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商都電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行(xing)業動態 閱讀:109465 發(fa)布時間:2019-07-05

導讀:由(you)于生產(chan)(chan)銅(tong)(tong)桿的兩者的工藝不(bu)同(tong),所生產(chan)(chan)的銅(tong)(tong)桿中(zhong)的含(han)氧量及外觀(guan)就不(bu)同(tong)。上引生產(chan)(chan)的銅(tong)(tong)桿,工藝得當(dang)氧含(han)量在(zai)10ppm以(yi)下(xia),叫無氧銅(tong)(tong)桿;連(lian)鑄連(lian)鑄生產(chan)(chan)的銅(tong)(tong)桿 是在(zai)保護條件下(xia)的熱軋,氧含(han)量在(zai)200-500ppm范圍內,但(dan)有時(shi)也高達(da)700ppm以(yi)上,一般情況下(xia),此種方法生產(chan)(chan)的銅(tong)(tong)外表光亮,低氧銅(tong)(tong)桿,有時(shi)也叫光桿。

銅桿是(shi)電纜行(xing)業的主要原料,生產(chan)(chan)的方式主要有兩(liang)種——連(lian)(lian)鑄(zhu)連(lian)(lian)軋法(fa)(fa)和(he)上引(yin)連(lian)(lian)鑄(zhu)法(fa)(fa)。連(lian)(lian)鑄(zhu)連(lian)(lian)軋低氧(yang)(yang)銅桿的生產(chan)(chan)方法(fa)(fa)較(jiao)多,其特點是(shi)金屬在豎爐中(zhong)融化(hua)后(hou)(hou),銅液通過保(bao)溫爐、溜(liu)槽、中(zhong)間包,從(cong)澆管(guan)進(jin)入封閉的模(mo)腔內(nei),采(cai)用較(jiao)大的冷(leng)卻強度進(jin)行(xing)冷(leng)卻,形(xing)成鑄(zhu)坯,然后(hou)(hou)進(jin)行(xing)多道次軋制,生產(chan)(chan)的低氧(yang)(yang)銅桿為熱加(jia)工組織(zhi),原來的鑄(zhu)造(zao)組織(zhi)已經破碎(sui),含氧(yang)(yang)量(liang)(liang)(liang)一般為200~400ppm之間。無氧(yang)(yang)銅桿國內(nei)基本(ben)全(quan)部采(cai)用上引(yin)連(lian)(lian)鑄(zhu)法(fa)(fa)生產(chan)(chan),金屬在感應(ying)電爐中(zhong)融化(hua)后(hou)(hou)通過石墨模(mo)進(jin)行(xing)上引(yin)連(lian)(lian)續鑄(zhu)造(zao),之后(hou)(hou)進(jin)行(xing)冷(leng)軋或冷(leng)加(jia)工,生產(chan)(chan)的無氧(yang)(yang)銅桿為鑄(zhu)造(zao)組織(zhi),含氧(yang)(yang)量(liang)(liang)(liang)一般在20ppm以下。由于制造(zao)工藝的不同,所(suo)以在組織(zhi)結(jie)構、氧(yang)(yang)含量(liang)(liang)(liang)分(fen)(fen)布(bu)、雜質的形(xing)式及(ji)分(fen)(fen)布(bu)等諸多方面(mian)有較(jiao)大差別。

一、拉制性能

銅(tong)桿的拉制(zhi)性能跟很多因(yin)素有關,如雜(za)質的含(han)量(liang)、氧含(han)量(liang)及分布、工(gong)藝控(kong)制(zhi)等(deng)。下面(mian)分別從以上(shang)幾個方(fang)面(mian)對(dui)銅(tong)桿的拉制(zhi)性能進行分析。

1、熔化方式對S等(deng)雜(za)質的(de)影響

連鑄(zhu)(zhu)連軋生產銅(tong)(tong)(tong)桿主要(yao)是(shi)通過氣體的燃(ran)燒使銅(tong)(tong)(tong)桿熔化(hua)(hua),在燃(ran)燒的過程(cheng)中,通過氧化(hua)(hua)和揮發作用(yong),可(ke)一定程(cheng)度減(jian)少部分(fen)雜質進入銅(tong)(tong)(tong)液(ye),因此連鑄(zhu)(zhu)連軋法對原(yuan)料要(yao)求相對低一些。上引連鑄(zhu)(zhu)生產無(wu)氧銅(tong)(tong)(tong)桿,由于是(shi)用(yong)感(gan)應電(dian)(dian)爐熔化(hua)(hua),電(dian)(dian)解銅(tong)(tong)(tong)表面的“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基本都熔入到銅(tong)(tong)(tong)液(ye)中。其中熔入的S對無(wu)氧銅(tong)(tong)(tong)桿塑性影響極大,會(hui)增加拉絲斷線率。

2、鑄(zhu)造過程中雜質的進入

在生(sheng)產過程(cheng)中(zhong),連鑄連軋(ya)(ya)工藝需(xu)通(tong)過保溫(wen)爐(lu)(lu)、溜槽、中(zhong)間包轉(zhuan)運(yun)銅(tong)液,相(xiang)對容易造(zao)成(cheng)耐(nai)(nai)火材料的剝落,在軋(ya)(ya)制過程(cheng)中(zhong)需(xu)要通(tong)過軋(ya)(ya)輥,造(zao)成(cheng)鐵(tie)質的脫落,會(hui)(hui)(hui)給銅(tong)桿造(zao)成(cheng)外部夾雜。而(er)熱(re)軋(ya)(ya)中(zhong)皮(pi)上(shang)和(he)皮(pi)下氧化物的軋(ya)(ya)入,會(hui)(hui)(hui)給低氧桿的拉絲(si)造(zao)成(cheng)不利的影(ying)響。上(shang)引(yin)連鑄法生(sheng)產工藝流(liu)程(cheng)較(jiao)(jiao)短,銅(tong)液是通(tong)過聯體爐(lu)(lu)內(nei)潛流(liu)式完成(cheng),對耐(nai)(nai)火材料的沖擊不大,結(jie)晶是通(tong)過石墨(mo)模內(nei)進行,所(suo)以過程(cheng)中(zhong)可能(neng)產生(sheng)的污(wu)染(ran)源較(jiao)(jiao)少,雜質進入的機會(hui)(hui)(hui)較(jiao)(jiao)少。

O、S、P是與銅(tong)會生產化(hua)合物的(de)元素。在熔(rong)態銅(tong)中,氧可以(yi)溶解一(yi)部分(fen),但(dan)當銅(tong)冷凝時(shi)(shi),氧幾乎不溶解于銅(tong)中。熔(rong)態時(shi)(shi)所溶解的(de)氧,以(yi)銅(tong)=氧化(hua)亞銅(tong)共晶(jing)體析出(chu),分(fen)布在晶(jing)粒晶(jing)界處。銅(tong)-氧化(hua)亞銅(tong)共晶(jing)體的(de)出(chu)現,顯著降低了銅(tong)的(de)塑性。

硫(liu)可以溶解在(zai)熔體(ti)的銅(tong)中,但(dan)在(zai)室溫下,其溶解度幾乎降低到零(ling),它以硫(liu)化亞銅(tong)的形(xing)式出現(xian)在(zai)晶(jing)粒晶(jing)界處,會顯著(zhu)降低銅(tong)的塑性。

3、氧(yang)在低氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)中(zhong)分(fen)布形式及其影(ying)響

氧(yang)含(han)量(liang)對低氧(yang)銅(tong)桿的(de)(de)拉線性能有著明顯的(de)(de)影響。當(dang)氧(yang)含(han)量(liang)增加到最佳值時,銅(tong)桿的(de)(de)斷線率最低。這是因為氧(yang)在與大部分雜質反應的(de)(de)過(guo)程中(zhong)都起到了清除器的(de)(de)作用。適度(du)的(de)(de)氧(yang)還有利于去除銅(tong)液(ye)中(zhong)的(de)(de)氫,生成水蒸氣溢出,減少(shao)氣孔(kong)的(de)(de)形成。最佳的(de)(de)氧(yang)含(han)量(liang)為拉線工藝提供(gong)了最好的(de)(de)條件(jian)。

低氧(yang)(yang)銅(tong)桿(gan)氧(yang)(yang)化物的(de)分布(bu):在連續(xu)澆鑄(zhu)中凝固的(de)最初(chu)階段(duan),散(san)熱速(su)率(lv)和(he)均勻冷卻是(shi)決定銅(tong)桿(gan)氧(yang)(yang)化物分布(bu)的(de)主要因素(su)。不均勻冷卻會(hui)引(yin)起銅(tong)桿(gan)內部結構本質(zhi)上的(de)差異,但后續(xu)的(de)熱加(jia)工,柱狀晶通常會(hui)遭到破(po)壞(huai),使氧(yang)(yang)化亞(ya)銅(tong)顆(ke)粒(li)(li)(li)(li)細微(wei)化和(he)均勻分布(bu)。氧(yang)(yang)化物顆(ke)粒(li)(li)(li)(li)聚集而(er)產生的(de)典型(xing)情況是(shi)中心爆裂(lie)。除氧(yang)(yang)化物顆(ke)粒(li)(li)(li)(li)分布(bu)的(de)影響外,具有較小氧(yang)(yang)化物顆(ke)粒(li)(li)(li)(li)的(de)銅(tong)桿(gan)顯示出較好的(de)拉線特性,較大的(de)Cu2O顆(ke)粒(li)(li)(li)(li)容易造(zao)成應力集中點而(er)斷裂(lie)。

無氧(yang)(yang)(yang)銅(tong)含(han)氧(yang)(yang)(yang)量(liang)超標,銅(tong)桿變脆(cui),延伸率(lv)下降,拉伸式樣端口顯暗紅(hong)色,結晶(jing)組織(zhi)疏松。當(dang)氧(yang)(yang)(yang)含(han)量(liang)超出8ppm時,工藝性(xing)能(neng)變差,表(biao)現為鑄造及(ji)(ji)拉伸過程中(zhong)斷桿及(ji)(ji)斷線率(lv)極具增高。這是由于(yu)氧(yang)(yang)(yang)能(neng)與(yu)銅(tong)生(sheng)成(cheng)氧(yang)(yang)(yang)化亞銅(tong)脆(cui)性(xing)相(xiang)(xiang),形(xing)成(cheng)銅(tong)-氧(yang)(yang)(yang)化亞銅(tong)共晶(jing)體,以網狀組織(zhi)分布(bu)在境(jing)界上。這種脆(cui)性(xing)相(xiang)(xiang)硬度(du)高,在冷變形(xing)時將會與(yu)銅(tong)機體脫離,導(dao)致銅(tong)桿的機械性(xing)能(neng)下降,在后續加工中(zhong)容(rong)易造成(cheng)斷裂現象(xiang)。氧(yang)(yang)(yang)含(han)量(liang)高還能(neng)導(dao)致無氧(yang)(yang)(yang)銅(tong)桿導(dao)電率(lv)下降。因此,必須嚴(yan)格控制上引連鑄工藝及(ji)(ji)產品質量(liang)。

4、氫的影響

在上引連鑄中,氧含量(liang)控制較(jiao)低,氧化物的(de)副作用唄**降低,但氫的(de)影響成為較(jiao)顯著的(de)問題。吸(xi)氣后熔體(ti)中存在平衡反應:H2O(g)=[O]+2[H];

氣(qi)體及疏松是(shi)在(zai)(zai)結(jie)(jie)(jie)晶(jing)(jing)的過(guo)(guo)程中(zhong)(zhong),氫從過(guo)(guo)飽和(he)的溶液(ye)(ye)中(zhong)(zhong)析出并聚集而形(xing)成(cheng)的。在(zai)(zai)結(jie)(jie)(jie)晶(jing)(jing)前析出的氫又(you)可還原氧化(hua)亞銅而生成(cheng)水氣(qi)泡。由于上引鑄(zhu)造(zao)的特點是(shi)銅液(ye)(ye)自上而下(xia)的結(jie)(jie)(jie)晶(jing)(jing),形(xing)成(cheng)的液(ye)(ye)**形(xing)狀(zhuang)近似錐(zhui)型。銅液(ye)(ye)結(jie)(jie)(jie)晶(jing)(jing)前析出的氣(qi)體在(zai)(zai)上浮過(guo)(guo)程中(zhong)(zhong)被堵在(zai)(zai)凝固組織內(nei),結(jie)(jie)(jie)晶(jing)(jing)時(shi)在(zai)(zai)鑄(zhu)桿(gan)內(nei)形(xing)成(cheng)氣(qi)孔。上引的含氣(qi)量(liang)少時(shi),析出的氫存在(zai)(zai)于晶(jing)(jing)界(jie)處,形(xing)成(cheng)疏松;含氣(qi)量(liang)多時(shi),則聚集成(cheng)氣(qi)孔,因此(ci),氣(qi)孔和(he)疏松是(shi)氫氣(qi)和(he)水蒸氣(qi)兩者形(xing)成(cheng)的。

氫來源于上引生產過程中的(de)各個工(gong)藝環節,如原料電(dian)解(jie)銅(tong)的(de)“銅(tong)綠(lv)”、輔料木(mu)炭**、氣候環境(jing)**、石墨結晶(jing)器未干燥等。因此,熔化爐中的(de)銅(tong)液表面應覆蓋經烘(hong)烤的(de)木(mu)炭,電(dian)解(jie)銅(tong)應盡(jin)量(liang)去除“銅(tong)綠(lv)”、“銅(tong)豆”“耳朵”,對提高無氧銅(tong)桿(gan)質量(liang)非常重要。

在(zai)連(lian)鑄連(lian)軋工藝中,往往采用適度控制(zhi)氧含量來控制(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)(tong)(tong)液(ye)在(zai)鑄造過(guo)程中是(shi)自下(xia)而上結晶,銅(tong)(tong)(tong)液(ye)中的氧和氫(qing)所產生的水蒸(zheng)氣(qi)很容易上浮跑出,銅(tong)(tong)(tong)液(ye)中的氫(qing)大部分能被(bei)有效去除,因(yin)而對銅(tong)(tong)(tong)桿的影響較小。

二、表面質量

在生產電磁線(xian)等產品(pin)的(de)過(guo)程中,對銅(tong)(tong)桿的(de)表面(mian)質(zhi)(zhi)量(liang)(liang)也需提出要求。需要拉制后的(de)銅(tong)(tong)絲表面(mian)無毛刺、銅(tong)(tong)粉少、無油污。并通(tong)過(guo)扭轉試驗測量(liang)(liang)表面(mian)銅(tong)(tong)粉的(de)質(zhi)(zhi)量(liang)(liang)和扭轉后觀察(cha)銅(tong)(tong)桿的(de)復原情況來判(pan)定其好(hao)壞。

在連鑄連軋(ya)(ya)過程中,從(cong)鑄造到(dao)軋(ya)(ya)制前,溫(wen)度高(gao),完全暴露于(yu)空氣中,使(shi)鑄坯表(biao)面形成(cheng)較厚的(de)(de)氧(yang)(yang)(yang)化(hua)層,在軋(ya)(ya)制過程中,隨著軋(ya)(ya)輥(gun)的(de)(de)轉動,氧(yang)(yang)(yang)化(hua)物(wu)顆粒軋(ya)(ya)入銅線表(biao)面。由于(yu)氧(yang)(yang)(yang)化(hua)亞銅是(shi)(shi)高(gao)熔點脆性(xing)化(hua)合物(wu),對于(yu)軋(ya)(ya)入較深的(de)(de)氧(yang)(yang)(yang)化(hua)亞銅,當(dang)成(cheng)條狀(zhuang)的(de)(de)聚(ju)集物(wu)遇(yu)模具拉伸時(shi),就會(hui)是(shi)(shi)銅桿外表(biao)面產(chan)生(sheng)毛刺,給后續的(de)(de)涂漆造成(cheng)麻煩。

而上引連鑄工藝制(zhi)造(zao)(zao)的無(wu)氧(yang)銅桿,由于鑄造(zao)(zao)和冷卻完全(quan)與氧(yang)隔絕(jue),后(hou)續亦無(wu)熱軋過程,銅桿表(biao)面無(wu)軋入表(biao)面的氧(yang)化物,質量較好,拉制(zhi)后(hou)銅粉(fen)少(shao),上述問題較少(shao)存在。

無氧(yang)銅桿(gan)(gan)也分(fen)進口設(she)(she)備(bei)做的(de)(de)(de)(de)(de)和國(guo)產(chan)(chan)設(she)(she)備(bei)做的(de)(de)(de)(de)(de),但目前進口產(chan)(chan)品已無明顯優勢,銅桿(gan)(gan)產(chan)(chan)品出來后(hou)區(qu)別不(bu)是(shi)很大,只(zhi)要銅板選的(de)(de)(de)(de)(de)好,生產(chan)(chan)控(kong)制比較穩定,國(guo)產(chan)(chan)設(she)(she)備(bei)也能產(chan)(chan)出可(ke)拉(la)伸0.05的(de)(de)(de)(de)(de)銅桿(gan)(gan).進口設(she)(she)備(bei)一般(ban)是(shi)芬蘭奧托昆普(pu)的(de)(de)(de)(de)(de)設(she)(she)備(bei),國(guo)產(chan)(chan)設(she)(she)備(bei)最(zui)好的(de)(de)(de)(de)(de)應(ying)該(gai)是(shi)上海的(de)(de)(de)(de)(de)海軍(jun)廠的(de)(de)(de)(de)(de)了(le),生產(chan)(chan)時間最(zui)長,軍(jun)工企業,質量可(ke)靠。

低氧銅(tong)桿(gan)進口設備國(guo)際主要有兩(liang)種(zhong),一(yi)種(zhong)是(shi)(shi)美國(guo)南(nan)線設備,英文是(shi)(shi)SOUTHWIRE,國(guo)內廠家(jia)是(shi)(shi)南(nan)京(jing)華(hua)新,江(jiang)西銅(tong)業,另一(yi)種(zhong)是(shi)(shi)德國(guo)CONTIROD設備,國(guo)內廠家(jia)是(shi)(shi)常州金(jin)源,天(tian)津大無(wu)縫(feng)。

無(wu)氧(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)從含氧(yang)(yang)(yang)(yang)量上容(rong)易區別,無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)是(shi)含氧(yang)(yang)(yang)(yang)量在(zai)(zai)10-20個PPM以下(xia),但目前有(you)(you)的(de)(de)(de)廠家只能(neng)(neng)做到50個PPM以下(xia).低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)在(zai)(zai) 200-400個PPM,好(hao)的(de)(de)(de)桿(gan)(gan)子一(yi)般含氧(yang)(yang)(yang)(yang)量控制在(zai)(zai)250個PPM左右,無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)一(yi)般采(cai)取的(de)(de)(de)是(shi)上引法,低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)是(shi)連鑄連軋,兩種產品相對(dui)(dui)而言低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)(dui)漆包線(xian)性(xing)(xing) 能(neng)(neng)更適應些(xie)(xie),如(ru)柔軟性(xing)(xing),回彈(dan)角,繞線(xian)性(xing)(xing)能(neng)(neng).但低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)(dui)拉(la)絲條(tiao)件相對(dui)(dui)要苛刻些(xie)(xie),同(tong)樣(yang)拉(la)伸(shen)0.2的(de)(de)(de)細絲,如(ru)果(guo)伸(shen)線(xian)條(tiao)件不(bu)好(hao),普通的(de)(de)(de)無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)可拉(la)而好(hao)的(de)(de)(de)低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)就(jiu)斷 線(xian),但如(ru)果(guo)放(fang)在(zai)(zai)好(hao)的(de)(de)(de)伸(shen)線(xian)條(tiao)件,同(tong)樣(yang)的(de)(de)(de)桿(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)說不(bu)定就(jiu)能(neng)(neng)拉(la)到雙零五(wu),而普通無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)最(zui)多(duo)只能(neng)(neng)拉(la)伸(shen)到0.1而已,當然做的(de)(de)(de)最(zui)細的(de)(de)(de)如(ru)雙零二卻非得依靠進口的(de)(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)了.目前有(you)(you)企(qi)業嘗試用剝皮的(de)(de)(de)方式來處理低(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)來伸(shen)0.03線(xian).但有(you)(you)關(guan)這(zhe)方面的(de)(de)(de)內容(rong)我(wo)還不(bu)是(shi)很(hen)清楚。

音(yin)響線一般反而(er)喜歡(huan)用無(wu)氧桿,這(zhe)和無(wu)氧桿是單(dan)晶(jing)(jing)銅,低氧桿是多晶(jing)(jing)銅有(you)關(guan)。

氧銅桿和無氧銅桿由于制造(zao)方(fang)法的不(bu)同,致使存在差別,具有(you)各自的特點(dian)。

一、關(guan)于氧的(de)(de)吸入和脫(tuo)去以及(ji)它的(de)(de)存在狀態(tai)

生產(chan)銅(tong)(tong)(tong)(tong)桿的(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下(xia)(xia)(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)進(jin)入(ru)是(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)液態(tai)(tai)下(xia)(xia)(xia)吸入(ru)的(de)(de)(de),而(er)上引(yin)法無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿則(ze)相反(fan),氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態(tai)(tai)銅(tong)(tong)(tong)(tong)下(xia)(xia)(xia)保持(chi)相當(dang)時間(jian)后,被還原而(er)脫去,通常(chang)(chang)這種桿的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)10—50ppm以下(xia)(xia)(xia),最(zui)低(di)可(ke)達1-2ppm,從組織(zhi)(zhi)上看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀態(tai)(tai),存在(zai)(zai)于晶粒邊界(jie)附近,這對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿而(er)言可(ke)以說(shuo)是(shi)常(chang)(chang)見的(de)(de)(de)但(dan)對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿則(ze)很少見。氧(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以夾雜形式(shi)在(zai)(zai)晶界(jie)出現對(dui)材料的(de)(de)(de)韌性產(chan)生負面影響。而(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所以這種銅(tong)(tong)(tong)(tong)的(de)(de)(de)組織(zhi)(zhi)是(shi)均勻(yun)的(de)(de)(de)單相組織(zhi)(zhi)對(dui)韌性有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿中(zhong)的(de)(de)(de)多孔性是(shi)不常(chang)(chang)見的(de)(de)(de),而(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿中(zhong)則(ze)是(shi)常(chang)(chang)見的(de)(de)(de)一種缺陷。

二(er)、熱軋組(zu)織和鑄造組(zu)織的區別

低氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)由于經過(guo)熱軋,所以(yi)(yi)其組織(zhi)屬熱加(jia)工組織(zhi),原來的(de)(de)(de)(de)鑄(zhu)造組織(zhi)已(yi)(yi)經破碎,在8mm的(de)(de)(de)(de)桿(gan)時(shi)(shi)已(yi)(yi)有再結晶的(de)(de)(de)(de)形(xing)式出現,而無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)屬鑄(zhu)造組織(zhi),晶粒(li)(li)粗(cu)大(da),這是為(wei)什么,無氧(yang)(yang)(yang)銅(tong)(tong)(tong)的(de)(de)(de)(de)再結晶溫度較(jiao)高,需(xu)要較(jiao)高退火溫度的(de)(de)(de)(de)固有原因(yin)。這是因(yin)為(wei),再結晶發生在晶粒(li)(li)邊界附近,無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)組織(zhi)晶粒(li)(li)粗(cu)大(da),晶粒(li)(li)尺寸(cun)甚至能達幾(ji)個(ge)毫米(mi),因(yin)而晶粒(li)(li)邊界少,即使通過(guo)拉(la)制(zhi)變形(xing),但(dan)晶粒(li)(li)邊界相對(dui)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)還是較(jiao)少,所以(yi)(yi)需(xu)要較(jiao)高的(de)(de)(de)(de)退火功(gong)率。對(dui)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)成功(gong)的(de)(de)(de)(de)退火要求是:由桿(gan)經拉(la)制(zhi),但(dan)尚未鑄(zhu)造組織(zhi)的(de)(de)(de)(de)線時(shi)(shi)的(de)(de)(de)(de)第一次退火,其退火功(gong)率應比同(tong)樣(yang)情況的(de)(de)(de)(de)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)高10——15%。經繼續拉(la)制(zhi),在以(yi)(yi)后階段的(de)(de)(de)(de)退火功(gong)率應留有足(zu)夠的(de)(de)(de)(de)余量和對(dui)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)和無氧(yang)(yang)(yang)銅(tong)(tong)(tong)切(qie)實區別執行不同(tong)的(de)(de)(de)(de)退火工藝,以(yi)(yi)保證在制(zhi)品和成品導線的(de)(de)(de)(de)柔軟(ruan)性。

三(san)、夾雜,氧(yang)含量(liang)波動,表面氧(yang)化(hua)物(wu)和可(ke)能(neng)存(cun)在的熱軋缺(que)陷的差別

無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)可(ke)拉性在(zai)所有(you)線徑里與低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)相(xiang)比都是優(you)越(yue)的(de),除(chu)上述(shu)組(zu)織(zhi)原(yuan)因(yin)外(wai),無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)夾雜少,含氧(yang)(yang)量穩(wen)定(ding),無熱軋可(ke)能產(chan)生的(de)缺(que)陷,桿(gan)(gan)表氧(yang)(yang)化(hua)(hua)物(wu)厚度(du)可(ke)達≤15A。在(zai)連(lian)鑄連(lian)軋生產(chan)過(guo)程中如果工(gong)藝不(bu)(bu)穩(wen)定(ding),對氧(yang)(yang)監(jian)控不(bu)(bu)嚴,含氧(yang)(yang)量不(bu)(bu)穩(wen)定(ding)將(jiang)直接影響(xiang)桿(gan)(gan)的(de)性能。如果桿(gan)(gan)的(de)表面氧(yang)(yang)化(hua)(hua)物(wu)能在(zai)后工(gong)序的(de)連(lian)續(xu)清洗中得以彌(mi)補外(wai),但(dan)比較麻煩的(de)是有(you)相(xiang)當多(duo)的(de)氧(yang)(yang)化(hua)(hua)物(wu)存在(zai)于“皮(pi)下(xia)(xia)”,對拉線斷(duan)線影響(xiang)更(geng)直接,故而在(zai)拉制微(wei)細線,超微(wei)細線時,為了減少斷(duan)線,有(you)時要對銅(tong)(tong)桿(gan)(gan)采取不(bu)(bu)得已的(de)辦法——剝皮(pi),甚(shen)至二次剝皮(pi)的(de)原(yuan)因(yin)所在(zai),目的(de)要除(chu)去皮(pi)下(xia)(xia)氧(yang)(yang)化(hua)(hua)物(wu)。

四、低(di)氧(yang)銅桿和無氧(yang)銅桿的韌性有差(cha)別(bie)

兩者都(dou)可以(yi)拉到0.015mm,但在低溫超導線(xian)中的(de)低溫級無氧銅,其細絲(si)間的(de)間距只(zhi)有(you)0.001mm.

五(wu)、從(cong)制桿的原(yuan)材料到制線的經濟性有(you)差別。

制造(zao)無(wu)氧銅(tong)桿要求質量較高(gao)的(de)(de)原材料(liao)。一般,拉(la)制直徑(jing)>1mm的(de)(de)銅(tong)線(xian)時,低氧銅(tong)桿的(de)(de)優點比較明顯(xian),而無(wu)氧銅(tong)桿顯(xian)得(de)更為(wei)優越的(de)(de)是拉(la)制直徑(jing)<0.5mm的(de)(de)銅(tong)線(xian)。

六、低(di)氧銅桿(gan)的制線工藝與(yu)無氧銅桿(gan)的有所不同(tong)。

低氧銅桿(gan)的制線工(gong)藝不能照搬到無氧銅桿(gan)的制線工(gong)藝上來,至(zhi)少兩者的退火工(gong)藝是不同的。因為線的柔軟(ruan)性深受(shou)材料(liao)成份(fen)和制桿(gan),制線和退火工(gong)藝的影響,不能簡單地說低氧銅或無氧銅誰軟(ruan)誰硬。