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來源:行(xing)業(ye)動態 閱讀(du):109306 發(fa)布時(shi)間:2019-07-05
導讀:由(you)于(yu)生產(chan)銅桿(gan)的(de)兩者的(de)工藝不(bu)同(tong),所(suo)生產(chan)的(de)銅桿(gan)中的(de)含氧(yang)量及外觀就不(bu)同(tong)。上(shang)引生產(chan)的(de)銅桿(gan),工藝得當氧(yang)含量在10ppm以(yi)下,叫無(wu)氧(yang)銅桿(gan);連鑄連鑄生產(chan)的(de)銅桿(gan) 是在保(bao)護條件(jian)下的(de)熱軋,氧(yang)含量在200-500ppm范圍內(nei),但有(you)時(shi)(shi)也高達(da)700ppm以(yi)上(shang),一般情況下,此(ci)種方法生產(chan)的(de)銅外表光亮,低氧(yang)銅桿(gan),有(you)時(shi)(shi)也叫光桿(gan)。
銅(tong)桿(gan)是電纜(lan)行(xing)(xing)業的(de)主要原料,生(sheng)產(chan)的(de)方(fang)式(shi)主要有(you)兩種——連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)(ya)法(fa)和上(shang)引(yin)連(lian)(lian)鑄(zhu)法(fa)。連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)(ya)低氧(yang)銅(tong)桿(gan)的(de)生(sheng)產(chan)方(fang)法(fa)較(jiao)多,其特點是金(jin)屬(shu)在(zai)豎爐(lu)中融(rong)化后(hou)(hou),銅(tong)液通過保溫爐(lu)、溜槽、中間包,從澆管進(jin)入封閉(bi)的(de)模腔內,采用較(jiao)大的(de)冷(leng)卻(que)強度進(jin)行(xing)(xing)冷(leng)卻(que),形(xing)成鑄(zhu)坯,然(ran)后(hou)(hou)進(jin)行(xing)(xing)多道次軋(ya)(ya)制,生(sheng)產(chan)的(de)低氧(yang)銅(tong)桿(gan)為熱加工(gong)組(zu)織(zhi),原來(lai)的(de)鑄(zhu)造(zao)組(zu)織(zhi)已經破(po)碎,含(han)氧(yang)量(liang)(liang)一般為200~400ppm之(zhi)間。無氧(yang)銅(tong)桿(gan)國內基本全部采用上(shang)引(yin)連(lian)(lian)鑄(zhu)法(fa)生(sheng)產(chan),金(jin)屬(shu)在(zai)感應電爐(lu)中融(rong)化后(hou)(hou)通過石墨(mo)模進(jin)行(xing)(xing)上(shang)引(yin)連(lian)(lian)續鑄(zhu)造(zao),之(zhi)后(hou)(hou)進(jin)行(xing)(xing)冷(leng)軋(ya)(ya)或冷(leng)加工(gong),生(sheng)產(chan)的(de)無氧(yang)銅(tong)桿(gan)為鑄(zhu)造(zao)組(zu)織(zhi),含(han)氧(yang)量(liang)(liang)一般在(zai)20ppm以下(xia)。由(you)于(yu)制造(zao)工(gong)藝的(de)不同,所以在(zai)組(zu)織(zhi)結構、氧(yang)含(han)量(liang)(liang)分(fen)(fen)布、雜質的(de)形(xing)式(shi)及分(fen)(fen)布等(deng)諸多方(fang)面有(you)較(jiao)大差別(bie)。
一、拉制性能
銅(tong)桿(gan)的拉制性能跟很多因素有關,如雜(za)質的含量、氧(yang)含量及分(fen)(fen)布、工藝控制等(deng)。下面分(fen)(fen)別從(cong)以(yi)上幾個方面對(dui)銅(tong)桿(gan)的拉制性能進(jin)行分(fen)(fen)析。
1、熔化方式對S等(deng)雜質的影響
連(lian)(lian)鑄連(lian)(lian)軋生產銅(tong)(tong)(tong)(tong)桿(gan)主要(yao)是通(tong)過(guo)(guo)氣體的(de)燃燒(shao)使(shi)銅(tong)(tong)(tong)(tong)桿(gan)熔化(hua)(hua),在燃燒(shao)的(de)過(guo)(guo)程中(zhong),通(tong)過(guo)(guo)氧(yang)化(hua)(hua)和(he)揮發作用,可(ke)一定程度減少部分雜質進(jin)入(ru)銅(tong)(tong)(tong)(tong)液,因(yin)此連(lian)(lian)鑄連(lian)(lian)軋法對(dui)原料要(yao)求相對(dui)低一些。上引連(lian)(lian)鑄生產無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan),由于是用感應電(dian)爐(lu)熔化(hua)(hua),電(dian)解銅(tong)(tong)(tong)(tong)表面(mian)的(de)“銅(tong)(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)(tong)豆”基本都熔入(ru)到銅(tong)(tong)(tong)(tong)液中(zhong)。其中(zhong)熔入(ru)的(de)S對(dui)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)塑性影響極大,會(hui)增(zeng)加拉絲斷線率。
2、鑄造過(guo)程(cheng)中雜質的(de)進入
在生(sheng)產(chan)過程中,連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)工藝需通過保溫爐、溜(liu)槽、中間包轉(zhuan)運銅液(ye),相對容(rong)易造成(cheng)耐火材(cai)料(liao)的(de)(de)剝落,在軋(ya)(ya)制過程中需要通過軋(ya)(ya)輥,造成(cheng)鐵質的(de)(de)脫落,會(hui)(hui)給(gei)銅桿造成(cheng)外部夾雜。而熱軋(ya)(ya)中皮上和(he)皮下氧化物(wu)的(de)(de)軋(ya)(ya)入(ru)(ru),會(hui)(hui)給(gei)低(di)氧桿的(de)(de)拉絲造成(cheng)不利(li)的(de)(de)影響。上引連(lian)鑄(zhu)(zhu)法生(sheng)產(chan)工藝流(liu)程較(jiao)短,銅液(ye)是通過聯(lian)體爐內(nei)(nei)潛流(liu)式(shi)完成(cheng),對耐火材(cai)料(liao)的(de)(de)沖擊不大,結晶是通過石墨模內(nei)(nei)進行,所以過程中可(ke)能(neng)產(chan)生(sheng)的(de)(de)污(wu)染源較(jiao)少(shao),雜質進入(ru)(ru)的(de)(de)機會(hui)(hui)較(jiao)少(shao)。
O、S、P是與銅(tong)(tong)會生產化合物的元素(su)。在熔態銅(tong)(tong)中,氧(yang)(yang)(yang)可以(yi)溶解(jie)一(yi)部(bu)分(fen),但當銅(tong)(tong)冷(leng)凝時,氧(yang)(yang)(yang)幾乎不溶解(jie)于(yu)銅(tong)(tong)中。熔態時所溶解(jie)的氧(yang)(yang)(yang),以(yi)銅(tong)(tong)=氧(yang)(yang)(yang)化亞銅(tong)(tong)共晶體析出,分(fen)布在晶粒晶界(jie)處(chu)。銅(tong)(tong)-氧(yang)(yang)(yang)化亞銅(tong)(tong)共晶體的出現,顯著降低了銅(tong)(tong)的塑性。
硫可以溶(rong)解(jie)在(zai)(zai)熔體的銅(tong)中,但(dan)在(zai)(zai)室(shi)溫下,其溶(rong)解(jie)度幾乎降低(di)到零,它以硫化亞(ya)銅(tong)的形式出現在(zai)(zai)晶(jing)(jing)粒晶(jing)(jing)界處(chu),會顯(xian)著降低(di)銅(tong)的塑性(xing)。
3、氧(yang)(yang)在(zai)低(di)氧(yang)(yang)銅桿和無(wu)氧(yang)(yang)銅桿中分布形式及(ji)其影響
氧(yang)(yang)含(han)量(liang)對(dui)低氧(yang)(yang)銅(tong)桿的(de)(de)(de)(de)(de)拉線(xian)(xian)性能有(you)著明(ming)顯的(de)(de)(de)(de)(de)影響。當氧(yang)(yang)含(han)量(liang)增加到最佳值(zhi)時,銅(tong)桿的(de)(de)(de)(de)(de)斷(duan)線(xian)(xian)率最低。這是因(yin)為(wei)氧(yang)(yang)在與大(da)部分雜質反應的(de)(de)(de)(de)(de)過程中都起到了清除器的(de)(de)(de)(de)(de)作用。適度的(de)(de)(de)(de)(de)氧(yang)(yang)還(huan)有(you)利(li)于去除銅(tong)液中的(de)(de)(de)(de)(de)氫(qing),生成水蒸氣(qi)溢(yi)出,減少(shao)氣(qi)孔(kong)的(de)(de)(de)(de)(de)形成。最佳的(de)(de)(de)(de)(de)氧(yang)(yang)含(han)量(liang)為(wei)拉線(xian)(xian)工藝提(ti)供了最好的(de)(de)(de)(de)(de)條件(jian)。
低氧(yang)銅(tong)桿(gan)(gan)氧(yang)化(hua)物的(de)(de)(de)分(fen)(fen)布:在連續澆(jiao)鑄中(zhong)凝(ning)固的(de)(de)(de)最初階段,散熱速率(lv)和均勻(yun)冷(leng)卻(que)是(shi)決定(ding)銅(tong)桿(gan)(gan)氧(yang)化(hua)物分(fen)(fen)布的(de)(de)(de)主要因素。不均勻(yun)冷(leng)卻(que)會引(yin)起銅(tong)桿(gan)(gan)內部(bu)結構本(ben)質上的(de)(de)(de)差異,但后續的(de)(de)(de)熱加工,柱(zhu)狀(zhuang)晶(jing)通(tong)常會遭到(dao)破壞,使(shi)氧(yang)化(hua)亞(ya)銅(tong)顆粒(li)細微化(hua)和均勻(yun)分(fen)(fen)布。氧(yang)化(hua)物顆粒(li)聚集而產生的(de)(de)(de)典型情況是(shi)中(zhong)心爆裂。除(chu)氧(yang)化(hua)物顆粒(li)分(fen)(fen)布的(de)(de)(de)影響外,具有較小氧(yang)化(hua)物顆粒(li)的(de)(de)(de)銅(tong)桿(gan)(gan)顯示(shi)出較好的(de)(de)(de)拉線特性,較大的(de)(de)(de)Cu2O顆粒(li)容(rong)易造成應力集中(zhong)點而斷裂。
無(wu)氧(yang)銅(tong)(tong)(tong)含氧(yang)量超(chao)標,銅(tong)(tong)(tong)桿(gan)變(bian)脆(cui)(cui),延伸率下(xia)降(jiang),拉(la)伸式樣端口(kou)顯暗紅色(se),結晶組織(zhi)疏松(song)。當氧(yang)含量超(chao)出8ppm時,工藝(yi)(yi)性(xing)(xing)能變(bian)差(cha),表現(xian)為鑄造(zao)及拉(la)伸過程中斷(duan)(duan)桿(gan)及斷(duan)(duan)線率極具(ju)增高(gao)。這是由于氧(yang)能與銅(tong)(tong)(tong)生成氧(yang)化(hua)亞銅(tong)(tong)(tong)脆(cui)(cui)性(xing)(xing)相,形成銅(tong)(tong)(tong)-氧(yang)化(hua)亞銅(tong)(tong)(tong)共晶體(ti),以網狀組織(zhi)分(fen)布在(zai)境界上。這種脆(cui)(cui)性(xing)(xing)相硬(ying)度高(gao),在(zai)冷變(bian)形時將會與銅(tong)(tong)(tong)機體(ti)脫離,導致銅(tong)(tong)(tong)桿(gan)的機械(xie)性(xing)(xing)能下(xia)降(jiang),在(zai)后續加工中容易造(zao)成斷(duan)(duan)裂現(xian)象。氧(yang)含量高(gao)還能導致無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)導電率下(xia)降(jiang)。因(yin)此,必須嚴(yan)格(ge)控制上引連鑄工藝(yi)(yi)及產品質量。
4、氫的影響
在(zai)上引連鑄(zhu)中(zhong),氧含量控制較(jiao)低,氧化物的(de)副作用唄**降低,但氫的(de)影響成為較(jiao)顯著的(de)問題。吸氣后熔(rong)體中(zhong)存在(zai)平(ping)衡反應:H2O(g)=[O]+2[H];
氣體(ti)及(ji)疏(shu)松是(shi)(shi)在(zai)結(jie)晶(jing)的(de)過(guo)程中,氫(qing)從過(guo)飽和(he)的(de)溶液(ye)中析(xi)(xi)出(chu)(chu)(chu)(chu)并聚(ju)集(ji)而形(xing)(xing)成的(de)。在(zai)結(jie)晶(jing)前析(xi)(xi)出(chu)(chu)(chu)(chu)的(de)氫(qing)又可還原氧化(hua)亞銅(tong)而生成水氣泡。由于上引鑄(zhu)造(zao)的(de)特點是(shi)(shi)銅(tong)液(ye)自上而下的(de)結(jie)晶(jing),形(xing)(xing)成的(de)液(ye)**形(xing)(xing)狀近似錐型。銅(tong)液(ye)結(jie)晶(jing)前析(xi)(xi)出(chu)(chu)(chu)(chu)的(de)氣體(ti)在(zai)上浮過(guo)程中被堵(du)在(zai)凝(ning)固組織內,結(jie)晶(jing)時在(zai)鑄(zhu)桿內形(xing)(xing)成氣孔。上引的(de)含(han)氣量(liang)少(shao)時,析(xi)(xi)出(chu)(chu)(chu)(chu)的(de)氫(qing)存在(zai)于晶(jing)界處,形(xing)(xing)成疏(shu)松;含(han)氣量(liang)多時,則(ze)聚(ju)集(ji)成氣孔,因此(ci),氣孔和(he)疏(shu)松是(shi)(shi)氫(qing)氣和(he)水蒸氣兩者形(xing)(xing)成的(de)。
氫來源(yuan)于上引生(sheng)產過程中的(de)各個工藝(yi)環(huan)節,如原料電解銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔料木(mu)炭**、氣候環(huan)境**、石墨結晶器(qi)未(wei)干燥等。因此,熔化(hua)爐中的(de)銅(tong)(tong)液表面應覆(fu)蓋經烘烤的(de)木(mu)炭,電解銅(tong)(tong)應盡量去除“銅(tong)(tong)綠”、“銅(tong)(tong)豆(dou)”“耳朵”,對提高無(wu)氧銅(tong)(tong)桿質量非常重要(yao)。
在連(lian)鑄連(lian)軋工藝中,往(wang)往(wang)采用適度控制氧含量來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液在鑄造過程中是自下而上結晶,銅(tong)液中的(de)氧和(he)氫所產(chan)生的(de)水(shui)蒸(zheng)氣很(hen)容易上浮跑出,銅(tong)液中的(de)氫大部(bu)分能被有效去(qu)除(chu),因(yin)而對銅(tong)桿的(de)影響較小。
二、表面質量
在(zai)生(sheng)產(chan)電磁線等(deng)產(chan)品(pin)的過(guo)程中,對銅(tong)(tong)桿(gan)的表面質量(liang)也需提出要(yao)求(qiu)。需要(yao)拉制(zhi)后(hou)的銅(tong)(tong)絲表面無(wu)毛(mao)刺(ci)、銅(tong)(tong)粉(fen)少(shao)、無(wu)油污。并通過(guo)扭轉(zhuan)(zhuan)試驗測量(liang)表面銅(tong)(tong)粉(fen)的質量(liang)和扭轉(zhuan)(zhuan)后(hou)觀察銅(tong)(tong)桿(gan)的復原情況來判定其好(hao)壞(huai)。
在連鑄連軋(ya)過(guo)程(cheng)中(zhong),從鑄造到軋(ya)制前(qian),溫度高,完全暴露于空(kong)氣中(zhong),使(shi)鑄坯表(biao)面(mian)(mian)形成較厚的(de)氧化(hua)層,在軋(ya)制過(guo)程(cheng)中(zhong),隨著軋(ya)輥的(de)轉動,氧化(hua)物顆粒軋(ya)入銅線表(biao)面(mian)(mian)。由于氧化(hua)亞(ya)銅是(shi)(shi)高熔點脆性化(hua)合物,對于軋(ya)入較深的(de)氧化(hua)亞(ya)銅,當成條狀(zhuang)的(de)聚集物遇模具拉伸(shen)時,就會(hui)是(shi)(shi)銅桿外表(biao)面(mian)(mian)產生毛刺,給后(hou)續的(de)涂(tu)漆造成麻煩。
而上引連(lian)鑄(zhu)工藝制造的(de)無(wu)氧(yang)銅(tong)桿,由于鑄(zhu)造和冷(leng)卻完全與氧(yang)隔絕,后續亦無(wu)熱軋過程(cheng),銅(tong)桿表面無(wu)軋入表面的(de)氧(yang)化物,質量較好,拉制后銅(tong)粉少,上述問題較少存在。
無氧銅桿也分進(jin)口設(she)備(bei)(bei)(bei)做的(de)(de)和國(guo)產(chan)(chan)設(she)備(bei)(bei)(bei)做的(de)(de),但目前進(jin)口產(chan)(chan)品已(yi)無明顯優勢,銅桿產(chan)(chan)品出(chu)(chu)來后區別不是(shi)很大,只要銅板選的(de)(de)好(hao),生產(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)設(she)備(bei)(bei)(bei)也能產(chan)(chan)出(chu)(chu)可(ke)拉伸(shen)0.05的(de)(de)銅桿.進(jin)口設(she)備(bei)(bei)(bei)一般是(shi)芬蘭(lan)奧托昆普的(de)(de)設(she)備(bei)(bei)(bei),國(guo)產(chan)(chan)設(she)備(bei)(bei)(bei)最(zui)(zui)好(hao)的(de)(de)應該是(shi)上海(hai)的(de)(de)海(hai)軍廠(chang)的(de)(de)了,生產(chan)(chan)時間最(zui)(zui)長,軍工(gong)企(qi)業(ye),質量可(ke)靠。
低氧(yang)銅桿進口設備國(guo)(guo)(guo)(guo)際主要(yao)有(you)兩種(zhong),一種(zhong)是美國(guo)(guo)(guo)(guo)南(nan)線設備,英文是SOUTHWIRE,國(guo)(guo)(guo)(guo)內廠家是南(nan)京華(hua)新,江西銅業,另一種(zhong)是德國(guo)(guo)(guo)(guo)CONTIROD設備,國(guo)(guo)(guo)(guo)內廠家是常(chang)州金(jin)源,天津大無縫。
無(wu)氧(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從(cong)含氧(yang)(yang)(yang)(yang)(yang)量上容(rong)易(yi)區(qu)別,無(wu)氧(yang)(yang)(yang)(yang)(yang)銅是(shi)含氧(yang)(yang)(yang)(yang)(yang)量在(zai)10-20個(ge)PPM以(yi)(yi)下,但(dan)目前有(you)的(de)(de)廠家只(zhi)能(neng)做(zuo)到50個(ge)PPM以(yi)(yi)下.低(di)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好的(de)(de)桿(gan)(gan)(gan)(gan)子一般(ban)含氧(yang)(yang)(yang)(yang)(yang)量控制在(zai)250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一般(ban)采取的(de)(de)是(shi)上引法,低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)連(lian)鑄連(lian)軋,兩(liang)種(zhong)產品(pin)相對(dui)而(er)(er)言低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)漆包線(xian)性 能(neng)更適應些,如柔軟(ruan)性,回(hui)彈(dan)角,繞線(xian)性能(neng).但(dan)低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)拉(la)(la)絲條件(jian)相對(dui)要苛刻些,同樣拉(la)(la)伸(shen)(shen)0.2的(de)(de)細絲,如果伸(shen)(shen)線(xian)條件(jian)不好,普(pu)通的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可(ke)拉(la)(la)而(er)(er)好的(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷(duan) 線(xian),但(dan)如果放在(zai)好的(de)(de)伸(shen)(shen)線(xian)條件(jian),同樣的(de)(de)桿(gan)(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說不定就能(neng)拉(la)(la)到雙(shuang)零(ling)五(wu),而(er)(er)普(pu)通無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最多只(zhi)能(neng)拉(la)(la)伸(shen)(shen)到0.1而(er)(er)已,當然做(zuo)的(de)(de)最細的(de)(de)如雙(shuang)零(ling)二卻非(fei)得依靠(kao)進口的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了.目前有(you)企業嘗試用剝皮(pi)的(de)(de)方式來(lai)處理低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來(lai)伸(shen)(shen)0.03線(xian).但(dan)有(you)關(guan)這方面的(de)(de)內容(rong)我還不是(shi)很清楚。
音響線一般反(fan)而喜歡用(yong)無(wu)氧(yang)桿(gan),這(zhe)和無(wu)氧(yang)桿(gan)是單晶(jing)銅(tong)(tong),低(di)氧(yang)桿(gan)是多晶(jing)銅(tong)(tong)有關。
氧(yang)銅桿和無氧(yang)銅桿由于制(zhi)造方法的(de)(de)不同,致使存在差別,具有各自的(de)(de)特點。
一、關于氧(yang)的(de)吸入和(he)脫去以及它的(de)存在狀態(tai)
生產(chan)銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)一般在(zai)10—50ppm,在(zai)常(chang)溫下(xia)(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)固溶度(du)約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)一般在(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是(shi)在(zai)銅(tong)(tong)的(de)(de)(de)(de)液(ye)(ye)態下(xia)(xia)吸(xi)入的(de)(de)(de)(de),而(er)上(shang)引法無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)則相反(fan),氧(yang)(yang)(yang)(yang)(yang)在(zai)液(ye)(ye)態銅(tong)(tong)下(xia)(xia)保持(chi)相當時(shi)間后(hou),被還原(yuan)而(er)脫去,通常(chang)這(zhe)種(zhong)(zhong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)都在(zai)10—50ppm以下(xia)(xia),最(zui)低(di)(di)(di)可達1-2ppm,從組織(zhi)上(shang)看,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)化(hua)(hua)銅(tong)(tong)狀態,存在(zai)于晶粒(li)邊界附近(jin),這(zhe)對低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)而(er)言可以說是(shi)常(chang)見(jian)的(de)(de)(de)(de)但(dan)對無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)則很少(shao)見(jian)。氧(yang)(yang)(yang)(yang)(yang)化(hua)(hua)銅(tong)(tong)以夾雜形式在(zai)晶界出現對材(cai)料的(de)(de)(de)(de)韌(ren)性(xing)(xing)產(chan)生負面影響。而(er)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di)(di)(di),所以這(zhe)種(zhong)(zhong)銅(tong)(tong)的(de)(de)(de)(de)組織(zhi)是(shi)均勻(yun)的(de)(de)(de)(de)單相組織(zhi)對韌(ren)性(xing)(xing)有利。在(zai)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)的(de)(de)(de)(de)多孔性(xing)(xing)是(shi)不常(chang)見(jian)的(de)(de)(de)(de),而(er)在(zai)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)則是(shi)常(chang)見(jian)的(de)(de)(de)(de)一種(zhong)(zhong)缺陷(xian)。
二、熱(re)軋組織和鑄造組織的區(qu)別(bie)
低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)由于經(jing)過(guo)熱(re)軋,所以(yi)其組(zu)(zu)織(zhi)屬(shu)熱(re)加工組(zu)(zu)織(zhi),原(yuan)(yuan)來(lai)的(de)(de)(de)(de)(de)鑄造(zao)組(zu)(zu)織(zhi)已經(jing)破(po)碎,在(zai)8mm的(de)(de)(de)(de)(de)桿(gan)(gan)時(shi)已有(you)再結晶(jing)(jing)(jing)的(de)(de)(de)(de)(de)形式出現,而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)屬(shu)鑄造(zao)組(zu)(zu)織(zhi),晶(jing)(jing)(jing)粒(li)粗(cu)(cu)大,這是(shi)為什么,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)的(de)(de)(de)(de)(de)再結晶(jing)(jing)(jing)溫(wen)(wen)度較(jiao)高(gao)(gao),需要(yao)(yao)較(jiao)高(gao)(gao)退(tui)(tui)火溫(wen)(wen)度的(de)(de)(de)(de)(de)固有(you)原(yuan)(yuan)因(yin)。這是(shi)因(yin)為,再結晶(jing)(jing)(jing)發(fa)生在(zai)晶(jing)(jing)(jing)粒(li)邊界附(fu)近,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)組(zu)(zu)織(zhi)晶(jing)(jing)(jing)粒(li)粗(cu)(cu)大,晶(jing)(jing)(jing)粒(li)尺寸(cun)甚至能達幾(ji)個毫(hao)米,因(yin)而晶(jing)(jing)(jing)粒(li)邊界少,即(ji)使通(tong)過(guo)拉制(zhi)變形,但晶(jing)(jing)(jing)粒(li)邊界相對(dui)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)還是(shi)較(jiao)少,所以(yi)需要(yao)(yao)較(jiao)高(gao)(gao)的(de)(de)(de)(de)(de)退(tui)(tui)火功(gong)(gong)率(lv)(lv)。對(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)成(cheng)(cheng)功(gong)(gong)的(de)(de)(de)(de)(de)退(tui)(tui)火要(yao)(yao)求(qiu)是(shi):由桿(gan)(gan)經(jing)拉制(zhi),但尚未(wei)鑄造(zao)組(zu)(zu)織(zhi)的(de)(de)(de)(de)(de)線時(shi)的(de)(de)(de)(de)(de)第一(yi)次退(tui)(tui)火,其退(tui)(tui)火功(gong)(gong)率(lv)(lv)應(ying)(ying)比同樣情況的(de)(de)(de)(de)(de)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)高(gao)(gao)10——15%。經(jing)繼續(xu)拉制(zhi),在(zai)以(yi)后(hou)階段的(de)(de)(de)(de)(de)退(tui)(tui)火功(gong)(gong)率(lv)(lv)應(ying)(ying)留有(you)足夠(gou)的(de)(de)(de)(de)(de)余量(liang)和對(dui)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)和無(wu)氧(yang)(yang)(yang)銅(tong)(tong)切實區別執行(xing)不同的(de)(de)(de)(de)(de)退(tui)(tui)火工藝,以(yi)保(bao)證在(zai)制(zhi)品(pin)和成(cheng)(cheng)品(pin)導線的(de)(de)(de)(de)(de)柔軟性。
三(san)、夾雜(za),氧含量波動,表面氧化物(wu)和可能存(cun)在的(de)熱軋缺陷的(de)差別
無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)可拉性(xing)在所有(you)線徑里與低氧(yang)(yang)(yang)銅(tong)桿(gan)相(xiang)比(bi)都是優越的(de),除上(shang)述組織原(yuan)因外,無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)夾(jia)雜少,含氧(yang)(yang)(yang)量穩(wen)定,無(wu)熱軋可能產生的(de)缺陷(xian),桿(gan)表氧(yang)(yang)(yang)化(hua)(hua)物厚度可達≤15A。在連鑄連軋生產過程中如果工(gong)(gong)藝(yi)不(bu)穩(wen)定,對氧(yang)(yang)(yang)監(jian)控不(bu)嚴,含氧(yang)(yang)(yang)量不(bu)穩(wen)定將(jiang)直接影響桿(gan)的(de)性(xing)能。如果桿(gan)的(de)表面氧(yang)(yang)(yang)化(hua)(hua)物能在后工(gong)(gong)序的(de)連續(xu)清洗(xi)中得以(yi)彌(mi)補(bu)外,但比(bi)較(jiao)麻煩的(de)是有(you)相(xiang)當(dang)多(duo)的(de)氧(yang)(yang)(yang)化(hua)(hua)物存在于“皮下(xia)”,對拉線斷(duan)線影響更直接,故而在拉制微(wei)細線,超微(wei)細線時,為(wei)了減少斷(duan)線,有(you)時要對銅(tong)桿(gan)采取不(bu)得已的(de)辦法——剝皮,甚至二(er)次(ci)剝皮的(de)原(yuan)因所在,目的(de)要除去皮下(xia)氧(yang)(yang)(yang)化(hua)(hua)物。
四(si)、低氧銅(tong)桿(gan)和無(wu)氧銅(tong)桿(gan)的韌性有差別
兩(liang)者(zhe)都可(ke)以(yi)拉到0.015mm,但(dan)在低溫(wen)超(chao)導線中(zhong)的低溫(wen)級無(wu)氧銅,其細絲間的間距只有0.001mm.
五、從制桿的原材(cai)料到(dao)制線(xian)的經濟性有差別。
制造無氧銅(tong)桿(gan)要求質(zhi)量較高的(de)(de)原材料(liao)。一般(ban),拉制直徑(jing)>1mm的(de)(de)銅(tong)線時,低氧銅(tong)桿(gan)的(de)(de)優(you)點比較明顯,而無氧銅(tong)桿(gan)顯得更為(wei)優(you)越的(de)(de)是(shi)拉制直徑(jing)<0.5mm的(de)(de)銅(tong)線。
六、低氧銅桿的制線工藝與無氧銅桿的有所不同。
低氧銅(tong)(tong)桿的制(zhi)(zhi)線(xian)工藝不能照搬(ban)到無(wu)氧銅(tong)(tong)桿的制(zhi)(zhi)線(xian)工藝上(shang)來,至少兩者的退火工藝是(shi)不同的。因為線(xian)的柔軟性深受材料成份和(he)制(zhi)(zhi)桿,制(zhi)(zhi)線(xian)和(he)退火工藝的影響,不能簡單地說低氧銅(tong)(tong)或無(wu)氧銅(tong)(tong)誰(shui)軟誰(shui)硬(ying)。
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