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工農電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業動態 閱(yue)讀:109443 發布時間:2019-07-05

導讀:由于生產(chan)銅(tong)桿(gan)的(de)(de)兩(liang)者(zhe)的(de)(de)工藝(yi)不(bu)(bu)同,所生產(chan)的(de)(de)銅(tong)桿(gan)中的(de)(de)含氧(yang)量及外觀就不(bu)(bu)同。上(shang)引(yin)生產(chan)的(de)(de)銅(tong)桿(gan),工藝(yi)得當氧(yang)含量在10ppm以下(xia),叫(jiao)無氧(yang)銅(tong)桿(gan);連鑄連鑄生產(chan)的(de)(de)銅(tong)桿(gan) 是(shi)在保護條件下(xia)的(de)(de)熱軋,氧(yang)含量在200-500ppm范圍內,但有時也高達700ppm以上(shang),一般(ban)情況下(xia),此(ci)種方法生產(chan)的(de)(de)銅(tong)外表光亮,低氧(yang)銅(tong)桿(gan),有時也叫(jiao)光桿(gan)。

銅(tong)(tong)桿(gan)(gan)是電纜(lan)行(xing)(xing)業(ye)的(de)主(zhu)要(yao)(yao)原料,生產的(de)方(fang)式主(zhu)要(yao)(yao)有(you)兩種——連鑄(zhu)(zhu)連軋法(fa)和上(shang)引連鑄(zhu)(zhu)法(fa)。連鑄(zhu)(zhu)連軋低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)生產方(fang)法(fa)較(jiao)多(duo),其特點是金屬在(zai)豎爐(lu)(lu)中融化(hua)后(hou),銅(tong)(tong)液通過保溫爐(lu)(lu)、溜(liu)槽(cao)、中間(jian)包,從(cong)澆(jiao)管進(jin)入封(feng)閉的(de)模(mo)腔內,采用(yong)(yong)較(jiao)大的(de)冷(leng)卻(que)強度(du)進(jin)行(xing)(xing)冷(leng)卻(que),形成鑄(zhu)(zhu)坯(pi),然(ran)后(hou)進(jin)行(xing)(xing)多(duo)道次軋制,生產的(de)低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)為熱加工組(zu)織,原來的(de)鑄(zhu)(zhu)造組(zu)織已經(jing)破(po)碎,含氧(yang)(yang)(yang)量(liang)(liang)一般(ban)為200~400ppm之間(jian)。無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)國內基本全部采用(yong)(yong)上(shang)引連鑄(zhu)(zhu)法(fa)生產,金屬在(zai)感(gan)應電爐(lu)(lu)中融化(hua)后(hou)通過石墨(mo)模(mo)進(jin)行(xing)(xing)上(shang)引連續鑄(zhu)(zhu)造,之后(hou)進(jin)行(xing)(xing)冷(leng)軋或冷(leng)加工,生產的(de)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)為鑄(zhu)(zhu)造組(zu)織,含氧(yang)(yang)(yang)量(liang)(liang)一般(ban)在(zai)20ppm以下(xia)。由(you)于(yu)制造工藝的(de)不同,所以在(zai)組(zu)織結構、氧(yang)(yang)(yang)含量(liang)(liang)分(fen)布、雜質的(de)形式及分(fen)布等諸(zhu)多(duo)方(fang)面有(you)較(jiao)大差(cha)別。

一、拉制性能

銅(tong)桿的拉(la)制性(xing)能(neng)跟很多(duo)因素有(you)關,如雜質的含(han)量、氧含(han)量及分(fen)布、工藝控(kong)制等。下面分(fen)別(bie)從以上幾個方(fang)面對銅(tong)桿的拉(la)制性(xing)能(neng)進行分(fen)析。

1、熔化(hua)方式對S等雜質的影響

連(lian)鑄(zhu)連(lian)軋生產銅(tong)(tong)桿(gan)主要是通過(guo)氣體的(de)(de)(de)燃(ran)燒使銅(tong)(tong)桿(gan)熔化,在燃(ran)燒的(de)(de)(de)過(guo)程(cheng)中(zhong),通過(guo)氧化和揮發作用(yong),可一(yi)定程(cheng)度減少(shao)部分雜(za)質進入(ru)銅(tong)(tong)液(ye),因此連(lian)鑄(zhu)連(lian)軋法對(dui)原料要求相對(dui)低一(yi)些。上(shang)引連(lian)鑄(zhu)生產無(wu)氧銅(tong)(tong)桿(gan),由于是用(yong)感(gan)應電爐熔化,電解銅(tong)(tong)表面的(de)(de)(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都(dou)熔入(ru)到(dao)銅(tong)(tong)液(ye)中(zhong)。其中(zhong)熔入(ru)的(de)(de)(de)S對(dui)無(wu)氧銅(tong)(tong)桿(gan)塑(su)性影(ying)響極大,會增加(jia)拉絲斷線(xian)率。

2、鑄造過程中雜質的進入(ru)

在生產(chan)(chan)過(guo)程(cheng)中(zhong),連(lian)鑄(zhu)連(lian)軋(ya)(ya)工藝(yi)需通過(guo)保溫(wen)爐(lu)、溜槽(cao)、中(zhong)間包轉運銅液(ye),相對(dui)容易(yi)造成耐(nai)火材料的剝落(luo),在軋(ya)(ya)制過(guo)程(cheng)中(zhong)需要通過(guo)軋(ya)(ya)輥(gun),造成鐵質的脫落(luo),會(hui)給銅桿造成外部夾(jia)雜。而熱(re)軋(ya)(ya)中(zhong)皮上(shang)和皮下氧化(hua)物的軋(ya)(ya)入(ru),會(hui)給低氧桿的拉絲造成不利的影響。上(shang)引連(lian)鑄(zhu)法生產(chan)(chan)工藝(yi)流程(cheng)較(jiao)短,銅液(ye)是通過(guo)聯(lian)體爐(lu)內潛流式完成,對(dui)耐(nai)火材料的沖擊(ji)不大(da),結晶是通過(guo)石墨模內進(jin)行,所(suo)以過(guo)程(cheng)中(zhong)可能產(chan)(chan)生的污(wu)染(ran)源較(jiao)少,雜質進(jin)入(ru)的機(ji)會(hui)較(jiao)少。

O、S、P是與(yu)銅(tong)(tong)(tong)會生產化合物的(de)(de)元(yuan)素。在熔態(tai)銅(tong)(tong)(tong)中(zhong),氧可以溶(rong)(rong)解一(yi)部分,但當銅(tong)(tong)(tong)冷凝時,氧幾乎不溶(rong)(rong)解于銅(tong)(tong)(tong)中(zhong)。熔態(tai)時所(suo)溶(rong)(rong)解的(de)(de)氧,以銅(tong)(tong)(tong)=氧化亞(ya)銅(tong)(tong)(tong)共(gong)晶(jing)(jing)體析出,分布在晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)(tong)(tong)-氧化亞(ya)銅(tong)(tong)(tong)共(gong)晶(jing)(jing)體的(de)(de)出現,顯著(zhu)降(jiang)低了銅(tong)(tong)(tong)的(de)(de)塑性。

硫可(ke)以溶(rong)(rong)解在熔體的(de)銅(tong)中,但(dan)在室(shi)溫下,其溶(rong)(rong)解度幾(ji)乎(hu)降低到(dao)零(ling),它以硫化(hua)亞銅(tong)的(de)形式出現在晶粒晶界處,會(hui)顯(xian)著降低銅(tong)的(de)塑性。

3、氧(yang)在低氧(yang)銅桿(gan)和(he)無氧(yang)銅桿(gan)中分(fen)布形式(shi)及(ji)其(qi)影(ying)響

氧(yang)(yang)含量對低(di)氧(yang)(yang)銅(tong)桿的拉線(xian)(xian)性(xing)能(neng)有著明顯的影響。當氧(yang)(yang)含量增(zeng)加到最(zui)(zui)佳(jia)值時,銅(tong)桿的斷線(xian)(xian)率(lv)最(zui)(zui)低(di)。這是因(yin)為(wei)氧(yang)(yang)在與(yu)大部(bu)分雜質反(fan)應(ying)的過程中都(dou)起到了清除器的作用(yong)。適度的氧(yang)(yang)還有利于(yu)去除銅(tong)液(ye)中的氫,生成(cheng)水(shui)蒸氣溢(yi)出,減少氣孔(kong)的形(xing)成(cheng)。最(zui)(zui)佳(jia)的氧(yang)(yang)含量為(wei)拉線(xian)(xian)工藝(yi)提供了最(zui)(zui)好的條(tiao)件。

低(di)氧銅(tong)(tong)(tong)桿氧化(hua)(hua)(hua)物(wu)的(de)分(fen)布:在連續澆(jiao)鑄(zhu)中(zhong)(zhong)凝固的(de)最初(chu)階段,散(san)熱速率和(he)均勻冷卻是(shi)決定(ding)銅(tong)(tong)(tong)桿氧化(hua)(hua)(hua)物(wu)分(fen)布的(de)主(zhu)要因素。不均勻冷卻會(hui)(hui)引起銅(tong)(tong)(tong)桿內(nei)部結構本質上的(de)差異,但后續的(de)熱加工,柱狀晶(jing)通常會(hui)(hui)遭到(dao)破壞,使氧化(hua)(hua)(hua)亞銅(tong)(tong)(tong)顆(ke)粒(li)細微(wei)化(hua)(hua)(hua)和(he)均勻分(fen)布。氧化(hua)(hua)(hua)物(wu)顆(ke)粒(li)聚集(ji)而(er)產(chan)生的(de)典型情況是(shi)中(zhong)(zhong)心爆裂。除(chu)氧化(hua)(hua)(hua)物(wu)顆(ke)粒(li)分(fen)布的(de)影響外,具有(you)較小(xiao)氧化(hua)(hua)(hua)物(wu)顆(ke)粒(li)的(de)銅(tong)(tong)(tong)桿顯示出較好的(de)拉線特(te)性,較大的(de)Cu2O顆(ke)粒(li)容易(yi)造成應力集(ji)中(zhong)(zhong)點(dian)而(er)斷裂。

無氧(yang)(yang)(yang)(yang)銅(tong)(tong)含氧(yang)(yang)(yang)(yang)量(liang)(liang)超標,銅(tong)(tong)桿(gan)變脆,延(yan)伸(shen)率下降,拉伸(shen)式樣端口顯暗紅色(se),結晶組(zu)織疏松。當氧(yang)(yang)(yang)(yang)含量(liang)(liang)超出8ppm時,工藝性能(neng)變差,表現為鑄造及拉伸(shen)過程中斷(duan)桿(gan)及斷(duan)線率極具增高。這是由于氧(yang)(yang)(yang)(yang)能(neng)與銅(tong)(tong)生成氧(yang)(yang)(yang)(yang)化亞銅(tong)(tong)脆性相(xiang),形成銅(tong)(tong)-氧(yang)(yang)(yang)(yang)化亞銅(tong)(tong)共晶體,以網狀(zhuang)組(zu)織分布在境界上。這種脆性相(xiang)硬度高,在冷變形時將會與銅(tong)(tong)機體脫(tuo)離,導(dao)(dao)致(zhi)銅(tong)(tong)桿(gan)的機械性能(neng)下降,在后續加工中容易造成斷(duan)裂現象。氧(yang)(yang)(yang)(yang)含量(liang)(liang)高還能(neng)導(dao)(dao)致(zhi)無氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)導(dao)(dao)電(dian)率下降。因此,必須嚴格控制上引連鑄工藝及產品質量(liang)(liang)。

4、氫的影響

在上引(yin)連(lian)鑄中,氧含量控(kong)制較低(di)(di),氧化物的副作用唄(bai)**降低(di)(di),但氫的影響(xiang)成為較顯著的問題(ti)。吸(xi)氣(qi)后熔體中存在平(ping)衡(heng)反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)(qi)體及疏松是在(zai)(zai)(zai)(zai)(zai)結(jie)晶(jing)的(de)(de)(de)過(guo)程(cheng)中(zhong)(zhong),氫(qing)(qing)(qing)從(cong)過(guo)飽和的(de)(de)(de)溶液中(zhong)(zhong)析出(chu)并聚集(ji)而(er)形成的(de)(de)(de)。在(zai)(zai)(zai)(zai)(zai)結(jie)晶(jing)前析出(chu)的(de)(de)(de)氫(qing)(qing)(qing)又可(ke)還原氧化亞銅(tong)(tong)而(er)生成水氣(qi)(qi)(qi)(qi)泡。由于(yu)上引(yin)鑄造的(de)(de)(de)特點是銅(tong)(tong)液自上而(er)下的(de)(de)(de)結(jie)晶(jing),形成的(de)(de)(de)液**形狀近似(si)錐(zhui)型(xing)。銅(tong)(tong)液結(jie)晶(jing)前析出(chu)的(de)(de)(de)氣(qi)(qi)(qi)(qi)體在(zai)(zai)(zai)(zai)(zai)上浮(fu)過(guo)程(cheng)中(zhong)(zhong)被(bei)堵(du)在(zai)(zai)(zai)(zai)(zai)凝(ning)固組織內(nei),結(jie)晶(jing)時(shi)在(zai)(zai)(zai)(zai)(zai)鑄桿內(nei)形成氣(qi)(qi)(qi)(qi)孔。上引(yin)的(de)(de)(de)含氣(qi)(qi)(qi)(qi)量少時(shi),析出(chu)的(de)(de)(de)氫(qing)(qing)(qing)存在(zai)(zai)(zai)(zai)(zai)于(yu)晶(jing)界處,形成疏松;含氣(qi)(qi)(qi)(qi)量多時(shi),則聚集(ji)成氣(qi)(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)(qi)孔和疏松是氫(qing)(qing)(qing)氣(qi)(qi)(qi)(qi)和水蒸氣(qi)(qi)(qi)(qi)兩者形成的(de)(de)(de)。

氫來源(yuan)于上引生產過(guo)程中的各(ge)個工藝環節,如原料電(dian)解(jie)銅(tong)的“銅(tong)綠”、輔料木炭**、氣候環境**、石墨結晶器未(wei)干燥等。因此,熔(rong)化爐(lu)中的銅(tong)液表面(mian)應覆蓋經烘(hong)烤的木炭,電(dian)解(jie)銅(tong)應盡量去(qu)除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對提高無(wu)氧銅(tong)桿(gan)質量非常重(zhong)要。

在(zai)連鑄(zhu)連軋工藝中(zhong),往往采(cai)用適(shi)度控制氧含量(liang)來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)液在鑄造過(guo)程(cheng)中是自下而上結晶,銅(tong)液中的(de)氧和(he)氫所(suo)產生的(de)水蒸氣很容易上浮跑出,銅(tong)液中的(de)氫大部分能被有(you)效去除,因(yin)而對銅(tong)桿的(de)影(ying)響較小。

二、表面質量

在(zai)生產電磁線等產品的(de)過(guo)程中,對(dui)銅(tong)桿的(de)表面(mian)(mian)質量也需提出要(yao)求(qiu)。需要(yao)拉制后的(de)銅(tong)絲表面(mian)(mian)無毛(mao)刺、銅(tong)粉少、無油污。并通過(guo)扭轉(zhuan)試驗測量表面(mian)(mian)銅(tong)粉的(de)質量和扭轉(zhuan)后觀察銅(tong)桿的(de)復原情況(kuang)來判定其(qi)好壞。

在連鑄(zhu)連軋(ya)(ya)過(guo)程(cheng)中,從鑄(zhu)造到軋(ya)(ya)制前(qian),溫(wen)度高,完全(quan)暴露(lu)于空(kong)氣(qi)中,使鑄(zhu)坯表(biao)面形成較(jiao)厚的氧化(hua)層,在軋(ya)(ya)制過(guo)程(cheng)中,隨著(zhu)軋(ya)(ya)輥的轉動,氧化(hua)物顆粒(li)軋(ya)(ya)入(ru)銅(tong)線表(biao)面。由于氧化(hua)亞銅(tong)是(shi)高熔點(dian)脆性(xing)化(hua)合(he)物,對于軋(ya)(ya)入(ru)較(jiao)深的氧化(hua)亞銅(tong),當(dang)成條(tiao)狀的聚集物遇模具(ju)拉伸時,就(jiu)會是(shi)銅(tong)桿外表(biao)面產生毛(mao)刺,給后續的涂漆(qi)造成麻煩(fan)。

而上引(yin)連鑄(zhu)工(gong)藝制(zhi)(zhi)造(zao)的(de)無氧(yang)銅(tong)桿,由(you)于鑄(zhu)造(zao)和冷卻完(wan)全與氧(yang)隔絕,后(hou)續亦無熱軋(ya)(ya)過程,銅(tong)桿表(biao)面無軋(ya)(ya)入表(biao)面的(de)氧(yang)化物,質量較(jiao)好,拉制(zhi)(zhi)后(hou)銅(tong)粉少(shao),上述問題較(jiao)少(shao)存在(zai)。

無氧銅桿(gan)也分進(jin)(jin)口(kou)設(she)備(bei)做的(de)和國產(chan)(chan)設(she)備(bei)做的(de),但目(mu)前進(jin)(jin)口(kou)產(chan)(chan)品已無明顯優勢,銅桿(gan)產(chan)(chan)品出來后區別不是很大,只(zhi)要銅板選的(de)好,生產(chan)(chan)控制(zhi)比較穩定,國產(chan)(chan)設(she)備(bei)也能產(chan)(chan)出可(ke)拉伸0.05的(de)銅桿(gan).進(jin)(jin)口(kou)設(she)備(bei)一般是芬蘭奧托(tuo)昆普的(de)設(she)備(bei),國產(chan)(chan)設(she)備(bei)最好的(de)應該是上(shang)海(hai)(hai)的(de)海(hai)(hai)軍(jun)廠的(de)了,生產(chan)(chan)時(shi)間最長,軍(jun)工企業,質量(liang)可(ke)靠。

低氧銅(tong)桿進口(kou)設備國(guo)際(ji)主要有兩種,一(yi)(yi)種是(shi)(shi)美國(guo)南線設備,英文是(shi)(shi)SOUTHWIRE,國(guo)內廠家(jia)(jia)是(shi)(shi)南京(jing)華新(xin),江西銅(tong)業,另一(yi)(yi)種是(shi)(shi)德國(guo)CONTIROD設備,國(guo)內廠家(jia)(jia)是(shi)(shi)常州(zhou)金源,天(tian)津大無(wu)縫。

無氧(yang)(yang)及低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)從含(han)(han)氧(yang)(yang)量上容易區別,無氧(yang)(yang)銅(tong)(tong)是(shi)含(han)(han)氧(yang)(yang)量在10-20個PPM以下,但目(mu)前有(you)的(de)廠家只能(neng)(neng)(neng)做(zuo)到50個PPM以下.低(di)(di)(di)(di)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)在 200-400個PPM,好(hao)的(de)桿(gan)(gan)子(zi)一(yi)(yi)般(ban)含(han)(han)氧(yang)(yang)量控制(zhi)在250個PPM左右,無氧(yang)(yang)桿(gan)(gan)一(yi)(yi)般(ban)采取的(de)是(shi)上引法,低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)是(shi)連(lian)鑄連(lian)軋(ya),兩(liang)種產品相(xiang)對而(er)(er)言(yan)低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)對漆包線性 能(neng)(neng)(neng)更適應些,如柔軟性,回彈(dan)角,繞線性能(neng)(neng)(neng).但低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)對拉(la)(la)絲條件相(xiang)對要(yao)苛刻些,同(tong)樣(yang)拉(la)(la)伸(shen)0.2的(de)細(xi)絲,如果(guo)伸(shen)線條件不(bu)好(hao),普通的(de)無氧(yang)(yang)桿(gan)(gan)可拉(la)(la)而(er)(er)好(hao)的(de)低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)就斷 線,但如果(guo)放在好(hao)的(de)伸(shen)線條件,同(tong)樣(yang)的(de)桿(gan)(gan)子(zi),低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)說不(bu)定就能(neng)(neng)(neng)拉(la)(la)到雙零五,而(er)(er)普通無氧(yang)(yang)桿(gan)(gan)最多(duo)只能(neng)(neng)(neng)拉(la)(la)伸(shen)到0.1而(er)(er)已(yi),當(dang)然做(zuo)的(de)最細(xi)的(de)如雙零二卻非得依(yi)靠(kao)進口的(de) 無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)了(le).目(mu)前有(you)企業(ye)嘗試(shi)用剝皮的(de)方式(shi)來處理(li)低(di)(di)(di)(di)氧(yang)(yang)桿(gan)(gan)來伸(shen)0.03線.但有(you)關這方面的(de)內(nei)容我還不(bu)是(shi)很清楚。

音(yin)響線一(yi)般反而喜歡(huan)用無氧(yang)桿(gan),這和無氧(yang)桿(gan)是(shi)單(dan)晶銅,低(di)氧(yang)桿(gan)是(shi)多(duo)晶銅有關(guan)。

氧(yang)銅桿和無氧(yang)銅桿由(you)于制造方(fang)法(fa)的(de)(de)不(bu)同(tong),致使存在差別,具有各自的(de)(de)特點(dian)。

一、關于(yu)氧的吸入和脫去以及它的存在狀態

生產(chan)銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)(tong)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量(liang)一(yi)般在10—50ppm,在常溫下氧(yang)(yang)(yang)在銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量(liang)一(yi)般在200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)(de)進入是(shi)在銅(tong)(tong)(tong)的(de)(de)(de)(de)液態下吸入的(de)(de)(de)(de),而(er)上引法無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則相(xiang)(xiang)反(fan),氧(yang)(yang)(yang)在液態銅(tong)(tong)(tong)下保持相(xiang)(xiang)當時間后,被還原(yuan)而(er)脫去(qu),通常這種(zhong)桿(gan)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量(liang)都(dou)在10—50ppm以(yi)(yi)下,最低(di)可達1-2ppm,從組織上看,低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)狀態,存在于晶(jing)粒邊界附近,這對(dui)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)而(er)言可以(yi)(yi)說(shuo)是(shi)常見(jian)的(de)(de)(de)(de)但對(dui)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則很少見(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)以(yi)(yi)夾雜形式在晶(jing)界出(chu)現對(dui)材料(liao)的(de)(de)(de)(de)韌(ren)性(xing)產(chan)生負面(mian)影響。而(er)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)很低(di),所以(yi)(yi)這種(zhong)銅(tong)(tong)(tong)的(de)(de)(de)(de)組織是(shi)均勻的(de)(de)(de)(de)單相(xiang)(xiang)組織對(dui)韌(ren)性(xing)有(you)利。在無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)(de)多(duo)孔性(xing)是(shi)不常見(jian)的(de)(de)(de)(de),而(er)在低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中(zhong)則是(shi)常見(jian)的(de)(de)(de)(de)一(yi)種(zhong)缺陷(xian)。

二、熱軋組(zu)織和鑄造(zao)組(zu)織的(de)區別

低(di)(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)由(you)于(yu)經過熱軋,所以(yi)(yi)其(qi)組織(zhi)屬(shu)熱加工組織(zhi),原(yuan)來的鑄(zhu)造(zao)組織(zhi)已(yi)經破碎,在(zai)8mm的桿(gan)(gan)(gan)時已(yi)有再(zai)結晶(jing)(jing)(jing)的形式(shi)出(chu)現,而(er)無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)屬(shu)鑄(zhu)造(zao)組織(zhi),晶(jing)(jing)(jing)粒(li)(li)粗大,這是為什么,無(wu)氧(yang)(yang)(yang)銅的再(zai)結晶(jing)(jing)(jing)溫度較高,需要較高退(tui)(tui)火(huo)(huo)溫度的固有原(yuan)因(yin)。這是因(yin)為,再(zai)結晶(jing)(jing)(jing)發(fa)生在(zai)晶(jing)(jing)(jing)粒(li)(li)邊界(jie)附近,無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)組織(zhi)晶(jing)(jing)(jing)粒(li)(li)粗大,晶(jing)(jing)(jing)粒(li)(li)尺(chi)寸甚至(zhi)能達幾(ji)個(ge)毫米(mi),因(yin)而(er)晶(jing)(jing)(jing)粒(li)(li)邊界(jie)少,即使通過拉(la)制變形,但(dan)晶(jing)(jing)(jing)粒(li)(li)邊界(jie)相對(dui)低(di)(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)還是較少,所以(yi)(yi)需要較高的退(tui)(tui)火(huo)(huo)功率(lv)。對(dui)無(wu)氧(yang)(yang)(yang)銅成功的退(tui)(tui)火(huo)(huo)要求是:由(you)桿(gan)(gan)(gan)經拉(la)制,但(dan)尚未鑄(zhu)造(zao)組織(zhi)的線時的第(di)一次退(tui)(tui)火(huo)(huo),其(qi)退(tui)(tui)火(huo)(huo)功率(lv)應比同(tong)樣(yang)情況的低(di)(di)氧(yang)(yang)(yang)銅高10——15%。經繼續(xu)拉(la)制,在(zai)以(yi)(yi)后階段(duan)的退(tui)(tui)火(huo)(huo)功率(lv)應留有足夠的余量(liang)和對(dui)低(di)(di)氧(yang)(yang)(yang)銅和無(wu)氧(yang)(yang)(yang)銅切實區別(bie)執行不同(tong)的退(tui)(tui)火(huo)(huo)工藝(yi),以(yi)(yi)保證在(zai)制品和成品導線的柔軟性。

三(san)、夾雜(za),氧含量波(bo)動,表(biao)面氧化物和可能(neng)存在的熱軋(ya)缺陷的差別

無氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)(de)可(ke)拉(la)性(xing)在所有線(xian)(xian)徑(jing)里(li)與低氧(yang)(yang)(yang)銅(tong)桿(gan)相比(bi)都是(shi)優越的(de)(de),除上述組織原因(yin)外(wai),無氧(yang)(yang)(yang)銅(tong)桿(gan)夾雜少,含氧(yang)(yang)(yang)量穩定(ding),無熱軋(ya)可(ke)能產(chan)生的(de)(de)缺(que)陷,桿(gan)表氧(yang)(yang)(yang)化(hua)物厚度(du)可(ke)達(da)≤15A。在連鑄連軋(ya)生產(chan)過程中如(ru)果工藝不(bu)穩定(ding),對氧(yang)(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)(yang)量不(bu)穩定(ding)將直接(jie)影響(xiang)桿(gan)的(de)(de)性(xing)能。如(ru)果桿(gan)的(de)(de)表面氧(yang)(yang)(yang)化(hua)物能在后工序的(de)(de)連續清(qing)洗(xi)中得以彌補外(wai),但比(bi)較麻(ma)煩的(de)(de)是(shi)有相當(dang)多(duo)的(de)(de)氧(yang)(yang)(yang)化(hua)物存(cun)在于“皮(pi)下”,對拉(la)線(xian)(xian)斷線(xian)(xian)影響(xiang)更(geng)直接(jie),故而在拉(la)制微細(xi)線(xian)(xian),超微細(xi)線(xian)(xian)時(shi),為(wei)了減少斷線(xian)(xian),有時(shi)要對銅(tong)桿(gan)采取不(bu)得已的(de)(de)辦法(fa)——剝(bo)皮(pi),甚至二次剝(bo)皮(pi)的(de)(de)原因(yin)所在,目(mu)的(de)(de)要除去皮(pi)下氧(yang)(yang)(yang)化(hua)物。

四、低氧(yang)銅桿和無氧(yang)銅桿的韌性(xing)有差別

兩(liang)者都可以拉到0.015mm,但在低溫超導線中的低溫級無氧銅,其(qi)細絲間的間距只有0.001mm.

五、從(cong)制(zhi)桿的(de)原材料到制(zhi)線的(de)經濟性有(you)差別。

制(zhi)造無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)要求質量較高(gao)的原材料。一(yi)般,拉(la)制(zhi)直(zhi)(zhi)徑>1mm的銅(tong)(tong)(tong)線(xian)時,低氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)的優(you)點比(bi)較明顯,而無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)顯得更為優(you)越的是拉(la)制(zhi)直(zhi)(zhi)徑<0.5mm的銅(tong)(tong)(tong)線(xian)。

六(liu)、低(di)氧(yang)(yang)銅(tong)桿的制(zhi)線工藝(yi)與無氧(yang)(yang)銅(tong)桿的有所不同(tong)。

低氧銅桿的制(zhi)線工(gong)藝(yi)不能(neng)(neng)照搬到無氧銅桿的制(zhi)線工(gong)藝(yi)上來,至少(shao)兩者的退火(huo)工(gong)藝(yi)是(shi)不同(tong)的。因為線的柔(rou)軟性深受材料成(cheng)份和制(zhi)桿,制(zhi)線和退火(huo)工(gong)藝(yi)的影響,不能(neng)(neng)簡單地說低氧銅或(huo)無氧銅誰軟誰硬。