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白塔電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱(yue)讀:109584 發(fa)布(bu)時間:2019-07-05

導讀:由(you)于生(sheng)(sheng)產銅(tong)(tong)(tong)桿的(de)(de)兩者的(de)(de)工藝(yi)不同,所(suo)生(sheng)(sheng)產的(de)(de)銅(tong)(tong)(tong)桿中(zhong)的(de)(de)含氧量(liang)及(ji)外觀就(jiu)不同。上引生(sheng)(sheng)產的(de)(de)銅(tong)(tong)(tong)桿,工藝(yi)得當(dang)氧含量(liang)在10ppm以下(xia),叫(jiao)無氧銅(tong)(tong)(tong)桿;連鑄連鑄生(sheng)(sheng)產的(de)(de)銅(tong)(tong)(tong)桿 是(shi)在保護條件下(xia)的(de)(de)熱軋,氧含量(liang)在200-500ppm范圍(wei)內(nei),但有(you)時(shi)也高(gao)達700ppm以上,一般情況下(xia),此(ci)種方法生(sheng)(sheng)產的(de)(de)銅(tong)(tong)(tong)外表光(guang)亮,低氧銅(tong)(tong)(tong)桿,有(you)時(shi)也叫(jiao)光(guang)桿。

銅(tong)桿是電纜行(xing)(xing)業的(de)主(zhu)要原料,生(sheng)產(chan)的(de)方(fang)式主(zhu)要有兩種——連鑄連軋(ya)(ya)法和上引(yin)連鑄法。連鑄連軋(ya)(ya)低氧銅(tong)桿的(de)生(sheng)產(chan)方(fang)法較(jiao)多(duo),其特點是金屬在(zai)(zai)豎爐(lu)中融化后(hou),銅(tong)液通過(guo)保溫爐(lu)、溜槽(cao)、中間(jian)包(bao),從澆管進(jin)(jin)入(ru)封(feng)閉的(de)模腔內,采用(yong)較(jiao)大(da)的(de)冷卻強度進(jin)(jin)行(xing)(xing)冷卻,形(xing)成鑄坯,然后(hou)進(jin)(jin)行(xing)(xing)多(duo)道次(ci)軋(ya)(ya)制,生(sheng)產(chan)的(de)低氧銅(tong)桿為熱(re)加(jia)工(gong)組(zu)(zu)織,原來的(de)鑄造組(zu)(zu)織已經破碎,含氧量(liang)一般(ban)為200~400ppm之間(jian)。無氧銅(tong)桿國內基本全部采用(yong)上引(yin)連鑄法生(sheng)產(chan),金屬在(zai)(zai)感應電爐(lu)中融化后(hou)通過(guo)石墨模進(jin)(jin)行(xing)(xing)上引(yin)連續(xu)鑄造,之后(hou)進(jin)(jin)行(xing)(xing)冷軋(ya)(ya)或冷加(jia)工(gong),生(sheng)產(chan)的(de)無氧銅(tong)桿為鑄造組(zu)(zu)織,含氧量(liang)一般(ban)在(zai)(zai)20ppm以(yi)下。由于制造工(gong)藝的(de)不同,所以(yi)在(zai)(zai)組(zu)(zu)織結(jie)構、氧含量(liang)分(fen)布、雜質的(de)形(xing)式及分(fen)布等(deng)諸多(duo)方(fang)面(mian)有較(jiao)大(da)差別。

一、拉制性能

銅桿的(de)拉(la)制(zhi)性(xing)能跟很(hen)多因素(su)有關,如雜質(zhi)的(de)含量(liang)、氧含量(liang)及分布、工藝控(kong)制(zhi)等。下(xia)面(mian)分別從(cong)以上幾個方面(mian)對銅桿的(de)拉(la)制(zhi)性(xing)能進行分析。

1、熔化方式對S等雜質的影響(xiang)

連(lian)鑄連(lian)軋生產(chan)(chan)銅(tong)(tong)桿主要是(shi)(shi)通(tong)過氣體的燃燒(shao)使銅(tong)(tong)桿熔(rong)(rong)(rong)化(hua),在燃燒(shao)的過程中(zhong),通(tong)過氧(yang)化(hua)和揮發作用,可一定程度減(jian)少部分(fen)雜(za)質進入(ru)銅(tong)(tong)液,因此連(lian)鑄連(lian)軋法對(dui)原料(liao)要求相對(dui)低(di)一些。上引連(lian)鑄生產(chan)(chan)無(wu)氧(yang)銅(tong)(tong)桿,由于是(shi)(shi)用感應電(dian)爐(lu)熔(rong)(rong)(rong)化(hua),電(dian)解銅(tong)(tong)表面的“銅(tong)(tong)綠”“銅(tong)(tong)豆”基(ji)本都熔(rong)(rong)(rong)入(ru)到銅(tong)(tong)液中(zhong)。其中(zhong)熔(rong)(rong)(rong)入(ru)的S對(dui)無(wu)氧(yang)銅(tong)(tong)桿塑性影(ying)響(xiang)極大(da),會增加拉絲斷線率(lv)。

2、鑄造過程中雜質的進入

在生產過(guo)程中(zhong),連(lian)鑄連(lian)軋工藝需(xu)通過(guo)保溫爐、溜槽、中(zhong)間包轉運銅液,相對(dui)容易造成(cheng)耐火材(cai)料的(de)(de)(de)(de)剝(bo)落,在軋制過(guo)程中(zhong)需(xu)要(yao)通過(guo)軋輥,造成(cheng)鐵質(zhi)的(de)(de)(de)(de)脫(tuo)落,會給銅桿(gan)造成(cheng)外部(bu)夾雜(za)(za)。而熱軋中(zhong)皮上和皮下氧(yang)化物(wu)的(de)(de)(de)(de)軋入,會給低氧(yang)桿(gan)的(de)(de)(de)(de)拉絲造成(cheng)不(bu)利(li)的(de)(de)(de)(de)影響。上引連(lian)鑄法(fa)生產工藝流程較短,銅液是通過(guo)聯體爐內(nei)潛流式(shi)完成(cheng),對(dui)耐火材(cai)料的(de)(de)(de)(de)沖擊不(bu)大,結晶(jing)是通過(guo)石墨模(mo)內(nei)進行(xing),所以過(guo)程中(zhong)可能(neng)產生的(de)(de)(de)(de)污(wu)染源較少,雜(za)(za)質(zhi)進入的(de)(de)(de)(de)機(ji)會較少。

O、S、P是(shi)與銅(tong)(tong)(tong)會生產化(hua)合物的(de)元素。在熔(rong)態銅(tong)(tong)(tong)中,氧(yang)(yang)可(ke)以溶解(jie)(jie)一部(bu)分,但當銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)幾乎不溶解(jie)(jie)于(yu)銅(tong)(tong)(tong)中。熔(rong)態時所溶解(jie)(jie)的(de)氧(yang)(yang),以銅(tong)(tong)(tong)=氧(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共(gong)晶(jing)體析(xi)出,分布在晶(jing)粒晶(jing)界處(chu)。銅(tong)(tong)(tong)-氧(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共(gong)晶(jing)體的(de)出現,顯著降低了銅(tong)(tong)(tong)的(de)塑性。

硫可以溶解在熔體(ti)的銅(tong)(tong)中,但(dan)在室溫下,其溶解度幾乎降低到零,它以硫化亞銅(tong)(tong)的形(xing)式出現(xian)在晶粒(li)晶界(jie)處,會顯著降低銅(tong)(tong)的塑性(xing)。

3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中分布形式及(ji)其(qi)影響

氧(yang)含量對低(di)(di)氧(yang)銅桿的拉(la)線(xian)性能有著明顯的影響(xiang)。當(dang)氧(yang)含量增加到最佳值(zhi)時,銅桿的斷線(xian)率最低(di)(di)。這是因為氧(yang)在與大部分雜質反應的過程中都起到了清除器的作用。適度的氧(yang)還(huan)有利于(yu)去除銅液中的氫,生成水蒸氣溢(yi)出,減少(shao)氣孔的形成。最佳的氧(yang)含量為拉(la)線(xian)工藝(yi)提(ti)供了最好的條件(jian)。

低氧銅(tong)桿(gan)(gan)氧化(hua)物(wu)的(de)(de)(de)(de)分布:在連(lian)續澆鑄(zhu)中(zhong)(zhong)凝固的(de)(de)(de)(de)最初(chu)階段,散熱速率(lv)和(he)均勻(yun)冷卻(que)(que)是(shi)決定銅(tong)桿(gan)(gan)氧化(hua)物(wu)分布的(de)(de)(de)(de)主要因素。不均勻(yun)冷卻(que)(que)會(hui)引起(qi)銅(tong)桿(gan)(gan)內部結構本質上的(de)(de)(de)(de)差異,但后續的(de)(de)(de)(de)熱加工,柱狀晶通常會(hui)遭(zao)到破(po)壞,使氧化(hua)亞銅(tong)顆粒(li)細微(wei)化(hua)和(he)均勻(yun)分布。氧化(hua)物(wu)顆粒(li)聚(ju)集而產(chan)生(sheng)的(de)(de)(de)(de)典型情況是(shi)中(zhong)(zhong)心爆裂。除氧化(hua)物(wu)顆粒(li)分布的(de)(de)(de)(de)影響外(wai),具(ju)有較小(xiao)氧化(hua)物(wu)顆粒(li)的(de)(de)(de)(de)銅(tong)桿(gan)(gan)顯示出較好(hao)的(de)(de)(de)(de)拉線特(te)性,較大的(de)(de)(de)(de)Cu2O顆粒(li)容易造成(cheng)應力集中(zhong)(zhong)點(dian)而斷裂。

無(wu)氧(yang)(yang)(yang)(yang)銅含(han)氧(yang)(yang)(yang)(yang)量超(chao)標,銅桿變(bian)脆(cui)(cui),延伸率(lv)下降(jiang),拉(la)伸式樣(yang)端口(kou)顯暗紅色,結晶(jing)組織(zhi)疏松。當氧(yang)(yang)(yang)(yang)含(han)量超(chao)出8ppm時(shi),工(gong)藝(yi)性(xing)(xing)能變(bian)差(cha),表現(xian)為鑄造(zao)及拉(la)伸過程(cheng)中斷(duan)桿及斷(duan)線率(lv)極具增高(gao)(gao)。這是由于氧(yang)(yang)(yang)(yang)能與銅生成氧(yang)(yang)(yang)(yang)化亞銅脆(cui)(cui)性(xing)(xing)相,形成銅-氧(yang)(yang)(yang)(yang)化亞銅共晶(jing)體(ti),以網(wang)狀組織(zhi)分布在境(jing)界(jie)上(shang)。這種脆(cui)(cui)性(xing)(xing)相硬度(du)高(gao)(gao),在冷變(bian)形時(shi)將會與銅機(ji)體(ti)脫(tuo)離,導致(zhi)銅桿的機(ji)械性(xing)(xing)能下降(jiang),在后續加工(gong)中容易造(zao)成斷(duan)裂現(xian)象。氧(yang)(yang)(yang)(yang)含(han)量高(gao)(gao)還(huan)能導致(zhi)無(wu)氧(yang)(yang)(yang)(yang)銅桿導電(dian)率(lv)下降(jiang)。因此(ci),必(bi)須嚴格控制上(shang)引(yin)連鑄工(gong)藝(yi)及產品(pin)質(zhi)量。

4、氫的影響

在上引連(lian)鑄(zhu)中,氧(yang)含量控制(zhi)較低,氧(yang)化物的副作用唄**降低,但氫的影響(xiang)成(cheng)為較顯著的問題。吸氣后熔(rong)體中存在平衡反應:H2O(g)=[O]+2[H];

氣體(ti)(ti)及(ji)疏松(song)(song)是(shi)在(zai)結(jie)(jie)晶的(de)(de)過程中,氫(qing)(qing)從過飽和(he)的(de)(de)溶液(ye)中析出(chu)并聚(ju)(ju)集而形(xing)成(cheng)的(de)(de)。在(zai)結(jie)(jie)晶前析出(chu)的(de)(de)氫(qing)(qing)又可還(huan)原(yuan)氧(yang)化亞銅而生成(cheng)水(shui)氣泡。由于(yu)上引鑄(zhu)造的(de)(de)特點是(shi)銅液(ye)自上而下的(de)(de)結(jie)(jie)晶,形(xing)成(cheng)的(de)(de)液(ye)**形(xing)狀近似錐型。銅液(ye)結(jie)(jie)晶前析出(chu)的(de)(de)氣體(ti)(ti)在(zai)上浮過程中被堵在(zai)凝固組織(zhi)內,結(jie)(jie)晶時(shi)在(zai)鑄(zhu)桿內形(xing)成(cheng)氣孔。上引的(de)(de)含(han)氣量少時(shi),析出(chu)的(de)(de)氫(qing)(qing)存在(zai)于(yu)晶界(jie)處,形(xing)成(cheng)疏松(song)(song);含(han)氣量多時(shi),則聚(ju)(ju)集成(cheng)氣孔,因此,氣孔和(he)疏松(song)(song)是(shi)氫(qing)(qing)氣和(he)水(shui)蒸氣兩者形(xing)成(cheng)的(de)(de)。

氫來源于上引生產過程中(zhong)的各(ge)個(ge)工(gong)藝環(huan)節(jie),如(ru)原(yuan)料電解(jie)(jie)銅(tong)的“銅(tong)綠”、輔料木炭**、氣候環(huan)境**、石墨結晶器未干(gan)燥等。因(yin)此,熔化(hua)爐中(zhong)的銅(tong)液表面應(ying)覆蓋經烘(hong)烤的木炭,電解(jie)(jie)銅(tong)應(ying)盡(jin)量去除(chu)“銅(tong)綠”、“銅(tong)豆”“耳朵(duo)”,對(dui)提高無氧銅(tong)桿質量非常(chang)重要(yao)。

在連鑄連軋工藝中(zhong),往(wang)往(wang)采用適(shi)度控制(zhi)(zhi)氧(yang)含(han)量來控制(zhi)(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)液(ye)(ye)在鑄造過程中是自下而上(shang)結(jie)晶,銅(tong)液(ye)(ye)中的(de)(de)(de)氧和氫所產生(sheng)的(de)(de)(de)水(shui)蒸氣很(hen)容易上(shang)浮跑(pao)出,銅(tong)液(ye)(ye)中的(de)(de)(de)氫大部分能(neng)被有效去除,因而對銅(tong)桿的(de)(de)(de)影響(xiang)較(jiao)小(xiao)。

二、表面質量

在(zai)生產(chan)電磁(ci)線等(deng)產(chan)品的過(guo)程中,對銅(tong)(tong)桿的表面(mian)質量(liang)也需(xu)提出(chu)要(yao)求。需(xu)要(yao)拉制后的銅(tong)(tong)絲表面(mian)無毛刺、銅(tong)(tong)粉少、無油污。并(bing)通(tong)過(guo)扭轉試驗測量(liang)表面(mian)銅(tong)(tong)粉的質量(liang)和扭轉后觀(guan)察銅(tong)(tong)桿的復原情況來判定其好壞。

在連鑄連軋(ya)(ya)過程中(zhong),從(cong)鑄造(zao)到(dao)軋(ya)(ya)制(zhi)前,溫度高,完全暴露于空氣中(zhong),使鑄坯表(biao)面形成較(jiao)厚的(de)(de)(de)氧(yang)(yang)(yang)化(hua)(hua)(hua)層,在軋(ya)(ya)制(zhi)過程中(zhong),隨著(zhu)軋(ya)(ya)輥(gun)的(de)(de)(de)轉動,氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)顆粒軋(ya)(ya)入銅(tong)線表(biao)面。由于氧(yang)(yang)(yang)化(hua)(hua)(hua)亞銅(tong)是高熔點脆性(xing)化(hua)(hua)(hua)合(he)物(wu),對于軋(ya)(ya)入較(jiao)深的(de)(de)(de)氧(yang)(yang)(yang)化(hua)(hua)(hua)亞銅(tong),當成條(tiao)狀的(de)(de)(de)聚集物(wu)遇模(mo)具拉伸時,就會是銅(tong)桿外表(biao)面產生毛刺,給后續的(de)(de)(de)涂(tu)漆造(zao)成麻煩。

而上引(yin)連鑄工(gong)藝制(zhi)造的(de)無氧(yang)銅桿,由于鑄造和冷卻完全與氧(yang)隔(ge)絕,后續(xu)亦無熱軋過程,銅桿表面(mian)無軋入表面(mian)的(de)氧(yang)化物,質(zhi)量較(jiao)(jiao)好(hao),拉(la)制(zhi)后銅粉少,上述(shu)問題較(jiao)(jiao)少存在。

無氧銅桿也分進口(kou)設(she)(she)備(bei)做(zuo)的(de)(de)和國(guo)產(chan)(chan)(chan)設(she)(she)備(bei)做(zuo)的(de)(de),但目前進口(kou)產(chan)(chan)(chan)品已無明(ming)顯優勢,銅桿產(chan)(chan)(chan)品出(chu)來后區別不是很(hen)大,只要銅板選(xuan)的(de)(de)好,生產(chan)(chan)(chan)控(kong)制比(bi)較穩定,國(guo)產(chan)(chan)(chan)設(she)(she)備(bei)也能產(chan)(chan)(chan)出(chu)可拉伸0.05的(de)(de)銅桿.進口(kou)設(she)(she)備(bei)一般是芬(fen)蘭奧(ao)托昆普的(de)(de)設(she)(she)備(bei),國(guo)產(chan)(chan)(chan)設(she)(she)備(bei)最(zui)好的(de)(de)應該是上海的(de)(de)海軍廠的(de)(de)了,生產(chan)(chan)(chan)時間最(zui)長,軍工企業,質量(liang)可靠(kao)。

低氧銅桿進口設備(bei)國(guo)(guo)際主要有兩種,一種是(shi)(shi)美國(guo)(guo)南線設備(bei),英文是(shi)(shi)SOUTHWIRE,國(guo)(guo)內(nei)廠家是(shi)(shi)南京華新,江西銅業(ye),另(ling)一種是(shi)(shi)德國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內(nei)廠家是(shi)(shi)常(chang)州金源,天津大無縫。

無(wu)(wu)氧(yang)(yang)(yang)及(ji)低(di)氧(yang)(yang)(yang)桿(gan)從含(han)(han)氧(yang)(yang)(yang)量(liang)上(shang)容易區(qu)別,無(wu)(wu)氧(yang)(yang)(yang)銅是含(han)(han)氧(yang)(yang)(yang)量(liang)在10-20個(ge)PPM以下,但目(mu)前有的(de)(de)(de)(de)(de)廠家只(zhi)能(neng)做(zuo)到(dao)50個(ge)PPM以下.低(di)氧(yang)(yang)(yang)銅桿(gan)在 200-400個(ge)PPM,好(hao)的(de)(de)(de)(de)(de)桿(gan)子一(yi)般含(han)(han)氧(yang)(yang)(yang)量(liang)控制(zhi)在250個(ge)PPM左(zuo)右,無(wu)(wu)氧(yang)(yang)(yang)桿(gan)一(yi)般采取的(de)(de)(de)(de)(de)是上(shang)引(yin)法(fa),低(di)氧(yang)(yang)(yang)桿(gan)是連(lian)鑄連(lian)軋,兩種產品相對(dui)而(er)言低(di)氧(yang)(yang)(yang)桿(gan)對(dui)漆包線(xian)性 能(neng)更(geng)適應(ying)些(xie)(xie),如(ru)柔軟性,回彈角,繞線(xian)性能(neng).但低(di)氧(yang)(yang)(yang)桿(gan)對(dui)拉(la)(la)絲條(tiao)(tiao)件相對(dui)要苛刻些(xie)(xie),同(tong)樣拉(la)(la)伸(shen)(shen)0.2的(de)(de)(de)(de)(de)細絲,如(ru)果伸(shen)(shen)線(xian)條(tiao)(tiao)件不好(hao),普(pu)通(tong)的(de)(de)(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)可拉(la)(la)而(er)好(hao)的(de)(de)(de)(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)就斷(duan) 線(xian),但如(ru)果放在好(hao)的(de)(de)(de)(de)(de)伸(shen)(shen)線(xian)條(tiao)(tiao)件,同(tong)樣的(de)(de)(de)(de)(de)桿(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)說不定(ding)就能(neng)拉(la)(la)到(dao)雙零(ling)五,而(er)普(pu)通(tong)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)最多(duo)只(zhi)能(neng)拉(la)(la)伸(shen)(shen)到(dao)0.1而(er)已,當然做(zuo)的(de)(de)(de)(de)(de)最細的(de)(de)(de)(de)(de)如(ru)雙零(ling)二卻非得依靠進口(kou)的(de)(de)(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)了.目(mu)前有企業嘗試用剝皮的(de)(de)(de)(de)(de)方(fang)(fang)式來處理低(di)氧(yang)(yang)(yang)桿(gan)來伸(shen)(shen)0.03線(xian).但有關這(zhe)方(fang)(fang)面的(de)(de)(de)(de)(de)內容我還不是很清楚。

音響線一般反而喜歡用無氧(yang)桿(gan),這和(he)無氧(yang)桿(gan)是單晶銅,低氧(yang)桿(gan)是多晶銅有關。

氧銅(tong)桿(gan)和無氧銅(tong)桿(gan)由于制造方法的不同,致(zhi)使存在(zai)差別,具有(you)各(ge)自的特(te)點。

一、關于氧(yang)的(de)吸入和脫(tuo)去以(yi)及它的(de)存(cun)在狀態

生(sheng)產(chan)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)陰極(ji)銅(tong)(tong)的(de)(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常溫下(xia)氧(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)(zai)200(175)—400(450)ppm,因此(ci)氧(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入(ru)是在(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)(de)液(ye)態下(xia)吸入(ru)的(de)(de)(de)(de)(de),而(er)上引法(fa)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則相反,氧(yang)(yang)(yang)(yang)在(zai)(zai)液(ye)態銅(tong)(tong)下(xia)保持(chi)相當時間(jian)后,被還(huan)原(yuan)而(er)脫(tuo)去,通常這種(zhong)桿(gan)的(de)(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低(di)可(ke)達(da)1-2ppm,從組織(zhi)上看(kan),低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)狀態,存(cun)在(zai)(zai)于晶粒邊界附近,這對低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)而(er)言可(ke)以(yi)(yi)說是常見(jian)(jian)的(de)(de)(de)(de)(de)但對無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則很少見(jian)(jian)。氧(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)以(yi)(yi)夾(jia)雜形式在(zai)(zai)晶界出現對材料(liao)的(de)(de)(de)(de)(de)韌(ren)性(xing)產(chan)生(sheng)負面影響。而(er)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)很低(di),所以(yi)(yi)這種(zhong)銅(tong)(tong)的(de)(de)(de)(de)(de)組織(zhi)是均勻的(de)(de)(de)(de)(de)單相組織(zhi)對韌(ren)性(xing)有利。在(zai)(zai)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)(de)(de)多孔性(xing)是不常見(jian)(jian)的(de)(de)(de)(de)(de),而(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)則是常見(jian)(jian)的(de)(de)(de)(de)(de)一(yi)種(zhong)缺陷。

二、熱(re)軋組織和鑄造組織的區(qu)別

低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)由于經過熱(re)軋,所以其組(zu)織(zhi)(zhi)(zhi)(zhi)屬熱(re)加工組(zu)織(zhi)(zhi)(zhi)(zhi),原來的(de)鑄造組(zu)織(zhi)(zhi)(zhi)(zhi)已經破碎,在(zai)(zai)8mm的(de)桿(gan)時(shi)已有再(zai)結(jie)晶(jing)(jing)的(de)形式出現,而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)屬鑄造組(zu)織(zhi)(zhi)(zhi)(zhi),晶(jing)(jing)粒粗大(da),這是(shi)為(wei)什么,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)的(de)再(zai)結(jie)晶(jing)(jing)溫(wen)度較(jiao)(jiao)高,需要(yao)較(jiao)(jiao)高退(tui)(tui)火溫(wen)度的(de)固(gu)有原因(yin)。這是(shi)因(yin)為(wei),再(zai)結(jie)晶(jing)(jing)發生在(zai)(zai)晶(jing)(jing)粒邊界附近,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)組(zu)織(zhi)(zhi)(zhi)(zhi)晶(jing)(jing)粒粗大(da),晶(jing)(jing)粒尺寸(cun)甚(shen)至(zhi)能(neng)達幾個毫米,因(yin)而晶(jing)(jing)粒邊界少,即使通過拉(la)制(zhi)(zhi)(zhi)(zhi)變形,但晶(jing)(jing)粒邊界相對(dui)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)還是(shi)較(jiao)(jiao)少,所以需要(yao)較(jiao)(jiao)高的(de)退(tui)(tui)火功率(lv)。對(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)成功的(de)退(tui)(tui)火要(yao)求是(shi):由桿(gan)經拉(la)制(zhi)(zhi)(zhi)(zhi),但尚未鑄造組(zu)織(zhi)(zhi)(zhi)(zhi)的(de)線(xian)時(shi)的(de)第(di)一次退(tui)(tui)火,其退(tui)(tui)火功率(lv)應比同(tong)樣(yang)情況的(de)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)高10——15%。經繼續拉(la)制(zhi)(zhi)(zhi)(zhi),在(zai)(zai)以后階(jie)段的(de)退(tui)(tui)火功率(lv)應留有足夠(gou)的(de)余量(liang)和(he)(he)對(dui)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)和(he)(he)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)切實區別執(zhi)行不同(tong)的(de)退(tui)(tui)火工藝(yi),以保證(zheng)在(zai)(zai)制(zhi)(zhi)(zhi)(zhi)品(pin)和(he)(he)成品(pin)導線(xian)的(de)柔(rou)軟性。

三、夾雜,氧含量波動,表面氧化物和可(ke)能存在的熱(re)軋(ya)缺陷的差別

無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)(de)可(ke)(ke)拉性在所有(you)線(xian)(xian)(xian)徑里(li)與低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)相比都是優越的(de)(de),除(chu)上述(shu)組織原因外(wai),無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)夾雜少(shao),含氧(yang)(yang)(yang)(yang)量穩(wen)定,無(wu)熱軋可(ke)(ke)能產生(sheng)的(de)(de)缺陷,桿(gan)(gan)表(biao)氧(yang)(yang)(yang)(yang)化物(wu)厚度(du)可(ke)(ke)達≤15A。在連(lian)鑄(zhu)連(lian)軋生(sheng)產過程中如果工藝不穩(wen)定,對氧(yang)(yang)(yang)(yang)監控不嚴,含氧(yang)(yang)(yang)(yang)量不穩(wen)定將直接影響桿(gan)(gan)的(de)(de)性能。如果桿(gan)(gan)的(de)(de)表(biao)面氧(yang)(yang)(yang)(yang)化物(wu)能在后工序的(de)(de)連(lian)續清(qing)洗中得以彌補外(wai),但比較(jiao)麻(ma)煩的(de)(de)是有(you)相當多的(de)(de)氧(yang)(yang)(yang)(yang)化物(wu)存在于(yu)“皮(pi)下”,對拉線(xian)(xian)(xian)斷(duan)線(xian)(xian)(xian)影響更直接,故而在拉制微細線(xian)(xian)(xian),超微細線(xian)(xian)(xian)時,為了(le)減(jian)少(shao)斷(duan)線(xian)(xian)(xian),有(you)時要(yao)對銅(tong)(tong)桿(gan)(gan)采取不得已的(de)(de)辦法(fa)——剝皮(pi),甚至二次剝皮(pi)的(de)(de)原因所在,目的(de)(de)要(yao)除(chu)去皮(pi)下氧(yang)(yang)(yang)(yang)化物(wu)。

四、低(di)氧(yang)銅桿和無氧(yang)銅桿的韌性有差別

兩者都可以拉到0.015mm,但在低(di)溫(wen)超導線(xian)中的低(di)溫(wen)級無氧(yang)銅,其細(xi)絲間(jian)的間(jian)距只有0.001mm.

五、從(cong)制(zhi)桿的原材料到制(zhi)線(xian)的經(jing)濟(ji)性(xing)有(you)差別。

制(zhi)造無(wu)氧(yang)銅桿要求質量(liang)較(jiao)高的原材料。一般,拉制(zhi)直徑(jing)>1mm的銅線(xian)時(shi),低氧(yang)銅桿的優點比較(jiao)明顯,而(er)無(wu)氧(yang)銅桿顯得更為優越的是(shi)拉制(zhi)直徑(jing)<0.5mm的銅線(xian)。

六、低氧銅桿(gan)的(de)制線(xian)工藝與無(wu)氧銅桿(gan)的(de)有(you)所不同。

低(di)氧(yang)銅桿的(de)制(zhi)(zhi)線(xian)工(gong)藝不(bu)能(neng)照搬到無(wu)氧(yang)銅桿的(de)制(zhi)(zhi)線(xian)工(gong)藝上來,至(zhi)少兩者的(de)退(tui)火(huo)工(gong)藝是(shi)不(bu)同的(de)。因為線(xian)的(de)柔(rou)軟(ruan)(ruan)性深(shen)受材料成(cheng)份(fen)和制(zhi)(zhi)桿,制(zhi)(zhi)線(xian)和退(tui)火(huo)工(gong)藝的(de)影響(xiang),不(bu)能(neng)簡單(dan)地說低(di)氧(yang)銅或無(wu)氧(yang)銅誰(shui)軟(ruan)(ruan)誰(shui)硬。