熱門(men)關鍵(jian)詞:
來(lai)源:行(xing)業動態 閱讀(du):109467 發(fa)布(bu)時間:2019-07-05
導讀:由于生產(chan)銅(tong)桿(gan)的(de)兩者的(de)工藝不同,所生產(chan)的(de)銅(tong)桿(gan)中的(de)含(han)氧量及外(wai)觀就不同。上引生產(chan)的(de)銅(tong)桿(gan),工藝得當(dang)氧含(han)量在(zai)10ppm以下,叫(jiao)無(wu)氧銅(tong)桿(gan);連鑄連鑄生產(chan)的(de)銅(tong)桿(gan) 是(shi)在(zai)保護(hu)條件下的(de)熱軋,氧含(han)量在(zai)200-500ppm范(fan)圍(wei)內,但有時也高(gao)達700ppm以上,一般(ban)情況下,此種(zhong)方法生產(chan)的(de)銅(tong)外(wai)表(biao)光(guang)亮,低氧銅(tong)桿(gan),有時也叫(jiao)光(guang)桿(gan)。
銅(tong)桿(gan)是電纜行(xing)業的(de)主要(yao)原(yuan)料,生產(chan)(chan)的(de)方式主要(yao)有兩種(zhong)——連(lian)鑄(zhu)連(lian)軋(ya)(ya)法(fa)(fa)和上引(yin)連(lian)鑄(zhu)法(fa)(fa)。連(lian)鑄(zhu)連(lian)軋(ya)(ya)低氧銅(tong)桿(gan)的(de)生產(chan)(chan)方法(fa)(fa)較(jiao)多(duo),其特點是金(jin)屬在豎爐中融化后(hou),銅(tong)液通過保溫(wen)爐、溜槽(cao)、中間(jian)(jian)包,從澆管進入封閉的(de)模(mo)腔內,采(cai)用較(jiao)大的(de)冷(leng)卻強度進行(xing)冷(leng)卻,形成(cheng)鑄(zhu)坯,然后(hou)進行(xing)多(duo)道次(ci)軋(ya)(ya)制,生產(chan)(chan)的(de)低氧銅(tong)桿(gan)為熱(re)加(jia)工組(zu)織,原(yuan)來的(de)鑄(zhu)造(zao)組(zu)織已經破碎,含氧量一般(ban)為200~400ppm之間(jian)(jian)。無(wu)(wu)氧銅(tong)桿(gan)國內基本(ben)全(quan)部采(cai)用上引(yin)連(lian)鑄(zhu)法(fa)(fa)生產(chan)(chan),金(jin)屬在感(gan)應電爐中融化后(hou)通過石墨模(mo)進行(xing)上引(yin)連(lian)續鑄(zhu)造(zao),之后(hou)進行(xing)冷(leng)軋(ya)(ya)或冷(leng)加(jia)工,生產(chan)(chan)的(de)無(wu)(wu)氧銅(tong)桿(gan)為鑄(zhu)造(zao)組(zu)織,含氧量一般(ban)在20ppm以下(xia)。由于制造(zao)工藝(yi)的(de)不同,所以在組(zu)織結構、氧含量分布、雜質的(de)形式及分布等諸多(duo)方面有較(jiao)大差別。
一、拉制性能
銅(tong)桿的拉制性能跟(gen)很多因(yin)素有關(guan),如雜(za)質的含量(liang)、氧含量(liang)及分布、工(gong)藝控(kong)制等。下面分別從以上幾個方面對銅(tong)桿的拉制性能進行(xing)分析。
1、熔化方式(shi)對(dui)S等雜質的影響
連(lian)鑄連(lian)軋生產(chan)(chan)銅(tong)桿(gan)(gan)主要(yao)是通過氣(qi)體的(de)燃燒使銅(tong)桿(gan)(gan)熔(rong)化(hua),在燃燒的(de)過程中(zhong)(zhong),通過氧(yang)化(hua)和揮發作用,可一定(ding)程度減(jian)少部分雜質進入銅(tong)液(ye),因此連(lian)鑄連(lian)軋法對(dui)(dui)原(yuan)料要(yao)求相(xiang)對(dui)(dui)低一些。上引連(lian)鑄生產(chan)(chan)無氧(yang)銅(tong)桿(gan)(gan),由于是用感應電爐熔(rong)化(hua),電解銅(tong)表(biao)面(mian)的(de)“銅(tong)綠(lv)”“銅(tong)豆”基(ji)本都熔(rong)入到銅(tong)液(ye)中(zhong)(zhong)。其中(zhong)(zhong)熔(rong)入的(de)S對(dui)(dui)無氧(yang)銅(tong)桿(gan)(gan)塑性(xing)影響極大,會增加拉絲斷(duan)線率(lv)。
2、鑄造過(guo)程中雜質的(de)進入
在生(sheng)產過(guo)(guo)程中(zhong),連(lian)鑄(zhu)連(lian)軋(ya)(ya)工(gong)藝(yi)需通過(guo)(guo)保溫爐(lu)、溜槽(cao)、中(zhong)間包轉運銅(tong)液(ye),相(xiang)對(dui)容易(yi)造成耐(nai)(nai)火(huo)材(cai)料的(de)(de)剝落,在軋(ya)(ya)制過(guo)(guo)程中(zhong)需要(yao)通過(guo)(guo)軋(ya)(ya)輥,造成鐵質的(de)(de)脫落,會給銅(tong)桿造成外部(bu)夾(jia)雜。而熱(re)軋(ya)(ya)中(zhong)皮上(shang)(shang)和皮下氧化(hua)物(wu)的(de)(de)軋(ya)(ya)入,會給低氧桿的(de)(de)拉絲造成不利的(de)(de)影響。上(shang)(shang)引連(lian)鑄(zhu)法(fa)生(sheng)產工(gong)藝(yi)流程較(jiao)(jiao)短,銅(tong)液(ye)是通過(guo)(guo)聯體爐(lu)內潛流式完(wan)成,對(dui)耐(nai)(nai)火(huo)材(cai)料的(de)(de)沖擊不大,結晶(jing)是通過(guo)(guo)石墨模內進(jin)行,所以過(guo)(guo)程中(zhong)可(ke)能產生(sheng)的(de)(de)污染源較(jiao)(jiao)少,雜質進(jin)入的(de)(de)機會較(jiao)(jiao)少。
O、S、P是與銅(tong)(tong)(tong)會生產化合物的元素。在熔(rong)態(tai)銅(tong)(tong)(tong)中,氧(yang)(yang)可以溶(rong)解(jie)一(yi)部分,但當銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)幾乎不溶(rong)解(jie)于銅(tong)(tong)(tong)中。熔(rong)態(tai)時所溶(rong)解(jie)的氧(yang)(yang),以銅(tong)(tong)(tong)=氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)(gong)晶體析(xi)出,分布在晶粒晶界處(chu)。銅(tong)(tong)(tong)-氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)(gong)晶體的出現,顯著降低了銅(tong)(tong)(tong)的塑(su)性。
硫可(ke)以(yi)溶解在(zai)(zai)熔體的(de)銅中,但在(zai)(zai)室溫下,其(qi)溶解度幾乎降低(di)到零,它以(yi)硫化亞銅的(de)形式出(chu)現在(zai)(zai)晶粒晶界處(chu),會顯(xian)著降低(di)銅的(de)塑性。
3、氧(yang)在低氧(yang)銅桿和(he)無氧(yang)銅桿中分(fen)布形式及其影響
氧(yang)(yang)含量對低氧(yang)(yang)銅(tong)桿(gan)的拉線性能(neng)有著明(ming)顯的影響。當氧(yang)(yang)含量增加(jia)到(dao)最(zui)(zui)佳(jia)值(zhi)時,銅(tong)桿(gan)的斷線率(lv)最(zui)(zui)低。這是因(yin)為(wei)(wei)氧(yang)(yang)在(zai)與(yu)大(da)部分雜質反應的過(guo)程中(zhong)都起到(dao)了(le)清除器(qi)的作(zuo)用。適度的氧(yang)(yang)還有利(li)于去除銅(tong)液中(zhong)的氫(qing),生成水蒸氣(qi)溢(yi)出,減少氣(qi)孔(kong)的形成。最(zui)(zui)佳(jia)的氧(yang)(yang)含量為(wei)(wei)拉線工藝提供(gong)了(le)最(zui)(zui)好的條件(jian)。
低氧(yang)(yang)銅(tong)桿(gan)(gan)氧(yang)(yang)化(hua)(hua)(hua)(hua)物(wu)的分布(bu):在連續(xu)澆鑄中凝(ning)固(gu)的最初階段,散熱速率和均(jun)勻冷卻(que)(que)是(shi)決定銅(tong)桿(gan)(gan)氧(yang)(yang)化(hua)(hua)(hua)(hua)物(wu)分布(bu)的主要因素。不均(jun)勻冷卻(que)(que)會(hui)引起銅(tong)桿(gan)(gan)內部結構(gou)本質上的差異(yi),但后續(xu)的熱加(jia)工(gong),柱(zhu)狀晶通(tong)常會(hui)遭到(dao)破壞,使氧(yang)(yang)化(hua)(hua)(hua)(hua)亞銅(tong)顆粒(li)(li)(li)細微化(hua)(hua)(hua)(hua)和均(jun)勻分布(bu)。氧(yang)(yang)化(hua)(hua)(hua)(hua)物(wu)顆粒(li)(li)(li)聚集(ji)而產生的典型(xing)情(qing)況是(shi)中心(xin)爆裂(lie)。除(chu)氧(yang)(yang)化(hua)(hua)(hua)(hua)物(wu)顆粒(li)(li)(li)分布(bu)的影響外,具有較(jiao)小氧(yang)(yang)化(hua)(hua)(hua)(hua)物(wu)顆粒(li)(li)(li)的銅(tong)桿(gan)(gan)顯示出較(jiao)好(hao)的拉線特性(xing),較(jiao)大的Cu2O顆粒(li)(li)(li)容易造成應力集(ji)中點而斷(duan)裂(lie)。
無(wu)氧(yang)銅(tong)(tong)(tong)含(han)(han)氧(yang)量超標(biao),銅(tong)(tong)(tong)桿變脆,延(yan)伸(shen)率(lv)(lv)下降(jiang),拉(la)伸(shen)式樣端口顯暗紅色,結(jie)晶組(zu)織疏松。當氧(yang)含(han)(han)量超出8ppm時,工藝性能變差(cha),表現為(wei)鑄(zhu)造(zao)及(ji)拉(la)伸(shen)過(guo)程中(zhong)斷桿及(ji)斷線率(lv)(lv)極具(ju)增高(gao)。這是(shi)由于氧(yang)能與銅(tong)(tong)(tong)生成氧(yang)化亞銅(tong)(tong)(tong)脆性相,形成銅(tong)(tong)(tong)-氧(yang)化亞銅(tong)(tong)(tong)共晶體(ti),以(yi)網狀組(zu)織分(fen)布(bu)在(zai)境界上(shang)(shang)。這種脆性相硬度(du)高(gao),在(zai)冷變形時將會與銅(tong)(tong)(tong)機體(ti)脫離,導致銅(tong)(tong)(tong)桿的機械性能下降(jiang),在(zai)后續加(jia)工中(zhong)容易(yi)造(zao)成斷裂現象。氧(yang)含(han)(han)量高(gao)還能導致無(wu)氧(yang)銅(tong)(tong)(tong)桿導電率(lv)(lv)下降(jiang)。因此,必須嚴(yan)格控(kong)制上(shang)(shang)引連(lian)鑄(zhu)工藝及(ji)產品質量。
4、氫的影響
在(zai)上引連鑄(zhu)中,氧(yang)含量控制較(jiao)低,氧(yang)化物(wu)的副作(zuo)用唄(bai)**降低,但氫的影響成為較(jiao)顯著的問題。吸氣后熔體中存在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)(qi)體及疏松是在(zai)結(jie)晶的(de)過(guo)(guo)程中,氫(qing)(qing)從(cong)過(guo)(guo)飽(bao)和的(de)溶液(ye)中析(xi)(xi)出并聚集(ji)而(er)(er)形(xing)成(cheng)(cheng)的(de)。在(zai)結(jie)晶前(qian)析(xi)(xi)出的(de)氫(qing)(qing)又可還原氧化亞銅(tong)而(er)(er)生成(cheng)(cheng)水氣(qi)(qi)(qi)(qi)泡。由于上(shang)(shang)(shang)(shang)引鑄造(zao)的(de)特點是銅(tong)液(ye)自(zi)上(shang)(shang)(shang)(shang)而(er)(er)下的(de)結(jie)晶,形(xing)成(cheng)(cheng)的(de)液(ye)**形(xing)狀(zhuang)近似錐型(xing)。銅(tong)液(ye)結(jie)晶前(qian)析(xi)(xi)出的(de)氣(qi)(qi)(qi)(qi)體在(zai)上(shang)(shang)(shang)(shang)浮過(guo)(guo)程中被堵在(zai)凝固組(zu)織(zhi)內,結(jie)晶時(shi)在(zai)鑄桿內形(xing)成(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔。上(shang)(shang)(shang)(shang)引的(de)含氣(qi)(qi)(qi)(qi)量少時(shi),析(xi)(xi)出的(de)氫(qing)(qing)存(cun)在(zai)于晶界處,形(xing)成(cheng)(cheng)疏松;含氣(qi)(qi)(qi)(qi)量多時(shi),則聚集(ji)成(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔,因此(ci),氣(qi)(qi)(qi)(qi)孔和疏松是氫(qing)(qing)氣(qi)(qi)(qi)(qi)和水蒸氣(qi)(qi)(qi)(qi)兩者形(xing)成(cheng)(cheng)的(de)。
氫來源(yuan)于上引生產(chan)過程中(zhong)的(de)各個工藝環(huan)節,如原料(liao)電解(jie)銅(tong)的(de)“銅(tong)綠(lv)”、輔(fu)料(liao)木(mu)炭**、氣候環(huan)境(jing)**、石墨結(jie)晶器未(wei)干(gan)燥等(deng)。因(yin)此,熔化爐中(zhong)的(de)銅(tong)液表(biao)面應覆蓋經烘烤的(de)木(mu)炭,電解(jie)銅(tong)應盡量去除(chu)“銅(tong)綠(lv)”、“銅(tong)豆”“耳(er)朵”,對(dui)提高無氧銅(tong)桿質量非常重要。
在連鑄連軋工藝中(zhong),往往采用(yong)適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由(you)于銅(tong)液在鑄(zhu)造過程中是(shi)自下而上(shang)結晶,銅(tong)液中的(de)氧和氫(qing)所產(chan)生的(de)水蒸氣很(hen)容易上(shang)浮跑出,銅(tong)液中的(de)氫(qing)大部分能被有效(xiao)去除(chu),因(yin)而對銅(tong)桿的(de)影響較小。
二、表面質量
在(zai)生產電磁線等產品的過(guo)程中,對銅桿(gan)的表(biao)面(mian)質量也(ye)需提出要(yao)求。需要(yao)拉制(zhi)后的銅絲表(biao)面(mian)無毛(mao)刺、銅粉少(shao)、無油污。并通過(guo)扭轉(zhuan)試驗測(ce)量表(biao)面(mian)銅粉的質量和(he)扭轉(zhuan)后觀察銅桿(gan)的復原情況來判定(ding)其好壞。
在(zai)連鑄連軋(ya)過(guo)程中,從鑄造到軋(ya)制前,溫度高,完全暴露于空氣中,使鑄坯表(biao)(biao)面形(xing)成較厚的氧化(hua)層,在(zai)軋(ya)制過(guo)程中,隨著(zhu)軋(ya)輥的轉動(dong),氧化(hua)物(wu)顆粒軋(ya)入銅線表(biao)(biao)面。由于氧化(hua)亞銅是高熔點脆性化(hua)合物(wu),對于軋(ya)入較深的氧化(hua)亞銅,當成條狀(zhuang)的聚集物(wu)遇模(mo)具拉伸時(shi),就會是銅桿外表(biao)(biao)面產生毛(mao)刺,給(gei)后續(xu)的涂漆造成麻煩(fan)。
而上(shang)引連鑄(zhu)工藝制造(zao)(zao)的無氧銅桿,由于鑄(zhu)造(zao)(zao)和冷卻完(wan)全與氧隔絕,后續(xu)亦(yi)無熱(re)軋過程(cheng),銅桿表面(mian)(mian)無軋入表面(mian)(mian)的氧化物,質量較(jiao)好,拉制后銅粉(fen)少,上(shang)述問題較(jiao)少存在。
無氧銅桿也分進(jin)口設(she)備做的(de)(de)和(he)國產(chan)設(she)備做的(de)(de),但目前進(jin)口產(chan)品(pin)已無明顯優勢,銅桿產(chan)品(pin)出來后(hou)區(qu)別不是(shi)很大(da),只(zhi)要銅板選的(de)(de)好,生產(chan)控制比較(jiao)穩定,國產(chan)設(she)備也能產(chan)出可拉伸0.05的(de)(de)銅桿.進(jin)口設(she)備一般是(shi)芬蘭奧托昆普的(de)(de)設(she)備,國產(chan)設(she)備最好的(de)(de)應該是(shi)上海的(de)(de)海軍(jun)廠的(de)(de)了,生產(chan)時間最長,軍(jun)工企業(ye),質量可靠。
低(di)氧銅(tong)(tong)桿進口(kou)設備(bei)(bei)國際主要有兩種,一種是美國南線設備(bei)(bei),英文(wen)是SOUTHWIRE,國內(nei)廠(chang)(chang)家是南京華新,江西銅(tong)(tong)業,另一種是德國CONTIROD設備(bei)(bei),國內(nei)廠(chang)(chang)家是常州金源,天津大無縫。
無(wu)(wu)氧(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)量上(shang)容(rong)(rong)易區別,無(wu)(wu)氧(yang)(yang)(yang)銅是(shi)(shi)(shi)含(han)氧(yang)(yang)(yang)量在(zai)(zai)10-20個(ge)PPM以下(xia),但(dan)(dan)目(mu)前有(you)的(de)(de)廠家只(zhi)(zhi)能(neng)做到50個(ge)PPM以下(xia).低(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)桿(gan)(gan)(gan)子一(yi)(yi)般(ban)含(han)氧(yang)(yang)(yang)量控制在(zai)(zai)250個(ge)PPM左右,無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)一(yi)(yi)般(ban)采(cai)取的(de)(de)是(shi)(shi)(shi)上(shang)引(yin)法,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)(shi)(shi)連(lian)鑄(zhu)連(lian)軋,兩種產品相(xiang)對(dui)而(er)言低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)漆包線(xian)性(xing) 能(neng)更(geng)適應些,如(ru)(ru)柔軟性(xing),回彈(dan)角(jiao),繞線(xian)性(xing)能(neng).但(dan)(dan)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)拉絲(si)(si)條件(jian)相(xiang)對(dui)要苛刻些,同樣(yang)拉伸(shen)(shen)0.2的(de)(de)細(xi)絲(si)(si),如(ru)(ru)果(guo)伸(shen)(shen)線(xian)條件(jian)不(bu)好,普通的(de)(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉而(er)好的(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就(jiu)斷 線(xian),但(dan)(dan)如(ru)(ru)果(guo)放在(zai)(zai)好的(de)(de)伸(shen)(shen)線(xian)條件(jian),同樣(yang)的(de)(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不(bu)定就(jiu)能(neng)拉到雙(shuang)零(ling)五,而(er)普通無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)最多(duo)只(zhi)(zhi)能(neng)拉伸(shen)(shen)到0.1而(er)已,當然做的(de)(de)最細(xi)的(de)(de)如(ru)(ru)雙(shuang)零(ling)二卻非得依(yi)靠進口(kou)的(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)了.目(mu)前有(you)企業嘗試用(yong)剝皮的(de)(de)方(fang)式來處理低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)(shen)0.03線(xian).但(dan)(dan)有(you)關這(zhe)方(fang)面的(de)(de)內容(rong)(rong)我還不(bu)是(shi)(shi)(shi)很清楚(chu)。
音響(xiang)線一般反而喜歡用無氧桿,這和(he)無氧桿是(shi)單晶銅(tong),低氧桿是(shi)多晶銅(tong)有關。
氧(yang)銅桿和無氧(yang)銅桿由于制造方法(fa)的不同,致使存(cun)在(zai)差別(bie),具有各(ge)自(zi)的特點。
一、關于(yu)氧的吸入和脫去以及(ji)它的存在狀態
生(sheng)產(chan)銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一般在(zai)10—50ppm,在(zai)常溫下氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)固溶(rong)度約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一般在(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)進入(ru)是(shi)在(zai)銅(tong)(tong)(tong)的(de)(de)(de)液態(tai)(tai)下吸入(ru)的(de)(de)(de),而上引法(fa)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)則相(xiang)反(fan),氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液態(tai)(tai)銅(tong)(tong)(tong)下保(bao)持相(xiang)當時(shi)間后(hou),被還原而脫(tuo)去(qu),通常這(zhe)種桿(gan)(gan)(gan)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量都在(zai)10—50ppm以(yi)下,最低(di)(di)(di)可達1-2ppm,從(cong)組織上看,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)狀態(tai)(tai),存(cun)在(zai)于晶(jing)粒邊界附(fu)近,這(zhe)對(dui)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)而言可以(yi)說(shuo)是(shi)常見(jian)(jian)的(de)(de)(de)但(dan)對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)則很少(shao)見(jian)(jian)。氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)以(yi)夾雜形(xing)式在(zai)晶(jing)界出現對(dui)材料的(de)(de)(de)韌(ren)性(xing)(xing)產(chan)生(sheng)負面影(ying)響。而無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)很低(di)(di)(di),所以(yi)這(zhe)種銅(tong)(tong)(tong)的(de)(de)(de)組織是(shi)均勻的(de)(de)(de)單相(xiang)組織對(dui)韌(ren)性(xing)(xing)有利。在(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)的(de)(de)(de)多(duo)孔性(xing)(xing)是(shi)不常見(jian)(jian)的(de)(de)(de),而在(zai)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)則是(shi)常見(jian)(jian)的(de)(de)(de)一種缺陷(xian)。
二、熱軋組織(zhi)(zhi)和鑄造組織(zhi)(zhi)的區別
低氧(yang)(yang)銅(tong)(tong)桿(gan)由(you)于經(jing)過熱(re)軋,所以(yi)其(qi)組(zu)織(zhi)屬熱(re)加工組(zu)織(zhi),原來(lai)的(de)(de)鑄(zhu)(zhu)造組(zu)織(zhi)已(yi)經(jing)破碎,在8mm的(de)(de)桿(gan)時(shi)已(yi)有再(zai)結晶(jing)的(de)(de)形(xing)式出現,而無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)屬鑄(zhu)(zhu)造組(zu)織(zhi),晶(jing)粒(li)粗大(da),這是(shi)為什么,無(wu)氧(yang)(yang)銅(tong)(tong)的(de)(de)再(zai)結晶(jing)溫度較(jiao)高,需(xu)要(yao)(yao)較(jiao)高退(tui)火(huo)溫度的(de)(de)固有原因(yin)。這是(shi)因(yin)為,再(zai)結晶(jing)發生(sheng)在晶(jing)粒(li)邊界附近,無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)組(zu)織(zhi)晶(jing)粒(li)粗大(da),晶(jing)粒(li)尺寸甚至能(neng)達幾(ji)個毫米,因(yin)而晶(jing)粒(li)邊界少(shao)(shao),即(ji)使通過拉制(zhi)變形(xing),但晶(jing)粒(li)邊界相對低氧(yang)(yang)銅(tong)(tong)桿(gan)還是(shi)較(jiao)少(shao)(shao),所以(yi)需(xu)要(yao)(yao)較(jiao)高的(de)(de)退(tui)火(huo)功(gong)率。對無(wu)氧(yang)(yang)銅(tong)(tong)成功(gong)的(de)(de)退(tui)火(huo)要(yao)(yao)求是(shi):由(you)桿(gan)經(jing)拉制(zhi),但尚未鑄(zhu)(zhu)造組(zu)織(zhi)的(de)(de)線時(shi)的(de)(de)第(di)一(yi)次退(tui)火(huo),其(qi)退(tui)火(huo)功(gong)率應(ying)比同樣情況的(de)(de)低氧(yang)(yang)銅(tong)(tong)高10——15%。經(jing)繼續拉制(zhi),在以(yi)后階段的(de)(de)退(tui)火(huo)功(gong)率應(ying)留(liu)有足夠的(de)(de)余量和對低氧(yang)(yang)銅(tong)(tong)和無(wu)氧(yang)(yang)銅(tong)(tong)切實(shi)區別(bie)執行不同的(de)(de)退(tui)火(huo)工藝,以(yi)保(bao)證在制(zhi)品和成品導線的(de)(de)柔軟性。
三(san)、夾雜,氧含(han)量(liang)波(bo)動,表面氧化物和可(ke)能存在的熱軋缺陷的差別
無氧(yang)(yang)銅桿(gan)的(de)可(ke)(ke)拉(la)性(xing)在(zai)所有(you)線(xian)徑里(li)與低氧(yang)(yang)銅桿(gan)相比都是優越(yue)的(de),除(chu)上述組織(zhi)原(yuan)因(yin)外,無氧(yang)(yang)銅桿(gan)夾雜少,含(han)氧(yang)(yang)量(liang)穩(wen)定,無熱軋可(ke)(ke)能產生(sheng)的(de)缺陷,桿(gan)表氧(yang)(yang)化物厚度(du)可(ke)(ke)達≤15A。在(zai)連(lian)鑄連(lian)軋生(sheng)產過程中如果工藝不穩(wen)定,對氧(yang)(yang)監控不嚴(yan),含(han)氧(yang)(yang)量(liang)不穩(wen)定將(jiang)直接影響(xiang)桿(gan)的(de)性(xing)能。如果桿(gan)的(de)表面氧(yang)(yang)化物能在(zai)后(hou)工序的(de)連(lian)續(xu)清洗中得以彌(mi)補外,但比較麻煩的(de)是有(you)相當多的(de)氧(yang)(yang)化物存(cun)在(zai)于(yu)“皮(pi)下(xia)”,對拉(la)線(xian)斷線(xian)影響(xiang)更直接,故(gu)而(er)在(zai)拉(la)制微(wei)(wei)細(xi)線(xian),超微(wei)(wei)細(xi)線(xian)時,為了減(jian)少斷線(xian),有(you)時要對銅桿(gan)采取不得已(yi)的(de)辦(ban)法——剝(bo)皮(pi),甚至二次剝(bo)皮(pi)的(de)原(yuan)因(yin)所在(zai),目的(de)要除(chu)去皮(pi)下(xia)氧(yang)(yang)化物。
四、低氧銅桿和無(wu)氧銅桿的(de)韌(ren)性(xing)有差別
兩者都可以拉到0.015mm,但在低(di)溫(wen)超導(dao)線中的(de)低(di)溫(wen)級無氧銅,其細絲間(jian)的(de)間(jian)距(ju)只有0.001mm.
五(wu)、從制桿(gan)的(de)原材料到制線的(de)經濟性有差別。
制造無氧(yang)(yang)銅(tong)(tong)(tong)桿要(yao)求質量較高的(de)原材料(liao)。一般,拉(la)制直徑>1mm的(de)銅(tong)(tong)(tong)線時,低(di)氧(yang)(yang)銅(tong)(tong)(tong)桿的(de)優(you)點比較明顯(xian),而無氧(yang)(yang)銅(tong)(tong)(tong)桿顯(xian)得更為(wei)優(you)越的(de)是(shi)拉(la)制直徑<0.5mm的(de)銅(tong)(tong)(tong)線。
六、低(di)氧銅(tong)桿的制(zhi)線工(gong)藝(yi)與(yu)無(wu)氧銅(tong)桿的有(you)所不同。
低(di)氧銅(tong)(tong)桿(gan)的(de)制(zhi)(zhi)線工藝不(bu)能照搬到(dao)無氧銅(tong)(tong)桿(gan)的(de)制(zhi)(zhi)線工藝上來,至少兩者的(de)退火工藝是(shi)不(bu)同的(de)。因為(wei)線的(de)柔軟性深受(shou)材(cai)料成份和(he)制(zhi)(zhi)桿(gan),制(zhi)(zhi)線和(he)退火工藝的(de)影響(xiang),不(bu)能簡單(dan)地說(shuo)低(di)氧銅(tong)(tong)或(huo)無氧銅(tong)(tong)誰軟誰硬。
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