熱門關鍵(jian)詞:
來(lai)源:行業動態 閱讀:109603 發布時間:2019-07-05
導讀:由于生(sheng)產(chan)銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)兩(liang)者(zhe)的(de)(de)(de)(de)(de)工藝不同,所生(sheng)產(chan)的(de)(de)(de)(de)(de)銅(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量(liang)及外觀(guan)就不同。上(shang)(shang)引生(sheng)產(chan)的(de)(de)(de)(de)(de)銅(tong)(tong)桿(gan)(gan),工藝得當氧(yang)(yang)(yang)含(han)(han)量(liang)在10ppm以下,叫無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan);連(lian)鑄連(lian)鑄生(sheng)產(chan)的(de)(de)(de)(de)(de)銅(tong)(tong)桿(gan)(gan) 是在保護條件下的(de)(de)(de)(de)(de)熱軋,氧(yang)(yang)(yang)含(han)(han)量(liang)在200-500ppm范圍內,但有時(shi)也(ye)高(gao)達700ppm以上(shang)(shang),一般情(qing)況下,此種方法生(sheng)產(chan)的(de)(de)(de)(de)(de)銅(tong)(tong)外表光亮,低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan),有時(shi)也(ye)叫光桿(gan)(gan)。
銅桿(gan)是(shi)電(dian)(dian)纜行業(ye)的(de)(de)主要原(yuan)料,生(sheng)產的(de)(de)方式主要有兩種——連(lian)(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)(lian)軋(ya)(ya)法(fa)和上(shang)引連(lian)(lian)(lian)鑄(zhu)(zhu)法(fa)。連(lian)(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)(lian)軋(ya)(ya)低(di)氧(yang)銅桿(gan)的(de)(de)生(sheng)產方法(fa)較(jiao)(jiao)多(duo),其特點是(shi)金屬(shu)在豎爐(lu)中融(rong)化后(hou)(hou),銅液(ye)通過保(bao)溫(wen)爐(lu)、溜(liu)槽、中間包(bao),從澆管進入(ru)封閉的(de)(de)模(mo)腔內,采用(yong)較(jiao)(jiao)大的(de)(de)冷(leng)卻強(qiang)度進行冷(leng)卻,形成鑄(zhu)(zhu)坯,然后(hou)(hou)進行多(duo)道次軋(ya)(ya)制,生(sheng)產的(de)(de)低(di)氧(yang)銅桿(gan)為熱(re)加工組織(zhi),原(yuan)來的(de)(de)鑄(zhu)(zhu)造(zao)(zao)組織(zhi)已經破碎,含(han)氧(yang)量(liang)一般為200~400ppm之(zhi)間。無氧(yang)銅桿(gan)國內基本全部(bu)采用(yong)上(shang)引連(lian)(lian)(lian)鑄(zhu)(zhu)法(fa)生(sheng)產,金屬(shu)在感應電(dian)(dian)爐(lu)中融(rong)化后(hou)(hou)通過石墨模(mo)進行上(shang)引連(lian)(lian)(lian)續鑄(zhu)(zhu)造(zao)(zao),之(zhi)后(hou)(hou)進行冷(leng)軋(ya)(ya)或冷(leng)加工,生(sheng)產的(de)(de)無氧(yang)銅桿(gan)為鑄(zhu)(zhu)造(zao)(zao)組織(zhi),含(han)氧(yang)量(liang)一般在20ppm以(yi)下(xia)。由(you)于制造(zao)(zao)工藝的(de)(de)不同,所以(yi)在組織(zhi)結構、氧(yang)含(han)量(liang)分布、雜(za)質的(de)(de)形式及(ji)分布等諸多(duo)方面有較(jiao)(jiao)大差別。
一、拉制性能
銅(tong)桿的拉(la)制(zhi)性能跟很多因素有(you)關,如雜質的含(han)量、氧含(han)量及分布(bu)、工藝控制(zhi)等。下面分別從以(yi)上(shang)幾個方面對銅(tong)桿的拉(la)制(zhi)性能進行分析。
1、熔化方(fang)式對S等雜質的影響(xiang)
連(lian)(lian)鑄連(lian)(lian)軋(ya)生產銅(tong)(tong)(tong)桿主要(yao)是(shi)(shi)通過氣體的(de)燃燒(shao)使銅(tong)(tong)(tong)桿熔化,在燃燒(shao)的(de)過程中,通過氧(yang)化和揮發作用(yong),可一定程度減少部分(fen)雜質進入(ru)(ru)(ru)銅(tong)(tong)(tong)液(ye),因此連(lian)(lian)鑄連(lian)(lian)軋(ya)法對原(yuan)料要(yao)求相對低一些。上引(yin)連(lian)(lian)鑄生產無(wu)氧(yang)銅(tong)(tong)(tong)桿,由于是(shi)(shi)用(yong)感應電(dian)爐熔化,電(dian)解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基(ji)本(ben)都熔入(ru)(ru)(ru)到(dao)銅(tong)(tong)(tong)液(ye)中。其中熔入(ru)(ru)(ru)的(de)S對無(wu)氧(yang)銅(tong)(tong)(tong)桿塑性影響(xiang)極大(da),會增加(jia)拉絲斷(duan)線率。
2、鑄造過程中雜質的進(jin)入
在生產(chan)過(guo)程中(zhong),連鑄(zhu)連軋(ya)工(gong)藝需(xu)通過(guo)保溫爐、溜槽、中(zhong)間(jian)包轉(zhuan)運銅(tong)液,相對(dui)容易(yi)造(zao)成耐火(huo)材(cai)料的(de)剝落,在軋(ya)制(zhi)過(guo)程中(zhong)需(xu)要通過(guo)軋(ya)輥,造(zao)成鐵(tie)質的(de)脫(tuo)落,會給銅(tong)桿造(zao)成外部夾(jia)雜。而熱軋(ya)中(zhong)皮(pi)上(shang)和(he)皮(pi)下氧化物的(de)軋(ya)入(ru),會給低氧桿的(de)拉絲(si)造(zao)成不利的(de)影響。上(shang)引連鑄(zhu)法生產(chan)工(gong)藝流程較短(duan),銅(tong)液是通過(guo)聯體爐內(nei)潛流式完成,對(dui)耐火(huo)材(cai)料的(de)沖(chong)擊(ji)不大,結晶是通過(guo)石墨模內(nei)進行,所(suo)以過(guo)程中(zhong)可能產(chan)生的(de)污(wu)染源較少(shao),雜質進入(ru)的(de)機會較少(shao)。
O、S、P是與(yu)銅(tong)會生(sheng)產化合物的(de)(de)元素。在(zai)熔態銅(tong)中(zhong),氧(yang)(yang)可以溶解(jie)(jie)一部分,但當銅(tong)冷凝時(shi)(shi),氧(yang)(yang)幾乎不溶解(jie)(jie)于(yu)銅(tong)中(zhong)。熔態時(shi)(shi)所溶解(jie)(jie)的(de)(de)氧(yang)(yang),以銅(tong)=氧(yang)(yang)化亞(ya)銅(tong)共晶(jing)體析出(chu)(chu),分布(bu)在(zai)晶(jing)粒晶(jing)界處。銅(tong)-氧(yang)(yang)化亞(ya)銅(tong)共晶(jing)體的(de)(de)出(chu)(chu)現,顯著降低了銅(tong)的(de)(de)塑性(xing)。
硫(liu)可以溶(rong)解(jie)在熔體的銅(tong)中,但在室溫下,其溶(rong)解(jie)度(du)幾乎降低到零,它以硫(liu)化亞銅(tong)的形(xing)式出現在晶(jing)粒晶(jing)界處,會(hui)顯著降低銅(tong)的塑性。
3、氧在低氧銅桿(gan)和無氧銅桿(gan)中分布形式及(ji)其影響
氧(yang)含量(liang)對低氧(yang)銅桿(gan)的(de)(de)拉(la)線性(xing)能有著明顯(xian)的(de)(de)影響。當氧(yang)含量(liang)增加到(dao)最佳(jia)值時,銅桿(gan)的(de)(de)斷線率最低。這是因為氧(yang)在與(yu)大部分雜質反(fan)應的(de)(de)過程中(zhong)都起到(dao)了(le)清除器的(de)(de)作用。適(shi)度(du)的(de)(de)氧(yang)還(huan)有利于去除銅液中(zhong)的(de)(de)氫,生(sheng)成(cheng)水蒸氣溢(yi)出,減少氣孔(kong)的(de)(de)形成(cheng)。最佳(jia)的(de)(de)氧(yang)含量(liang)為拉(la)線工藝(yi)提供了(le)最好(hao)的(de)(de)條件。
低氧(yang)銅(tong)桿(gan)氧(yang)化物的(de)分(fen)(fen)(fen)布:在(zai)連續(xu)(xu)澆鑄(zhu)中凝固的(de)最初階(jie)段,散熱(re)(re)速率和均(jun)勻冷(leng)卻是決(jue)定銅(tong)桿(gan)氧(yang)化物分(fen)(fen)(fen)布的(de)主要(yao)因素。不均(jun)勻冷(leng)卻會(hui)引起銅(tong)桿(gan)內部結構(gou)本(ben)質上的(de)差(cha)異,但后(hou)續(xu)(xu)的(de)熱(re)(re)加工,柱狀晶(jing)通常會(hui)遭到破(po)壞,使氧(yang)化亞銅(tong)顆粒(li)細微化和均(jun)勻分(fen)(fen)(fen)布。氧(yang)化物顆粒(li)聚集而產生的(de)典型(xing)情(qing)況是中心(xin)爆裂(lie)。除(chu)氧(yang)化物顆粒(li)分(fen)(fen)(fen)布的(de)影響外,具有(you)較(jiao)小氧(yang)化物顆粒(li)的(de)銅(tong)桿(gan)顯示出較(jiao)好(hao)的(de)拉線特(te)性(xing),較(jiao)大的(de)Cu2O顆粒(li)容易造成應力集中點而斷(duan)裂(lie)。
無氧(yang)(yang)(yang)銅(tong)(tong)含氧(yang)(yang)(yang)量(liang)(liang)(liang)超標,銅(tong)(tong)桿(gan)(gan)變(bian)脆,延伸率下(xia)降,拉伸式(shi)樣端(duan)口顯暗紅(hong)色,結晶組織(zhi)疏松(song)。當氧(yang)(yang)(yang)含量(liang)(liang)(liang)超出(chu)8ppm時,工藝(yi)性能(neng)變(bian)差,表現為鑄造及拉伸過程中斷(duan)(duan)桿(gan)(gan)及斷(duan)(duan)線率極具增高。這是(shi)由(you)于氧(yang)(yang)(yang)能(neng)與銅(tong)(tong)生成(cheng)(cheng)氧(yang)(yang)(yang)化(hua)(hua)亞(ya)銅(tong)(tong)脆性相(xiang),形成(cheng)(cheng)銅(tong)(tong)-氧(yang)(yang)(yang)化(hua)(hua)亞(ya)銅(tong)(tong)共晶體,以網狀組織(zhi)分布在境(jing)界上。這種脆性相(xiang)硬度高,在冷變(bian)形時將會(hui)與銅(tong)(tong)機體脫離,導致銅(tong)(tong)桿(gan)(gan)的機械(xie)性能(neng)下(xia)降,在后(hou)續(xu)加工中容易造成(cheng)(cheng)斷(duan)(duan)裂(lie)現象(xiang)。氧(yang)(yang)(yang)含量(liang)(liang)(liang)高還能(neng)導致無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)導電(dian)率下(xia)降。因此(ci),必須(xu)嚴格(ge)控制上引連鑄工藝(yi)及產(chan)品質(zhi)量(liang)(liang)(liang)。
4、氫的影響
在(zai)上引連鑄中(zhong),氧含量控(kong)制較低(di),氧化(hua)物的(de)副作用唄**降低(di),但(dan)氫的(de)影(ying)響成為較顯著的(de)問題。吸氣后(hou)熔體(ti)中(zhong)存(cun)在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體及疏松是(shi)在結(jie)晶(jing)的(de)(de)過程中(zhong),氫(qing)從過飽和的(de)(de)溶液中(zhong)析(xi)(xi)出(chu)(chu)(chu)并(bing)聚集(ji)而形(xing)(xing)成的(de)(de)。在結(jie)晶(jing)前析(xi)(xi)出(chu)(chu)(chu)的(de)(de)氫(qing)又可(ke)還原氧化亞(ya)銅而生成水(shui)氣(qi)(qi)(qi)泡。由于上引鑄(zhu)造的(de)(de)特(te)點(dian)是(shi)銅液自上而下的(de)(de)結(jie)晶(jing),形(xing)(xing)成的(de)(de)液**形(xing)(xing)狀近似錐型(xing)。銅液結(jie)晶(jing)前析(xi)(xi)出(chu)(chu)(chu)的(de)(de)氣(qi)(qi)(qi)體在上浮(fu)過程中(zhong)被堵在凝固組(zu)織(zhi)內(nei),結(jie)晶(jing)時在鑄(zhu)桿內(nei)形(xing)(xing)成氣(qi)(qi)(qi)孔(kong)。上引的(de)(de)含(han)氣(qi)(qi)(qi)量少時,析(xi)(xi)出(chu)(chu)(chu)的(de)(de)氫(qing)存在于晶(jing)界(jie)處,形(xing)(xing)成疏松;含(han)氣(qi)(qi)(qi)量多時,則(ze)聚集(ji)成氣(qi)(qi)(qi)孔(kong),因(yin)此,氣(qi)(qi)(qi)孔(kong)和疏松是(shi)氫(qing)氣(qi)(qi)(qi)和水(shui)蒸氣(qi)(qi)(qi)兩者形(xing)(xing)成的(de)(de)。
氫來源(yuan)于上引生產過(guo)程中的(de)(de)各個工藝環(huan)節,如(ru)原料電解銅(tong)(tong)(tong)(tong)(tong)的(de)(de)“銅(tong)(tong)(tong)(tong)(tong)綠”、輔(fu)料木炭**、氣候環(huan)境**、石(shi)墨結晶(jing)器未干燥等。因此,熔化爐(lu)中的(de)(de)銅(tong)(tong)(tong)(tong)(tong)液表面應覆蓋(gai)經烘(hong)烤(kao)的(de)(de)木炭,電解銅(tong)(tong)(tong)(tong)(tong)應盡量去(qu)除“銅(tong)(tong)(tong)(tong)(tong)綠”、“銅(tong)(tong)(tong)(tong)(tong)豆”“耳(er)朵”,對提高無氧銅(tong)(tong)(tong)(tong)(tong)桿質量非常(chang)重要。
在連(lian)鑄連(lian)軋工藝中,往往采用適度控制(zhi)氧(yang)含量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅液在鑄造過程中是自下(xia)而(er)上結晶(jing),銅液中的氧和氫所(suo)產生的水蒸(zheng)氣很容易上浮跑出,銅液中的氫大部(bu)分能被有效去除(chu),因而(er)對(dui)銅桿的影響較小。
二、表面質量
在生產(chan)電磁線等(deng)產(chan)品的(de)(de)過程(cheng)中,對銅(tong)桿(gan)的(de)(de)表面(mian)質量也需提(ti)出(chu)要(yao)求。需要(yao)拉制后(hou)的(de)(de)銅(tong)絲表面(mian)無毛刺、銅(tong)粉少、無油(you)污。并通過扭轉試驗測(ce)量表面(mian)銅(tong)粉的(de)(de)質量和扭轉后(hou)觀察銅(tong)桿(gan)的(de)(de)復原(yuan)情況(kuang)來判(pan)定(ding)其好(hao)壞。
在連鑄連軋(ya)(ya)過程中(zhong),從(cong)鑄造到軋(ya)(ya)制前(qian),溫(wen)度(du)高(gao),完全暴露于空氣中(zhong),使(shi)鑄坯(pi)表(biao)面形成(cheng)(cheng)較厚的(de)(de)(de)氧(yang)化層,在軋(ya)(ya)制過程中(zhong),隨著軋(ya)(ya)輥(gun)的(de)(de)(de)轉動,氧(yang)化物顆粒(li)軋(ya)(ya)入銅線(xian)表(biao)面。由于氧(yang)化亞(ya)銅是(shi)高(gao)熔點脆性化合物,對(dui)于軋(ya)(ya)入較深的(de)(de)(de)氧(yang)化亞(ya)銅,當成(cheng)(cheng)條(tiao)狀的(de)(de)(de)聚(ju)集物遇模具拉伸(shen)時,就會是(shi)銅桿外表(biao)面產生毛(mao)刺,給后續的(de)(de)(de)涂漆造成(cheng)(cheng)麻煩。
而(er)上引連(lian)鑄工藝(yi)制造(zao)的無氧(yang)銅(tong)桿(gan),由(you)于鑄造(zao)和冷卻完全與(yu)氧(yang)隔絕,后續亦無熱軋過程(cheng),銅(tong)桿(gan)表(biao)面無軋入表(biao)面的氧(yang)化物,質量(liang)較好,拉制后銅(tong)粉少,上述(shu)問(wen)題較少存在。
無(wu)氧銅桿也分(fen)進(jin)口(kou)設(she)(she)備(bei)做的和國產(chan)(chan)設(she)(she)備(bei)做的,但目(mu)前進(jin)口(kou)產(chan)(chan)品(pin)已(yi)無(wu)明顯優勢(shi),銅桿產(chan)(chan)品(pin)出(chu)來(lai)后區(qu)別不是(shi)(shi)很大,只要(yao)銅板選的好,生產(chan)(chan)控制比較(jiao)穩定,國產(chan)(chan)設(she)(she)備(bei)也能產(chan)(chan)出(chu)可拉伸0.05的銅桿.進(jin)口(kou)設(she)(she)備(bei)一般是(shi)(shi)芬(fen)蘭奧托昆普(pu)的設(she)(she)備(bei),國產(chan)(chan)設(she)(she)備(bei)最好的應該(gai)是(shi)(shi)上海的海軍廠的了,生產(chan)(chan)時間最長,軍工(gong)企(qi)業,質量可靠(kao)。
低氧銅(tong)(tong)桿進口(kou)設備(bei)國(guo)(guo)際主要有兩種(zhong),一(yi)種(zhong)是(shi)(shi)美國(guo)(guo)南線設備(bei),英(ying)文是(shi)(shi)SOUTHWIRE,國(guo)(guo)內廠(chang)家是(shi)(shi)南京華新,江(jiang)西銅(tong)(tong)業,另一(yi)種(zhong)是(shi)(shi)德國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內廠(chang)家是(shi)(shi)常州金源,天津大(da)無縫(feng)。
無(wu)氧(yang)(yang)(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)從(cong)含氧(yang)(yang)(yang)(yang)(yang)量(liang)(liang)上容易(yi)區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)是(shi)(shi)含氧(yang)(yang)(yang)(yang)(yang)量(liang)(liang)在(zai)10-20個(ge)PPM以下(xia),但目(mu)前有的(de)(de)(de)(de)廠家只能做到(dao)50個(ge)PPM以下(xia).低(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)在(zai) 200-400個(ge)PPM,好(hao)的(de)(de)(de)(de)桿(gan)(gan)子一般(ban)(ban)含氧(yang)(yang)(yang)(yang)(yang)量(liang)(liang)控(kong)制在(zai)250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)一般(ban)(ban)采取的(de)(de)(de)(de)是(shi)(shi)上引法,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)是(shi)(shi)連(lian)鑄(zhu)連(lian)軋,兩種產品相對而言低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對漆包線(xian)性(xing) 能更(geng)適應(ying)些,如(ru)(ru)柔軟性(xing),回彈角,繞線(xian)性(xing)能.但低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對拉絲(si)條(tiao)件(jian)(jian)相對要(yao)苛刻(ke)些,同樣拉伸0.2的(de)(de)(de)(de)細(xi)絲(si),如(ru)(ru)果伸線(xian)條(tiao)件(jian)(jian)不(bu)好(hao),普通的(de)(de)(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)可(ke)拉而好(hao)的(de)(de)(de)(de)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)就斷 線(xian),但如(ru)(ru)果放在(zai)好(hao)的(de)(de)(de)(de)伸線(xian)條(tiao)件(jian)(jian),同樣的(de)(de)(de)(de)桿(gan)(gan)子,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)說(shuo)不(bu)定就能拉到(dao)雙零(ling)五,而普通無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)最多只能拉伸到(dao)0.1而已,當然做的(de)(de)(de)(de)最細(xi)的(de)(de)(de)(de)如(ru)(ru)雙零(ling)二卻非(fei)得(de)依靠進口的(de)(de)(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)了.目(mu)前有企業嘗(chang)試(shi)用剝皮(pi)的(de)(de)(de)(de)方(fang)式來(lai)處理(li)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)來(lai)伸0.03線(xian).但有關這方(fang)面的(de)(de)(de)(de)內容我還不(bu)是(shi)(shi)很清楚。
音(yin)響線一般反而喜歡用無氧(yang)桿(gan),這和(he)無氧(yang)桿(gan)是(shi)單晶銅,低氧(yang)桿(gan)是(shi)多晶銅有關。
氧(yang)(yang)銅桿和無氧(yang)(yang)銅桿由(you)于(yu)制造方法的不同,致(zhi)使(shi)存(cun)在差(cha)別,具有各自的特(te)點。
一、關于氧的吸入和脫去以(yi)及它的存在狀態
生產銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)陰(yin)極銅(tong)(tong)(tong)的(de)(de)(de)含(han)(han)氧(yang)量一般在(zai)(zai)10—50ppm,在(zai)(zai)常溫下(xia)氧(yang)在(zai)(zai)銅(tong)(tong)(tong)中的(de)(de)(de)固溶度約2ppm。低氧(yang)銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)含(han)(han)氧(yang)量一般在(zai)(zai)200(175)—400(450)ppm,因此(ci)氧(yang)的(de)(de)(de)進入是在(zai)(zai)銅(tong)(tong)(tong)的(de)(de)(de)液態(tai)下(xia)吸入的(de)(de)(de),而(er)上引法無氧(yang)銅(tong)(tong)(tong)桿(gan)則相(xiang)反,氧(yang)在(zai)(zai)液態(tai)銅(tong)(tong)(tong)下(xia)保持(chi)相(xiang)當時(shi)間后,被還原而(er)脫去,通常這(zhe)種桿(gan)的(de)(de)(de)含(han)(han)氧(yang)量都在(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低可達1-2ppm,從組織上看,低氧(yang)銅(tong)(tong)(tong)中的(de)(de)(de)氧(yang),以(yi)(yi)氧(yang)化銅(tong)(tong)(tong)狀態(tai),存在(zai)(zai)于晶粒(li)邊界附近,這(zhe)對(dui)低氧(yang)銅(tong)(tong)(tong)桿(gan)而(er)言(yan)可以(yi)(yi)說是常見(jian)(jian)的(de)(de)(de)但對(dui)無氧(yang)銅(tong)(tong)(tong)桿(gan)則很少見(jian)(jian)。氧(yang)化銅(tong)(tong)(tong)以(yi)(yi)夾雜形式(shi)在(zai)(zai)晶界出現對(dui)材料(liao)的(de)(de)(de)韌性產生負面(mian)影響(xiang)。而(er)無氧(yang)銅(tong)(tong)(tong)中的(de)(de)(de)氧(yang)很低,所以(yi)(yi)這(zhe)種銅(tong)(tong)(tong)的(de)(de)(de)組織是均勻的(de)(de)(de)單相(xiang)組織對(dui)韌性有利。在(zai)(zai)無氧(yang)銅(tong)(tong)(tong)桿(gan)中的(de)(de)(de)多孔性是不(bu)常見(jian)(jian)的(de)(de)(de),而(er)在(zai)(zai)低氧(yang)銅(tong)(tong)(tong)桿(gan)中則是常見(jian)(jian)的(de)(de)(de)一種缺陷。
二、熱(re)軋組織和鑄(zhu)造組織的(de)區別
低(di)氧(yang)銅(tong)(tong)桿由于經(jing)(jing)過(guo)熱(re)(re)軋,所(suo)以其組(zu)織屬(shu)熱(re)(re)加工組(zu)織,原(yuan)(yuan)來的(de)(de)(de)鑄(zhu)造組(zu)織已經(jing)(jing)破碎,在(zai)8mm的(de)(de)(de)桿時已有(you)再(zai)(zai)結晶(jing)的(de)(de)(de)形(xing)式出現,而無(wu)(wu)(wu)氧(yang)銅(tong)(tong)桿屬(shu)鑄(zhu)造組(zu)織,晶(jing)粒(li)(li)粗(cu)大(da),這是為什么,無(wu)(wu)(wu)氧(yang)銅(tong)(tong)的(de)(de)(de)再(zai)(zai)結晶(jing)溫度較高(gao),需要較高(gao)退(tui)火(huo)溫度的(de)(de)(de)固有(you)原(yuan)(yuan)因。這是因為,再(zai)(zai)結晶(jing)發生在(zai)晶(jing)粒(li)(li)邊(bian)(bian)界附(fu)近,無(wu)(wu)(wu)氧(yang)銅(tong)(tong)桿組(zu)織晶(jing)粒(li)(li)粗(cu)大(da),晶(jing)粒(li)(li)尺寸甚至能(neng)達(da)幾個毫米,因而晶(jing)粒(li)(li)邊(bian)(bian)界少,即使通過(guo)拉(la)制(zhi)變形(xing),但(dan)晶(jing)粒(li)(li)邊(bian)(bian)界相對(dui)(dui)低(di)氧(yang)銅(tong)(tong)桿還是較少,所(suo)以需要較高(gao)的(de)(de)(de)退(tui)火(huo)功(gong)率(lv)(lv)。對(dui)(dui)無(wu)(wu)(wu)氧(yang)銅(tong)(tong)成功(gong)的(de)(de)(de)退(tui)火(huo)要求(qiu)是:由桿經(jing)(jing)拉(la)制(zhi),但(dan)尚未鑄(zhu)造組(zu)織的(de)(de)(de)線時的(de)(de)(de)第(di)一次(ci)退(tui)火(huo),其退(tui)火(huo)功(gong)率(lv)(lv)應比(bi)同樣情況的(de)(de)(de)低(di)氧(yang)銅(tong)(tong)高(gao)10——15%。經(jing)(jing)繼續(xu)拉(la)制(zhi),在(zai)以后階段的(de)(de)(de)退(tui)火(huo)功(gong)率(lv)(lv)應留(liu)有(you)足夠的(de)(de)(de)余量和(he)對(dui)(dui)低(di)氧(yang)銅(tong)(tong)和(he)無(wu)(wu)(wu)氧(yang)銅(tong)(tong)切實區(qu)別執行(xing)不同的(de)(de)(de)退(tui)火(huo)工藝,以保證在(zai)制(zhi)品(pin)和(he)成品(pin)導線的(de)(de)(de)柔軟(ruan)性。
三、夾雜,氧含量波動,表面氧化物和可能(neng)存在的(de)熱軋缺陷的(de)差(cha)別
無(wu)氧(yang)(yang)銅桿(gan)(gan)的(de)(de)可(ke)拉性(xing)在(zai)所有(you)線徑里(li)與(yu)低(di)氧(yang)(yang)銅桿(gan)(gan)相比都是(shi)(shi)優越的(de)(de),除上(shang)述組織原因外(wai),無(wu)氧(yang)(yang)銅桿(gan)(gan)夾(jia)雜(za)少,含(han)氧(yang)(yang)量穩定,無(wu)熱軋可(ke)能(neng)產生的(de)(de)缺陷,桿(gan)(gan)表氧(yang)(yang)化(hua)物(wu)厚度(du)可(ke)達≤15A。在(zai)連(lian)(lian)鑄連(lian)(lian)軋生產過程中(zhong)如(ru)(ru)果(guo)(guo)工藝不穩定,對(dui)氧(yang)(yang)監控(kong)不嚴,含(han)氧(yang)(yang)量不穩定將直接影響桿(gan)(gan)的(de)(de)性(xing)能(neng)。如(ru)(ru)果(guo)(guo)桿(gan)(gan)的(de)(de)表面氧(yang)(yang)化(hua)物(wu)能(neng)在(zai)后工序的(de)(de)連(lian)(lian)續清洗(xi)中(zhong)得以彌補外(wai),但比較麻煩的(de)(de)是(shi)(shi)有(you)相當(dang)多的(de)(de)氧(yang)(yang)化(hua)物(wu)存(cun)在(zai)于“皮(pi)下(xia)”,對(dui)拉線斷線影響更直接,故而在(zai)拉制(zhi)微細(xi)線,超微細(xi)線時(shi),為(wei)了(le)減少斷線,有(you)時(shi)要(yao)對(dui)銅桿(gan)(gan)采取不得已的(de)(de)辦法——剝皮(pi),甚(shen)至二次(ci)剝皮(pi)的(de)(de)原因所在(zai),目的(de)(de)要(yao)除去皮(pi)下(xia)氧(yang)(yang)化(hua)物(wu)。
四、低氧銅(tong)桿(gan)(gan)和無氧銅(tong)桿(gan)(gan)的韌性(xing)有差別(bie)
兩者都可以拉(la)到0.015mm,但在(zai)低溫超導線中的低溫級無(wu)氧銅,其細絲間(jian)的間(jian)距(ju)只(zhi)有0.001mm.
五(wu)、從制(zhi)桿的原材料到制(zhi)線的經濟性有差別。
制造無氧銅(tong)(tong)桿(gan)要求質量(liang)較高的原材料。一般,拉制直徑>1mm的銅(tong)(tong)線(xian)時,低氧銅(tong)(tong)桿(gan)的優點(dian)比(bi)較明顯,而(er)無氧銅(tong)(tong)桿(gan)顯得(de)更為優越(yue)的是拉制直徑<0.5mm的銅(tong)(tong)線(xian)。
六、低(di)氧(yang)銅桿的(de)(de)制線工藝與無氧(yang)銅桿的(de)(de)有(you)所不同(tong)。
低(di)氧銅(tong)桿的(de)制(zhi)線(xian)工(gong)藝不(bu)能(neng)照搬(ban)到無(wu)氧銅(tong)桿的(de)制(zhi)線(xian)工(gong)藝上(shang)來,至(zhi)少兩者的(de)退火工(gong)藝是(shi)不(bu)同的(de)。因為線(xian)的(de)柔軟(ruan)性深(shen)受材料成份(fen)和制(zhi)桿,制(zhi)線(xian)和退火工(gong)藝的(de)影(ying)響,不(bu)能(neng)簡單地說低(di)氧銅(tong)或無(wu)氧銅(tong)誰(shui)軟(ruan)誰(shui)硬(ying)。
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