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來源(yuan):行業動態 閱(yue)讀:109238 發布時間:2019-07-05
導(dao)讀(du):由于生產銅(tong)桿的(de)兩者的(de)工藝不同,所生產的(de)銅(tong)桿中的(de)含氧量(liang)及外(wai)觀就(jiu)不同。上(shang)引生產的(de)銅(tong)桿,工藝得當氧含量(liang)在(zai)10ppm以下(xia),叫(jiao)無氧銅(tong)桿;連(lian)鑄連(lian)鑄生產的(de)銅(tong)桿 是在(zai)保護條(tiao)件下(xia)的(de)熱軋,氧含量(liang)在(zai)200-500ppm范(fan)圍內,但有時(shi)(shi)也高達700ppm以上(shang),一(yi)般(ban)情況下(xia),此種方法生產的(de)銅(tong)外(wai)表光亮,低氧銅(tong)桿,有時(shi)(shi)也叫(jiao)光桿。
銅(tong)桿(gan)是電(dian)纜行業(ye)的主要(yao)原(yuan)(yuan)料,生(sheng)產(chan)(chan)的方式(shi)主要(yao)有(you)兩(liang)種——連鑄(zhu)連軋(ya)(ya)(ya)法(fa)和上(shang)(shang)引連鑄(zhu)法(fa)。連鑄(zhu)連軋(ya)(ya)(ya)低氧(yang)(yang)銅(tong)桿(gan)的生(sheng)產(chan)(chan)方法(fa)較多,其特點是金屬在豎爐中(zhong)融(rong)化后(hou),銅(tong)液通過保溫爐、溜槽、中(zhong)間包,從(cong)澆管進(jin)(jin)(jin)入封(feng)閉的模腔內,采用較大(da)的冷(leng)卻(que)強度進(jin)(jin)(jin)行冷(leng)卻(que),形成(cheng)鑄(zhu)坯,然后(hou)進(jin)(jin)(jin)行多道次軋(ya)(ya)(ya)制(zhi),生(sheng)產(chan)(chan)的低氧(yang)(yang)銅(tong)桿(gan)為(wei)熱加(jia)工(gong)組織(zhi)(zhi),原(yuan)(yuan)來的鑄(zhu)造(zao)組織(zhi)(zhi)已(yi)經破碎,含氧(yang)(yang)量(liang)一般(ban)為(wei)200~400ppm之(zhi)間。無氧(yang)(yang)銅(tong)桿(gan)國內基本全部采用上(shang)(shang)引連鑄(zhu)法(fa)生(sheng)產(chan)(chan),金屬在感應電(dian)爐中(zhong)融(rong)化后(hou)通過石墨模進(jin)(jin)(jin)行上(shang)(shang)引連續(xu)鑄(zhu)造(zao),之(zhi)后(hou)進(jin)(jin)(jin)行冷(leng)軋(ya)(ya)(ya)或(huo)冷(leng)加(jia)工(gong),生(sheng)產(chan)(chan)的無氧(yang)(yang)銅(tong)桿(gan)為(wei)鑄(zhu)造(zao)組織(zhi)(zhi),含氧(yang)(yang)量(liang)一般(ban)在20ppm以(yi)下。由于(yu)制(zhi)造(zao)工(gong)藝的不同(tong),所(suo)以(yi)在組織(zhi)(zhi)結構(gou)、氧(yang)(yang)含量(liang)分布(bu)、雜(za)質的形式(shi)及分布(bu)等諸多方面有(you)較大(da)差別。
一、拉制性能
銅桿的(de)拉制性能跟很多因素有(you)關,如(ru)雜質(zhi)的(de)含(han)量(liang)、氧含(han)量(liang)及分(fen)布(bu)、工藝控制等。下面分(fen)別從以上幾個方面對銅桿的(de)拉制性能進行分(fen)析(xi)。
1、熔化方式(shi)對S等雜質的影響
連鑄連軋生產銅(tong)桿(gan)主(zhu)要(yao)(yao)是(shi)(shi)通過氣體的燃燒使銅(tong)桿(gan)熔(rong)(rong)化,在(zai)燃燒的過程中(zhong),通過氧化和揮發作(zuo)用(yong),可(ke)一(yi)定(ding)程度減少部分雜質(zhi)進(jin)入(ru)銅(tong)液(ye),因此連鑄連軋法對(dui)原料要(yao)(yao)求相對(dui)低一(yi)些。上引連鑄生產無氧銅(tong)桿(gan),由于是(shi)(shi)用(yong)感應電(dian)爐熔(rong)(rong)化,電(dian)解銅(tong)表面(mian)的“銅(tong)綠”“銅(tong)豆”基本都熔(rong)(rong)入(ru)到(dao)銅(tong)液(ye)中(zhong)。其中(zhong)熔(rong)(rong)入(ru)的S對(dui)無氧銅(tong)桿(gan)塑(su)性影(ying)響極大,會增加拉絲斷線率。
2、鑄造過程中雜(za)質的進入(ru)
在生(sheng)產(chan)(chan)過程(cheng)中(zhong),連(lian)鑄連(lian)軋工藝需通過保溫爐、溜(liu)槽、中(zhong)間包轉運(yun)銅(tong)液,相對(dui)(dui)容易造(zao)成耐火材料的(de)剝落(luo),在軋制過程(cheng)中(zhong)需要通過軋輥,造(zao)成鐵質(zhi)的(de)脫落(luo),會給(gei)銅(tong)桿造(zao)成外部(bu)夾雜(za)。而熱(re)軋中(zhong)皮(pi)上和皮(pi)下氧化物的(de)軋入(ru),會給(gei)低氧桿的(de)拉絲造(zao)成不利的(de)影響。上引連(lian)鑄法生(sheng)產(chan)(chan)工藝流程(cheng)較(jiao)短(duan),銅(tong)液是通過聯體爐內潛流式完(wan)成,對(dui)(dui)耐火材料的(de)沖擊(ji)不大,結晶是通過石墨模內進(jin)行,所以過程(cheng)中(zhong)可能產(chan)(chan)生(sheng)的(de)污染源較(jiao)少,雜(za)質(zhi)進(jin)入(ru)的(de)機會較(jiao)少。
O、S、P是與銅(tong)會生產(chan)化(hua)(hua)合物的元(yuan)素(su)。在熔(rong)(rong)態銅(tong)中,氧(yang)可以(yi)溶(rong)(rong)解一部分(fen),但當銅(tong)冷凝時,氧(yang)幾(ji)乎不(bu)溶(rong)(rong)解于(yu)銅(tong)中。熔(rong)(rong)態時所(suo)溶(rong)(rong)解的氧(yang),以(yi)銅(tong)=氧(yang)化(hua)(hua)亞銅(tong)共(gong)晶(jing)體析出(chu),分(fen)布(bu)在晶(jing)粒晶(jing)界處。銅(tong)-氧(yang)化(hua)(hua)亞銅(tong)共(gong)晶(jing)體的出(chu)現,顯著降低了銅(tong)的塑(su)性。
硫可以溶解在熔體的(de)銅(tong)(tong)中,但(dan)在室溫(wen)下,其溶解度幾乎(hu)降低到零,它以硫化亞銅(tong)(tong)的(de)形式出現在晶粒晶界處,會顯(xian)著降低銅(tong)(tong)的(de)塑性(xing)。
3、氧在低(di)氧銅桿和無氧銅桿中(zhong)分布(bu)形式及(ji)其影(ying)響
氧(yang)(yang)含(han)量對低氧(yang)(yang)銅桿(gan)的(de)(de)拉線(xian)(xian)性能有(you)著明顯的(de)(de)影響。當(dang)氧(yang)(yang)含(han)量增加到最(zui)佳值時,銅桿(gan)的(de)(de)斷線(xian)(xian)率最(zui)低。這是因為氧(yang)(yang)在與(yu)大(da)部分雜質反(fan)應的(de)(de)過程中(zhong)都起(qi)到了(le)清除器(qi)的(de)(de)作用(yong)。適度的(de)(de)氧(yang)(yang)還有(you)利于(yu)去除銅液中(zhong)的(de)(de)氫,生成(cheng)水蒸氣(qi)溢出,減少氣(qi)孔的(de)(de)形(xing)成(cheng)。最(zui)佳的(de)(de)氧(yang)(yang)含(han)量為拉線(xian)(xian)工藝提供(gong)了(le)最(zui)好的(de)(de)條件。
低氧(yang)(yang)(yang)銅(tong)桿(gan)氧(yang)(yang)(yang)化(hua)(hua)物(wu)的(de)(de)(de)分(fen)布(bu):在連續澆鑄中(zhong)(zhong)凝(ning)固(gu)的(de)(de)(de)最(zui)初(chu)階段,散熱速(su)率(lv)和(he)均勻(yun)(yun)冷卻是(shi)決定銅(tong)桿(gan)氧(yang)(yang)(yang)化(hua)(hua)物(wu)分(fen)布(bu)的(de)(de)(de)主要因素。不(bu)均勻(yun)(yun)冷卻會(hui)引起(qi)銅(tong)桿(gan)內部結(jie)構本質上的(de)(de)(de)差異,但后續的(de)(de)(de)熱加工,柱狀晶通常(chang)會(hui)遭到破(po)壞,使(shi)氧(yang)(yang)(yang)化(hua)(hua)亞(ya)銅(tong)顆(ke)粒細微化(hua)(hua)和(he)均勻(yun)(yun)分(fen)布(bu)。氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒聚(ju)集而產生的(de)(de)(de)典型(xing)情(qing)況是(shi)中(zhong)(zhong)心(xin)爆裂(lie)。除氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒分(fen)布(bu)的(de)(de)(de)影(ying)響外,具(ju)有較小氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒的(de)(de)(de)銅(tong)桿(gan)顯示出較好的(de)(de)(de)拉線特(te)性(xing),較大的(de)(de)(de)Cu2O顆(ke)粒容易造(zao)成應(ying)力集中(zhong)(zhong)點而斷(duan)裂(lie)。
無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)含氧(yang)(yang)(yang)量超標(biao),銅(tong)(tong)(tong)(tong)桿變脆(cui),延伸率(lv)(lv)下降,拉伸式樣(yang)端口(kou)顯暗紅色,結晶組織疏松。當(dang)氧(yang)(yang)(yang)含量超出(chu)8ppm時,工藝性能變差(cha),表(biao)現為鑄造(zao)(zao)及拉伸過程中斷(duan)桿及斷(duan)線率(lv)(lv)極具增高。這是由于氧(yang)(yang)(yang)能與銅(tong)(tong)(tong)(tong)生成氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)(tong)(tong)脆(cui)性相,形成銅(tong)(tong)(tong)(tong)-氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)(tong)(tong)共晶體(ti),以網狀組織分(fen)布在境界上(shang)(shang)。這種脆(cui)性相硬度高,在冷變形時將會與銅(tong)(tong)(tong)(tong)機體(ti)脫(tuo)離,導(dao)致銅(tong)(tong)(tong)(tong)桿的(de)機械(xie)性能下降,在后續加工中容易(yi)造(zao)(zao)成斷(duan)裂現象。氧(yang)(yang)(yang)含量高還能導(dao)致無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿導(dao)電率(lv)(lv)下降。因此(ci),必須嚴(yan)格控制上(shang)(shang)引連鑄工藝及產品質量。
4、氫的影響
在上引連鑄中,氧(yang)含量控制較(jiao)低(di),氧(yang)化物的副作(zuo)用唄**降低(di),但氫(qing)的影響成為較(jiao)顯(xian)著(zhu)的問題(ti)。吸氣后熔體中存在平衡反應:H2O(g)=[O]+2[H];
氣(qi)體(ti)及(ji)疏松是(shi)在(zai)結(jie)晶(jing)的(de)(de)過(guo)程中(zhong),氫(qing)從過(guo)飽(bao)和的(de)(de)溶(rong)液(ye)中(zhong)析(xi)(xi)出并聚集而(er)形(xing)成(cheng)的(de)(de)。在(zai)結(jie)晶(jing)前析(xi)(xi)出的(de)(de)氫(qing)又可還原氧化亞銅而(er)生成(cheng)水(shui)氣(qi)泡。由(you)于上(shang)(shang)(shang)引鑄(zhu)造的(de)(de)特點是(shi)銅液(ye)自上(shang)(shang)(shang)而(er)下的(de)(de)結(jie)晶(jing),形(xing)成(cheng)的(de)(de)液(ye)**形(xing)狀近似錐型。銅液(ye)結(jie)晶(jing)前析(xi)(xi)出的(de)(de)氣(qi)體(ti)在(zai)上(shang)(shang)(shang)浮過(guo)程中(zhong)被堵在(zai)凝固(gu)組織內,結(jie)晶(jing)時在(zai)鑄(zhu)桿(gan)內形(xing)成(cheng)氣(qi)孔(kong)。上(shang)(shang)(shang)引的(de)(de)含(han)氣(qi)量少(shao)時,析(xi)(xi)出的(de)(de)氫(qing)存在(zai)于晶(jing)界處,形(xing)成(cheng)疏松;含(han)氣(qi)量多(duo)時,則聚集成(cheng)氣(qi)孔(kong),因(yin)此,氣(qi)孔(kong)和疏松是(shi)氫(qing)氣(qi)和水(shui)蒸(zheng)氣(qi)兩(liang)者形(xing)成(cheng)的(de)(de)。
氫來(lai)源于上引生產過程(cheng)中(zhong)的(de)各個工藝環(huan)節,如原料電解銅(tong)的(de)“銅(tong)綠”、輔料木(mu)炭(tan)**、氣候環(huan)境**、石墨結晶器未干燥(zao)等。因此,熔化(hua)爐中(zhong)的(de)銅(tong)液表面應(ying)覆(fu)蓋經烘烤的(de)木(mu)炭(tan),電解銅(tong)應(ying)盡(jin)量去除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對提(ti)高無氧銅(tong)桿質量非常重要。
在連鑄連軋(ya)工藝中,往往采用適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由(you)于銅液在(zai)鑄造過(guo)程中是自(zi)下而(er)(er)上(shang)(shang)結晶,銅液中的(de)氧和氫所(suo)產(chan)生的(de)水(shui)蒸氣很容易(yi)上(shang)(shang)浮(fu)跑(pao)出,銅液中的(de)氫大部(bu)分(fen)能被有(you)效去除,因而(er)(er)對銅桿的(de)影響較小。
二、表面質量
在生產(chan)電磁線等產(chan)品的(de)過程中,對(dui)銅(tong)桿的(de)表面(mian)質量(liang)(liang)也需(xu)(xu)提出要求(qiu)。需(xu)(xu)要拉制(zhi)后的(de)銅(tong)絲表面(mian)無毛刺、銅(tong)粉少(shao)、無油(you)污。并通過扭轉試驗測(ce)量(liang)(liang)表面(mian)銅(tong)粉的(de)質量(liang)(liang)和扭轉后觀察(cha)銅(tong)桿的(de)復原情(qing)況來(lai)判定其好壞。
在連(lian)鑄連(lian)軋(ya)過(guo)程中(zhong),從鑄造到軋(ya)制(zhi)(zhi)前,溫度(du)高(gao),完全暴露(lu)于(yu)空氣中(zhong),使鑄坯表面(mian)形成較厚的(de)(de)氧化(hua)(hua)層,在軋(ya)制(zhi)(zhi)過(guo)程中(zhong),隨著軋(ya)輥的(de)(de)轉(zhuan)動,氧化(hua)(hua)物(wu)顆粒軋(ya)入(ru)銅線表面(mian)。由于(yu)氧化(hua)(hua)亞(ya)銅是高(gao)熔點(dian)脆性化(hua)(hua)合物(wu),對于(yu)軋(ya)入(ru)較深的(de)(de)氧化(hua)(hua)亞(ya)銅,當(dang)成條狀的(de)(de)聚集物(wu)遇模具(ju)拉(la)伸時,就(jiu)會是銅桿外(wai)表面(mian)產(chan)生毛(mao)刺,給后續(xu)的(de)(de)涂漆(qi)造成麻煩。
而(er)上引連鑄(zhu)工(gong)藝(yi)制造的無(wu)氧(yang)銅桿(gan),由于鑄(zhu)造和冷(leng)卻完全與氧(yang)隔絕,后續亦無(wu)熱軋(ya)過程(cheng),銅桿(gan)表面無(wu)軋(ya)入(ru)表面的氧(yang)化物(wu),質量較(jiao)好,拉制后銅粉少,上述(shu)問題(ti)較(jiao)少存在。
無氧(yang)銅桿(gan)也分進(jin)口設(she)備(bei)做的(de)(de)和國(guo)產(chan)設(she)備(bei)做的(de)(de),但目前進(jin)口產(chan)品(pin)已無明顯優勢,銅桿(gan)產(chan)品(pin)出來后區別不(bu)是(shi)(shi)很大,只(zhi)要銅板選的(de)(de)好,生產(chan)控(kong)制比較穩定,國(guo)產(chan)設(she)備(bei)也能產(chan)出可(ke)拉伸0.05的(de)(de)銅桿(gan).進(jin)口設(she)備(bei)一般(ban)是(shi)(shi)芬蘭奧(ao)托昆普的(de)(de)設(she)備(bei),國(guo)產(chan)設(she)備(bei)最(zui)好的(de)(de)應該(gai)是(shi)(shi)上(shang)海的(de)(de)海軍廠的(de)(de)了,生產(chan)時間最(zui)長(chang),軍工企業,質(zhi)量可(ke)靠。
低氧銅桿(gan)進口(kou)設備(bei)(bei)國(guo)(guo)際主要有(you)兩種,一種是(shi)美國(guo)(guo)南(nan)線設備(bei)(bei),英文是(shi)SOUTHWIRE,國(guo)(guo)內廠(chang)家(jia)是(shi)南(nan)京華(hua)新(xin),江(jiang)西銅業(ye),另一種是(shi)德國(guo)(guo)CONTIROD設備(bei)(bei),國(guo)(guo)內廠(chang)家(jia)是(shi)常州金源,天津大無縫。
無(wu)氧(yang)(yang)及低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)量(liang)上容易區別(bie),無(wu)氧(yang)(yang)銅(tong)是(shi)(shi)(shi)含(han)氧(yang)(yang)量(liang)在(zai)10-20個PPM以下(xia)(xia),但目前有的(de)(de)(de)廠家(jia)只能做到50個PPM以下(xia)(xia).低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子(zi)一般(ban)含(han)氧(yang)(yang)量(liang)控制在(zai)250個PPM左右,無(wu)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)一般(ban)采取的(de)(de)(de)是(shi)(shi)(shi)上引法,低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)是(shi)(shi)(shi)連鑄連軋,兩種產品相對(dui)而(er)言低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對(dui)漆包線(xian)性 能更適(shi)應(ying)些,如柔軟性,回彈角,繞線(xian)性能.但低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對(dui)拉(la)絲條(tiao)件相對(dui)要苛刻些,同(tong)樣(yang)(yang)拉(la)伸(shen)0.2的(de)(de)(de)細絲,如果(guo)伸(shen)線(xian)條(tiao)件不好(hao),普(pu)通的(de)(de)(de)無(wu)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)可拉(la)而(er)好(hao)的(de)(de)(de)低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)就(jiu)斷 線(xian),但如果(guo)放(fang)在(zai)好(hao)的(de)(de)(de)伸(shen)線(xian)條(tiao)件,同(tong)樣(yang)(yang)的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子(zi),低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)說(shuo)不定就(jiu)能拉(la)到雙零五,而(er)普(pu)通無(wu)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)最(zui)(zui)多只能拉(la)伸(shen)到0.1而(er)已,當然做的(de)(de)(de)最(zui)(zui)細的(de)(de)(de)如雙零二卻非(fei)得依靠進口的(de)(de)(de) 無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)了.目前有企業嘗試(shi)用剝(bo)皮的(de)(de)(de)方式來處理低(di)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)來伸(shen)0.03線(xian).但有關(guan)這(zhe)方面的(de)(de)(de)內容我還不是(shi)(shi)(shi)很清楚(chu)。
音響線一般反(fan)而喜歡用無(wu)氧(yang)桿,這和無(wu)氧(yang)桿是單晶(jing)銅(tong),低氧(yang)桿是多晶(jing)銅(tong)有(you)關。
氧(yang)銅(tong)桿和無(wu)氧(yang)銅(tong)桿由于制造方法的不同,致使存在差別(bie),具(ju)有各自的特(te)點。
一(yi)、關于氧(yang)的(de)吸入和(he)脫去以及(ji)它的(de)存在狀態
生產銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)(tong)的(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量一般(ban)在(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)常溫(wen)下(xia)氧(yang)(yang)(yang)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)固溶度約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量一般(ban)在(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)進入(ru)是(shi)(shi)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)液態下(xia)吸入(ru)的(de)(de)(de),而(er)(er)(er)上引法(fa)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則(ze)相(xiang)(xiang)反,氧(yang)(yang)(yang)在(zai)(zai)(zai)(zai)液態銅(tong)(tong)(tong)(tong)下(xia)保持(chi)相(xiang)(xiang)當(dang)時間后,被還原而(er)(er)(er)脫去(qu),通(tong)常這種桿(gan)的(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量都(dou)在(zai)(zai)(zai)(zai)10—50ppm以下(xia),最低(di)(di)(di)可(ke)達1-2ppm,從組織上看,低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang),以氧(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態,存(cun)在(zai)(zai)(zai)(zai)于晶(jing)粒(li)邊界附近,這對(dui)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)而(er)(er)(er)言可(ke)以說是(shi)(shi)常見的(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則(ze)很少見。氧(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以夾雜形式在(zai)(zai)(zai)(zai)晶(jing)界出現對(dui)材料的(de)(de)(de)韌性(xing)產生負面影(ying)響。而(er)(er)(er)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)很低(di)(di)(di),所以這種銅(tong)(tong)(tong)(tong)的(de)(de)(de)組織是(shi)(shi)均勻的(de)(de)(de)單相(xiang)(xiang)組織對(dui)韌性(xing)有利(li)。在(zai)(zai)(zai)(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)多(duo)孔性(xing)是(shi)(shi)不(bu)常見的(de)(de)(de),而(er)(er)(er)在(zai)(zai)(zai)(zai)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中(zhong)則(ze)是(shi)(shi)常見的(de)(de)(de)一種缺(que)陷。
二、熱軋組(zu)織(zhi)和(he)鑄造組(zu)織(zhi)的區別
低(di)(di)(di)(di)氧(yang)銅(tong)(tong)桿由于經(jing)(jing)(jing)過熱軋,所以(yi)其組(zu)(zu)(zu)織(zhi)屬(shu)熱加(jia)工(gong)組(zu)(zu)(zu)織(zhi),原來的(de)(de)(de)鑄(zhu)造組(zu)(zu)(zu)織(zhi)已(yi)經(jing)(jing)(jing)破碎,在8mm的(de)(de)(de)桿時(shi)已(yi)有再(zai)結晶(jing)(jing)的(de)(de)(de)形式出現,而(er)無(wu)氧(yang)銅(tong)(tong)桿屬(shu)鑄(zhu)造組(zu)(zu)(zu)織(zhi),晶(jing)(jing)粒(li)(li)粗大,這是為什么(me),無(wu)氧(yang)銅(tong)(tong)的(de)(de)(de)再(zai)結晶(jing)(jing)溫度(du)較高,需(xu)要(yao)(yao)較高退(tui)(tui)火(huo)(huo)溫度(du)的(de)(de)(de)固有原因(yin)(yin)。這是因(yin)(yin)為,再(zai)結晶(jing)(jing)發生在晶(jing)(jing)粒(li)(li)邊界附近,無(wu)氧(yang)銅(tong)(tong)桿組(zu)(zu)(zu)織(zhi)晶(jing)(jing)粒(li)(li)粗大,晶(jing)(jing)粒(li)(li)尺寸甚(shen)至能達幾(ji)個毫(hao)米,因(yin)(yin)而(er)晶(jing)(jing)粒(li)(li)邊界少,即使(shi)通過拉制(zhi)(zhi)變(bian)形,但晶(jing)(jing)粒(li)(li)邊界相對低(di)(di)(di)(di)氧(yang)銅(tong)(tong)桿還是較少,所以(yi)需(xu)要(yao)(yao)較高的(de)(de)(de)退(tui)(tui)火(huo)(huo)功率。對無(wu)氧(yang)銅(tong)(tong)成(cheng)功的(de)(de)(de)退(tui)(tui)火(huo)(huo)要(yao)(yao)求是:由桿經(jing)(jing)(jing)拉制(zhi)(zhi),但尚未(wei)鑄(zhu)造組(zu)(zu)(zu)織(zhi)的(de)(de)(de)線(xian)時(shi)的(de)(de)(de)第一次退(tui)(tui)火(huo)(huo),其退(tui)(tui)火(huo)(huo)功率應(ying)比同樣情況的(de)(de)(de)低(di)(di)(di)(di)氧(yang)銅(tong)(tong)高10——15%。經(jing)(jing)(jing)繼續(xu)拉制(zhi)(zhi),在以(yi)后(hou)階段的(de)(de)(de)退(tui)(tui)火(huo)(huo)功率應(ying)留有足(zu)夠(gou)的(de)(de)(de)余(yu)量和對低(di)(di)(di)(di)氧(yang)銅(tong)(tong)和無(wu)氧(yang)銅(tong)(tong)切實區別執行不(bu)同的(de)(de)(de)退(tui)(tui)火(huo)(huo)工(gong)藝,以(yi)保證在制(zhi)(zhi)品(pin)(pin)和成(cheng)品(pin)(pin)導線(xian)的(de)(de)(de)柔(rou)軟性。
三、夾(jia)雜,氧含(han)量波動,表面氧化物和可能存在的熱軋缺陷的差別
無(wu)氧(yang)銅(tong)桿(gan)(gan)的(de)(de)(de)可拉(la)性(xing)在(zai)所有(you)線(xian)徑里與(yu)低氧(yang)銅(tong)桿(gan)(gan)相(xiang)比(bi)都是(shi)優越的(de)(de)(de),除(chu)上(shang)述組織原因外,無(wu)氧(yang)銅(tong)桿(gan)(gan)夾雜少,含氧(yang)量穩定,無(wu)熱軋可能(neng)產生(sheng)的(de)(de)(de)缺陷,桿(gan)(gan)表(biao)氧(yang)化(hua)物(wu)厚度可達≤15A。在(zai)連鑄連軋生(sheng)產過程中(zhong)(zhong)如(ru)果工藝不(bu)穩定,對(dui)氧(yang)監控不(bu)嚴,含氧(yang)量不(bu)穩定將直接影(ying)響桿(gan)(gan)的(de)(de)(de)性(xing)能(neng)。如(ru)果桿(gan)(gan)的(de)(de)(de)表(biao)面氧(yang)化(hua)物(wu)能(neng)在(zai)后工序的(de)(de)(de)連續清(qing)洗中(zhong)(zhong)得以(yi)彌補外,但比(bi)較(jiao)麻煩(fan)的(de)(de)(de)是(shi)有(you)相(xiang)當多(duo)的(de)(de)(de)氧(yang)化(hua)物(wu)存在(zai)于“皮下”,對(dui)拉(la)線(xian)斷(duan)線(xian)影(ying)響更直接,故而在(zai)拉(la)制微細(xi)(xi)線(xian),超微細(xi)(xi)線(xian)時,為(wei)了減少斷(duan)線(xian),有(you)時要(yao)對(dui)銅(tong)桿(gan)(gan)采取(qu)不(bu)得已(yi)的(de)(de)(de)辦法——剝(bo)皮,甚至二次剝(bo)皮的(de)(de)(de)原因所在(zai),目的(de)(de)(de)要(yao)除(chu)去皮下氧(yang)化(hua)物(wu)。
四、低氧(yang)銅桿和(he)無氧(yang)銅桿的韌性有(you)差別
兩者都可以拉(la)到0.015mm,但在低溫超導(dao)線中(zhong)的低溫級(ji)無氧(yang)銅,其細(xi)絲間的間距只有0.001mm.
五、從(cong)制(zhi)(zhi)桿(gan)的原材料到制(zhi)(zhi)線的經濟性(xing)有差別。
制造無氧銅(tong)桿(gan)要求質量較(jiao)高的原材料。一般(ban),拉制直徑>1mm的銅(tong)線時,低氧銅(tong)桿(gan)的優點比(bi)較(jiao)明顯(xian),而無氧銅(tong)桿(gan)顯(xian)得更(geng)為優越的是拉制直徑<0.5mm的銅(tong)線。
六、低(di)氧銅桿(gan)的制線工藝(yi)與無氧銅桿(gan)的有所不同(tong)。
低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)的制(zhi)(zhi)(zhi)線工藝(yi)不(bu)(bu)能照搬到無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)的制(zhi)(zhi)(zhi)線工藝(yi)上(shang)來,至少兩(liang)者的退火工藝(yi)是(shi)不(bu)(bu)同(tong)的。因為線的柔軟性深受(shou)材料成份和制(zhi)(zhi)(zhi)桿(gan),制(zhi)(zhi)(zhi)線和退火工藝(yi)的影響,不(bu)(bu)能簡單地(di)說低(di)氧(yang)(yang)(yang)銅(tong)或無(wu)氧(yang)(yang)(yang)銅(tong)誰軟誰硬。