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九臺電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱讀:109546 發布(bu)時間:2019-07-05

導(dao)讀:由于(yu)生(sheng)(sheng)產(chan)(chan)(chan)銅桿的(de)(de)兩者的(de)(de)工藝不(bu)(bu)同(tong),所(suo)生(sheng)(sheng)產(chan)(chan)(chan)的(de)(de)銅桿中的(de)(de)含氧(yang)(yang)(yang)量(liang)及外觀就不(bu)(bu)同(tong)。上引生(sheng)(sheng)產(chan)(chan)(chan)的(de)(de)銅桿,工藝得當氧(yang)(yang)(yang)含量(liang)在(zai)10ppm以(yi)下(xia)(xia),叫無氧(yang)(yang)(yang)銅桿;連(lian)鑄(zhu)連(lian)鑄(zhu)生(sheng)(sheng)產(chan)(chan)(chan)的(de)(de)銅桿 是在(zai)保護(hu)條件下(xia)(xia)的(de)(de)熱軋(ya),氧(yang)(yang)(yang)含量(liang)在(zai)200-500ppm范圍內,但有(you)時也(ye)高達700ppm以(yi)上,一般情況下(xia)(xia),此種方法生(sheng)(sheng)產(chan)(chan)(chan)的(de)(de)銅外表光亮,低氧(yang)(yang)(yang)銅桿,有(you)時也(ye)叫光桿。

銅桿(gan)是電(dian)(dian)纜行(xing)業(ye)的(de)主(zhu)要原料,生(sheng)產的(de)方式(shi)主(zhu)要有兩種——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)法(fa)和上(shang)(shang)引(yin)連(lian)鑄(zhu)(zhu)法(fa)。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)低氧(yang)(yang)(yang)(yang)銅桿(gan)的(de)生(sheng)產方法(fa)較(jiao)多(duo),其特點是金屬在(zai)豎(shu)爐(lu)中融(rong)(rong)化后,銅液(ye)通過(guo)(guo)保溫爐(lu)、溜槽(cao)、中間包(bao),從(cong)澆(jiao)管進入封閉的(de)模(mo)腔內(nei)(nei),采用較(jiao)大的(de)冷(leng)(leng)卻(que)強度進行(xing)冷(leng)(leng)卻(que),形成鑄(zhu)(zhu)坯,然后進行(xing)多(duo)道次軋(ya)(ya)制,生(sheng)產的(de)低氧(yang)(yang)(yang)(yang)銅桿(gan)為(wei)熱加工(gong)組(zu)織(zhi)(zhi),原來(lai)的(de)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi)已經(jing)破碎,含氧(yang)(yang)(yang)(yang)量(liang)一(yi)般(ban)為(wei)200~400ppm之間。無(wu)氧(yang)(yang)(yang)(yang)銅桿(gan)國內(nei)(nei)基本全部采用上(shang)(shang)引(yin)連(lian)鑄(zhu)(zhu)法(fa)生(sheng)產,金屬在(zai)感應(ying)電(dian)(dian)爐(lu)中融(rong)(rong)化后通過(guo)(guo)石(shi)墨模(mo)進行(xing)上(shang)(shang)引(yin)連(lian)續鑄(zhu)(zhu)造(zao),之后進行(xing)冷(leng)(leng)軋(ya)(ya)或冷(leng)(leng)加工(gong),生(sheng)產的(de)無(wu)氧(yang)(yang)(yang)(yang)銅桿(gan)為(wei)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi),含氧(yang)(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)20ppm以(yi)下。由(you)于制造(zao)工(gong)藝的(de)不同,所以(yi)在(zai)組(zu)織(zhi)(zhi)結構、氧(yang)(yang)(yang)(yang)含量(liang)分(fen)布、雜(za)質的(de)形式(shi)及分(fen)布等諸多(duo)方面(mian)有較(jiao)大差別。

一、拉制性能

銅桿的拉制性能(neng)跟很多因素有(you)關,如雜質的含(han)量、氧含(han)量及分布、工藝控制等。下面分別從以上幾(ji)個方面對(dui)銅桿的拉制性能(neng)進行分析。

1、熔化方式對S等(deng)雜(za)質的影響

連(lian)(lian)鑄連(lian)(lian)軋生(sheng)產銅(tong)桿主要是通(tong)過(guo)氣(qi)體的燃燒(shao)使銅(tong)桿熔(rong)化(hua),在燃燒(shao)的過(guo)程中(zhong),通(tong)過(guo)氧(yang)化(hua)和(he)揮發作(zuo)用,可一定程度減少部分雜(za)質進入銅(tong)液,因此連(lian)(lian)鑄連(lian)(lian)軋法對原料要求相對低(di)一些。上引連(lian)(lian)鑄生(sheng)產無氧(yang)銅(tong)桿,由于是用感應電(dian)(dian)爐(lu)熔(rong)化(hua),電(dian)(dian)解銅(tong)表面(mian)的“銅(tong)綠”“銅(tong)豆”基本都(dou)熔(rong)入到銅(tong)液中(zhong)。其中(zhong)熔(rong)入的S對無氧(yang)銅(tong)桿塑性(xing)影(ying)響極大,會增加拉(la)絲斷線率。

2、鑄造過程(cheng)中雜質的進入

在生(sheng)產過程(cheng)中(zhong),連(lian)鑄連(lian)軋(ya)工藝(yi)需通過保(bao)溫爐、溜槽(cao)、中(zhong)間包(bao)轉(zhuan)運銅(tong)液(ye),相(xiang)對容易造(zao)成(cheng)(cheng)耐火材(cai)料的(de)剝落,在軋(ya)制過程(cheng)中(zhong)需要通過軋(ya)輥,造(zao)成(cheng)(cheng)鐵質(zhi)的(de)脫(tuo)落,會(hui)給銅(tong)桿(gan)造(zao)成(cheng)(cheng)外(wai)部夾(jia)雜(za)。而熱軋(ya)中(zhong)皮上和皮下氧化物的(de)軋(ya)入,會(hui)給低(di)氧桿(gan)的(de)拉絲造(zao)成(cheng)(cheng)不利(li)的(de)影響。上引連(lian)鑄法生(sheng)產工藝(yi)流(liu)程(cheng)較短,銅(tong)液(ye)是通過聯體爐內潛流(liu)式完成(cheng)(cheng),對耐火材(cai)料的(de)沖擊不大(da),結晶是通過石墨模內進行,所以過程(cheng)中(zhong)可能(neng)產生(sheng)的(de)污染(ran)源較少,雜(za)質(zhi)進入的(de)機會(hui)較少。

O、S、P是與銅(tong)(tong)(tong)會(hui)生產化(hua)(hua)合物的(de)元素。在熔(rong)態銅(tong)(tong)(tong)中(zhong)(zhong),氧(yang)(yang)(yang)可以溶(rong)解(jie)一部分,但當銅(tong)(tong)(tong)冷凝時(shi),氧(yang)(yang)(yang)幾(ji)乎(hu)不(bu)溶(rong)解(jie)于銅(tong)(tong)(tong)中(zhong)(zhong)。熔(rong)態時(shi)所溶(rong)解(jie)的(de)氧(yang)(yang)(yang),以銅(tong)(tong)(tong)=氧(yang)(yang)(yang)化(hua)(hua)亞(ya)(ya)銅(tong)(tong)(tong)共晶體(ti)析出,分布在晶粒(li)晶界(jie)處。銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化(hua)(hua)亞(ya)(ya)銅(tong)(tong)(tong)共晶體(ti)的(de)出現,顯著降(jiang)低了銅(tong)(tong)(tong)的(de)塑(su)性(xing)。

硫可以溶解在熔體(ti)的(de)銅中,但在室溫下,其(qi)溶解度幾乎降低到(dao)零,它以硫化亞銅的(de)形式出(chu)現(xian)在晶(jing)粒晶(jing)界處,會顯著降低銅的(de)塑(su)性。

3、氧在(zai)低氧銅桿(gan)和(he)無氧銅桿(gan)中分布形(xing)式及其(qi)影響(xiang)

氧(yang)(yang)含(han)量(liang)對低(di)(di)氧(yang)(yang)銅(tong)桿的拉線性能有著明顯的影響(xiang)。當(dang)氧(yang)(yang)含(han)量(liang)增加到(dao)最(zui)(zui)佳值時,銅(tong)桿的斷線率最(zui)(zui)低(di)(di)。這是因(yin)為氧(yang)(yang)在與大部分雜質反應的過程(cheng)中(zhong)都起(qi)到(dao)了清除(chu)器的作用。適(shi)度的氧(yang)(yang)還(huan)有利于去除(chu)銅(tong)液中(zhong)的氫,生(sheng)成水蒸氣溢(yi)出(chu),減少氣孔的形成。最(zui)(zui)佳的氧(yang)(yang)含(han)量(liang)為拉線工藝提供了最(zui)(zui)好的條件(jian)。

低氧銅(tong)(tong)桿氧化(hua)(hua)物(wu)(wu)的(de)(de)分布(bu):在連續澆鑄(zhu)中凝(ning)固的(de)(de)最初階段(duan),散熱速率和(he)均(jun)勻冷卻是決定銅(tong)(tong)桿氧化(hua)(hua)物(wu)(wu)分布(bu)的(de)(de)主要因(yin)素。不均(jun)勻冷卻會(hui)引(yin)起銅(tong)(tong)桿內部結構本質上(shang)的(de)(de)差異,但(dan)后續的(de)(de)熱加(jia)工,柱狀晶通常會(hui)遭到破壞(huai),使氧化(hua)(hua)亞銅(tong)(tong)顆(ke)粒(li)(li)細微化(hua)(hua)和(he)均(jun)勻分布(bu)。氧化(hua)(hua)物(wu)(wu)顆(ke)粒(li)(li)聚集(ji)而產(chan)生的(de)(de)典型情況是中心爆裂。除氧化(hua)(hua)物(wu)(wu)顆(ke)粒(li)(li)分布(bu)的(de)(de)影響外(wai),具有較小氧化(hua)(hua)物(wu)(wu)顆(ke)粒(li)(li)的(de)(de)銅(tong)(tong)桿顯(xian)示出較好(hao)的(de)(de)拉線(xian)特性(xing),較大的(de)(de)Cu2O顆(ke)粒(li)(li)容(rong)易造成應力(li)集(ji)中點而斷裂。

無(wu)氧(yang)銅(tong)(tong)含氧(yang)量超標,銅(tong)(tong)桿變脆(cui),延(yan)伸率下降(jiang),拉伸式樣端(duan)口顯暗紅色,結(jie)晶(jing)組織疏松。當(dang)氧(yang)含量超出(chu)8ppm時(shi),工(gong)藝性能變差,表現為鑄造(zao)及(ji)(ji)拉伸過程(cheng)中斷(duan)桿及(ji)(ji)斷(duan)線率極(ji)具增高(gao)。這是(shi)由于氧(yang)能與銅(tong)(tong)生成(cheng)氧(yang)化(hua)(hua)亞銅(tong)(tong)脆(cui)性相,形(xing)成(cheng)銅(tong)(tong)-氧(yang)化(hua)(hua)亞銅(tong)(tong)共晶(jing)體,以網狀組織分(fen)布在(zai)(zai)(zai)境界上。這種(zhong)脆(cui)性相硬(ying)度高(gao),在(zai)(zai)(zai)冷變形(xing)時(shi)將會與銅(tong)(tong)機(ji)體脫離,導(dao)致(zhi)銅(tong)(tong)桿的機(ji)械性能下降(jiang),在(zai)(zai)(zai)后續(xu)加(jia)工(gong)中容(rong)易造(zao)成(cheng)斷(duan)裂(lie)現象。氧(yang)含量高(gao)還能導(dao)致(zhi)無(wu)氧(yang)銅(tong)(tong)桿導(dao)電率下降(jiang)。因此,必(bi)須嚴格控制上引連鑄工(gong)藝及(ji)(ji)產品質量。

4、氫的影響

在上引連(lian)鑄中(zhong),氧(yang)含量控制較低(di)(di),氧(yang)化物的(de)副作(zuo)用唄(bai)**降低(di)(di),但氫的(de)影響成為較顯著的(de)問題。吸(xi)氣后熔體(ti)中(zhong)存在平衡(heng)反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)體及疏(shu)松是在結(jie)晶(jing)的過程(cheng)(cheng)中,氫(qing)從過飽和(he)的溶液中析出并(bing)聚集而(er)形(xing)成(cheng)的。在結(jie)晶(jing)前析出的氫(qing)又可(ke)還原氧化亞銅而(er)生成(cheng)水(shui)氣(qi)(qi)(qi)泡(pao)。由于上(shang)引鑄造的特點(dian)是銅液自上(shang)而(er)下的結(jie)晶(jing),形(xing)成(cheng)的液**形(xing)狀近似錐型(xing)。銅液結(jie)晶(jing)前析出的氣(qi)(qi)(qi)體在上(shang)浮過程(cheng)(cheng)中被堵在凝固組織內,結(jie)晶(jing)時在鑄桿內形(xing)成(cheng)氣(qi)(qi)(qi)孔(kong)。上(shang)引的含氣(qi)(qi)(qi)量少時,析出的氫(qing)存在于晶(jing)界處,形(xing)成(cheng)疏(shu)松;含氣(qi)(qi)(qi)量多時,則聚集成(cheng)氣(qi)(qi)(qi)孔(kong),因此,氣(qi)(qi)(qi)孔(kong)和(he)疏(shu)松是氫(qing)氣(qi)(qi)(qi)和(he)水(shui)蒸(zheng)氣(qi)(qi)(qi)兩者形(xing)成(cheng)的。

氫來(lai)源于上引生(sheng)產過程中(zhong)的各個工藝(yi)環節(jie),如原料電解銅的“銅綠”、輔料木炭**、氣候(hou)環境(jing)**、石墨結晶器未(wei)干燥等。因此,熔化爐(lu)中(zhong)的銅液表面(mian)應(ying)覆(fu)蓋經烘烤的木炭,電解銅應(ying)盡量(liang)去除“銅綠”、“銅豆”“耳朵”,對(dui)提高(gao)無(wu)氧銅桿質量(liang)非常(chang)重要。

在連鑄連軋(ya)工藝中,往(wang)往(wang)采用適度(du)控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅(tong)液(ye)在鑄造過(guo)程(cheng)中(zhong)(zhong)是自(zi)下而上結晶,銅(tong)液(ye)中(zhong)(zhong)的(de)(de)氧(yang)和氫(qing)所產生的(de)(de)水蒸氣很(hen)容易(yi)上浮跑出,銅(tong)液(ye)中(zhong)(zhong)的(de)(de)氫(qing)大部分(fen)能被有(you)效去除,因而對銅(tong)桿的(de)(de)影響較小。

二、表面質量

在生產(chan)電(dian)磁線等產(chan)品的過程(cheng)中,對銅桿的表面(mian)(mian)質(zhi)量也需(xu)提出要(yao)求。需(xu)要(yao)拉(la)制后的銅絲表面(mian)(mian)無(wu)毛刺、銅粉少、無(wu)油(you)污。并通過扭轉(zhuan)試(shi)驗測量表面(mian)(mian)銅粉的質(zhi)量和扭轉(zhuan)后觀察銅桿的復原情況來判(pan)定(ding)其好壞。

在(zai)連(lian)鑄(zhu)連(lian)軋(ya)(ya)過(guo)程中(zhong),從鑄(zhu)造(zao)到軋(ya)(ya)制前,溫(wen)度高,完全暴露(lu)于(yu)空氣(qi)中(zhong),使鑄(zhu)坯表面形成(cheng)(cheng)較厚的(de)(de)(de)氧化(hua)(hua)層,在(zai)軋(ya)(ya)制過(guo)程中(zhong),隨著軋(ya)(ya)輥(gun)的(de)(de)(de)轉動(dong),氧化(hua)(hua)物(wu)顆粒軋(ya)(ya)入銅(tong)(tong)(tong)線表面。由于(yu)氧化(hua)(hua)亞(ya)銅(tong)(tong)(tong)是高熔點(dian)脆(cui)性化(hua)(hua)合物(wu),對于(yu)軋(ya)(ya)入較深的(de)(de)(de)氧化(hua)(hua)亞(ya)銅(tong)(tong)(tong),當(dang)成(cheng)(cheng)條狀的(de)(de)(de)聚集物(wu)遇模具拉(la)伸時,就會是銅(tong)(tong)(tong)桿外表面產生毛(mao)刺,給后續(xu)的(de)(de)(de)涂漆造(zao)成(cheng)(cheng)麻煩。

而上(shang)引連鑄工藝制(zhi)造的無氧銅(tong)桿(gan),由于鑄造和冷卻完全與氧隔絕,后(hou)續亦無熱軋過(guo)程,銅(tong)桿(gan)表面(mian)無軋入表面(mian)的氧化物(wu),質量較好,拉制(zhi)后(hou)銅(tong)粉少,上(shang)述(shu)問題(ti)較少存在(zai)。

無(wu)氧銅(tong)(tong)桿也分進(jin)口(kou)(kou)設備(bei)做(zuo)的(de)(de)和國產設備(bei)做(zuo)的(de)(de),但目前進(jin)口(kou)(kou)產品已無(wu)明顯(xian)優(you)勢,銅(tong)(tong)桿產品出(chu)來后區(qu)別不是(shi)很大,只要銅(tong)(tong)板選的(de)(de)好,生產控制比(bi)較穩定,國產設備(bei)也能產出(chu)可(ke)拉伸0.05的(de)(de)銅(tong)(tong)桿.進(jin)口(kou)(kou)設備(bei)一般是(shi)芬(fen)蘭奧托昆普(pu)的(de)(de)設備(bei),國產設備(bei)最好的(de)(de)應該是(shi)上海的(de)(de)海軍廠的(de)(de)了,生產時間最長,軍工企(qi)業(ye),質量可(ke)靠。

低氧銅桿進口設備國際主要(yao)有(you)兩種(zhong),一種(zhong)是(shi)美國南(nan)線(xian)設備,英文是(shi)SOUTHWIRE,國內廠家(jia)是(shi)南(nan)京華新,江西銅業,另一種(zhong)是(shi)德國CONTIROD設備,國內廠家(jia)是(shi)常州金源(yuan),天津大無縫。

無氧(yang)(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量上(shang)容(rong)易區別,無氧(yang)(yang)(yang)(yang)(yang)(yang)銅是(shi)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量在(zai)10-20個(ge)PPM以下(xia),但(dan)(dan)目前有(you)的(de)(de)廠家只能做(zuo)到(dao)50個(ge)PPM以下(xia).低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)在(zai) 200-400個(ge)PPM,好(hao)的(de)(de)桿(gan)(gan)子一般含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量控制在(zai)250個(ge)PPM左右,無氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)一般采取的(de)(de)是(shi)上(shang)引法,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)是(shi)連鑄連軋,兩種(zhong)產品相對(dui)而言低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)漆(qi)包(bao)線性(xing) 能更適應些,如柔軟性(xing),回彈角,繞線性(xing)能.但(dan)(dan)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)拉(la)絲條件(jian)相對(dui)要苛刻些,同(tong)樣(yang)拉(la)伸0.2的(de)(de)細(xi)絲,如果伸線條件(jian)不好(hao),普通的(de)(de)無氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)可拉(la)而好(hao)的(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)就(jiu)(jiu)斷 線,但(dan)(dan)如果放在(zai)好(hao)的(de)(de)伸線條件(jian),同(tong)樣(yang)的(de)(de)桿(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)說不定就(jiu)(jiu)能拉(la)到(dao)雙(shuang)(shuang)零(ling)(ling)五(wu),而普通無氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)最多只能拉(la)伸到(dao)0.1而已,當然做(zuo)的(de)(de)最細(xi)的(de)(de)如雙(shuang)(shuang)零(ling)(ling)二(er)卻(que)非得依靠進口的(de)(de) 無氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)了(le).目前有(you)企業嘗試用剝皮的(de)(de)方式(shi)來處理(li)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)來伸0.03線.但(dan)(dan)有(you)關這方面的(de)(de)內(nei)容(rong)我還不是(shi)很清楚。

音響(xiang)線一般反而喜歡用無(wu)氧(yang)桿(gan),這和無(wu)氧(yang)桿(gan)是單晶銅,低氧(yang)桿(gan)是多晶銅有關。

氧銅(tong)桿和無(wu)氧銅(tong)桿由于制造方(fang)法(fa)的(de)不(bu)同,致使存在差別,具(ju)有各自(zi)的(de)特(te)點。

一(yi)、關于氧的(de)吸入(ru)和脫去以及它的(de)存在狀態

生產銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)陰極(ji)銅(tong)(tong)(tong)的(de)(de)含氧(yang)(yang)(yang)量一般(ban)在10—50ppm,在常(chang)溫下(xia)氧(yang)(yang)(yang)在銅(tong)(tong)(tong)中的(de)(de)固溶度(du)約2ppm。低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)含氧(yang)(yang)(yang)量一般(ban)在200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)進入(ru)是(shi)在銅(tong)(tong)(tong)的(de)(de)液(ye)態(tai)(tai)下(xia)吸(xi)入(ru)的(de)(de),而(er)(er)上(shang)引法無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)則相反,氧(yang)(yang)(yang)在液(ye)態(tai)(tai)銅(tong)(tong)(tong)下(xia)保持相當時間(jian)后,被還原而(er)(er)脫去(qu),通常(chang)這(zhe)種桿(gan)(gan)(gan)的(de)(de)含氧(yang)(yang)(yang)量都在10—50ppm以下(xia),最低(di)可(ke)達1-2ppm,從組織上(shang)看,低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)(yang),以氧(yang)(yang)(yang)化銅(tong)(tong)(tong)狀態(tai)(tai),存在于(yu)晶粒邊界(jie)(jie)附近,這(zhe)對(dui)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)而(er)(er)言可(ke)以說是(shi)常(chang)見的(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)則很少(shao)見。氧(yang)(yang)(yang)化銅(tong)(tong)(tong)以夾雜形式(shi)在晶界(jie)(jie)出(chu)現對(dui)材料的(de)(de)韌(ren)性產生負(fu)面影響。而(er)(er)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)(yang)很低(di),所(suo)以這(zhe)種銅(tong)(tong)(tong)的(de)(de)組織是(shi)均勻的(de)(de)單相組織對(dui)韌(ren)性有(you)利。在無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中的(de)(de)多孔性是(shi)不常(chang)見的(de)(de),而(er)(er)在低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中則是(shi)常(chang)見的(de)(de)一種缺陷(xian)。

二、熱軋組織(zhi)和鑄造組織(zhi)的區別(bie)

低氧(yang)(yang)銅(tong)桿由于經(jing)過熱軋(ya),所(suo)以(yi)(yi)(yi)其(qi)(qi)組(zu)(zu)織(zhi)屬熱加工(gong)組(zu)(zu)織(zhi),原來的鑄造組(zu)(zu)織(zhi)已(yi)經(jing)破碎(sui),在8mm的桿時(shi)已(yi)有(you)再(zai)結(jie)晶(jing)(jing)(jing)的形(xing)式(shi)出現,而(er)無(wu)(wu)氧(yang)(yang)銅(tong)桿屬鑄造組(zu)(zu)織(zhi),晶(jing)(jing)(jing)粒(li)(li)粗(cu)(cu)大,這是(shi)為什么(me),無(wu)(wu)氧(yang)(yang)銅(tong)的再(zai)結(jie)晶(jing)(jing)(jing)溫(wen)度(du)較高,需(xu)要較高退火(huo)溫(wen)度(du)的固有(you)原因(yin)(yin)。這是(shi)因(yin)(yin)為,再(zai)結(jie)晶(jing)(jing)(jing)發生在晶(jing)(jing)(jing)粒(li)(li)邊界附近(jin),無(wu)(wu)氧(yang)(yang)銅(tong)桿組(zu)(zu)織(zhi)晶(jing)(jing)(jing)粒(li)(li)粗(cu)(cu)大,晶(jing)(jing)(jing)粒(li)(li)尺寸甚至(zhi)能達幾個(ge)毫米,因(yin)(yin)而(er)晶(jing)(jing)(jing)粒(li)(li)邊界少,即(ji)使通(tong)過拉(la)制變形(xing),但晶(jing)(jing)(jing)粒(li)(li)邊界相對低氧(yang)(yang)銅(tong)桿還是(shi)較少,所(suo)以(yi)(yi)(yi)需(xu)要較高的退火(huo)功(gong)(gong)率。對無(wu)(wu)氧(yang)(yang)銅(tong)成功(gong)(gong)的退火(huo)要求是(shi):由桿經(jing)拉(la)制,但尚未鑄造組(zu)(zu)織(zhi)的線時(shi)的第一次退火(huo),其(qi)(qi)退火(huo)功(gong)(gong)率應比同(tong)樣情況的低氧(yang)(yang)銅(tong)高10——15%。經(jing)繼(ji)續拉(la)制,在以(yi)(yi)(yi)后階段的退火(huo)功(gong)(gong)率應留有(you)足(zu)夠的余量和對低氧(yang)(yang)銅(tong)和無(wu)(wu)氧(yang)(yang)銅(tong)切實區別執(zhi)行不同(tong)的退火(huo)工(gong)藝,以(yi)(yi)(yi)保證在制品和成品導(dao)線的柔軟性。

三、夾雜,氧(yang)含量波動,表面氧(yang)化(hua)物(wu)和可能存在的熱軋缺陷的差別(bie)

無(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)的(de)(de)(de)可拉性(xing)在(zai)所(suo)有線徑里與低(di)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)相(xiang)比都是優越的(de)(de)(de),除上述組織(zhi)原因外,無(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)夾雜少,含氧(yang)(yang)(yang)(yang)(yang)量穩定,無(wu)熱軋(ya)可能(neng)(neng)產生(sheng)的(de)(de)(de)缺陷,桿(gan)表氧(yang)(yang)(yang)(yang)(yang)化物(wu)厚度(du)可達≤15A。在(zai)連鑄(zhu)連軋(ya)生(sheng)產過程中(zhong)如(ru)果(guo)(guo)工藝不穩定,對(dui)氧(yang)(yang)(yang)(yang)(yang)監控不嚴(yan),含氧(yang)(yang)(yang)(yang)(yang)量不穩定將直(zhi)接影響桿(gan)的(de)(de)(de)性(xing)能(neng)(neng)。如(ru)果(guo)(guo)桿(gan)的(de)(de)(de)表面氧(yang)(yang)(yang)(yang)(yang)化物(wu)能(neng)(neng)在(zai)后工序(xu)的(de)(de)(de)連續清洗中(zhong)得以彌補(bu)外,但比較麻煩的(de)(de)(de)是有相(xiang)當多的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)化物(wu)存(cun)在(zai)于(yu)“皮下”,對(dui)拉線斷線影響更直(zhi)接,故而在(zai)拉制微細線,超微細線時,為了減(jian)少斷線,有時要(yao)對(dui)銅桿(gan)采取不得已的(de)(de)(de)辦法——剝皮,甚至二次(ci)剝皮的(de)(de)(de)原因所(suo)在(zai),目的(de)(de)(de)要(yao)除去皮下氧(yang)(yang)(yang)(yang)(yang)化物(wu)。

四、低氧銅桿(gan)和無氧銅桿(gan)的(de)韌性有差別

兩者都可以拉到(dao)0.015mm,但(dan)在(zai)低溫(wen)超導(dao)線中的(de)低溫(wen)級(ji)無氧銅(tong),其細絲間(jian)的(de)間(jian)距只(zhi)有0.001mm.

五(wu)、從制(zhi)(zhi)桿的(de)原材料到制(zhi)(zhi)線(xian)的(de)經濟性(xing)有差別。

制(zhi)造(zao)無(wu)氧銅(tong)桿要求質(zhi)量較高的(de)(de)原材料(liao)。一般,拉(la)制(zhi)直徑>1mm的(de)(de)銅(tong)線時,低氧銅(tong)桿的(de)(de)優(you)點比較明顯,而無(wu)氧銅(tong)桿顯得(de)更(geng)為(wei)優(you)越(yue)的(de)(de)是拉(la)制(zhi)直徑<0.5mm的(de)(de)銅(tong)線。

六(liu)、低氧(yang)銅桿(gan)的制線(xian)工(gong)藝與無氧(yang)銅桿(gan)的有所不(bu)同。

低氧銅桿的(de)制線(xian)(xian)工(gong)藝不(bu)能(neng)照搬到無氧銅桿的(de)制線(xian)(xian)工(gong)藝上來,至少兩者的(de)退火工(gong)藝是不(bu)同的(de)。因為(wei)線(xian)(xian)的(de)柔軟性(xing)深受材(cai)料成份和(he)制桿,制線(xian)(xian)和(he)退火工(gong)藝的(de)影響(xiang),不(bu)能(neng)簡單地說(shuo)低氧銅或無氧銅誰(shui)軟誰(shui)硬。