熱門關鍵詞(ci):
來源:行業動態(tai) 閱讀:109502 發布時間(jian):2019-07-05
導讀:由于(yu)生產(chan)(chan)銅(tong)桿(gan)(gan)的(de)(de)兩者的(de)(de)工(gong)藝不(bu)同(tong),所生產(chan)(chan)的(de)(de)銅(tong)桿(gan)(gan)中的(de)(de)含氧量(liang)及外觀就不(bu)同(tong)。上(shang)引生產(chan)(chan)的(de)(de)銅(tong)桿(gan)(gan),工(gong)藝得當氧含量(liang)在10ppm以(yi)下(xia),叫(jiao)無氧銅(tong)桿(gan)(gan);連鑄(zhu)連鑄(zhu)生產(chan)(chan)的(de)(de)銅(tong)桿(gan)(gan) 是在保護(hu)條(tiao)件下(xia)的(de)(de)熱軋(ya),氧含量(liang)在200-500ppm范(fan)圍內,但有(you)時也(ye)高達700ppm以(yi)上(shang),一(yi)般情況下(xia),此種方法生產(chan)(chan)的(de)(de)銅(tong)外表光(guang)亮,低氧銅(tong)桿(gan)(gan),有(you)時也(ye)叫(jiao)光(guang)桿(gan)(gan)。
銅桿(gan)是(shi)電纜行(xing)(xing)業的(de)(de)主要(yao)原(yuan)料,生(sheng)產(chan)的(de)(de)方(fang)(fang)式(shi)主要(yao)有兩種——連鑄(zhu)(zhu)(zhu)連軋法和上引(yin)連鑄(zhu)(zhu)(zhu)法。連鑄(zhu)(zhu)(zhu)連軋低(di)氧(yang)(yang)銅桿(gan)的(de)(de)生(sheng)產(chan)方(fang)(fang)法較多(duo),其特點是(shi)金(jin)(jin)屬在豎爐(lu)(lu)中融(rong)化后(hou),銅液通(tong)過保溫爐(lu)(lu)、溜槽(cao)、中間包,從澆管進(jin)(jin)入封閉的(de)(de)模腔內(nei),采用較大的(de)(de)冷(leng)卻強(qiang)度進(jin)(jin)行(xing)(xing)冷(leng)卻,形成鑄(zhu)(zhu)(zhu)坯,然(ran)后(hou)進(jin)(jin)行(xing)(xing)多(duo)道次(ci)軋制(zhi),生(sheng)產(chan)的(de)(de)低(di)氧(yang)(yang)銅桿(gan)為熱加(jia)工(gong)組(zu)織(zhi),原(yuan)來的(de)(de)鑄(zhu)(zhu)(zhu)造(zao)組(zu)織(zhi)已經破碎(sui),含(han)(han)氧(yang)(yang)量(liang)(liang)一般為200~400ppm之間。無氧(yang)(yang)銅桿(gan)國內(nei)基本全部采用上引(yin)連鑄(zhu)(zhu)(zhu)法生(sheng)產(chan),金(jin)(jin)屬在感應電爐(lu)(lu)中融(rong)化后(hou)通(tong)過石墨模進(jin)(jin)行(xing)(xing)上引(yin)連續鑄(zhu)(zhu)(zhu)造(zao),之后(hou)進(jin)(jin)行(xing)(xing)冷(leng)軋或冷(leng)加(jia)工(gong),生(sheng)產(chan)的(de)(de)無氧(yang)(yang)銅桿(gan)為鑄(zhu)(zhu)(zhu)造(zao)組(zu)織(zhi),含(han)(han)氧(yang)(yang)量(liang)(liang)一般在20ppm以下。由于制(zhi)造(zao)工(gong)藝(yi)的(de)(de)不同,所以在組(zu)織(zhi)結構(gou)、氧(yang)(yang)含(han)(han)量(liang)(liang)分(fen)(fen)布(bu)、雜質的(de)(de)形式(shi)及分(fen)(fen)布(bu)等諸多(duo)方(fang)(fang)面有較大差別。
一、拉制性能
銅桿的拉制性(xing)能跟很多因素有關,如雜質的含量、氧含量及分(fen)(fen)布、工藝控制等(deng)。下面分(fen)(fen)別從以上幾個方面對(dui)銅桿的拉制性(xing)能進(jin)行分(fen)(fen)析。
1、熔化方式(shi)對S等雜(za)質的影響(xiang)
連(lian)鑄(zhu)連(lian)軋(ya)生(sheng)產銅(tong)(tong)(tong)桿(gan)主要(yao)是通過氣體的燃(ran)燒(shao)使銅(tong)(tong)(tong)桿(gan)熔(rong)化,在燃(ran)燒(shao)的過程(cheng)中,通過氧(yang)化和揮(hui)發作用(yong),可一(yi)定(ding)程(cheng)度(du)減少(shao)部分雜質進入(ru)銅(tong)(tong)(tong)液,因此連(lian)鑄(zhu)連(lian)軋(ya)法對原料要(yao)求相對低一(yi)些。上引連(lian)鑄(zhu)生(sheng)產無氧(yang)銅(tong)(tong)(tong)桿(gan),由于(yu)是用(yong)感(gan)應電爐熔(rong)化,電解銅(tong)(tong)(tong)表面的“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆(dou)”基本都熔(rong)入(ru)到銅(tong)(tong)(tong)液中。其(qi)中熔(rong)入(ru)的S對無氧(yang)銅(tong)(tong)(tong)桿(gan)塑性影響(xiang)極大(da),會增加拉(la)絲斷線率(lv)。
2、鑄造(zao)過(guo)程中雜質的進入
在生產(chan)過(guo)(guo)(guo)程中(zhong)(zhong),連(lian)鑄(zhu)連(lian)軋工藝需通過(guo)(guo)(guo)保溫爐、溜(liu)槽、中(zhong)(zhong)間包轉運銅液,相(xiang)對容易造(zao)(zao)成耐(nai)火材料(liao)的(de)(de)(de)剝(bo)落(luo),在軋制過(guo)(guo)(guo)程中(zhong)(zhong)需要通過(guo)(guo)(guo)軋輥,造(zao)(zao)成鐵質(zhi)(zhi)的(de)(de)(de)脫落(luo),會給銅桿(gan)造(zao)(zao)成外部(bu)夾(jia)雜。而熱軋中(zhong)(zhong)皮上和皮下氧(yang)化物的(de)(de)(de)軋入,會給低(di)氧(yang)桿(gan)的(de)(de)(de)拉(la)絲造(zao)(zao)成不(bu)利的(de)(de)(de)影響。上引連(lian)鑄(zhu)法(fa)生產(chan)工藝流(liu)程較短,銅液是(shi)通過(guo)(guo)(guo)聯體(ti)爐內潛流(liu)式完成,對耐(nai)火材料(liao)的(de)(de)(de)沖擊不(bu)大(da),結(jie)晶是(shi)通過(guo)(guo)(guo)石墨模內進行,所以(yi)過(guo)(guo)(guo)程中(zhong)(zhong)可能產(chan)生的(de)(de)(de)污染(ran)源較少(shao),雜質(zhi)(zhi)進入的(de)(de)(de)機會較少(shao)。
O、S、P是與銅(tong)會生產化合物的(de)(de)元素。在熔態銅(tong)中,氧可以溶(rong)解一部分,但(dan)當銅(tong)冷凝(ning)時(shi),氧幾乎不(bu)溶(rong)解于銅(tong)中。熔態時(shi)所溶(rong)解的(de)(de)氧,以銅(tong)=氧化亞(ya)銅(tong)共(gong)晶體(ti)析出(chu),分布在晶粒晶界(jie)處。銅(tong)-氧化亞(ya)銅(tong)共(gong)晶體(ti)的(de)(de)出(chu)現(xian),顯著降(jiang)低(di)了(le)銅(tong)的(de)(de)塑(su)性。
硫可以(yi)溶解在熔(rong)體的(de)銅中(zhong),但(dan)在室溫下(xia),其溶解度幾乎(hu)降低到(dao)零(ling),它(ta)以(yi)硫化亞銅的(de)形式出(chu)現在晶粒晶界處,會顯著(zhu)降低銅的(de)塑性。
3、氧在低氧銅(tong)桿和無氧銅(tong)桿中分(fen)布形式及其影響(xiang)
氧(yang)(yang)含量對(dui)低氧(yang)(yang)銅桿的拉線(xian)性能有著(zhu)明顯的影響(xiang)。當氧(yang)(yang)含量增加到最(zui)佳值時(shi),銅桿的斷線(xian)率最(zui)低。這是因為氧(yang)(yang)在與大部(bu)分雜質(zhi)反(fan)應的過(guo)程中都起到了清除(chu)器的作用。適度的氧(yang)(yang)還有利(li)于去(qu)除(chu)銅液中的氫(qing),生成水蒸氣溢出,減少氣孔(kong)的形成。最(zui)佳的氧(yang)(yang)含量為拉線(xian)工(gong)藝提供了最(zui)好的條件。
低氧(yang)銅(tong)(tong)桿(gan)氧(yang)化(hua)物的(de)(de)分(fen)(fen)布:在(zai)連(lian)續(xu)澆(jiao)鑄(zhu)中(zhong)凝固的(de)(de)最(zui)初(chu)階段,散熱速(su)率和(he)均勻(yun)冷(leng)卻是決(jue)定銅(tong)(tong)桿(gan)氧(yang)化(hua)物分(fen)(fen)布的(de)(de)主要因素。不(bu)均勻(yun)冷(leng)卻會(hui)引(yin)起銅(tong)(tong)桿(gan)內部結構本(ben)質上的(de)(de)差異(yi),但后續(xu)的(de)(de)熱加工,柱狀(zhuang)晶通常會(hui)遭到破壞,使氧(yang)化(hua)亞銅(tong)(tong)顆(ke)(ke)粒(li)(li)(li)細微化(hua)和(he)均勻(yun)分(fen)(fen)布。氧(yang)化(hua)物顆(ke)(ke)粒(li)(li)(li)聚集(ji)而產(chan)生(sheng)的(de)(de)典型情(qing)況是中(zhong)心(xin)爆裂。除氧(yang)化(hua)物顆(ke)(ke)粒(li)(li)(li)分(fen)(fen)布的(de)(de)影(ying)響外,具有(you)較(jiao)小氧(yang)化(hua)物顆(ke)(ke)粒(li)(li)(li)的(de)(de)銅(tong)(tong)桿(gan)顯示(shi)出較(jiao)好的(de)(de)拉線特性,較(jiao)大的(de)(de)Cu2O顆(ke)(ke)粒(li)(li)(li)容易造成應力集(ji)中(zhong)點而斷裂。
無(wu)氧(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)量(liang)超標,銅(tong)(tong)(tong)桿變(bian)脆(cui),延伸率下降,拉(la)伸式樣端口顯暗(an)紅色,結晶組(zu)織疏松。當氧(yang)(yang)含量(liang)超出(chu)8ppm時,工(gong)藝性能變(bian)差(cha),表(biao)現為(wei)鑄(zhu)造及(ji)(ji)(ji)拉(la)伸過程中斷(duan)桿及(ji)(ji)(ji)斷(duan)線(xian)率極具增高(gao)。這(zhe)是(shi)由于(yu)氧(yang)(yang)能與銅(tong)(tong)(tong)生成(cheng)氧(yang)(yang)化(hua)亞(ya)銅(tong)(tong)(tong)脆(cui)性相,形(xing)成(cheng)銅(tong)(tong)(tong)-氧(yang)(yang)化(hua)亞(ya)銅(tong)(tong)(tong)共晶體,以(yi)網狀(zhuang)組(zu)織分布(bu)在境界上(shang)。這(zhe)種(zhong)脆(cui)性相硬度高(gao),在冷(leng)變(bian)形(xing)時將會與銅(tong)(tong)(tong)機體脫離(li),導致(zhi)銅(tong)(tong)(tong)桿的機械(xie)性能下降,在后續(xu)加工(gong)中容(rong)易造成(cheng)斷(duan)裂(lie)現象(xiang)。氧(yang)(yang)含量(liang)高(gao)還能導致(zhi)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿導電率下降。因(yin)此(ci),必(bi)須嚴格控制(zhi)上(shang)引連鑄(zhu)工(gong)藝及(ji)(ji)(ji)產品質量(liang)。
4、氫的影響
在上引(yin)連鑄中(zhong),氧含量控(kong)制較低(di),氧化(hua)物的(de)(de)副作用唄**降低(di),但(dan)氫(qing)的(de)(de)影響成為(wei)較顯著的(de)(de)問(wen)題。吸氣后熔體中(zhong)存在平(ping)衡反應:H2O(g)=[O]+2[H];
氣(qi)體(ti)及疏(shu)松(song)是在(zai)結晶的(de)(de)(de)(de)過程中,氫(qing)從(cong)過飽和的(de)(de)(de)(de)溶液(ye)中析出(chu)并聚集而(er)形(xing)成(cheng)的(de)(de)(de)(de)。在(zai)結晶前析出(chu)的(de)(de)(de)(de)氫(qing)又可(ke)還原氧化(hua)亞銅(tong)而(er)生成(cheng)水氣(qi)泡。由于上引(yin)鑄造的(de)(de)(de)(de)特點是銅(tong)液(ye)自上而(er)下(xia)的(de)(de)(de)(de)結晶,形(xing)成(cheng)的(de)(de)(de)(de)液(ye)**形(xing)狀近似錐型。銅(tong)液(ye)結晶前析出(chu)的(de)(de)(de)(de)氣(qi)體(ti)在(zai)上浮過程中被堵(du)在(zai)凝(ning)固(gu)組織內,結晶時在(zai)鑄桿(gan)內形(xing)成(cheng)氣(qi)孔。上引(yin)的(de)(de)(de)(de)含(han)氣(qi)量少時,析出(chu)的(de)(de)(de)(de)氫(qing)存(cun)在(zai)于晶界處,形(xing)成(cheng)疏(shu)松(song);含(han)氣(qi)量多時,則(ze)聚集成(cheng)氣(qi)孔,因此,氣(qi)孔和疏(shu)松(song)是氫(qing)氣(qi)和水蒸氣(qi)兩者形(xing)成(cheng)的(de)(de)(de)(de)。
氫來(lai)源于上(shang)引生產過程中的(de)各個工(gong)藝(yi)環節,如原料電(dian)解(jie)銅(tong)的(de)“銅(tong)綠”、輔料木(mu)炭(tan)**、氣候環境**、石墨結晶(jing)器未干燥等(deng)。因(yin)此(ci),熔化爐中的(de)銅(tong)液表面應(ying)(ying)覆(fu)蓋(gai)經烘烤的(de)木(mu)炭(tan),電(dian)解(jie)銅(tong)應(ying)(ying)盡(jin)量去除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對提高無氧銅(tong)桿質量非(fei)常重(zhong)要(yao)。
在連鑄連軋工(gong)藝中,往(wang)(wang)往(wang)(wang)采用適度控制(zhi)(zhi)氧含量來控制(zhi)(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)(tong)液(ye)在鑄(zhu)造過程(cheng)中(zhong)是自下而上(shang)結(jie)晶,銅(tong)(tong)液(ye)中(zhong)的氧和氫所產生的水(shui)蒸氣很容易上(shang)浮跑出,銅(tong)(tong)液(ye)中(zhong)的氫大部(bu)分(fen)能被有效去除,因而對銅(tong)(tong)桿的影(ying)響較小。
二、表面質量
在生(sheng)產(chan)(chan)電(dian)磁線等產(chan)(chan)品的(de)(de)過程中,對銅桿(gan)的(de)(de)表(biao)面(mian)質(zhi)量也需提出(chu)要求(qiu)。需要拉制后的(de)(de)銅絲表(biao)面(mian)無毛刺(ci)、銅粉少、無油污。并通過扭轉試驗測量表(biao)面(mian)銅粉的(de)(de)質(zhi)量和扭轉后觀察銅桿(gan)的(de)(de)復原情況來判定(ding)其好壞。
在(zai)連(lian)鑄連(lian)軋(ya)(ya)過程中,從鑄造到(dao)軋(ya)(ya)制(zhi)前,溫度高,完全暴露于(yu)(yu)(yu)空氣(qi)中,使鑄坯表面形成(cheng)較厚的(de)(de)氧(yang)化(hua)層,在(zai)軋(ya)(ya)制(zhi)過程中,隨著軋(ya)(ya)輥的(de)(de)轉動(dong),氧(yang)化(hua)物(wu)顆粒(li)軋(ya)(ya)入(ru)銅線表面。由于(yu)(yu)(yu)氧(yang)化(hua)亞(ya)銅是(shi)(shi)高熔點脆性化(hua)合物(wu),對于(yu)(yu)(yu)軋(ya)(ya)入(ru)較深的(de)(de)氧(yang)化(hua)亞(ya)銅,當成(cheng)條狀的(de)(de)聚集物(wu)遇(yu)模具拉伸時,就(jiu)會是(shi)(shi)銅桿外(wai)表面產生(sheng)毛(mao)刺,給后續的(de)(de)涂漆(qi)造成(cheng)麻煩。
而(er)上引連(lian)鑄工(gong)藝制造的(de)無(wu)氧銅桿,由于(yu)鑄造和冷卻完全(quan)與氧隔絕,后續亦無(wu)熱軋過程,銅桿表(biao)面無(wu)軋入表(biao)面的(de)氧化(hua)物,質量較好,拉制后銅粉(fen)少,上述問題較少存在。
無氧銅(tong)桿(gan)也分進口設(she)備(bei)做(zuo)(zuo)的(de)和國(guo)(guo)產(chan)(chan)(chan)設(she)備(bei)做(zuo)(zuo)的(de),但目前進口產(chan)(chan)(chan)品(pin)已無明(ming)顯(xian)優勢,銅(tong)桿(gan)產(chan)(chan)(chan)品(pin)出來后區別不是(shi)很大,只要銅(tong)板選的(de)好,生產(chan)(chan)(chan)控(kong)制比較穩定,國(guo)(guo)產(chan)(chan)(chan)設(she)備(bei)也能產(chan)(chan)(chan)出可拉(la)伸0.05的(de)銅(tong)桿(gan).進口設(she)備(bei)一(yi)般是(shi)芬蘭奧托(tuo)昆普的(de)設(she)備(bei),國(guo)(guo)產(chan)(chan)(chan)設(she)備(bei)最(zui)好的(de)應該是(shi)上(shang)海(hai)的(de)海(hai)軍廠的(de)了,生產(chan)(chan)(chan)時間最(zui)長,軍工(gong)企業(ye),質(zhi)量可靠。
低氧銅(tong)桿(gan)進口設備(bei)國(guo)際主要有兩種(zhong),一種(zhong)是(shi)美國(guo)南線設備(bei),英文是(shi)SOUTHWIRE,國(guo)內廠家是(shi)南京華新,江西銅(tong)業,另一種(zhong)是(shi)德國(guo)CONTIROD設備(bei),國(guo)內廠家是(shi)常州金(jin)源,天津(jin)大無縫。
無(wu)氧(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)桿從含(han)氧(yang)(yang)(yang)(yang)(yang)量上容(rong)易區別(bie),無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)是含(han)氧(yang)(yang)(yang)(yang)(yang)量在(zai)10-20個(ge)PPM以下(xia),但(dan)目(mu)前有的(de)(de)廠家只能(neng)做到50個(ge)PPM以下(xia).低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿在(zai) 200-400個(ge)PPM,好(hao)的(de)(de)桿子一般含(han)氧(yang)(yang)(yang)(yang)(yang)量控制在(zai)250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)(yang)桿一般采(cai)取的(de)(de)是上引法,低(di)氧(yang)(yang)(yang)(yang)(yang)桿是連鑄連軋,兩種產品相對(dui)而(er)言低(di)氧(yang)(yang)(yang)(yang)(yang)桿對(dui)漆包線性 能(neng)更(geng)適(shi)應些(xie)(xie),如(ru)柔(rou)軟(ruan)性,回彈角,繞線性能(neng).但(dan)低(di)氧(yang)(yang)(yang)(yang)(yang)桿對(dui)拉(la)絲(si)條(tiao)件(jian)相對(dui)要苛刻些(xie)(xie),同樣拉(la)伸0.2的(de)(de)細絲(si),如(ru)果(guo)(guo)伸線條(tiao)件(jian)不好(hao),普通的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)桿可拉(la)而(er)好(hao)的(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)桿就(jiu)斷 線,但(dan)如(ru)果(guo)(guo)放在(zai)好(hao)的(de)(de)伸線條(tiao)件(jian),同樣的(de)(de)桿子,低(di)氧(yang)(yang)(yang)(yang)(yang)桿說不定就(jiu)能(neng)拉(la)到雙(shuang)零五,而(er)普通無(wu)氧(yang)(yang)(yang)(yang)(yang)桿最(zui)多只能(neng)拉(la)伸到0.1而(er)已,當然做的(de)(de)最(zui)細的(de)(de)如(ru)雙(shuang)零二卻非(fei)得(de)依靠進口的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿了.目(mu)前有企(qi)業嘗(chang)試用(yong)剝皮的(de)(de)方式來(lai)處理低(di)氧(yang)(yang)(yang)(yang)(yang)桿來(lai)伸0.03線.但(dan)有關(guan)這(zhe)方面的(de)(de)內容(rong)我還不是很清(qing)楚。
音響(xiang)線一般反(fan)而喜歡用無氧(yang)桿,這和無氧(yang)桿是單晶銅,低氧(yang)桿是多晶銅有(you)關(guan)。
氧銅(tong)桿和(he)無氧銅(tong)桿由(you)于制造方(fang)法的不同,致使存在差(cha)別,具有各自(zi)的特點。
一、關于氧的吸入和脫去以及它的存在(zai)狀態
生產銅(tong)(tong)(tong)桿的(de)(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)固溶度約(yue)2ppm。低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是(shi)在(zai)(zai)銅(tong)(tong)(tong)的(de)(de)(de)(de)液態下(xia)吸(xi)入的(de)(de)(de)(de),而(er)上引法無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿則(ze)(ze)相(xiang)反,氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態銅(tong)(tong)(tong)下(xia)保持(chi)相(xiang)當時間后,被還原而(er)脫去,通(tong)常(chang)(chang)這(zhe)種桿的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)10—50ppm以(yi)下(xia),最(zui)低(di)(di)(di)可達1-2ppm,從組織(zhi)上看,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)狀(zhuang)態,存在(zai)(zai)于晶粒(li)邊界附近,這(zhe)對(dui)(dui)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿而(er)言(yan)可以(yi)說是(shi)常(chang)(chang)見(jian)的(de)(de)(de)(de)但(dan)對(dui)(dui)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿則(ze)(ze)很少見(jian)。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)以(yi)夾(jia)雜(za)形式(shi)在(zai)(zai)晶界出(chu)現(xian)對(dui)(dui)材料的(de)(de)(de)(de)韌(ren)性(xing)(xing)產生負面影響。而(er)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di)(di)(di),所以(yi)這(zhe)種銅(tong)(tong)(tong)的(de)(de)(de)(de)組織(zhi)是(shi)均(jun)勻的(de)(de)(de)(de)單相(xiang)組織(zhi)對(dui)(dui)韌(ren)性(xing)(xing)有利。在(zai)(zai)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿中(zhong)(zhong)的(de)(de)(de)(de)多孔性(xing)(xing)是(shi)不常(chang)(chang)見(jian)的(de)(de)(de)(de),而(er)在(zai)(zai)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿中(zhong)(zhong)則(ze)(ze)是(shi)常(chang)(chang)見(jian)的(de)(de)(de)(de)一種缺陷。
二、熱軋組織(zhi)和鑄造組織(zhi)的區別
低氧(yang)銅(tong)(tong)(tong)桿(gan)由于經過熱軋,所以(yi)其組(zu)織(zhi)(zhi)(zhi)屬(shu)熱加工(gong)組(zu)織(zhi)(zhi)(zhi),原(yuan)(yuan)來(lai)的(de)(de)鑄造(zao)(zao)組(zu)織(zhi)(zhi)(zhi)已(yi)經破碎,在(zai)(zai)8mm的(de)(de)桿(gan)時(shi)已(yi)有(you)再(zai)結晶(jing)(jing)的(de)(de)形式出現(xian),而(er)無(wu)(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)屬(shu)鑄造(zao)(zao)組(zu)織(zhi)(zhi)(zhi),晶(jing)(jing)粒(li)(li)粗(cu)(cu)大,這是(shi)為(wei)什么,無(wu)(wu)氧(yang)銅(tong)(tong)(tong)的(de)(de)再(zai)結晶(jing)(jing)溫(wen)度(du)較(jiao)(jiao)高,需(xu)要較(jiao)(jiao)高退(tui)(tui)火(huo)溫(wen)度(du)的(de)(de)固(gu)有(you)原(yuan)(yuan)因。這是(shi)因為(wei),再(zai)結晶(jing)(jing)發生在(zai)(zai)晶(jing)(jing)粒(li)(li)邊(bian)界(jie)附(fu)近,無(wu)(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)組(zu)織(zhi)(zhi)(zhi)晶(jing)(jing)粒(li)(li)粗(cu)(cu)大,晶(jing)(jing)粒(li)(li)尺寸甚至能達幾個毫(hao)米,因而(er)晶(jing)(jing)粒(li)(li)邊(bian)界(jie)少(shao),即使(shi)通過拉制變形,但(dan)晶(jing)(jing)粒(li)(li)邊(bian)界(jie)相對(dui)低氧(yang)銅(tong)(tong)(tong)桿(gan)還(huan)是(shi)較(jiao)(jiao)少(shao),所以(yi)需(xu)要較(jiao)(jiao)高的(de)(de)退(tui)(tui)火(huo)功率(lv)。對(dui)無(wu)(wu)氧(yang)銅(tong)(tong)(tong)成(cheng)功的(de)(de)退(tui)(tui)火(huo)要求是(shi):由桿(gan)經拉制,但(dan)尚未(wei)鑄造(zao)(zao)組(zu)織(zhi)(zhi)(zhi)的(de)(de)線時(shi)的(de)(de)第一次退(tui)(tui)火(huo),其退(tui)(tui)火(huo)功率(lv)應比同樣情況(kuang)的(de)(de)低氧(yang)銅(tong)(tong)(tong)高10——15%。經繼(ji)續拉制,在(zai)(zai)以(yi)后階段的(de)(de)退(tui)(tui)火(huo)功率(lv)應留有(you)足夠(gou)的(de)(de)余(yu)量和(he)(he)對(dui)低氧(yang)銅(tong)(tong)(tong)和(he)(he)無(wu)(wu)氧(yang)銅(tong)(tong)(tong)切實(shi)區別執行不同的(de)(de)退(tui)(tui)火(huo)工(gong)藝(yi),以(yi)保證在(zai)(zai)制品和(he)(he)成(cheng)品導線的(de)(de)柔軟性。
三、夾(jia)雜,氧含量波動,表面(mian)氧化物和可(ke)能(neng)存在的熱軋缺陷的差(cha)別(bie)
無(wu)氧銅(tong)桿(gan)(gan)(gan)的可(ke)拉性(xing)在(zai)(zai)所有線(xian)(xian)徑里(li)與低氧銅(tong)桿(gan)(gan)(gan)相(xiang)比都(dou)是(shi)優越(yue)的,除(chu)上述組織原因外(wai),無(wu)氧銅(tong)桿(gan)(gan)(gan)夾雜(za)少(shao),含(han)氧量穩定(ding),無(wu)熱軋(ya)可(ke)能(neng)產生的缺陷,桿(gan)(gan)(gan)表氧化物(wu)厚度可(ke)達≤15A。在(zai)(zai)連鑄連軋(ya)生產過程(cheng)中如果工藝(yi)不(bu)穩定(ding),對(dui)氧監(jian)控(kong)不(bu)嚴,含(han)氧量不(bu)穩定(ding)將(jiang)直接(jie)(jie)影(ying)響(xiang)桿(gan)(gan)(gan)的性(xing)能(neng)。如果桿(gan)(gan)(gan)的表面氧化物(wu)能(neng)在(zai)(zai)后(hou)工序的連續清洗(xi)中得以(yi)彌補外(wai),但比較麻煩的是(shi)有相(xiang)當多的氧化物(wu)存在(zai)(zai)于“皮(pi)下”,對(dui)拉線(xian)(xian)斷(duan)線(xian)(xian)影(ying)響(xiang)更直接(jie)(jie),故而在(zai)(zai)拉制微(wei)細(xi)線(xian)(xian),超微(wei)細(xi)線(xian)(xian)時(shi),為了減少(shao)斷(duan)線(xian)(xian),有時(shi)要對(dui)銅(tong)桿(gan)(gan)(gan)采取不(bu)得已(yi)的辦(ban)法(fa)——剝皮(pi),甚(shen)至二次(ci)剝皮(pi)的原因所在(zai)(zai),目(mu)的要除(chu)去(qu)皮(pi)下氧化物(wu)。
四、低氧銅桿和無(wu)氧銅桿的韌(ren)性有差別
兩者(zhe)都可以拉到0.015mm,但在(zai)低(di)溫超(chao)導線(xian)中的低(di)溫級無氧(yang)銅(tong),其(qi)細絲(si)間的間距只有0.001mm.
五、從(cong)制(zhi)(zhi)桿的原材料到制(zhi)(zhi)線(xian)的經濟性有差(cha)別(bie)。
制造(zao)無氧(yang)銅桿(gan)(gan)要求質量較高的原(yuan)材料(liao)。一般,拉制直徑>1mm的銅線時(shi),低氧(yang)銅桿(gan)(gan)的優點比較明顯,而無氧(yang)銅桿(gan)(gan)顯得更為(wei)優越的是拉制直徑<0.5mm的銅線。
六、低氧銅桿(gan)的(de)制(zhi)線工藝與無氧銅桿(gan)的(de)有所不同。
低(di)氧(yang)銅(tong)桿(gan)的(de)(de)制(zhi)線(xian)工(gong)藝(yi)不能照搬到無(wu)氧(yang)銅(tong)桿(gan)的(de)(de)制(zhi)線(xian)工(gong)藝(yi)上來(lai),至少兩(liang)者的(de)(de)退(tui)火(huo)工(gong)藝(yi)是不同的(de)(de)。因為線(xian)的(de)(de)柔軟性深受材料成份和(he)制(zhi)桿(gan),制(zhi)線(xian)和(he)退(tui)火(huo)工(gong)藝(yi)的(de)(de)影響,不能簡單地說低(di)氧(yang)銅(tong)或無(wu)氧(yang)銅(tong)誰軟誰硬(ying)。
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