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北安電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱讀(du):109582 發布時(shi)間:2019-07-05

導讀(du):由于生(sheng)產(chan)銅(tong)桿(gan)的(de)(de)(de)兩(liang)者(zhe)的(de)(de)(de)工(gong)藝不同(tong),所生(sheng)產(chan)的(de)(de)(de)銅(tong)桿(gan)中(zhong)的(de)(de)(de)含氧量(liang)及外觀就(jiu)不同(tong)。上引生(sheng)產(chan)的(de)(de)(de)銅(tong)桿(gan),工(gong)藝得當氧含量(liang)在(zai)10ppm以(yi)下,叫無氧銅(tong)桿(gan);連(lian)(lian)鑄連(lian)(lian)鑄生(sheng)產(chan)的(de)(de)(de)銅(tong)桿(gan) 是在(zai)保護條件下的(de)(de)(de)熱軋,氧含量(liang)在(zai)200-500ppm范圍(wei)內,但有時(shi)也(ye)(ye)高達700ppm以(yi)上,一般情況下,此(ci)種方法生(sheng)產(chan)的(de)(de)(de)銅(tong)外表光亮,低氧銅(tong)桿(gan),有時(shi)也(ye)(ye)叫光桿(gan)。

銅(tong)桿是電纜行(xing)(xing)業的(de)主要原料,生產(chan)的(de)方(fang)式(shi)主要有(you)(you)兩(liang)種——連(lian)鑄(zhu)連(lian)軋法(fa)(fa)和上引連(lian)鑄(zhu)法(fa)(fa)。連(lian)鑄(zhu)連(lian)軋低氧(yang)(yang)(yang)銅(tong)桿的(de)生產(chan)方(fang)法(fa)(fa)較(jiao)多(duo),其特點(dian)是金屬在(zai)豎爐中(zhong)融化(hua)后(hou),銅(tong)液通過(guo)保溫(wen)爐、溜槽、中(zhong)間包(bao),從澆管(guan)進入封閉的(de)模腔內,采(cai)用(yong)較(jiao)大的(de)冷卻(que)強度進行(xing)(xing)冷卻(que),形(xing)成鑄(zhu)坯,然(ran)后(hou)進行(xing)(xing)多(duo)道次軋制,生產(chan)的(de)低氧(yang)(yang)(yang)銅(tong)桿為(wei)熱加工組織(zhi),原來的(de)鑄(zhu)造(zao)組織(zhi)已經破(po)碎,含(han)氧(yang)(yang)(yang)量一般為(wei)200~400ppm之(zhi)間。無(wu)氧(yang)(yang)(yang)銅(tong)桿國內基本全部采(cai)用(yong)上引連(lian)鑄(zhu)法(fa)(fa)生產(chan),金屬在(zai)感應電爐中(zhong)融化(hua)后(hou)通過(guo)石墨模進行(xing)(xing)上引連(lian)續鑄(zhu)造(zao),之(zhi)后(hou)進行(xing)(xing)冷軋或冷加工,生產(chan)的(de)無(wu)氧(yang)(yang)(yang)銅(tong)桿為(wei)鑄(zhu)造(zao)組織(zhi),含(han)氧(yang)(yang)(yang)量一般在(zai)20ppm以(yi)下。由于(yu)制造(zao)工藝的(de)不同,所以(yi)在(zai)組織(zhi)結構、氧(yang)(yang)(yang)含(han)量分布、雜質的(de)形(xing)式(shi)及分布等諸多(duo)方(fang)面有(you)(you)較(jiao)大差別。

一、拉制性能

銅桿(gan)的拉制性能(neng)跟很(hen)多(duo)因(yin)素有關,如雜質的含量、氧含量及分布、工藝控(kong)制等。下面分別從以上(shang)幾個(ge)方面對銅桿(gan)的拉制性能(neng)進行分析。

1、熔化方式對S等雜質的(de)影響

連(lian)鑄連(lian)軋生(sheng)(sheng)產銅(tong)(tong)桿(gan)(gan)主(zhu)要是通過(guo)氣體(ti)的(de)燃燒使(shi)銅(tong)(tong)桿(gan)(gan)熔(rong)化,在燃燒的(de)過(guo)程(cheng)(cheng)中(zhong),通過(guo)氧(yang)化和揮發作用,可(ke)一定程(cheng)(cheng)度(du)減少(shao)部分雜質(zhi)進入銅(tong)(tong)液(ye),因此連(lian)鑄連(lian)軋法對原料要求(qiu)相對低一些。上引連(lian)鑄生(sheng)(sheng)產無氧(yang)銅(tong)(tong)桿(gan)(gan),由于是用感應電(dian)爐熔(rong)化,電(dian)解(jie)銅(tong)(tong)表面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都熔(rong)入到(dao)銅(tong)(tong)液(ye)中(zhong)。其(qi)中(zhong)熔(rong)入的(de)S對無氧(yang)銅(tong)(tong)桿(gan)(gan)塑(su)性影響極大,會增加拉絲斷線率。

2、鑄造過程中雜質的進(jin)入

在生產(chan)(chan)過(guo)程(cheng)中,連鑄(zhu)連軋(ya)工藝(yi)需通(tong)(tong)過(guo)保溫爐、溜槽、中間包轉運銅(tong)(tong)液,相對容易造(zao)成(cheng)耐火(huo)材料(liao)(liao)的剝落,在軋(ya)制過(guo)程(cheng)中需要通(tong)(tong)過(guo)軋(ya)輥,造(zao)成(cheng)鐵質(zhi)的脫落,會(hui)給銅(tong)(tong)桿(gan)造(zao)成(cheng)外部夾雜。而熱(re)軋(ya)中皮上和皮下氧化物的軋(ya)入,會(hui)給低氧桿(gan)的拉絲造(zao)成(cheng)不利的影響。上引連鑄(zhu)法生產(chan)(chan)工藝(yi)流程(cheng)較短,銅(tong)(tong)液是通(tong)(tong)過(guo)聯體(ti)爐內潛流式完成(cheng),對耐火(huo)材料(liao)(liao)的沖擊不大,結晶(jing)是通(tong)(tong)過(guo)石(shi)墨模內進(jin)行(xing),所以過(guo)程(cheng)中可能產(chan)(chan)生的污染源較少,雜質(zhi)進(jin)入的機會(hui)較少。

O、S、P是與銅(tong)(tong)會生產化合(he)物的(de)元素(su)。在熔態銅(tong)(tong)中,氧(yang)(yang)可以溶(rong)解(jie)一(yi)部分(fen)(fen),但(dan)當(dang)銅(tong)(tong)冷凝時(shi),氧(yang)(yang)幾乎不溶(rong)解(jie)于銅(tong)(tong)中。熔態時(shi)所溶(rong)解(jie)的(de)氧(yang)(yang),以銅(tong)(tong)=氧(yang)(yang)化亞(ya)銅(tong)(tong)共(gong)晶體析出(chu)(chu),分(fen)(fen)布在晶粒晶界處。銅(tong)(tong)-氧(yang)(yang)化亞(ya)銅(tong)(tong)共(gong)晶體的(de)出(chu)(chu)現,顯(xian)著降低(di)了銅(tong)(tong)的(de)塑性。

硫(liu)可以溶(rong)解在熔體的銅(tong)中,但在室溫下(xia),其溶(rong)解度幾乎(hu)降低到(dao)零(ling),它以硫(liu)化亞銅(tong)的形式(shi)出現在晶粒晶界處,會顯著降低銅(tong)的塑性。

3、氧在低氧銅桿和無(wu)氧銅桿中(zhong)分布形式及其影響

氧含量對(dui)低氧銅桿(gan)的(de)(de)拉線(xian)(xian)性能有著明顯的(de)(de)影響(xiang)。當氧含量增加(jia)到(dao)最佳值時,銅桿(gan)的(de)(de)斷線(xian)(xian)率最低。這是因為氧在(zai)與大部分雜質反(fan)應的(de)(de)過程(cheng)中(zhong)都起(qi)到(dao)了清除器的(de)(de)作用。適(shi)度的(de)(de)氧還有利于去除銅液中(zhong)的(de)(de)氫,生成水蒸氣(qi)(qi)溢出,減少氣(qi)(qi)孔的(de)(de)形成。最佳的(de)(de)氧含量為拉線(xian)(xian)工藝提供了最好(hao)的(de)(de)條件。

低氧銅(tong)(tong)桿(gan)氧化(hua)(hua)(hua)物(wu)(wu)的(de)(de)(de)分布:在(zai)連續澆鑄中凝固(gu)的(de)(de)(de)最初階段(duan),散(san)熱(re)速率和均勻(yun)冷卻是決(jue)定銅(tong)(tong)桿(gan)氧化(hua)(hua)(hua)物(wu)(wu)分布的(de)(de)(de)主要因(yin)素。不均勻(yun)冷卻會引起銅(tong)(tong)桿(gan)內部結構本質上的(de)(de)(de)差異,但后續的(de)(de)(de)熱(re)加工,柱狀晶通常會遭(zao)到破壞,使氧化(hua)(hua)(hua)亞銅(tong)(tong)顆(ke)(ke)粒(li)(li)(li)細微(wei)化(hua)(hua)(hua)和均勻(yun)分布。氧化(hua)(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)(li)(li)聚(ju)集(ji)而產(chan)生(sheng)的(de)(de)(de)典型情況是中心爆裂(lie)。除氧化(hua)(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)(li)(li)分布的(de)(de)(de)影響(xiang)外,具(ju)有較小氧化(hua)(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)(li)(li)的(de)(de)(de)銅(tong)(tong)桿(gan)顯示出較好的(de)(de)(de)拉線特性,較大的(de)(de)(de)Cu2O顆(ke)(ke)粒(li)(li)(li)容易(yi)造(zao)成(cheng)應(ying)力(li)集(ji)中點(dian)而斷(duan)裂(lie)。

無(wu)氧(yang)(yang)銅(tong)含氧(yang)(yang)量(liang)(liang)超標,銅(tong)桿(gan)(gan)變(bian)脆(cui),延伸(shen)(shen)率(lv)下(xia)降(jiang)(jiang),拉伸(shen)(shen)式(shi)樣(yang)端口顯暗紅色(se),結晶(jing)組織疏松。當氧(yang)(yang)含量(liang)(liang)超出8ppm時(shi),工藝(yi)性能(neng)變(bian)差,表現為鑄造及拉伸(shen)(shen)過程(cheng)中斷桿(gan)(gan)及斷線(xian)率(lv)極具增(zeng)高(gao)。這(zhe)是(shi)由于氧(yang)(yang)能(neng)與銅(tong)生成(cheng)氧(yang)(yang)化亞銅(tong)脆(cui)性相,形(xing)成(cheng)銅(tong)-氧(yang)(yang)化亞銅(tong)共晶(jing)體,以網狀組織分布在(zai)境(jing)界上。這(zhe)種脆(cui)性相硬(ying)度(du)高(gao),在(zai)冷變(bian)形(xing)時(shi)將會(hui)與銅(tong)機(ji)體脫離,導致銅(tong)桿(gan)(gan)的(de)機(ji)械(xie)性能(neng)下(xia)降(jiang)(jiang),在(zai)后續加工中容易造成(cheng)斷裂現象。氧(yang)(yang)含量(liang)(liang)高(gao)還能(neng)導致無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)導電率(lv)下(xia)降(jiang)(jiang)。因此,必(bi)須嚴格控制上引(yin)連鑄工藝(yi)及產品質量(liang)(liang)。

4、氫的影響

在上引(yin)連鑄中,氧含量(liang)控制(zhi)較低(di),氧化物的副作(zuo)用唄**降(jiang)低(di),但氫的影響成(cheng)為(wei)較顯著的問題。吸氣(qi)后熔體中存(cun)在平衡反(fan)應:H2O(g)=[O]+2[H];

氣(qi)(qi)體及(ji)疏(shu)松(song)是在(zai)(zai)(zai)(zai)結(jie)(jie)晶的(de)過程(cheng)中,氫從過飽和的(de)溶液中析出(chu)并(bing)聚集(ji)而(er)形成(cheng)的(de)。在(zai)(zai)(zai)(zai)結(jie)(jie)晶前析出(chu)的(de)氫又可還原氧(yang)化亞(ya)銅而(er)生(sheng)成(cheng)水氣(qi)(qi)泡(pao)。由于(yu)上(shang)引鑄(zhu)造的(de)特點是銅液自(zi)上(shang)而(er)下的(de)結(jie)(jie)晶,形成(cheng)的(de)液**形狀近(jin)似錐型。銅液結(jie)(jie)晶前析出(chu)的(de)氣(qi)(qi)體在(zai)(zai)(zai)(zai)上(shang)浮(fu)過程(cheng)中被(bei)堵在(zai)(zai)(zai)(zai)凝固組(zu)織內(nei),結(jie)(jie)晶時在(zai)(zai)(zai)(zai)鑄(zhu)桿內(nei)形成(cheng)氣(qi)(qi)孔。上(shang)引的(de)含氣(qi)(qi)量(liang)少時,析出(chu)的(de)氫存在(zai)(zai)(zai)(zai)于(yu)晶界處,形成(cheng)疏(shu)松(song);含氣(qi)(qi)量(liang)多時,則(ze)聚集(ji)成(cheng)氣(qi)(qi)孔,因此(ci),氣(qi)(qi)孔和疏(shu)松(song)是氫氣(qi)(qi)和水蒸氣(qi)(qi)兩者(zhe)形成(cheng)的(de)。

氫(qing)來源于上(shang)引(yin)生產過程中的(de)(de)各個工(gong)藝環節,如原料(liao)電解銅(tong)的(de)(de)“銅(tong)綠”、輔料(liao)木(mu)炭**、氣候(hou)環境(jing)**、石墨結晶器未干燥等。因此,熔化(hua)爐(lu)中的(de)(de)銅(tong)液表面應覆蓋經烘烤的(de)(de)木(mu)炭,電解銅(tong)應盡(jin)量去除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對提高(gao)無氧銅(tong)桿質(zhi)量非常重要。

在連(lian)鑄連(lian)軋工(gong)藝中,往(wang)往(wang)采用適度控制氧(yang)含量來(lai)控制氫。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅(tong)(tong)(tong)液(ye)在(zai)鑄造過(guo)程中(zhong)是自(zi)下而上(shang)結晶,銅(tong)(tong)(tong)液(ye)中(zhong)的氧和氫(qing)所產生(sheng)的水蒸氣很容(rong)易上(shang)浮(fu)跑出(chu),銅(tong)(tong)(tong)液(ye)中(zhong)的氫(qing)大部分能(neng)被(bei)有效去除,因而對銅(tong)(tong)(tong)桿的影響較小。

二、表面質量

在生產電磁線(xian)等(deng)產品的(de)(de)過程中,對(dui)銅(tong)桿的(de)(de)表(biao)面(mian)(mian)質量(liang)也需提(ti)出要(yao)求。需要(yao)拉制后的(de)(de)銅(tong)絲表(biao)面(mian)(mian)無(wu)毛刺、銅(tong)粉少、無(wu)油污。并通過扭轉試驗測量(liang)表(biao)面(mian)(mian)銅(tong)粉的(de)(de)質量(liang)和扭轉后觀察銅(tong)桿的(de)(de)復原情(qing)況來判定其好壞。

在連鑄(zhu)連軋(ya)(ya)過程(cheng)中,從鑄(zhu)造(zao)到軋(ya)(ya)制前,溫(wen)度高,完(wan)全暴露于空(kong)氣中,使鑄(zhu)坯表面形成(cheng)(cheng)較(jiao)厚的(de)(de)氧(yang)化(hua)層(ceng),在軋(ya)(ya)制過程(cheng)中,隨著軋(ya)(ya)輥的(de)(de)轉動,氧(yang)化(hua)物顆粒軋(ya)(ya)入銅(tong)(tong)線表面。由于氧(yang)化(hua)亞銅(tong)(tong)是高熔點(dian)脆性化(hua)合(he)物,對于軋(ya)(ya)入較(jiao)深的(de)(de)氧(yang)化(hua)亞銅(tong)(tong),當成(cheng)(cheng)條狀的(de)(de)聚集物遇(yu)模具(ju)拉伸時,就會是銅(tong)(tong)桿外表面產(chan)生毛刺(ci),給后續的(de)(de)涂漆造(zao)成(cheng)(cheng)麻煩。

而上引連鑄(zhu)工(gong)藝制造的無(wu)氧(yang)銅(tong)桿,由于鑄(zhu)造和冷(leng)卻完全與氧(yang)隔(ge)絕,后續亦無(wu)熱軋(ya)過(guo)程,銅(tong)桿表(biao)面無(wu)軋(ya)入表(biao)面的氧(yang)化物,質量較好,拉制后銅(tong)粉少,上述問題較少存在。

無氧(yang)銅(tong)桿也分進口設備(bei)做的(de)(de)(de)和國(guo)產(chan)(chan)設備(bei)做的(de)(de)(de),但目前(qian)進口產(chan)(chan)品(pin)已無明顯優(you)勢,銅(tong)桿產(chan)(chan)品(pin)出(chu)來后區別不是很大,只要銅(tong)板選的(de)(de)(de)好,生(sheng)產(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)設備(bei)也能產(chan)(chan)出(chu)可拉伸0.05的(de)(de)(de)銅(tong)桿.進口設備(bei)一般是芬(fen)蘭奧托昆普的(de)(de)(de)設備(bei),國(guo)產(chan)(chan)設備(bei)最好的(de)(de)(de)應(ying)該是上海的(de)(de)(de)海軍廠(chang)的(de)(de)(de)了,生(sheng)產(chan)(chan)時間最長,軍工企業(ye),質(zhi)量可靠(kao)。

低氧銅桿(gan)進口(kou)設(she)備(bei)(bei)國際(ji)主要有兩種,一種是(shi)美(mei)國南(nan)線設(she)備(bei)(bei),英(ying)文是(shi)SOUTHWIRE,國內廠(chang)家是(shi)南(nan)京華(hua)新,江西(xi)銅業,另一種是(shi)德國CONTIROD設(she)備(bei)(bei),國內廠(chang)家是(shi)常州金源,天津大無縫。

無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)及低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)上容(rong)易區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)是含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)10-20個PPM以(yi)下,但(dan)目前(qian)有(you)的(de)(de)廠家(jia)只(zhi)能做到(dao)(dao)50個PPM以(yi)下.低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子一般(ban)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)控(kong)制(zhi)在(zai)250個PPM左右(you),無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)一般(ban)采取的(de)(de)是上引法(fa),低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)是連(lian)鑄連(lian)軋,兩種產品(pin)相對(dui)而(er)(er)言低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對(dui)漆(qi)包線(xian)性(xing) 能更適應些,如(ru)柔軟性(xing),回彈角,繞線(xian)性(xing)能.但(dan)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對(dui)拉絲條件相對(dui)要(yao)苛刻些,同樣拉伸0.2的(de)(de)細絲,如(ru)果伸線(xian)條件不好(hao),普通的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)可拉而(er)(er)好(hao)的(de)(de)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)就斷(duan) 線(xian),但(dan)如(ru)果放在(zai)好(hao)的(de)(de)伸線(xian)條件,同樣的(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)說(shuo)不定就能拉到(dao)(dao)雙零(ling)五,而(er)(er)普通無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)最(zui)多(duo)只(zhi)能拉伸到(dao)(dao)0.1而(er)(er)已,當然做的(de)(de)最(zui)細的(de)(de)如(ru)雙零(ling)二卻(que)非得(de)依(yi)靠進口的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)了.目前(qian)有(you)企業嘗(chang)試用剝皮(pi)的(de)(de)方(fang)式(shi)來處理低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)來伸0.03線(xian).但(dan)有(you)關(guan)這方(fang)面的(de)(de)內容(rong)我還不是很清楚(chu)。

音響線一般反而喜歡用無(wu)氧桿(gan),這(zhe)和無(wu)氧桿(gan)是(shi)單晶銅,低氧桿(gan)是(shi)多晶銅有(you)關。

氧銅桿(gan)(gan)和無氧銅桿(gan)(gan)由(you)于(yu)制造方法的不同,致使存在差別,具有各自的特點。

一、關于氧的吸入(ru)和脫去以及它的存在狀態

生產銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)含(han)(han)氧(yang)量一(yi)般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)(chang)(chang)溫(wen)下氧(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)固溶(rong)度約2ppm。低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)(de)含(han)(han)氧(yang)量一(yi)般在(zai)(zai)(zai)200(175)—400(450)ppm,因(yin)此氧(yang)的(de)(de)進入是(shi)(shi)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)液(ye)態(tai)下吸入的(de)(de),而(er)上引法無氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則(ze)相反,氧(yang)在(zai)(zai)(zai)液(ye)態(tai)銅(tong)(tong)(tong)(tong)(tong)下保持相當時間后,被還原而(er)脫去,通常(chang)(chang)(chang)這種(zhong)桿(gan)(gan)(gan)(gan)的(de)(de)含(han)(han)氧(yang)量都在(zai)(zai)(zai)10—50ppm以(yi)(yi)下,最低(di)(di)可達1-2ppm,從組織(zhi)上看,低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang),以(yi)(yi)氧(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)于晶粒邊界附(fu)近,這對(dui)低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)而(er)言可以(yi)(yi)說是(shi)(shi)常(chang)(chang)(chang)見的(de)(de)但對(dui)無氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則(ze)很(hen)少見。氧(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形式在(zai)(zai)(zai)晶界出現(xian)對(dui)材料的(de)(de)韌(ren)性產生負面(mian)影響。而(er)無氧(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)很(hen)低(di)(di),所以(yi)(yi)這種(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)組織(zhi)是(shi)(shi)均勻的(de)(de)單相組織(zhi)對(dui)韌(ren)性有利(li)。在(zai)(zai)(zai)無氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中的(de)(de)多孔(kong)性是(shi)(shi)不常(chang)(chang)(chang)見的(de)(de),而(er)在(zai)(zai)(zai)低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中則(ze)是(shi)(shi)常(chang)(chang)(chang)見的(de)(de)一(yi)種(zhong)缺陷。

二、熱軋組(zu)織和鑄造組(zu)織的區(qu)別(bie)

低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)由于(yu)經過(guo)熱(re)軋,所(suo)以(yi)其(qi)組(zu)織(zhi)屬熱(re)加工組(zu)織(zhi),原來的(de)鑄(zhu)造組(zu)織(zhi)已經破碎,在(zai)8mm的(de)桿(gan)時已有再結晶(jing)(jing)的(de)形(xing)式出現,而無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)屬鑄(zhu)造組(zu)織(zhi),晶(jing)(jing)粒(li)粗大(da),這是為什(shen)么,無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅的(de)再結晶(jing)(jing)溫度較高(gao)(gao),需(xu)要較高(gao)(gao)退(tui)(tui)火(huo)(huo)溫度的(de)固有原因。這是因為,再結晶(jing)(jing)發生在(zai)晶(jing)(jing)粒(li)邊界(jie)(jie)附近(jin),無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)組(zu)織(zhi)晶(jing)(jing)粒(li)粗大(da),晶(jing)(jing)粒(li)尺寸甚至能達幾個毫米,因而晶(jing)(jing)粒(li)邊界(jie)(jie)少(shao),即使通過(guo)拉制(zhi)(zhi)變形(xing),但晶(jing)(jing)粒(li)邊界(jie)(jie)相對(dui)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)還(huan)是較少(shao),所(suo)以(yi)需(xu)要較高(gao)(gao)的(de)退(tui)(tui)火(huo)(huo)功率(lv)(lv)。對(dui)無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅成功的(de)退(tui)(tui)火(huo)(huo)要求(qiu)是:由桿(gan)經拉制(zhi)(zhi),但尚(shang)未鑄(zhu)造組(zu)織(zhi)的(de)線時的(de)第一(yi)次退(tui)(tui)火(huo)(huo),其(qi)退(tui)(tui)火(huo)(huo)功率(lv)(lv)應比同樣情況的(de)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅高(gao)(gao)10——15%。經繼續拉制(zhi)(zhi),在(zai)以(yi)后階(jie)段(duan)的(de)退(tui)(tui)火(huo)(huo)功率(lv)(lv)應留有足(zu)夠的(de)余(yu)量和對(dui)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅和無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅切實區別(bie)執行不(bu)同的(de)退(tui)(tui)火(huo)(huo)工藝(yi),以(yi)保證在(zai)制(zhi)(zhi)品和成品導線的(de)柔(rou)軟性。

三、夾雜,氧含量波動,表面(mian)氧化物和可能存在的熱軋缺(que)陷的差別

無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)的可拉(la)性在(zai)所(suo)有(you)線(xian)(xian)徑里與低(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)相比都是優越的,除(chu)上述組織原因外,無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)夾雜(za)少(shao),含氧(yang)(yang)(yang)量穩(wen)定,無(wu)熱軋可能產(chan)生(sheng)(sheng)的缺(que)陷,桿(gan)(gan)(gan)表氧(yang)(yang)(yang)化物厚度可達≤15A。在(zai)連鑄連軋生(sheng)(sheng)產(chan)過程中如果工(gong)藝不(bu)(bu)穩(wen)定,對氧(yang)(yang)(yang)監控不(bu)(bu)嚴,含氧(yang)(yang)(yang)量不(bu)(bu)穩(wen)定將(jiang)直接(jie)影響桿(gan)(gan)(gan)的性能。如果桿(gan)(gan)(gan)的表面氧(yang)(yang)(yang)化物能在(zai)后工(gong)序的連續(xu)清洗中得以彌補(bu)外,但比較麻煩的是有(you)相當多的氧(yang)(yang)(yang)化物存在(zai)于“皮(pi)下”,對拉(la)線(xian)(xian)斷線(xian)(xian)影響更直接(jie),故而在(zai)拉(la)制微(wei)細(xi)線(xian)(xian),超微(wei)細(xi)線(xian)(xian)時(shi),為(wei)了減少(shao)斷線(xian)(xian),有(you)時(shi)要對銅桿(gan)(gan)(gan)采取不(bu)(bu)得已的辦(ban)法——剝(bo)皮(pi),甚至二次剝(bo)皮(pi)的原因所(suo)在(zai),目的要除(chu)去(qu)皮(pi)下氧(yang)(yang)(yang)化物。

四、低(di)氧銅桿和無氧銅桿的韌性(xing)有(you)差別

兩者都可以拉到(dao)0.015mm,但在(zai)低溫(wen)超導(dao)線中的低溫(wen)級無(wu)氧銅,其細(xi)絲間的間距(ju)只(zhi)有0.001mm.

五、從制桿的原(yuan)材料到制線的經濟性有差(cha)別(bie)。

制(zhi)造(zao)無(wu)氧銅(tong)(tong)桿要求質(zhi)量較(jiao)高的(de)原材料。一般,拉制(zhi)直徑(jing)>1mm的(de)銅(tong)(tong)線時,低氧銅(tong)(tong)桿的(de)優點比較(jiao)明顯,而無(wu)氧銅(tong)(tong)桿顯得更為優越的(de)是(shi)拉制(zhi)直徑(jing)<0.5mm的(de)銅(tong)(tong)線。

六(liu)、低氧銅桿(gan)的(de)制線(xian)工(gong)藝(yi)與無(wu)氧銅桿(gan)的(de)有所不同。

低(di)氧銅(tong)(tong)桿(gan)的制線工藝(yi)(yi)不能照搬到無(wu)氧銅(tong)(tong)桿(gan)的制線工藝(yi)(yi)上來(lai),至少兩(liang)者的退(tui)火工藝(yi)(yi)是不同的。因為線的柔軟性深(shen)受材料成份(fen)和制桿(gan),制線和退(tui)火工藝(yi)(yi)的影(ying)響,不能簡單地說低(di)氧銅(tong)(tong)或無(wu)氧銅(tong)(tong)誰軟誰硬。