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來源:行業動態 閱讀(du):109587 發布時間:2019-07-05
導(dao)讀:由于生產(chan)銅(tong)(tong)桿(gan)的(de)兩者的(de)工(gong)藝不同(tong),所(suo)生產(chan)的(de)銅(tong)(tong)桿(gan)中的(de)含(han)氧(yang)(yang)(yang)量(liang)(liang)及外觀(guan)就不同(tong)。上引生產(chan)的(de)銅(tong)(tong)桿(gan),工(gong)藝得(de)當氧(yang)(yang)(yang)含(han)量(liang)(liang)在10ppm以下(xia),叫無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan);連鑄連鑄生產(chan)的(de)銅(tong)(tong)桿(gan) 是(shi)在保護(hu)條(tiao)件下(xia)的(de)熱(re)軋,氧(yang)(yang)(yang)含(han)量(liang)(liang)在200-500ppm范圍(wei)內(nei),但有時也高達700ppm以上,一般情(qing)況(kuang)下(xia),此種方(fang)法(fa)生產(chan)的(de)銅(tong)(tong)外表光亮,低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan),有時也叫光桿(gan)。
銅(tong)桿(gan)是電纜行(xing)業的(de)(de)主(zhu)要原料,生產(chan)的(de)(de)方式(shi)主(zhu)要有兩種——連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)(ya)法和上(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)(zhu)法。連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)(ya)低氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)(de)生產(chan)方法較多,其特點(dian)是金(jin)屬(shu)在(zai)豎爐(lu)中(zhong)融(rong)化后(hou),銅(tong)液通過保溫爐(lu)、溜槽(cao)、中(zhong)間包,從(cong)澆管進(jin)入封(feng)閉(bi)的(de)(de)模(mo)腔(qiang)內(nei),采用較大(da)的(de)(de)冷(leng)卻(que)強度進(jin)行(xing)冷(leng)卻(que),形成(cheng)鑄(zhu)(zhu)(zhu)坯,然后(hou)進(jin)行(xing)多道次軋(ya)(ya)制,生產(chan)的(de)(de)低氧(yang)(yang)(yang)銅(tong)桿(gan)為(wei)熱加工(gong)(gong)組織(zhi),原來的(de)(de)鑄(zhu)(zhu)(zhu)造組織(zhi)已(yi)經破碎,含(han)(han)氧(yang)(yang)(yang)量一般為(wei)200~400ppm之間。無氧(yang)(yang)(yang)銅(tong)桿(gan)國內(nei)基本全部采用上(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)(zhu)法生產(chan),金(jin)屬(shu)在(zai)感應電爐(lu)中(zhong)融(rong)化后(hou)通過石(shi)墨模(mo)進(jin)行(xing)上(shang)引(yin)連(lian)(lian)續鑄(zhu)(zhu)(zhu)造,之后(hou)進(jin)行(xing)冷(leng)軋(ya)(ya)或冷(leng)加工(gong)(gong),生產(chan)的(de)(de)無氧(yang)(yang)(yang)銅(tong)桿(gan)為(wei)鑄(zhu)(zhu)(zhu)造組織(zhi),含(han)(han)氧(yang)(yang)(yang)量一般在(zai)20ppm以(yi)下。由于制造工(gong)(gong)藝(yi)的(de)(de)不(bu)同,所以(yi)在(zai)組織(zhi)結(jie)構、氧(yang)(yang)(yang)含(han)(han)量分布(bu)、雜(za)質的(de)(de)形式(shi)及分布(bu)等諸(zhu)多方面有較大(da)差(cha)別。
一、拉制性能
銅桿的拉制(zhi)性(xing)能跟很多因素(su)有(you)關(guan),如雜質的含量、氧含量及分布、工藝(yi)控制(zhi)等。下(xia)面分別從以上(shang)幾個方(fang)面對銅桿的拉制(zhi)性(xing)能進行分析。
1、熔(rong)化方式對S等雜(za)質(zhi)的(de)影(ying)響
連鑄連軋生(sheng)產(chan)銅(tong)(tong)(tong)桿(gan)主要是(shi)通過(guo)氣體的燃燒使銅(tong)(tong)(tong)桿(gan)熔(rong)(rong)化(hua)(hua),在(zai)燃燒的過(guo)程(cheng)中,通過(guo)氧(yang)化(hua)(hua)和揮發作用,可一定程(cheng)度減少部分(fen)雜質(zhi)進入銅(tong)(tong)(tong)液(ye),因此連鑄連軋法對(dui)原料要求相對(dui)低一些。上引連鑄生(sheng)產(chan)無氧(yang)銅(tong)(tong)(tong)桿(gan),由于(yu)是(shi)用感應電(dian)爐熔(rong)(rong)化(hua)(hua),電(dian)解銅(tong)(tong)(tong)表(biao)面的“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基本都(dou)熔(rong)(rong)入到銅(tong)(tong)(tong)液(ye)中。其中熔(rong)(rong)入的S對(dui)無氧(yang)銅(tong)(tong)(tong)桿(gan)塑性影響極(ji)大,會增(zeng)加(jia)拉絲斷線率。
2、鑄(zhu)造過程中雜質的進入(ru)
在生產過(guo)(guo)程中(zhong),連(lian)鑄連(lian)軋(ya)(ya)工藝(yi)需(xu)通(tong)(tong)過(guo)(guo)保溫爐(lu)、溜(liu)槽(cao)、中(zhong)間包轉運銅液,相(xiang)對容易(yi)造(zao)成(cheng)耐火(huo)材(cai)料(liao)(liao)的(de)(de)(de)剝落(luo),在軋(ya)(ya)制過(guo)(guo)程中(zhong)需(xu)要通(tong)(tong)過(guo)(guo)軋(ya)(ya)輥(gun),造(zao)成(cheng)鐵質的(de)(de)(de)脫(tuo)落(luo),會(hui)給銅桿造(zao)成(cheng)外(wai)部夾雜。而熱軋(ya)(ya)中(zhong)皮(pi)上(shang)和(he)皮(pi)下氧化物的(de)(de)(de)軋(ya)(ya)入,會(hui)給低氧桿的(de)(de)(de)拉絲造(zao)成(cheng)不(bu)利的(de)(de)(de)影(ying)響(xiang)。上(shang)引連(lian)鑄法(fa)生產工藝(yi)流程較短,銅液是(shi)通(tong)(tong)過(guo)(guo)聯(lian)體(ti)爐(lu)內(nei)潛(qian)流式完成(cheng),對耐火(huo)材(cai)料(liao)(liao)的(de)(de)(de)沖擊不(bu)大,結(jie)晶是(shi)通(tong)(tong)過(guo)(guo)石墨(mo)模內(nei)進(jin)行,所以(yi)過(guo)(guo)程中(zhong)可能產生的(de)(de)(de)污染(ran)源(yuan)較少(shao),雜質進(jin)入的(de)(de)(de)機會(hui)較少(shao)。
O、S、P是(shi)與銅(tong)(tong)(tong)會生產(chan)化合(he)物的元素。在熔態銅(tong)(tong)(tong)中,氧(yang)可(ke)以溶(rong)(rong)解一部分,但當銅(tong)(tong)(tong)冷凝時(shi),氧(yang)幾乎不(bu)溶(rong)(rong)解于(yu)銅(tong)(tong)(tong)中。熔態時(shi)所(suo)溶(rong)(rong)解的氧(yang),以銅(tong)(tong)(tong)=氧(yang)化亞銅(tong)(tong)(tong)共晶體析出,分布(bu)在晶粒(li)晶界處。銅(tong)(tong)(tong)-氧(yang)化亞銅(tong)(tong)(tong)共晶體的出現,顯著(zhu)降低了銅(tong)(tong)(tong)的塑性。
硫(liu)可以溶(rong)解在(zai)(zai)熔(rong)體的(de)銅中,但在(zai)(zai)室(shi)溫下(xia),其溶(rong)解度幾乎降低到(dao)零,它以硫(liu)化亞銅的(de)形式出現在(zai)(zai)晶粒晶界處,會顯著降低銅的(de)塑性。
3、氧在(zai)低氧銅(tong)(tong)桿和無氧銅(tong)(tong)桿中分(fen)布形式及其影響
氧(yang)含(han)量(liang)對低氧(yang)銅桿的(de)(de)拉(la)線性能(neng)有(you)著明顯的(de)(de)影(ying)響。當氧(yang)含(han)量(liang)增加到(dao)(dao)最(zui)(zui)佳(jia)值時,銅桿的(de)(de)斷(duan)線率最(zui)(zui)低。這(zhe)是(shi)因為氧(yang)在與大(da)部分雜(za)質反應的(de)(de)過程中都起到(dao)(dao)了(le)清除器的(de)(de)作用(yong)。適度的(de)(de)氧(yang)還有(you)利于去(qu)除銅液(ye)中的(de)(de)氫(qing),生成水(shui)蒸氣溢出,減少氣孔的(de)(de)形成。最(zui)(zui)佳(jia)的(de)(de)氧(yang)含(han)量(liang)為拉(la)線工藝提供了(le)最(zui)(zui)好的(de)(de)條(tiao)件。
低氧(yang)銅桿(gan)氧(yang)化(hua)(hua)物(wu)的(de)(de)分布(bu):在連續澆鑄中(zhong)凝(ning)固(gu)的(de)(de)最初階(jie)段,散(san)熱速率和(he)均勻(yun)冷卻(que)是(shi)(shi)決定銅桿(gan)氧(yang)化(hua)(hua)物(wu)分布(bu)的(de)(de)主要因素。不均勻(yun)冷卻(que)會(hui)引起銅桿(gan)內部結構本(ben)質上的(de)(de)差(cha)異,但(dan)后續的(de)(de)熱加(jia)工,柱狀晶通常會(hui)遭到破壞,使氧(yang)化(hua)(hua)亞銅顆(ke)粒(li)(li)細(xi)微(wei)化(hua)(hua)和(he)均勻(yun)分布(bu)。氧(yang)化(hua)(hua)物(wu)顆(ke)粒(li)(li)聚集而(er)產生的(de)(de)典型(xing)情況是(shi)(shi)中(zhong)心(xin)爆裂(lie)。除氧(yang)化(hua)(hua)物(wu)顆(ke)粒(li)(li)分布(bu)的(de)(de)影響外,具有較小氧(yang)化(hua)(hua)物(wu)顆(ke)粒(li)(li)的(de)(de)銅桿(gan)顯示(shi)出較好的(de)(de)拉線特性,較大的(de)(de)Cu2O顆(ke)粒(li)(li)容易造成應力集中(zhong)點而(er)斷裂(lie)。
無(wu)氧(yang)(yang)銅(tong)含氧(yang)(yang)量(liang)超標,銅(tong)桿變脆,延伸(shen)率下(xia)降(jiang),拉伸(shen)式樣端口顯暗(an)紅色,結晶組(zu)織(zhi)疏(shu)松。當氧(yang)(yang)含量(liang)超出8ppm時,工(gong)藝(yi)(yi)性(xing)(xing)能(neng)變差,表現為鑄造及拉伸(shen)過程中(zhong)斷桿及斷線(xian)率極(ji)具(ju)增高(gao)。這是由于氧(yang)(yang)能(neng)與銅(tong)生成氧(yang)(yang)化亞銅(tong)脆性(xing)(xing)相(xiang),形成銅(tong)-氧(yang)(yang)化亞銅(tong)共(gong)晶體,以網狀組(zu)織(zhi)分布(bu)在(zai)境(jing)界上(shang)。這種脆性(xing)(xing)相(xiang)硬度高(gao),在(zai)冷變形時將會與銅(tong)機體脫離(li),導致銅(tong)桿的機械性(xing)(xing)能(neng)下(xia)降(jiang),在(zai)后續(xu)加工(gong)中(zhong)容易造成斷裂現象。氧(yang)(yang)含量(liang)高(gao)還能(neng)導致無(wu)氧(yang)(yang)銅(tong)桿導電率下(xia)降(jiang)。因此,必須嚴格控制(zhi)上(shang)引連鑄工(gong)藝(yi)(yi)及產品(pin)質量(liang)。
4、氫的影響
在上引(yin)連鑄中,氧(yang)含(han)量控制較(jiao)低(di),氧(yang)化物的副作用唄**降低(di),但氫(qing)的影響(xiang)成為較(jiao)顯著的問題。吸(xi)氣后(hou)熔體中存在平衡(heng)反應(ying):H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體及疏(shu)松是在(zai)(zai)結(jie)晶(jing)(jing)的(de)(de)過(guo)程(cheng)中(zhong),氫從過(guo)飽和(he)(he)的(de)(de)溶液(ye)(ye)中(zhong)析出(chu)并聚集而形(xing)(xing)成(cheng)(cheng)的(de)(de)。在(zai)(zai)結(jie)晶(jing)(jing)前析出(chu)的(de)(de)氫又(you)可(ke)還原(yuan)氧化(hua)亞(ya)銅(tong)而生成(cheng)(cheng)水(shui)氣(qi)(qi)(qi)泡。由于(yu)上(shang)引鑄造的(de)(de)特點是銅(tong)液(ye)(ye)自(zi)上(shang)而下的(de)(de)結(jie)晶(jing)(jing),形(xing)(xing)成(cheng)(cheng)的(de)(de)液(ye)(ye)**形(xing)(xing)狀(zhuang)近(jin)似錐型。銅(tong)液(ye)(ye)結(jie)晶(jing)(jing)前析出(chu)的(de)(de)氣(qi)(qi)(qi)體在(zai)(zai)上(shang)浮過(guo)程(cheng)中(zhong)被堵在(zai)(zai)凝固組織(zhi)內(nei),結(jie)晶(jing)(jing)時在(zai)(zai)鑄桿內(nei)形(xing)(xing)成(cheng)(cheng)氣(qi)(qi)(qi)孔。上(shang)引的(de)(de)含氣(qi)(qi)(qi)量少時,析出(chu)的(de)(de)氫存在(zai)(zai)于(yu)晶(jing)(jing)界處,形(xing)(xing)成(cheng)(cheng)疏(shu)松;含氣(qi)(qi)(qi)量多時,則聚集成(cheng)(cheng)氣(qi)(qi)(qi)孔,因(yin)此,氣(qi)(qi)(qi)孔和(he)(he)疏(shu)松是氫氣(qi)(qi)(qi)和(he)(he)水(shui)蒸氣(qi)(qi)(qi)兩(liang)者(zhe)形(xing)(xing)成(cheng)(cheng)的(de)(de)。
氫來源于上引生產過(guo)程中的(de)(de)各個工藝環節,如(ru)原料電(dian)解(jie)銅的(de)(de)“銅綠”、輔(fu)料木炭**、氣候環境**、石墨結晶器未干燥(zao)等。因此,熔化(hua)爐中的(de)(de)銅液表面應覆蓋經烘烤的(de)(de)木炭,電(dian)解(jie)銅應盡量(liang)去除(chu)“銅綠”、“銅豆(dou)”“耳(er)朵(duo)”,對提高無氧(yang)銅桿質量(liang)非常重要。
在連鑄(zhu)連軋工藝(yi)中(zhong),往往采(cai)用適(shi)度(du)控(kong)制氧含量來控(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅(tong)液在鑄造(zao)過(guo)程中是自下(xia)而(er)上結晶,銅(tong)液中的(de)氧和氫(qing)所(suo)產生的(de)水(shui)蒸(zheng)氣很容易上浮跑出,銅(tong)液中的(de)氫(qing)大部分能被有效去(qu)除,因而(er)對(dui)銅(tong)桿的(de)影響較小。
二、表面質量
在生(sheng)產(chan)電磁(ci)線等(deng)產(chan)品的過程中,對銅(tong)桿(gan)的表(biao)(biao)面(mian)(mian)質量也需提出要(yao)求。需要(yao)拉制后(hou)的銅(tong)絲表(biao)(biao)面(mian)(mian)無毛刺、銅(tong)粉少、無油(you)污。并通過扭轉試驗測量表(biao)(biao)面(mian)(mian)銅(tong)粉的質量和扭轉后(hou)觀察銅(tong)桿(gan)的復原情況(kuang)來(lai)判(pan)定其(qi)好壞。
在連(lian)鑄(zhu)連(lian)軋過程(cheng)中(zhong),從鑄(zhu)造(zao)到(dao)軋制前,溫度高(gao),完全(quan)暴露于空氣(qi)中(zhong),使(shi)鑄(zhu)坯表面(mian)(mian)形(xing)成較厚的氧化層(ceng),在軋制過程(cheng)中(zhong),隨著(zhu)軋輥的轉動,氧化物(wu)顆粒軋入銅(tong)線表面(mian)(mian)。由于氧化亞銅(tong)是高(gao)熔點脆性化合物(wu),對于軋入較深的氧化亞銅(tong),當成條(tiao)狀的聚集物(wu)遇模具拉伸時,就會是銅(tong)桿外表面(mian)(mian)產生毛(mao)刺,給(gei)后(hou)續(xu)的涂漆造(zao)成麻(ma)煩。
而(er)上引連鑄工(gong)藝制造(zao)的無氧銅桿(gan),由于鑄造(zao)和冷卻完全與氧隔絕,后(hou)續亦無熱軋過程,銅桿(gan)表(biao)面無軋入表(biao)面的氧化物,質量較好,拉制后(hou)銅粉少,上述問題較少存在。
無氧銅桿也分進口(kou)(kou)設(she)備(bei)做的(de)和國產(chan)(chan)設(she)備(bei)做的(de),但目前進口(kou)(kou)產(chan)(chan)品已無明顯(xian)優(you)勢,銅桿產(chan)(chan)品出(chu)來后區別(bie)不(bu)是(shi)(shi)很大(da),只要銅板選(xuan)的(de)好(hao),生產(chan)(chan)控制比較穩定,國產(chan)(chan)設(she)備(bei)也能產(chan)(chan)出(chu)可拉伸0.05的(de)銅桿.進口(kou)(kou)設(she)備(bei)一般是(shi)(shi)芬蘭奧托昆普的(de)設(she)備(bei),國產(chan)(chan)設(she)備(bei)最好(hao)的(de)應該是(shi)(shi)上(shang)海(hai)的(de)海(hai)軍(jun)廠(chang)的(de)了(le),生產(chan)(chan)時間(jian)最長,軍(jun)工(gong)企(qi)業(ye),質量可靠。
低氧銅桿進口(kou)設(she)備國際(ji)主要有兩(liang)種,一種是美國南線(xian)設(she)備,英(ying)文(wen)是SOUTHWIRE,國內廠家是南京華新,江西銅業,另一種是德國CONTIROD設(she)備,國內廠家是常州金源(yuan),天津大無縫。
無氧(yang)及低(di)(di)氧(yang)桿(gan)(gan)(gan)從含氧(yang)量(liang)上(shang)容易區別,無氧(yang)銅(tong)是(shi)含氧(yang)量(liang)在(zai)10-20個(ge)(ge)PPM以下,但目前(qian)有的(de)廠家只能做到50個(ge)(ge)PPM以下.低(di)(di)氧(yang)銅(tong)桿(gan)(gan)(gan)在(zai) 200-400個(ge)(ge)PPM,好的(de)桿(gan)(gan)(gan)子一般含氧(yang)量(liang)控制在(zai)250個(ge)(ge)PPM左右,無氧(yang)桿(gan)(gan)(gan)一般采取(qu)的(de)是(shi)上(shang)引法(fa),低(di)(di)氧(yang)桿(gan)(gan)(gan)是(shi)連(lian)鑄連(lian)軋,兩種產品相對(dui)而言(yan)低(di)(di)氧(yang)桿(gan)(gan)(gan)對(dui)漆包線(xian)(xian)(xian)性 能更(geng)適(shi)應些,如(ru)柔軟(ruan)性,回彈(dan)角,繞(rao)線(xian)(xian)(xian)性能.但低(di)(di)氧(yang)桿(gan)(gan)(gan)對(dui)拉(la)絲條件(jian)相對(dui)要苛刻些,同樣拉(la)伸(shen)0.2的(de)細(xi)絲,如(ru)果伸(shen)線(xian)(xian)(xian)條件(jian)不好,普通的(de)無氧(yang)桿(gan)(gan)(gan)可拉(la)而好的(de)低(di)(di)氧(yang)桿(gan)(gan)(gan)就(jiu)斷 線(xian)(xian)(xian),但如(ru)果放在(zai)好的(de)伸(shen)線(xian)(xian)(xian)條件(jian),同樣的(de)桿(gan)(gan)(gan)子,低(di)(di)氧(yang)桿(gan)(gan)(gan)說(shuo)不定就(jiu)能拉(la)到雙(shuang)零五,而普通無氧(yang)桿(gan)(gan)(gan)最多只能拉(la)伸(shen)到0.1而已,當然做的(de)最細(xi)的(de)如(ru)雙(shuang)零二卻非得(de)依靠進口的(de) 無氧(yang)銅(tong)桿(gan)(gan)(gan)了.目前(qian)有企業嘗試用剝(bo)皮的(de)方式來(lai)處理低(di)(di)氧(yang)桿(gan)(gan)(gan)來(lai)伸(shen)0.03線(xian)(xian)(xian).但有關這方面(mian)的(de)內(nei)容我還不是(shi)很清楚(chu)。
音響(xiang)線一般反而(er)喜歡(huan)用無(wu)氧(yang)(yang)桿,這(zhe)和無(wu)氧(yang)(yang)桿是(shi)單晶(jing)銅(tong)(tong),低氧(yang)(yang)桿是(shi)多晶(jing)銅(tong)(tong)有(you)關。
氧銅(tong)桿(gan)和無(wu)氧銅(tong)桿(gan)由于制造方法(fa)的(de)不同,致使存在差別,具有各(ge)自的(de)特點。
一、關(guan)于(yu)氧的吸入和(he)脫(tuo)去以及它(ta)的存在狀態
生(sheng)產銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)含氧(yang)(yang)(yang)量(liang)一(yi)般在(zai)(zai)10—50ppm,在(zai)(zai)常溫下(xia)(xia)氧(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中(zhong)的(de)(de)固(gu)溶度約2ppm。低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)含氧(yang)(yang)(yang)量(liang)一(yi)般在(zai)(zai)200(175)—400(450)ppm,因(yin)此(ci)氧(yang)(yang)(yang)的(de)(de)進(jin)入是(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)液態(tai)下(xia)(xia)吸入的(de)(de),而(er)上引(yin)法無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則相反,氧(yang)(yang)(yang)在(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)下(xia)(xia)保持相當時間(jian)后,被還原而(er)脫去,通(tong)常這(zhe)(zhe)種(zhong)桿(gan)的(de)(de)含氧(yang)(yang)(yang)量(liang)都(dou)在(zai)(zai)10—50ppm以下(xia)(xia),最(zui)低(di)可(ke)達1-2ppm,從組(zu)織(zhi)上看(kan),低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang),以氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)于(yu)晶粒邊界附(fu)近(jin),這(zhe)(zhe)對(dui)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)而(er)言可(ke)以說(shuo)是(shi)常見(jian)的(de)(de)但對(dui)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則很少(shao)見(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)以夾雜形(xing)式在(zai)(zai)晶界出現對(dui)材料(liao)的(de)(de)韌性(xing)(xing)產生(sheng)負面影響。而(er)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang)很低(di),所以這(zhe)(zhe)種(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)組(zu)織(zhi)是(shi)均勻的(de)(de)單(dan)相組(zu)織(zhi)對(dui)韌性(xing)(xing)有利。在(zai)(zai)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中(zhong)的(de)(de)多孔性(xing)(xing)是(shi)不常見(jian)的(de)(de),而(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中(zhong)則是(shi)常見(jian)的(de)(de)一(yi)種(zhong)缺陷。
二、熱軋組織(zhi)和鑄(zhu)造組織(zhi)的區別
低(di)氧(yang)銅(tong)(tong)桿(gan)由于經過熱軋,所(suo)以(yi)(yi)其(qi)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)屬熱加工組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi),原(yuan)來(lai)的(de)(de)(de)(de)鑄造(zao)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)已經破碎,在8mm的(de)(de)(de)(de)桿(gan)時已有(you)(you)再(zai)結晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)的(de)(de)(de)(de)形式出現(xian),而無氧(yang)銅(tong)(tong)桿(gan)屬鑄造(zao)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi),晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)粒粗大(da),這是(shi)為什么,無氧(yang)銅(tong)(tong)的(de)(de)(de)(de)再(zai)結晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)溫度較(jiao)高,需要較(jiao)高退(tui)(tui)火溫度的(de)(de)(de)(de)固有(you)(you)原(yuan)因(yin)。這是(shi)因(yin)為,再(zai)結晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)發生(sheng)在晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)粒邊界附近,無氧(yang)銅(tong)(tong)桿(gan)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)粒粗大(da),晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)粒尺(chi)寸甚(shen)至能達(da)幾個毫米,因(yin)而晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)粒邊界少,即使通過拉(la)制變形,但(dan)晶(jing)(jing)(jing)(jing)(jing)(jing)(jing)(jing)粒邊界相對低(di)氧(yang)銅(tong)(tong)桿(gan)還是(shi)較(jiao)少,所(suo)以(yi)(yi)需要較(jiao)高的(de)(de)(de)(de)退(tui)(tui)火功(gong)率。對無氧(yang)銅(tong)(tong)成功(gong)的(de)(de)(de)(de)退(tui)(tui)火要求是(shi):由桿(gan)經拉(la)制,但(dan)尚(shang)未鑄造(zao)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)的(de)(de)(de)(de)線(xian)時的(de)(de)(de)(de)第一次(ci)退(tui)(tui)火,其(qi)退(tui)(tui)火功(gong)率應比(bi)同樣情況的(de)(de)(de)(de)低(di)氧(yang)銅(tong)(tong)高10——15%。經繼續拉(la)制,在以(yi)(yi)后(hou)階段的(de)(de)(de)(de)退(tui)(tui)火功(gong)率應留有(you)(you)足夠(gou)的(de)(de)(de)(de)余量(liang)和對低(di)氧(yang)銅(tong)(tong)和無氧(yang)銅(tong)(tong)切實區別(bie)執行不同的(de)(de)(de)(de)退(tui)(tui)火工藝,以(yi)(yi)保證在制品和成品導(dao)線(xian)的(de)(de)(de)(de)柔(rou)軟性。
三、夾雜,氧含量(liang)波動,表面氧化物和可能存在的熱軋缺陷(xian)的差別
無氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)可(ke)(ke)(ke)拉性在(zai)(zai)所(suo)有(you)線(xian)徑里與低氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)相比(bi)都(dou)是優越的(de)(de),除(chu)上述組織原因外(wai),無氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)夾(jia)雜(za)少,含(han)氧(yang)(yang)(yang)(yang)量穩定(ding),無熱軋(ya)可(ke)(ke)(ke)能(neng)產生的(de)(de)缺陷(xian),桿(gan)(gan)表氧(yang)(yang)(yang)(yang)化(hua)物(wu)厚度(du)可(ke)(ke)(ke)達≤15A。在(zai)(zai)連(lian)(lian)鑄連(lian)(lian)軋(ya)生產過程中(zhong)如(ru)果(guo)工藝不穩定(ding),對(dui)氧(yang)(yang)(yang)(yang)監(jian)控不嚴,含(han)氧(yang)(yang)(yang)(yang)量不穩定(ding)將直(zhi)接影響(xiang)桿(gan)(gan)的(de)(de)性能(neng)。如(ru)果(guo)桿(gan)(gan)的(de)(de)表面氧(yang)(yang)(yang)(yang)化(hua)物(wu)能(neng)在(zai)(zai)后工序的(de)(de)連(lian)(lian)續清(qing)洗中(zhong)得(de)以彌補(bu)外(wai),但比(bi)較麻(ma)煩的(de)(de)是有(you)相當多的(de)(de)氧(yang)(yang)(yang)(yang)化(hua)物(wu)存在(zai)(zai)于“皮(pi)下”,對(dui)拉線(xian)斷線(xian)影響(xiang)更直(zhi)接,故而在(zai)(zai)拉制(zhi)微細線(xian),超微細線(xian)時,為了(le)減少斷線(xian),有(you)時要對(dui)銅(tong)桿(gan)(gan)采(cai)取不得(de)已的(de)(de)辦法——剝皮(pi),甚至二次剝皮(pi)的(de)(de)原因所(suo)在(zai)(zai),目的(de)(de)要除(chu)去皮(pi)下氧(yang)(yang)(yang)(yang)化(hua)物(wu)。
四(si)、低氧(yang)銅桿和無氧(yang)銅桿的韌(ren)性有差別(bie)
兩者都可以拉到0.015mm,但在低溫超導線中的(de)(de)低溫級無氧銅,其細絲間的(de)(de)間距只有(you)0.001mm.
五、從制桿的原材料到制線的經濟性有差別。
制造無氧(yang)銅桿要求(qiu)質(zhi)量較高的(de)原材料。一般,拉(la)(la)制直(zhi)徑(jing)>1mm的(de)銅線時,低氧(yang)銅桿的(de)優點比較明(ming)顯(xian),而無氧(yang)銅桿顯(xian)得更為優越的(de)是拉(la)(la)制直(zhi)徑(jing)<0.5mm的(de)銅線。
六、低氧銅桿的制線(xian)工藝(yi)與無(wu)氧銅桿的有(you)所不同。
低氧銅桿(gan)的(de)(de)制線(xian)工(gong)藝不(bu)(bu)能照搬到無(wu)氧銅桿(gan)的(de)(de)制線(xian)工(gong)藝上來,至少兩者的(de)(de)退火工(gong)藝是不(bu)(bu)同的(de)(de)。因為(wei)線(xian)的(de)(de)柔(rou)軟(ruan)性深受材料成份和(he)制桿(gan),制線(xian)和(he)退火工(gong)藝的(de)(de)影響,不(bu)(bu)能簡(jian)單(dan)地說(shuo)低氧銅或(huo)無(wu)氧銅誰軟(ruan)誰硬。
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