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海城電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行(xing)業動態 閱(yue)讀:109488 發布時間(jian):2019-07-05

導讀(du):由于生(sheng)(sheng)產(chan)銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)兩者的(de)(de)(de)(de)工(gong)藝不同,所生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)含(han)氧量(liang)及外(wai)觀就不同。上引生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan),工(gong)藝得當氧含(han)量(liang)在10ppm以下(xia),叫無氧銅(tong)(tong)(tong)桿(gan)(gan);連鑄(zhu)連鑄(zhu)生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿(gan)(gan) 是在保(bao)護條件(jian)下(xia)的(de)(de)(de)(de)熱軋,氧含(han)量(liang)在200-500ppm范圍內,但有(you)時也高(gao)達700ppm以上,一般情況下(xia),此種(zhong)方法生(sheng)(sheng)產(chan)的(de)(de)(de)(de)銅(tong)(tong)(tong)外(wai)表(biao)光亮,低氧銅(tong)(tong)(tong)桿(gan)(gan),有(you)時也叫光桿(gan)(gan)。

銅桿是(shi)電(dian)纜行(xing)(xing)業(ye)的(de)(de)(de)主(zhu)要原(yuan)料(liao),生產(chan)的(de)(de)(de)方式主(zhu)要有(you)兩種(zhong)——連(lian)(lian)(lian)鑄(zhu)連(lian)(lian)(lian)軋(ya)法和上引連(lian)(lian)(lian)鑄(zhu)法。連(lian)(lian)(lian)鑄(zhu)連(lian)(lian)(lian)軋(ya)低氧(yang)(yang)銅桿的(de)(de)(de)生產(chan)方法較多,其特(te)點是(shi)金屬在(zai)豎爐(lu)(lu)中(zhong)(zhong)融(rong)化后(hou),銅液通過(guo)保溫爐(lu)(lu)、溜槽、中(zhong)(zhong)間包,從澆管進(jin)(jin)入(ru)封閉的(de)(de)(de)模腔內,采用較大的(de)(de)(de)冷卻(que)強度進(jin)(jin)行(xing)(xing)冷卻(que),形成鑄(zhu)坯,然后(hou)進(jin)(jin)行(xing)(xing)多道次(ci)軋(ya)制,生產(chan)的(de)(de)(de)低氧(yang)(yang)銅桿為熱(re)加工組織(zhi),原(yuan)來的(de)(de)(de)鑄(zhu)造(zao)組織(zhi)已經破碎,含氧(yang)(yang)量(liang)一般為200~400ppm之間。無氧(yang)(yang)銅桿國(guo)內基本(ben)全部采用上引連(lian)(lian)(lian)鑄(zhu)法生產(chan),金屬在(zai)感(gan)應電(dian)爐(lu)(lu)中(zhong)(zhong)融(rong)化后(hou)通過(guo)石墨模進(jin)(jin)行(xing)(xing)上引連(lian)(lian)(lian)續(xu)鑄(zhu)造(zao),之后(hou)進(jin)(jin)行(xing)(xing)冷軋(ya)或冷加工,生產(chan)的(de)(de)(de)無氧(yang)(yang)銅桿為鑄(zhu)造(zao)組織(zhi),含氧(yang)(yang)量(liang)一般在(zai)20ppm以下(xia)。由于制造(zao)工藝的(de)(de)(de)不同,所(suo)以在(zai)組織(zhi)結構、氧(yang)(yang)含量(liang)分布、雜質的(de)(de)(de)形式及(ji)分布等諸多方面有(you)較大差別。

一、拉制性能

銅桿的拉(la)制(zhi)性能跟很多因素有關,如雜質的含量、氧含量及(ji)分(fen)布(bu)、工(gong)藝控制(zhi)等(deng)。下面分(fen)別從(cong)以上幾個(ge)方面對銅桿的拉(la)制(zhi)性能進行分(fen)析。

1、熔(rong)化方(fang)式對(dui)S等雜質(zhi)的(de)影響

連(lian)鑄連(lian)軋生產(chan)銅(tong)桿主要是通(tong)過氣體的(de)燃(ran)燒使銅(tong)桿熔(rong)化(hua),在燃(ran)燒的(de)過程(cheng)中,通(tong)過氧化(hua)和揮(hui)發作用,可一(yi)(yi)定程(cheng)度(du)減少部分雜質進入銅(tong)液(ye),因此連(lian)鑄連(lian)軋法對(dui)(dui)原料要求相對(dui)(dui)低一(yi)(yi)些。上(shang)引連(lian)鑄生產(chan)無氧銅(tong)桿,由于是用感應電爐熔(rong)化(hua),電解銅(tong)表(biao)面的(de)“銅(tong)綠”“銅(tong)豆(dou)”基本都熔(rong)入到銅(tong)液(ye)中。其中熔(rong)入的(de)S對(dui)(dui)無氧銅(tong)桿塑(su)性影響極(ji)大,會(hui)增加拉(la)絲斷(duan)線(xian)率。

2、鑄造過程(cheng)中雜質(zhi)的進入

在生產(chan)過(guo)(guo)程(cheng)(cheng)中(zhong)(zhong),連鑄(zhu)連軋(ya)(ya)(ya)工藝(yi)需通過(guo)(guo)保溫(wen)爐、溜槽、中(zhong)(zhong)間包轉運銅(tong)液,相對(dui)容易造成(cheng)耐(nai)火(huo)材料(liao)的(de)剝落(luo),在軋(ya)(ya)(ya)制(zhi)過(guo)(guo)程(cheng)(cheng)中(zhong)(zhong)需要通過(guo)(guo)軋(ya)(ya)(ya)輥,造成(cheng)鐵質的(de)脫落(luo),會給銅(tong)桿造成(cheng)外部夾雜。而熱軋(ya)(ya)(ya)中(zhong)(zhong)皮上(shang)和皮下(xia)氧化物的(de)軋(ya)(ya)(ya)入(ru),會給低氧桿的(de)拉(la)絲造成(cheng)不利(li)的(de)影響。上(shang)引連鑄(zhu)法生產(chan)工藝(yi)流程(cheng)(cheng)較(jiao)短,銅(tong)液是通過(guo)(guo)聯體爐內(nei)潛流式完成(cheng),對(dui)耐(nai)火(huo)材料(liao)的(de)沖擊(ji)不大(da),結晶是通過(guo)(guo)石(shi)墨模內(nei)進(jin)行(xing),所以(yi)過(guo)(guo)程(cheng)(cheng)中(zhong)(zhong)可能(neng)產(chan)生的(de)污染源較(jiao)少,雜質進(jin)入(ru)的(de)機會較(jiao)少。

O、S、P是與(yu)銅(tong)會生產化合物的(de)(de)元素。在(zai)熔(rong)態(tai)銅(tong)中,氧可以溶(rong)解(jie)(jie)(jie)一部分(fen),但當銅(tong)冷凝時(shi),氧幾乎不溶(rong)解(jie)(jie)(jie)于銅(tong)中。熔(rong)態(tai)時(shi)所溶(rong)解(jie)(jie)(jie)的(de)(de)氧,以銅(tong)=氧化亞銅(tong)共晶(jing)(jing)體析(xi)出,分(fen)布在(zai)晶(jing)(jing)粒(li)晶(jing)(jing)界處。銅(tong)-氧化亞銅(tong)共晶(jing)(jing)體的(de)(de)出現,顯著降(jiang)低(di)了(le)銅(tong)的(de)(de)塑性。

硫(liu)(liu)可以(yi)(yi)溶解在熔(rong)體的銅中,但在室溫下(xia),其溶解度幾乎降低到零,它以(yi)(yi)硫(liu)(liu)化亞(ya)銅的形式(shi)出現在晶粒晶界處,會顯著降低銅的塑性。

3、氧(yang)在低氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)中分(fen)布形式及(ji)其影響(xiang)

氧(yang)(yang)(yang)含量對低氧(yang)(yang)(yang)銅桿的(de)(de)拉線(xian)性能有(you)著明(ming)顯的(de)(de)影響。當氧(yang)(yang)(yang)含量增加(jia)到最(zui)佳值(zhi)時,銅桿的(de)(de)斷(duan)線(xian)率(lv)最(zui)低。這是因為氧(yang)(yang)(yang)在與大部分雜質(zhi)反應的(de)(de)過程中都起到了清除(chu)器的(de)(de)作用。適度的(de)(de)氧(yang)(yang)(yang)還有(you)利于去(qu)除(chu)銅液(ye)中的(de)(de)氫(qing),生成(cheng)水蒸氣(qi)(qi)溢出,減少(shao)氣(qi)(qi)孔的(de)(de)形成(cheng)。最(zui)佳的(de)(de)氧(yang)(yang)(yang)含量為拉線(xian)工(gong)藝提供(gong)了最(zui)好(hao)的(de)(de)條件(jian)。

低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)氧(yang)(yang)(yang)(yang)化(hua)物(wu)(wu)(wu)的(de)(de)(de)(de)分(fen)布(bu):在(zai)連續(xu)澆鑄中(zhong)凝固的(de)(de)(de)(de)最初階(jie)段,散(san)熱速(su)率和(he)均(jun)勻(yun)(yun)冷卻是決定銅(tong)(tong)桿(gan)氧(yang)(yang)(yang)(yang)化(hua)物(wu)(wu)(wu)分(fen)布(bu)的(de)(de)(de)(de)主(zhu)要因素。不均(jun)勻(yun)(yun)冷卻會引起銅(tong)(tong)桿(gan)內部結構本質(zhi)上的(de)(de)(de)(de)差異,但后續(xu)的(de)(de)(de)(de)熱加工,柱狀晶通常會遭到破壞,使氧(yang)(yang)(yang)(yang)化(hua)亞銅(tong)(tong)顆(ke)(ke)(ke)粒(li)(li)(li)細(xi)微化(hua)和(he)均(jun)勻(yun)(yun)分(fen)布(bu)。氧(yang)(yang)(yang)(yang)化(hua)物(wu)(wu)(wu)顆(ke)(ke)(ke)粒(li)(li)(li)聚集(ji)而產生(sheng)的(de)(de)(de)(de)典型情況是中(zhong)心爆(bao)裂(lie)。除氧(yang)(yang)(yang)(yang)化(hua)物(wu)(wu)(wu)顆(ke)(ke)(ke)粒(li)(li)(li)分(fen)布(bu)的(de)(de)(de)(de)影響外,具有較小氧(yang)(yang)(yang)(yang)化(hua)物(wu)(wu)(wu)顆(ke)(ke)(ke)粒(li)(li)(li)的(de)(de)(de)(de)銅(tong)(tong)桿(gan)顯示出(chu)較好(hao)的(de)(de)(de)(de)拉線特性,較大(da)的(de)(de)(de)(de)Cu2O顆(ke)(ke)(ke)粒(li)(li)(li)容(rong)易造成應力集(ji)中(zhong)點而斷裂(lie)。

無氧(yang)(yang)(yang)銅(tong)含(han)氧(yang)(yang)(yang)量(liang)超(chao)標,銅(tong)桿變(bian)脆(cui),延(yan)伸率(lv)下(xia)降,拉伸式樣端口顯(xian)暗紅(hong)色,結(jie)晶組織疏松。當氧(yang)(yang)(yang)含(han)量(liang)超(chao)出8ppm時,工(gong)藝(yi)(yi)性(xing)能(neng)變(bian)差(cha),表現為鑄造(zao)及(ji)拉伸過程中(zhong)(zhong)斷(duan)桿及(ji)斷(duan)線率(lv)極(ji)具增高。這是由于氧(yang)(yang)(yang)能(neng)與銅(tong)生成氧(yang)(yang)(yang)化亞(ya)銅(tong)脆(cui)性(xing)相(xiang),形成銅(tong)-氧(yang)(yang)(yang)化亞(ya)銅(tong)共晶體,以(yi)網狀組織分布在(zai)境界上(shang)。這種(zhong)脆(cui)性(xing)相(xiang)硬(ying)度高,在(zai)冷變(bian)形時將會與銅(tong)機體脫(tuo)離(li),導(dao)致銅(tong)桿的機械性(xing)能(neng)下(xia)降,在(zai)后(hou)續(xu)加工(gong)中(zhong)(zhong)容易造(zao)成斷(duan)裂現象。氧(yang)(yang)(yang)含(han)量(liang)高還能(neng)導(dao)致無氧(yang)(yang)(yang)銅(tong)桿導(dao)電率(lv)下(xia)降。因此,必(bi)須嚴格控制上(shang)引連鑄工(gong)藝(yi)(yi)及(ji)產品質(zhi)量(liang)。

4、氫的影響

在上引連鑄中,氧含量(liang)控制較(jiao)低(di),氧化物的(de)(de)副作用唄**降(jiang)低(di),但氫的(de)(de)影響成為(wei)較(jiao)顯(xian)著的(de)(de)問(wen)題。吸(xi)氣后(hou)熔體(ti)中存(cun)在平(ping)衡反應:H2O(g)=[O]+2[H];

氣(qi)體及疏(shu)松是在(zai)(zai)結(jie)(jie)晶(jing)(jing)的(de)過程中(zhong),氫(qing)從過飽和(he)的(de)溶液中(zhong)析出(chu)(chu)并聚(ju)集而形(xing)(xing)成(cheng)的(de)。在(zai)(zai)結(jie)(jie)晶(jing)(jing)前析出(chu)(chu)的(de)氫(qing)又可還(huan)原(yuan)氧(yang)化亞銅而生成(cheng)水氣(qi)泡。由于(yu)上(shang)引(yin)鑄(zhu)造的(de)特(te)點是銅液自(zi)上(shang)而下(xia)的(de)結(jie)(jie)晶(jing)(jing),形(xing)(xing)成(cheng)的(de)液**形(xing)(xing)狀近(jin)似錐型。銅液結(jie)(jie)晶(jing)(jing)前析出(chu)(chu)的(de)氣(qi)體在(zai)(zai)上(shang)浮過程中(zhong)被堵在(zai)(zai)凝固組織內,結(jie)(jie)晶(jing)(jing)時在(zai)(zai)鑄(zhu)桿內形(xing)(xing)成(cheng)氣(qi)孔。上(shang)引(yin)的(de)含氣(qi)量少時,析出(chu)(chu)的(de)氫(qing)存(cun)在(zai)(zai)于(yu)晶(jing)(jing)界處,形(xing)(xing)成(cheng)疏(shu)松;含氣(qi)量多時,則(ze)聚(ju)集成(cheng)氣(qi)孔,因此,氣(qi)孔和(he)疏(shu)松是氫(qing)氣(qi)和(he)水蒸氣(qi)兩者形(xing)(xing)成(cheng)的(de)。

氫(qing)來源(yuan)于(yu)上(shang)引(yin)生產過程中(zhong)的各(ge)個工藝(yi)環節,如(ru)原(yuan)料電(dian)解(jie)銅(tong)(tong)的“銅(tong)(tong)綠(lv)”、輔(fu)料木(mu)炭(tan)(tan)**、氣候(hou)環境**、石(shi)墨結晶器未干燥(zao)等。因(yin)此,熔化爐中(zhong)的銅(tong)(tong)液(ye)表面應覆蓋經(jing)烘(hong)烤的木(mu)炭(tan)(tan),電(dian)解(jie)銅(tong)(tong)應盡量去除(chu)“銅(tong)(tong)綠(lv)”、“銅(tong)(tong)豆(dou)”“耳朵”,對提高無氧銅(tong)(tong)桿(gan)質(zhi)量非常(chang)重要(yao)。

在連鑄連軋工藝中,往往采用適度控(kong)制氧含(han)量(liang)來(lai)控(kong)制氫。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)(tong)液在鑄造過程中(zhong)是自(zi)下而上(shang)結晶,銅(tong)(tong)液中(zhong)的(de)(de)氧和氫所(suo)產生的(de)(de)水蒸氣很容易上(shang)浮(fu)跑(pao)出,銅(tong)(tong)液中(zhong)的(de)(de)氫大部分能被有效去(qu)除,因而對(dui)銅(tong)(tong)桿(gan)的(de)(de)影響(xiang)較(jiao)小。

二、表面質量

在生產(chan)電磁(ci)線(xian)等產(chan)品的過(guo)程中,對銅(tong)桿(gan)的表(biao)面(mian)質量也(ye)需提出要求(qiu)。需要拉制后(hou)(hou)的銅(tong)絲表(biao)面(mian)無(wu)毛刺、銅(tong)粉少、無(wu)油污。并通過(guo)扭(niu)轉試(shi)驗測量表(biao)面(mian)銅(tong)粉的質量和(he)扭(niu)轉后(hou)(hou)觀察銅(tong)桿(gan)的復原情況來判定(ding)其好(hao)壞。

在(zai)連鑄連軋(ya)(ya)(ya)過(guo)程(cheng)中(zhong),從鑄造到軋(ya)(ya)(ya)制(zhi)前,溫度(du)高(gao),完全暴露于(yu)(yu)(yu)空(kong)氣中(zhong),使鑄坯表(biao)面(mian)(mian)形成較厚的氧化(hua)(hua)層(ceng),在(zai)軋(ya)(ya)(ya)制(zhi)過(guo)程(cheng)中(zhong),隨著軋(ya)(ya)(ya)輥的轉動(dong),氧化(hua)(hua)物顆粒軋(ya)(ya)(ya)入(ru)銅(tong)線表(biao)面(mian)(mian)。由(you)于(yu)(yu)(yu)氧化(hua)(hua)亞(ya)銅(tong)是(shi)高(gao)熔(rong)點脆性化(hua)(hua)合物,對于(yu)(yu)(yu)軋(ya)(ya)(ya)入(ru)較深的氧化(hua)(hua)亞(ya)銅(tong),當成條狀的聚集(ji)物遇模具拉伸(shen)時,就(jiu)會是(shi)銅(tong)桿(gan)外表(biao)面(mian)(mian)產生毛(mao)刺(ci),給后續的涂(tu)漆造成麻煩。

而(er)上(shang)引連鑄(zhu)工藝制造的(de)無(wu)氧(yang)銅(tong)桿,由(you)于鑄(zhu)造和冷卻完全與氧(yang)隔絕,后(hou)續亦無(wu)熱(re)軋過(guo)程(cheng),銅(tong)桿表(biao)面無(wu)軋入(ru)表(biao)面的(de)氧(yang)化物,質量較好,拉(la)制后(hou)銅(tong)粉少(shao),上(shang)述問題較少(shao)存在。

無氧銅(tong)桿也分(fen)進(jin)口設(she)備(bei)做(zuo)的(de)和國(guo)產(chan)(chan)設(she)備(bei)做(zuo)的(de),但目(mu)前(qian)進(jin)口產(chan)(chan)品(pin)已無明顯優勢,銅(tong)桿產(chan)(chan)品(pin)出(chu)來后(hou)區別不是很(hen)大,只要銅(tong)板選的(de)好,生產(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)設(she)備(bei)也能產(chan)(chan)出(chu)可拉伸0.05的(de)銅(tong)桿.進(jin)口設(she)備(bei)一般(ban)是芬(fen)蘭奧托昆普的(de)設(she)備(bei),國(guo)產(chan)(chan)設(she)備(bei)最(zui)好的(de)應該是上(shang)海的(de)海軍廠的(de)了,生產(chan)(chan)時間最(zui)長(chang),軍工企業,質(zhi)量可靠(kao)。

低氧銅桿(gan)進口設(she)(she)備(bei)國(guo)(guo)際主(zhu)要有(you)兩種(zhong),一種(zhong)是(shi)(shi)(shi)美國(guo)(guo)南(nan)線(xian)設(she)(she)備(bei),英文是(shi)(shi)(shi)SOUTHWIRE,國(guo)(guo)內廠家是(shi)(shi)(shi)南(nan)京華新(xin),江西銅業,另一種(zhong)是(shi)(shi)(shi)德國(guo)(guo)CONTIROD設(she)(she)備(bei),國(guo)(guo)內廠家是(shi)(shi)(shi)常州金(jin)源,天津大無縫。

無(wu)氧(yang)及低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)從含氧(yang)量(liang)上(shang)容易區別,無(wu)氧(yang)銅是含氧(yang)量(liang)在(zai)10-20個(ge)PPM以下,但目前有的(de)(de)(de)廠家只(zhi)能(neng)做(zuo)到50個(ge)PPM以下.低(di)(di)氧(yang)銅桿(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好(hao)的(de)(de)(de)桿(gan)(gan)(gan)(gan)子一般(ban)含氧(yang)量(liang)控制(zhi)在(zai)250個(ge)PPM左右(you),無(wu)氧(yang)桿(gan)(gan)(gan)(gan)一般(ban)采取的(de)(de)(de)是上(shang)引法,低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)是連鑄連軋,兩種產品(pin)相對(dui)而言(yan)低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)對(dui)漆包線(xian)性(xing) 能(neng)更適應(ying)些,如(ru)柔軟性(xing),回(hui)彈角(jiao),繞線(xian)性(xing)能(neng).但低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)對(dui)拉絲條件(jian)相對(dui)要苛刻(ke)些,同樣(yang)拉伸(shen)0.2的(de)(de)(de)細絲,如(ru)果伸(shen)線(xian)條件(jian)不好(hao),普(pu)通的(de)(de)(de)無(wu)氧(yang)桿(gan)(gan)(gan)(gan)可拉而好(hao)的(de)(de)(de)低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)就斷 線(xian),但如(ru)果放在(zai)好(hao)的(de)(de)(de)伸(shen)線(xian)條件(jian),同樣(yang)的(de)(de)(de)桿(gan)(gan)(gan)(gan)子,低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)說不定就能(neng)拉到雙零(ling)五,而普(pu)通無(wu)氧(yang)桿(gan)(gan)(gan)(gan)最(zui)(zui)多只(zhi)能(neng)拉伸(shen)到0.1而已,當然做(zuo)的(de)(de)(de)最(zui)(zui)細的(de)(de)(de)如(ru)雙零(ling)二卻(que)非(fei)得依(yi)靠進(jin)口的(de)(de)(de) 無(wu)氧(yang)銅桿(gan)(gan)(gan)(gan)了.目前有企(qi)業嘗試用剝皮的(de)(de)(de)方(fang)式來處理低(di)(di)氧(yang)桿(gan)(gan)(gan)(gan)來伸(shen)0.03線(xian).但有關這方(fang)面的(de)(de)(de)內容我還不是很(hen)清楚(chu)。

音響(xiang)線一般反而喜(xi)歡(huan)用(yong)無氧(yang)桿(gan),這和無氧(yang)桿(gan)是(shi)單(dan)晶(jing)銅,低氧(yang)桿(gan)是(shi)多晶(jing)銅有(you)關(guan)。

氧銅桿和無氧銅桿由于制造(zao)方(fang)法的(de)不同,致使存在差別,具(ju)有(you)各自的(de)特點。

一、關(guan)于氧的(de)吸入和脫去以及它(ta)的(de)存在狀態

生(sheng)產銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)一(yi)般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)固(gu)溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)一(yi)般在(zai)(zai)200(175)—400(450)ppm,因此(ci)氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)液態(tai)下(xia)吸入的(de)(de)(de)(de),而(er)(er)上(shang)引法無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)則相(xiang)反(fan),氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)(tong)下(xia)保持相(xiang)當(dang)時間(jian)后,被還原而(er)(er)脫去,通常(chang)這種(zhong)桿(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以下(xia),最(zui)低(di)可達1-2ppm,從組織(zhi)(zhi)上(shang)看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)(tong)狀態(tai),存(cun)在(zai)(zai)于晶(jing)粒(li)邊界附(fu)近,這對低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)而(er)(er)言(yan)可以說是常(chang)見的(de)(de)(de)(de)但對無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)則很少(shao)見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)(tong)以夾雜形式在(zai)(zai)晶(jing)界出現對材(cai)料(liao)的(de)(de)(de)(de)韌性(xing)產生(sheng)負(fu)面影響。而(er)(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所(suo)以這種(zhong)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)組織(zhi)(zhi)是均勻的(de)(de)(de)(de)單(dan)相(xiang)組織(zhi)(zhi)對韌性(xing)有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)多(duo)孔性(xing)是不常(chang)見的(de)(de)(de)(de),而(er)(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)中則是常(chang)見的(de)(de)(de)(de)一(yi)種(zhong)缺陷。

二、熱(re)軋組(zu)織(zhi)和鑄造(zao)組(zu)織(zhi)的區別

低氧銅(tong)(tong)桿(gan)由于經過熱(re)軋,所以(yi)其組(zu)(zu)織(zhi)(zhi)屬熱(re)加工組(zu)(zu)織(zhi)(zhi),原來(lai)的(de)(de)鑄造(zao)組(zu)(zu)織(zhi)(zhi)已(yi)經破碎,在(zai)(zai)8mm的(de)(de)桿(gan)時已(yi)有(you)再(zai)結(jie)晶(jing)的(de)(de)形式出現(xian),而(er)無氧銅(tong)(tong)桿(gan)屬鑄造(zao)組(zu)(zu)織(zhi)(zhi),晶(jing)粒(li)粗大(da),這是(shi)為(wei)什么,無氧銅(tong)(tong)的(de)(de)再(zai)結(jie)晶(jing)溫(wen)度(du)較(jiao)高,需要(yao)(yao)較(jiao)高退(tui)(tui)火溫(wen)度(du)的(de)(de)固有(you)原因。這是(shi)因為(wei),再(zai)結(jie)晶(jing)發生在(zai)(zai)晶(jing)粒(li)邊(bian)界附近,無氧銅(tong)(tong)桿(gan)組(zu)(zu)織(zhi)(zhi)晶(jing)粒(li)粗大(da),晶(jing)粒(li)尺寸甚至能達幾個(ge)毫米,因而(er)晶(jing)粒(li)邊(bian)界少,即使(shi)通(tong)過拉(la)制(zhi)(zhi)(zhi)(zhi)變形,但晶(jing)粒(li)邊(bian)界相對低氧銅(tong)(tong)桿(gan)還是(shi)較(jiao)少,所以(yi)需要(yao)(yao)較(jiao)高的(de)(de)退(tui)(tui)火功率(lv)。對無氧銅(tong)(tong)成(cheng)功的(de)(de)退(tui)(tui)火要(yao)(yao)求(qiu)是(shi):由桿(gan)經拉(la)制(zhi)(zhi)(zhi)(zhi),但尚未鑄造(zao)組(zu)(zu)織(zhi)(zhi)的(de)(de)線時的(de)(de)第一(yi)次退(tui)(tui)火,其退(tui)(tui)火功率(lv)應(ying)(ying)比(bi)同(tong)樣情況的(de)(de)低氧銅(tong)(tong)高10——15%。經繼(ji)續拉(la)制(zhi)(zhi)(zhi)(zhi),在(zai)(zai)以(yi)后階段(duan)的(de)(de)退(tui)(tui)火功率(lv)應(ying)(ying)留有(you)足(zu)夠的(de)(de)余(yu)量和對低氧銅(tong)(tong)和無氧銅(tong)(tong)切實區(qu)別執行不同(tong)的(de)(de)退(tui)(tui)火工藝(yi),以(yi)保證(zheng)在(zai)(zai)制(zhi)(zhi)(zhi)(zhi)品和成(cheng)品導線的(de)(de)柔軟性。

三、夾雜,氧含量(liang)波動,表(biao)面氧化(hua)物(wu)和可能(neng)存(cun)在的熱軋缺陷的差(cha)別

無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)的(de)可拉性在(zai)所有線(xian)(xian)徑里與低氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)相比都是優越的(de),除上述(shu)組織原因(yin)外,無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)夾雜少,含(han)(han)氧(yang)(yang)(yang)量(liang)穩定,無(wu)熱軋可能(neng)產生(sheng)(sheng)的(de)缺陷,桿(gan)(gan)表(biao)氧(yang)(yang)(yang)化物厚(hou)度可達≤15A。在(zai)連鑄連軋生(sheng)(sheng)產過程(cheng)中如(ru)果工(gong)藝不(bu)穩定,對(dui)氧(yang)(yang)(yang)監控不(bu)嚴,含(han)(han)氧(yang)(yang)(yang)量(liang)不(bu)穩定將(jiang)直接(jie)影(ying)響桿(gan)(gan)的(de)性能(neng)。如(ru)果桿(gan)(gan)的(de)表(biao)面(mian)氧(yang)(yang)(yang)化物能(neng)在(zai)后工(gong)序(xu)的(de)連續清(qing)洗中得以(yi)彌補外,但比較麻煩的(de)是有相當(dang)多的(de)氧(yang)(yang)(yang)化物存在(zai)于“皮(pi)(pi)(pi)下”,對(dui)拉線(xian)(xian)斷線(xian)(xian)影(ying)響更(geng)直接(jie),故(gu)而(er)在(zai)拉制(zhi)微細線(xian)(xian),超(chao)微細線(xian)(xian)時,為了(le)減少斷線(xian)(xian),有時要對(dui)銅(tong)桿(gan)(gan)采取不(bu)得已的(de)辦法——剝皮(pi)(pi)(pi),甚至二次剝皮(pi)(pi)(pi)的(de)原因(yin)所在(zai),目的(de)要除去皮(pi)(pi)(pi)下氧(yang)(yang)(yang)化物。

四(si)、低氧(yang)銅(tong)桿(gan)和無氧(yang)銅(tong)桿(gan)的韌性有(you)差別

兩者都可以拉到0.015mm,但(dan)在低溫(wen)超導線中(zhong)的低溫(wen)級無(wu)氧銅(tong),其細絲間的間距只有0.001mm.

五、從(cong)制桿的(de)(de)原(yuan)材(cai)料到制線的(de)(de)經濟性有差別。

制造(zao)無氧銅桿要求(qiu)質(zhi)量較(jiao)高的(de)原(yuan)材料(liao)。一般,拉制直徑(jing)(jing)>1mm的(de)銅線(xian)時,低氧銅桿的(de)優(you)點比較(jiao)明顯(xian),而無氧銅桿顯(xian)得更為優(you)越的(de)是拉制直徑(jing)(jing)<0.5mm的(de)銅線(xian)。

六、低氧(yang)銅(tong)桿的制(zhi)線工藝(yi)與無氧(yang)銅(tong)桿的有所不同。

低氧(yang)銅(tong)桿(gan)的制(zhi)線(xian)工藝不能照搬(ban)到無氧(yang)銅(tong)桿(gan)的制(zhi)線(xian)工藝上來,至(zhi)少兩者的退(tui)火工藝是不同的。因為(wei)線(xian)的柔(rou)軟性深(shen)受(shou)材(cai)料(liao)成份和(he)制(zhi)桿(gan),制(zhi)線(xian)和(he)退(tui)火工藝的影(ying)響(xiang),不能簡單地說低氧(yang)銅(tong)或無氧(yang)銅(tong)誰軟誰硬(ying)。