熱門關鍵詞(ci):
來源:行業動態(tai) 閱(yue)讀:109417 發(fa)布時間(jian):2019-07-05
導讀:由于生(sheng)產(chan)銅(tong)桿的(de)(de)兩者的(de)(de)工藝不(bu)(bu)同(tong),所(suo)生(sheng)產(chan)的(de)(de)銅(tong)桿中(zhong)的(de)(de)含(han)氧(yang)量及外(wai)觀就不(bu)(bu)同(tong)。上引生(sheng)產(chan)的(de)(de)銅(tong)桿,工藝得當氧(yang)含(han)量在(zai)10ppm以下(xia),叫(jiao)無氧(yang)銅(tong)桿;連鑄連鑄生(sheng)產(chan)的(de)(de)銅(tong)桿 是在(zai)保護條件下(xia)的(de)(de)熱軋,氧(yang)含(han)量在(zai)200-500ppm范(fan)圍內,但(dan)有(you)時(shi)(shi)也高達(da)700ppm以上,一般情況下(xia),此種(zhong)方法生(sheng)產(chan)的(de)(de)銅(tong)外(wai)表(biao)光亮,低氧(yang)銅(tong)桿,有(you)時(shi)(shi)也叫(jiao)光桿。
銅(tong)(tong)桿是電纜行(xing)業的(de)主(zhu)要原(yuan)料(liao),生(sheng)產的(de)方式主(zhu)要有(you)兩種——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)法和上引(yin)連(lian)鑄(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)低(di)氧(yang)(yang)銅(tong)(tong)桿的(de)生(sheng)產方法較多(duo),其特點是金(jin)屬在(zai)(zai)豎爐中融化(hua)后(hou),銅(tong)(tong)液通過(guo)保溫爐、溜槽、中間包,從澆(jiao)管進入(ru)封閉的(de)模腔(qiang)內(nei),采用(yong)較大的(de)冷(leng)卻(que)強度(du)進行(xing)冷(leng)卻(que),形(xing)成鑄(zhu)(zhu)坯,然后(hou)進行(xing)多(duo)道次(ci)軋(ya)制,生(sheng)產的(de)低(di)氧(yang)(yang)銅(tong)(tong)桿為熱加工(gong)組織,原(yuan)來(lai)的(de)鑄(zhu)(zhu)造組織已經(jing)破碎,含(han)氧(yang)(yang)量一(yi)般(ban)(ban)為200~400ppm之(zhi)(zhi)間。無氧(yang)(yang)銅(tong)(tong)桿國內(nei)基本全(quan)部采用(yong)上引(yin)連(lian)鑄(zhu)(zhu)法生(sheng)產,金(jin)屬在(zai)(zai)感應電爐中融化(hua)后(hou)通過(guo)石(shi)墨模進行(xing)上引(yin)連(lian)續鑄(zhu)(zhu)造,之(zhi)(zhi)后(hou)進行(xing)冷(leng)軋(ya)或冷(leng)加工(gong),生(sheng)產的(de)無氧(yang)(yang)銅(tong)(tong)桿為鑄(zhu)(zhu)造組織,含(han)氧(yang)(yang)量一(yi)般(ban)(ban)在(zai)(zai)20ppm以下。由于(yu)制造工(gong)藝的(de)不同,所以在(zai)(zai)組織結構、氧(yang)(yang)含(han)量分(fen)布、雜質(zhi)的(de)形(xing)式及分(fen)布等諸多(duo)方面有(you)較大差(cha)別(bie)。
一、拉制性能
銅(tong)(tong)桿的拉制性能跟(gen)很(hen)多因素有(you)關,如(ru)雜質(zhi)的含量(liang)、氧含量(liang)及分布、工藝(yi)控制等。下面分別從以上幾個方(fang)面對銅(tong)(tong)桿的拉制性能進行分析。
1、熔化方式(shi)對S等雜質的影響
連(lian)鑄連(lian)軋生(sheng)產銅(tong)(tong)桿主要是(shi)通過氣體的(de)燃燒使(shi)銅(tong)(tong)桿熔(rong)(rong)化(hua)(hua),在燃燒的(de)過程中(zhong)(zhong),通過氧(yang)(yang)化(hua)(hua)和揮發作用,可一定(ding)程度減少部分雜質(zhi)進入銅(tong)(tong)液,因(yin)此連(lian)鑄連(lian)軋法對(dui)原料要求相對(dui)低(di)一些。上(shang)引連(lian)鑄生(sheng)產無(wu)氧(yang)(yang)銅(tong)(tong)桿,由于是(shi)用感應電(dian)爐(lu)熔(rong)(rong)化(hua)(hua),電(dian)解銅(tong)(tong)表面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆(dou)”基本都(dou)熔(rong)(rong)入到銅(tong)(tong)液中(zhong)(zhong)。其中(zhong)(zhong)熔(rong)(rong)入的(de)S對(dui)無(wu)氧(yang)(yang)銅(tong)(tong)桿塑(su)性影響極大,會增加(jia)拉絲斷線率。
2、鑄造過(guo)程中雜質的進入(ru)
在(zai)生產(chan)(chan)過(guo)程中(zhong)(zhong),連(lian)鑄(zhu)連(lian)軋(ya)工藝需通(tong)(tong)(tong)過(guo)保溫爐、溜(liu)槽、中(zhong)(zhong)間包(bao)轉(zhuan)運(yun)銅液,相對容易造(zao)(zao)成耐火(huo)材料的(de)剝落(luo),在(zai)軋(ya)制過(guo)程中(zhong)(zhong)需要通(tong)(tong)(tong)過(guo)軋(ya)輥,造(zao)(zao)成鐵(tie)質(zhi)(zhi)的(de)脫落(luo),會給銅桿造(zao)(zao)成外部夾雜。而熱軋(ya)中(zhong)(zhong)皮(pi)上(shang)和皮(pi)下氧(yang)化物的(de)軋(ya)入(ru),會給低氧(yang)桿的(de)拉絲(si)造(zao)(zao)成不利的(de)影響。上(shang)引連(lian)鑄(zhu)法生產(chan)(chan)工藝流(liu)程較(jiao)短,銅液是通(tong)(tong)(tong)過(guo)聯體爐內潛流(liu)式完成,對耐火(huo)材料的(de)沖擊不大,結晶是通(tong)(tong)(tong)過(guo)石(shi)墨模內進(jin)行,所以過(guo)程中(zhong)(zhong)可能產(chan)(chan)生的(de)污染源較(jiao)少,雜質(zhi)(zhi)進(jin)入(ru)的(de)機會較(jiao)少。
O、S、P是與銅(tong)(tong)(tong)會(hui)生產化(hua)合物的(de)元素(su)。在熔態銅(tong)(tong)(tong)中,氧(yang)可(ke)以(yi)溶(rong)解(jie)一(yi)部分,但當銅(tong)(tong)(tong)冷(leng)凝時(shi),氧(yang)幾乎不溶(rong)解(jie)于銅(tong)(tong)(tong)中。熔態時(shi)所(suo)溶(rong)解(jie)的(de)氧(yang),以(yi)銅(tong)(tong)(tong)=氧(yang)化(hua)亞銅(tong)(tong)(tong)共晶(jing)體析(xi)出(chu),分布在晶(jing)粒晶(jing)界處。銅(tong)(tong)(tong)-氧(yang)化(hua)亞銅(tong)(tong)(tong)共晶(jing)體的(de)出(chu)現,顯(xian)著降低了銅(tong)(tong)(tong)的(de)塑性。
硫(liu)可以溶解在熔體的銅中,但在室溫下(xia),其溶解度幾乎(hu)降(jiang)低到(dao)零,它(ta)以硫(liu)化(hua)亞(ya)銅的形(xing)式出現在晶(jing)粒晶(jing)界處(chu),會顯著降(jiang)低銅的塑性。
3、氧(yang)在低氧(yang)銅桿(gan)和無(wu)氧(yang)銅桿(gan)中分布形式及其影響
氧(yang)(yang)含量對低(di)氧(yang)(yang)銅(tong)桿的(de)(de)(de)拉線(xian)性能有著明顯(xian)的(de)(de)(de)影響(xiang)。當氧(yang)(yang)含量增(zeng)加(jia)到最(zui)(zui)佳值(zhi)時,銅(tong)桿的(de)(de)(de)斷線(xian)率最(zui)(zui)低(di)。這是因(yin)為(wei)氧(yang)(yang)在與大(da)部分雜質(zhi)反應的(de)(de)(de)過程(cheng)中都起到了清除(chu)器(qi)的(de)(de)(de)作(zuo)用。適(shi)度的(de)(de)(de)氧(yang)(yang)還有利(li)于去(qu)除(chu)銅(tong)液中的(de)(de)(de)氫,生(sheng)成水(shui)蒸(zheng)氣溢出(chu),減少氣孔的(de)(de)(de)形(xing)成。最(zui)(zui)佳的(de)(de)(de)氧(yang)(yang)含量為(wei)拉線(xian)工藝提供了最(zui)(zui)好的(de)(de)(de)條件。
低(di)氧(yang)(yang)銅桿氧(yang)(yang)化(hua)(hua)物(wu)(wu)的(de)(de)(de)分(fen)布:在連續澆鑄中(zhong)凝固的(de)(de)(de)最初階段,散熱速率和均勻(yun)(yun)冷卻是(shi)決定銅桿氧(yang)(yang)化(hua)(hua)物(wu)(wu)分(fen)布的(de)(de)(de)主(zhu)要因素。不均勻(yun)(yun)冷卻會(hui)引起銅桿內(nei)部結構本質上的(de)(de)(de)差異,但后續的(de)(de)(de)熱加工,柱狀晶通常會(hui)遭(zao)到破壞,使氧(yang)(yang)化(hua)(hua)亞銅顆(ke)(ke)粒(li)細微化(hua)(hua)和均勻(yun)(yun)分(fen)布。氧(yang)(yang)化(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)聚集而產生的(de)(de)(de)典型情況(kuang)是(shi)中(zhong)心爆裂。除氧(yang)(yang)化(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)分(fen)布的(de)(de)(de)影響外,具有(you)較小氧(yang)(yang)化(hua)(hua)物(wu)(wu)顆(ke)(ke)粒(li)的(de)(de)(de)銅桿顯示(shi)出較好的(de)(de)(de)拉線特性(xing),較大的(de)(de)(de)Cu2O顆(ke)(ke)粒(li)容易造成應力集中(zhong)點(dian)而斷裂。
無氧(yang)(yang)銅(tong)(tong)含氧(yang)(yang)量(liang)超(chao)標,銅(tong)(tong)桿變脆,延伸率(lv)下降,拉伸式樣(yang)端口顯暗紅色,結晶組(zu)織疏松。當氧(yang)(yang)含量(liang)超(chao)出8ppm時,工藝性能(neng)(neng)(neng)變差,表現為(wei)鑄造及拉伸過程中斷(duan)桿及斷(duan)線率(lv)極具(ju)增高。這(zhe)是由于氧(yang)(yang)能(neng)(neng)(neng)與銅(tong)(tong)生成氧(yang)(yang)化(hua)亞銅(tong)(tong)脆性相(xiang),形(xing)成銅(tong)(tong)-氧(yang)(yang)化(hua)亞銅(tong)(tong)共(gong)晶體(ti),以網狀組(zu)織分(fen)布在(zai)境界(jie)上(shang)。這(zhe)種脆性相(xiang)硬(ying)度高,在(zai)冷變形(xing)時將(jiang)會與銅(tong)(tong)機體(ti)脫離,導致銅(tong)(tong)桿的(de)機械性能(neng)(neng)(neng)下降,在(zai)后續加(jia)工中容易(yi)造成斷(duan)裂(lie)現象。氧(yang)(yang)含量(liang)高還能(neng)(neng)(neng)導致無氧(yang)(yang)銅(tong)(tong)桿導電率(lv)下降。因此(ci),必須嚴格控(kong)制上(shang)引連鑄工藝及產品質量(liang)。
4、氫的影響
在上引(yin)連(lian)鑄中(zhong),氧含量控制較低,氧化物的(de)副作用唄**降低,但氫(qing)的(de)影響(xiang)成為較顯(xian)著的(de)問題(ti)。吸(xi)氣后(hou)熔體中(zhong)存在平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體(ti)及疏松(song)是在結(jie)晶(jing)的(de)(de)過程中,氫(qing)從過飽和(he)(he)的(de)(de)溶(rong)液(ye)中析(xi)出(chu)并(bing)聚(ju)集而(er)形(xing)成(cheng)(cheng)的(de)(de)。在結(jie)晶(jing)前(qian)析(xi)出(chu)的(de)(de)氫(qing)又(you)可還原氧化亞銅(tong)而(er)生成(cheng)(cheng)水氣(qi)(qi)(qi)泡。由于上引(yin)鑄造的(de)(de)特點是銅(tong)液(ye)自上而(er)下的(de)(de)結(jie)晶(jing),形(xing)成(cheng)(cheng)的(de)(de)液(ye)**形(xing)狀近似錐型(xing)。銅(tong)液(ye)結(jie)晶(jing)前(qian)析(xi)出(chu)的(de)(de)氣(qi)(qi)(qi)體(ti)在上浮過程中被(bei)堵在凝固組(zu)織內(nei),結(jie)晶(jing)時在鑄桿內(nei)形(xing)成(cheng)(cheng)氣(qi)(qi)(qi)孔(kong)(kong)。上引(yin)的(de)(de)含氣(qi)(qi)(qi)量少時,析(xi)出(chu)的(de)(de)氫(qing)存在于晶(jing)界處,形(xing)成(cheng)(cheng)疏松(song);含氣(qi)(qi)(qi)量多(duo)時,則聚(ju)集成(cheng)(cheng)氣(qi)(qi)(qi)孔(kong)(kong),因此,氣(qi)(qi)(qi)孔(kong)(kong)和(he)(he)疏松(song)是氫(qing)氣(qi)(qi)(qi)和(he)(he)水蒸氣(qi)(qi)(qi)兩者形(xing)成(cheng)(cheng)的(de)(de)。
氫來源于(yu)上(shang)引生產過程(cheng)中的(de)各個工藝環(huan)(huan)節(jie),如原料電解銅(tong)(tong)的(de)“銅(tong)(tong)綠(lv)”、輔(fu)料木炭(tan)**、氣(qi)候環(huan)(huan)境**、石墨(mo)結晶器未干燥等。因此,熔化爐中的(de)銅(tong)(tong)液表面應覆蓋(gai)經(jing)烘烤的(de)木炭(tan),電解銅(tong)(tong)應盡(jin)量去除“銅(tong)(tong)綠(lv)”、“銅(tong)(tong)豆(dou)”“耳朵”,對提高無氧銅(tong)(tong)桿質量非常重要。
在連(lian)鑄連(lian)軋工藝中,往往采用適(shi)度(du)控(kong)制氧含量(liang)來(lai)控(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由于銅液在鑄造過程中是自下而上結晶,銅液中的氧(yang)和氫(qing)所(suo)產(chan)生的水蒸氣很容易上浮跑出,銅液中的氫(qing)大部分能被有(you)效去(qu)除,因而對銅桿(gan)的影響(xiang)較小。
二、表面質量
在生產電磁(ci)線等產品的(de)過程中,對銅(tong)(tong)桿的(de)表(biao)面(mian)質量(liang)也需提(ti)出(chu)要求。需要拉制后(hou)的(de)銅(tong)(tong)絲(si)表(biao)面(mian)無毛刺、銅(tong)(tong)粉(fen)少(shao)、無油污。并通過扭(niu)轉(zhuan)(zhuan)試驗測量(liang)表(biao)面(mian)銅(tong)(tong)粉(fen)的(de)質量(liang)和扭(niu)轉(zhuan)(zhuan)后(hou)觀察銅(tong)(tong)桿的(de)復原情況來判(pan)定其(qi)好壞(huai)。
在(zai)(zai)連鑄(zhu)連軋(ya)(ya)過(guo)程(cheng)中,從(cong)鑄(zhu)造到軋(ya)(ya)制前(qian),溫度高,完全(quan)暴露于(yu)空氣中,使鑄(zhu)坯表面形(xing)成(cheng)(cheng)較厚(hou)的(de)氧化(hua)層,在(zai)(zai)軋(ya)(ya)制過(guo)程(cheng)中,隨著軋(ya)(ya)輥的(de)轉動,氧化(hua)物(wu)(wu)顆粒軋(ya)(ya)入(ru)銅(tong)線表面。由于(yu)氧化(hua)亞銅(tong)是(shi)高熔點脆(cui)性化(hua)合物(wu)(wu),對(dui)于(yu)軋(ya)(ya)入(ru)較深的(de)氧化(hua)亞銅(tong),當成(cheng)(cheng)條狀的(de)聚(ju)集物(wu)(wu)遇(yu)模具拉伸(shen)時,就會是(shi)銅(tong)桿外表面產生(sheng)毛(mao)刺,給后續的(de)涂漆(qi)造成(cheng)(cheng)麻煩(fan)。
而上(shang)引連(lian)鑄(zhu)工藝制造的無(wu)氧銅桿(gan),由于鑄(zhu)造和冷卻完全與氧隔絕,后續亦(yi)無(wu)熱軋過程(cheng),銅桿(gan)表面無(wu)軋入(ru)表面的氧化物(wu),質量較好(hao),拉制后銅粉(fen)少(shao),上(shang)述(shu)問題(ti)較少(shao)存在。
無氧銅桿也分(fen)進口(kou)設(she)備(bei)做(zuo)的(de)(de)和(he)國(guo)(guo)(guo)產(chan)設(she)備(bei)做(zuo)的(de)(de),但目前進口(kou)產(chan)品已無明(ming)顯優(you)勢,銅桿產(chan)品出(chu)來后區別(bie)不是(shi)很大,只要銅板選(xuan)的(de)(de)好,生產(chan)控(kong)制比較穩(wen)定(ding),國(guo)(guo)(guo)產(chan)設(she)備(bei)也能(neng)產(chan)出(chu)可拉伸0.05的(de)(de)銅桿.進口(kou)設(she)備(bei)一般是(shi)芬蘭奧托昆普的(de)(de)設(she)備(bei),國(guo)(guo)(guo)產(chan)設(she)備(bei)最好的(de)(de)應(ying)該(gai)是(shi)上海的(de)(de)海軍(jun)(jun)廠的(de)(de)了,生產(chan)時間(jian)最長(chang),軍(jun)(jun)工企業,質量可靠。
低氧銅桿(gan)進口設(she)備(bei)(bei)國(guo)際主要有(you)兩(liang)種(zhong),一(yi)種(zhong)是(shi)(shi)美國(guo)南線(xian)設(she)備(bei)(bei),英文是(shi)(shi)SOUTHWIRE,國(guo)內(nei)廠家是(shi)(shi)南京華新,江(jiang)西銅業,另(ling)一(yi)種(zhong)是(shi)(shi)德(de)國(guo)CONTIROD設(she)備(bei)(bei),國(guo)內(nei)廠家是(shi)(shi)常州(zhou)金源,天津大無縫(feng)。
無(wu)(wu)(wu)(wu)氧(yang)(yang)及低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)量上容易區別,無(wu)(wu)(wu)(wu)氧(yang)(yang)銅(tong)是(shi)(shi)含氧(yang)(yang)量在10-20個PPM以下,但(dan)目前(qian)有(you)的(de)廠(chang)家只能(neng)做(zuo)到50個PPM以下.低(di)(di)(di)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)在 200-400個PPM,好(hao)的(de)桿(gan)(gan)(gan)子(zi)一般(ban)含氧(yang)(yang)量控制在250個PPM左右,無(wu)(wu)(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)一般(ban)采取的(de)是(shi)(shi)上引法,低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)是(shi)(shi)連鑄連軋,兩種產品相(xiang)對(dui)而言低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)對(dui)漆包線性 能(neng)更適應些,如(ru)柔軟(ruan)性,回(hui)彈角,繞線性能(neng).但(dan)低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)對(dui)拉(la)絲條件相(xiang)對(dui)要苛刻些,同(tong)(tong)樣(yang)拉(la)伸0.2的(de)細(xi)絲,如(ru)果伸線條件不(bu)好(hao),普(pu)通的(de)無(wu)(wu)(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)可(ke)拉(la)而好(hao)的(de)低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)就斷 線,但(dan)如(ru)果放(fang)在好(hao)的(de)伸線條件,同(tong)(tong)樣(yang)的(de)桿(gan)(gan)(gan)子(zi),低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)說不(bu)定(ding)就能(neng)拉(la)到雙零五,而普(pu)通無(wu)(wu)(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)最多只能(neng)拉(la)伸到0.1而已,當然做(zuo)的(de)最細(xi)的(de)如(ru)雙零二卻非得依靠(kao)進(jin)口(kou)的(de) 無(wu)(wu)(wu)(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)了.目前(qian)有(you)企業嘗試用剝(bo)皮的(de)方式來處(chu)理低(di)(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)來伸0.03線.但(dan)有(you)關這方面的(de)內容我還不(bu)是(shi)(shi)很(hen)清(qing)楚。
音響線(xian)一般反而(er)喜(xi)歡用無(wu)氧(yang)桿(gan),這和無(wu)氧(yang)桿(gan)是單晶(jing)銅,低(di)氧(yang)桿(gan)是多晶(jing)銅有關。
氧(yang)銅(tong)(tong)桿和無氧(yang)銅(tong)(tong)桿由于制造方法的不同,致使(shi)存在差別,具(ju)有(you)各(ge)自的特點。
一、關于氧的(de)吸(xi)入(ru)和脫去以及(ji)它的(de)存在(zai)狀態
生產(chan)銅(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)陰極(ji)銅(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般在(zai)10—50ppm,在(zai)常溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)中(zhong)的(de)(de)(de)(de)固溶度(du)約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入(ru)是(shi)在(zai)銅(tong)的(de)(de)(de)(de)液態(tai)(tai)下(xia)吸入(ru)的(de)(de)(de)(de),而(er)(er)上(shang)引法無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)則(ze)相反,氧(yang)(yang)(yang)(yang)(yang)在(zai)液態(tai)(tai)銅(tong)下(xia)保持(chi)相當(dang)時(shi)間后,被還(huan)原而(er)(er)脫去,通常這種(zhong)(zhong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)都(dou)在(zai)10—50ppm以(yi)下(xia),最低(di)可(ke)達1-2ppm,從組(zu)織上(shang)看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)狀(zhuang)態(tai)(tai),存在(zai)于晶粒邊界(jie)附近,這對低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)而(er)(er)言可(ke)以(yi)說是(shi)常見的(de)(de)(de)(de)但對無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)則(ze)很少見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)以(yi)夾雜形(xing)式在(zai)晶界(jie)出現對材料的(de)(de)(de)(de)韌性產(chan)生負面影響。而(er)(er)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所以(yi)這種(zhong)(zhong)銅(tong)的(de)(de)(de)(de)組(zu)織是(shi)均勻(yun)的(de)(de)(de)(de)單(dan)相組(zu)織對韌性有利。在(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)中(zhong)的(de)(de)(de)(de)多孔性是(shi)不常見的(de)(de)(de)(de),而(er)(er)在(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)中(zhong)則(ze)是(shi)常見的(de)(de)(de)(de)一(yi)(yi)種(zhong)(zhong)缺陷。
二、熱(re)軋組(zu)織(zhi)和鑄(zhu)造組(zu)織(zhi)的區別(bie)
低氧(yang)銅(tong)桿(gan)(gan)由(you)于經(jing)(jing)過(guo)熱(re)軋,所以其組織屬(shu)熱(re)加工組織,原(yuan)來的(de)(de)鑄造(zao)組織已(yi)經(jing)(jing)破(po)碎,在(zai)8mm的(de)(de)桿(gan)(gan)時已(yi)有(you)(you)再結(jie)晶(jing)(jing)的(de)(de)形式(shi)出現,而(er)(er)無(wu)氧(yang)銅(tong)桿(gan)(gan)屬(shu)鑄造(zao)組織,晶(jing)(jing)粒(li)粗大,這是(shi)為什么,無(wu)氧(yang)銅(tong)的(de)(de)再結(jie)晶(jing)(jing)溫度較高,需要較高退(tui)(tui)火(huo)(huo)(huo)溫度的(de)(de)固(gu)有(you)(you)原(yuan)因(yin)。這是(shi)因(yin)為,再結(jie)晶(jing)(jing)發生在(zai)晶(jing)(jing)粒(li)邊(bian)界附近(jin),無(wu)氧(yang)銅(tong)桿(gan)(gan)組織晶(jing)(jing)粒(li)粗大,晶(jing)(jing)粒(li)尺寸(cun)甚至(zhi)能達幾個毫米,因(yin)而(er)(er)晶(jing)(jing)粒(li)邊(bian)界少,即(ji)使通過(guo)拉(la)制(zhi)變形,但晶(jing)(jing)粒(li)邊(bian)界相(xiang)對低氧(yang)銅(tong)桿(gan)(gan)還是(shi)較少,所以需要較高的(de)(de)退(tui)(tui)火(huo)(huo)(huo)功(gong)率。對無(wu)氧(yang)銅(tong)成(cheng)功(gong)的(de)(de)退(tui)(tui)火(huo)(huo)(huo)要求是(shi):由(you)桿(gan)(gan)經(jing)(jing)拉(la)制(zhi),但尚未鑄造(zao)組織的(de)(de)線(xian)時的(de)(de)第一次(ci)退(tui)(tui)火(huo)(huo)(huo),其退(tui)(tui)火(huo)(huo)(huo)功(gong)率應比(bi)同(tong)(tong)樣情況的(de)(de)低氧(yang)銅(tong)高10——15%。經(jing)(jing)繼續拉(la)制(zhi),在(zai)以后階(jie)段的(de)(de)退(tui)(tui)火(huo)(huo)(huo)功(gong)率應留有(you)(you)足夠的(de)(de)余量和(he)對低氧(yang)銅(tong)和(he)無(wu)氧(yang)銅(tong)切實區別執行不同(tong)(tong)的(de)(de)退(tui)(tui)火(huo)(huo)(huo)工藝(yi),以保證在(zai)制(zhi)品和(he)成(cheng)品導線(xian)的(de)(de)柔軟性。
三、夾雜,氧含(han)量(liang)波動,表面氧化物和可(ke)能存在的熱軋缺(que)陷的差別
無氧銅桿(gan)(gan)(gan)的可(ke)拉(la)(la)性在所有線(xian)徑(jing)里(li)與低氧銅桿(gan)(gan)(gan)相比(bi)都(dou)是優越的,除(chu)上述組(zu)織原因外,無氧銅桿(gan)(gan)(gan)夾雜少,含(han)氧量(liang)穩(wen)定(ding),無熱軋可(ke)能(neng)產生的缺陷,桿(gan)(gan)(gan)表(biao)氧化(hua)物(wu)(wu)(wu)厚度可(ke)達≤15A。在連鑄連軋生產過程中如果工藝不(bu)(bu)穩(wen)定(ding),對氧監控不(bu)(bu)嚴,含(han)氧量(liang)不(bu)(bu)穩(wen)定(ding)將直(zhi)接(jie)影響桿(gan)(gan)(gan)的性能(neng)。如果桿(gan)(gan)(gan)的表(biao)面氧化(hua)物(wu)(wu)(wu)能(neng)在后工序的連續清洗(xi)中得(de)以彌補外,但比(bi)較(jiao)麻煩(fan)的是有相當多的氧化(hua)物(wu)(wu)(wu)存在于(yu)“皮下”,對拉(la)(la)線(xian)斷線(xian)影響更(geng)直(zhi)接(jie),故而在拉(la)(la)制微細(xi)線(xian),超(chao)微細(xi)線(xian)時(shi),為了減少斷線(xian),有時(shi)要對銅桿(gan)(gan)(gan)采取不(bu)(bu)得(de)已的辦法——剝皮,甚(shen)至二次剝皮的原因所在,目(mu)的要除(chu)去皮下氧化(hua)物(wu)(wu)(wu)。
四、低(di)氧(yang)銅桿和(he)無氧(yang)銅桿的韌性有差別(bie)
兩者(zhe)都可以(yi)拉到0.015mm,但(dan)在低溫超導線(xian)中的(de)低溫級無氧銅,其細絲(si)間的(de)間距只(zhi)有0.001mm.
五(wu)、從(cong)制桿的原材(cai)料到制線(xian)的經濟性有差別。
制(zhi)造無氧銅桿要求(qiu)質(zhi)量較(jiao)(jiao)高的(de)原材料。一般,拉制(zhi)直徑>1mm的(de)銅線(xian)時,低(di)氧銅桿的(de)優點比(bi)較(jiao)(jiao)明顯(xian)(xian),而無氧銅桿顯(xian)(xian)得更為優越的(de)是拉制(zhi)直徑<0.5mm的(de)銅線(xian)。
六、低氧(yang)銅(tong)桿的制線工藝與(yu)無(wu)氧(yang)銅(tong)桿的有(you)所不同。
低氧(yang)銅(tong)桿的(de)(de)(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)不能照(zhao)搬到無氧(yang)銅(tong)桿的(de)(de)(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)上(shang)來,至少兩者的(de)(de)(de)退火工(gong)(gong)藝(yi)是不同的(de)(de)(de)。因為線(xian)的(de)(de)(de)柔(rou)軟(ruan)性深受材(cai)料成份(fen)和制(zhi)(zhi)桿,制(zhi)(zhi)線(xian)和退火工(gong)(gong)藝(yi)的(de)(de)(de)影響,不能簡單(dan)地(di)說低氧(yang)銅(tong)或無氧(yang)銅(tong)誰軟(ruan)誰硬。
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