熱門(men)關(guan)鍵(jian)詞(ci):
來(lai)源:行業動態 閱讀:109548 發布時間(jian):2019-07-05
導讀(du):由于生(sheng)產(chan)銅桿(gan)(gan)的兩者的工藝不同,所生(sheng)產(chan)的銅桿(gan)(gan)中的含氧(yang)量(liang)及外(wai)觀就不同。上引生(sheng)產(chan)的銅桿(gan)(gan),工藝得當(dang)氧(yang)含量(liang)在10ppm以(yi)下,叫無氧(yang)銅桿(gan)(gan);連鑄連鑄生(sheng)產(chan)的銅桿(gan)(gan) 是在保(bao)護(hu)條件下的熱軋,氧(yang)含量(liang)在200-500ppm范(fan)圍內,但有(you)時(shi)也高達700ppm以(yi)上,一般(ban)情況下,此種(zhong)方(fang)法生(sheng)產(chan)的銅外(wai)表光亮,低(di)氧(yang)銅桿(gan)(gan),有(you)時(shi)也叫光桿(gan)(gan)。
銅(tong)桿是電纜行(xing)業(ye)的(de)(de)主要(yao)原料(liao),生產(chan)的(de)(de)方式主要(yao)有(you)兩種——連(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)(lian)軋(ya)法(fa)和(he)上(shang)引(yin)連(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)法(fa)。連(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)(lian)軋(ya)低氧(yang)(yang)(yang)銅(tong)桿的(de)(de)生產(chan)方法(fa)較多,其(qi)特點(dian)是金(jin)(jin)屬在豎爐中(zhong)(zhong)融(rong)化后(hou),銅(tong)液通過保溫爐、溜槽、中(zhong)(zhong)間包,從澆管進(jin)(jin)入封閉(bi)的(de)(de)模腔(qiang)內(nei),采用(yong)較大(da)的(de)(de)冷(leng)(leng)卻強(qiang)度進(jin)(jin)行(xing)冷(leng)(leng)卻,形(xing)(xing)成鑄(zhu)(zhu)(zhu)坯,然后(hou)進(jin)(jin)行(xing)多道次軋(ya)制(zhi),生產(chan)的(de)(de)低氧(yang)(yang)(yang)銅(tong)桿為熱加(jia)工組(zu)織,原來的(de)(de)鑄(zhu)(zhu)(zhu)造(zao)組(zu)織已(yi)經破碎,含氧(yang)(yang)(yang)量(liang)一般(ban)(ban)為200~400ppm之(zhi)(zhi)間。無氧(yang)(yang)(yang)銅(tong)桿國內(nei)基本全部采用(yong)上(shang)引(yin)連(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)法(fa)生產(chan),金(jin)(jin)屬在感應電爐中(zhong)(zhong)融(rong)化后(hou)通過石墨模進(jin)(jin)行(xing)上(shang)引(yin)連(lian)(lian)(lian)續鑄(zhu)(zhu)(zhu)造(zao),之(zhi)(zhi)后(hou)進(jin)(jin)行(xing)冷(leng)(leng)軋(ya)或冷(leng)(leng)加(jia)工,生產(chan)的(de)(de)無氧(yang)(yang)(yang)銅(tong)桿為鑄(zhu)(zhu)(zhu)造(zao)組(zu)織,含氧(yang)(yang)(yang)量(liang)一般(ban)(ban)在20ppm以下。由于制(zhi)造(zao)工藝的(de)(de)不同,所以在組(zu)織結構(gou)、氧(yang)(yang)(yang)含量(liang)分(fen)布(bu)、雜質的(de)(de)形(xing)(xing)式及分(fen)布(bu)等諸多方面有(you)較大(da)差(cha)別。
一、拉制性能
銅桿的(de)拉制(zhi)性能跟很(hen)多因(yin)素有關,如雜質(zhi)的(de)含量、氧含量及分布、工藝控制(zhi)等。下面分別從以(yi)上(shang)幾個方面對銅桿的(de)拉制(zhi)性能進(jin)行分析。
1、熔化方式對S等雜質的影響
連(lian)(lian)鑄連(lian)(lian)軋(ya)生(sheng)產銅(tong)桿(gan)主(zhu)要是通過(guo)氣體的燃燒(shao)使銅(tong)桿(gan)熔化(hua),在燃燒(shao)的過(guo)程中,通過(guo)氧化(hua)和揮發作用,可(ke)一定程度(du)減(jian)少部分雜質進入銅(tong)液,因此連(lian)(lian)鑄連(lian)(lian)軋(ya)法對原料要求相(xiang)對低一些。上引連(lian)(lian)鑄生(sheng)產無氧銅(tong)桿(gan),由于是用感應電(dian)爐熔化(hua),電(dian)解銅(tong)表面的“銅(tong)綠”“銅(tong)豆”基(ji)本都熔入到銅(tong)液中。其中熔入的S對無氧銅(tong)桿(gan)塑(su)性影響(xiang)極(ji)大,會增加拉(la)絲斷(duan)線率。
2、鑄造過程中雜質(zhi)的進入
在生(sheng)產(chan)過(guo)(guo)程中(zhong),連鑄連軋工(gong)(gong)藝(yi)需通(tong)過(guo)(guo)保溫爐、溜(liu)槽、中(zhong)間包轉(zhuan)運銅液(ye),相對(dui)容易造(zao)(zao)成耐火(huo)(huo)材料的剝落,在軋制過(guo)(guo)程中(zhong)需要通(tong)過(guo)(guo)軋輥,造(zao)(zao)成鐵(tie)質(zhi)的脫落,會(hui)給(gei)銅桿造(zao)(zao)成外部(bu)夾雜。而熱軋中(zhong)皮上和(he)皮下氧化物的軋入,會(hui)給(gei)低氧桿的拉絲造(zao)(zao)成不(bu)利的影響。上引(yin)連鑄法生(sheng)產(chan)工(gong)(gong)藝(yi)流程較短,銅液(ye)是(shi)通(tong)過(guo)(guo)聯體爐內(nei)潛流式完成,對(dui)耐火(huo)(huo)材料的沖擊不(bu)大,結晶是(shi)通(tong)過(guo)(guo)石(shi)墨模內(nei)進行,所以過(guo)(guo)程中(zhong)可能產(chan)生(sheng)的污染(ran)源較少(shao)(shao),雜質(zhi)進入的機會(hui)較少(shao)(shao)。
O、S、P是(shi)與銅(tong)(tong)(tong)會生(sheng)產化(hua)合物的(de)元素。在熔態銅(tong)(tong)(tong)中(zhong),氧(yang)(yang)(yang)可(ke)以(yi)溶(rong)解一部(bu)分,但當銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)(yang)幾乎不(bu)溶(rong)解于銅(tong)(tong)(tong)中(zhong)。熔態時所溶(rong)解的(de)氧(yang)(yang)(yang),以(yi)銅(tong)(tong)(tong)=氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共晶體析(xi)出(chu),分布在晶粒(li)晶界處。銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共晶體的(de)出(chu)現,顯著降低了銅(tong)(tong)(tong)的(de)塑性。
硫(liu)可以溶解在(zai)熔(rong)體的(de)銅中,但在(zai)室溫下,其(qi)溶解度(du)幾乎(hu)降低到零,它以硫(liu)化亞銅的(de)形(xing)式出現(xian)在(zai)晶粒晶界處(chu),會顯著降低銅的(de)塑性。
3、氧在(zai)低氧銅(tong)桿和(he)無氧銅(tong)桿中分布形式及其影響
氧(yang)含(han)量對(dui)低氧(yang)銅桿的(de)(de)拉(la)線性能有著明顯的(de)(de)影響。當氧(yang)含(han)量增加到(dao)最佳值時(shi),銅桿的(de)(de)斷線率(lv)最低。這是因為氧(yang)在與大(da)部分雜質反(fan)應的(de)(de)過程中都起到(dao)了清除(chu)器的(de)(de)作(zuo)用。適度的(de)(de)氧(yang)還有利于(yu)去除(chu)銅液中的(de)(de)氫,生(sheng)成水蒸(zheng)氣溢出(chu),減少氣孔(kong)的(de)(de)形成。最佳的(de)(de)氧(yang)含(han)量為拉(la)線工藝提供了最好的(de)(de)條(tiao)件。
低氧(yang)銅桿(gan)(gan)氧(yang)化(hua)(hua)(hua)物(wu)(wu)的(de)(de)(de)(de)(de)分(fen)布(bu)(bu)(bu):在(zai)連續(xu)澆鑄中(zhong)凝固(gu)的(de)(de)(de)(de)(de)最初階段,散(san)熱速率和均(jun)勻冷卻(que)是決定(ding)銅桿(gan)(gan)氧(yang)化(hua)(hua)(hua)物(wu)(wu)分(fen)布(bu)(bu)(bu)的(de)(de)(de)(de)(de)主(zhu)要因素。不(bu)均(jun)勻冷卻(que)會(hui)引起銅桿(gan)(gan)內部結(jie)構本(ben)質上的(de)(de)(de)(de)(de)差異,但后續(xu)的(de)(de)(de)(de)(de)熱加(jia)工,柱(zhu)狀晶(jing)通常(chang)會(hui)遭(zao)到破(po)壞,使氧(yang)化(hua)(hua)(hua)亞(ya)銅顆(ke)(ke)粒(li)細微化(hua)(hua)(hua)和均(jun)勻分(fen)布(bu)(bu)(bu)。氧(yang)化(hua)(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)聚集而產生(sheng)的(de)(de)(de)(de)(de)典型情況是中(zhong)心爆(bao)裂。除氧(yang)化(hua)(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)分(fen)布(bu)(bu)(bu)的(de)(de)(de)(de)(de)影響(xiang)外,具有較(jiao)小氧(yang)化(hua)(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)的(de)(de)(de)(de)(de)銅桿(gan)(gan)顯(xian)示出(chu)較(jiao)好的(de)(de)(de)(de)(de)拉線特性,較(jiao)大的(de)(de)(de)(de)(de)Cu2O顆(ke)(ke)粒(li)容易造成應力(li)集中(zhong)點而斷裂。
無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)(yang)量超標,銅(tong)(tong)(tong)桿(gan)變(bian)(bian)脆(cui),延(yan)伸(shen)率下降(jiang),拉伸(shen)式(shi)樣端口顯(xian)暗紅色,結晶組織(zhi)疏(shu)松。當(dang)氧(yang)(yang)(yang)含量超出8ppm時,工藝性(xing)(xing)能變(bian)(bian)差,表現(xian)為鑄造及拉伸(shen)過程中斷(duan)桿(gan)及斷(duan)線率極具(ju)增高(gao)(gao)。這是由于氧(yang)(yang)(yang)能與銅(tong)(tong)(tong)生成(cheng)氧(yang)(yang)(yang)化亞銅(tong)(tong)(tong)脆(cui)性(xing)(xing)相(xiang),形成(cheng)銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化亞銅(tong)(tong)(tong)共晶體,以網(wang)狀組織(zhi)分布在(zai)(zai)境界(jie)上(shang)。這種脆(cui)性(xing)(xing)相(xiang)硬度高(gao)(gao),在(zai)(zai)冷變(bian)(bian)形時將會與銅(tong)(tong)(tong)機(ji)體脫(tuo)離,導(dao)致銅(tong)(tong)(tong)桿(gan)的機(ji)械(xie)性(xing)(xing)能下降(jiang),在(zai)(zai)后續(xu)加工中容易造成(cheng)斷(duan)裂現(xian)象。氧(yang)(yang)(yang)含量高(gao)(gao)還能導(dao)致無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)導(dao)電率下降(jiang)。因(yin)此,必(bi)須嚴格控制上(shang)引連鑄工藝及產品質量。
4、氫的影響
在上(shang)引連(lian)鑄中,氧含(han)量控制較低,氧化物的(de)副作用唄**降低,但氫的(de)影響成(cheng)為較顯(xian)著的(de)問題。吸氣后熔體中存在平衡反應:H2O(g)=[O]+2[H];
氣(qi)體(ti)及疏松是(shi)(shi)在(zai)結晶的過(guo)程(cheng)中(zhong),氫(qing)從(cong)過(guo)飽和(he)的溶(rong)液中(zhong)析出(chu)并聚(ju)集(ji)而形(xing)成(cheng)的。在(zai)結晶前析出(chu)的氫(qing)又可(ke)還(huan)原氧化亞(ya)銅而生成(cheng)水(shui)氣(qi)泡。由于(yu)上(shang)引鑄造的特點是(shi)(shi)銅液自上(shang)而下(xia)的結晶,形(xing)成(cheng)的液**形(xing)狀近似錐型。銅液結晶前析出(chu)的氣(qi)體(ti)在(zai)上(shang)浮過(guo)程(cheng)中(zhong)被堵(du)在(zai)凝(ning)固組織內(nei)(nei),結晶時在(zai)鑄桿內(nei)(nei)形(xing)成(cheng)氣(qi)孔。上(shang)引的含氣(qi)量少時,析出(chu)的氫(qing)存在(zai)于(yu)晶界處,形(xing)成(cheng)疏松;含氣(qi)量多時,則(ze)聚(ju)集(ji)成(cheng)氣(qi)孔,因(yin)此,氣(qi)孔和(he)疏松是(shi)(shi)氫(qing)氣(qi)和(he)水(shui)蒸氣(qi)兩者形(xing)成(cheng)的。
氫來源于上引(yin)生產過程中的各個工藝環節,如原料電解銅(tong)的“銅(tong)綠(lv)”、輔(fu)料木炭(tan)**、氣候(hou)環境**、石墨(mo)結晶器(qi)未干燥等。因此,熔化爐中的銅(tong)液表面應覆蓋經烘烤(kao)的木炭(tan),電解銅(tong)應盡(jin)量(liang)去除“銅(tong)綠(lv)”、“銅(tong)豆(dou)”“耳朵”,對提高無氧(yang)銅(tong)桿質(zhi)量(liang)非常重要。
在連鑄連軋工藝(yi)中(zhong),往往采用適度控制(zhi)氧含量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于銅液在(zai)鑄造過(guo)程中(zhong)是自下(xia)而上(shang)結晶,銅液中(zhong)的氧和氫(qing)所產生的水蒸氣很(hen)容易上(shang)浮跑出,銅液中(zhong)的氫(qing)大部分能被有效去除,因(yin)而對銅桿(gan)的影(ying)響(xiang)較小。
二、表面質量
在(zai)生產電磁線等產品的(de)(de)過程(cheng)中,對(dui)銅桿(gan)的(de)(de)表(biao)面質(zhi)(zhi)量(liang)也需提出要(yao)求。需要(yao)拉制后(hou)的(de)(de)銅絲表(biao)面無(wu)毛刺、銅粉少、無(wu)油污。并通過扭轉(zhuan)試(shi)驗測量(liang)表(biao)面銅粉的(de)(de)質(zhi)(zhi)量(liang)和扭轉(zhuan)后(hou)觀察銅桿(gan)的(de)(de)復(fu)原情況來判定其好壞。
在連(lian)鑄(zhu)連(lian)軋(ya)(ya)過程中,從(cong)鑄(zhu)造到(dao)軋(ya)(ya)制前,溫度高,完全暴露于空氣中,使鑄(zhu)坯表面(mian)形成(cheng)較(jiao)厚的(de)氧(yang)化(hua)(hua)層,在軋(ya)(ya)制過程中,隨著軋(ya)(ya)輥的(de)轉動,氧(yang)化(hua)(hua)物顆粒(li)軋(ya)(ya)入銅(tong)線表面(mian)。由于氧(yang)化(hua)(hua)亞銅(tong)是高熔(rong)點脆性化(hua)(hua)合物,對于軋(ya)(ya)入較(jiao)深的(de)氧(yang)化(hua)(hua)亞銅(tong),當成(cheng)條(tiao)狀的(de)聚集物遇(yu)模具拉伸時,就會是銅(tong)桿外表面(mian)產生毛刺,給(gei)后續的(de)涂漆造成(cheng)麻(ma)煩。
而(er)上(shang)(shang)引連鑄工藝制(zhi)造的無氧(yang)銅(tong)桿,由于鑄造和冷卻完全與氧(yang)隔絕,后續亦無熱軋(ya)過程,銅(tong)桿表面無軋(ya)入表面的氧(yang)化物,質量(liang)較(jiao)好,拉制(zhi)后銅(tong)粉(fen)少,上(shang)(shang)述(shu)問題較(jiao)少存(cun)在。
無氧銅(tong)(tong)桿也分進口設備(bei)做的(de)(de)和國(guo)產(chan)(chan)設備(bei)做的(de)(de),但目前(qian)進口產(chan)(chan)品已無明顯優勢(shi),銅(tong)(tong)桿產(chan)(chan)品出(chu)來后區別不是(shi)很大,只(zhi)要銅(tong)(tong)板(ban)選(xuan)的(de)(de)好,生產(chan)(chan)控制比較穩(wen)定,國(guo)產(chan)(chan)設備(bei)也能產(chan)(chan)出(chu)可(ke)拉伸0.05的(de)(de)銅(tong)(tong)桿.進口設備(bei)一般是(shi)芬蘭奧托昆普的(de)(de)設備(bei),國(guo)產(chan)(chan)設備(bei)最(zui)好的(de)(de)應該是(shi)上海(hai)(hai)的(de)(de)海(hai)(hai)軍廠的(de)(de)了,生產(chan)(chan)時間最(zui)長,軍工企(qi)業,質量可(ke)靠。
低氧銅桿進口設(she)備國際主(zhu)要有兩(liang)種,一種是(shi)美國南線(xian)設(she)備,英文是(shi)SOUTHWIRE,國內(nei)(nei)廠(chang)家(jia)是(shi)南京華新,江(jiang)西銅業,另一種是(shi)德國CONTIROD設(she)備,國內(nei)(nei)廠(chang)家(jia)是(shi)常(chang)州(zhou)金(jin)源,天津大無縫。
無(wu)(wu)氧(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)(yang)量(liang)(liang)上容(rong)易區別,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)是(shi)含氧(yang)(yang)(yang)量(liang)(liang)在(zai)(zai)10-20個(ge)PPM以(yi)下,但目前有的(de)(de)(de)(de)廠家只能(neng)做到50個(ge)PPM以(yi)下.低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)(de)(de)桿(gan)(gan)(gan)子一般含氧(yang)(yang)(yang)量(liang)(liang)控制在(zai)(zai)250個(ge)PPM左右,無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)一般采取的(de)(de)(de)(de)是(shi)上引法,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)連鑄連軋,兩(liang)種產品(pin)相(xiang)對而(er)言(yan)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對漆包線(xian)(xian)性(xing) 能(neng)更適應些,如柔軟性(xing),回(hui)彈角,繞(rao)線(xian)(xian)性(xing)能(neng).但低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對拉(la)絲條件相(xiang)對要苛刻些,同樣拉(la)伸(shen)0.2的(de)(de)(de)(de)細絲,如果伸(shen)線(xian)(xian)條件不(bu)好,普通的(de)(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)而(er)好的(de)(de)(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就斷 線(xian)(xian),但如果放在(zai)(zai)好的(de)(de)(de)(de)伸(shen)線(xian)(xian)條件,同樣的(de)(de)(de)(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不(bu)定就能(neng)拉(la)到雙(shuang)零(ling)五,而(er)普通無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)最(zui)多只能(neng)拉(la)伸(shen)到0.1而(er)已,當(dang)然做的(de)(de)(de)(de)最(zui)細的(de)(de)(de)(de)如雙(shuang)零(ling)二卻非得依靠進口(kou)的(de)(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)了.目前有企業嘗試(shi)用剝皮的(de)(de)(de)(de)方式(shi)來處理低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)0.03線(xian)(xian).但有關這(zhe)方面的(de)(de)(de)(de)內容(rong)我還不(bu)是(shi)很清楚。
音響線一般(ban)反(fan)而喜歡(huan)用無氧桿,這和無氧桿是單晶銅,低氧桿是多晶銅有關。
氧銅桿(gan)和無氧銅桿(gan)由于制造(zao)方法(fa)的不同(tong),致(zhi)使存(cun)在差別,具有各自的特點(dian)。
一、關于氧的吸入和脫去以及它的存在(zai)狀態(tai)
生產銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)(yi)般在(zai)10—50ppm,在(zai)常(chang)(chang)溫下氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)中的(de)(de)(de)(de)固溶度約2ppm。低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)(yi)般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進(jin)入是在(zai)銅(tong)(tong)(tong)的(de)(de)(de)(de)液態下吸入的(de)(de)(de)(de),而(er)上引法無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則相反(fan),氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液態銅(tong)(tong)(tong)下保持相當時間后,被(bei)還原而(er)脫去,通常(chang)(chang)這種(zhong)桿(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量都在(zai)10—50ppm以(yi)下,最低(di)(di)可達1-2ppm,從組(zu)織上看,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)狀態,存在(zai)于晶粒(li)邊界附近,這對(dui)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)而(er)言可以(yi)說是常(chang)(chang)見的(de)(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則很少見。氧(yang)(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)以(yi)夾雜形式在(zai)晶界出現對(dui)材料的(de)(de)(de)(de)韌(ren)性產生負面影響。而(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)很低(di)(di),所以(yi)這種(zhong)銅(tong)(tong)(tong)的(de)(de)(de)(de)組(zu)織是均勻(yun)的(de)(de)(de)(de)單(dan)相組(zu)織對(dui)韌(ren)性有利。在(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中的(de)(de)(de)(de)多孔性是不常(chang)(chang)見的(de)(de)(de)(de),而(er)在(zai)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中則是常(chang)(chang)見的(de)(de)(de)(de)一(yi)(yi)種(zhong)缺陷(xian)。
二、熱(re)軋組織(zhi)和(he)鑄造(zao)組織(zhi)的區別
低氧(yang)(yang)(yang)銅(tong)桿(gan)由于(yu)經過熱軋(ya),所以(yi)其組(zu)織(zhi)(zhi)屬熱加(jia)工(gong)(gong)組(zu)織(zhi)(zhi),原來的(de)(de)(de)(de)鑄造組(zu)織(zhi)(zhi)已(yi)經破碎,在8mm的(de)(de)(de)(de)桿(gan)時已(yi)有再(zai)結(jie)晶(jing)(jing)(jing)的(de)(de)(de)(de)形(xing)(xing)式(shi)出現,而(er)無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)屬鑄造組(zu)織(zhi)(zhi),晶(jing)(jing)(jing)粒(li)粗大,這(zhe)是為什么,無(wu)氧(yang)(yang)(yang)銅(tong)的(de)(de)(de)(de)再(zai)結(jie)晶(jing)(jing)(jing)溫(wen)度較(jiao)高(gao)(gao),需(xu)要較(jiao)高(gao)(gao)退(tui)(tui)(tui)火(huo)溫(wen)度的(de)(de)(de)(de)固(gu)有原因。這(zhe)是因為,再(zai)結(jie)晶(jing)(jing)(jing)發生(sheng)在晶(jing)(jing)(jing)粒(li)邊界附(fu)近(jin),無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)組(zu)織(zhi)(zhi)晶(jing)(jing)(jing)粒(li)粗大,晶(jing)(jing)(jing)粒(li)尺(chi)寸(cun)甚至能達(da)幾個毫米,因而(er)晶(jing)(jing)(jing)粒(li)邊界少(shao),即使(shi)通過拉制(zhi)變(bian)形(xing)(xing),但晶(jing)(jing)(jing)粒(li)邊界相對低氧(yang)(yang)(yang)銅(tong)桿(gan)還是較(jiao)少(shao),所以(yi)需(xu)要較(jiao)高(gao)(gao)的(de)(de)(de)(de)退(tui)(tui)(tui)火(huo)功率(lv)。對無(wu)氧(yang)(yang)(yang)銅(tong)成功的(de)(de)(de)(de)退(tui)(tui)(tui)火(huo)要求(qiu)是:由桿(gan)經拉制(zhi),但尚未(wei)鑄造組(zu)織(zhi)(zhi)的(de)(de)(de)(de)線時的(de)(de)(de)(de)第一(yi)次退(tui)(tui)(tui)火(huo),其退(tui)(tui)(tui)火(huo)功率(lv)應比(bi)同樣(yang)情況的(de)(de)(de)(de)低氧(yang)(yang)(yang)銅(tong)高(gao)(gao)10——15%。經繼(ji)續拉制(zhi),在以(yi)后階段的(de)(de)(de)(de)退(tui)(tui)(tui)火(huo)功率(lv)應留有足夠的(de)(de)(de)(de)余量和對低氧(yang)(yang)(yang)銅(tong)和無(wu)氧(yang)(yang)(yang)銅(tong)切實(shi)區(qu)別執行不同的(de)(de)(de)(de)退(tui)(tui)(tui)火(huo)工(gong)(gong)藝,以(yi)保(bao)證在制(zhi)品(pin)和成品(pin)導線的(de)(de)(de)(de)柔軟性。
三、夾雜,氧含(han)量波動,表面氧化物和可能存在的熱(re)軋缺陷的差別
無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)(de)可拉(la)性在(zai)(zai)所(suo)有線徑里與低氧(yang)(yang)銅(tong)桿(gan)(gan)相比都是優越的(de)(de)(de),除(chu)上述組織原因(yin)外,無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)夾雜少(shao),含氧(yang)(yang)量(liang)穩定(ding),無(wu)熱軋(ya)可能(neng)產(chan)生(sheng)(sheng)的(de)(de)(de)缺陷,桿(gan)(gan)表氧(yang)(yang)化物厚度可達≤15A。在(zai)(zai)連鑄連軋(ya)生(sheng)(sheng)產(chan)過程中(zhong)如(ru)果(guo)工藝不(bu)穩定(ding),對(dui)氧(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)量(liang)不(bu)穩定(ding)將直(zhi)接影(ying)響桿(gan)(gan)的(de)(de)(de)性能(neng)。如(ru)果(guo)桿(gan)(gan)的(de)(de)(de)表面氧(yang)(yang)化物能(neng)在(zai)(zai)后工序的(de)(de)(de)連續清洗中(zhong)得以(yi)彌補外,但比較麻煩(fan)的(de)(de)(de)是有相當多(duo)的(de)(de)(de)氧(yang)(yang)化物存(cun)在(zai)(zai)于“皮(pi)(pi)下(xia)”,對(dui)拉(la)線斷線影(ying)響更直(zhi)接,故而在(zai)(zai)拉(la)制微細(xi)線,超微細(xi)線時(shi),為了減少(shao)斷線,有時(shi)要對(dui)銅(tong)桿(gan)(gan)采取不(bu)得已的(de)(de)(de)辦法(fa)——剝(bo)皮(pi)(pi),甚至二次剝(bo)皮(pi)(pi)的(de)(de)(de)原因(yin)所(suo)在(zai)(zai),目(mu)的(de)(de)(de)要除(chu)去皮(pi)(pi)下(xia)氧(yang)(yang)化物。
四、低氧銅桿和無氧銅桿的韌(ren)性有(you)差別
兩(liang)者都可以拉到0.015mm,但在低溫(wen)超導線中的低溫(wen)級無氧銅,其細絲間的間距只有0.001mm.
五、從制桿的(de)原材料到制線的(de)經濟性有(you)差別。
制(zhi)造無(wu)氧銅桿要求質量較(jiao)高的(de)原材料。一(yi)般,拉制(zhi)直徑(jing)(jing)>1mm的(de)銅線時(shi),低氧銅桿的(de)優點(dian)比較(jiao)明(ming)顯(xian),而無(wu)氧銅桿顯(xian)得更為優越的(de)是(shi)拉制(zhi)直徑(jing)(jing)<0.5mm的(de)銅線。
六、低氧銅桿的制線工藝與無氧銅桿的有所不同。
低氧(yang)銅(tong)桿的(de)(de)制線(xian)(xian)工(gong)藝不能照搬到無氧(yang)銅(tong)桿的(de)(de)制線(xian)(xian)工(gong)藝上來,至少兩者的(de)(de)退火工(gong)藝是(shi)不同的(de)(de)。因為線(xian)(xian)的(de)(de)柔軟性深(shen)受材料成份和制桿,制線(xian)(xian)和退火工(gong)藝的(de)(de)影響(xiang),不能簡單地說低氧(yang)銅(tong)或(huo)無氧(yang)銅(tong)誰軟誰硬。
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