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來(lai)源(yuan):行業動(dong)態 閱讀:109250 發布時(shi)間(jian):2019-07-05
導讀:由于生(sheng)產(chan)(chan)銅(tong)桿(gan)(gan)的(de)(de)(de)兩者的(de)(de)(de)工藝不同(tong),所生(sheng)產(chan)(chan)的(de)(de)(de)銅(tong)桿(gan)(gan)中的(de)(de)(de)含氧(yang)量(liang)及外觀就不同(tong)。上引生(sheng)產(chan)(chan)的(de)(de)(de)銅(tong)桿(gan)(gan),工藝得當氧(yang)含量(liang)在(zai)10ppm以下(xia),叫無氧(yang)銅(tong)桿(gan)(gan);連鑄(zhu)連鑄(zhu)生(sheng)產(chan)(chan)的(de)(de)(de)銅(tong)桿(gan)(gan) 是(shi)在(zai)保護條件下(xia)的(de)(de)(de)熱軋,氧(yang)含量(liang)在(zai)200-500ppm范圍內,但有(you)時(shi)也高達700ppm以上,一般(ban)情況下(xia),此(ci)種方(fang)法生(sheng)產(chan)(chan)的(de)(de)(de)銅(tong)外表光亮,低氧(yang)銅(tong)桿(gan)(gan),有(you)時(shi)也叫光桿(gan)(gan)。
銅(tong)(tong)(tong)桿是(shi)電纜(lan)行業的(de)(de)(de)主要原(yuan)料,生(sheng)產(chan)的(de)(de)(de)方(fang)式主要有(you)兩種(zhong)——連(lian)(lian)鑄(zhu)連(lian)(lian)軋法(fa)和上(shang)引連(lian)(lian)鑄(zhu)法(fa)。連(lian)(lian)鑄(zhu)連(lian)(lian)軋低氧(yang)(yang)銅(tong)(tong)(tong)桿的(de)(de)(de)生(sheng)產(chan)方(fang)法(fa)較(jiao)多,其特點是(shi)金屬在豎爐(lu)中融化后(hou)(hou),銅(tong)(tong)(tong)液通過保溫(wen)爐(lu)、溜槽(cao)、中間包,從澆管進(jin)(jin)入(ru)封(feng)閉的(de)(de)(de)模腔內,采用較(jiao)大的(de)(de)(de)冷(leng)卻(que)強度進(jin)(jin)行冷(leng)卻(que),形成鑄(zhu)坯(pi),然(ran)后(hou)(hou)進(jin)(jin)行多道次軋制,生(sheng)產(chan)的(de)(de)(de)低氧(yang)(yang)銅(tong)(tong)(tong)桿為熱加工(gong)組織(zhi),原(yuan)來的(de)(de)(de)鑄(zhu)造(zao)組織(zhi)已經破碎,含(han)氧(yang)(yang)量一(yi)般為200~400ppm之間。無氧(yang)(yang)銅(tong)(tong)(tong)桿國內基本全(quan)部(bu)采用上(shang)引連(lian)(lian)鑄(zhu)法(fa)生(sheng)產(chan),金屬在感應電爐(lu)中融化后(hou)(hou)通過石墨模進(jin)(jin)行上(shang)引連(lian)(lian)續鑄(zhu)造(zao),之后(hou)(hou)進(jin)(jin)行冷(leng)軋或冷(leng)加工(gong),生(sheng)產(chan)的(de)(de)(de)無氧(yang)(yang)銅(tong)(tong)(tong)桿為鑄(zhu)造(zao)組織(zhi),含(han)氧(yang)(yang)量一(yi)般在20ppm以下。由于制造(zao)工(gong)藝的(de)(de)(de)不同,所(suo)以在組織(zhi)結構(gou)、氧(yang)(yang)含(han)量分(fen)(fen)布、雜質的(de)(de)(de)形式及分(fen)(fen)布等(deng)諸多方(fang)面有(you)較(jiao)大差別。
一、拉制性能
銅桿的拉制性能跟很多因(yin)素有關,如雜質(zhi)的含量(liang)、氧含量(liang)及(ji)分(fen)布(bu)、工藝控(kong)制等。下面(mian)(mian)分(fen)別從以上幾(ji)個方面(mian)(mian)對銅桿的拉制性能進行分(fen)析。
1、熔化方式對S等雜質(zhi)的影響
連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋生(sheng)(sheng)產(chan)(chan)銅桿(gan)主要(yao)是通(tong)過氣(qi)體的(de)燃燒(shao)使銅桿(gan)熔(rong)化,在燃燒(shao)的(de)過程中(zhong),通(tong)過氧化和揮發作用,可一定程度減(jian)少部分(fen)雜質進入銅液,因此連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋法(fa)對原料要(yao)求相對低一些(xie)。上引連(lian)(lian)鑄(zhu)(zhu)生(sheng)(sheng)產(chan)(chan)無(wu)(wu)氧銅桿(gan),由于是用感應電爐熔(rong)化,電解銅表(biao)面(mian)的(de)“銅綠”“銅豆”基本都熔(rong)入到(dao)銅液中(zhong)。其中(zhong)熔(rong)入的(de)S對無(wu)(wu)氧銅桿(gan)塑性影響(xiang)極大,會(hui)增加拉絲斷(duan)線率。
2、鑄造過(guo)程中雜質的進(jin)入
在(zai)生產過(guo)(guo)程(cheng)中(zhong)(zhong)(zhong)(zhong),連(lian)鑄連(lian)軋(ya)(ya)工(gong)藝需通(tong)(tong)過(guo)(guo)保溫爐(lu)、溜槽、中(zhong)(zhong)(zhong)(zhong)間(jian)包轉運銅液(ye),相對(dui)容易造(zao)成耐火材料的(de)剝落(luo),在(zai)軋(ya)(ya)制(zhi)過(guo)(guo)程(cheng)中(zhong)(zhong)(zhong)(zhong)需要通(tong)(tong)過(guo)(guo)軋(ya)(ya)輥,造(zao)成鐵質的(de)脫落(luo),會給銅桿(gan)造(zao)成外部夾雜。而熱軋(ya)(ya)中(zhong)(zhong)(zhong)(zhong)皮(pi)上和皮(pi)下氧化物(wu)的(de)軋(ya)(ya)入(ru),會給低氧桿(gan)的(de)拉絲造(zao)成不利的(de)影響。上引連(lian)鑄法生產工(gong)藝流程(cheng)較短,銅液(ye)是(shi)通(tong)(tong)過(guo)(guo)聯(lian)體爐(lu)內(nei)潛流式(shi)完成,對(dui)耐火材料的(de)沖(chong)擊(ji)不大,結(jie)晶是(shi)通(tong)(tong)過(guo)(guo)石墨模內(nei)進(jin)行,所以(yi)過(guo)(guo)程(cheng)中(zhong)(zhong)(zhong)(zhong)可能產生的(de)污染源(yuan)較少,雜質進(jin)入(ru)的(de)機會較少。
O、S、P是(shi)與銅會生產化合物的元素。在(zai)熔態銅中,氧(yang)(yang)可以(yi)溶解一部分,但當(dang)銅冷凝(ning)時(shi),氧(yang)(yang)幾(ji)乎(hu)不(bu)溶解于銅中。熔態時(shi)所(suo)溶解的氧(yang)(yang),以(yi)銅=氧(yang)(yang)化亞銅共晶體析出,分布在(zai)晶粒晶界處。銅-氧(yang)(yang)化亞銅共晶體的出現,顯著降低了銅的塑性。
硫(liu)可以溶解在熔體的銅(tong)中(zhong),但(dan)在室溫(wen)下,其溶解度幾(ji)乎降(jiang)低到(dao)零,它以硫(liu)化亞銅(tong)的形式(shi)出現在晶(jing)粒晶(jing)界處,會顯著降(jiang)低銅(tong)的塑性。
3、氧在(zai)低氧銅(tong)(tong)桿和無(wu)氧銅(tong)(tong)桿中分布(bu)形式及其影響
氧含(han)量(liang)對低氧銅(tong)桿的(de)拉(la)線(xian)性能(neng)有著明顯的(de)影響。當氧含(han)量(liang)增加到最(zui)(zui)佳(jia)值時,銅(tong)桿的(de)斷線(xian)率最(zui)(zui)低。這是因為氧在與大部分雜質反應的(de)過程中都(dou)起到了(le)(le)清除器的(de)作(zuo)用。適度的(de)氧還(huan)有利于去除銅(tong)液中的(de)氫,生成水蒸(zheng)氣溢出(chu),減(jian)少氣孔(kong)的(de)形成。最(zui)(zui)佳(jia)的(de)氧含(han)量(liang)為拉(la)線(xian)工(gong)藝提供了(le)(le)最(zui)(zui)好的(de)條件。
低氧(yang)(yang)(yang)銅(tong)桿(gan)氧(yang)(yang)(yang)化(hua)物(wu)的(de)分(fen)布:在連(lian)續澆鑄中凝固的(de)最初階段,散(san)熱(re)速率和(he)均勻冷(leng)卻(que)是決定銅(tong)桿(gan)氧(yang)(yang)(yang)化(hua)物(wu)分(fen)布的(de)主要因(yin)素。不均勻冷(leng)卻(que)會引起銅(tong)桿(gan)內部結構(gou)本質(zhi)上的(de)差(cha)異,但后續的(de)熱(re)加工,柱狀晶通常會遭(zao)到(dao)破壞,使(shi)氧(yang)(yang)(yang)化(hua)亞銅(tong)顆(ke)粒(li)(li)細微化(hua)和(he)均勻分(fen)布。氧(yang)(yang)(yang)化(hua)物(wu)顆(ke)粒(li)(li)聚集(ji)而(er)產生的(de)典型情況是中心爆(bao)裂。除(chu)氧(yang)(yang)(yang)化(hua)物(wu)顆(ke)粒(li)(li)分(fen)布的(de)影響外(wai),具有較(jiao)小(xiao)氧(yang)(yang)(yang)化(hua)物(wu)顆(ke)粒(li)(li)的(de)銅(tong)桿(gan)顯示出較(jiao)好的(de)拉線特性,較(jiao)大(da)的(de)Cu2O顆(ke)粒(li)(li)容易造成應(ying)力集(ji)中點而(er)斷裂。
無(wu)氧(yang)(yang)(yang)銅含(han)(han)氧(yang)(yang)(yang)量(liang)(liang)(liang)超標,銅桿(gan)變脆,延伸率(lv)下(xia)降(jiang),拉(la)伸式樣端口(kou)顯暗紅色(se),結(jie)晶(jing)組織疏(shu)松。當氧(yang)(yang)(yang)含(han)(han)量(liang)(liang)(liang)超出(chu)8ppm時,工(gong)藝性能(neng)(neng)變差(cha),表(biao)現為(wei)鑄造(zao)及拉(la)伸過程中(zhong)斷(duan)桿(gan)及斷(duan)線率(lv)極具增高(gao)。這是由于氧(yang)(yang)(yang)能(neng)(neng)與(yu)銅生成氧(yang)(yang)(yang)化亞銅脆性相,形成銅-氧(yang)(yang)(yang)化亞銅共晶(jing)體,以網(wang)狀組織分布在(zai)(zai)境界上。這種脆性相硬度高(gao),在(zai)(zai)冷變形時將會(hui)與(yu)銅機體脫離,導致銅桿(gan)的機械性能(neng)(neng)下(xia)降(jiang),在(zai)(zai)后續加工(gong)中(zhong)容(rong)易(yi)造(zao)成斷(duan)裂現象。氧(yang)(yang)(yang)含(han)(han)量(liang)(liang)(liang)高(gao)還能(neng)(neng)導致無(wu)氧(yang)(yang)(yang)銅桿(gan)導電率(lv)下(xia)降(jiang)。因此(ci),必須嚴格控制上引連鑄工(gong)藝及產品質(zhi)量(liang)(liang)(liang)。
4、氫的影響
在上(shang)引連(lian)鑄中(zhong),氧含量(liang)控制(zhi)較低(di),氧化物(wu)的副作用(yong)唄**降低(di),但氫(qing)的影(ying)響(xiang)成(cheng)為較顯(xian)著(zhu)的問題。吸氣后(hou)熔體中(zhong)存在平(ping)衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)體(ti)及疏松是在(zai)結(jie)晶(jing)(jing)(jing)(jing)的(de)(de)過程中,氫(qing)從過飽(bao)和的(de)(de)溶液(ye)中析出(chu)(chu)并(bing)聚(ju)集(ji)而形(xing)成(cheng)(cheng)的(de)(de)。在(zai)結(jie)晶(jing)(jing)(jing)(jing)前析出(chu)(chu)的(de)(de)氫(qing)又可還原氧化(hua)亞(ya)銅而生成(cheng)(cheng)水(shui)氣(qi)(qi)泡。由于上引(yin)鑄造的(de)(de)特點是銅液(ye)自上而下的(de)(de)結(jie)晶(jing)(jing)(jing)(jing),形(xing)成(cheng)(cheng)的(de)(de)液(ye)**形(xing)狀(zhuang)近似錐型。銅液(ye)結(jie)晶(jing)(jing)(jing)(jing)前析出(chu)(chu)的(de)(de)氣(qi)(qi)體(ti)在(zai)上浮過程中被堵在(zai)凝固組織(zhi)內(nei),結(jie)晶(jing)(jing)(jing)(jing)時(shi)在(zai)鑄桿(gan)內(nei)形(xing)成(cheng)(cheng)氣(qi)(qi)孔。上引(yin)的(de)(de)含氣(qi)(qi)量少時(shi),析出(chu)(chu)的(de)(de)氫(qing)存(cun)在(zai)于晶(jing)(jing)(jing)(jing)界處,形(xing)成(cheng)(cheng)疏松;含氣(qi)(qi)量多(duo)時(shi),則聚(ju)集(ji)成(cheng)(cheng)氣(qi)(qi)孔,因(yin)此(ci),氣(qi)(qi)孔和疏松是氫(qing)氣(qi)(qi)和水(shui)蒸(zheng)氣(qi)(qi)兩者形(xing)成(cheng)(cheng)的(de)(de)。
氫來源(yuan)于(yu)上(shang)引生產過(guo)程中的(de)(de)各個工藝環節,如(ru)原料電解(jie)銅(tong)(tong)(tong)的(de)(de)“銅(tong)(tong)(tong)綠”、輔(fu)料木炭(tan)**、氣(qi)候環境**、石(shi)墨結(jie)晶器未干燥等。因此(ci),熔化爐中的(de)(de)銅(tong)(tong)(tong)液表面應覆蓋(gai)經烘烤的(de)(de)木炭(tan),電解(jie)銅(tong)(tong)(tong)應盡量(liang)去除“銅(tong)(tong)(tong)綠”、“銅(tong)(tong)(tong)豆”“耳朵(duo)”,對提高無(wu)氧銅(tong)(tong)(tong)桿(gan)質量(liang)非常重(zhong)要。
在連鑄連軋(ya)工藝中(zhong),往(wang)往(wang)采用適度(du)控(kong)(kong)制氧含量來控(kong)(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由(you)于銅(tong)液在(zai)鑄造過(guo)程中是(shi)自下而上結晶,銅(tong)液中的(de)氧和氫所產生(sheng)的(de)水蒸(zheng)氣很容(rong)易上浮跑出(chu),銅(tong)液中的(de)氫大部分能(neng)被有(you)效(xiao)去除,因而對銅(tong)桿的(de)影響較小。
二、表面質量
在生產電磁線等產品的(de)(de)過程中,對銅(tong)(tong)(tong)桿的(de)(de)表(biao)(biao)面(mian)質(zhi)量也需提(ti)出要求。需要拉制(zhi)后的(de)(de)銅(tong)(tong)(tong)絲表(biao)(biao)面(mian)無(wu)毛刺、銅(tong)(tong)(tong)粉少、無(wu)油污(wu)。并通(tong)過扭(niu)轉試驗測量表(biao)(biao)面(mian)銅(tong)(tong)(tong)粉的(de)(de)質(zhi)量和扭(niu)轉后觀察(cha)銅(tong)(tong)(tong)桿的(de)(de)復原情況來判定(ding)其好壞(huai)。
在(zai)連鑄連軋(ya)過程中,從鑄造到軋(ya)制(zhi)前,溫度高,完全暴(bao)露(lu)于空氣(qi)中,使鑄坯表面形成較厚的(de)氧(yang)化(hua)(hua)(hua)層(ceng),在(zai)軋(ya)制(zhi)過程中,隨(sui)著軋(ya)輥的(de)轉(zhuan)動,氧(yang)化(hua)(hua)(hua)物(wu)顆粒軋(ya)入銅線表面。由于氧(yang)化(hua)(hua)(hua)亞銅是高熔點脆性化(hua)(hua)(hua)合(he)物(wu),對于軋(ya)入較深的(de)氧(yang)化(hua)(hua)(hua)亞銅,當成條狀的(de)聚集物(wu)遇(yu)模(mo)具(ju)拉(la)伸時,就會是銅桿外表面產生毛刺,給后續(xu)的(de)涂(tu)漆造成麻煩(fan)。
而上引連鑄工藝制(zhi)造的無氧銅(tong)桿,由于鑄造和(he)冷卻完全與(yu)氧隔絕,后(hou)(hou)續亦(yi)無熱軋過(guo)程,銅(tong)桿表(biao)面無軋入(ru)表(biao)面的氧化(hua)物,質量(liang)較好,拉制(zhi)后(hou)(hou)銅(tong)粉少,上述問題較少存在。
無氧(yang)銅桿也分進口設(she)備(bei)(bei)做的(de)和(he)國產(chan)設(she)備(bei)(bei)做的(de),但目前進口產(chan)品(pin)已(yi)無明(ming)顯優勢,銅桿產(chan)品(pin)出來(lai)后區別不(bu)是(shi)很大,只要(yao)銅板選的(de)好,生產(chan)控制比較(jiao)穩定,國產(chan)設(she)備(bei)(bei)也能產(chan)出可拉伸0.05的(de)銅桿.進口設(she)備(bei)(bei)一(yi)般是(shi)芬蘭奧托昆(kun)普的(de)設(she)備(bei)(bei),國產(chan)設(she)備(bei)(bei)最好的(de)應該是(shi)上海(hai)的(de)海(hai)軍(jun)廠的(de)了,生產(chan)時間最長,軍(jun)工企業(ye),質量可靠。
低氧銅(tong)桿進口設(she)備(bei)(bei)國(guo)際主要有兩(liang)種,一種是(shi)美國(guo)南線(xian)設(she)備(bei)(bei),英文是(shi)SOUTHWIRE,國(guo)內廠家是(shi)南京華(hua)新,江西銅(tong)業(ye),另一種是(shi)德國(guo)CONTIROD設(she)備(bei)(bei),國(guo)內廠家是(shi)常(chang)州金源(yuan),天津(jin)大無(wu)縫。
無(wu)(wu)氧(yang)(yang)(yang)及低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)量(liang)上(shang)容易(yi)區別(bie),無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)是(shi)含(han)氧(yang)(yang)(yang)量(liang)在10-20個PPM以(yi)下(xia)(xia),但目前(qian)有的(de)(de)(de)(de)廠(chang)家只能(neng)做(zuo)到50個PPM以(yi)下(xia)(xia).低(di)(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)在 200-400個PPM,好的(de)(de)(de)(de)桿(gan)(gan)(gan)(gan)子(zi)一般含(han)氧(yang)(yang)(yang)量(liang)控制在250個PPM左右,無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一般采取(qu)的(de)(de)(de)(de)是(shi)上(shang)引法,低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)連(lian)鑄連(lian)軋,兩種(zhong)產品相(xiang)對而(er)言低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對漆包線(xian)(xian)(xian)(xian)性(xing) 能(neng)更適應(ying)些(xie),如(ru)柔軟(ruan)性(xing),回彈(dan)角,繞線(xian)(xian)(xian)(xian)性(xing)能(neng).但低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對拉(la)絲條(tiao)件相(xiang)對要苛刻些(xie),同樣拉(la)伸(shen)(shen)0.2的(de)(de)(de)(de)細(xi)絲,如(ru)果伸(shen)(shen)線(xian)(xian)(xian)(xian)條(tiao)件不好,普(pu)通(tong)(tong)的(de)(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可拉(la)而(er)好的(de)(de)(de)(de)低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷 線(xian)(xian)(xian)(xian),但如(ru)果放(fang)在好的(de)(de)(de)(de)伸(shen)(shen)線(xian)(xian)(xian)(xian)條(tiao)件,同樣的(de)(de)(de)(de)桿(gan)(gan)(gan)(gan)子(zi),低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說(shuo)不定就能(neng)拉(la)到雙(shuang)零五,而(er)普(pu)通(tong)(tong)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最多只能(neng)拉(la)伸(shen)(shen)到0.1而(er)已,當然做(zuo)的(de)(de)(de)(de)最細(xi)的(de)(de)(de)(de)如(ru)雙(shuang)零二卻非得依靠進口的(de)(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)了.目前(qian)有企業(ye)嘗試用剝皮的(de)(de)(de)(de)方(fang)式來(lai)處理低(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來(lai)伸(shen)(shen)0.03線(xian)(xian)(xian)(xian).但有關這方(fang)面的(de)(de)(de)(de)內容我(wo)還不是(shi)很清楚。
音響線一般(ban)反而喜(xi)歡用無氧(yang)桿,這和無氧(yang)桿是單晶銅,低(di)氧(yang)桿是多晶銅有關。
氧(yang)銅桿和無氧(yang)銅桿由于制造方(fang)法(fa)的不同,致(zhi)使存在差(cha)別,具有各自(zi)的特(te)點。
一(yi)、關于氧的吸入和(he)脫(tuo)去以及它的存在(zai)狀(zhuang)態(tai)
生(sheng)產銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)陰(yin)極銅(tong)(tong)(tong)(tong)的(de)(de)(de)含氧(yang)(yang)量一般(ban)在(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)常(chang)(chang)(chang)溫下(xia)氧(yang)(yang)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)含氧(yang)(yang)量一般(ban)在(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)的(de)(de)(de)進入(ru)是(shi)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)液態下(xia)吸入(ru)的(de)(de)(de),而(er)上引法無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則(ze)相反,氧(yang)(yang)在(zai)(zai)(zai)(zai)液態銅(tong)(tong)(tong)(tong)下(xia)保持(chi)相當(dang)時間后(hou),被還原而(er)脫去,通常(chang)(chang)(chang)這種(zhong)桿(gan)的(de)(de)(de)含氧(yang)(yang)量都在(zai)(zai)(zai)(zai)10—50ppm以(yi)下(xia),最低(di)可達1-2ppm,從組(zu)織(zhi)上看,低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang),以(yi)氧(yang)(yang)化銅(tong)(tong)(tong)(tong)狀(zhuang)態,存在(zai)(zai)(zai)(zai)于晶粒(li)邊界附近,這對低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)而(er)言可以(yi)說是(shi)常(chang)(chang)(chang)見(jian)的(de)(de)(de)但(dan)對無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則(ze)很(hen)少見(jian)。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)(zai)晶界出現對材料的(de)(de)(de)韌性產生(sheng)負面影響。而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)很(hen)低(di),所(suo)以(yi)這種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)組(zu)織(zhi)是(shi)均(jun)勻的(de)(de)(de)單相組(zu)織(zhi)對韌性有利。在(zai)(zai)(zai)(zai)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)(de)多孔性是(shi)不常(chang)(chang)(chang)見(jian)的(de)(de)(de),而(er)在(zai)(zai)(zai)(zai)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中則(ze)是(shi)常(chang)(chang)(chang)見(jian)的(de)(de)(de)一種(zhong)缺陷。
二(er)、熱軋組(zu)織(zhi)和鑄造(zao)組(zu)織(zhi)的區別
低(di)氧(yang)銅(tong)桿(gan)由于經(jing)過熱軋,所以(yi)其組(zu)(zu)織(zhi)(zhi)屬熱加工組(zu)(zu)織(zhi)(zhi),原來的(de)(de)鑄(zhu)造組(zu)(zu)織(zhi)(zhi)已(yi)經(jing)破碎,在8mm的(de)(de)桿(gan)時已(yi)有(you)再(zai)(zai)結(jie)晶(jing)(jing)的(de)(de)形(xing)式(shi)出現,而無氧(yang)銅(tong)桿(gan)屬鑄(zhu)造組(zu)(zu)織(zhi)(zhi),晶(jing)(jing)粒粗(cu)大(da),這(zhe)是(shi)為什么,無氧(yang)銅(tong)的(de)(de)再(zai)(zai)結(jie)晶(jing)(jing)溫度(du)較(jiao)高(gao)(gao),需(xu)(xu)要較(jiao)高(gao)(gao)退(tui)火(huo)(huo)溫度(du)的(de)(de)固有(you)原因。這(zhe)是(shi)因為,再(zai)(zai)結(jie)晶(jing)(jing)發(fa)生在晶(jing)(jing)粒邊(bian)界附近,無氧(yang)銅(tong)桿(gan)組(zu)(zu)織(zhi)(zhi)晶(jing)(jing)粒粗(cu)大(da),晶(jing)(jing)粒尺寸甚至能(neng)達幾個毫米,因而晶(jing)(jing)粒邊(bian)界少(shao)(shao),即(ji)使通過拉制(zhi)(zhi)變(bian)形(xing),但(dan)晶(jing)(jing)粒邊(bian)界相(xiang)對低(di)氧(yang)銅(tong)桿(gan)還是(shi)較(jiao)少(shao)(shao),所以(yi)需(xu)(xu)要較(jiao)高(gao)(gao)的(de)(de)退(tui)火(huo)(huo)功率(lv)。對無氧(yang)銅(tong)成功的(de)(de)退(tui)火(huo)(huo)要求是(shi):由桿(gan)經(jing)拉制(zhi)(zhi),但(dan)尚未鑄(zhu)造組(zu)(zu)織(zhi)(zhi)的(de)(de)線時的(de)(de)第一次退(tui)火(huo)(huo),其退(tui)火(huo)(huo)功率(lv)應(ying)比同樣情況(kuang)的(de)(de)低(di)氧(yang)銅(tong)高(gao)(gao)10——15%。經(jing)繼續拉制(zhi)(zhi),在以(yi)后階(jie)段的(de)(de)退(tui)火(huo)(huo)功率(lv)應(ying)留有(you)足夠的(de)(de)余(yu)量和(he)對低(di)氧(yang)銅(tong)和(he)無氧(yang)銅(tong)切實(shi)區(qu)別執行不同的(de)(de)退(tui)火(huo)(huo)工藝,以(yi)保證在制(zhi)(zhi)品和(he)成品導線的(de)(de)柔軟性(xing)。
三、夾雜,氧含量波(bo)動,表面氧化物和可能存在的熱軋缺(que)陷(xian)的差別
無氧(yang)(yang)銅(tong)桿(gan)的(de)(de)(de)可拉性在所(suo)有線(xian)(xian)徑里(li)與(yu)低氧(yang)(yang)銅(tong)桿(gan)相比(bi)都是(shi)優越(yue)的(de)(de)(de),除(chu)上(shang)述組織原因(yin)外,無氧(yang)(yang)銅(tong)桿(gan)夾(jia)雜少(shao),含氧(yang)(yang)量穩定,無熱軋(ya)可能產生的(de)(de)(de)缺陷(xian),桿(gan)表氧(yang)(yang)化(hua)物厚度(du)可達≤15A。在連(lian)鑄連(lian)軋(ya)生產過程中(zhong)如果(guo)工藝不(bu)穩定,對(dui)氧(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)量不(bu)穩定將直接影響桿(gan)的(de)(de)(de)性能。如果(guo)桿(gan)的(de)(de)(de)表面氧(yang)(yang)化(hua)物能在后工序的(de)(de)(de)連(lian)續(xu)清洗中(zhong)得(de)以彌補外,但(dan)比(bi)較(jiao)麻煩的(de)(de)(de)是(shi)有相當多(duo)的(de)(de)(de)氧(yang)(yang)化(hua)物存在于“皮(pi)下”,對(dui)拉線(xian)(xian)斷線(xian)(xian)影響更直接,故而在拉制微細(xi)線(xian)(xian),超(chao)微細(xi)線(xian)(xian)時,為了減少(shao)斷線(xian)(xian),有時要對(dui)銅(tong)桿(gan)采(cai)取(qu)不(bu)得(de)已的(de)(de)(de)辦(ban)法——剝皮(pi),甚至二次剝皮(pi)的(de)(de)(de)原因(yin)所(suo)在,目的(de)(de)(de)要除(chu)去皮(pi)下氧(yang)(yang)化(hua)物。
四(si)、低氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)的韌性有差別(bie)
兩者都可以拉到0.015mm,但(dan)在(zai)低(di)溫(wen)超導線中的(de)低(di)溫(wen)級無氧銅(tong),其細絲(si)間(jian)的(de)間(jian)距只有0.001mm.
五、從制桿的原材料到制線的經(jing)濟(ji)性(xing)有差別。
制造無氧銅(tong)桿(gan)要求質量較高的(de)(de)(de)原材料(liao)。一般,拉(la)制直(zhi)徑(jing)>1mm的(de)(de)(de)銅(tong)線時,低氧銅(tong)桿(gan)的(de)(de)(de)優(you)點比較明顯(xian),而無氧銅(tong)桿(gan)顯(xian)得(de)更為優(you)越的(de)(de)(de)是拉(la)制直(zhi)徑(jing)<0.5mm的(de)(de)(de)銅(tong)線。
六、低氧銅桿(gan)的(de)制線(xian)工藝與無氧銅桿(gan)的(de)有所不同。
低氧銅(tong)(tong)桿(gan)的制線(xian)工藝不(bu)(bu)能照搬(ban)到無氧銅(tong)(tong)桿(gan)的制線(xian)工藝上(shang)來,至少兩者的退火(huo)工藝是不(bu)(bu)同的。因為線(xian)的柔軟性深受材料成份和制桿(gan),制線(xian)和退火(huo)工藝的影(ying)響(xiang),不(bu)(bu)能簡單地說低氧銅(tong)(tong)或無氧銅(tong)(tong)誰(shui)軟誰(shui)硬。
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