生(sheng)產(chan)(chan)銅(tong)(tong)桿(gan)主(zhu)要是(shi)通過(guo)氣體的燃燒(shao)使(shi)銅(tong)(tong)桿(gan)熔化,在燃燒(shao)的過(guo)程中(zhong),通過(guo)氧化和揮發作用(yong),可一定程度減少部分雜(za)質(zhi)進(jin)入銅(tong)(tong)液,因此連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)法對(dui)原(yuan)料要求(qiu)相對(dui)低一些。上引(yin)連(lian)(lian)鑄(zhu)(zhu)生(sheng)產(chan)(chan)無氧銅(tong)(tong)桿(gan),由于(yu)是(shi)用(yong)感應電爐熔化,電解銅(tong)(tong)表面(mian)的“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本(ben)都熔入到銅(tong)(tong)液中(zhong)。其(qi)中(zhong)熔入的S對(dui)無氧銅(tong)(tong)桿(gan)塑性影響極大,會增加(jia)拉絲斷線率(lv)。
2、鑄造過程中雜質的進入
在生(sheng)產過(guo)(guo)程(cheng)中(zhong),連鑄(zhu)連軋(ya)(ya)工藝需通(tong)(tong)(tong)(tong)過(guo)(guo)保溫(wen)爐(lu)、溜槽、中(zhong)間包轉運銅液,相(xiang)對容易造(zao)(zao)成(cheng)耐火材料(liao)的(de)(de)(de)剝落,在軋(ya)(ya)制過(guo)(guo)程(cheng)中(zhong)需要通(tong)(tong)(tong)(tong)過(guo)(guo)軋(ya)(ya)輥,造(zao)(zao)成(cheng)鐵質(zhi)(zhi)的(de)(de)(de)脫落,會給(gei)銅桿造(zao)(zao)成(cheng)外部夾雜。而熱(re)軋(ya)(ya)中(zhong)皮(pi)上和皮(pi)下氧(yang)化物(wu)的(de)(de)(de)軋(ya)(ya)入,會給(gei)低(di)氧(yang)桿的(de)(de)(de)拉絲造(zao)(zao)成(cheng)不利的(de)(de)(de)影響。上引連鑄(zhu)法(fa)生(sheng)產工藝流(liu)程(cheng)較(jiao)短,銅液是通(tong)(tong)(tong)(tong)過(guo)(guo)聯體爐(lu)內潛流(liu)式完成(cheng),對耐火材料(liao)的(de)(de)(de)沖擊不大,結晶(jing)是通(tong)(tong)(tong)(tong)過(guo)(guo)石墨(mo)模內進行,所以(yi)過(guo)(guo)程(cheng)中(zhong)可能(neng)產生(sheng)的(de)(de)(de)污(wu)染(ran)源較(jiao)少,雜質(zhi)(zhi)進入的(de)(de)(de)機會較(jiao)少。
O、S、P是(shi)與銅(tong)(tong)(tong)會生(sheng)產化合物的(de)元素。在熔(rong)態銅(tong)(tong)(tong)中(zhong)(zhong),氧(yang)可以溶(rong)解一部(bu)分,但(dan)當銅(tong)(tong)(tong)冷(leng)凝時(shi),氧(yang)幾乎(hu)不溶(rong)解于(yu)銅(tong)(tong)(tong)中(zhong)(zhong)。熔(rong)態時(shi)所溶(rong)解的(de)氧(yang),以銅(tong)(tong)(tong)=氧(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)晶體析出,分布在晶粒晶界處。銅(tong)(tong)(tong)-氧(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)晶體的(de)出現,顯(xian)著降低了銅(tong)(tong)(tong)的(de)塑性。
硫可以溶(rong)解在(zai)熔體的(de)銅中(zhong),但在(zai)室(shi)溫下,其(qi)溶(rong)解度幾乎降低(di)到零,它以硫化亞銅的(de)形式出(chu)現(xian)在(zai)晶粒(li)晶界處,會(hui)顯著降低(di)銅的(de)塑性。
3、氧在低氧銅(tong)桿和無氧銅(tong)桿中分布形(xing)式及其影響
氧(yang)含(han)(han)量對低(di)氧(yang)銅(tong)(tong)桿的(de)(de)拉線(xian)性能有著明(ming)顯的(de)(de)影響。當氧(yang)含(han)(han)量增加到最(zui)佳(jia)值時,銅(tong)(tong)桿的(de)(de)斷(duan)線(xian)率最(zui)低(di)。這是(shi)因為氧(yang)在與大(da)部分雜質(zhi)反應的(de)(de)過程中都起到了清除器(qi)的(de)(de)作(zuo)用(yong)。適度(du)的(de)(de)氧(yang)還有利(li)于去(qu)除銅(tong)(tong)液(ye)中的(de)(de)氫,生成水蒸氣(qi)溢出,減少氣(qi)孔的(de)(de)形成。最(zui)佳(jia)的(de)(de)氧(yang)含(han)(han)量為拉線(xian)工藝(yi)提供了最(zui)好的(de)(de)條件。
低氧(yang)(yang)銅(tong)(tong)(tong)桿氧(yang)(yang)化物(wu)的(de)(de)分布:在連(lian)續(xu)澆鑄(zhu)中(zhong)凝(ning)固的(de)(de)最初階(jie)段(duan),散熱速率和均勻冷卻(que)是決定銅(tong)(tong)(tong)桿氧(yang)(yang)化物(wu)分布的(de)(de)主要因素(su)。不均勻冷卻(que)會(hui)引起銅(tong)(tong)(tong)桿內部結構本質上的(de)(de)差異,但后續(xu)的(de)(de)熱加工,柱狀晶通常會(hui)遭到破壞,使(shi)氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)顆(ke)粒(li)細微化和均勻分布。氧(yang)(yang)化物(wu)顆(ke)粒(li)聚集而產生(sheng)的(de)(de)典型情況是中(zhong)心爆裂。除氧(yang)(yang)化物(wu)顆(ke)粒(li)分布的(de)(de)影響外,具有較小氧(yang)(yang)化物(wu)顆(ke)粒(li)的(de)(de)銅(tong)(tong)(tong)桿顯示(shi)出較好的(de)(de)拉線(xian)特性,較大的(de)(de)Cu2O顆(ke)粒(li)容易造成應力集中(zhong)點而斷裂。
無氧(yang)(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)(yang)量(liang)(liang)超(chao)標,銅(tong)(tong)(tong)桿(gan)變(bian)脆,延伸(shen)率(lv)下降,拉伸(shen)式樣端口(kou)顯暗紅色(se),結晶組織(zhi)疏松。當氧(yang)(yang)(yang)含量(liang)(liang)超(chao)出8ppm時,工(gong)藝(yi)性能變(bian)差,表現為(wei)鑄造(zao)及(ji)拉伸(shen)過程中斷(duan)(duan)桿(gan)及(ji)斷(duan)(duan)線率(lv)極具增高(gao)。這是由于氧(yang)(yang)(yang)能與(yu)銅(tong)(tong)(tong)生成(cheng)氧(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)脆性相(xiang),形成(cheng)銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共晶體,以網(wang)狀(zhuang)組織(zhi)分布在境(jing)界上。這種脆性相(xiang)硬度高(gao),在冷變(bian)形時將會與(yu)銅(tong)(tong)(tong)機(ji)體脫離,導致銅(tong)(tong)(tong)桿(gan)的機(ji)械(xie)性能下降,在后續(xu)加(jia)工(gong)中容易造(zao)成(cheng)斷(duan)(duan)裂現象。氧(yang)(yang)(yang)含量(liang)(liang)高(gao)還能導致無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)導電率(lv)下降。因此(ci),必須嚴格控制(zhi)上引連鑄工(gong)藝(yi)及(ji)產品質(zhi)量(liang)(liang)。
4、氫的影響
在(zai)上引連(lian)鑄(zhu)中,氧含(han)量控制較低,氧化物的(de)副作用(yong)唄**降(jiang)低,但氫的(de)影(ying)響成為較顯著的(de)問題。吸(xi)氣后熔體中存(cun)在(zai)平衡反應:H2O(g)=[O]+2[H];
氣體及疏(shu)(shu)松(song)是在(zai)結晶(jing)(jing)的(de)(de)過(guo)(guo)程中(zhong)(zhong),氫從過(guo)(guo)飽和的(de)(de)溶液(ye)中(zhong)(zhong)析(xi)出(chu)(chu)(chu)并(bing)聚集而(er)形(xing)成(cheng)的(de)(de)。在(zai)結晶(jing)(jing)前(qian)析(xi)出(chu)(chu)(chu)的(de)(de)氫又可還原氧化亞銅(tong)而(er)生(sheng)成(cheng)水(shui)(shui)氣泡(pao)。由于上(shang)引鑄造(zao)的(de)(de)特點是銅(tong)液(ye)自上(shang)而(er)下(xia)的(de)(de)結晶(jing)(jing),形(xing)成(cheng)的(de)(de)液(ye)**形(xing)狀近似錐(zhui)型(xing)。銅(tong)液(ye)結晶(jing)(jing)前(qian)析(xi)出(chu)(chu)(chu)的(de)(de)氣體在(zai)上(shang)浮過(guo)(guo)程中(zhong)(zhong)被堵在(zai)凝固組織內,結晶(jing)(jing)時在(zai)鑄桿(gan)內形(xing)成(cheng)氣孔。上(shang)引的(de)(de)含(han)氣量少時,析(xi)出(chu)(chu)(chu)的(de)(de)氫存在(zai)于晶(jing)(jing)界處,形(xing)成(cheng)疏(shu)(shu)松(song);含(han)氣量多時,則聚集成(cheng)氣孔,因此,氣孔和疏(shu)(shu)松(song)是氫氣和水(shui)(shui)蒸氣兩者(zhe)形(xing)成(cheng)的(de)(de)。
氫(qing)來源于上引生產過程中的各個工藝環(huan)節,如原料電解(jie)銅的“銅綠(lv)”、輔料木炭(tan)(tan)**、氣候(hou)環(huan)境**、石墨結晶器未干燥等。因此(ci),熔化爐中的銅液表面應覆蓋經烘(hong)烤的木炭(tan)(tan),電解(jie)銅應盡量(liang)去除(chu)“銅綠(lv)”、“銅豆”“耳朵(duo)”,對提高無(wu)氧銅桿(gan)質(zhi)量(liang)非常重(zhong)要。
在連鑄連軋工(gong)藝(yi)中,往(wang)往(wang)采用適度控制氧含量來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O
由(you)于銅(tong)液(ye)在鑄造過(guo)程(cheng)中(zhong)是自下而上(shang)結晶,銅(tong)液(ye)中(zhong)的(de)(de)(de)氧(yang)和氫(qing)所產生的(de)(de)(de)水蒸氣很容(rong)易(yi)上(shang)浮跑出,銅(tong)液(ye)中(zhong)的(de)(de)(de)氫(qing)大(da)部(bu)分能被有(you)效去(qu)除,因(yin)而對銅(tong)桿的(de)(de)(de)影響較(jiao)小。
二、表面質量
在生產(chan)電磁線(xian)等產(chan)品的(de)過程中,對(dui)銅(tong)桿(gan)的(de)表面(mian)質量(liang)(liang)也需(xu)提出要(yao)求。需(xu)要(yao)拉制(zhi)后的(de)銅(tong)絲表面(mian)無毛刺(ci)、銅(tong)粉(fen)少、無油污。并通過扭轉試(shi)驗測(ce)量(liang)(liang)表面(mian)銅(tong)粉(fen)的(de)質量(liang)(liang)和扭轉后觀察銅(tong)桿(gan)的(de)復原情況(kuang)來判(pan)定其好壞(huai)。
在連(lian)鑄(zhu)連(lian)軋(ya)過(guo)程(cheng)中(zhong)(zhong),從鑄(zhu)造到軋(ya)制前(qian),溫度高(gao),完全暴露(lu)于(yu)空氣(qi)中(zhong)(zhong),使鑄(zhu)坯表(biao)面形成(cheng)較厚的(de)(de)氧化(hua)層,在軋(ya)制過(guo)程(cheng)中(zhong)(zhong),隨著軋(ya)輥的(de)(de)轉動,氧化(hua)物顆粒軋(ya)入銅(tong)線表(biao)面。由于(yu)氧化(hua)亞(ya)銅(tong)是高(gao)熔點脆性化(hua)合物,對于(yu)軋(ya)入較深(shen)的(de)(de)氧化(hua)亞(ya)銅(tong),當成(cheng)條狀的(de)(de)聚集(ji)物遇(yu)模(mo)具拉伸時,就(jiu)會是銅(tong)桿外表(biao)面產生毛(mao)刺,給后續的(de)(de)涂(tu)漆造成(cheng)麻煩。
而(er)上引連鑄工(gong)藝制(zhi)造的無(wu)氧(yang)銅(tong)桿,由于(yu)鑄造和冷卻完(wan)全與氧(yang)隔絕,后續亦無(wu)熱軋過程,銅(tong)桿表(biao)面無(wu)軋入表(biao)面的氧(yang)化物,質(zhi)量較(jiao)好,拉制(zhi)后銅(tong)粉(fen)少(shao),上述問題較(jiao)少(shao)存在。
無(wu)(wu)氧(yang)銅(tong)(tong)桿也(ye)分(fen)進口(kou)設(she)備(bei)(bei)做(zuo)的(de)(de)和國產(chan)設(she)備(bei)(bei)做(zuo)的(de)(de),但(dan)目(mu)前進口(kou)產(chan)品已無(wu)(wu)明顯優勢(shi),銅(tong)(tong)桿產(chan)品出來后區別(bie)不是(shi)很大(da),只要銅(tong)(tong)板選(xuan)的(de)(de)好,生產(chan)控(kong)制比較穩(wen)定(ding),國產(chan)設(she)備(bei)(bei)也(ye)能(neng)產(chan)出可拉伸0.05的(de)(de)銅(tong)(tong)桿.進口(kou)設(she)備(bei)(bei)一(yi)般是(shi)芬蘭奧托昆普的(de)(de)設(she)備(bei)(bei),國產(chan)設(she)備(bei)(bei)最好的(de)(de)應該是(shi)上海(hai)的(de)(de)海(hai)軍廠(chang)的(de)(de)了,生產(chan)時間最長,軍工企業,質量可靠。
低氧銅桿(gan)進口(kou)設備(bei)國際主要有兩(liang)種,一種是美(mei)國南線設備(bei),英文是SOUTHWIRE,國內廠(chang)家是南京華新,江(jiang)西銅業,另一種是德國CONTIROD設備(bei),國內廠(chang)家是常州金源(yuan),天津大無縫。
無(wu)(wu)氧(yang)(yang)(yang)及低氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)量上容易區別,無(wu)(wu)氧(yang)(yang)(yang)銅是(shi)含(han)氧(yang)(yang)(yang)量在(zai)10-20個PPM以下(xia),但目前(qian)有(you)的(de)廠家(jia)只能(neng)做到50個PPM以下(xia).低氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)在(zai) 200-400個PPM,好的(de)桿(gan)(gan)(gan)子一(yi)般(ban)(ban)含(han)氧(yang)(yang)(yang)量控制在(zai)250個PPM左右,無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)一(yi)般(ban)(ban)采(cai)取的(de)是(shi)上引法,低氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)連鑄連軋(ya),兩(liang)種(zhong)產品(pin)相對(dui)而言低氧(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)漆(qi)包線性 能(neng)更適應些(xie),如(ru)(ru)柔軟性,回(hui)彈(dan)角,繞線性能(neng).但低氧(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)拉(la)(la)絲(si)條(tiao)件(jian)(jian)相對(dui)要(yao)苛刻些(xie),同樣(yang)拉(la)(la)伸(shen)0.2的(de)細絲(si),如(ru)(ru)果伸(shen)線條(tiao)件(jian)(jian)不好,普(pu)通的(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)(la)而好的(de)低氧(yang)(yang)(yang)桿(gan)(gan)(gan)就斷 線,但如(ru)(ru)果放在(zai)好的(de)伸(shen)線條(tiao)件(jian)(jian),同樣(yang)的(de)桿(gan)(gan)(gan)子,低氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不定就能(neng)拉(la)(la)到雙(shuang)零(ling)五,而普(pu)通無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)最(zui)多只能(neng)拉(la)(la)伸(shen)到0.1而已,當(dang)然(ran)做的(de)最(zui)細的(de)如(ru)(ru)雙(shuang)零(ling)二卻非得依靠進口的(de) 無(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)了.目前(qian)有(you)企業嘗試用(yong)剝皮的(de)方式來處理低氧(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)0.03線.但有(you)關這方面的(de)內(nei)容我(wo)還不是(shi)很清楚。
音響(xiang)線一般反而喜(xi)歡用無氧桿,這和無氧桿是單(dan)晶銅(tong),低氧桿是多晶銅(tong)有關。
氧銅桿和無氧銅桿由(you)于制造方(fang)法的不同(tong),致使存在(zai)差別,具有各自的特點。
一、關于氧的吸入和脫(tuo)去以(yi)及(ji)它(ta)的存在(zai)狀(zhuang)態
生產(chan)銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)10—50ppm,在(zai)常(chang)(chang)溫下(xia)(xia)氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)固(gu)溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進(jin)入是在(zai)銅(tong)(tong)的(de)(de)(de)(de)液態(tai)下(xia)(xia)吸入的(de)(de)(de)(de),而(er)上引法無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)則相反(fan),氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液態(tai)銅(tong)(tong)下(xia)(xia)保持相當時間(jian)后,被(bei)還原而(er)脫去,通常(chang)(chang)這(zhe)(zhe)種(zhong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量都在(zai)10—50ppm以下(xia)(xia),最低(di)可達1-2ppm,從組(zu)織上看,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)狀態(tai),存在(zai)于晶粒邊界附近(jin),這(zhe)(zhe)對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)而(er)言可以說是常(chang)(chang)見(jian)的(de)(de)(de)(de)但對(dui)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)則很(hen)少(shao)見(jian)。氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)以夾雜形式在(zai)晶界出(chu)現對(dui)材料的(de)(de)(de)(de)韌(ren)性(xing)產(chan)生負面(mian)影響。而(er)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)很(hen)低(di),所以這(zhe)(zhe)種(zhong)銅(tong)(tong)的(de)(de)(de)(de)組(zu)織是均勻(yun)的(de)(de)(de)(de)單相組(zu)織對(dui)韌(ren)性(xing)有利(li)。在(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)中(zhong)的(de)(de)(de)(de)多(duo)孔性(xing)是不常(chang)(chang)見(jian)的(de)(de)(de)(de),而(er)在(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)中(zhong)則是常(chang)(chang)見(jian)的(de)(de)(de)(de)一(yi)種(zhong)缺陷(xian)。
二(er)、熱軋組(zu)織和(he)鑄造組(zu)織的區別
低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)由于經(jing)過熱(re)軋,所以(yi)其組(zu)(zu)織屬熱(re)加工組(zu)(zu)織,原來的(de)(de)鑄造組(zu)(zu)織已(yi)經(jing)破碎,在8mm的(de)(de)桿(gan)(gan)(gan)時已(yi)有(you)再(zai)(zai)結(jie)晶(jing)的(de)(de)形式出現,而無(wu)(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)屬鑄造組(zu)(zu)織,晶(jing)粒(li)(li)粗大(da),這(zhe)是為什么,無(wu)(wu)氧(yang)(yang)銅(tong)的(de)(de)再(zai)(zai)結(jie)晶(jing)溫度(du)較(jiao)高(gao),需要較(jiao)高(gao)退(tui)火(huo)(huo)溫度(du)的(de)(de)固(gu)有(you)原因。這(zhe)是因為,再(zai)(zai)結(jie)晶(jing)發生在晶(jing)粒(li)(li)邊(bian)(bian)界附近,無(wu)(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)組(zu)(zu)織晶(jing)粒(li)(li)粗大(da),晶(jing)粒(li)(li)尺(chi)寸甚(shen)至能達幾(ji)個(ge)毫(hao)米,因而晶(jing)粒(li)(li)邊(bian)(bian)界少,即使通過拉制(zhi)變形,但晶(jing)粒(li)(li)邊(bian)(bian)界相對(dui)低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)還(huan)是較(jiao)少,所以(yi)需要較(jiao)高(gao)的(de)(de)退(tui)火(huo)(huo)功率(lv)。對(dui)無(wu)(wu)氧(yang)(yang)銅(tong)成(cheng)功的(de)(de)退(tui)火(huo)(huo)要求是:由桿(gan)(gan)(gan)經(jing)拉制(zhi),但尚未鑄造組(zu)(zu)織的(de)(de)線時的(de)(de)第一次(ci)退(tui)火(huo)(huo),其退(tui)火(huo)(huo)功率(lv)應(ying)比同(tong)樣情況的(de)(de)低(di)氧(yang)(yang)銅(tong)高(gao)10——15%。經(jing)繼續拉制(zhi),在以(yi)后階段(duan)的(de)(de)退(tui)火(huo)(huo)功率(lv)應(ying)留有(you)足夠的(de)(de)余量和對(dui)低(di)氧(yang)(yang)銅(tong)和無(wu)(wu)氧(yang)(yang)銅(tong)切實區別執行不同(tong)的(de)(de)退(tui)火(huo)(huo)工藝(yi),以(yi)保(bao)證在制(zhi)品和成(cheng)品導線的(de)(de)柔(rou)軟性。
三、夾雜,氧(yang)含量波動,表面氧(yang)化物和可能存(cun)在的(de)熱軋缺陷的(de)差別
無氧(yang)(yang)銅(tong)桿(gan)的(de)可拉(la)性在(zai)所有線(xian)(xian)徑里與(yu)低氧(yang)(yang)銅(tong)桿(gan)相(xiang)比(bi)都是(shi)(shi)優越的(de),除(chu)上述組織原因外,無氧(yang)(yang)銅(tong)桿(gan)夾(jia)雜少(shao)(shao),含氧(yang)(yang)量穩(wen)定,無熱軋可能(neng)產生(sheng)的(de)缺(que)陷,桿(gan)表氧(yang)(yang)化物(wu)厚度(du)可達≤15A。在(zai)連鑄連軋生(sheng)產過程中(zhong)如(ru)果(guo)工(gong)藝不(bu)穩(wen)定,對氧(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)量不(bu)穩(wen)定將直(zhi)接(jie)影響桿(gan)的(de)性能(neng)。如(ru)果(guo)桿(gan)的(de)表面氧(yang)(yang)化物(wu)能(neng)在(zai)后工(gong)序的(de)連續清洗中(zhong)得以彌(mi)補外,但比(bi)較麻煩的(de)是(shi)(shi)有相(xiang)當多的(de)氧(yang)(yang)化物(wu)存在(zai)于(yu)“皮(pi)(pi)下”,對拉(la)線(xian)(xian)斷(duan)線(xian)(xian)影響更(geng)直(zhi)接(jie),故而在(zai)拉(la)制微(wei)細線(xian)(xian),超微(wei)細線(xian)(xian)時(shi),為了減少(shao)(shao)斷(duan)線(xian)(xian),有時(shi)要(yao)對銅(tong)桿(gan)采取不(bu)得已的(de)辦法——剝皮(pi)(pi),甚至二次(ci)剝皮(pi)(pi)的(de)原因所在(zai),目(mu)的(de)要(yao)除(chu)去皮(pi)(pi)下氧(yang)(yang)化物(wu)。
四、低氧(yang)銅桿和(he)無氧(yang)銅桿的韌性(xing)有差別(bie)
兩者都(dou)可以拉(la)到0.015mm,但在低溫(wen)超導線中的(de)低溫(wen)級無氧銅,其(qi)細絲間的(de)間距(ju)只(zhi)有(you)0.001mm.
五、從(cong)制桿的原(yuan)材料到制線的經濟(ji)性有(you)差(cha)別(bie)。
制造無氧(yang)銅(tong)桿(gan)要求質量較高的(de)原材料(liao)。一(yi)般,拉(la)制直徑>1mm的(de)銅(tong)線(xian)時,低氧(yang)銅(tong)桿(gan)的(de)優點比較明顯,而無氧(yang)銅(tong)桿(gan)顯得更(geng)為優越(yue)的(de)是(shi)拉(la)制直徑<0.5mm的(de)銅(tong)線(xian)。
六、低(di)氧(yang)銅桿的(de)制(zhi)線工藝與無氧(yang)銅桿的(de)有所不同。
低(di)氧銅桿(gan)(gan)的(de)(de)制(zhi)線(xian)(xian)工藝(yi)不能照搬到無氧銅桿(gan)(gan)的(de)(de)制(zhi)線(xian)(xian)工藝(yi)上來,至少兩者的(de)(de)退火工藝(yi)是不同的(de)(de)。因(yin)為線(xian)(xian)的(de)(de)柔(rou)軟(ruan)性深受材料(liao)成份(fen)和(he)制(zhi)桿(gan)(gan),制(zhi)線(xian)(xian)和(he)退火工藝(yi)的(de)(de)影響,不能簡(jian)單地說低(di)氧銅或無氧銅誰(shui)軟(ruan)誰(shui)硬。
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