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甘井子電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態(tai) 閱讀:109339 發布時間:2019-07-05

導讀:由于生產(chan)銅(tong)桿(gan)的兩者的工(gong)藝不同,所生產(chan)的銅(tong)桿(gan)中的含氧(yang)量(liang)及外觀就不同。上(shang)引生產(chan)的銅(tong)桿(gan),工(gong)藝得(de)當氧(yang)含量(liang)在(zai)10ppm以(yi)下,叫無氧(yang)銅(tong)桿(gan);連鑄連鑄生產(chan)的銅(tong)桿(gan) 是在(zai)保護條件下的熱軋,氧(yang)含量(liang)在(zai)200-500ppm范圍內(nei),但有時(shi)也高達(da)700ppm以(yi)上(shang),一般情況(kuang)下,此種(zhong)方法生產(chan)的銅(tong)外表光亮,低氧(yang)銅(tong)桿(gan),有時(shi)也叫光桿(gan)。

銅桿是電(dian)纜行(xing)(xing)業的(de)(de)(de)主要原料,生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)方式(shi)主要有兩種——連鑄(zhu)(zhu)連軋(ya)(ya)(ya)法(fa)和(he)上引(yin)連鑄(zhu)(zhu)法(fa)。連鑄(zhu)(zhu)連軋(ya)(ya)(ya)低氧(yang)銅桿的(de)(de)(de)生(sheng)(sheng)(sheng)產(chan)(chan)方法(fa)較(jiao)多(duo),其特點(dian)是金屬(shu)在(zai)豎爐(lu)(lu)中(zhong)融(rong)化(hua)后,銅液通過保溫(wen)爐(lu)(lu)、溜槽、中(zhong)間包,從(cong)澆管進(jin)入(ru)封閉的(de)(de)(de)模(mo)腔內,采用較(jiao)大的(de)(de)(de)冷(leng)卻(que)強度進(jin)行(xing)(xing)冷(leng)卻(que),形(xing)成鑄(zhu)(zhu)坯,然(ran)后進(jin)行(xing)(xing)多(duo)道次(ci)軋(ya)(ya)(ya)制,生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)低氧(yang)銅桿為熱(re)加工(gong)組(zu)織,原來的(de)(de)(de)鑄(zhu)(zhu)造(zao)組(zu)織已經破(po)碎,含(han)(han)氧(yang)量一般為200~400ppm之間。無氧(yang)銅桿國(guo)內基(ji)本全部采用上引(yin)連鑄(zhu)(zhu)法(fa)生(sheng)(sheng)(sheng)產(chan)(chan),金屬(shu)在(zai)感應電(dian)爐(lu)(lu)中(zhong)融(rong)化(hua)后通過石墨模(mo)進(jin)行(xing)(xing)上引(yin)連續鑄(zhu)(zhu)造(zao),之后進(jin)行(xing)(xing)冷(leng)軋(ya)(ya)(ya)或冷(leng)加工(gong),生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)無氧(yang)銅桿為鑄(zhu)(zhu)造(zao)組(zu)織,含(han)(han)氧(yang)量一般在(zai)20ppm以(yi)下。由(you)于制造(zao)工(gong)藝的(de)(de)(de)不同,所以(yi)在(zai)組(zu)織結(jie)構(gou)、氧(yang)含(han)(han)量分(fen)布、雜(za)質的(de)(de)(de)形(xing)式(shi)及分(fen)布等諸多(duo)方面有較(jiao)大差別。

一、拉制性能

銅(tong)桿的拉(la)制性能跟很多因素(su)有關,如雜質的含量(liang)、氧(yang)含量(liang)及分(fen)布、工(gong)藝控制等。下(xia)面分(fen)別(bie)從(cong)以上幾個(ge)方(fang)面對銅(tong)桿的拉(la)制性能進行分(fen)析。

1、熔化方式對S等(deng)雜(za)質的影響

連鑄連軋生產(chan)銅(tong)(tong)桿主要是通(tong)過氣體的燃燒使銅(tong)(tong)桿熔(rong)(rong)化(hua),在燃燒的過程中(zhong),通(tong)過氧化(hua)和(he)揮(hui)發作用,可(ke)一定程度減少部(bu)分雜(za)質進入(ru)(ru)銅(tong)(tong)液,因此連鑄連軋法對(dui)(dui)(dui)原料要求相對(dui)(dui)(dui)低一些。上引(yin)連鑄生產(chan)無(wu)氧銅(tong)(tong)桿,由于(yu)是用感應電爐熔(rong)(rong)化(hua),電解銅(tong)(tong)表面的“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都熔(rong)(rong)入(ru)(ru)到銅(tong)(tong)液中(zhong)。其中(zhong)熔(rong)(rong)入(ru)(ru)的S對(dui)(dui)(dui)無(wu)氧銅(tong)(tong)桿塑性影響(xiang)極(ji)大,會增加拉絲斷線率。

2、鑄造(zao)過程中雜質(zhi)的進入

在生產過(guo)程(cheng)(cheng)中,連(lian)(lian)鑄連(lian)(lian)軋(ya)工藝需通過(guo)保溫爐、溜槽、中間(jian)包(bao)轉運(yun)銅(tong)(tong)(tong)液,相對容易造(zao)成(cheng)(cheng)耐火(huo)材料的(de)(de)剝(bo)落,在軋(ya)制過(guo)程(cheng)(cheng)中需要通過(guo)軋(ya)輥,造(zao)成(cheng)(cheng)鐵質的(de)(de)脫落,會給銅(tong)(tong)(tong)桿造(zao)成(cheng)(cheng)外部夾雜。而(er)熱軋(ya)中皮(pi)上和皮(pi)下氧(yang)化物的(de)(de)軋(ya)入(ru),會給低(di)氧(yang)桿的(de)(de)拉絲造(zao)成(cheng)(cheng)不(bu)利(li)的(de)(de)影(ying)響(xiang)。上引連(lian)(lian)鑄法生產工藝流程(cheng)(cheng)較短,銅(tong)(tong)(tong)液是(shi)通過(guo)聯體爐內(nei)潛流式完成(cheng)(cheng),對耐火(huo)材料的(de)(de)沖(chong)擊不(bu)大,結晶是(shi)通過(guo)石墨模內(nei)進(jin)行(xing),所以過(guo)程(cheng)(cheng)中可能產生的(de)(de)污染(ran)源較少,雜質進(jin)入(ru)的(de)(de)機(ji)會較少。

O、S、P是與銅(tong)(tong)(tong)會生產化合物的元素。在熔(rong)態(tai)銅(tong)(tong)(tong)中(zhong),氧可以溶(rong)解一部分(fen),但當(dang)銅(tong)(tong)(tong)冷凝時,氧幾乎不(bu)溶(rong)解于(yu)銅(tong)(tong)(tong)中(zhong)。熔(rong)態(tai)時所溶(rong)解的氧,以銅(tong)(tong)(tong)=氧化亞(ya)銅(tong)(tong)(tong)共(gong)晶(jing)體析(xi)出,分(fen)布(bu)在晶(jing)粒晶(jing)界處。銅(tong)(tong)(tong)-氧化亞(ya)銅(tong)(tong)(tong)共(gong)晶(jing)體的出現,顯(xian)著降(jiang)低了(le)銅(tong)(tong)(tong)的塑性。

硫可以(yi)溶解在(zai)(zai)熔體(ti)的(de)銅中,但在(zai)(zai)室溫下,其溶解度幾乎降低到(dao)零,它(ta)以(yi)硫化亞銅的(de)形式出現在(zai)(zai)晶粒晶界(jie)處,會顯著降低銅的(de)塑性。

3、氧在低氧銅桿和無(wu)氧銅桿中分(fen)布形式及其影響

氧(yang)(yang)含(han)(han)量(liang)對(dui)低(di)氧(yang)(yang)銅(tong)桿的拉線(xian)性能有著明顯的影響。當(dang)氧(yang)(yang)含(han)(han)量(liang)增加(jia)到最佳值時(shi),銅(tong)桿的斷(duan)線(xian)率最低(di)。這是因為(wei)(wei)氧(yang)(yang)在(zai)與大(da)部分雜質反應的過程中(zhong)都起(qi)到了清除(chu)器的作用。適(shi)度的氧(yang)(yang)還有利(li)于去除(chu)銅(tong)液中(zhong)的氫,生成水蒸氣溢出,減少氣孔的形成。最佳的氧(yang)(yang)含(han)(han)量(liang)為(wei)(wei)拉線(xian)工藝提供(gong)了最好(hao)的條件。

低氧(yang)(yang)銅(tong)桿(gan)(gan)氧(yang)(yang)化物的(de)分(fen)布:在連(lian)續(xu)澆鑄中凝固的(de)最初階段,散熱(re)速率和均(jun)勻冷卻是(shi)決(jue)定銅(tong)桿(gan)(gan)氧(yang)(yang)化物分(fen)布的(de)主要(yao)因素。不均(jun)勻冷卻會(hui)引起(qi)銅(tong)桿(gan)(gan)內部結構本質上的(de)差異(yi),但后(hou)續(xu)的(de)熱(re)加工,柱狀晶通常會(hui)遭到破壞,使(shi)氧(yang)(yang)化亞銅(tong)顆(ke)粒細(xi)微化和均(jun)勻分(fen)布。氧(yang)(yang)化物顆(ke)粒聚集而(er)產生的(de)典型情況是(shi)中心爆裂。除氧(yang)(yang)化物顆(ke)粒分(fen)布的(de)影響外,具有較(jiao)小氧(yang)(yang)化物顆(ke)粒的(de)銅(tong)桿(gan)(gan)顯示出較(jiao)好的(de)拉線特性,較(jiao)大的(de)Cu2O顆(ke)粒容易造成應(ying)力集中點而(er)斷裂。

無氧(yang)銅(tong)(tong)(tong)含(han)氧(yang)量(liang)超標,銅(tong)(tong)(tong)桿(gan)變脆,延伸(shen)率下降(jiang)(jiang),拉伸(shen)式(shi)樣(yang)端(duan)口(kou)顯暗紅(hong)色(se),結晶(jing)組(zu)織(zhi)疏(shu)松。當氧(yang)含(han)量(liang)超出8ppm時(shi),工(gong)藝性(xing)能變差,表現(xian)為鑄造及(ji)拉伸(shen)過程中斷(duan)桿(gan)及(ji)斷(duan)線率極(ji)具(ju)增高(gao)。這(zhe)是由于氧(yang)能與(yu)銅(tong)(tong)(tong)生成(cheng)氧(yang)化(hua)(hua)亞銅(tong)(tong)(tong)脆性(xing)相,形成(cheng)銅(tong)(tong)(tong)-氧(yang)化(hua)(hua)亞銅(tong)(tong)(tong)共(gong)晶(jing)體,以網狀組(zu)織(zhi)分布在境界上(shang)。這(zhe)種脆性(xing)相硬度高(gao),在冷變形時(shi)將會(hui)與(yu)銅(tong)(tong)(tong)機體脫離(li),導致(zhi)銅(tong)(tong)(tong)桿(gan)的機械性(xing)能下降(jiang)(jiang),在后續加工(gong)中容易(yi)造成(cheng)斷(duan)裂現(xian)象(xiang)。氧(yang)含(han)量(liang)高(gao)還能導致(zhi)無氧(yang)銅(tong)(tong)(tong)桿(gan)導電(dian)率下降(jiang)(jiang)。因(yin)此,必須嚴格控制上(shang)引連鑄工(gong)藝及(ji)產品(pin)質量(liang)。

4、氫的影響

在上引連鑄(zhu)中,氧含量(liang)控制較低,氧化物的(de)副作用唄**降低,但氫的(de)影(ying)響(xiang)成為較顯著的(de)問(wen)題。吸氣后熔(rong)體中存在平衡反應(ying):H2O(g)=[O]+2[H];

氣(qi)體及疏松是在(zai)(zai)結(jie)(jie)晶的(de)(de)過程中,氫(qing)從過飽和的(de)(de)溶液中析(xi)(xi)出(chu)并聚(ju)集(ji)而(er)形(xing)(xing)成(cheng)的(de)(de)。在(zai)(zai)結(jie)(jie)晶前(qian)析(xi)(xi)出(chu)的(de)(de)氫(qing)又可(ke)還(huan)原(yuan)氧(yang)化亞銅(tong)而(er)生成(cheng)水氣(qi)泡(pao)。由于上(shang)(shang)引鑄造的(de)(de)特點是銅(tong)液自上(shang)(shang)而(er)下的(de)(de)結(jie)(jie)晶,形(xing)(xing)成(cheng)的(de)(de)液**形(xing)(xing)狀近似錐(zhui)型。銅(tong)液結(jie)(jie)晶前(qian)析(xi)(xi)出(chu)的(de)(de)氣(qi)體在(zai)(zai)上(shang)(shang)浮過程中被堵在(zai)(zai)凝固組織內,結(jie)(jie)晶時在(zai)(zai)鑄桿內形(xing)(xing)成(cheng)氣(qi)孔。上(shang)(shang)引的(de)(de)含(han)氣(qi)量少時,析(xi)(xi)出(chu)的(de)(de)氫(qing)存在(zai)(zai)于晶界處(chu),形(xing)(xing)成(cheng)疏松;含(han)氣(qi)量多時,則聚(ju)集(ji)成(cheng)氣(qi)孔,因此(ci),氣(qi)孔和疏松是氫(qing)氣(qi)和水蒸(zheng)氣(qi)兩(liang)者形(xing)(xing)成(cheng)的(de)(de)。

氫來源于(yu)上引生產過程(cheng)中的各個工藝環(huan)節,如原(yuan)料電解(jie)銅(tong)的“銅(tong)綠”、輔料木炭**、氣(qi)候環(huan)境**、石墨(mo)結晶器未干(gan)燥(zao)等(deng)。因此(ci),熔化爐(lu)中的銅(tong)液表面應覆蓋經(jing)烘烤的木炭,電解(jie)銅(tong)應盡量(liang)去(qu)除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對提(ti)高無(wu)氧銅(tong)桿質量(liang)非常(chang)重(zhong)要。

在連鑄連軋工藝中,往往采用(yong)適(shi)度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由(you)于(yu)銅(tong)(tong)(tong)液在鑄(zhu)造過程中是自(zi)下而(er)上結晶,銅(tong)(tong)(tong)液中的(de)氧和氫所產生的(de)水(shui)蒸氣很(hen)容易上浮跑出,銅(tong)(tong)(tong)液中的(de)氫大(da)部(bu)分能被(bei)有(you)效去(qu)除,因而(er)對銅(tong)(tong)(tong)桿的(de)影響(xiang)較小(xiao)。

二、表面質量

在生(sheng)產電磁線等產品的過程中(zhong),對銅(tong)(tong)桿的表(biao)面質(zhi)量(liang)也(ye)需提出要求。需要拉制(zhi)后的銅(tong)(tong)絲表(biao)面無毛刺、銅(tong)(tong)粉(fen)少(shao)、無油污。并(bing)通過扭(niu)轉試驗(yan)測量(liang)表(biao)面銅(tong)(tong)粉(fen)的質(zhi)量(liang)和扭(niu)轉后觀察(cha)銅(tong)(tong)桿的復原情況(kuang)來判定其好壞。

在連鑄連軋過(guo)程中,從(cong)鑄造(zao)到軋制前,溫度高,完全暴露(lu)于空氣中,使鑄坯表面形成較厚的(de)氧(yang)化(hua)層(ceng),在軋制過(guo)程中,隨著軋輥的(de)轉動,氧(yang)化(hua)物顆粒(li)軋入銅線表面。由于氧(yang)化(hua)亞(ya)銅是高熔(rong)點脆性化(hua)合物,對于軋入較深(shen)的(de)氧(yang)化(hua)亞(ya)銅,當成條狀的(de)聚(ju)集物遇模具拉伸(shen)時,就(jiu)會(hui)是銅桿外表面產生(sheng)毛刺(ci),給后續的(de)涂漆造(zao)成麻煩。

而上(shang)(shang)引連鑄工藝制造的(de)無(wu)氧(yang)銅桿,由于鑄造和冷卻完全(quan)與氧(yang)隔(ge)絕,后(hou)續亦無(wu)熱軋過程,銅桿表(biao)面(mian)無(wu)軋入(ru)表(biao)面(mian)的(de)氧(yang)化物,質量較好,拉制后(hou)銅粉少,上(shang)(shang)述(shu)問(wen)題較少存在。

無(wu)氧銅桿也(ye)分進(jin)口(kou)(kou)設(she)備做的和國(guo)產(chan)(chan)(chan)設(she)備做的,但目(mu)前進(jin)口(kou)(kou)產(chan)(chan)(chan)品(pin)(pin)已無(wu)明顯優勢,銅桿產(chan)(chan)(chan)品(pin)(pin)出來(lai)后區(qu)別不是很大(da),只要銅板(ban)選(xuan)的好,生產(chan)(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)(chan)設(she)備也(ye)能(neng)產(chan)(chan)(chan)出可(ke)(ke)拉伸0.05的銅桿.進(jin)口(kou)(kou)設(she)備一(yi)般是芬(fen)蘭奧托昆普的設(she)備,國(guo)產(chan)(chan)(chan)設(she)備最好的應該是上海(hai)的海(hai)軍廠的了,生產(chan)(chan)(chan)時(shi)間(jian)最長,軍工企業,質量(liang)可(ke)(ke)靠。

低氧銅(tong)桿進口設(she)備(bei)(bei)國(guo)(guo)際主要(yao)有兩種(zhong),一種(zhong)是(shi)(shi)美(mei)國(guo)(guo)南線設(she)備(bei)(bei),英(ying)文(wen)是(shi)(shi)SOUTHWIRE,國(guo)(guo)內(nei)廠(chang)家(jia)是(shi)(shi)南京華新(xin),江西銅(tong)業,另一種(zhong)是(shi)(shi)德國(guo)(guo)CONTIROD設(she)備(bei)(bei),國(guo)(guo)內(nei)廠(chang)家(jia)是(shi)(shi)常州(zhou)金源,天(tian)津(jin)大無縫。

無(wu)氧(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上(shang)容易區(qu)別,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)是(shi)含氧(yang)(yang)(yang)量在10-20個(ge)(ge)PPM以下,但(dan)目前有的(de)(de)廠家只(zhi)能(neng)(neng)做到50個(ge)(ge)PPM以下.低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)(gan)在 200-400個(ge)(ge)PPM,好(hao)的(de)(de)桿(gan)(gan)(gan)(gan)(gan)子一般含氧(yang)(yang)(yang)量控制在250個(ge)(ge)PPM左(zuo)右,無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)一般采取的(de)(de)是(shi)上(shang)引法,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)是(shi)連(lian)(lian)鑄連(lian)(lian)軋,兩(liang)種產品(pin)相(xiang)對而(er)言低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對漆包線(xian)(xian)(xian)性 能(neng)(neng)更適應些(xie),如柔軟(ruan)性,回彈(dan)角,繞線(xian)(xian)(xian)性能(neng)(neng).但(dan)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對拉絲(si)條(tiao)件(jian)相(xiang)對要苛刻些(xie),同樣(yang)拉伸(shen)(shen)(shen)0.2的(de)(de)細絲(si),如果伸(shen)(shen)(shen)線(xian)(xian)(xian)條(tiao)件(jian)不好(hao),普(pu)通的(de)(de)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)可拉而(er)好(hao)的(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)就(jiu)斷 線(xian)(xian)(xian),但(dan)如果放在好(hao)的(de)(de)伸(shen)(shen)(shen)線(xian)(xian)(xian)條(tiao)件(jian),同樣(yang)的(de)(de)桿(gan)(gan)(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)說不定就(jiu)能(neng)(neng)拉到雙零五,而(er)普(pu)通無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)最多只(zhi)能(neng)(neng)拉伸(shen)(shen)(shen)到0.1而(er)已,當然做的(de)(de)最細的(de)(de)如雙零二卻非得(de)依靠進口的(de)(de) 無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)(gan)了.目前有企業(ye)嘗試用剝皮的(de)(de)方式來處理低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)來伸(shen)(shen)(shen)0.03線(xian)(xian)(xian).但(dan)有關這方面的(de)(de)內容我(wo)還不是(shi)很(hen)清(qing)楚(chu)。

音(yin)響線(xian)一般反(fan)而喜歡用無氧桿,這和無氧桿是單晶(jing)銅(tong),低氧桿是多晶(jing)銅(tong)有(you)關(guan)。

氧銅(tong)桿(gan)和無氧銅(tong)桿(gan)由于制造方法的不(bu)同,致使存在(zai)差別,具(ju)有各自的特點。

一、關于氧(yang)的吸(xi)入和脫去(qu)以(yi)及它的存在狀態

生(sheng)產銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)陰極銅(tong)(tong)(tong)的(de)(de)(de)含氧(yang)(yang)(yang)量(liang)一般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)溫下(xia)氧(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)中的(de)(de)(de)固溶度約2ppm。低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)含氧(yang)(yang)(yang)量(liang)一般在(zai)(zai)(zai)200(175)—400(450)ppm,因(yin)此(ci)氧(yang)(yang)(yang)的(de)(de)(de)進入(ru)是(shi)在(zai)(zai)(zai)銅(tong)(tong)(tong)的(de)(de)(de)液態(tai)下(xia)吸(xi)入(ru)的(de)(de)(de),而上引法無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)則相(xiang)反(fan),氧(yang)(yang)(yang)在(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)下(xia)保持相(xiang)當時間(jian)后,被還(huan)原(yuan)而脫去,通常(chang)這種(zhong)桿(gan)(gan)(gan)的(de)(de)(de)含氧(yang)(yang)(yang)量(liang)都在(zai)(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低(di)(di)可(ke)(ke)達1-2ppm,從組織上看,低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)于晶粒邊界附(fu)近,這對低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)而言可(ke)(ke)以(yi)(yi)說是(shi)常(chang)見(jian)的(de)(de)(de)但對無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)則很(hen)少見(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)以(yi)(yi)夾雜形式(shi)在(zai)(zai)(zai)晶界出現對材料的(de)(de)(de)韌(ren)性產生(sheng)負面影響。而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)(yang)很(hen)低(di)(di),所以(yi)(yi)這種(zhong)銅(tong)(tong)(tong)的(de)(de)(de)組織是(shi)均勻的(de)(de)(de)單相(xiang)組織對韌(ren)性有利。在(zai)(zai)(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中的(de)(de)(de)多孔(kong)性是(shi)不常(chang)見(jian)的(de)(de)(de),而在(zai)(zai)(zai)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中則是(shi)常(chang)見(jian)的(de)(de)(de)一種(zhong)缺陷。

二(er)、熱軋組(zu)織和(he)鑄(zhu)造組(zu)織的區別

低氧(yang)銅(tong)(tong)(tong)桿(gan)由于經過熱(re)軋,所(suo)以(yi)(yi)其(qi)組(zu)(zu)(zu)織(zhi)屬(shu)熱(re)加(jia)工組(zu)(zu)(zu)織(zhi),原(yuan)來(lai)的(de)鑄(zhu)造(zao)(zao)組(zu)(zu)(zu)織(zhi)已經破碎,在(zai)8mm的(de)桿(gan)時(shi)已有再結晶(jing)的(de)形式出現,而無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)屬(shu)鑄(zhu)造(zao)(zao)組(zu)(zu)(zu)織(zhi),晶(jing)粒(li)(li)粗(cu)大(da)(da),這(zhe)是(shi)為(wei)(wei)什么,無(wu)氧(yang)銅(tong)(tong)(tong)的(de)再結晶(jing)溫度較(jiao)高,需要(yao)較(jiao)高退火(huo)溫度的(de)固有原(yuan)因(yin)。這(zhe)是(shi)因(yin)為(wei)(wei),再結晶(jing)發(fa)生在(zai)晶(jing)粒(li)(li)邊界附近,無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)組(zu)(zu)(zu)織(zhi)晶(jing)粒(li)(li)粗(cu)大(da)(da),晶(jing)粒(li)(li)尺寸甚至能達(da)幾個毫米,因(yin)而晶(jing)粒(li)(li)邊界少,即(ji)使通過拉(la)制(zhi)變形,但晶(jing)粒(li)(li)邊界相(xiang)對低氧(yang)銅(tong)(tong)(tong)桿(gan)還是(shi)較(jiao)少,所(suo)以(yi)(yi)需要(yao)較(jiao)高的(de)退火(huo)功(gong)率。對無(wu)氧(yang)銅(tong)(tong)(tong)成功(gong)的(de)退火(huo)要(yao)求是(shi):由桿(gan)經拉(la)制(zhi),但尚(shang)未鑄(zhu)造(zao)(zao)組(zu)(zu)(zu)織(zhi)的(de)線時(shi)的(de)第一(yi)次退火(huo),其(qi)退火(huo)功(gong)率應(ying)比同樣情況的(de)低氧(yang)銅(tong)(tong)(tong)高10——15%。經繼(ji)續拉(la)制(zhi),在(zai)以(yi)(yi)后階(jie)段的(de)退火(huo)功(gong)率應(ying)留有足(zu)夠的(de)余(yu)量和對低氧(yang)銅(tong)(tong)(tong)和無(wu)氧(yang)銅(tong)(tong)(tong)切實區別(bie)執(zhi)行不同的(de)退火(huo)工藝,以(yi)(yi)保證在(zai)制(zhi)品和成品導線的(de)柔軟性(xing)。

三、夾雜,氧(yang)含(han)量(liang)波動(dong),表(biao)面氧(yang)化物和可能(neng)存在(zai)的熱軋缺陷(xian)的差別

無氧(yang)(yang)銅桿(gan)(gan)的(de)可(ke)拉性在(zai)(zai)所有(you)線(xian)(xian)徑里與(yu)低氧(yang)(yang)銅桿(gan)(gan)相(xiang)比都(dou)是優越的(de),除上(shang)述組織原(yuan)因外,無氧(yang)(yang)銅桿(gan)(gan)夾雜少,含氧(yang)(yang)量穩定(ding),無熱軋可(ke)能(neng)產生的(de)缺陷,桿(gan)(gan)表氧(yang)(yang)化(hua)(hua)(hua)物厚度(du)可(ke)達≤15A。在(zai)(zai)連(lian)鑄連(lian)軋生產過程中如(ru)果工(gong)(gong)藝不(bu)(bu)穩定(ding),對(dui)氧(yang)(yang)監控不(bu)(bu)嚴,含氧(yang)(yang)量不(bu)(bu)穩定(ding)將直(zhi)接影(ying)響(xiang)桿(gan)(gan)的(de)性能(neng)。如(ru)果桿(gan)(gan)的(de)表面氧(yang)(yang)化(hua)(hua)(hua)物能(neng)在(zai)(zai)后(hou)工(gong)(gong)序(xu)的(de)連(lian)續(xu)清洗中得(de)以彌補外,但比較麻煩(fan)的(de)是有(you)相(xiang)當(dang)多的(de)氧(yang)(yang)化(hua)(hua)(hua)物存在(zai)(zai)于(yu)“皮下(xia)”,對(dui)拉線(xian)(xian)斷線(xian)(xian)影(ying)響(xiang)更(geng)直(zhi)接,故(gu)而在(zai)(zai)拉制微細線(xian)(xian),超微細線(xian)(xian)時(shi),為了減少斷線(xian)(xian),有(you)時(shi)要對(dui)銅桿(gan)(gan)采(cai)取(qu)不(bu)(bu)得(de)已的(de)辦(ban)法——剝皮,甚至二次剝皮的(de)原(yuan)因所在(zai)(zai),目的(de)要除去皮下(xia)氧(yang)(yang)化(hua)(hua)(hua)物。

四、低氧(yang)銅(tong)桿(gan)和無氧(yang)銅(tong)桿(gan)的韌性(xing)有差(cha)別(bie)

兩者(zhe)都可以拉到(dao)0.015mm,但在(zai)低溫(wen)超導(dao)線(xian)中的(de)低溫(wen)級無氧銅,其細絲間的(de)間距只有0.001mm.

五、從制(zhi)桿的原(yuan)材料(liao)到制(zhi)線的經(jing)濟(ji)性有差別。

制(zhi)造無氧銅(tong)桿(gan)要求質量(liang)較(jiao)高的原材料。一般,拉制(zhi)直(zhi)徑(jing)>1mm的銅(tong)線時,低氧銅(tong)桿(gan)的優點比較(jiao)明顯,而無氧銅(tong)桿(gan)顯得更為優越(yue)的是拉制(zhi)直(zhi)徑(jing)<0.5mm的銅(tong)線。

六(liu)、低(di)氧(yang)銅(tong)桿的(de)制線工藝與無氧(yang)銅(tong)桿的(de)有所(suo)不(bu)同。

低(di)氧(yang)銅桿的制(zhi)線工藝不(bu)能(neng)照(zhao)搬(ban)到無氧(yang)銅桿的制(zhi)線工藝上來,至少兩者的退火(huo)工藝是不(bu)同的。因為線的柔軟性(xing)深(shen)受材料成份和(he)制(zhi)桿,制(zhi)線和(he)退火(huo)工藝的影(ying)響(xiang),不(bu)能(neng)簡(jian)單(dan)地說低(di)氧(yang)銅或無氧(yang)銅誰軟誰硬。