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來源(yuan):行業動(dong)態 閱讀:109239 發布時間:2019-07-05
導讀:由于(yu)生(sheng)(sheng)產(chan)銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)兩者(zhe)的(de)(de)(de)(de)工藝不(bu)同(tong),所生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)含氧(yang)(yang)(yang)量及外(wai)觀就不(bu)同(tong)。上(shang)引生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan),工藝得當氧(yang)(yang)(yang)含量在10ppm以下,叫(jiao)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan);連(lian)鑄連(lian)鑄生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan) 是在保護條件下的(de)(de)(de)(de)熱軋,氧(yang)(yang)(yang)含量在200-500ppm范圍內,但(dan)有(you)時也高達(da)700ppm以上(shang),一般情況(kuang)下,此種方(fang)法生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)外(wai)表光(guang)(guang)亮,低氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan),有(you)時也叫(jiao)光(guang)(guang)桿(gan)(gan)。
銅(tong)(tong)(tong)桿(gan)是電纜行(xing)業的主要(yao)原料,生(sheng)(sheng)產(chan)的方(fang)式主要(yao)有兩種(zhong)——連(lian)鑄(zhu)(zhu)連(lian)軋法(fa)和上引(yin)(yin)連(lian)鑄(zhu)(zhu)法(fa)。連(lian)鑄(zhu)(zhu)連(lian)軋低氧(yang)銅(tong)(tong)(tong)桿(gan)的生(sheng)(sheng)產(chan)方(fang)法(fa)較多,其(qi)特點是金(jin)屬在豎爐中(zhong)融(rong)化后,銅(tong)(tong)(tong)液通過(guo)保(bao)溫爐、溜槽、中(zhong)間(jian)包,從澆管進(jin)入封閉(bi)的模(mo)腔內(nei)(nei),采(cai)用(yong)較大(da)的冷卻強度進(jin)行(xing)冷卻,形(xing)成鑄(zhu)(zhu)坯(pi),然后進(jin)行(xing)多道次軋制,生(sheng)(sheng)產(chan)的低氧(yang)銅(tong)(tong)(tong)桿(gan)為熱加(jia)工(gong)組(zu)織(zhi),原來的鑄(zhu)(zhu)造(zao)組(zu)織(zhi)已經(jing)破碎,含(han)氧(yang)量(liang)一(yi)般(ban)為200~400ppm之間(jian)。無氧(yang)銅(tong)(tong)(tong)桿(gan)國內(nei)(nei)基本全部采(cai)用(yong)上引(yin)(yin)連(lian)鑄(zhu)(zhu)法(fa)生(sheng)(sheng)產(chan),金(jin)屬在感應電爐中(zhong)融(rong)化后通過(guo)石墨模(mo)進(jin)行(xing)上引(yin)(yin)連(lian)續鑄(zhu)(zhu)造(zao),之后進(jin)行(xing)冷軋或(huo)冷加(jia)工(gong),生(sheng)(sheng)產(chan)的無氧(yang)銅(tong)(tong)(tong)桿(gan)為鑄(zhu)(zhu)造(zao)組(zu)織(zhi),含(han)氧(yang)量(liang)一(yi)般(ban)在20ppm以(yi)下。由(you)于(yu)制造(zao)工(gong)藝(yi)的不(bu)同,所以(yi)在組(zu)織(zhi)結構、氧(yang)含(han)量(liang)分布、雜(za)質的形(xing)式及分布等諸多方(fang)面有較大(da)差(cha)別(bie)。
一、拉制性能
銅桿(gan)的拉制性能跟很多因素有關(guan),如雜質(zhi)的含量(liang)、氧(yang)含量(liang)及分(fen)布(bu)、工藝控制等(deng)。下面(mian)分(fen)別從以(yi)上幾(ji)個(ge)方(fang)面(mian)對銅桿(gan)的拉制性能進行(xing)分(fen)析。
1、熔化方(fang)式對S等雜(za)質的影(ying)響
連(lian)鑄(zhu)連(lian)軋生產(chan)銅(tong)(tong)(tong)桿主要(yao)是(shi)通過氣體(ti)的(de)燃燒使(shi)銅(tong)(tong)(tong)桿熔(rong)化(hua),在燃燒的(de)過程(cheng)中,通過氧化(hua)和揮發作用,可一(yi)定程(cheng)度(du)減少部(bu)分(fen)雜質進入銅(tong)(tong)(tong)液,因此連(lian)鑄(zhu)連(lian)軋法對(dui)原(yuan)料要(yao)求相(xiang)對(dui)低一(yi)些。上引連(lian)鑄(zhu)生產(chan)無氧銅(tong)(tong)(tong)桿,由于是(shi)用感應電(dian)爐熔(rong)化(hua),電(dian)解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠(lv)”“銅(tong)(tong)(tong)豆”基本都熔(rong)入到銅(tong)(tong)(tong)液中。其中熔(rong)入的(de)S對(dui)無氧銅(tong)(tong)(tong)桿塑(su)性影響極大,會(hui)增(zeng)加拉絲斷線率。
2、鑄(zhu)造過程中雜質的進入(ru)
在生產(chan)過(guo)(guo)程中,連(lian)(lian)鑄(zhu)連(lian)(lian)軋工藝需通(tong)過(guo)(guo)保溫爐(lu)、溜槽、中間包轉(zhuan)運(yun)銅液(ye),相對(dui)容易造成耐(nai)火材(cai)料的(de)(de)(de)剝(bo)落,在軋制過(guo)(guo)程中需要通(tong)過(guo)(guo)軋輥,造成鐵質(zhi)的(de)(de)(de)脫落,會給(gei)(gei)銅桿(gan)造成外部夾(jia)雜。而熱軋中皮上(shang)和皮下氧化(hua)物的(de)(de)(de)軋入(ru),會給(gei)(gei)低(di)氧桿(gan)的(de)(de)(de)拉絲造成不(bu)利的(de)(de)(de)影響。上(shang)引連(lian)(lian)鑄(zhu)法生產(chan)工藝流程較短,銅液(ye)是(shi)通(tong)過(guo)(guo)聯體爐(lu)內潛流式完成,對(dui)耐(nai)火材(cai)料的(de)(de)(de)沖擊不(bu)大,結晶是(shi)通(tong)過(guo)(guo)石墨模內進(jin)行,所(suo)以(yi)過(guo)(guo)程中可能產(chan)生的(de)(de)(de)污染源較少(shao),雜質(zhi)進(jin)入(ru)的(de)(de)(de)機會較少(shao)。
O、S、P是(shi)與銅(tong)(tong)會生產化合物的(de)元素。在熔(rong)態銅(tong)(tong)中,氧可以溶解(jie)一部分(fen),但當銅(tong)(tong)冷(leng)凝時(shi),氧幾乎不溶解(jie)于銅(tong)(tong)中。熔(rong)態時(shi)所(suo)溶解(jie)的(de)氧,以銅(tong)(tong)=氧化亞銅(tong)(tong)共晶(jing)體(ti)析出,分(fen)布在晶(jing)粒晶(jing)界處。銅(tong)(tong)-氧化亞銅(tong)(tong)共晶(jing)體(ti)的(de)出現,顯著降低了銅(tong)(tong)的(de)塑性。
硫可以(yi)溶(rong)解在(zai)熔體的(de)銅(tong)中,但在(zai)室溫下(xia),其溶(rong)解度幾(ji)乎(hu)降(jiang)低(di)到(dao)零,它以(yi)硫化亞銅(tong)的(de)形(xing)式出現(xian)在(zai)晶(jing)(jing)粒晶(jing)(jing)界處,會顯著降(jiang)低(di)銅(tong)的(de)塑性(xing)。
3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中分布形式及其影響
氧(yang)含量對低(di)氧(yang)銅桿(gan)的(de)(de)拉線(xian)性能有著明顯的(de)(de)影響。當氧(yang)含量增加到(dao)最(zui)佳值時(shi),銅桿(gan)的(de)(de)斷線(xian)率最(zui)低(di)。這(zhe)是因為氧(yang)在與(yu)大部分雜(za)質(zhi)反(fan)應的(de)(de)過(guo)程中都起到(dao)了清除(chu)器(qi)的(de)(de)作用。適(shi)度的(de)(de)氧(yang)還有利于去除(chu)銅液中的(de)(de)氫(qing),生成水蒸氣(qi)溢(yi)出,減(jian)少氣(qi)孔的(de)(de)形成。最(zui)佳的(de)(de)氧(yang)含量為拉線(xian)工藝提供了最(zui)好(hao)的(de)(de)條件。
低氧銅(tong)(tong)(tong)桿(gan)氧化(hua)(hua)物(wu)的(de)分(fen)布(bu):在連續澆鑄(zhu)中凝固的(de)最初階段,散熱速率和均(jun)勻(yun)冷卻(que)是(shi)決定(ding)銅(tong)(tong)(tong)桿(gan)氧化(hua)(hua)物(wu)分(fen)布(bu)的(de)主要因素。不均(jun)勻(yun)冷卻(que)會引起(qi)銅(tong)(tong)(tong)桿(gan)內部(bu)結構本質(zhi)上(shang)的(de)差異,但后續的(de)熱加工(gong),柱狀晶通常會遭到破壞(huai),使氧化(hua)(hua)亞銅(tong)(tong)(tong)顆(ke)粒(li)細微化(hua)(hua)和均(jun)勻(yun)分(fen)布(bu)。氧化(hua)(hua)物(wu)顆(ke)粒(li)聚集而產生(sheng)的(de)典型情況是(shi)中心爆裂。除氧化(hua)(hua)物(wu)顆(ke)粒(li)分(fen)布(bu)的(de)影響(xiang)外,具有較(jiao)小(xiao)氧化(hua)(hua)物(wu)顆(ke)粒(li)的(de)銅(tong)(tong)(tong)桿(gan)顯(xian)示出較(jiao)好(hao)的(de)拉線(xian)特性,較(jiao)大的(de)Cu2O顆(ke)粒(li)容易造成(cheng)應力集中點而斷(duan)裂。
無氧(yang)銅(tong)(tong)(tong)(tong)(tong)含(han)氧(yang)量(liang)(liang)超標,銅(tong)(tong)(tong)(tong)(tong)桿(gan)變(bian)脆,延伸(shen)率下降(jiang),拉(la)伸(shen)式樣端口顯暗(an)紅色,結晶(jing)組(zu)(zu)織(zhi)疏松(song)。當氧(yang)含(han)量(liang)(liang)超出(chu)8ppm時,工藝性(xing)能變(bian)差,表現為鑄造及(ji)拉(la)伸(shen)過(guo)程(cheng)中斷(duan)桿(gan)及(ji)斷(duan)線率極具增高(gao)。這是由(you)于(yu)氧(yang)能與銅(tong)(tong)(tong)(tong)(tong)生成(cheng)氧(yang)化亞銅(tong)(tong)(tong)(tong)(tong)脆性(xing)相,形(xing)成(cheng)銅(tong)(tong)(tong)(tong)(tong)-氧(yang)化亞銅(tong)(tong)(tong)(tong)(tong)共晶(jing)體,以(yi)網狀組(zu)(zu)織(zhi)分布在(zai)境界上(shang)。這種(zhong)脆性(xing)相硬(ying)度(du)高(gao),在(zai)冷變(bian)形(xing)時將會與銅(tong)(tong)(tong)(tong)(tong)機(ji)體脫離,導致(zhi)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的機(ji)械(xie)性(xing)能下降(jiang),在(zai)后續加工中容易造成(cheng)斷(duan)裂現象。氧(yang)含(han)量(liang)(liang)高(gao)還能導致(zhi)無氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)導電率下降(jiang)。因(yin)此(ci),必須嚴格控制上(shang)引連鑄工藝及(ji)產(chan)品質量(liang)(liang)。
4、氫的影響
在(zai)上(shang)引連鑄中,氧(yang)含量(liang)控制(zhi)較低,氧(yang)化物的(de)(de)副作用(yong)唄**降低,但氫的(de)(de)影響成(cheng)為較顯(xian)著的(de)(de)問題。吸氣后熔體(ti)中存在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)體及疏(shu)松是在(zai)(zai)結(jie)晶的(de)(de)過(guo)(guo)程(cheng)中,氫(qing)(qing)從過(guo)(guo)飽和的(de)(de)溶液(ye)中析(xi)(xi)出(chu)并(bing)聚集而形成的(de)(de)。在(zai)(zai)結(jie)晶前析(xi)(xi)出(chu)的(de)(de)氫(qing)(qing)又可(ke)還(huan)原(yuan)氧化亞銅(tong)而生成水氣(qi)泡。由(you)于上引鑄造(zao)的(de)(de)特點(dian)是銅(tong)液(ye)自(zi)上而下的(de)(de)結(jie)晶,形成的(de)(de)液(ye)**形狀近似錐(zhui)型。銅(tong)液(ye)結(jie)晶前析(xi)(xi)出(chu)的(de)(de)氣(qi)體在(zai)(zai)上浮過(guo)(guo)程(cheng)中被堵在(zai)(zai)凝(ning)固組織內,結(jie)晶時(shi)在(zai)(zai)鑄桿(gan)內形成氣(qi)孔。上引的(de)(de)含(han)氣(qi)量(liang)少時(shi),析(xi)(xi)出(chu)的(de)(de)氫(qing)(qing)存在(zai)(zai)于晶界處(chu),形成疏(shu)松;含(han)氣(qi)量(liang)多時(shi),則聚集成氣(qi)孔,因此,氣(qi)孔和疏(shu)松是氫(qing)(qing)氣(qi)和水蒸氣(qi)兩者形成的(de)(de)。
氫(qing)來源于(yu)上引生產過程中(zhong)的(de)各個工藝環(huan)(huan)節,如原料電解銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔料木(mu)炭(tan)**、氣候環(huan)(huan)境**、石(shi)墨結晶器未干燥(zao)等。因此,熔(rong)化爐(lu)中(zhong)的(de)銅(tong)(tong)液(ye)表面應覆(fu)蓋經烘烤的(de)木(mu)炭(tan),電解銅(tong)(tong)應盡(jin)量去除“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳朵”,對提高無(wu)氧(yang)銅(tong)(tong)桿(gan)質量非常重要(yao)。
在連鑄連軋工藝中,往往采用適(shi)度(du)控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液(ye)(ye)在鑄造過(guo)程中是自下而(er)上結晶,銅(tong)液(ye)(ye)中的(de)(de)氧(yang)和氫(qing)所產生的(de)(de)水蒸氣(qi)很容(rong)易上浮跑出,銅(tong)液(ye)(ye)中的(de)(de)氫(qing)大部分能被有效去除,因而(er)對銅(tong)桿的(de)(de)影響較小。
二、表面質量
在生產(chan)電磁線等產(chan)品的過(guo)程中,對(dui)銅(tong)(tong)桿的表面質量(liang)(liang)也(ye)需提出要求。需要拉(la)制后(hou)的銅(tong)(tong)絲表面無毛(mao)刺、銅(tong)(tong)粉(fen)(fen)少、無油污。并通過(guo)扭(niu)轉試驗測量(liang)(liang)表面銅(tong)(tong)粉(fen)(fen)的質量(liang)(liang)和扭(niu)轉后(hou)觀察(cha)銅(tong)(tong)桿的復原(yuan)情(qing)況來判(pan)定其好壞。
在連鑄(zhu)連軋(ya)過程中(zhong),從(cong)鑄(zhu)造到軋(ya)制前,溫(wen)度高(gao),完全暴露于(yu)空(kong)氣中(zhong),使鑄(zhu)坯(pi)表(biao)面(mian)(mian)形成較厚(hou)的(de)氧(yang)化(hua)層,在軋(ya)制過程中(zhong),隨著(zhu)軋(ya)輥的(de)轉動(dong),氧(yang)化(hua)物顆粒軋(ya)入銅線(xian)表(biao)面(mian)(mian)。由于(yu)氧(yang)化(hua)亞(ya)銅是(shi)高(gao)熔點脆性化(hua)合物,對于(yu)軋(ya)入較深的(de)氧(yang)化(hua)亞(ya)銅,當(dang)成條狀的(de)聚(ju)集物遇模(mo)具(ju)拉伸時(shi),就會是(shi)銅桿外(wai)表(biao)面(mian)(mian)產生毛刺(ci),給后續(xu)的(de)涂漆造成麻煩。
而上(shang)引(yin)連鑄(zhu)工藝制造的(de)無氧(yang)銅桿(gan),由于鑄(zhu)造和冷(leng)卻完全(quan)與氧(yang)隔(ge)絕,后續(xu)亦無熱軋過程(cheng),銅桿(gan)表面(mian)(mian)無軋入表面(mian)(mian)的(de)氧(yang)化物,質量較好,拉制后銅粉少(shao),上(shang)述(shu)問(wen)題(ti)較少(shao)存在。
無氧銅(tong)桿(gan)也分進口設(she)備(bei)做(zuo)的(de)(de)和國產設(she)備(bei)做(zuo)的(de)(de),但目前進口產品(pin)(pin)已無明顯優勢,銅(tong)桿(gan)產品(pin)(pin)出(chu)來(lai)后區別(bie)不是很大,只要銅(tong)板選的(de)(de)好(hao),生產控制比較穩定,國產設(she)備(bei)也能(neng)產出(chu)可拉伸0.05的(de)(de)銅(tong)桿(gan).進口設(she)備(bei)一(yi)般是芬(fen)蘭奧托昆普的(de)(de)設(she)備(bei),國產設(she)備(bei)最好(hao)的(de)(de)應該是上海的(de)(de)海軍廠的(de)(de)了,生產時間(jian)最長(chang),軍工企(qi)業(ye),質(zhi)量可靠。
低(di)氧銅(tong)桿進口設備(bei)(bei)國(guo)際主要有兩(liang)種(zhong),一種(zhong)是美國(guo)南(nan)(nan)線(xian)設備(bei)(bei),英文(wen)是SOUTHWIRE,國(guo)內(nei)廠(chang)(chang)家是南(nan)(nan)京(jing)華新,江西銅(tong)業,另一種(zhong)是德(de)國(guo)CONTIROD設備(bei)(bei),國(guo)內(nei)廠(chang)(chang)家是常州金源,天津大無縫。
無(wu)氧(yang)(yang)及低(di)氧(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)量上容(rong)易區別,無(wu)氧(yang)(yang)銅是(shi)含氧(yang)(yang)量在(zai)10-20個PPM以(yi)下,但目(mu)前(qian)有的(de)(de)(de)廠家(jia)只(zhi)能(neng)做(zuo)(zuo)到50個PPM以(yi)下.低(di)氧(yang)(yang)銅桿(gan)(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)(de)(de)桿(gan)(gan)(gan)子一般含氧(yang)(yang)量控制在(zai)250個PPM左右,無(wu)氧(yang)(yang)桿(gan)(gan)(gan)一般采取的(de)(de)(de)是(shi)上引法,低(di)氧(yang)(yang)桿(gan)(gan)(gan)是(shi)連鑄連軋(ya),兩種產品相(xiang)對而言(yan)低(di)氧(yang)(yang)桿(gan)(gan)(gan)對漆包(bao)線(xian)(xian)性 能(neng)更適應些(xie),如(ru)柔(rou)軟(ruan)性,回彈角,繞線(xian)(xian)性能(neng).但低(di)氧(yang)(yang)桿(gan)(gan)(gan)對拉絲條件(jian)(jian)相(xiang)對要苛刻些(xie),同樣拉伸(shen)0.2的(de)(de)(de)細(xi)絲,如(ru)果伸(shen)線(xian)(xian)條件(jian)(jian)不好(hao),普(pu)通(tong)(tong)的(de)(de)(de)無(wu)氧(yang)(yang)桿(gan)(gan)(gan)可拉而好(hao)的(de)(de)(de)低(di)氧(yang)(yang)桿(gan)(gan)(gan)就(jiu)斷 線(xian)(xian),但如(ru)果放在(zai)好(hao)的(de)(de)(de)伸(shen)線(xian)(xian)條件(jian)(jian),同樣的(de)(de)(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)桿(gan)(gan)(gan)說(shuo)不定(ding)就(jiu)能(neng)拉到雙零五,而普(pu)通(tong)(tong)無(wu)氧(yang)(yang)桿(gan)(gan)(gan)最多(duo)只(zhi)能(neng)拉伸(shen)到0.1而已,當然做(zuo)(zuo)的(de)(de)(de)最細(xi)的(de)(de)(de)如(ru)雙零二(er)卻非得依(yi)靠進口的(de)(de)(de) 無(wu)氧(yang)(yang)銅桿(gan)(gan)(gan)了.目(mu)前(qian)有企業嘗試(shi)用(yong)剝皮的(de)(de)(de)方式來處(chu)理(li)低(di)氧(yang)(yang)桿(gan)(gan)(gan)來伸(shen)0.03線(xian)(xian).但有關這方面的(de)(de)(de)內容(rong)我還(huan)不是(shi)很清楚。
音(yin)響線一般反而喜(xi)歡用無(wu)氧桿,這(zhe)和(he)無(wu)氧桿是(shi)單(dan)晶銅,低氧桿是(shi)多晶銅有關。
氧銅(tong)桿(gan)和無氧銅(tong)桿(gan)由于制(zhi)造方法的不同(tong),致使存在差別(bie),具有各自(zi)的特點。
一(yi)、關于氧(yang)的吸入和脫(tuo)去以及它(ta)的存在狀態
生產銅(tong)桿(gan)的(de)(de)(de)陰極銅(tong)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)溫下(xia)(xia)氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)中(zhong)的(de)(de)(de)固溶度約2ppm。低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)的(de)(de)(de)進入是在(zai)(zai)(zai)銅(tong)的(de)(de)(de)液態下(xia)(xia)吸入的(de)(de)(de),而(er)(er)上(shang)引法無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)則相反,氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)液態銅(tong)下(xia)(xia)保持相當時間后,被還(huan)原(yuan)而(er)(er)脫去,通常(chang)這種(zhong)桿(gan)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)都在(zai)(zai)(zai)10—50ppm以下(xia)(xia),最(zui)低(di)(di)可達(da)1-2ppm,從組織上(shang)看,低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)化(hua)銅(tong)狀態,存在(zai)(zai)(zai)于晶粒邊界附近,這對(dui)低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)而(er)(er)言可以說是常(chang)見(jian)(jian)(jian)的(de)(de)(de)但對(dui)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)則很少見(jian)(jian)(jian)。氧(yang)(yang)(yang)(yang)化(hua)銅(tong)以夾(jia)雜形式在(zai)(zai)(zai)晶界出現對(dui)材料的(de)(de)(de)韌性產生負面影響。而(er)(er)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)(yang)很低(di)(di),所以這種(zhong)銅(tong)的(de)(de)(de)組織是均勻的(de)(de)(de)單(dan)相組織對(dui)韌性有(you)利(li)。在(zai)(zai)(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)中(zhong)的(de)(de)(de)多孔性是不常(chang)見(jian)(jian)(jian)的(de)(de)(de),而(er)(er)在(zai)(zai)(zai)低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)中(zhong)則是常(chang)見(jian)(jian)(jian)的(de)(de)(de)一(yi)(yi)種(zhong)缺(que)陷。
二、熱軋組織和鑄造(zao)組織的區(qu)別
低(di)氧(yang)(yang)銅(tong)桿由于經(jing)過(guo)熱軋,所以(yi)其(qi)組(zu)(zu)織屬熱加工(gong)組(zu)(zu)織,原來(lai)的(de)(de)(de)(de)(de)鑄(zhu)造組(zu)(zu)織已(yi)經(jing)破碎,在(zai)8mm的(de)(de)(de)(de)(de)桿時已(yi)有(you)再結(jie)(jie)晶(jing)的(de)(de)(de)(de)(de)形(xing)式出現,而無(wu)氧(yang)(yang)銅(tong)桿屬鑄(zhu)造組(zu)(zu)織,晶(jing)粒粗大,這是為什么,無(wu)氧(yang)(yang)銅(tong)的(de)(de)(de)(de)(de)再結(jie)(jie)晶(jing)溫(wen)度較高(gao),需要較高(gao)退火(huo)(huo)溫(wen)度的(de)(de)(de)(de)(de)固有(you)原因(yin)(yin)。這是因(yin)(yin)為,再結(jie)(jie)晶(jing)發(fa)生在(zai)晶(jing)粒邊界(jie)附近,無(wu)氧(yang)(yang)銅(tong)桿組(zu)(zu)織晶(jing)粒粗大,晶(jing)粒尺寸甚至能達幾個毫米,因(yin)(yin)而晶(jing)粒邊界(jie)少(shao),即使(shi)通過(guo)拉(la)制(zhi)變形(xing),但晶(jing)粒邊界(jie)相對低(di)氧(yang)(yang)銅(tong)桿還(huan)是較少(shao),所以(yi)需要較高(gao)的(de)(de)(de)(de)(de)退火(huo)(huo)功(gong)(gong)率。對無(wu)氧(yang)(yang)銅(tong)成(cheng)功(gong)(gong)的(de)(de)(de)(de)(de)退火(huo)(huo)要求是:由桿經(jing)拉(la)制(zhi),但尚未(wei)鑄(zhu)造組(zu)(zu)織的(de)(de)(de)(de)(de)線時的(de)(de)(de)(de)(de)第一次退火(huo)(huo),其(qi)退火(huo)(huo)功(gong)(gong)率應比同(tong)樣情(qing)況的(de)(de)(de)(de)(de)低(di)氧(yang)(yang)銅(tong)高(gao)10——15%。經(jing)繼(ji)續拉(la)制(zhi),在(zai)以(yi)后階段的(de)(de)(de)(de)(de)退火(huo)(huo)功(gong)(gong)率應留有(you)足(zu)夠的(de)(de)(de)(de)(de)余量(liang)和對低(di)氧(yang)(yang)銅(tong)和無(wu)氧(yang)(yang)銅(tong)切實區別執行不同(tong)的(de)(de)(de)(de)(de)退火(huo)(huo)工(gong)藝(yi),以(yi)保證在(zai)制(zhi)品(pin)和成(cheng)品(pin)導線的(de)(de)(de)(de)(de)柔軟性。
三(san)、夾雜(za),氧(yang)含量波動,表面氧(yang)化物和可能存在的熱軋缺(que)陷的差別
無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)可(ke)拉(la)性在(zai)(zai)所有(you)線(xian)(xian)徑里與低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)相比(bi)都是優越的(de),除上(shang)述組(zu)織原(yuan)因外,無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)夾(jia)雜(za)少,含(han)氧(yang)(yang)(yang)量穩定,無(wu)熱軋(ya)可(ke)能產(chan)生(sheng)(sheng)的(de)缺陷(xian),桿(gan)表(biao)氧(yang)(yang)(yang)化(hua)物(wu)厚度(du)可(ke)達≤15A。在(zai)(zai)連鑄連軋(ya)生(sheng)(sheng)產(chan)過程中(zhong)如(ru)果(guo)(guo)工藝(yi)不穩定,對氧(yang)(yang)(yang)監(jian)控(kong)不嚴,含(han)氧(yang)(yang)(yang)量不穩定將直接影響(xiang)桿(gan)的(de)性能。如(ru)果(guo)(guo)桿(gan)的(de)表(biao)面(mian)氧(yang)(yang)(yang)化(hua)物(wu)能在(zai)(zai)后工序(xu)的(de)連續清洗中(zhong)得以彌補外,但比(bi)較麻煩的(de)是有(you)相當多的(de)氧(yang)(yang)(yang)化(hua)物(wu)存(cun)在(zai)(zai)于“皮下(xia)”,對拉(la)線(xian)(xian)斷(duan)線(xian)(xian)影響(xiang)更直接,故而在(zai)(zai)拉(la)制微(wei)細線(xian)(xian),超微(wei)細線(xian)(xian)時,為了減少斷(duan)線(xian)(xian),有(you)時要對銅(tong)桿(gan)采取不得已的(de)辦法(fa)——剝皮,甚至二次剝皮的(de)原(yuan)因所在(zai)(zai),目的(de)要除去皮下(xia)氧(yang)(yang)(yang)化(hua)物(wu)。
四、低氧銅桿(gan)和無氧銅桿(gan)的韌(ren)性有差別(bie)
兩者都(dou)可以拉到(dao)0.015mm,但在(zai)低溫(wen)超導線中的低溫(wen)級無(wu)氧銅(tong),其(qi)細絲間的間距(ju)只有0.001mm.
五、從制(zhi)桿(gan)的原(yuan)材料到制(zhi)線的經(jing)濟性有差別(bie)。
制(zhi)造無(wu)(wu)氧銅(tong)桿(gan)要求質量較高(gao)的原材料。一般,拉制(zhi)直(zhi)徑>1mm的銅(tong)線時,低(di)氧銅(tong)桿(gan)的優點比(bi)較明(ming)顯,而(er)無(wu)(wu)氧銅(tong)桿(gan)顯得更為優越的是拉制(zhi)直(zhi)徑<0.5mm的銅(tong)線。
六、低氧銅桿的(de)制(zhi)線(xian)工藝與無氧銅桿的(de)有所(suo)不同。
低(di)氧(yang)銅(tong)(tong)桿(gan)的(de)制線(xian)工藝(yi)(yi)不(bu)(bu)能(neng)照搬到無氧(yang)銅(tong)(tong)桿(gan)的(de)制線(xian)工藝(yi)(yi)上來,至(zhi)少兩者的(de)退火工藝(yi)(yi)是不(bu)(bu)同(tong)的(de)。因(yin)為線(xian)的(de)柔軟(ruan)性深受材料(liao)成份和制桿(gan),制線(xian)和退火工藝(yi)(yi)的(de)影響,不(bu)(bu)能(neng)簡單地說低(di)氧(yang)銅(tong)(tong)或無氧(yang)銅(tong)(tong)誰(shui)軟(ruan)誰(shui)硬。
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