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虎林電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱讀(du):109586 發布(bu)時間:2019-07-05

導讀:由于生(sheng)產銅(tong)桿(gan)(gan)的(de)兩(liang)者(zhe)的(de)工藝不同(tong),所生(sheng)產的(de)銅(tong)桿(gan)(gan)中的(de)含(han)氧(yang)(yang)量(liang)及(ji)外觀(guan)就不同(tong)。上引生(sheng)產的(de)銅(tong)桿(gan)(gan),工藝得當氧(yang)(yang)含(han)量(liang)在(zai)10ppm以下,叫無氧(yang)(yang)銅(tong)桿(gan)(gan);連鑄連鑄生(sheng)產的(de)銅(tong)桿(gan)(gan) 是在(zai)保護(hu)條件下的(de)熱軋,氧(yang)(yang)含(han)量(liang)在(zai)200-500ppm范圍內,但有時也(ye)高(gao)達700ppm以上,一般(ban)情(qing)況下,此種方法(fa)生(sheng)產的(de)銅(tong)外表光(guang)亮,低(di)氧(yang)(yang)銅(tong)桿(gan)(gan),有時也(ye)叫光(guang)桿(gan)(gan)。

銅(tong)桿(gan)是電纜(lan)行(xing)業的(de)(de)(de)(de)(de)主要原料,生(sheng)產的(de)(de)(de)(de)(de)方式(shi)主要有(you)兩種——連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)(ya)法(fa)和上(shang)(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)(zhu)法(fa)。連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)(ya)低氧銅(tong)桿(gan)的(de)(de)(de)(de)(de)生(sheng)產方法(fa)較(jiao)多(duo),其特(te)點是金屬(shu)在豎爐中融化(hua)后,銅(tong)液(ye)通(tong)過(guo)保(bao)溫爐、溜槽、中間包,從澆管(guan)進(jin)入封閉的(de)(de)(de)(de)(de)模腔內,采用(yong)較(jiao)大的(de)(de)(de)(de)(de)冷卻強度進(jin)行(xing)冷卻,形成鑄(zhu)(zhu)(zhu)坯,然(ran)后進(jin)行(xing)多(duo)道(dao)次軋(ya)(ya)制(zhi)(zhi),生(sheng)產的(de)(de)(de)(de)(de)低氧銅(tong)桿(gan)為熱加(jia)工組織,原來(lai)的(de)(de)(de)(de)(de)鑄(zhu)(zhu)(zhu)造(zao)(zao)組織已經破碎(sui),含氧量(liang)一般為200~400ppm之間。無氧銅(tong)桿(gan)國內基本全(quan)部采用(yong)上(shang)(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)(zhu)法(fa)生(sheng)產,金屬(shu)在感應電爐中融化(hua)后通(tong)過(guo)石墨(mo)模進(jin)行(xing)上(shang)(shang)引(yin)連(lian)(lian)續鑄(zhu)(zhu)(zhu)造(zao)(zao),之后進(jin)行(xing)冷軋(ya)(ya)或(huo)冷加(jia)工,生(sheng)產的(de)(de)(de)(de)(de)無氧銅(tong)桿(gan)為鑄(zhu)(zhu)(zhu)造(zao)(zao)組織,含氧量(liang)一般在20ppm以(yi)下。由于制(zhi)(zhi)造(zao)(zao)工藝(yi)的(de)(de)(de)(de)(de)不(bu)同(tong),所以(yi)在組織結構、氧含量(liang)分(fen)布(bu)、雜質的(de)(de)(de)(de)(de)形式(shi)及分(fen)布(bu)等諸多(duo)方面有(you)較(jiao)大差別。

一、拉制性能

銅(tong)桿的(de)(de)拉制(zhi)性能跟很(hen)多因素有關(guan),如雜質的(de)(de)含量、氧含量及分(fen)布、工(gong)藝控(kong)制(zhi)等。下面分(fen)別從以上幾個方面對銅(tong)桿的(de)(de)拉制(zhi)性能進行分(fen)析。

1、熔化(hua)方式對S等雜質的影(ying)響

連(lian)鑄連(lian)軋生(sheng)產銅(tong)(tong)(tong)(tong)(tong)桿主(zhu)要是(shi)通過(guo)氣體的(de)燃燒使銅(tong)(tong)(tong)(tong)(tong)桿熔(rong)化(hua),在(zai)燃燒的(de)過(guo)程(cheng)中,通過(guo)氧(yang)化(hua)和揮(hui)發作用(yong),可(ke)一定程(cheng)度減少部分雜(za)質(zhi)進入(ru)(ru)銅(tong)(tong)(tong)(tong)(tong)液(ye),因(yin)此連(lian)鑄連(lian)軋法對原料要求相(xiang)對低(di)一些。上引連(lian)鑄生(sheng)產無(wu)氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿,由(you)于是(shi)用(yong)感應(ying)電(dian)爐熔(rong)化(hua),電(dian)解銅(tong)(tong)(tong)(tong)(tong)表(biao)面的(de)“銅(tong)(tong)(tong)(tong)(tong)綠(lv)”“銅(tong)(tong)(tong)(tong)(tong)豆(dou)”基本都熔(rong)入(ru)(ru)到銅(tong)(tong)(tong)(tong)(tong)液(ye)中。其中熔(rong)入(ru)(ru)的(de)S對無(wu)氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿塑(su)性影響(xiang)極大,會增加拉(la)絲斷線率。

2、鑄造過程中雜質的進入

在生產過程中,連(lian)鑄連(lian)軋(ya)工藝(yi)需通過保(bao)溫(wen)爐(lu)(lu)、溜槽、中間包(bao)轉運銅(tong)液,相對容易造(zao)(zao)成(cheng)耐火材(cai)(cai)料的(de)(de)剝落,在軋(ya)制過程中需要(yao)通過軋(ya)輥,造(zao)(zao)成(cheng)鐵質的(de)(de)脫落,會(hui)給銅(tong)桿造(zao)(zao)成(cheng)外部夾雜(za)。而(er)熱軋(ya)中皮上和皮下氧化物的(de)(de)軋(ya)入,會(hui)給低(di)氧桿的(de)(de)拉(la)絲造(zao)(zao)成(cheng)不利的(de)(de)影響(xiang)。上引連(lian)鑄法(fa)生產工藝(yi)流程較短(duan),銅(tong)液是(shi)通過聯(lian)體爐(lu)(lu)內潛流式(shi)完成(cheng),對耐火材(cai)(cai)料的(de)(de)沖擊不大,結晶是(shi)通過石墨(mo)模內進行,所以過程中可能產生的(de)(de)污染源較少,雜(za)質進入的(de)(de)機會(hui)較少。

O、S、P是與(yu)銅會生(sheng)產化(hua)合物(wu)的(de)(de)元(yuan)素(su)。在(zai)熔(rong)態銅中(zhong),氧(yang)可以(yi)溶(rong)解一部分,但當銅冷凝時(shi),氧(yang)幾乎不溶(rong)解于(yu)銅中(zhong)。熔(rong)態時(shi)所溶(rong)解的(de)(de)氧(yang),以(yi)銅=氧(yang)化(hua)亞銅共(gong)晶(jing)體(ti)析(xi)出,分布在(zai)晶(jing)粒晶(jing)界處(chu)。銅-氧(yang)化(hua)亞銅共(gong)晶(jing)體(ti)的(de)(de)出現(xian),顯著降低了銅的(de)(de)塑性。

硫可以(yi)溶(rong)解在熔(rong)體的銅中(zhong),但在室(shi)溫下,其(qi)溶(rong)解度幾乎降低到零,它以(yi)硫化亞銅的形式出現在晶粒(li)晶界(jie)處,會顯著降低銅的塑(su)性。

3、氧(yang)(yang)在低氧(yang)(yang)銅桿和無氧(yang)(yang)銅桿中分布形式及其影響(xiang)

氧含量對低氧銅桿的拉(la)線性能有著明顯(xian)的影響。當(dang)氧含量增加到(dao)最(zui)佳(jia)(jia)值時,銅桿的斷線率最(zui)低。這是因為(wei)氧在與大部(bu)分雜質(zhi)反(fan)應的過(guo)程中都(dou)起到(dao)了(le)清除器的作用。適(shi)度的氧還有利于去除銅液中的氫,生成水(shui)蒸氣(qi)溢出,減少氣(qi)孔的形成。最(zui)佳(jia)(jia)的氧含量為(wei)拉(la)線工藝提供了(le)最(zui)好的條(tiao)件(jian)。

低氧(yang)(yang)銅(tong)(tong)桿氧(yang)(yang)化(hua)(hua)物的(de)(de)分(fen)布(bu):在連續(xu)澆鑄中(zhong)凝固的(de)(de)最初階(jie)段,散熱速率和均勻(yun)冷(leng)卻(que)(que)是決定銅(tong)(tong)桿氧(yang)(yang)化(hua)(hua)物分(fen)布(bu)的(de)(de)主要因素。不均勻(yun)冷(leng)卻(que)(que)會(hui)引起銅(tong)(tong)桿內部結構本質上的(de)(de)差(cha)異,但后續(xu)的(de)(de)熱加工,柱狀(zhuang)晶通(tong)常會(hui)遭到破(po)壞,使氧(yang)(yang)化(hua)(hua)亞銅(tong)(tong)顆(ke)粒(li)細微化(hua)(hua)和均勻(yun)分(fen)布(bu)。氧(yang)(yang)化(hua)(hua)物顆(ke)粒(li)聚集而產(chan)生(sheng)的(de)(de)典型(xing)情況是中(zhong)心(xin)爆裂(lie)(lie)。除氧(yang)(yang)化(hua)(hua)物顆(ke)粒(li)分(fen)布(bu)的(de)(de)影(ying)響(xiang)外,具有(you)較小氧(yang)(yang)化(hua)(hua)物顆(ke)粒(li)的(de)(de)銅(tong)(tong)桿顯示(shi)出較好(hao)的(de)(de)拉線特(te)性,較大的(de)(de)Cu2O顆(ke)粒(li)容易造成應力集中(zhong)點而斷裂(lie)(lie)。

無氧銅(tong)(tong)(tong)含(han)氧量超(chao)標,銅(tong)(tong)(tong)桿(gan)(gan)變(bian)脆(cui),延伸率下(xia)降,拉伸式(shi)樣端口顯暗(an)紅色,結晶組織(zhi)疏(shu)松。當氧含(han)量超(chao)出(chu)8ppm時(shi),工藝(yi)性(xing)(xing)能變(bian)差,表現(xian)為(wei)鑄造(zao)及(ji)拉伸過程中斷(duan)(duan)桿(gan)(gan)及(ji)斷(duan)(duan)線率極具增高(gao)(gao)。這是由于氧能與銅(tong)(tong)(tong)生成(cheng)氧化亞(ya)銅(tong)(tong)(tong)脆(cui)性(xing)(xing)相,形成(cheng)銅(tong)(tong)(tong)-氧化亞(ya)銅(tong)(tong)(tong)共(gong)晶體(ti),以網狀組織(zhi)分布在(zai)(zai)境界上。這種脆(cui)性(xing)(xing)相硬度高(gao)(gao),在(zai)(zai)冷變(bian)形時(shi)將會(hui)與銅(tong)(tong)(tong)機體(ti)脫離,導致銅(tong)(tong)(tong)桿(gan)(gan)的機械性(xing)(xing)能下(xia)降,在(zai)(zai)后續加工中容(rong)易(yi)造(zao)成(cheng)斷(duan)(duan)裂現(xian)象。氧含(han)量高(gao)(gao)還能導致無氧銅(tong)(tong)(tong)桿(gan)(gan)導電率下(xia)降。因此,必須嚴格(ge)控(kong)制上引連鑄工藝(yi)及(ji)產品質(zhi)量。

4、氫的影響

在上引連鑄(zhu)中(zhong),氧(yang)含量控制較(jiao)低,氧(yang)化物的(de)副(fu)作用唄**降低,但氫(qing)的(de)影響成為較(jiao)顯著的(de)問題。吸(xi)氣后熔體中(zhong)存在平(ping)衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)(qi)體及(ji)疏松(song)是在(zai)結(jie)(jie)晶(jing)的(de)(de)(de)過(guo)程中,氫從(cong)過(guo)飽和(he)的(de)(de)(de)溶液中析(xi)(xi)出(chu)并聚集而(er)形(xing)(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)。在(zai)結(jie)(jie)晶(jing)前(qian)析(xi)(xi)出(chu)的(de)(de)(de)氫又可(ke)還原氧(yang)化(hua)亞銅而(er)生成(cheng)(cheng)(cheng)水氣(qi)(qi)(qi)(qi)泡(pao)。由于上引鑄(zhu)造(zao)的(de)(de)(de)特點是銅液自上而(er)下的(de)(de)(de)結(jie)(jie)晶(jing),形(xing)(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)液**形(xing)(xing)(xing)狀(zhuang)近似錐型。銅液結(jie)(jie)晶(jing)前(qian)析(xi)(xi)出(chu)的(de)(de)(de)氣(qi)(qi)(qi)(qi)體在(zai)上浮過(guo)程中被堵在(zai)凝(ning)固組(zu)織內,結(jie)(jie)晶(jing)時(shi)在(zai)鑄(zhu)桿內形(xing)(xing)(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔。上引的(de)(de)(de)含氣(qi)(qi)(qi)(qi)量少時(shi),析(xi)(xi)出(chu)的(de)(de)(de)氫存在(zai)于晶(jing)界處,形(xing)(xing)(xing)成(cheng)(cheng)(cheng)疏松(song);含氣(qi)(qi)(qi)(qi)量多時(shi),則聚集成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔,因(yin)此,氣(qi)(qi)(qi)(qi)孔和(he)疏松(song)是氫氣(qi)(qi)(qi)(qi)和(he)水蒸氣(qi)(qi)(qi)(qi)兩者形(xing)(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)。

氫(qing)來(lai)源于上引生產過程中(zhong)的(de)各個工藝環節(jie),如原料(liao)(liao)電解(jie)銅(tong)(tong)(tong)的(de)“銅(tong)(tong)(tong)綠”、輔料(liao)(liao)木炭**、氣候環境**、石墨結晶器未干(gan)燥等。因此,熔(rong)化爐中(zhong)的(de)銅(tong)(tong)(tong)液表面應覆蓋經(jing)烘烤的(de)木炭,電解(jie)銅(tong)(tong)(tong)應盡量(liang)去除“銅(tong)(tong)(tong)綠”、“銅(tong)(tong)(tong)豆(dou)”“耳朵”,對(dui)提高無氧銅(tong)(tong)(tong)桿(gan)質量(liang)非常重(zhong)要。

在連鑄連軋工藝中,往往采用(yong)適(shi)度控制(zhi)氧(yang)含量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O

由于銅液(ye)在鑄造過程中(zhong)是自下(xia)而(er)上結晶,銅液(ye)中(zhong)的(de)氧和氫(qing)所(suo)產生的(de)水蒸氣很容易(yi)上浮(fu)跑出,銅液(ye)中(zhong)的(de)氫(qing)大部分能被有效(xiao)去(qu)除,因而(er)對銅桿的(de)影(ying)響較小。

二、表面質量

在(zai)生產電磁線等產品(pin)的過(guo)程中,對(dui)銅(tong)(tong)桿的表面(mian)質(zhi)量(liang)也需提(ti)出要求(qiu)。需要拉制后的銅(tong)(tong)絲表面(mian)無(wu)毛刺、銅(tong)(tong)粉少、無(wu)油污。并(bing)通過(guo)扭轉(zhuan)(zhuan)試驗(yan)測(ce)量(liang)表面(mian)銅(tong)(tong)粉的質(zhi)量(liang)和扭轉(zhuan)(zhuan)后觀察(cha)銅(tong)(tong)桿的復原情況來判(pan)定其好壞。

在連鑄連軋(ya)過程(cheng)中,從鑄造到軋(ya)制(zhi)前,溫(wen)度(du)高(gao),完(wan)全暴露(lu)于(yu)(yu)空氣(qi)中,使(shi)鑄坯表面(mian)形成較(jiao)厚的氧(yang)化層,在軋(ya)制(zhi)過程(cheng)中,隨著軋(ya)輥(gun)的轉(zhuan)動,氧(yang)化物顆(ke)粒軋(ya)入(ru)銅(tong)線表面(mian)。由于(yu)(yu)氧(yang)化亞銅(tong)是高(gao)熔點脆(cui)性化合物,對于(yu)(yu)軋(ya)入(ru)較(jiao)深的氧(yang)化亞銅(tong),當成條狀的聚集物遇模(mo)具拉伸時,就會是銅(tong)桿外表面(mian)產(chan)生毛刺,給(gei)后續的涂漆造成麻煩(fan)。

而上引連(lian)鑄工藝制造的無氧(yang)銅桿(gan),由于鑄造和冷(leng)卻完全與(yu)氧(yang)隔(ge)絕,后續(xu)亦無熱(re)軋(ya)過程,銅桿(gan)表面(mian)無軋(ya)入表面(mian)的氧(yang)化物(wu),質量較好,拉(la)制后銅粉少,上述問題較少存(cun)在。

無(wu)氧銅桿(gan)也(ye)(ye)分進口(kou)設(she)(she)(she)備(bei)做(zuo)的(de)(de)和國產(chan)(chan)設(she)(she)(she)備(bei)做(zuo)的(de)(de),但目前進口(kou)產(chan)(chan)品(pin)已無(wu)明顯(xian)優勢,銅桿(gan)產(chan)(chan)品(pin)出(chu)來后區別不是很大,只(zhi)要銅板選的(de)(de)好,生產(chan)(chan)控制比較穩定,國產(chan)(chan)設(she)(she)(she)備(bei)也(ye)(ye)能產(chan)(chan)出(chu)可拉伸(shen)0.05的(de)(de)銅桿(gan).進口(kou)設(she)(she)(she)備(bei)一般是芬蘭(lan)奧托昆普(pu)的(de)(de)設(she)(she)(she)備(bei),國產(chan)(chan)設(she)(she)(she)備(bei)最好的(de)(de)應該(gai)是上海的(de)(de)海軍廠(chang)的(de)(de)了(le),生產(chan)(chan)時間最長(chang),軍工企業(ye),質量可靠(kao)。

低氧(yang)銅桿進口設備國(guo)(guo)際(ji)主要(yao)有兩種,一(yi)種是(shi)美(mei)國(guo)(guo)南線設備,英文是(shi)SOUTHWIRE,國(guo)(guo)內廠家(jia)是(shi)南京華新,江西銅業,另一(yi)種是(shi)德國(guo)(guo)CONTIROD設備,國(guo)(guo)內廠家(jia)是(shi)常州金源,天津大無縫。

無(wu)氧(yang)(yang)(yang)(yang)及低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿從含氧(yang)(yang)(yang)(yang)量上容易區別,無(wu)氧(yang)(yang)(yang)(yang)銅(tong)是(shi)含氧(yang)(yang)(yang)(yang)量在10-20個(ge)(ge)PPM以(yi)下,但(dan)(dan)目(mu)前有的廠(chang)家(jia)只能(neng)(neng)做到50個(ge)(ge)PPM以(yi)下.低(di)(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)桿在 200-400個(ge)(ge)PPM,好(hao)的桿子(zi)一般(ban)含氧(yang)(yang)(yang)(yang)量控制在250個(ge)(ge)PPM左右(you),無(wu)氧(yang)(yang)(yang)(yang)桿一般(ban)采取的是(shi)上引法,低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿是(shi)連(lian)鑄連(lian)軋(ya),兩種產品相對(dui)(dui)而(er)言(yan)低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿對(dui)(dui)漆包線(xian)性(xing) 能(neng)(neng)更適(shi)應些(xie),如柔軟性(xing),回(hui)彈角,繞線(xian)性(xing)能(neng)(neng).但(dan)(dan)低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿對(dui)(dui)拉(la)絲條(tiao)(tiao)件(jian)相對(dui)(dui)要苛刻些(xie),同(tong)樣拉(la)伸(shen)(shen)0.2的細絲,如果伸(shen)(shen)線(xian)條(tiao)(tiao)件(jian)不(bu)好(hao),普(pu)通(tong)的無(wu)氧(yang)(yang)(yang)(yang)桿可(ke)拉(la)而(er)好(hao)的低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿就斷 線(xian),但(dan)(dan)如果放在好(hao)的伸(shen)(shen)線(xian)條(tiao)(tiao)件(jian),同(tong)樣的桿子(zi),低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿說不(bu)定(ding)就能(neng)(neng)拉(la)到雙零五,而(er)普(pu)通(tong)無(wu)氧(yang)(yang)(yang)(yang)桿最多只能(neng)(neng)拉(la)伸(shen)(shen)到0.1而(er)已,當(dang)然做的最細的如雙零二卻非得依靠進口的 無(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿了.目(mu)前有企業嘗試用(yong)剝皮(pi)的方式來(lai)處理低(di)(di)(di)氧(yang)(yang)(yang)(yang)桿來(lai)伸(shen)(shen)0.03線(xian).但(dan)(dan)有關這方面的內容我還不(bu)是(shi)很清楚。

音響(xiang)線(xian)一(yi)般反而喜歡(huan)用(yong)無(wu)氧(yang)桿(gan),這(zhe)和無(wu)氧(yang)桿(gan)是單晶(jing)銅,低氧(yang)桿(gan)是多晶(jing)銅有關。

氧銅桿(gan)和無(wu)氧銅桿(gan)由于(yu)制造方(fang)法(fa)的不(bu)同,致使存在差別,具有各自的特點。

一、關于氧的吸入和脫去(qu)以及它的存在(zai)狀(zhuang)態

生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)(de)含氧(yang)量一(yi)(yi)般(ban)在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)溫下(xia)氧(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)(de)固溶度約2ppm。低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)(de)(de)含氧(yang)量一(yi)(yi)般(ban)在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)的(de)(de)(de)(de)(de)(de)(de)進(jin)入是(shi)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)(de)液態下(xia)吸(xi)入的(de)(de)(de)(de)(de)(de)(de),而(er)上引法(fa)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則相(xiang)(xiang)反,氧(yang)在(zai)(zai)(zai)液態銅(tong)(tong)(tong)(tong)下(xia)保(bao)持相(xiang)(xiang)當(dang)時間后(hou),被還原而(er)脫去,通常(chang)這(zhe)種桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)(de)(de)含氧(yang)量都在(zai)(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低(di)(di)可達1-2ppm,從組織上看,低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)(de)氧(yang),以(yi)(yi)氧(yang)化銅(tong)(tong)(tong)(tong)狀態,存在(zai)(zai)(zai)于(yu)晶(jing)粒(li)邊界(jie)附近(jin),這(zhe)對(dui)低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)而(er)言可以(yi)(yi)說是(shi)常(chang)見的(de)(de)(de)(de)(de)(de)(de)但對(dui)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則很(hen)少(shao)見。氧(yang)化銅(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形式在(zai)(zai)(zai)晶(jing)界(jie)出現對(dui)材料的(de)(de)(de)(de)(de)(de)(de)韌(ren)性(xing)(xing)產生負(fu)面(mian)影響。而(er)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)(de)氧(yang)很(hen)低(di)(di),所以(yi)(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)(de)組織是(shi)均勻的(de)(de)(de)(de)(de)(de)(de)單相(xiang)(xiang)組織對(dui)韌(ren)性(xing)(xing)有利(li)。在(zai)(zai)(zai)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)的(de)(de)(de)(de)(de)(de)(de)多孔性(xing)(xing)是(shi)不常(chang)見的(de)(de)(de)(de)(de)(de)(de),而(er)在(zai)(zai)(zai)低(di)(di)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)則是(shi)常(chang)見的(de)(de)(de)(de)(de)(de)(de)一(yi)(yi)種缺陷(xian)。

二、熱軋組織(zhi)和鑄造組織(zhi)的區(qu)別

低氧(yang)(yang)銅(tong)(tong)桿由(you)于(yu)經過(guo)熱(re)(re)軋,所以(yi)其(qi)組織(zhi)(zhi)屬熱(re)(re)加工(gong)組織(zhi)(zhi),原來(lai)的(de)(de)鑄造(zao)組織(zhi)(zhi)已經破碎(sui),在(zai)(zai)8mm的(de)(de)桿時已有再(zai)結(jie)(jie)晶(jing)(jing)的(de)(de)形(xing)式出現(xian),而無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿屬鑄造(zao)組織(zhi)(zhi),晶(jing)(jing)粒(li)(li)粗大(da),這是為什(shen)么,無(wu)(wu)氧(yang)(yang)銅(tong)(tong)的(de)(de)再(zai)結(jie)(jie)晶(jing)(jing)溫(wen)度(du)(du)較高(gao),需(xu)要較高(gao)退(tui)火溫(wen)度(du)(du)的(de)(de)固(gu)有原因(yin)。這是因(yin)為,再(zai)結(jie)(jie)晶(jing)(jing)發生在(zai)(zai)晶(jing)(jing)粒(li)(li)邊界附近(jin),無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿組織(zhi)(zhi)晶(jing)(jing)粒(li)(li)粗大(da),晶(jing)(jing)粒(li)(li)尺寸甚至能達(da)幾個毫米(mi),因(yin)而晶(jing)(jing)粒(li)(li)邊界少,即使(shi)通過(guo)拉(la)(la)制(zhi)變形(xing),但晶(jing)(jing)粒(li)(li)邊界相對(dui)低氧(yang)(yang)銅(tong)(tong)桿還(huan)是較少,所以(yi)需(xu)要較高(gao)的(de)(de)退(tui)火功率。對(dui)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)成(cheng)功的(de)(de)退(tui)火要求是:由(you)桿經拉(la)(la)制(zhi),但尚未(wei)鑄造(zao)組織(zhi)(zhi)的(de)(de)線時的(de)(de)第一次退(tui)火,其(qi)退(tui)火功率應(ying)比同樣情況的(de)(de)低氧(yang)(yang)銅(tong)(tong)高(gao)10——15%。經繼續拉(la)(la)制(zhi),在(zai)(zai)以(yi)后階段(duan)的(de)(de)退(tui)火功率應(ying)留有足夠的(de)(de)余量和對(dui)低氧(yang)(yang)銅(tong)(tong)和無(wu)(wu)氧(yang)(yang)銅(tong)(tong)切實區別執(zhi)行不(bu)同的(de)(de)退(tui)火工(gong)藝,以(yi)保證在(zai)(zai)制(zhi)品和成(cheng)品導線的(de)(de)柔軟性(xing)。

三、夾雜,氧含量波動,表面氧化物(wu)和可能存在的(de)熱(re)軋缺陷的(de)差別

無(wu)氧(yang)銅(tong)桿(gan)的(de)(de)(de)可拉性在(zai)所有線(xian)徑里與低氧(yang)銅(tong)桿(gan)相比都是優越的(de)(de)(de),除上述組(zu)織原(yuan)因(yin)外,無(wu)氧(yang)銅(tong)桿(gan)夾雜少,含氧(yang)量穩(wen)定(ding),無(wu)熱軋(ya)可能產生的(de)(de)(de)缺(que)陷,桿(gan)表氧(yang)化(hua)(hua)物(wu)(wu)厚(hou)度可達≤15A。在(zai)連鑄連軋(ya)生產過(guo)程中(zhong)(zhong)如(ru)果工(gong)(gong)藝不(bu)(bu)穩(wen)定(ding),對(dui)氧(yang)監控不(bu)(bu)嚴,含氧(yang)量不(bu)(bu)穩(wen)定(ding)將直(zhi)接(jie)影響桿(gan)的(de)(de)(de)性能。如(ru)果桿(gan)的(de)(de)(de)表面(mian)氧(yang)化(hua)(hua)物(wu)(wu)能在(zai)后工(gong)(gong)序的(de)(de)(de)連續(xu)清洗中(zhong)(zhong)得(de)以彌補外,但比較(jiao)麻煩的(de)(de)(de)是有相當(dang)多的(de)(de)(de)氧(yang)化(hua)(hua)物(wu)(wu)存在(zai)于“皮(pi)下(xia)(xia)”,對(dui)拉線(xian)斷(duan)(duan)線(xian)影響更直(zhi)接(jie),故而在(zai)拉制微(wei)細線(xian),超微(wei)細線(xian)時,為了減少斷(duan)(duan)線(xian),有時要對(dui)銅(tong)桿(gan)采取不(bu)(bu)得(de)已的(de)(de)(de)辦法——剝(bo)皮(pi),甚至二次剝(bo)皮(pi)的(de)(de)(de)原(yuan)因(yin)所在(zai),目的(de)(de)(de)要除去皮(pi)下(xia)(xia)氧(yang)化(hua)(hua)物(wu)(wu)。

四、低氧銅(tong)桿和無(wu)氧銅(tong)桿的(de)韌性有差(cha)別

兩者都可以拉到0.015mm,但在低溫超導線中的(de)低溫級無(wu)氧(yang)銅,其細絲(si)間(jian)的(de)間(jian)距只有0.001mm.

五、從制(zhi)桿的原(yuan)材(cai)料到制(zhi)線(xian)的經濟(ji)性(xing)有差別(bie)。

制(zhi)造無氧銅(tong)桿要求質量較高的(de)(de)(de)(de)原材料(liao)。一般(ban),拉(la)制(zhi)直徑>1mm的(de)(de)(de)(de)銅(tong)線(xian)時,低氧銅(tong)桿的(de)(de)(de)(de)優(you)點比較明顯(xian),而無氧銅(tong)桿顯(xian)得更為(wei)優(you)越(yue)的(de)(de)(de)(de)是拉(la)制(zhi)直徑<0.5mm的(de)(de)(de)(de)銅(tong)線(xian)。

六、低氧銅桿的制線(xian)工(gong)藝與無(wu)氧銅桿的有所不同。

低氧銅(tong)(tong)桿的(de)制線(xian)(xian)(xian)工藝(yi)不能照搬到無氧銅(tong)(tong)桿的(de)制線(xian)(xian)(xian)工藝(yi)上來,至少(shao)兩者的(de)退火工藝(yi)是不同(tong)的(de)。因為線(xian)(xian)(xian)的(de)柔軟性深受材(cai)料成份和制桿,制線(xian)(xian)(xian)和退火工藝(yi)的(de)影響,不能簡(jian)單地說(shuo)低氧銅(tong)(tong)或無氧銅(tong)(tong)誰軟誰硬(ying)。