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來源(yuan):行業動態 閱(yue)讀:109271 發布時間:2019-07-05
導讀:由于(yu)生產(chan)銅(tong)桿的(de)(de)兩者的(de)(de)工藝不(bu)同,所生產(chan)的(de)(de)銅(tong)桿中的(de)(de)含氧量(liang)(liang)及外觀就不(bu)同。上引生產(chan)的(de)(de)銅(tong)桿,工藝得當(dang)氧含量(liang)(liang)在(zai)10ppm以下,叫(jiao)無氧銅(tong)桿;連(lian)鑄連(lian)鑄生產(chan)的(de)(de)銅(tong)桿 是在(zai)保護條件下的(de)(de)熱軋(ya),氧含量(liang)(liang)在(zai)200-500ppm范圍內,但有時(shi)也高達700ppm以上,一般情況下,此種方(fang)法生產(chan)的(de)(de)銅(tong)外表光亮,低氧銅(tong)桿,有時(shi)也叫(jiao)光桿。
銅(tong)(tong)(tong)桿(gan)是(shi)電纜行(xing)(xing)(xing)業的(de)主(zhu)要原料(liao),生(sheng)(sheng)(sheng)(sheng)產(chan)的(de)方(fang)(fang)式主(zhu)要有兩種(zhong)——連(lian)鑄(zhu)(zhu)連(lian)軋法(fa)和上(shang)引連(lian)鑄(zhu)(zhu)法(fa)。連(lian)鑄(zhu)(zhu)連(lian)軋低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)的(de)生(sheng)(sheng)(sheng)(sheng)產(chan)方(fang)(fang)法(fa)較(jiao)多(duo)(duo),其特點是(shi)金屬在豎爐(lu)中融化(hua)后(hou)(hou),銅(tong)(tong)(tong)液通(tong)過保溫爐(lu)、溜槽(cao)、中間(jian)包,從澆(jiao)管(guan)進(jin)入(ru)封閉(bi)的(de)模(mo)腔內,采用較(jiao)大(da)的(de)冷(leng)卻(que)強度進(jin)行(xing)(xing)(xing)冷(leng)卻(que),形(xing)成鑄(zhu)(zhu)坯,然后(hou)(hou)進(jin)行(xing)(xing)(xing)多(duo)(duo)道次軋制(zhi),生(sheng)(sheng)(sheng)(sheng)產(chan)的(de)低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)為(wei)熱(re)加工組織(zhi)(zhi),原來(lai)的(de)鑄(zhu)(zhu)造(zao)組織(zhi)(zhi)已經破碎,含(han)(han)氧(yang)量(liang)一般為(wei)200~400ppm之(zhi)間(jian)。無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)國內基(ji)本全部采用上(shang)引連(lian)鑄(zhu)(zhu)法(fa)生(sheng)(sheng)(sheng)(sheng)產(chan),金屬在感應電爐(lu)中融化(hua)后(hou)(hou)通(tong)過石墨模(mo)進(jin)行(xing)(xing)(xing)上(shang)引連(lian)續鑄(zhu)(zhu)造(zao),之(zhi)后(hou)(hou)進(jin)行(xing)(xing)(xing)冷(leng)軋或(huo)冷(leng)加工,生(sheng)(sheng)(sheng)(sheng)產(chan)的(de)無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)為(wei)鑄(zhu)(zhu)造(zao)組織(zhi)(zhi),含(han)(han)氧(yang)量(liang)一般在20ppm以下。由于制(zhi)造(zao)工藝的(de)不同,所以在組織(zhi)(zhi)結構、氧(yang)含(han)(han)量(liang)分(fen)布、雜質的(de)形(xing)式及分(fen)布等(deng)諸多(duo)(duo)方(fang)(fang)面有較(jiao)大(da)差別(bie)。
一、拉制性能
銅桿的拉制(zhi)性能跟很多因(yin)素有關,如雜質的含量(liang)、氧含量(liang)及(ji)分(fen)(fen)布、工(gong)藝(yi)控(kong)制(zhi)等。下面(mian)分(fen)(fen)別從以上幾個方(fang)面(mian)對銅桿的拉制(zhi)性能進行分(fen)(fen)析。
1、熔化(hua)方式對S等雜質的(de)影響
連(lian)鑄連(lian)軋生(sheng)產銅(tong)(tong)(tong)桿(gan)主要是(shi)通過氣體(ti)的(de)(de)燃(ran)燒使銅(tong)(tong)(tong)桿(gan)熔(rong)化(hua),在燃(ran)燒的(de)(de)過程(cheng)中(zhong),通過氧(yang)化(hua)和揮發(fa)作用(yong),可一(yi)定程(cheng)度減少部(bu)分雜(za)質(zhi)進(jin)入銅(tong)(tong)(tong)液,因此連(lian)鑄連(lian)軋法對原(yuan)料要求相對低一(yi)些。上引連(lian)鑄生(sheng)產無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan),由于是(shi)用(yong)感應電爐(lu)熔(rong)化(hua),電解銅(tong)(tong)(tong)表(biao)面(mian)的(de)(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基(ji)本(ben)都熔(rong)入到銅(tong)(tong)(tong)液中(zhong)。其中(zhong)熔(rong)入的(de)(de)S對無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)塑性影響極大,會(hui)增加拉絲斷線率(lv)。
2、鑄造過(guo)程中(zhong)雜質的進入
在生(sheng)產過(guo)程(cheng)中(zhong)(zhong),連(lian)鑄連(lian)軋(ya)工藝需(xu)通(tong)過(guo)保溫(wen)爐(lu)(lu)、溜(liu)槽、中(zhong)(zhong)間包(bao)轉運銅液(ye),相(xiang)對容易造成耐火材(cai)料的(de)剝落(luo),在軋(ya)制(zhi)過(guo)程(cheng)中(zhong)(zhong)需(xu)要通(tong)過(guo)軋(ya)輥(gun),造成鐵(tie)質的(de)脫落(luo),會(hui)給銅桿(gan)造成外部夾雜(za)。而熱軋(ya)中(zhong)(zhong)皮上和皮下氧化物的(de)軋(ya)入(ru),會(hui)給低(di)氧桿(gan)的(de)拉絲(si)造成不利的(de)影響。上引連(lian)鑄法生(sheng)產工藝流程(cheng)較(jiao)短,銅液(ye)是通(tong)過(guo)聯體(ti)爐(lu)(lu)內潛流式完(wan)成,對耐火材(cai)料的(de)沖擊不大(da),結晶是通(tong)過(guo)石墨模(mo)內進(jin)行,所(suo)以過(guo)程(cheng)中(zhong)(zhong)可能產生(sheng)的(de)污染源較(jiao)少(shao),雜(za)質進(jin)入(ru)的(de)機會(hui)較(jiao)少(shao)。
O、S、P是與銅(tong)(tong)會(hui)生產化合物(wu)的元素。在熔態銅(tong)(tong)中,氧(yang)(yang)可以溶解(jie)一部分,但當銅(tong)(tong)冷凝時,氧(yang)(yang)幾乎不溶解(jie)于銅(tong)(tong)中。熔態時所溶解(jie)的氧(yang)(yang),以銅(tong)(tong)=氧(yang)(yang)化亞銅(tong)(tong)共晶(jing)體析(xi)出(chu),分布在晶(jing)粒(li)晶(jing)界處。銅(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)共晶(jing)體的出(chu)現,顯著降低了銅(tong)(tong)的塑性。
硫(liu)可以溶(rong)解在(zai)熔體的(de)(de)銅中,但在(zai)室溫下,其溶(rong)解度幾乎降低(di)到零,它以硫(liu)化亞(ya)銅的(de)(de)形式出現在(zai)晶(jing)粒晶(jing)界處,會(hui)顯(xian)著降低(di)銅的(de)(de)塑(su)性。
3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中(zhong)分布形式及(ji)其影(ying)響
氧(yang)(yang)含量對低氧(yang)(yang)銅(tong)桿的(de)(de)(de)拉線性能有著明顯的(de)(de)(de)影響。當(dang)氧(yang)(yang)含量增加到(dao)最佳(jia)值時,銅(tong)桿的(de)(de)(de)斷線率最低。這是因為氧(yang)(yang)在與大部分雜質反應的(de)(de)(de)過程中都起到(dao)了清除器(qi)的(de)(de)(de)作(zuo)用。適度的(de)(de)(de)氧(yang)(yang)還有利于去除銅(tong)液中的(de)(de)(de)氫(qing),生成水(shui)蒸(zheng)氣溢出,減少氣孔的(de)(de)(de)形成。最佳(jia)的(de)(de)(de)氧(yang)(yang)含量為拉線工藝提(ti)供了最好的(de)(de)(de)條件(jian)。
低(di)氧(yang)銅(tong)(tong)桿氧(yang)化(hua)物(wu)的(de)分(fen)布(bu)(bu):在連(lian)續澆鑄中(zhong)凝固的(de)最初階段,散熱速率和(he)均(jun)(jun)勻(yun)冷卻(que)是決定銅(tong)(tong)桿氧(yang)化(hua)物(wu)分(fen)布(bu)(bu)的(de)主要因素。不均(jun)(jun)勻(yun)冷卻(que)會引起銅(tong)(tong)桿內部結構本質上(shang)的(de)差(cha)異,但后續的(de)熱加工,柱狀晶通常會遭到破壞,使氧(yang)化(hua)亞銅(tong)(tong)顆粒(li)(li)細微化(hua)和(he)均(jun)(jun)勻(yun)分(fen)布(bu)(bu)。氧(yang)化(hua)物(wu)顆粒(li)(li)聚集(ji)而(er)產生的(de)典型情況是中(zhong)心爆裂。除氧(yang)化(hua)物(wu)顆粒(li)(li)分(fen)布(bu)(bu)的(de)影響外,具有(you)較小氧(yang)化(hua)物(wu)顆粒(li)(li)的(de)銅(tong)(tong)桿顯示出較好的(de)拉線特性,較大(da)的(de)Cu2O顆粒(li)(li)容易造成應力集(ji)中(zhong)點(dian)而(er)斷裂。
無氧(yang)銅(tong)含氧(yang)量(liang)超(chao)標,銅(tong)桿(gan)變(bian)脆,延伸率下(xia)降(jiang),拉伸式樣端口顯暗紅色,結晶組(zu)織疏松(song)。當氧(yang)含量(liang)超(chao)出(chu)8ppm時,工(gong)藝性(xing)(xing)能(neng)變(bian)差,表現為鑄造(zao)及拉伸過(guo)程(cheng)中(zhong)斷桿(gan)及斷線率極(ji)具增高。這是(shi)由于(yu)氧(yang)能(neng)與銅(tong)生成氧(yang)化亞(ya)銅(tong)脆性(xing)(xing)相(xiang),形(xing)成銅(tong)-氧(yang)化亞(ya)銅(tong)共(gong)晶體(ti),以網狀組(zu)織分布在境(jing)界上(shang)。這種脆性(xing)(xing)相(xiang)硬度高,在冷變(bian)形(xing)時將(jiang)會與銅(tong)機(ji)體(ti)脫(tuo)離,導(dao)致銅(tong)桿(gan)的機(ji)械(xie)性(xing)(xing)能(neng)下(xia)降(jiang),在后續加工(gong)中(zhong)容易造(zao)成斷裂現象。氧(yang)含量(liang)高還能(neng)導(dao)致無氧(yang)銅(tong)桿(gan)導(dao)電(dian)率下(xia)降(jiang)。因此,必須(xu)嚴格控制上(shang)引(yin)連鑄工(gong)藝及產(chan)品質量(liang)。
4、氫的影響
在(zai)上引(yin)連(lian)鑄中,氧含量控(kong)制較低,氧化物的(de)副作用唄(bai)**降低,但(dan)氫的(de)影(ying)響成為較顯著的(de)問題。吸氣后熔體中存(cun)在(zai)平衡反應(ying):H2O(g)=[O]+2[H];
氣體(ti)及疏松是(shi)在(zai)結晶(jing)的過程(cheng)中,氫(qing)從過飽和的溶液中析(xi)(xi)出(chu)并聚集而形(xing)(xing)(xing)成(cheng)的。在(zai)結晶(jing)前析(xi)(xi)出(chu)的氫(qing)又可還原氧化亞銅(tong)而生成(cheng)水氣泡(pao)。由于上(shang)引鑄(zhu)造的特點是(shi)銅(tong)液自上(shang)而下的結晶(jing),形(xing)(xing)(xing)成(cheng)的液**形(xing)(xing)(xing)狀近似錐(zhui)型。銅(tong)液結晶(jing)前析(xi)(xi)出(chu)的氣體(ti)在(zai)上(shang)浮過程(cheng)中被(bei)堵在(zai)凝固組(zu)織內,結晶(jing)時在(zai)鑄(zhu)桿內形(xing)(xing)(xing)成(cheng)氣孔(kong)。上(shang)引的含氣量少時,析(xi)(xi)出(chu)的氫(qing)存在(zai)于晶(jing)界(jie)處,形(xing)(xing)(xing)成(cheng)疏松;含氣量多時,則聚集成(cheng)氣孔(kong),因此(ci),氣孔(kong)和疏松是(shi)氫(qing)氣和水蒸氣兩者形(xing)(xing)(xing)成(cheng)的。
氫來源于上(shang)引生產過程中(zhong)的(de)各個工藝(yi)環節(jie),如原料電(dian)解銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔料木(mu)炭**、氣(qi)候環境**、石(shi)墨結(jie)晶(jing)器未干燥等(deng)。因此,熔化爐(lu)中(zhong)的(de)銅(tong)(tong)液表面應(ying)覆(fu)蓋經烘(hong)烤的(de)木(mu)炭,電(dian)解銅(tong)(tong)應(ying)盡量去除“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳(er)朵”,對提高無氧銅(tong)(tong)桿質量非常重(zhong)要。
在連鑄連軋工藝(yi)中,往往采用適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅液(ye)在鑄造過(guo)程中是自下而上結(jie)晶,銅液(ye)中的(de)(de)氧和氫所產生的(de)(de)水蒸氣很(hen)容(rong)易上浮跑出(chu),銅液(ye)中的(de)(de)氫大(da)部(bu)分能被有(you)效去除,因而對銅桿的(de)(de)影(ying)響較(jiao)小。
二、表面質量
在生產(chan)(chan)電磁線(xian)等(deng)產(chan)(chan)品(pin)的過(guo)(guo)程中,對(dui)銅(tong)(tong)桿的表面(mian)質(zhi)量(liang)也需提出要求。需要拉制后(hou)的銅(tong)(tong)絲表面(mian)無毛刺(ci)、銅(tong)(tong)粉少(shao)、無油污。并通過(guo)(guo)扭轉試驗測量(liang)表面(mian)銅(tong)(tong)粉的質(zhi)量(liang)和扭轉后(hou)觀(guan)察銅(tong)(tong)桿的復原情況(kuang)來判定其好壞(huai)。
在連鑄(zhu)連軋(ya)過(guo)(guo)程中,從鑄(zhu)造到(dao)軋(ya)制前(qian),溫度高(gao),完(wan)全暴露于空氣中,使鑄(zhu)坯表面形成(cheng)較厚的(de)氧化(hua)層,在軋(ya)制過(guo)(guo)程中,隨著軋(ya)輥的(de)轉動,氧化(hua)物顆(ke)粒軋(ya)入銅(tong)線表面。由(you)于氧化(hua)亞銅(tong)是高(gao)熔點(dian)脆性化(hua)合物,對(dui)于軋(ya)入較深的(de)氧化(hua)亞銅(tong),當成(cheng)條狀的(de)聚集(ji)物遇模具(ju)拉(la)伸時,就會是銅(tong)桿(gan)外(wai)表面產生毛(mao)刺,給后續的(de)涂漆造成(cheng)麻煩。
而(er)上引連鑄工藝制(zhi)造的(de)無氧銅(tong)(tong)桿,由(you)于鑄造和冷卻完全與(yu)氧隔絕,后續(xu)亦無熱軋(ya)過程,銅(tong)(tong)桿表面(mian)無軋(ya)入表面(mian)的(de)氧化物,質量較(jiao)好,拉制(zhi)后銅(tong)(tong)粉少(shao),上述問(wen)題較(jiao)少(shao)存(cun)在。
無氧銅(tong)(tong)桿(gan)也分進口(kou)(kou)設(she)(she)備做(zuo)的和國(guo)產(chan)設(she)(she)備做(zuo)的,但目(mu)前進口(kou)(kou)產(chan)品已(yi)無明(ming)顯優勢,銅(tong)(tong)桿(gan)產(chan)品出來后區別不是(shi)很(hen)大,只要銅(tong)(tong)板(ban)選的好,生(sheng)產(chan)控(kong)制比較穩(wen)定,國(guo)產(chan)設(she)(she)備也能(neng)產(chan)出可拉伸0.05的銅(tong)(tong)桿(gan).進口(kou)(kou)設(she)(she)備一般是(shi)芬蘭奧托昆普的設(she)(she)備,國(guo)產(chan)設(she)(she)備最好的應該是(shi)上海的海軍廠的了,生(sheng)產(chan)時間(jian)最長,軍工企(qi)業,質量可靠。
低(di)氧銅桿進(jin)口設(she)備(bei)國際主要有(you)兩種(zhong),一種(zhong)是美(mei)國南線設(she)備(bei),英(ying)文是SOUTHWIRE,國內廠(chang)家是南京華新,江西銅業,另一種(zhong)是德國CONTIROD設(she)備(bei),國內廠(chang)家是常州金源,天津大無(wu)縫。
無氧及(ji)低(di)(di)氧桿(gan)(gan)從含(han)氧量上(shang)容(rong)易區別,無氧銅(tong)是含(han)氧量在(zai)10-20個(ge)PPM以下,但目(mu)前有的(de)(de)(de)廠家只能做到50個(ge)PPM以下.低(di)(di)氧銅(tong)桿(gan)(gan)在(zai) 200-400個(ge)PPM,好(hao)的(de)(de)(de)桿(gan)(gan)子(zi)一(yi)般(ban)含(han)氧量控制在(zai)250個(ge)PPM左(zuo)右(you),無氧桿(gan)(gan)一(yi)般(ban)采取(qu)的(de)(de)(de)是上(shang)引法(fa),低(di)(di)氧桿(gan)(gan)是連(lian)鑄連(lian)軋(ya),兩種(zhong)產品相對而(er)言低(di)(di)氧桿(gan)(gan)對漆包線性(xing)(xing) 能更適應些,如(ru)柔軟性(xing)(xing),回彈角,繞(rao)線性(xing)(xing)能.但低(di)(di)氧桿(gan)(gan)對拉(la)(la)(la)(la)絲(si)條(tiao)件相對要苛刻些,同(tong)樣拉(la)(la)(la)(la)伸(shen)(shen)0.2的(de)(de)(de)細(xi)絲(si),如(ru)果伸(shen)(shen)線條(tiao)件不好(hao),普通(tong)(tong)的(de)(de)(de)無氧桿(gan)(gan)可(ke)拉(la)(la)(la)(la)而(er)好(hao)的(de)(de)(de)低(di)(di)氧桿(gan)(gan)就(jiu)斷 線,但如(ru)果放(fang)在(zai)好(hao)的(de)(de)(de)伸(shen)(shen)線條(tiao)件,同(tong)樣的(de)(de)(de)桿(gan)(gan)子(zi),低(di)(di)氧桿(gan)(gan)說(shuo)不定就(jiu)能拉(la)(la)(la)(la)到雙(shuang)零五,而(er)普通(tong)(tong)無氧桿(gan)(gan)最(zui)多只能拉(la)(la)(la)(la)伸(shen)(shen)到0.1而(er)已,當然(ran)做的(de)(de)(de)最(zui)細(xi)的(de)(de)(de)如(ru)雙(shuang)零二卻非(fei)得依(yi)靠進(jin)口(kou)的(de)(de)(de) 無氧銅(tong)桿(gan)(gan)了.目(mu)前有企業嘗試用(yong)剝皮的(de)(de)(de)方式(shi)來處理低(di)(di)氧桿(gan)(gan)來伸(shen)(shen)0.03線.但有關這(zhe)方面(mian)的(de)(de)(de)內容(rong)我還(huan)不是很清楚。
音響(xiang)線一般反而喜歡用無(wu)(wu)氧桿(gan),這和無(wu)(wu)氧桿(gan)是(shi)單晶銅,低氧桿(gan)是(shi)多晶銅有關(guan)。
氧(yang)銅桿和(he)無氧(yang)銅桿由(you)于制造(zao)方法的不(bu)同,致使存在差(cha)別,具有各自的特點(dian)。
一、關于氧的(de)吸入和脫去(qu)以及它的(de)存在狀(zhuang)態
生產(chan)銅(tong)(tong)桿的(de)(de)陰極(ji)銅(tong)(tong)的(de)(de)含氧(yang)(yang)(yang)量一(yi)般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常溫下氧(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)固(gu)溶度(du)約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿的(de)(de)含氧(yang)(yang)(yang)量一(yi)般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)進(jin)入是(shi)在(zai)(zai)(zai)銅(tong)(tong)的(de)(de)液態下吸入的(de)(de),而(er)(er)上引法無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿則(ze)相(xiang)反(fan),氧(yang)(yang)(yang)在(zai)(zai)(zai)液態銅(tong)(tong)下保持相(xiang)當時(shi)間(jian)后,被還原(yuan)而(er)(er)脫去,通常這(zhe)(zhe)種(zhong)桿的(de)(de)含氧(yang)(yang)(yang)量都(dou)在(zai)(zai)(zai)10—50ppm以(yi)下,最(zui)低(di)(di)(di)可達(da)1-2ppm,從(cong)組織(zhi)上看,低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)狀(zhuang)態,存在(zai)(zai)(zai)于(yu)晶粒(li)邊界(jie)附近,這(zhe)(zhe)對(dui)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿而(er)(er)言可以(yi)說是(shi)常見(jian)的(de)(de)但對(dui)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿則(ze)很少見(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)以(yi)夾雜形(xing)式在(zai)(zai)(zai)晶界(jie)出現對(dui)材料的(de)(de)韌性(xing)產(chan)生負(fu)面影(ying)響。而(er)(er)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang)很低(di)(di)(di),所以(yi)這(zhe)(zhe)種(zhong)銅(tong)(tong)的(de)(de)組織(zhi)是(shi)均勻(yun)的(de)(de)單(dan)相(xiang)組織(zhi)對(dui)韌性(xing)有利。在(zai)(zai)(zai)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿中(zhong)的(de)(de)多孔性(xing)是(shi)不(bu)常見(jian)的(de)(de),而(er)(er)在(zai)(zai)(zai)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿中(zhong)則(ze)是(shi)常見(jian)的(de)(de)一(yi)種(zhong)缺陷。
二、熱軋組織和鑄造組織的區別
低氧(yang)(yang)銅(tong)桿由于經(jing)過(guo)熱軋(ya),所以其組(zu)織屬熱加工(gong)組(zu)織,原來的(de)鑄(zhu)造(zao)(zao)(zao)組(zu)織已經(jing)破碎,在8mm的(de)桿時(shi)已有再(zai)結(jie)晶(jing)(jing)(jing)的(de)形式出現,而(er)無(wu)氧(yang)(yang)銅(tong)桿屬鑄(zhu)造(zao)(zao)(zao)組(zu)織,晶(jing)(jing)(jing)粒(li)粗大,這(zhe)是(shi)為(wei)什么,無(wu)氧(yang)(yang)銅(tong)的(de)再(zai)結(jie)晶(jing)(jing)(jing)溫度較(jiao)高(gao),需(xu)要較(jiao)高(gao)退(tui)火(huo)(huo)(huo)溫度的(de)固有原因(yin)。這(zhe)是(shi)因(yin)為(wei),再(zai)結(jie)晶(jing)(jing)(jing)發生在晶(jing)(jing)(jing)粒(li)邊界(jie)附(fu)近,無(wu)氧(yang)(yang)銅(tong)桿組(zu)織晶(jing)(jing)(jing)粒(li)粗大,晶(jing)(jing)(jing)粒(li)尺(chi)寸甚至能達(da)幾(ji)個毫米,因(yin)而(er)晶(jing)(jing)(jing)粒(li)邊界(jie)少,即使通過(guo)拉(la)制變形,但晶(jing)(jing)(jing)粒(li)邊界(jie)相對低氧(yang)(yang)銅(tong)桿還是(shi)較(jiao)少,所以需(xu)要較(jiao)高(gao)的(de)退(tui)火(huo)(huo)(huo)功(gong)率(lv)。對無(wu)氧(yang)(yang)銅(tong)成功(gong)的(de)退(tui)火(huo)(huo)(huo)要求是(shi):由桿經(jing)拉(la)制,但尚未鑄(zhu)造(zao)(zao)(zao)組(zu)織的(de)線(xian)時(shi)的(de)第一(yi)次退(tui)火(huo)(huo)(huo),其退(tui)火(huo)(huo)(huo)功(gong)率(lv)應比同(tong)樣情況的(de)低氧(yang)(yang)銅(tong)高(gao)10——15%。經(jing)繼續拉(la)制,在以后階段的(de)退(tui)火(huo)(huo)(huo)功(gong)率(lv)應留(liu)有足(zu)夠的(de)余量和(he)對低氧(yang)(yang)銅(tong)和(he)無(wu)氧(yang)(yang)銅(tong)切實區別執行不同(tong)的(de)退(tui)火(huo)(huo)(huo)工(gong)藝,以保證(zheng)在制品和(he)成品導線(xian)的(de)柔軟性(xing)。
三、夾雜,氧(yang)含量(liang)波動(dong),表(biao)面氧(yang)化物和可(ke)能存(cun)在的熱(re)軋缺陷的差(cha)別
無氧(yang)(yang)(yang)銅桿(gan)的(de)(de)(de)可(ke)拉性在(zai)所有線(xian)(xian)徑(jing)里(li)與低氧(yang)(yang)(yang)銅桿(gan)相比(bi)都(dou)是優越的(de)(de)(de),除上述(shu)組織原因外,無氧(yang)(yang)(yang)銅桿(gan)夾雜少,含氧(yang)(yang)(yang)量穩定,無熱軋可(ke)能(neng)(neng)產(chan)(chan)生的(de)(de)(de)缺(que)陷,桿(gan)表氧(yang)(yang)(yang)化(hua)物(wu)厚度可(ke)達≤15A。在(zai)連鑄(zhu)連軋生產(chan)(chan)過(guo)程中如果(guo)工(gong)藝不穩定,對氧(yang)(yang)(yang)監控不嚴,含氧(yang)(yang)(yang)量不穩定將直(zhi)接影響桿(gan)的(de)(de)(de)性能(neng)(neng)。如果(guo)桿(gan)的(de)(de)(de)表面氧(yang)(yang)(yang)化(hua)物(wu)能(neng)(neng)在(zai)后工(gong)序的(de)(de)(de)連續清洗(xi)中得以彌補外,但(dan)比(bi)較麻煩(fan)的(de)(de)(de)是有相當多的(de)(de)(de)氧(yang)(yang)(yang)化(hua)物(wu)存在(zai)于“皮(pi)下”,對拉線(xian)(xian)斷線(xian)(xian)影響更直(zhi)接,故(gu)而在(zai)拉制(zhi)微(wei)細線(xian)(xian),超微(wei)細線(xian)(xian)時,為了減少斷線(xian)(xian),有時要對銅桿(gan)采(cai)取不得已的(de)(de)(de)辦法——剝皮(pi),甚至二(er)次剝皮(pi)的(de)(de)(de)原因所在(zai),目的(de)(de)(de)要除去皮(pi)下氧(yang)(yang)(yang)化(hua)物(wu)。
四(si)、低氧銅桿和無氧銅桿的韌性(xing)有差(cha)別
兩者(zhe)都可以拉(la)到0.015mm,但(dan)在低(di)溫(wen)超導線中的(de)低(di)溫(wen)級無氧銅,其細絲(si)間的(de)間距只有0.001mm.
五、從制(zhi)桿(gan)的(de)原材料到制(zhi)線的(de)經濟性(xing)有差別(bie)。
制(zhi)造無氧(yang)銅(tong)(tong)桿要求質量較高的(de)原材料。一(yi)般,拉(la)制(zhi)直(zhi)徑(jing)>1mm的(de)銅(tong)(tong)線時,低氧(yang)銅(tong)(tong)桿的(de)優(you)點比較明顯(xian),而無氧(yang)銅(tong)(tong)桿顯(xian)得(de)更(geng)為優(you)越(yue)的(de)是拉(la)制(zhi)直(zhi)徑(jing)<0.5mm的(de)銅(tong)(tong)線。
六、低(di)氧銅桿(gan)的制線工藝(yi)與(yu)無(wu)氧銅桿(gan)的有所不同。
低(di)氧(yang)銅(tong)桿(gan)(gan)的制(zhi)線(xian)(xian)工藝不能照搬到無氧(yang)銅(tong)桿(gan)(gan)的制(zhi)線(xian)(xian)工藝上(shang)來,至少兩者的退(tui)火工藝是不同的。因為線(xian)(xian)的柔(rou)軟(ruan)性(xing)深受材料(liao)成份和制(zhi)桿(gan)(gan),制(zhi)線(xian)(xian)和退(tui)火工藝的影響,不能簡單地說(shuo)低(di)氧(yang)銅(tong)或無氧(yang)銅(tong)誰軟(ruan)誰硬。
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