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來(lai)源:行(xing)業動(dong)態 閱讀(du):109321 發(fa)布(bu)時間:2019-07-05
導讀:由于生(sheng)產(chan)(chan)銅(tong)桿(gan)的(de)兩者的(de)工藝(yi)不同,所生(sheng)產(chan)(chan)的(de)銅(tong)桿(gan)中的(de)含(han)氧(yang)(yang)量及外觀(guan)就(jiu)不同。上引生(sheng)產(chan)(chan)的(de)銅(tong)桿(gan),工藝(yi)得(de)當氧(yang)(yang)含(han)量在10ppm以下(xia),叫無(wu)氧(yang)(yang)銅(tong)桿(gan);連鑄連鑄生(sheng)產(chan)(chan)的(de)銅(tong)桿(gan) 是(shi)在保護條件下(xia)的(de)熱軋,氧(yang)(yang)含(han)量在200-500ppm范圍內,但有(you)時也高達700ppm以上,一般情(qing)況下(xia),此種方法生(sheng)產(chan)(chan)的(de)銅(tong)外表光亮,低(di)氧(yang)(yang)銅(tong)桿(gan),有(you)時也叫光桿(gan)。
銅桿(gan)(gan)是(shi)(shi)電纜行業(ye)的主(zhu)要原(yuan)料,生(sheng)產的方式主(zhu)要有兩種——連(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)軋(ya)法(fa)和上(shang)引連(lian)鑄(zhu)(zhu)(zhu)(zhu)法(fa)。連(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)軋(ya)低氧(yang)銅桿(gan)(gan)的生(sheng)產方法(fa)較(jiao)多,其特點是(shi)(shi)金屬(shu)在豎爐(lu)(lu)中融(rong)化后(hou)(hou),銅液通過(guo)保溫(wen)爐(lu)(lu)、溜槽、中間包,從(cong)澆管進(jin)(jin)入(ru)封(feng)閉的模腔內(nei),采(cai)用(yong)較(jiao)大的冷卻強(qiang)度進(jin)(jin)行冷卻,形成鑄(zhu)(zhu)(zhu)(zhu)坯,然后(hou)(hou)進(jin)(jin)行多道次軋(ya)制(zhi)(zhi),生(sheng)產的低氧(yang)銅桿(gan)(gan)為熱加工(gong)組(zu)織(zhi),原(yuan)來的鑄(zhu)(zhu)(zhu)(zhu)造組(zu)織(zhi)已經破碎(sui),含氧(yang)量(liang)(liang)一(yi)般(ban)為200~400ppm之(zhi)間。無氧(yang)銅桿(gan)(gan)國(guo)內(nei)基(ji)本全部采(cai)用(yong)上(shang)引連(lian)鑄(zhu)(zhu)(zhu)(zhu)法(fa)生(sheng)產,金屬(shu)在感應電爐(lu)(lu)中融(rong)化后(hou)(hou)通過(guo)石(shi)墨(mo)模進(jin)(jin)行上(shang)引連(lian)續鑄(zhu)(zhu)(zhu)(zhu)造,之(zhi)后(hou)(hou)進(jin)(jin)行冷軋(ya)或冷加工(gong),生(sheng)產的無氧(yang)銅桿(gan)(gan)為鑄(zhu)(zhu)(zhu)(zhu)造組(zu)織(zhi),含氧(yang)量(liang)(liang)一(yi)般(ban)在20ppm以(yi)下(xia)。由于制(zhi)(zhi)造工(gong)藝的不同,所以(yi)在組(zu)織(zhi)結構、氧(yang)含量(liang)(liang)分(fen)布、雜質的形式及分(fen)布等諸(zhu)多方面(mian)有較(jiao)大差(cha)別。
一、拉制性能
銅(tong)桿(gan)的(de)拉制性能(neng)(neng)跟很(hen)多因素有(you)關,如雜質的(de)含量(liang)、氧含量(liang)及分布、工藝控制等。下面(mian)分別從以上幾個(ge)方面(mian)對銅(tong)桿(gan)的(de)拉制性能(neng)(neng)進行(xing)分析。
1、熔化方式對S等雜質的影響(xiang)
連(lian)鑄連(lian)軋(ya)生(sheng)產銅(tong)(tong)桿(gan)主要(yao)是(shi)通(tong)過(guo)氣體的燃(ran)燒(shao)使(shi)銅(tong)(tong)桿(gan)熔化,在燃(ran)燒(shao)的過(guo)程(cheng)中(zhong),通(tong)過(guo)氧(yang)化和揮發(fa)作用(yong)(yong),可一定(ding)程(cheng)度(du)減(jian)少部分雜質進入銅(tong)(tong)液(ye),因此連(lian)鑄連(lian)軋(ya)法(fa)對(dui)(dui)原料(liao)要(yao)求相(xiang)對(dui)(dui)低一些。上引連(lian)鑄生(sheng)產無(wu)氧(yang)銅(tong)(tong)桿(gan),由于是(shi)用(yong)(yong)感應電(dian)爐熔化,電(dian)解(jie)銅(tong)(tong)表(biao)面的“銅(tong)(tong)綠”“銅(tong)(tong)豆(dou)”基(ji)本都熔入到銅(tong)(tong)液(ye)中(zhong)。其中(zhong)熔入的S對(dui)(dui)無(wu)氧(yang)銅(tong)(tong)桿(gan)塑性影(ying)響極大,會增加拉絲斷線率。
2、鑄造(zao)過程中雜(za)質的進入
在生產(chan)過(guo)(guo)程(cheng)中(zhong)(zhong),連鑄(zhu)連軋工藝需通(tong)過(guo)(guo)保溫爐(lu)、溜槽、中(zhong)(zhong)間包(bao)轉(zhuan)運銅液,相對(dui)容易造成(cheng)耐火(huo)材料的剝落,在軋制過(guo)(guo)程(cheng)中(zhong)(zhong)需要通(tong)過(guo)(guo)軋輥,造成(cheng)鐵質的脫(tuo)落,會給銅桿造成(cheng)外(wai)部夾雜。而熱(re)軋中(zhong)(zhong)皮上和皮下氧化物的軋入(ru),會給低氧桿的拉絲造成(cheng)不利的影(ying)響。上引(yin)連鑄(zhu)法生產(chan)工藝流程(cheng)較(jiao)(jiao)短(duan),銅液是通(tong)過(guo)(guo)聯體(ti)爐(lu)內潛流式完成(cheng),對(dui)耐火(huo)材料的沖擊不大,結晶是通(tong)過(guo)(guo)石墨模(mo)內進行,所以過(guo)(guo)程(cheng)中(zhong)(zhong)可能產(chan)生的污染源較(jiao)(jiao)少,雜質進入(ru)的機會較(jiao)(jiao)少。
O、S、P是(shi)與銅(tong)(tong)會生產(chan)化(hua)合(he)物的(de)元素。在熔(rong)態銅(tong)(tong)中,氧(yang)可以(yi)溶解(jie)一部分,但(dan)當(dang)銅(tong)(tong)冷凝(ning)時,氧(yang)幾乎不(bu)溶解(jie)于銅(tong)(tong)中。熔(rong)態時所溶解(jie)的(de)氧(yang),以(yi)銅(tong)(tong)=氧(yang)化(hua)亞(ya)銅(tong)(tong)共(gong)晶(jing)(jing)體析出,分布在晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)(tong)-氧(yang)化(hua)亞(ya)銅(tong)(tong)共(gong)晶(jing)(jing)體的(de)出現(xian),顯(xian)著降低(di)了銅(tong)(tong)的(de)塑性。
硫可以溶解(jie)在熔體的銅中(zhong),但在室溫下,其溶解(jie)度幾乎(hu)降(jiang)低(di)到零,它(ta)以硫化(hua)亞銅的形(xing)式出現(xian)在晶(jing)粒晶(jing)界處,會顯(xian)著降(jiang)低(di)銅的塑性。
3、氧(yang)在低(di)氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿中分布形式及其影(ying)響
氧(yang)含量對低氧(yang)銅(tong)桿的(de)(de)(de)拉線(xian)(xian)性能有著(zhu)明顯的(de)(de)(de)影響(xiang)。當氧(yang)含量增加到最(zui)(zui)(zui)佳值時,銅(tong)桿的(de)(de)(de)斷線(xian)(xian)率最(zui)(zui)(zui)低。這是因(yin)為氧(yang)在與大部(bu)分雜(za)質反應的(de)(de)(de)過(guo)程中(zhong)都起到了(le)清(qing)除(chu)器的(de)(de)(de)作用(yong)。適度(du)的(de)(de)(de)氧(yang)還有利于(yu)去除(chu)銅(tong)液中(zhong)的(de)(de)(de)氫(qing),生(sheng)成(cheng)水蒸(zheng)氣(qi)溢出,減(jian)少氣(qi)孔的(de)(de)(de)形(xing)成(cheng)。最(zui)(zui)(zui)佳的(de)(de)(de)氧(yang)含量為拉線(xian)(xian)工藝提(ti)供了(le)最(zui)(zui)(zui)好的(de)(de)(de)條件(jian)。
低(di)氧銅(tong)(tong)桿氧化(hua)(hua)物(wu)的(de)分布(bu):在連續(xu)澆鑄中凝固的(de)最初階段(duan),散(san)熱(re)(re)速(su)率和均(jun)勻(yun)冷卻是決(jue)定銅(tong)(tong)桿氧化(hua)(hua)物(wu)分布(bu)的(de)主要因素。不均(jun)勻(yun)冷卻會(hui)(hui)引起銅(tong)(tong)桿內部結構本質上的(de)差異,但后續(xu)的(de)熱(re)(re)加工(gong),柱狀晶通常會(hui)(hui)遭到破(po)壞,使(shi)氧化(hua)(hua)亞銅(tong)(tong)顆(ke)粒(li)細(xi)微化(hua)(hua)和均(jun)勻(yun)分布(bu)。氧化(hua)(hua)物(wu)顆(ke)粒(li)聚集(ji)而(er)產生的(de)典型情(qing)況是中心爆裂。除氧化(hua)(hua)物(wu)顆(ke)粒(li)分布(bu)的(de)影響外(wai),具有較小氧化(hua)(hua)物(wu)顆(ke)粒(li)的(de)銅(tong)(tong)桿顯(xian)示出較好(hao)的(de)拉線特性,較大的(de)Cu2O顆(ke)粒(li)容易造成應力集(ji)中點而(er)斷裂。
無氧(yang)(yang)銅(tong)(tong)(tong)(tong)含氧(yang)(yang)量(liang)超標,銅(tong)(tong)(tong)(tong)桿變(bian)脆,延伸(shen)(shen)率(lv)(lv)下(xia)降(jiang),拉(la)伸(shen)(shen)式樣端口顯(xian)暗紅色,結晶組織疏松。當氧(yang)(yang)含量(liang)超出(chu)8ppm時,工(gong)(gong)(gong)藝(yi)性能(neng)(neng)(neng)變(bian)差,表現為鑄造及(ji)(ji)(ji)拉(la)伸(shen)(shen)過程中斷桿及(ji)(ji)(ji)斷線率(lv)(lv)極具增高。這(zhe)(zhe)是(shi)由于(yu)氧(yang)(yang)能(neng)(neng)(neng)與(yu)銅(tong)(tong)(tong)(tong)生成氧(yang)(yang)化亞銅(tong)(tong)(tong)(tong)脆性相,形成銅(tong)(tong)(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)(tong)(tong)共晶體,以(yi)網(wang)狀組織分布在(zai)(zai)境界上。這(zhe)(zhe)種脆性相硬度高,在(zai)(zai)冷變(bian)形時將會(hui)與(yu)銅(tong)(tong)(tong)(tong)機體脫離,導致(zhi)銅(tong)(tong)(tong)(tong)桿的機械性能(neng)(neng)(neng)下(xia)降(jiang),在(zai)(zai)后(hou)續加工(gong)(gong)(gong)中容易造成斷裂現象。氧(yang)(yang)含量(liang)高還能(neng)(neng)(neng)導致(zhi)無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿導電率(lv)(lv)下(xia)降(jiang)。因(yin)此,必須(xu)嚴格(ge)控制上引連鑄工(gong)(gong)(gong)藝(yi)及(ji)(ji)(ji)產(chan)品質量(liang)。
4、氫的影響
在上(shang)引連鑄(zhu)中,氧含量控制較(jiao)低,氧化物的副(fu)作用唄(bai)**降(jiang)低,但氫的影響成為較(jiao)顯著的問題(ti)。吸氣(qi)后熔體中存在平衡反(fan)應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體及疏松(song)是(shi)在(zai)(zai)結(jie)晶(jing)(jing)的(de)(de)(de)(de)過(guo)程中,氫從過(guo)飽和(he)(he)(he)的(de)(de)(de)(de)溶液中析(xi)出(chu)(chu)(chu)并聚集而形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)(de)。在(zai)(zai)結(jie)晶(jing)(jing)前析(xi)出(chu)(chu)(chu)的(de)(de)(de)(de)氫又可(ke)還原氧化(hua)亞銅而生成(cheng)(cheng)水氣(qi)(qi)(qi)泡(pao)。由于上(shang)引(yin)鑄造的(de)(de)(de)(de)特點是(shi)銅液自上(shang)而下的(de)(de)(de)(de)結(jie)晶(jing)(jing),形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)(de)液**形(xing)(xing)狀近似錐(zhui)型。銅液結(jie)晶(jing)(jing)前析(xi)出(chu)(chu)(chu)的(de)(de)(de)(de)氣(qi)(qi)(qi)體在(zai)(zai)上(shang)浮(fu)過(guo)程中被(bei)堵在(zai)(zai)凝(ning)固組織(zhi)內,結(jie)晶(jing)(jing)時(shi)在(zai)(zai)鑄桿內形(xing)(xing)成(cheng)(cheng)氣(qi)(qi)(qi)孔。上(shang)引(yin)的(de)(de)(de)(de)含(han)氣(qi)(qi)(qi)量(liang)少時(shi),析(xi)出(chu)(chu)(chu)的(de)(de)(de)(de)氫存在(zai)(zai)于晶(jing)(jing)界處,形(xing)(xing)成(cheng)(cheng)疏松(song);含(han)氣(qi)(qi)(qi)量(liang)多時(shi),則(ze)聚集成(cheng)(cheng)氣(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)孔和(he)(he)(he)疏松(song)是(shi)氫氣(qi)(qi)(qi)和(he)(he)(he)水蒸氣(qi)(qi)(qi)兩(liang)者形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)(de)。
氫來源于上引(yin)生(sheng)產過程中的各個工藝環節,如原(yuan)料電解銅(tong)(tong)的“銅(tong)(tong)綠”、輔(fu)料木炭**、氣候(hou)環境**、石墨結晶(jing)器未干燥等。因此,熔化(hua)爐中的銅(tong)(tong)液表面應覆(fu)蓋(gai)經烘烤的木炭,電解銅(tong)(tong)應盡量去除(chu)“銅(tong)(tong)綠”、“銅(tong)(tong)豆(dou)”“耳朵”,對提高無氧銅(tong)(tong)桿質量非常重要。
在(zai)連鑄連軋工藝中(zhong),往(wang)往(wang)采(cai)用適度控(kong)制氧含量來控(kong)制氫(qing)。Cu2O+ H2= 2Cu+ H2O
由(you)于銅液(ye)在鑄造過程(cheng)中(zhong)是自下而(er)上(shang)(shang)結(jie)晶,銅液(ye)中(zhong)的(de)(de)氧(yang)和氫所產生的(de)(de)水(shui)蒸氣(qi)很容易(yi)上(shang)(shang)浮跑出,銅液(ye)中(zhong)的(de)(de)氫大(da)部(bu)分能被有效去除,因而(er)對(dui)銅桿的(de)(de)影響較小。
二、表面質量
在(zai)生(sheng)產(chan)電磁線等產(chan)品(pin)的(de)(de)過程中,對銅(tong)桿的(de)(de)表面(mian)質量(liang)也(ye)需(xu)提出要求(qiu)。需(xu)要拉制后(hou)的(de)(de)銅(tong)絲表面(mian)無(wu)(wu)毛(mao)刺、銅(tong)粉(fen)少、無(wu)(wu)油(you)污。并通(tong)過扭轉試驗測量(liang)表面(mian)銅(tong)粉(fen)的(de)(de)質量(liang)和扭轉后(hou)觀察銅(tong)桿的(de)(de)復原情況來判定其好壞。
在連(lian)鑄(zhu)連(lian)軋(ya)過程中(zhong),從鑄(zhu)造到(dao)軋(ya)制(zhi)前,溫度(du)高(gao),完全暴(bao)露于(yu)空氣中(zhong),使(shi)鑄(zhu)坯表(biao)面形(xing)成較厚的氧化層,在軋(ya)制(zhi)過程中(zhong),隨(sui)著軋(ya)輥的轉動,氧化物顆(ke)粒軋(ya)入銅線(xian)表(biao)面。由(you)于(yu)氧化亞(ya)銅是高(gao)熔點脆性化合物,對于(yu)軋(ya)入較深的氧化亞(ya)銅,當成條狀(zhuang)的聚集物遇模具拉伸時,就會是銅桿外表(biao)面產生毛(mao)刺(ci),給后續的涂漆造成麻煩(fan)。
而(er)上(shang)引連鑄工藝制造(zao)(zao)的(de)(de)無(wu)(wu)氧(yang)銅桿(gan),由于鑄造(zao)(zao)和冷卻完全與氧(yang)隔(ge)絕,后續亦無(wu)(wu)熱軋(ya)過程,銅桿(gan)表(biao)面(mian)無(wu)(wu)軋(ya)入表(biao)面(mian)的(de)(de)氧(yang)化物,質量較好,拉制后銅粉少(shao),上(shang)述問題較少(shao)存在。
無氧銅桿也分進口(kou)(kou)設(she)備(bei)(bei)(bei)做的和國產(chan)設(she)備(bei)(bei)(bei)做的,但(dan)目前(qian)進口(kou)(kou)產(chan)品(pin)已無明顯(xian)優勢,銅桿產(chan)品(pin)出來后(hou)區別(bie)不是(shi)很(hen)大,只要(yao)銅板選的好,生產(chan)控制比較穩定,國產(chan)設(she)備(bei)(bei)(bei)也能產(chan)出可(ke)拉伸0.05的銅桿.進口(kou)(kou)設(she)備(bei)(bei)(bei)一(yi)般(ban)是(shi)芬蘭奧(ao)托昆普的設(she)備(bei)(bei)(bei),國產(chan)設(she)備(bei)(bei)(bei)最(zui)好的應該是(shi)上海的海軍(jun)廠的了,生產(chan)時間(jian)最(zui)長,軍(jun)工企業,質量可(ke)靠。
低氧銅(tong)桿(gan)進口(kou)設(she)備(bei)國際主要有兩種(zhong)(zhong),一種(zhong)(zhong)是(shi)美國南線設(she)備(bei),英文是(shi)SOUTHWIRE,國內廠家是(shi)南京華新,江西銅(tong)業(ye),另一種(zhong)(zhong)是(shi)德國CONTIROD設(she)備(bei),國內廠家是(shi)常州金(jin)源,天津大無縫(feng)。
無(wu)氧(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)從(cong)含(han)氧(yang)(yang)(yang)(yang)量(liang)上容(rong)易區別,無(wu)氧(yang)(yang)(yang)(yang)銅是含(han)氧(yang)(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)PPM以(yi)下,但(dan)目前有(you)的(de)(de)(de)(de)廠家只(zhi)能做到(dao)50個(ge)PPM以(yi)下.低(di)氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)(de)(de)桿(gan)(gan)(gan)子一般(ban)(ban)含(han)氧(yang)(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)一般(ban)(ban)采取(qu)的(de)(de)(de)(de)是上引法(fa),低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)是連(lian)鑄連(lian)軋(ya),兩種(zhong)產品相(xiang)對(dui)而言低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)漆包線(xian)性(xing)(xing) 能更適應(ying)些(xie),如柔軟性(xing)(xing),回彈(dan)角,繞線(xian)性(xing)(xing)能.但(dan)低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)拉(la)(la)(la)絲條(tiao)(tiao)件(jian)相(xiang)對(dui)要苛刻(ke)些(xie),同(tong)樣拉(la)(la)(la)伸(shen)0.2的(de)(de)(de)(de)細絲,如果(guo)伸(shen)線(xian)條(tiao)(tiao)件(jian)不(bu)(bu)(bu)好,普通的(de)(de)(de)(de)無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)(la)(la)而好的(de)(de)(de)(de)低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)就斷(duan) 線(xian),但(dan)如果(guo)放在(zai)(zai)好的(de)(de)(de)(de)伸(shen)線(xian)條(tiao)(tiao)件(jian),同(tong)樣的(de)(de)(de)(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)說不(bu)(bu)(bu)定就能拉(la)(la)(la)到(dao)雙(shuang)零五,而普通無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)最多(duo)只(zhi)能拉(la)(la)(la)伸(shen)到(dao)0.1而已,當然做的(de)(de)(de)(de)最細的(de)(de)(de)(de)如雙(shuang)零二卻非(fei)得依靠進口的(de)(de)(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)了.目前有(you)企業嘗試用(yong)剝皮的(de)(de)(de)(de)方式來處理低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)0.03線(xian).但(dan)有(you)關這(zhe)方面的(de)(de)(de)(de)內容(rong)我還不(bu)(bu)(bu)是很清楚。
音響線一(yi)般反而(er)喜(xi)歡用(yong)無氧(yang)桿,這和無氧(yang)桿是(shi)單晶銅,低氧(yang)桿是(shi)多晶銅有(you)關。
氧(yang)銅(tong)桿(gan)和無氧(yang)銅(tong)桿(gan)由(you)于制造方法的不同,致使存在差(cha)別,具有(you)各自的特點。
一、關于氧(yang)的吸入(ru)和脫去以及它的存(cun)在狀態(tai)
生(sheng)產銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)一(yi)般在(zai)(zai)10—50ppm,在(zai)(zai)常溫(wen)下(xia)氧(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)固溶(rong)度約2ppm。低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)一(yi)般在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)的(de)(de)(de)進入是(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)液態(tai)(tai)下(xia)吸入的(de)(de)(de),而(er)上引法無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則相(xiang)反,氧(yang)(yang)(yang)(yang)在(zai)(zai)液態(tai)(tai)銅(tong)(tong)(tong)(tong)下(xia)保持相(xiang)當(dang)時間后,被(bei)還原(yuan)而(er)脫去,通常這(zhe)種桿(gan)(gan)(gan)(gan)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低(di)可達1-2ppm,從組織(zhi)(zhi)上看,低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀態(tai)(tai),存在(zai)(zai)于晶粒邊界附近,這(zhe)對(dui)低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)而(er)言可以(yi)(yi)說是(shi)常見(jian)的(de)(de)(de)但對(dui)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則很(hen)少見(jian)。氧(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形(xing)式在(zai)(zai)晶界出現對(dui)材料的(de)(de)(de)韌性產生(sheng)負面影響。而(er)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang)很(hen)低(di),所以(yi)(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)(de)組織(zhi)(zhi)是(shi)均(jun)勻的(de)(de)(de)單相(xiang)組織(zhi)(zhi)對(dui)韌性有利。在(zai)(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中(zhong)的(de)(de)(de)多孔性是(shi)不常見(jian)的(de)(de)(de),而(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中(zhong)則是(shi)常見(jian)的(de)(de)(de)一(yi)種缺陷。
二、熱軋組織(zhi)和鑄造組織(zhi)的區(qu)別
低(di)氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)由于經過熱軋,所以其(qi)組(zu)(zu)(zu)織(zhi)(zhi)屬熱加工(gong)組(zu)(zu)(zu)織(zhi)(zhi),原(yuan)來的(de)(de)(de)(de)(de)鑄造組(zu)(zu)(zu)織(zhi)(zhi)已經破碎,在(zai)8mm的(de)(de)(de)(de)(de)桿(gan)(gan)(gan)(gan)時已有再(zai)結晶(jing)的(de)(de)(de)(de)(de)形(xing)式(shi)出現,而(er)無氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)屬鑄造組(zu)(zu)(zu)織(zhi)(zhi),晶(jing)粒(li)粗(cu)大,這(zhe)是(shi)為(wei)什么,無氧(yang)(yang)(yang)(yang)銅的(de)(de)(de)(de)(de)再(zai)結晶(jing)溫度(du)較(jiao)高(gao),需(xu)(xu)要較(jiao)高(gao)退(tui)(tui)火(huo)溫度(du)的(de)(de)(de)(de)(de)固有原(yuan)因(yin)(yin)(yin)。這(zhe)是(shi)因(yin)(yin)(yin)為(wei),再(zai)結晶(jing)發生(sheng)在(zai)晶(jing)粒(li)邊界附近,無氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)組(zu)(zu)(zu)織(zhi)(zhi)晶(jing)粒(li)粗(cu)大,晶(jing)粒(li)尺寸甚至能達幾個毫米,因(yin)(yin)(yin)而(er)晶(jing)粒(li)邊界少,即使(shi)通過拉制變形(xing),但(dan)晶(jing)粒(li)邊界相對(dui)低(di)氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)還(huan)是(shi)較(jiao)少,所以需(xu)(xu)要較(jiao)高(gao)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)功(gong)(gong)率(lv)(lv)。對(dui)無氧(yang)(yang)(yang)(yang)銅成功(gong)(gong)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)要求是(shi):由桿(gan)(gan)(gan)(gan)經拉制,但(dan)尚(shang)未(wei)鑄造組(zu)(zu)(zu)織(zhi)(zhi)的(de)(de)(de)(de)(de)線時的(de)(de)(de)(de)(de)第一(yi)次退(tui)(tui)火(huo),其(qi)退(tui)(tui)火(huo)功(gong)(gong)率(lv)(lv)應(ying)比同(tong)樣情(qing)況的(de)(de)(de)(de)(de)低(di)氧(yang)(yang)(yang)(yang)銅高(gao)10——15%。經繼續拉制,在(zai)以后階段(duan)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)功(gong)(gong)率(lv)(lv)應(ying)留(liu)有足夠的(de)(de)(de)(de)(de)余量和對(dui)低(di)氧(yang)(yang)(yang)(yang)銅和無氧(yang)(yang)(yang)(yang)銅切實區別(bie)執行不(bu)同(tong)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)工(gong)藝(yi),以保證在(zai)制品和成品導線的(de)(de)(de)(de)(de)柔(rou)軟性(xing)。
三(san)、夾雜,氧(yang)含量波(bo)動,表(biao)面(mian)氧(yang)化物(wu)和(he)可能存在的熱軋缺陷的差別
無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)(de)(de)可(ke)拉(la)性在(zai)所有(you)(you)線(xian)(xian)(xian)徑里(li)與低氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)相比都是優越的(de)(de)(de)(de),除上述組織原(yuan)因(yin)外,無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)夾雜(za)少,含(han)氧(yang)(yang)(yang)量穩定(ding),無(wu)熱軋可(ke)能(neng)產(chan)生的(de)(de)(de)(de)缺(que)陷,桿(gan)(gan)表(biao)氧(yang)(yang)(yang)化物厚度可(ke)達≤15A。在(zai)連鑄(zhu)連軋生產(chan)過程中如(ru)果工藝不(bu)(bu)穩定(ding),對(dui)(dui)氧(yang)(yang)(yang)監控(kong)不(bu)(bu)嚴,含(han)氧(yang)(yang)(yang)量不(bu)(bu)穩定(ding)將直接(jie)影響(xiang)桿(gan)(gan)的(de)(de)(de)(de)性能(neng)。如(ru)果桿(gan)(gan)的(de)(de)(de)(de)表(biao)面氧(yang)(yang)(yang)化物能(neng)在(zai)后工序的(de)(de)(de)(de)連續清洗中得以彌(mi)補外,但比較麻煩的(de)(de)(de)(de)是有(you)(you)相當(dang)多的(de)(de)(de)(de)氧(yang)(yang)(yang)化物存在(zai)于“皮(pi)下”,對(dui)(dui)拉(la)線(xian)(xian)(xian)斷線(xian)(xian)(xian)影響(xiang)更直接(jie),故而在(zai)拉(la)制微細(xi)線(xian)(xian)(xian),超微細(xi)線(xian)(xian)(xian)時(shi),為了減少斷線(xian)(xian)(xian),有(you)(you)時(shi)要(yao)對(dui)(dui)銅(tong)桿(gan)(gan)采取(qu)不(bu)(bu)得已(yi)的(de)(de)(de)(de)辦法——剝皮(pi),甚至(zhi)二次剝皮(pi)的(de)(de)(de)(de)原(yuan)因(yin)所在(zai),目(mu)的(de)(de)(de)(de)要(yao)除去皮(pi)下氧(yang)(yang)(yang)化物。
四、低氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿的(de)韌性有差別
兩(liang)者都可以(yi)拉到0.015mm,但在低(di)溫超導(dao)線中的低(di)溫級無氧(yang)銅,其(qi)細絲間的間距(ju)只有0.001mm.
五、從制(zhi)桿(gan)的(de)原(yuan)材料到制(zhi)線的(de)經(jing)濟性有(you)差(cha)別。
制(zhi)造無氧銅桿要求質量較高(gao)的(de)原(yuan)材(cai)料。一(yi)般,拉制(zhi)直(zhi)徑>1mm的(de)銅線時,低氧銅桿的(de)優點比較明顯(xian),而無氧銅桿顯(xian)得更為(wei)優越的(de)是拉制(zhi)直(zhi)徑<0.5mm的(de)銅線。
六、低氧(yang)銅(tong)桿的(de)制線工藝(yi)與無氧(yang)銅(tong)桿的(de)有所不同。
低氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)制線(xian)工(gong)藝不能照搬到無氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)制線(xian)工(gong)藝上來(lai),至少兩者的(de)退(tui)(tui)火工(gong)藝是(shi)不同的(de)。因為線(xian)的(de)柔(rou)軟性深(shen)受材(cai)料(liao)成份和制桿(gan),制線(xian)和退(tui)(tui)火工(gong)藝的(de)影響(xiang),不能簡單地說低氧(yang)(yang)(yang)銅(tong)或(huo)無氧(yang)(yang)(yang)銅(tong)誰軟誰硬。
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