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來(lai)源:行業(ye)動態 閱(yue)讀:109509 發布時間:2019-07-05
導(dao)讀:由于生產(chan)銅(tong)桿(gan)(gan)的(de)兩者的(de)工藝(yi)不同,所生產(chan)的(de)銅(tong)桿(gan)(gan)中的(de)含(han)氧量(liang)及外觀就不同。上引生產(chan)的(de)銅(tong)桿(gan)(gan),工藝(yi)得當(dang)氧含(han)量(liang)在(zai)10ppm以下,叫無(wu)氧銅(tong)桿(gan)(gan);連鑄連鑄生產(chan)的(de)銅(tong)桿(gan)(gan) 是在(zai)保護條件下的(de)熱軋,氧含(han)量(liang)在(zai)200-500ppm范圍內,但有(you)時(shi)也高達700ppm以上,一般情況下,此種方(fang)法生產(chan)的(de)銅(tong)外表光亮,低(di)氧銅(tong)桿(gan)(gan),有(you)時(shi)也叫光桿(gan)(gan)。
銅(tong)桿(gan)(gan)是電纜行(xing)業(ye)的(de)(de)(de)主(zhu)要原料,生(sheng)產的(de)(de)(de)方(fang)(fang)式(shi)主(zhu)要有兩(liang)種——連(lian)鑄(zhu)(zhu)(zhu)連(lian)軋法和(he)上引(yin)連(lian)鑄(zhu)(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)(zhu)連(lian)軋低氧銅(tong)桿(gan)(gan)的(de)(de)(de)生(sheng)產方(fang)(fang)法較多(duo)(duo),其特點是金屬在豎爐中(zhong)融化(hua)后(hou),銅(tong)液通(tong)(tong)過(guo)保溫爐、溜槽、中(zhong)間包,從澆(jiao)管進(jin)入封閉的(de)(de)(de)模腔內(nei),采(cai)用(yong)較大(da)的(de)(de)(de)冷(leng)卻(que)強度進(jin)行(xing)冷(leng)卻(que),形(xing)成(cheng)鑄(zhu)(zhu)(zhu)坯,然后(hou)進(jin)行(xing)多(duo)(duo)道次軋制,生(sheng)產的(de)(de)(de)低氧銅(tong)桿(gan)(gan)為熱加工組織,原來(lai)的(de)(de)(de)鑄(zhu)(zhu)(zhu)造組織已經破碎(sui),含(han)(han)氧量(liang)一般為200~400ppm之間。無氧銅(tong)桿(gan)(gan)國內(nei)基(ji)本全部采(cai)用(yong)上引(yin)連(lian)鑄(zhu)(zhu)(zhu)法生(sheng)產,金屬在感應電爐中(zhong)融化(hua)后(hou)通(tong)(tong)過(guo)石墨模進(jin)行(xing)上引(yin)連(lian)續鑄(zhu)(zhu)(zhu)造,之后(hou)進(jin)行(xing)冷(leng)軋或冷(leng)加工,生(sheng)產的(de)(de)(de)無氧銅(tong)桿(gan)(gan)為鑄(zhu)(zhu)(zhu)造組織,含(han)(han)氧量(liang)一般在20ppm以下。由于制造工藝(yi)的(de)(de)(de)不同(tong),所(suo)以在組織結構(gou)、氧含(han)(han)量(liang)分(fen)布、雜(za)質的(de)(de)(de)形(xing)式(shi)及分(fen)布等(deng)諸多(duo)(duo)方(fang)(fang)面有較大(da)差別。
一、拉制性能
銅桿的(de)拉(la)(la)制性(xing)能跟很多因(yin)素有關,如(ru)雜質的(de)含量(liang)、氧含量(liang)及分(fen)布、工藝控(kong)制等。下面(mian)分(fen)別(bie)從以上幾個(ge)方面(mian)對銅桿的(de)拉(la)(la)制性(xing)能進行分(fen)析(xi)。
1、熔(rong)化方式對S等雜(za)質的影(ying)響
連鑄連軋生產銅(tong)(tong)(tong)(tong)(tong)桿(gan)主(zhu)要(yao)是通(tong)過氣體的燃燒使銅(tong)(tong)(tong)(tong)(tong)桿(gan)熔化(hua),在燃燒的過程中(zhong),通(tong)過氧化(hua)和揮發作(zuo)用,可(ke)一定程度(du)減(jian)少部(bu)分雜質進(jin)入(ru)銅(tong)(tong)(tong)(tong)(tong)液(ye),因此連鑄連軋法(fa)對(dui)原(yuan)料要(yao)求(qiu)相對(dui)低(di)一些。上引連鑄生產無氧銅(tong)(tong)(tong)(tong)(tong)桿(gan),由于是用感應(ying)電爐熔化(hua),電解銅(tong)(tong)(tong)(tong)(tong)表面的“銅(tong)(tong)(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)(tong)(tong)豆”基本(ben)都熔入(ru)到銅(tong)(tong)(tong)(tong)(tong)液(ye)中(zhong)。其中(zhong)熔入(ru)的S對(dui)無氧銅(tong)(tong)(tong)(tong)(tong)桿(gan)塑(su)性影響極大(da),會增(zeng)加拉絲斷線率。
2、鑄造(zao)過(guo)程中(zhong)雜質(zhi)的進入(ru)
在生產過(guo)(guo)(guo)程中(zhong),連鑄連軋(ya)工藝需通(tong)過(guo)(guo)(guo)保(bao)溫爐、溜槽、中(zhong)間包轉運銅液,相對(dui)容易造成耐(nai)火(huo)材料(liao)的剝(bo)落,在軋(ya)制過(guo)(guo)(guo)程中(zhong)需要通(tong)過(guo)(guo)(guo)軋(ya)輥,造成鐵質的脫(tuo)落,會給銅桿(gan)造成外部夾雜(za)。而熱軋(ya)中(zhong)皮(pi)上和皮(pi)下氧(yang)化物的軋(ya)入,會給低氧(yang)桿(gan)的拉絲造成不(bu)利(li)的影(ying)響。上引連鑄法生產工藝流(liu)程較(jiao)短,銅液是(shi)通(tong)過(guo)(guo)(guo)聯體爐內潛流(liu)式完成,對(dui)耐(nai)火(huo)材料(liao)的沖擊不(bu)大,結晶是(shi)通(tong)過(guo)(guo)(guo)石墨模(mo)內進行(xing),所(suo)以(yi)過(guo)(guo)(guo)程中(zhong)可能產生的污染源較(jiao)少,雜(za)質進入的機會較(jiao)少。
O、S、P是與銅(tong)(tong)(tong)(tong)會生產化合物的元素。在熔態銅(tong)(tong)(tong)(tong)中,氧(yang)可(ke)以(yi)溶(rong)解(jie)一部分,但(dan)當銅(tong)(tong)(tong)(tong)冷凝時(shi),氧(yang)幾乎不溶(rong)解(jie)于銅(tong)(tong)(tong)(tong)中。熔態時(shi)所溶(rong)解(jie)的氧(yang),以(yi)銅(tong)(tong)(tong)(tong)=氧(yang)化亞(ya)銅(tong)(tong)(tong)(tong)共晶(jing)體析出(chu),分布(bu)在晶(jing)粒晶(jing)界處。銅(tong)(tong)(tong)(tong)-氧(yang)化亞(ya)銅(tong)(tong)(tong)(tong)共晶(jing)體的出(chu)現(xian),顯著降低了銅(tong)(tong)(tong)(tong)的塑性(xing)。
硫(liu)可以(yi)溶解(jie)在(zai)熔體(ti)的(de)銅(tong)中,但在(zai)室(shi)溫下,其(qi)溶解(jie)度幾乎(hu)降(jiang)低(di)到零,它以(yi)硫(liu)化亞(ya)銅(tong)的(de)形式出現在(zai)晶(jing)粒(li)晶(jing)界處,會(hui)顯著降(jiang)低(di)銅(tong)的(de)塑性。
3、氧(yang)(yang)在低氧(yang)(yang)銅(tong)桿(gan)(gan)和無氧(yang)(yang)銅(tong)桿(gan)(gan)中分布形式(shi)及其影響(xiang)
氧(yang)(yang)含量對低氧(yang)(yang)銅(tong)桿的拉線性能有著明顯的影響。當氧(yang)(yang)含量增加(jia)到最佳值時,銅(tong)桿的斷線率(lv)最低。這(zhe)是因為(wei)氧(yang)(yang)在(zai)與大部(bu)分(fen)雜(za)質反(fan)應的過程中都起到了清除(chu)器的作用(yong)。適度的氧(yang)(yang)還有利于去(qu)除(chu)銅(tong)液中的氫,生成水蒸氣溢出,減(jian)少氣孔(kong)的形成。最佳的氧(yang)(yang)含量為(wei)拉線工藝提供了最好的條件。
低(di)氧(yang)(yang)銅(tong)桿氧(yang)(yang)化(hua)物(wu)的(de)(de)分(fen)布:在連續澆鑄中(zhong)凝(ning)固的(de)(de)最初階段,散熱(re)速(su)率和均勻(yun)(yun)冷卻是(shi)決定銅(tong)桿氧(yang)(yang)化(hua)物(wu)分(fen)布的(de)(de)主要因(yin)素。不均勻(yun)(yun)冷卻會引起(qi)銅(tong)桿內部結構本(ben)質上(shang)的(de)(de)差異,但后(hou)續的(de)(de)熱(re)加工,柱(zhu)狀晶通常會遭到破壞,使(shi)氧(yang)(yang)化(hua)亞銅(tong)顆(ke)(ke)粒細微化(hua)和均勻(yun)(yun)分(fen)布。氧(yang)(yang)化(hua)物(wu)顆(ke)(ke)粒聚集而產生的(de)(de)典(dian)型情(qing)況是(shi)中(zhong)心爆裂。除氧(yang)(yang)化(hua)物(wu)顆(ke)(ke)粒分(fen)布的(de)(de)影響外,具有(you)較(jiao)小(xiao)氧(yang)(yang)化(hua)物(wu)顆(ke)(ke)粒的(de)(de)銅(tong)桿顯示出較(jiao)好的(de)(de)拉線(xian)特性,較(jiao)大的(de)(de)Cu2O顆(ke)(ke)粒容(rong)易(yi)造成(cheng)應力集中(zhong)點而斷裂。
無氧銅含(han)氧量(liang)(liang)超(chao)標,銅桿(gan)變脆(cui)(cui),延(yan)伸率下(xia)(xia)降(jiang)(jiang)(jiang),拉伸式樣端口顯暗紅色,結晶組織疏松。當氧含(han)量(liang)(liang)超(chao)出8ppm時(shi),工藝性(xing)能變差,表現為鑄造及拉伸過(guo)程(cheng)中斷桿(gan)及斷線率極具增高(gao)。這(zhe)是由(you)于氧能與銅生(sheng)成(cheng)氧化(hua)亞(ya)銅脆(cui)(cui)性(xing)相(xiang),形(xing)成(cheng)銅-氧化(hua)亞(ya)銅共(gong)晶體,以(yi)網(wang)狀(zhuang)組織分布在境(jing)界上。這(zhe)種脆(cui)(cui)性(xing)相(xiang)硬度高(gao),在冷(leng)變形(xing)時(shi)將會與銅機體脫(tuo)離(li),導致銅桿(gan)的機械性(xing)能下(xia)(xia)降(jiang)(jiang)(jiang),在后續加工中容易造成(cheng)斷裂(lie)現象。氧含(han)量(liang)(liang)高(gao)還(huan)能導致無氧銅桿(gan)導電率下(xia)(xia)降(jiang)(jiang)(jiang)。因此,必須嚴格控(kong)制(zhi)上引連(lian)鑄工藝及產品質量(liang)(liang)。
4、氫的影響
在(zai)上引連鑄中(zhong)(zhong),氧含量(liang)控制(zhi)較低(di),氧化物的(de)(de)副作(zuo)用唄**降低(di),但氫(qing)的(de)(de)影響成為較顯著的(de)(de)問題。吸氣后熔體(ti)中(zhong)(zhong)存在(zai)平衡反(fan)應(ying):H2O(g)=[O]+2[H];
氣(qi)體及疏(shu)松(song)是(shi)在(zai)(zai)(zai)結(jie)晶(jing)的(de)(de)(de)(de)過(guo)程中(zhong),氫(qing)從(cong)過(guo)飽(bao)和(he)(he)(he)的(de)(de)(de)(de)溶(rong)液中(zhong)析出(chu)并(bing)聚集而形(xing)(xing)(xing)(xing)(xing)成(cheng)(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)。在(zai)(zai)(zai)結(jie)晶(jing)前(qian)析出(chu)的(de)(de)(de)(de)氫(qing)又(you)可還原氧化(hua)亞銅(tong)而生成(cheng)(cheng)(cheng)(cheng)(cheng)水氣(qi)泡(pao)。由于(yu)(yu)上(shang)引鑄造(zao)的(de)(de)(de)(de)特點是(shi)銅(tong)液自上(shang)而下的(de)(de)(de)(de)結(jie)晶(jing),形(xing)(xing)(xing)(xing)(xing)成(cheng)(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)液**形(xing)(xing)(xing)(xing)(xing)狀(zhuang)近似錐型。銅(tong)液結(jie)晶(jing)前(qian)析出(chu)的(de)(de)(de)(de)氣(qi)體在(zai)(zai)(zai)上(shang)浮過(guo)程中(zhong)被(bei)堵(du)在(zai)(zai)(zai)凝(ning)固組織內,結(jie)晶(jing)時(shi)在(zai)(zai)(zai)鑄桿內形(xing)(xing)(xing)(xing)(xing)成(cheng)(cheng)(cheng)(cheng)(cheng)氣(qi)孔(kong)。上(shang)引的(de)(de)(de)(de)含(han)氣(qi)量少時(shi),析出(chu)的(de)(de)(de)(de)氫(qing)存在(zai)(zai)(zai)于(yu)(yu)晶(jing)界(jie)處,形(xing)(xing)(xing)(xing)(xing)成(cheng)(cheng)(cheng)(cheng)(cheng)疏(shu)松(song);含(han)氣(qi)量多(duo)時(shi),則(ze)聚集成(cheng)(cheng)(cheng)(cheng)(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和(he)(he)(he)疏(shu)松(song)是(shi)氫(qing)氣(qi)和(he)(he)(he)水蒸(zheng)氣(qi)兩者形(xing)(xing)(xing)(xing)(xing)成(cheng)(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)。
氫來(lai)源于(yu)上引(yin)生產過程中(zhong)的(de)各個(ge)工藝環(huan)節,如原料電解銅(tong)的(de)“銅(tong)綠”、輔料木(mu)炭**、氣(qi)候環(huan)境**、石墨結晶器未干燥(zao)等。因此,熔化(hua)爐中(zhong)的(de)銅(tong)液表面應覆蓋經烘烤的(de)木(mu)炭,電解銅(tong)應盡量去除“銅(tong)綠”、“銅(tong)豆(dou)”“耳朵”,對提高無氧銅(tong)桿(gan)質量非常重要。
在(zai)連鑄連軋工藝(yi)中(zhong),往往采用(yong)適度控制氧含量來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O
由(you)于(yu)銅液(ye)在鑄造(zao)過程中是自下(xia)而(er)(er)上(shang)結晶(jing),銅液(ye)中的(de)氧和(he)氫所產生(sheng)的(de)水蒸氣很容易上(shang)浮跑出,銅液(ye)中的(de)氫大部分能被有(you)效(xiao)去(qu)除,因而(er)(er)對銅桿的(de)影(ying)響較小。
二、表面質量
在生(sheng)產電(dian)磁線等(deng)產品的(de)(de)過程中,對(dui)銅桿的(de)(de)表面(mian)質(zhi)量也(ye)需提出要(yao)求。需要(yao)拉制后(hou)的(de)(de)銅絲表面(mian)無毛刺、銅粉少、無油污。并通過扭轉試驗測量表面(mian)銅粉的(de)(de)質(zhi)量和扭轉后(hou)觀察銅桿的(de)(de)復原情況來判定其好(hao)壞。
在(zai)連鑄(zhu)(zhu)連軋(ya)(ya)過程中,從鑄(zhu)(zhu)造到軋(ya)(ya)制(zhi)前,溫(wen)度高,完全暴露于(yu)空氣中,使(shi)鑄(zhu)(zhu)坯(pi)表面(mian)形(xing)成較厚的(de)(de)(de)氧(yang)化(hua)層,在(zai)軋(ya)(ya)制(zhi)過程中,隨著軋(ya)(ya)輥的(de)(de)(de)轉(zhuan)動,氧(yang)化(hua)物(wu)(wu)顆粒軋(ya)(ya)入銅線表面(mian)。由于(yu)氧(yang)化(hua)亞銅是(shi)高熔點脆性化(hua)合物(wu)(wu),對于(yu)軋(ya)(ya)入較深的(de)(de)(de)氧(yang)化(hua)亞銅,當成條狀(zhuang)的(de)(de)(de)聚(ju)集(ji)物(wu)(wu)遇模具拉(la)伸時(shi),就會是(shi)銅桿(gan)外表面(mian)產生毛刺(ci),給(gei)后(hou)續的(de)(de)(de)涂漆造成麻煩。
而上引連鑄工藝制(zhi)造(zao)(zao)的無(wu)氧(yang)銅(tong)桿,由(you)于鑄造(zao)(zao)和冷(leng)卻完(wan)全(quan)與氧(yang)隔絕,后(hou)續亦無(wu)熱(re)軋過(guo)程,銅(tong)桿表(biao)面無(wu)軋入表(biao)面的氧(yang)化物,質量較(jiao)好,拉制(zhi)后(hou)銅(tong)粉少,上述(shu)問題較(jiao)少存(cun)在(zai)。
無氧銅(tong)桿(gan)(gan)也(ye)分進(jin)口設備(bei)做(zuo)的(de)(de)和國產(chan)(chan)設備(bei)做(zuo)的(de)(de),但目前(qian)進(jin)口產(chan)(chan)品已無明(ming)顯(xian)優勢,銅(tong)桿(gan)(gan)產(chan)(chan)品出(chu)(chu)來后區別(bie)不(bu)是很大,只(zhi)要銅(tong)板選的(de)(de)好(hao),生產(chan)(chan)控制比(bi)較穩定(ding),國產(chan)(chan)設備(bei)也(ye)能產(chan)(chan)出(chu)(chu)可拉伸0.05的(de)(de)銅(tong)桿(gan)(gan).進(jin)口設備(bei)一般是芬蘭奧(ao)托(tuo)昆普的(de)(de)設備(bei),國產(chan)(chan)設備(bei)最(zui)好(hao)的(de)(de)應該是上海的(de)(de)海軍廠的(de)(de)了,生產(chan)(chan)時間最(zui)長,軍工(gong)企業,質(zhi)量可靠(kao)。
低(di)氧(yang)銅桿進口設備國(guo)際主要有(you)兩(liang)種(zhong),一種(zhong)是(shi)美國(guo)南線(xian)設備,英(ying)文是(shi)SOUTHWIRE,國(guo)內(nei)廠家是(shi)南京華新(xin),江西(xi)銅業,另(ling)一種(zhong)是(shi)德國(guo)CONTIROD設備,國(guo)內(nei)廠家是(shi)常州(zhou)金(jin)源,天津大無(wu)縫。
無(wu)氧(yang)(yang)(yang)及低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上(shang)容易區別,無(wu)氧(yang)(yang)(yang)銅(tong)是(shi)(shi)含氧(yang)(yang)(yang)量在(zai)10-20個PPM以下,但(dan)目前(qian)有的(de)廠家只(zhi)能(neng)(neng)做到50個PPM以下.低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)桿(gan)(gan)(gan)子(zi)一般(ban)含氧(yang)(yang)(yang)量控制在(zai)250個PPM左右(you),無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)一般(ban)采取的(de)是(shi)(shi)上(shang)引法,低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)(shi)連鑄連軋,兩(liang)種產品相對而言低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對漆包(bao)線性(xing)(xing) 能(neng)(neng)更(geng)適(shi)應些,如(ru)(ru)柔軟性(xing)(xing),回彈角,繞線性(xing)(xing)能(neng)(neng).但(dan)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對拉(la)(la)絲條件相對要苛刻(ke)些,同(tong)樣拉(la)(la)伸(shen)(shen)0.2的(de)細(xi)絲,如(ru)(ru)果伸(shen)(shen)線條件不(bu)好(hao),普通(tong)的(de)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)(la)而好(hao)的(de)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就斷 線,但(dan)如(ru)(ru)果放在(zai)好(hao)的(de)伸(shen)(shen)線條件,同(tong)樣的(de)桿(gan)(gan)(gan)子(zi),低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不(bu)定就能(neng)(neng)拉(la)(la)到雙零五,而普通(tong)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)最多只(zhi)能(neng)(neng)拉(la)(la)伸(shen)(shen)到0.1而已,當然做的(de)最細(xi)的(de)如(ru)(ru)雙零二卻非得依(yi)靠進口(kou)的(de) 無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)了.目前(qian)有企(qi)業嘗試用剝皮(pi)的(de)方式(shi)來處理低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)(shen)0.03線.但(dan)有關(guan)這方面的(de)內(nei)容我還不(bu)是(shi)(shi)很清(qing)楚。
音響線一(yi)般(ban)反而喜歡用無(wu)氧桿(gan),這(zhe)和(he)無(wu)氧桿(gan)是單(dan)晶銅(tong),低氧桿(gan)是多晶銅(tong)有(you)關。
氧銅桿和無氧銅桿由于制造方(fang)法(fa)的(de)不(bu)同,致使存在差別,具有各自的(de)特點。
一(yi)、關于氧的(de)(de)吸入和脫去以及它的(de)(de)存在狀態
生產銅(tong)(tong)桿(gan)的(de)(de)陰極(ji)銅(tong)(tong)的(de)(de)含氧(yang)(yang)(yang)量(liang)一(yi)(yi)般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)溫下氧(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)中的(de)(de)固溶度約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)含氧(yang)(yang)(yang)量(liang)一(yi)(yi)般(ban)在(zai)(zai)200(175)—400(450)ppm,因此(ci)氧(yang)(yang)(yang)的(de)(de)進入(ru)是在(zai)(zai)銅(tong)(tong)的(de)(de)液態下吸入(ru)的(de)(de),而上引法無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)則相(xiang)(xiang)反,氧(yang)(yang)(yang)在(zai)(zai)液態銅(tong)(tong)下保持相(xiang)(xiang)當時(shi)間(jian)后,被還原(yuan)而脫去,通常(chang)這(zhe)種桿(gan)的(de)(de)含氧(yang)(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以下,最(zui)低(di)(di)(di)可達1-2ppm,從組織上看,低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)中的(de)(de)氧(yang)(yang)(yang),以氧(yang)(yang)(yang)化(hua)銅(tong)(tong)狀態,存在(zai)(zai)于晶(jing)粒邊(bian)界附近,這(zhe)對低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)而言可以說是常(chang)見(jian)(jian)的(de)(de)但對無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)則很(hen)少見(jian)(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)以夾雜(za)形式在(zai)(zai)晶(jing)界出現對材料的(de)(de)韌性產生負面影響(xiang)。而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)中的(de)(de)氧(yang)(yang)(yang)很(hen)低(di)(di)(di),所(suo)以這(zhe)種銅(tong)(tong)的(de)(de)組織是均(jun)勻的(de)(de)單相(xiang)(xiang)組織對韌性有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)中的(de)(de)多孔性是不常(chang)見(jian)(jian)的(de)(de),而在(zai)(zai)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)中則是常(chang)見(jian)(jian)的(de)(de)一(yi)(yi)種缺(que)陷。
二、熱軋組(zu)織(zhi)和鑄造組(zu)織(zhi)的區別
低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)由于(yu)經(jing)過熱軋,所(suo)以(yi)其(qi)組(zu)(zu)織(zhi)屬熱加工組(zu)(zu)織(zhi),原來的鑄造(zao)組(zu)(zu)織(zhi)已經(jing)破(po)碎,在(zai)(zai)8mm的桿(gan)時已有(you)再(zai)結(jie)晶(jing)(jing)的形(xing)式出現,而無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)屬鑄造(zao)組(zu)(zu)織(zhi),晶(jing)(jing)粒(li)(li)粗大,這(zhe)是(shi)為(wei)什(shen)么,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)的再(zai)結(jie)晶(jing)(jing)溫度較高(gao)(gao),需要(yao)較高(gao)(gao)退火(huo)(huo)(huo)溫度的固(gu)有(you)原因。這(zhe)是(shi)因為(wei),再(zai)結(jie)晶(jing)(jing)發生(sheng)在(zai)(zai)晶(jing)(jing)粒(li)(li)邊(bian)(bian)(bian)界(jie)附近,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)組(zu)(zu)織(zhi)晶(jing)(jing)粒(li)(li)粗大,晶(jing)(jing)粒(li)(li)尺寸甚至能(neng)達幾個毫米,因而晶(jing)(jing)粒(li)(li)邊(bian)(bian)(bian)界(jie)少(shao),即使通過拉(la)制變形(xing),但(dan)晶(jing)(jing)粒(li)(li)邊(bian)(bian)(bian)界(jie)相對(dui)(dui)(dui)低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)還是(shi)較少(shao),所(suo)以(yi)需要(yao)較高(gao)(gao)的退火(huo)(huo)(huo)功(gong)率(lv)。對(dui)(dui)(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)成功(gong)的退火(huo)(huo)(huo)要(yao)求是(shi):由桿(gan)經(jing)拉(la)制,但(dan)尚(shang)未鑄造(zao)組(zu)(zu)織(zhi)的線(xian)時的第(di)一次退火(huo)(huo)(huo),其(qi)退火(huo)(huo)(huo)功(gong)率(lv)應(ying)比(bi)同(tong)樣情況(kuang)的低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)高(gao)(gao)10——15%。經(jing)繼續拉(la)制,在(zai)(zai)以(yi)后(hou)階段(duan)的退火(huo)(huo)(huo)功(gong)率(lv)應(ying)留有(you)足夠的余量和(he)對(dui)(dui)(dui)低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)和(he)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)切實(shi)區(qu)別(bie)執行不同(tong)的退火(huo)(huo)(huo)工藝(yi),以(yi)保證在(zai)(zai)制品(pin)和(he)成品(pin)導線(xian)的柔軟(ruan)性。
三(san)、夾雜,氧(yang)含量波動,表面氧(yang)化物和可能存在的(de)熱軋缺陷(xian)的(de)差別
無氧(yang)銅(tong)桿(gan)的(de)(de)(de)可(ke)(ke)拉性(xing)在(zai)所(suo)有(you)線(xian)徑里與低氧(yang)銅(tong)桿(gan)相比(bi)(bi)都是優越(yue)的(de)(de)(de),除(chu)上述組織原因外,無氧(yang)銅(tong)桿(gan)夾雜少,含(han)氧(yang)量穩定(ding),無熱軋可(ke)(ke)能產(chan)生的(de)(de)(de)缺陷(xian),桿(gan)表氧(yang)化(hua)物厚度可(ke)(ke)達≤15A。在(zai)連(lian)鑄(zhu)連(lian)軋生產(chan)過(guo)程中(zhong)如(ru)果工藝(yi)不穩定(ding),對氧(yang)監(jian)控(kong)不嚴,含(han)氧(yang)量不穩定(ding)將直接影(ying)響(xiang)桿(gan)的(de)(de)(de)性(xing)能。如(ru)果桿(gan)的(de)(de)(de)表面氧(yang)化(hua)物能在(zai)后工序的(de)(de)(de)連(lian)續(xu)清洗中(zhong)得(de)(de)以彌補外,但比(bi)(bi)較麻煩的(de)(de)(de)是有(you)相當多的(de)(de)(de)氧(yang)化(hua)物存在(zai)于“皮下(xia)”,對拉線(xian)斷(duan)線(xian)影(ying)響(xiang)更直接,故而在(zai)拉制微細線(xian),超微細線(xian)時,為了減少斷(duan)線(xian),有(you)時要對銅(tong)桿(gan)采(cai)取不得(de)(de)已的(de)(de)(de)辦法(fa)——剝皮,甚至二次(ci)剝皮的(de)(de)(de)原因所(suo)在(zai),目的(de)(de)(de)要除(chu)去皮下(xia)氧(yang)化(hua)物。
四、低氧銅(tong)(tong)桿(gan)(gan)和(he)無氧銅(tong)(tong)桿(gan)(gan)的韌性有差(cha)別
兩者都可以拉到0.015mm,但在低溫超導(dao)線中的(de)低溫級無(wu)氧銅,其細絲(si)間的(de)間距只有(you)0.001mm.
五、從制(zhi)桿的原(yuan)材料(liao)到制(zhi)線的經濟性有差別(bie)。
制造無氧(yang)(yang)銅桿(gan)(gan)要(yao)求(qiu)質(zhi)量較高的原材料。一般,拉(la)制直(zhi)徑>1mm的銅線(xian)時,低(di)氧(yang)(yang)銅桿(gan)(gan)的優點比較明顯,而無氧(yang)(yang)銅桿(gan)(gan)顯得更為優越的是拉(la)制直(zhi)徑<0.5mm的銅線(xian)。
六(liu)、低氧銅桿的(de)制線(xian)工藝與無氧銅桿的(de)有所不同。
低(di)氧(yang)(yang)銅(tong)桿(gan)的(de)制(zhi)線(xian)工(gong)藝(yi)不能照搬到(dao)無氧(yang)(yang)銅(tong)桿(gan)的(de)制(zhi)線(xian)工(gong)藝(yi)上來,至少兩者的(de)退(tui)火工(gong)藝(yi)是不同的(de)。因為線(xian)的(de)柔(rou)軟(ruan)性(xing)深受(shou)材料成(cheng)份和(he)制(zhi)桿(gan),制(zhi)線(xian)和(he)退(tui)火工(gong)藝(yi)的(de)影響(xiang),不能簡單地說低(di)氧(yang)(yang)銅(tong)或無氧(yang)(yang)銅(tong)誰軟(ruan)誰硬。
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