熱(re)門關鍵詞:
來源:行業動(dong)態 閱(yue)讀:109458 發布時間:2019-07-05
導讀(du):由(you)于生(sheng)產(chan)銅桿的兩者的工(gong)藝不同(tong),所生(sheng)產(chan)的銅桿中(zhong)的含氧量及(ji)外觀(guan)就不同(tong)。上引生(sheng)產(chan)的銅桿,工(gong)藝得(de)當氧含量在10ppm以下(xia),叫(jiao)無氧銅桿;連(lian)鑄連(lian)鑄生(sheng)產(chan)的銅桿 是(shi)在保護條(tiao)件下(xia)的熱(re)軋,氧含量在200-500ppm范圍內,但有時也(ye)高達700ppm以上,一般情況下(xia),此(ci)種方法生(sheng)產(chan)的銅外表光亮,低氧銅桿,有時也(ye)叫(jiao)光桿。
銅(tong)(tong)(tong)桿(gan)是(shi)電纜行(xing)(xing)業的(de)主要原(yuan)料,生(sheng)產的(de)方(fang)式主要有兩種——連(lian)鑄連(lian)軋(ya)法和(he)上引(yin)連(lian)鑄法。連(lian)鑄連(lian)軋(ya)低氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)的(de)生(sheng)產方(fang)法較多(duo)(duo)(duo),其特點是(shi)金(jin)屬(shu)在(zai)豎爐(lu)中融化后(hou),銅(tong)(tong)(tong)液通過保溫爐(lu)、溜槽、中間包,從澆管(guan)進(jin)入(ru)封閉的(de)模腔(qiang)內,采用較大的(de)冷卻(que)強度進(jin)行(xing)(xing)冷卻(que),形成鑄坯,然(ran)后(hou)進(jin)行(xing)(xing)多(duo)(duo)(duo)道次(ci)軋(ya)制,生(sheng)產的(de)低氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)為熱(re)加(jia)工(gong)組(zu)織(zhi)(zhi),原(yuan)來的(de)鑄造組(zu)織(zhi)(zhi)已經破碎(sui),含(han)氧(yang)(yang)量(liang)一般為200~400ppm之(zhi)間。無氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)國內基本全(quan)部采用上引(yin)連(lian)鑄法生(sheng)產,金(jin)屬(shu)在(zai)感應電爐(lu)中融化后(hou)通過石墨模進(jin)行(xing)(xing)上引(yin)連(lian)續鑄造,之(zhi)后(hou)進(jin)行(xing)(xing)冷軋(ya)或冷加(jia)工(gong),生(sheng)產的(de)無氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)為鑄造組(zu)織(zhi)(zhi),含(han)氧(yang)(yang)量(liang)一般在(zai)20ppm以下。由于制造工(gong)藝的(de)不同(tong),所以在(zai)組(zu)織(zhi)(zhi)結構、氧(yang)(yang)含(han)量(liang)分布、雜質的(de)形式及分布等諸多(duo)(duo)(duo)方(fang)面有較大差別。
一、拉制性能
銅桿的(de)拉制(zhi)性(xing)能跟很多(duo)因素有關,如雜質的(de)含(han)量、氧(yang)含(han)量及分布、工藝控制(zhi)等。下(xia)面分別從以上幾(ji)個方面對銅桿的(de)拉制(zhi)性(xing)能進(jin)行分析。
1、熔(rong)化方式對S等雜質的影響
連(lian)(lian)鑄連(lian)(lian)軋生產銅桿(gan)主要是通過氣體的(de)燃燒(shao)(shao)使銅桿(gan)熔(rong)化(hua),在燃燒(shao)(shao)的(de)過程中,通過氧化(hua)和揮發作用(yong),可一(yi)(yi)定程度減少部分雜(za)質進(jin)入銅液(ye),因此連(lian)(lian)鑄連(lian)(lian)軋法對原料要求相對低一(yi)(yi)些。上引連(lian)(lian)鑄生產無氧銅桿(gan),由于是用(yong)感應電爐(lu)熔(rong)化(hua),電解銅表(biao)面(mian)的(de)“銅綠”“銅豆”基本都熔(rong)入到銅液(ye)中。其(qi)中熔(rong)入的(de)S對無氧銅桿(gan)塑(su)性影(ying)響極大(da),會增加拉絲(si)斷線率。
2、鑄(zhu)造過程中雜質(zhi)的進(jin)入(ru)
在生產(chan)過(guo)(guo)(guo)(guo)程(cheng)中(zhong),連鑄連軋(ya)工藝(yi)需通(tong)過(guo)(guo)(guo)(guo)保溫爐、溜(liu)槽、中(zhong)間包轉運銅(tong)液,相對容易(yi)造(zao)成耐火材料的(de)(de)剝落,在軋(ya)制過(guo)(guo)(guo)(guo)程(cheng)中(zhong)需要通(tong)過(guo)(guo)(guo)(guo)軋(ya)輥,造(zao)成鐵質的(de)(de)脫落,會給銅(tong)桿造(zao)成外(wai)部(bu)夾雜(za)。而熱軋(ya)中(zhong)皮上和皮下(xia)氧化物的(de)(de)軋(ya)入,會給低(di)氧桿的(de)(de)拉(la)絲造(zao)成不(bu)利的(de)(de)影響。上引連鑄法(fa)生產(chan)工藝(yi)流(liu)程(cheng)較(jiao)(jiao)短,銅(tong)液是通(tong)過(guo)(guo)(guo)(guo)聯體爐內潛(qian)流(liu)式完成,對耐火材料的(de)(de)沖(chong)擊不(bu)大,結晶是通(tong)過(guo)(guo)(guo)(guo)石墨模內進(jin)行(xing),所以過(guo)(guo)(guo)(guo)程(cheng)中(zhong)可能(neng)產(chan)生的(de)(de)污染源較(jiao)(jiao)少,雜(za)質進(jin)入的(de)(de)機(ji)會較(jiao)(jiao)少。
O、S、P是與(yu)銅(tong)(tong)會生產化(hua)合物的(de)(de)元素。在(zai)熔態銅(tong)(tong)中,氧可以溶解一部分,但(dan)當銅(tong)(tong)冷凝時,氧幾乎不溶解于銅(tong)(tong)中。熔態時所溶解的(de)(de)氧,以銅(tong)(tong)=氧化(hua)亞銅(tong)(tong)共(gong)晶(jing)體(ti)析出(chu),分布在(zai)晶(jing)粒晶(jing)界處(chu)。銅(tong)(tong)-氧化(hua)亞銅(tong)(tong)共(gong)晶(jing)體(ti)的(de)(de)出(chu)現,顯著降(jiang)低(di)了銅(tong)(tong)的(de)(de)塑(su)性。
硫(liu)可以(yi)溶解在(zai)熔體的銅中(zhong),但在(zai)室溫下,其溶解度幾(ji)乎降(jiang)低(di)到(dao)零(ling),它以(yi)硫(liu)化亞銅的形式出現(xian)在(zai)晶(jing)粒晶(jing)界處,會顯著降(jiang)低(di)銅的塑性。
3、氧(yang)(yang)在低氧(yang)(yang)銅桿和無氧(yang)(yang)銅桿中分布形式及其影響
氧(yang)(yang)(yang)含量(liang)對(dui)低氧(yang)(yang)(yang)銅桿的(de)(de)拉(la)線(xian)性能有著明顯的(de)(de)影(ying)響。當氧(yang)(yang)(yang)含量(liang)增加到(dao)最(zui)佳值時(shi),銅桿的(de)(de)斷線(xian)率(lv)最(zui)低。這是因為(wei)氧(yang)(yang)(yang)在與大部分雜質反應的(de)(de)過(guo)程中都起到(dao)了清除(chu)器的(de)(de)作用。適度的(de)(de)氧(yang)(yang)(yang)還(huan)有利于(yu)去除(chu)銅液中的(de)(de)氫,生成水蒸氣溢出,減少氣孔(kong)的(de)(de)形成。最(zui)佳的(de)(de)氧(yang)(yang)(yang)含量(liang)為(wei)拉(la)線(xian)工藝提供了最(zui)好的(de)(de)條件。
低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿氧(yang)(yang)(yang)化(hua)物(wu)的分(fen)布:在連(lian)續(xu)(xu)澆鑄中(zhong)凝固的最初階段,散熱速率(lv)和均勻(yun)冷卻是決(jue)定銅(tong)(tong)桿氧(yang)(yang)(yang)化(hua)物(wu)分(fen)布的主要因素。不均勻(yun)冷卻會(hui)引起銅(tong)(tong)桿內(nei)部(bu)結構(gou)本(ben)質上的差異,但后續(xu)(xu)的熱加工,柱狀(zhuang)晶通常會(hui)遭到破壞,使氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)顆(ke)(ke)粒(li)(li)(li)(li)細微化(hua)和均勻(yun)分(fen)布。氧(yang)(yang)(yang)化(hua)物(wu)顆(ke)(ke)粒(li)(li)(li)(li)聚集(ji)(ji)而產(chan)生的典型情況(kuang)是中(zhong)心(xin)爆裂。除氧(yang)(yang)(yang)化(hua)物(wu)顆(ke)(ke)粒(li)(li)(li)(li)分(fen)布的影響(xiang)外,具有(you)較(jiao)(jiao)小氧(yang)(yang)(yang)化(hua)物(wu)顆(ke)(ke)粒(li)(li)(li)(li)的銅(tong)(tong)桿顯示出較(jiao)(jiao)好的拉線(xian)特性(xing),較(jiao)(jiao)大(da)的Cu2O顆(ke)(ke)粒(li)(li)(li)(li)容易造成應力集(ji)(ji)中(zhong)點而斷裂。
無氧(yang)(yang)(yang)銅(tong)含氧(yang)(yang)(yang)量超(chao)標,銅(tong)桿(gan)變(bian)脆,延伸(shen)率(lv)下(xia)(xia)降,拉伸(shen)式樣端口顯暗紅(hong)色,結晶組織疏松。當氧(yang)(yang)(yang)含量超(chao)出8ppm時,工(gong)藝性(xing)能變(bian)差,表現為鑄造(zao)及拉伸(shen)過(guo)程(cheng)中斷(duan)桿(gan)及斷(duan)線率(lv)極具增高(gao)(gao)。這是由于氧(yang)(yang)(yang)能與(yu)銅(tong)生成(cheng)(cheng)氧(yang)(yang)(yang)化(hua)亞(ya)銅(tong)脆性(xing)相,形(xing)成(cheng)(cheng)銅(tong)-氧(yang)(yang)(yang)化(hua)亞(ya)銅(tong)共(gong)晶體(ti),以網狀組織分布在(zai)境界上。這種脆性(xing)相硬度高(gao)(gao),在(zai)冷變(bian)形(xing)時將會與(yu)銅(tong)機體(ti)脫離,導致(zhi)銅(tong)桿(gan)的(de)機械性(xing)能下(xia)(xia)降,在(zai)后續加工(gong)中容易造(zao)成(cheng)(cheng)斷(duan)裂現象。氧(yang)(yang)(yang)含量高(gao)(gao)還能導致(zhi)無氧(yang)(yang)(yang)銅(tong)桿(gan)導電率(lv)下(xia)(xia)降。因(yin)此,必須嚴格(ge)控(kong)制(zhi)上引連鑄工(gong)藝及產品質量。
4、氫的影響
在(zai)上(shang)引(yin)連鑄中,氧含量控制較低,氧化物的(de)副(fu)作用唄**降低,但(dan)氫的(de)影響(xiang)成為較顯著的(de)問題。吸氣(qi)后熔(rong)體中存在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)體及疏松(song)是在結晶的(de)(de)(de)過程中(zhong),氫從過飽和(he)的(de)(de)(de)溶液中(zhong)析(xi)出(chu)并(bing)聚集而形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)。在結晶前(qian)析(xi)出(chu)的(de)(de)(de)氫又可還原(yuan)氧(yang)化亞銅而生成(cheng)(cheng)水(shui)氣(qi)(qi)泡。由于上(shang)引(yin)鑄(zhu)造的(de)(de)(de)特點是銅液自上(shang)而下的(de)(de)(de)結晶,形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)液**形(xing)(xing)狀近(jin)似錐型。銅液結晶前(qian)析(xi)出(chu)的(de)(de)(de)氣(qi)(qi)體在上(shang)浮過程中(zhong)被堵在凝固組織(zhi)內,結晶時(shi)在鑄(zhu)桿內形(xing)(xing)成(cheng)(cheng)氣(qi)(qi)孔(kong)。上(shang)引(yin)的(de)(de)(de)含(han)氣(qi)(qi)量(liang)(liang)少時(shi),析(xi)出(chu)的(de)(de)(de)氫存在于晶界處,形(xing)(xing)成(cheng)(cheng)疏松(song);含(han)氣(qi)(qi)量(liang)(liang)多時(shi),則(ze)聚集成(cheng)(cheng)氣(qi)(qi)孔(kong),因此(ci),氣(qi)(qi)孔(kong)和(he)疏松(song)是氫氣(qi)(qi)和(he)水(shui)蒸氣(qi)(qi)兩者(zhe)形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)。
氫來源于上引生(sheng)產過程中(zhong)的(de)(de)各個工藝(yi)環節,如原料電解銅(tong)的(de)(de)“銅(tong)綠”、輔料木炭**、氣候環境**、石墨結晶(jing)器未(wei)干燥等(deng)。因此,熔化爐(lu)中(zhong)的(de)(de)銅(tong)液(ye)表面應覆蓋(gai)經烘烤的(de)(de)木炭,電解銅(tong)應盡量(liang)(liang)去除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對提高無氧銅(tong)桿質(zhi)量(liang)(liang)非常重要。
在(zai)連(lian)鑄連(lian)軋工藝中,往往采用適(shi)度控制(zhi)氧含量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液在鑄造過程中(zhong)(zhong)是自(zi)下而(er)上結(jie)晶,銅(tong)液中(zhong)(zhong)的(de)(de)氧和氫所產(chan)生的(de)(de)水蒸氣很容易上浮跑出,銅(tong)液中(zhong)(zhong)的(de)(de)氫大部分能被有效去除,因而(er)對(dui)銅(tong)桿的(de)(de)影(ying)響較小。
二、表面質量
在生(sheng)產電磁(ci)線(xian)等產品的(de)過程(cheng)中(zhong),對(dui)銅(tong)桿的(de)表(biao)面(mian)(mian)質(zhi)量也需提出要(yao)求(qiu)。需要(yao)拉制后(hou)(hou)的(de)銅(tong)絲表(biao)面(mian)(mian)無毛刺、銅(tong)粉少、無油污。并通過扭轉試驗測量表(biao)面(mian)(mian)銅(tong)粉的(de)質(zhi)量和扭轉后(hou)(hou)觀察銅(tong)桿的(de)復(fu)原情況來判定其好壞。
在(zai)連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)(ya)(ya)過(guo)程中,從鑄(zhu)(zhu)造(zao)到軋(ya)(ya)(ya)(ya)制(zhi)前,溫度高,完全暴露于空氣中,使鑄(zhu)(zhu)坯表(biao)面(mian)形成較(jiao)厚的(de)氧化層,在(zai)軋(ya)(ya)(ya)(ya)制(zhi)過(guo)程中,隨著(zhu)軋(ya)(ya)(ya)(ya)輥(gun)的(de)轉動(dong),氧化物(wu)顆粒軋(ya)(ya)(ya)(ya)入(ru)銅(tong)(tong)線表(biao)面(mian)。由于氧化亞銅(tong)(tong)是高熔點脆性化合物(wu),對于軋(ya)(ya)(ya)(ya)入(ru)較(jiao)深的(de)氧化亞銅(tong)(tong),當成條狀的(de)聚集(ji)物(wu)遇模具拉(la)伸時,就會是銅(tong)(tong)桿(gan)外表(biao)面(mian)產生(sheng)毛刺,給(gei)后(hou)續的(de)涂漆造(zao)成麻煩。
而上引連鑄工藝(yi)制造(zao)的無(wu)氧銅(tong)桿(gan),由(you)于(yu)鑄造(zao)和(he)冷卻完(wan)全與氧隔(ge)絕,后續(xu)亦無(wu)熱軋過程,銅(tong)桿(gan)表面無(wu)軋入表面的氧化物,質量較好,拉制后銅(tong)粉(fen)少(shao),上述問題較少(shao)存在。
無氧(yang)銅桿也分進口設(she)(she)(she)備做(zuo)(zuo)的(de)(de)(de)(de)和國(guo)產(chan)(chan)(chan)設(she)(she)(she)備做(zuo)(zuo)的(de)(de)(de)(de),但(dan)目(mu)前進口產(chan)(chan)(chan)品已無明顯優勢,銅桿產(chan)(chan)(chan)品出來后(hou)區別不(bu)是很(hen)大,只(zhi)要(yao)銅板選的(de)(de)(de)(de)好,生(sheng)產(chan)(chan)(chan)控制比(bi)較穩定,國(guo)產(chan)(chan)(chan)設(she)(she)(she)備也能(neng)產(chan)(chan)(chan)出可(ke)拉伸0.05的(de)(de)(de)(de)銅桿.進口設(she)(she)(she)備一般是芬(fen)蘭奧托昆普的(de)(de)(de)(de)設(she)(she)(she)備,國(guo)產(chan)(chan)(chan)設(she)(she)(she)備最好的(de)(de)(de)(de)應(ying)該是上海的(de)(de)(de)(de)海軍(jun)廠的(de)(de)(de)(de)了,生(sheng)產(chan)(chan)(chan)時間最長(chang),軍(jun)工企業(ye),質量可(ke)靠(kao)。
低氧(yang)銅桿進口設(she)備國(guo)(guo)(guo)際(ji)主要有兩(liang)種,一種是(shi)美國(guo)(guo)(guo)南(nan)線設(she)備,英(ying)文是(shi)SOUTHWIRE,國(guo)(guo)(guo)內廠(chang)家(jia)是(shi)南(nan)京(jing)華(hua)新,江西銅業,另一種是(shi)德國(guo)(guo)(guo)CONTIROD設(she)備,國(guo)(guo)(guo)內廠(chang)家(jia)是(shi)常(chang)州金源(yuan),天津大無縫。
無氧(yang)(yang)及(ji)低(di)(di)(di)氧(yang)(yang)桿(gan)從含(han)氧(yang)(yang)量上容易區別,無氧(yang)(yang)銅是含(han)氧(yang)(yang)量在10-20個PPM以下,但(dan)目(mu)前有(you)(you)的(de)(de)(de)廠家只(zhi)能做到(dao)50個PPM以下.低(di)(di)(di)氧(yang)(yang)銅桿(gan)在 200-400個PPM,好(hao)的(de)(de)(de)桿(gan)子(zi)一(yi)般含(han)氧(yang)(yang)量控制在250個PPM左(zuo)右,無氧(yang)(yang)桿(gan)一(yi)般采取的(de)(de)(de)是上引法,低(di)(di)(di)氧(yang)(yang)桿(gan)是連(lian)鑄連(lian)軋,兩(liang)種產品相對(dui)(dui)而(er)言低(di)(di)(di)氧(yang)(yang)桿(gan)對(dui)(dui)漆包線(xian)性(xing) 能更適應些,如柔軟性(xing),回彈角(jiao),繞(rao)線(xian)性(xing)能.但(dan)低(di)(di)(di)氧(yang)(yang)桿(gan)對(dui)(dui)拉絲條(tiao)件相對(dui)(dui)要苛刻些,同(tong)樣拉伸(shen)0.2的(de)(de)(de)細絲,如果伸(shen)線(xian)條(tiao)件不好(hao),普(pu)(pu)通(tong)的(de)(de)(de)無氧(yang)(yang)桿(gan)可拉而(er)好(hao)的(de)(de)(de)低(di)(di)(di)氧(yang)(yang)桿(gan)就斷 線(xian),但(dan)如果放在好(hao)的(de)(de)(de)伸(shen)線(xian)條(tiao)件,同(tong)樣的(de)(de)(de)桿(gan)子(zi),低(di)(di)(di)氧(yang)(yang)桿(gan)說不定就能拉到(dao)雙(shuang)零五,而(er)普(pu)(pu)通(tong)無氧(yang)(yang)桿(gan)最(zui)多(duo)只(zhi)能拉伸(shen)到(dao)0.1而(er)已,當然做的(de)(de)(de)最(zui)細的(de)(de)(de)如雙(shuang)零二(er)卻非得依靠進口的(de)(de)(de) 無氧(yang)(yang)銅桿(gan)了.目(mu)前有(you)(you)企(qi)業(ye)嘗試用剝皮的(de)(de)(de)方式來處理低(di)(di)(di)氧(yang)(yang)桿(gan)來伸(shen)0.03線(xian).但(dan)有(you)(you)關這方面的(de)(de)(de)內容我還不是很(hen)清(qing)楚。
音響線一般反而喜歡(huan)用無氧桿,這(zhe)和無氧桿是(shi)單(dan)晶(jing)銅,低氧桿是(shi)多晶(jing)銅有關。
氧銅(tong)(tong)桿和無氧銅(tong)(tong)桿由于制(zhi)造方(fang)法的(de)不(bu)同,致使存在差別,具有(you)各自的(de)特點。
一(yi)、關于(yu)氧(yang)的吸入和脫去以及它的存在(zai)狀態
生產(chan)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)(liang)一(yi)般在(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)常溫下(xia)氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)固溶度約(yue)2ppm。低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)(liang)一(yi)般在(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)液態下(xia)吸入的(de)(de)(de)(de),而上引法無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則相(xiang)反,氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)(zai)液態銅(tong)(tong)(tong)(tong)下(xia)保(bao)持(chi)相(xiang)當時間后(hou),被(bei)還原而脫去(qu),通常這種(zhong)桿(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)(liang)都在(zai)(zai)(zai)(zai)10—50ppm以(yi)下(xia),最低(di)可達1-2ppm,從組織上看,低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態,存在(zai)(zai)(zai)(zai)于晶(jing)粒邊界附近,這對低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)而言可以(yi)說(shuo)是常見的(de)(de)(de)(de)但對無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則很(hen)(hen)少(shao)見。氧(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)(zai)晶(jing)界出現對材(cai)料(liao)的(de)(de)(de)(de)韌性(xing)產(chan)生負面影響。而無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)很(hen)(hen)低(di),所以(yi)這種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)組織是均勻的(de)(de)(de)(de)單相(xiang)組織對韌性(xing)有(you)利。在(zai)(zai)(zai)(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)(de)(de)多孔性(xing)是不常見的(de)(de)(de)(de),而在(zai)(zai)(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中則是常見的(de)(de)(de)(de)一(yi)種(zhong)缺(que)陷。
二(er)、熱軋組織和鑄造組織的區別
低氧(yang)(yang)銅(tong)(tong)(tong)桿由(you)于經過熱(re)軋,所(suo)以(yi)其組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)屬熱(re)加工組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi),原來的(de)鑄(zhu)造(zao)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)已經破碎(sui),在(zai)8mm的(de)桿時(shi)已有再(zai)結晶(jing)(jing)(jing)(jing)的(de)形式出現,而(er)無氧(yang)(yang)銅(tong)(tong)(tong)桿屬鑄(zhu)造(zao)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi),晶(jing)(jing)(jing)(jing)粒(li)粗大,這(zhe)是為(wei)什么(me),無氧(yang)(yang)銅(tong)(tong)(tong)的(de)再(zai)結晶(jing)(jing)(jing)(jing)溫度較(jiao)(jiao)高(gao),需要較(jiao)(jiao)高(gao)退(tui)(tui)火溫度的(de)固有原因。這(zhe)是因為(wei),再(zai)結晶(jing)(jing)(jing)(jing)發生(sheng)在(zai)晶(jing)(jing)(jing)(jing)粒(li)邊界(jie)附近,無氧(yang)(yang)銅(tong)(tong)(tong)桿組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)晶(jing)(jing)(jing)(jing)粒(li)粗大,晶(jing)(jing)(jing)(jing)粒(li)尺寸甚至能達幾個毫米(mi),因而(er)晶(jing)(jing)(jing)(jing)粒(li)邊界(jie)少,即使(shi)通過拉制(zhi)變形,但晶(jing)(jing)(jing)(jing)粒(li)邊界(jie)相對(dui)(dui)低氧(yang)(yang)銅(tong)(tong)(tong)桿還(huan)是較(jiao)(jiao)少,所(suo)以(yi)需要較(jiao)(jiao)高(gao)的(de)退(tui)(tui)火功率。對(dui)(dui)無氧(yang)(yang)銅(tong)(tong)(tong)成功的(de)退(tui)(tui)火要求(qiu)是:由(you)桿經拉制(zhi),但尚(shang)未鑄(zhu)造(zao)組(zu)(zu)(zu)(zu)織(zhi)(zhi)(zhi)的(de)線(xian)時(shi)的(de)第一次退(tui)(tui)火,其退(tui)(tui)火功率應(ying)比(bi)同樣情(qing)況的(de)低氧(yang)(yang)銅(tong)(tong)(tong)高(gao)10——15%。經繼續拉制(zhi),在(zai)以(yi)后階段(duan)的(de)退(tui)(tui)火功率應(ying)留(liu)有足夠(gou)的(de)余量和(he)(he)對(dui)(dui)低氧(yang)(yang)銅(tong)(tong)(tong)和(he)(he)無氧(yang)(yang)銅(tong)(tong)(tong)切實區別執行不(bu)同的(de)退(tui)(tui)火工藝,以(yi)保證在(zai)制(zhi)品和(he)(he)成品導線(xian)的(de)柔(rou)軟性。
三、夾雜(za),氧(yang)含量波動,表面(mian)氧(yang)化物和可能存在的(de)(de)熱軋缺(que)陷的(de)(de)差(cha)別
無氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)(de)(de)可拉性在所(suo)有線徑里(li)與(yu)低氧(yang)(yang)(yang)銅(tong)桿(gan)相比都是優越(yue)的(de)(de)(de),除(chu)上述組(zu)織原(yuan)(yuan)因(yin)外(wai)(wai),無氧(yang)(yang)(yang)銅(tong)桿(gan)夾(jia)雜(za)少(shao),含(han)氧(yang)(yang)(yang)量(liang)穩(wen)(wen)定,無熱軋可能產生的(de)(de)(de)缺陷(xian),桿(gan)表(biao)氧(yang)(yang)(yang)化物厚度可達≤15A。在連(lian)鑄連(lian)軋生產過(guo)程中(zhong)如果(guo)工藝不(bu)穩(wen)(wen)定,對氧(yang)(yang)(yang)監控不(bu)嚴,含(han)氧(yang)(yang)(yang)量(liang)不(bu)穩(wen)(wen)定將直(zhi)接影響桿(gan)的(de)(de)(de)性能。如果(guo)桿(gan)的(de)(de)(de)表(biao)面(mian)氧(yang)(yang)(yang)化物能在后工序(xu)的(de)(de)(de)連(lian)續清洗(xi)中(zhong)得以彌補(bu)外(wai)(wai),但比較麻(ma)煩的(de)(de)(de)是有相當多的(de)(de)(de)氧(yang)(yang)(yang)化物存在于“皮(pi)(pi)(pi)下(xia)”,對拉線斷線影響更(geng)直(zhi)接,故而在拉制微細(xi)(xi)線,超微細(xi)(xi)線時,為了減少(shao)斷線,有時要對銅(tong)桿(gan)采取不(bu)得已(yi)的(de)(de)(de)辦法(fa)——剝(bo)皮(pi)(pi)(pi),甚至二次剝(bo)皮(pi)(pi)(pi)的(de)(de)(de)原(yuan)(yuan)因(yin)所(suo)在,目的(de)(de)(de)要除(chu)去皮(pi)(pi)(pi)下(xia)氧(yang)(yang)(yang)化物。
四、低氧銅(tong)桿(gan)和無氧銅(tong)桿(gan)的(de)韌(ren)性有差別
兩者都可(ke)以拉到0.015mm,但在(zai)低(di)溫超(chao)導線中的低(di)溫級(ji)無氧銅,其細絲間的間距(ju)只有(you)0.001mm.
五、從制桿的原(yuan)材料到制線的經濟性有差別(bie)。
制(zhi)造無氧(yang)銅桿(gan)(gan)要求質(zhi)量較(jiao)高的原(yuan)材料。一般,拉制(zhi)直徑>1mm的銅線(xian)時,低氧(yang)銅桿(gan)(gan)的優(you)點(dian)比較(jiao)明顯(xian),而(er)無氧(yang)銅桿(gan)(gan)顯(xian)得更為(wei)優(you)越的是拉制(zhi)直徑<0.5mm的銅線(xian)。
六、低氧(yang)銅(tong)桿的制線工藝與無氧(yang)銅(tong)桿的有(you)所(suo)不同。
低氧(yang)(yang)銅桿的(de)(de)(de)(de)制(zhi)(zhi)線工藝(yi)(yi)不能照搬到無氧(yang)(yang)銅桿的(de)(de)(de)(de)制(zhi)(zhi)線工藝(yi)(yi)上(shang)來,至少兩(liang)者(zhe)的(de)(de)(de)(de)退火(huo)工藝(yi)(yi)是不同的(de)(de)(de)(de)。因為線的(de)(de)(de)(de)柔軟(ruan)性深(shen)受材料成(cheng)份和制(zhi)(zhi)桿,制(zhi)(zhi)線和退火(huo)工藝(yi)(yi)的(de)(de)(de)(de)影響,不能簡單(dan)地(di)說低氧(yang)(yang)銅或(huo)無氧(yang)(yang)銅誰軟(ruan)誰硬。
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