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昌圖電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源(yuan):行(xing)業動(dong)態 閱讀:109439 發(fa)布(bu)時(shi)間:2019-07-05

導讀:由于生(sheng)產銅(tong)(tong)桿(gan)的兩(liang)者的工(gong)藝不(bu)同(tong),所生(sheng)產的銅(tong)(tong)桿(gan)中的含氧(yang)量及外(wai)觀就不(bu)同(tong)。上(shang)引生(sheng)產的銅(tong)(tong)桿(gan),工(gong)藝得(de)當氧(yang)含量在(zai)10ppm以下(xia),叫(jiao)無氧(yang)銅(tong)(tong)桿(gan);連(lian)鑄連(lian)鑄生(sheng)產的銅(tong)(tong)桿(gan) 是(shi)在(zai)保護條(tiao)件(jian)下(xia)的熱軋,氧(yang)含量在(zai)200-500ppm范圍(wei)內,但有時也(ye)高(gao)達700ppm以上(shang),一般情(qing)況(kuang)下(xia),此種(zhong)方法(fa)生(sheng)產的銅(tong)(tong)外(wai)表光亮(liang),低氧(yang)銅(tong)(tong)桿(gan),有時也(ye)叫(jiao)光桿(gan)。

銅(tong)桿(gan)是(shi)電(dian)纜行(xing)(xing)業(ye)的(de)(de)(de)(de)主要原料,生(sheng)產的(de)(de)(de)(de)方(fang)式(shi)主要有(you)兩種——連鑄(zhu)連軋(ya)(ya)法(fa)和上引連鑄(zhu)法(fa)。連鑄(zhu)連軋(ya)(ya)低(di)氧銅(tong)桿(gan)的(de)(de)(de)(de)生(sheng)產方(fang)法(fa)較(jiao)多(duo),其特點(dian)是(shi)金屬在(zai)(zai)豎爐中(zhong)融化(hua)后(hou),銅(tong)液通過保(bao)溫爐、溜槽、中(zhong)間包(bao),從澆管進入(ru)封閉的(de)(de)(de)(de)模腔內,采用較(jiao)大的(de)(de)(de)(de)冷卻強度進行(xing)(xing)冷卻,形成鑄(zhu)坯(pi),然后(hou)進行(xing)(xing)多(duo)道(dao)次軋(ya)(ya)制,生(sheng)產的(de)(de)(de)(de)低(di)氧銅(tong)桿(gan)為熱加工組織,原來(lai)的(de)(de)(de)(de)鑄(zhu)造(zao)組織已經(jing)破碎,含氧量一(yi)般(ban)為200~400ppm之(zhi)間。無(wu)氧銅(tong)桿(gan)國內基本全部采用上引連鑄(zhu)法(fa)生(sheng)產,金屬在(zai)(zai)感(gan)應(ying)電(dian)爐中(zhong)融化(hua)后(hou)通過石墨模進行(xing)(xing)上引連續鑄(zhu)造(zao),之(zhi)后(hou)進行(xing)(xing)冷軋(ya)(ya)或冷加工,生(sheng)產的(de)(de)(de)(de)無(wu)氧銅(tong)桿(gan)為鑄(zhu)造(zao)組織,含氧量一(yi)般(ban)在(zai)(zai)20ppm以(yi)下。由于制造(zao)工藝的(de)(de)(de)(de)不(bu)同,所(suo)以(yi)在(zai)(zai)組織結構(gou)、氧含量分布(bu)、雜質(zhi)的(de)(de)(de)(de)形式(shi)及分布(bu)等諸多(duo)方(fang)面有(you)較(jiao)大差別。

一、拉制性能

銅(tong)桿(gan)的(de)拉制性能(neng)跟很多因(yin)素有關,如雜(za)質的(de)含量、氧含量及分布、工藝控制等(deng)。下(xia)面分別從以(yi)上幾個方面對銅(tong)桿(gan)的(de)拉制性能(neng)進行分析(xi)。

1、熔化方式(shi)對S等雜質的影響(xiang)

連(lian)鑄連(lian)軋生產銅(tong)桿(gan)(gan)主要是(shi)通過(guo)氣(qi)體的(de)燃燒(shao)使(shi)銅(tong)桿(gan)(gan)熔(rong)化,在燃燒(shao)的(de)過(guo)程(cheng)(cheng)中(zhong)(zhong),通過(guo)氧(yang)(yang)化和(he)揮(hui)發作(zuo)用,可(ke)一(yi)定程(cheng)(cheng)度減少(shao)部(bu)分雜質進入(ru)銅(tong)液(ye)(ye),因此連(lian)鑄連(lian)軋法(fa)對原(yuan)料要求相(xiang)對低一(yi)些。上引(yin)連(lian)鑄生產無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan),由于是(shi)用感應電爐(lu)熔(rong)化,電解銅(tong)表(biao)面的(de)“銅(tong)綠(lv)”“銅(tong)豆”基本(ben)都熔(rong)入(ru)到銅(tong)液(ye)(ye)中(zhong)(zhong)。其中(zhong)(zhong)熔(rong)入(ru)的(de)S對無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)塑性(xing)影(ying)響極大,會增加拉絲(si)斷線率。

2、鑄造過程中雜質的進入

在(zai)生產過程(cheng)中(zhong),連鑄(zhu)連軋(ya)(ya)工藝需通(tong)過保溫(wen)爐(lu)、溜槽(cao)、中(zhong)間包轉運銅(tong)(tong)(tong)液,相對容易造(zao)成耐(nai)火材料的(de)(de)(de)剝落(luo),在(zai)軋(ya)(ya)制過程(cheng)中(zhong)需要通(tong)過軋(ya)(ya)輥,造(zao)成鐵(tie)質的(de)(de)(de)脫(tuo)落(luo),會給銅(tong)(tong)(tong)桿造(zao)成外部夾雜。而熱軋(ya)(ya)中(zhong)皮上和皮下氧化(hua)物的(de)(de)(de)軋(ya)(ya)入(ru),會給低氧桿的(de)(de)(de)拉絲造(zao)成不利的(de)(de)(de)影響(xiang)。上引(yin)連鑄(zhu)法生產工藝流程(cheng)較(jiao)(jiao)短,銅(tong)(tong)(tong)液是通(tong)過聯體爐(lu)內(nei)潛流式完成,對耐(nai)火材料的(de)(de)(de)沖擊不大(da),結晶是通(tong)過石墨模內(nei)進(jin)行,所以過程(cheng)中(zhong)可能產生的(de)(de)(de)污(wu)染(ran)源較(jiao)(jiao)少(shao),雜質進(jin)入(ru)的(de)(de)(de)機會較(jiao)(jiao)少(shao)。

O、S、P是與銅(tong)(tong)(tong)會(hui)生(sheng)產化合(he)物的(de)(de)元(yuan)素。在熔態銅(tong)(tong)(tong)中(zhong),氧(yang)(yang)可以(yi)溶(rong)解一(yi)部分,但當(dang)銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)幾(ji)乎(hu)不溶(rong)解于銅(tong)(tong)(tong)中(zhong)。熔態時所溶(rong)解的(de)(de)氧(yang)(yang),以(yi)銅(tong)(tong)(tong)=氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共晶(jing)(jing)(jing)體(ti)析出(chu),分布(bu)在晶(jing)(jing)(jing)粒(li)晶(jing)(jing)(jing)界處。銅(tong)(tong)(tong)-氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共晶(jing)(jing)(jing)體(ti)的(de)(de)出(chu)現(xian),顯著降低了銅(tong)(tong)(tong)的(de)(de)塑性。

硫可(ke)以(yi)溶解(jie)在(zai)熔體(ti)的(de)銅中(zhong),但在(zai)室溫下,其溶解(jie)度幾(ji)乎(hu)降低到零(ling),它以(yi)硫化(hua)亞銅的(de)形式出現在(zai)晶(jing)粒晶(jing)界(jie)處,會(hui)顯著降低銅的(de)塑性。

3、氧(yang)在低氧(yang)銅桿(gan)和無(wu)氧(yang)銅桿(gan)中分布(bu)形式及其影響

氧(yang)(yang)含(han)量對(dui)低(di)氧(yang)(yang)銅(tong)(tong)桿的(de)(de)拉線(xian)(xian)性能(neng)有(you)著明(ming)顯的(de)(de)影響。當(dang)氧(yang)(yang)含(han)量增加(jia)到(dao)(dao)最(zui)佳值時,銅(tong)(tong)桿的(de)(de)斷線(xian)(xian)率(lv)最(zui)低(di)。這是(shi)因為氧(yang)(yang)在與(yu)大部分雜質反應的(de)(de)過程中(zhong)都(dou)起到(dao)(dao)了清除器(qi)的(de)(de)作用。適度的(de)(de)氧(yang)(yang)還(huan)有(you)利于去除銅(tong)(tong)液中(zhong)的(de)(de)氫,生成水蒸(zheng)氣溢出(chu),減(jian)少(shao)氣孔的(de)(de)形(xing)成。最(zui)佳的(de)(de)氧(yang)(yang)含(han)量為拉線(xian)(xian)工藝提(ti)供了最(zui)好的(de)(de)條(tiao)件。

低(di)氧(yang)銅(tong)桿氧(yang)化物的(de)(de)(de)(de)分布:在連續(xu)澆鑄中(zhong)凝固的(de)(de)(de)(de)最初階段(duan),散熱速(su)率和(he)均(jun)勻(yun)冷卻(que)是決(jue)定銅(tong)桿氧(yang)化物分布的(de)(de)(de)(de)主要因(yin)素(su)。不均(jun)勻(yun)冷卻(que)會引起銅(tong)桿內部結構本質上的(de)(de)(de)(de)差異,但后續(xu)的(de)(de)(de)(de)熱加工,柱狀晶通常會遭到(dao)破壞,使氧(yang)化亞銅(tong)顆(ke)粒(li)細(xi)微化和(he)均(jun)勻(yun)分布。氧(yang)化物顆(ke)粒(li)聚集(ji)而(er)產生的(de)(de)(de)(de)典型(xing)情況是中(zhong)心爆(bao)裂(lie)。除氧(yang)化物顆(ke)粒(li)分布的(de)(de)(de)(de)影響外(wai),具有較小(xiao)氧(yang)化物顆(ke)粒(li)的(de)(de)(de)(de)銅(tong)桿顯(xian)示出(chu)較好的(de)(de)(de)(de)拉(la)線特(te)性,較大的(de)(de)(de)(de)Cu2O顆(ke)粒(li)容易造成(cheng)應力集(ji)中(zhong)點而(er)斷裂(lie)。

無(wu)氧(yang)(yang)(yang)銅(tong)含氧(yang)(yang)(yang)量(liang)超(chao)標,銅(tong)桿(gan)變(bian)脆(cui),延伸(shen)率(lv)下(xia)降,拉(la)(la)伸(shen)式樣端(duan)口顯暗紅色,結晶組織疏松。當(dang)氧(yang)(yang)(yang)含量(liang)超(chao)出8ppm時,工(gong)藝(yi)性能(neng)變(bian)差,表現為鑄(zhu)造(zao)及(ji)拉(la)(la)伸(shen)過程中斷(duan)桿(gan)及(ji)斷(duan)線(xian)率(lv)極具增(zeng)高。這是由(you)于氧(yang)(yang)(yang)能(neng)與銅(tong)生(sheng)成(cheng)(cheng)氧(yang)(yang)(yang)化亞銅(tong)脆(cui)性相,形成(cheng)(cheng)銅(tong)-氧(yang)(yang)(yang)化亞銅(tong)共晶體(ti),以網狀組織分布在境界上(shang)。這種脆(cui)性相硬度(du)高,在冷變(bian)形時將會(hui)與銅(tong)機體(ti)脫離,導(dao)致銅(tong)桿(gan)的機械(xie)性能(neng)下(xia)降,在后續加工(gong)中容易(yi)造(zao)成(cheng)(cheng)斷(duan)裂現象。氧(yang)(yang)(yang)含量(liang)高還能(neng)導(dao)致無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)導(dao)電(dian)率(lv)下(xia)降。因(yin)此,必須嚴(yan)格控制上(shang)引連鑄(zhu)工(gong)藝(yi)及(ji)產品質量(liang)。

4、氫的影響

在上(shang)引連鑄(zhu)中(zhong)(zhong),氧含(han)量控制較(jiao)低,氧化物的(de)副作用唄**降低,但氫(qing)的(de)影響成(cheng)為(wei)較(jiao)顯著(zhu)的(de)問題。吸氣后熔體中(zhong)(zhong)存在平衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)體(ti)(ti)及疏松(song)是(shi)在(zai)(zai)結晶(jing)的過程中,氫從過飽和的溶液中析(xi)(xi)出并聚(ju)集而(er)形(xing)成(cheng)的。在(zai)(zai)結晶(jing)前析(xi)(xi)出的氫又可還原(yuan)氧化亞銅而(er)生成(cheng)水氣(qi)(qi)泡。由于(yu)上引鑄造的特點是(shi)銅液自上而(er)下(xia)的結晶(jing),形(xing)成(cheng)的液**形(xing)狀近似(si)錐型。銅液結晶(jing)前析(xi)(xi)出的氣(qi)(qi)體(ti)(ti)在(zai)(zai)上浮過程中被堵在(zai)(zai)凝固組織內(nei),結晶(jing)時(shi)(shi)在(zai)(zai)鑄桿(gan)內(nei)形(xing)成(cheng)氣(qi)(qi)孔(kong)。上引的含氣(qi)(qi)量少時(shi)(shi),析(xi)(xi)出的氫存在(zai)(zai)于(yu)晶(jing)界處(chu),形(xing)成(cheng)疏松(song);含氣(qi)(qi)量多(duo)時(shi)(shi),則(ze)聚(ju)集成(cheng)氣(qi)(qi)孔(kong),因此,氣(qi)(qi)孔(kong)和疏松(song)是(shi)氫氣(qi)(qi)和水蒸(zheng)氣(qi)(qi)兩者形(xing)成(cheng)的。

氫來源于上引(yin)生產過程中的各個工藝環節,如原料電解(jie)銅(tong)(tong)(tong)(tong)的“銅(tong)(tong)(tong)(tong)綠”、輔料木(mu)炭**、氣候(hou)環境**、石(shi)墨結晶器未(wei)干燥等(deng)。因此,熔化爐中的銅(tong)(tong)(tong)(tong)液(ye)表面應覆蓋經烘烤的木(mu)炭,電解(jie)銅(tong)(tong)(tong)(tong)應盡量去除“銅(tong)(tong)(tong)(tong)綠”、“銅(tong)(tong)(tong)(tong)豆”“耳朵”,對提高無(wu)氧銅(tong)(tong)(tong)(tong)桿質(zhi)量非常重要。

在(zai)連(lian)鑄連(lian)軋(ya)工藝中,往往采用適度控制氧含量來(lai)控制氫。Cu2O+ H2= 2Cu+ H2O

由于銅液在鑄(zhu)造過程中是自下而上結(jie)晶,銅液中的(de)氧和(he)氫(qing)所產生的(de)水蒸氣(qi)很容易上浮跑(pao)出(chu),銅液中的(de)氫(qing)大部分(fen)能(neng)被有效(xiao)去除(chu),因而對銅桿的(de)影響較小。

二、表面質量

在(zai)生產電磁(ci)線(xian)等產品(pin)的(de)(de)過程(cheng)中,對銅(tong)(tong)桿(gan)的(de)(de)表(biao)(biao)面(mian)質(zhi)量(liang)也(ye)需提(ti)出要(yao)求。需要(yao)拉制后的(de)(de)銅(tong)(tong)絲表(biao)(biao)面(mian)無毛刺(ci)、銅(tong)(tong)粉(fen)少、無油(you)污。并(bing)通(tong)過扭轉(zhuan)試驗測量(liang)表(biao)(biao)面(mian)銅(tong)(tong)粉(fen)的(de)(de)質(zhi)量(liang)和(he)扭轉(zhuan)后觀察(cha)銅(tong)(tong)桿(gan)的(de)(de)復原情況來判定其(qi)好壞。

在(zai)連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)(ya)(ya)過程(cheng)中,從鑄(zhu)(zhu)造到軋(ya)(ya)(ya)(ya)制前(qian),溫度高,完全暴(bao)露于空氣中,使鑄(zhu)(zhu)坯表(biao)面(mian)形成較(jiao)厚(hou)的氧(yang)化(hua)(hua)層,在(zai)軋(ya)(ya)(ya)(ya)制過程(cheng)中,隨著軋(ya)(ya)(ya)(ya)輥的轉動,氧(yang)化(hua)(hua)物顆粒軋(ya)(ya)(ya)(ya)入銅(tong)線(xian)表(biao)面(mian)。由于氧(yang)化(hua)(hua)亞(ya)銅(tong)是高熔點脆性化(hua)(hua)合物,對于軋(ya)(ya)(ya)(ya)入較(jiao)深的氧(yang)化(hua)(hua)亞(ya)銅(tong),當成條狀的聚(ju)集(ji)物遇模具拉伸(shen)時,就會是銅(tong)桿外(wai)表(biao)面(mian)產生毛(mao)刺(ci),給后續的涂漆造成麻煩。

而上引連鑄工藝制造的無氧銅(tong)桿(gan),由(you)于鑄造和(he)冷卻完全(quan)與氧隔絕,后續亦無熱軋(ya)過程,銅(tong)桿(gan)表面無軋(ya)入表面的氧化物,質量較(jiao)好,拉制后銅(tong)粉少(shao),上述問題較(jiao)少(shao)存在。

無氧(yang)銅(tong)桿也分進(jin)口(kou)設(she)(she)備(bei)做(zuo)的(de)(de)和(he)國產(chan)(chan)設(she)(she)備(bei)做(zuo)的(de)(de),但目前進(jin)口(kou)產(chan)(chan)品(pin)已無明顯優勢(shi),銅(tong)桿產(chan)(chan)品(pin)出(chu)來后區別不是(shi)很大,只(zhi)要銅(tong)板選的(de)(de)好(hao)(hao),生產(chan)(chan)控(kong)制(zhi)比(bi)較(jiao)穩(wen)定,國產(chan)(chan)設(she)(she)備(bei)也能(neng)產(chan)(chan)出(chu)可拉伸0.05的(de)(de)銅(tong)桿.進(jin)口(kou)設(she)(she)備(bei)一般是(shi)芬蘭奧(ao)托昆(kun)普的(de)(de)設(she)(she)備(bei),國產(chan)(chan)設(she)(she)備(bei)最好(hao)(hao)的(de)(de)應該是(shi)上海的(de)(de)海軍(jun)廠的(de)(de)了,生產(chan)(chan)時間最長(chang),軍(jun)工企業,質量可靠(kao)。

低氧銅桿進口設備(bei)國(guo)(guo)際主(zhu)要(yao)有兩種,一種是(shi)美國(guo)(guo)南(nan)線(xian)設備(bei),英文是(shi)SOUTHWIRE,國(guo)(guo)內(nei)廠家是(shi)南(nan)京華新,江西銅業,另一種是(shi)德國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內(nei)廠家是(shi)常州金源,天津大無縫。

無(wu)(wu)氧(yang)及低(di)(di)氧(yang)桿從含(han)氧(yang)量(liang)上(shang)容(rong)易區別(bie),無(wu)(wu)氧(yang)銅(tong)是(shi)含(han)氧(yang)量(liang)在(zai)10-20個(ge)PPM以下(xia),但(dan)目(mu)前有的(de)(de)廠家只(zhi)能(neng)做(zuo)到(dao)(dao)50個(ge)PPM以下(xia).低(di)(di)氧(yang)銅(tong)桿在(zai) 200-400個(ge)PPM,好的(de)(de)桿子一般含(han)氧(yang)量(liang)控制在(zai)250個(ge)PPM左右,無(wu)(wu)氧(yang)桿一般采取的(de)(de)是(shi)上(shang)引法(fa),低(di)(di)氧(yang)桿是(shi)連(lian)鑄(zhu)連(lian)軋,兩(liang)種產品相對而(er)言低(di)(di)氧(yang)桿對漆包線(xian)(xian)性(xing) 能(neng)更(geng)適(shi)應些,如柔軟(ruan)性(xing),回彈角,繞(rao)線(xian)(xian)性(xing)能(neng).但(dan)低(di)(di)氧(yang)桿對拉(la)絲條件相對要苛刻些,同(tong)樣拉(la)伸(shen)0.2的(de)(de)細絲,如果(guo)伸(shen)線(xian)(xian)條件不好,普(pu)通的(de)(de)無(wu)(wu)氧(yang)桿可拉(la)而(er)好的(de)(de)低(di)(di)氧(yang)桿就斷 線(xian)(xian),但(dan)如果(guo)放(fang)在(zai)好的(de)(de)伸(shen)線(xian)(xian)條件,同(tong)樣的(de)(de)桿子,低(di)(di)氧(yang)桿說不定就能(neng)拉(la)到(dao)(dao)雙(shuang)零(ling)五,而(er)普(pu)通無(wu)(wu)氧(yang)桿最多只(zhi)能(neng)拉(la)伸(shen)到(dao)(dao)0.1而(er)已,當(dang)然做(zuo)的(de)(de)最細的(de)(de)如雙(shuang)零(ling)二卻非(fei)得依(yi)靠進口(kou)的(de)(de) 無(wu)(wu)氧(yang)銅(tong)桿了.目(mu)前有企業嘗試用剝(bo)皮的(de)(de)方(fang)式來(lai)處理低(di)(di)氧(yang)桿來(lai)伸(shen)0.03線(xian)(xian).但(dan)有關這(zhe)方(fang)面(mian)的(de)(de)內容(rong)我還(huan)不是(shi)很清楚。

音響線一般反而喜歡用(yong)無氧桿(gan),這和(he)無氧桿(gan)是單晶銅(tong),低(di)氧桿(gan)是多晶銅(tong)有關。

氧(yang)銅(tong)桿(gan)和無(wu)氧(yang)銅(tong)桿(gan)由于制造方法的不同,致使存(cun)在差別,具(ju)有各自(zi)的特點。

一、關于氧的吸(xi)入和脫去(qu)以(yi)及它的存(cun)在狀態

生產(chan)銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)10—50ppm,在(zai)常溫下(xia)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)固(gu)溶度約2ppm。低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是(shi)在(zai)銅(tong)(tong)的(de)(de)(de)(de)(de)液(ye)態(tai)下(xia)吸(xi)入的(de)(de)(de)(de)(de),而上引(yin)法無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)則相反,氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液(ye)態(tai)銅(tong)(tong)下(xia)保持(chi)相當時間后,被還原而脫去,通常這(zhe)(zhe)種桿(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量都在(zai)10—50ppm以(yi)下(xia),最(zui)低可(ke)達1-2ppm,從組織上看,低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化(hua)(hua)銅(tong)(tong)狀態(tai),存在(zai)于晶(jing)粒邊界(jie)附近,這(zhe)(zhe)對(dui)(dui)低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)而言可(ke)以(yi)說是(shi)常見的(de)(de)(de)(de)(de)但對(dui)(dui)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)則很(hen)(hen)少見。氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化(hua)(hua)銅(tong)(tong)以(yi)夾雜形式(shi)在(zai)晶(jing)界(jie)出(chu)現對(dui)(dui)材料(liao)的(de)(de)(de)(de)(de)韌性(xing)(xing)產(chan)生負面影(ying)響。而無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)很(hen)(hen)低,所以(yi)這(zhe)(zhe)種銅(tong)(tong)的(de)(de)(de)(de)(de)組織是(shi)均勻的(de)(de)(de)(de)(de)單(dan)相組織對(dui)(dui)韌性(xing)(xing)有利。在(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)中(zhong)(zhong)的(de)(de)(de)(de)(de)多孔性(xing)(xing)是(shi)不(bu)常見的(de)(de)(de)(de)(de),而在(zai)低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)中(zhong)(zhong)則是(shi)常見的(de)(de)(de)(de)(de)一種缺(que)陷。

二、熱(re)軋組織和鑄造組織的區別

低氧(yang)銅(tong)桿(gan)由(you)于經過熱(re)軋,所(suo)以其組(zu)(zu)織(zhi)(zhi)屬熱(re)加工組(zu)(zu)織(zhi)(zhi),原(yuan)來的(de)(de)鑄造組(zu)(zu)織(zhi)(zhi)已經破碎,在8mm的(de)(de)桿(gan)時(shi)已有再結晶(jing)(jing)的(de)(de)形(xing)式出現,而無(wu)氧(yang)銅(tong)桿(gan)屬鑄造組(zu)(zu)織(zhi)(zhi),晶(jing)(jing)粒(li)粗(cu)大,這是(shi)(shi)為(wei)什么,無(wu)氧(yang)銅(tong)的(de)(de)再結晶(jing)(jing)溫(wen)度較高,需要(yao)較高退(tui)火(huo)溫(wen)度的(de)(de)固有原(yuan)因。這是(shi)(shi)因為(wei),再結晶(jing)(jing)發生在晶(jing)(jing)粒(li)邊(bian)界附近,無(wu)氧(yang)銅(tong)桿(gan)組(zu)(zu)織(zhi)(zhi)晶(jing)(jing)粒(li)粗(cu)大,晶(jing)(jing)粒(li)尺寸甚至能達幾個(ge)毫(hao)米,因而晶(jing)(jing)粒(li)邊(bian)界少,即使通過拉(la)制(zhi)變形(xing),但晶(jing)(jing)粒(li)邊(bian)界相(xiang)對低氧(yang)銅(tong)桿(gan)還是(shi)(shi)較少,所(suo)以需要(yao)較高的(de)(de)退(tui)火(huo)功率(lv)。對無(wu)氧(yang)銅(tong)成功的(de)(de)退(tui)火(huo)要(yao)求是(shi)(shi):由(you)桿(gan)經拉(la)制(zhi),但尚未鑄造組(zu)(zu)織(zhi)(zhi)的(de)(de)線時(shi)的(de)(de)第一次退(tui)火(huo),其退(tui)火(huo)功率(lv)應比同樣情況(kuang)的(de)(de)低氧(yang)銅(tong)高10——15%。經繼續(xu)拉(la)制(zhi),在以后(hou)階段的(de)(de)退(tui)火(huo)功率(lv)應留有足夠(gou)的(de)(de)余量和對低氧(yang)銅(tong)和無(wu)氧(yang)銅(tong)切實區別(bie)執行(xing)不同的(de)(de)退(tui)火(huo)工藝(yi),以保證在制(zhi)品和成品導線的(de)(de)柔軟性。

三、夾雜,氧含量波動(dong),表面氧化物和(he)可(ke)能存在的(de)熱(re)軋(ya)缺陷的(de)差別

無(wu)氧(yang)(yang)(yang)(yang)銅桿(gan)的(de)(de)(de)(de)可拉(la)性(xing)在(zai)所有(you)線(xian)徑里與低氧(yang)(yang)(yang)(yang)銅桿(gan)相比都(dou)是(shi)優越的(de)(de)(de)(de),除上述組織原(yuan)因外(wai),無(wu)氧(yang)(yang)(yang)(yang)銅桿(gan)夾(jia)雜少(shao),含氧(yang)(yang)(yang)(yang)量穩(wen)(wen)定(ding),無(wu)熱軋可能產生的(de)(de)(de)(de)缺陷,桿(gan)表(biao)氧(yang)(yang)(yang)(yang)化物(wu)厚度可達≤15A。在(zai)連鑄(zhu)連軋生產過程(cheng)中如(ru)果工藝不穩(wen)(wen)定(ding),對(dui)氧(yang)(yang)(yang)(yang)監控不嚴,含氧(yang)(yang)(yang)(yang)量不穩(wen)(wen)定(ding)將直接影響(xiang)桿(gan)的(de)(de)(de)(de)性(xing)能。如(ru)果桿(gan)的(de)(de)(de)(de)表(biao)面氧(yang)(yang)(yang)(yang)化物(wu)能在(zai)后工序的(de)(de)(de)(de)連續(xu)清洗中得以彌(mi)補外(wai),但比較麻煩的(de)(de)(de)(de)是(shi)有(you)相當(dang)多的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)化物(wu)存在(zai)于“皮(pi)下(xia)”,對(dui)拉(la)線(xian)斷線(xian)影響(xiang)更直接,故(gu)而在(zai)拉(la)制微(wei)細線(xian),超微(wei)細線(xian)時(shi),為了減少(shao)斷線(xian),有(you)時(shi)要對(dui)銅桿(gan)采取不得已(yi)的(de)(de)(de)(de)辦法——剝皮(pi),甚至(zhi)二次(ci)剝皮(pi)的(de)(de)(de)(de)原(yuan)因所在(zai),目的(de)(de)(de)(de)要除去皮(pi)下(xia)氧(yang)(yang)(yang)(yang)化物(wu)。

四、低氧銅桿和無氧銅桿的(de)韌(ren)性有差(cha)別

兩(liang)者都可以拉到0.015mm,但在低溫(wen)超導線中的低溫(wen)級無氧(yang)銅(tong),其細絲間(jian)的間(jian)距只(zhi)有0.001mm.

五、從(cong)制(zhi)桿的(de)原(yuan)材料到制(zhi)線的(de)經濟性有差別。

制造無(wu)氧銅桿要求質量較(jiao)高(gao)的(de)(de)原材(cai)料。一般,拉制直徑>1mm的(de)(de)銅線(xian)時,低氧銅桿的(de)(de)優點比(bi)較(jiao)明(ming)顯,而無(wu)氧銅桿顯得更為優越的(de)(de)是拉制直徑<0.5mm的(de)(de)銅線(xian)。

六、低氧(yang)銅(tong)桿(gan)的制線工(gong)藝與無氧(yang)銅(tong)桿(gan)的有所不同。

低(di)氧銅(tong)(tong)桿的(de)制(zhi)線工藝不(bu)能(neng)照搬(ban)到無氧銅(tong)(tong)桿的(de)制(zhi)線工藝上來,至少兩者的(de)退火工藝是不(bu)同的(de)。因為(wei)線的(de)柔軟性深受材料(liao)成份和制(zhi)桿,制(zhi)線和退火工藝的(de)影響,不(bu)能(neng)簡單地(di)說低(di)氧銅(tong)(tong)或無氧銅(tong)(tong)誰軟誰硬。