熱門關鍵(jian)詞:
來源:行業動態(tai) 閱讀:109304 發布時間:2019-07-05
導(dao)讀(du):由于(yu)生產(chan)銅(tong)(tong)(tong)桿(gan)的(de)兩者的(de)工(gong)(gong)藝不(bu)同(tong)(tong),所生產(chan)的(de)銅(tong)(tong)(tong)桿(gan)中的(de)含(han)氧量(liang)及外觀就不(bu)同(tong)(tong)。上引生產(chan)的(de)銅(tong)(tong)(tong)桿(gan),工(gong)(gong)藝得當氧含(han)量(liang)在10ppm以下(xia),叫(jiao)無(wu)氧銅(tong)(tong)(tong)桿(gan);連(lian)鑄(zhu)(zhu)連(lian)鑄(zhu)(zhu)生產(chan)的(de)銅(tong)(tong)(tong)桿(gan) 是在保(bao)護條件(jian)下(xia)的(de)熱軋,氧含(han)量(liang)在200-500ppm范圍內,但有時(shi)也高(gao)達700ppm以上,一(yi)般(ban)情況(kuang)下(xia),此種方法(fa)生產(chan)的(de)銅(tong)(tong)(tong)外表光亮,低(di)氧銅(tong)(tong)(tong)桿(gan),有時(shi)也叫(jiao)光桿(gan)。
銅(tong)桿(gan)是電(dian)纜(lan)行業(ye)的(de)主要原料,生(sheng)產的(de)方式(shi)主要有(you)兩種——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)法(fa)(fa)和上引(yin)(yin)連(lian)鑄(zhu)(zhu)法(fa)(fa)。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)低(di)氧(yang)銅(tong)桿(gan)的(de)生(sheng)產方法(fa)(fa)較(jiao)多,其特點是金(jin)屬(shu)在(zai)豎爐(lu)(lu)(lu)中融化后(hou),銅(tong)液通(tong)過(guo)保(bao)溫爐(lu)(lu)(lu)、溜槽、中間(jian)包,從(cong)澆管進(jin)入封(feng)閉(bi)的(de)模腔內(nei),采用(yong)(yong)較(jiao)大的(de)冷卻強度進(jin)行冷卻,形(xing)成鑄(zhu)(zhu)坯,然后(hou)進(jin)行多道次軋(ya)制(zhi),生(sheng)產的(de)低(di)氧(yang)銅(tong)桿(gan)為熱加(jia)工組織(zhi),原來的(de)鑄(zhu)(zhu)造組織(zhi)已經破碎,含(han)(han)氧(yang)量一(yi)般(ban)為200~400ppm之(zhi)間(jian)。無(wu)氧(yang)銅(tong)桿(gan)國內(nei)基本全部采用(yong)(yong)上引(yin)(yin)連(lian)鑄(zhu)(zhu)法(fa)(fa)生(sheng)產,金(jin)屬(shu)在(zai)感(gan)應電(dian)爐(lu)(lu)(lu)中融化后(hou)通(tong)過(guo)石(shi)墨模進(jin)行上引(yin)(yin)連(lian)續鑄(zhu)(zhu)造,之(zhi)后(hou)進(jin)行冷軋(ya)或冷加(jia)工,生(sheng)產的(de)無(wu)氧(yang)銅(tong)桿(gan)為鑄(zhu)(zhu)造組織(zhi),含(han)(han)氧(yang)量一(yi)般(ban)在(zai)20ppm以下。由于制(zhi)造工藝的(de)不(bu)同,所以在(zai)組織(zhi)結構、氧(yang)含(han)(han)量分布(bu)(bu)、雜質的(de)形(xing)式(shi)及分布(bu)(bu)等諸多方面有(you)較(jiao)大差(cha)別。
一、拉制性能
銅(tong)桿(gan)的(de)拉制性能跟(gen)很多因(yin)素有關,如雜質的(de)含量、氧含量及分(fen)布、工藝(yi)控制等。下(xia)面(mian)分(fen)別(bie)從以(yi)上幾個方面(mian)對(dui)銅(tong)桿(gan)的(de)拉制性能進行分(fen)析。
1、熔化(hua)方式(shi)對S等雜質(zhi)的影響
連(lian)鑄連(lian)軋生產(chan)銅(tong)桿(gan)(gan)主要是(shi)(shi)通過(guo)氣體的(de)燃燒(shao)(shao)使銅(tong)桿(gan)(gan)熔化(hua),在(zai)燃燒(shao)(shao)的(de)過(guo)程(cheng)中(zhong)(zhong),通過(guo)氧化(hua)和揮(hui)發作用,可一定程(cheng)度減少部分雜質進(jin)入(ru)銅(tong)液(ye),因此連(lian)鑄連(lian)軋法對(dui)原料要求(qiu)相對(dui)低一些(xie)。上引連(lian)鑄生產(chan)無(wu)氧銅(tong)桿(gan)(gan),由于(yu)是(shi)(shi)用感應電爐(lu)熔化(hua),電解銅(tong)表面的(de)“銅(tong)綠”“銅(tong)豆”基本都熔入(ru)到銅(tong)液(ye)中(zhong)(zhong)。其中(zhong)(zhong)熔入(ru)的(de)S對(dui)無(wu)氧銅(tong)桿(gan)(gan)塑性(xing)影(ying)響極大,會(hui)增加拉絲斷(duan)線率(lv)。
2、鑄造(zao)過程中雜質的(de)進入
在(zai)生(sheng)產(chan)過(guo)(guo)(guo)程中(zhong)(zhong)(zhong),連鑄連軋工藝(yi)需通過(guo)(guo)(guo)保溫爐、溜槽、中(zhong)(zhong)(zhong)間包轉運銅液,相對容易(yi)造(zao)成(cheng)(cheng)耐火(huo)材料的(de)剝落,在(zai)軋制過(guo)(guo)(guo)程中(zhong)(zhong)(zhong)需要通過(guo)(guo)(guo)軋輥,造(zao)成(cheng)(cheng)鐵(tie)質(zhi)的(de)脫落,會(hui)(hui)給銅桿造(zao)成(cheng)(cheng)外(wai)部(bu)夾雜。而(er)熱(re)軋中(zhong)(zhong)(zhong)皮上和皮下(xia)氧化物的(de)軋入,會(hui)(hui)給低氧桿的(de)拉絲造(zao)成(cheng)(cheng)不利的(de)影響。上引連鑄法生(sheng)產(chan)工藝(yi)流(liu)程較(jiao)短,銅液是通過(guo)(guo)(guo)聯體爐內(nei)潛流(liu)式(shi)完成(cheng)(cheng),對耐火(huo)材料的(de)沖(chong)擊不大,結晶(jing)是通過(guo)(guo)(guo)石墨模內(nei)進行,所(suo)以過(guo)(guo)(guo)程中(zhong)(zhong)(zhong)可(ke)能(neng)產(chan)生(sheng)的(de)污染源較(jiao)少,雜質(zhi)進入的(de)機(ji)會(hui)(hui)較(jiao)少。
O、S、P是與銅(tong)(tong)會生產化(hua)(hua)合物的(de)(de)元(yuan)素(su)。在(zai)熔態銅(tong)(tong)中(zhong),氧(yang)可以(yi)溶(rong)解(jie)一部分(fen),但當銅(tong)(tong)冷凝時,氧(yang)幾乎不溶(rong)解(jie)于(yu)銅(tong)(tong)中(zhong)。熔態時所溶(rong)解(jie)的(de)(de)氧(yang),以(yi)銅(tong)(tong)=氧(yang)化(hua)(hua)亞銅(tong)(tong)共晶(jing)體析出,分(fen)布在(zai)晶(jing)粒晶(jing)界處。銅(tong)(tong)-氧(yang)化(hua)(hua)亞銅(tong)(tong)共晶(jing)體的(de)(de)出現,顯(xian)著(zhu)降(jiang)低了銅(tong)(tong)的(de)(de)塑(su)性。
硫可以(yi)溶解(jie)在(zai)熔體的(de)銅(tong)中,但在(zai)室溫下(xia),其溶解(jie)度幾乎降(jiang)低到(dao)零(ling),它以(yi)硫化亞(ya)銅(tong)的(de)形(xing)式(shi)出現在(zai)晶粒晶界處(chu),會顯(xian)著降(jiang)低銅(tong)的(de)塑性。
3、氧(yang)在(zai)低(di)氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿中分布形式及其影響
氧(yang)(yang)含(han)量(liang)對低氧(yang)(yang)銅桿的拉線性(xing)能有著明顯的影(ying)響。當氧(yang)(yang)含(han)量(liang)增(zeng)加(jia)到(dao)最(zui)(zui)佳值時,銅桿的斷線率最(zui)(zui)低。這是因(yin)為氧(yang)(yang)在與(yu)大部分(fen)雜質反應的過程中都(dou)起到(dao)了清除器的作(zuo)用。適度的氧(yang)(yang)還有利(li)于去除銅液中的氫,生成水蒸氣溢出(chu),減少氣孔的形成。最(zui)(zui)佳的氧(yang)(yang)含(han)量(liang)為拉線工藝提(ti)供(gong)了最(zui)(zui)好的條件。
低(di)氧(yang)(yang)銅(tong)(tong)桿氧(yang)(yang)化物(wu)(wu)的(de)(de)(de)(de)(de)(de)分(fen)布(bu)(bu):在連續澆鑄中凝固的(de)(de)(de)(de)(de)(de)最(zui)初階段,散熱(re)速率和均(jun)勻冷卻是(shi)決定銅(tong)(tong)桿氧(yang)(yang)化物(wu)(wu)分(fen)布(bu)(bu)的(de)(de)(de)(de)(de)(de)主要因素(su)。不均(jun)勻冷卻會(hui)引(yin)起(qi)銅(tong)(tong)桿內部(bu)結構(gou)本(ben)質上的(de)(de)(de)(de)(de)(de)差異,但后(hou)續的(de)(de)(de)(de)(de)(de)熱(re)加工,柱狀晶(jing)通常會(hui)遭到破(po)壞,使(shi)氧(yang)(yang)化亞銅(tong)(tong)顆(ke)(ke)粒(li)(li)細微化和均(jun)勻分(fen)布(bu)(bu)。氧(yang)(yang)化物(wu)(wu)顆(ke)(ke)粒(li)(li)聚集(ji)而產生(sheng)的(de)(de)(de)(de)(de)(de)典(dian)型(xing)情況是(shi)中心爆裂。除氧(yang)(yang)化物(wu)(wu)顆(ke)(ke)粒(li)(li)分(fen)布(bu)(bu)的(de)(de)(de)(de)(de)(de)影響外,具有較小氧(yang)(yang)化物(wu)(wu)顆(ke)(ke)粒(li)(li)的(de)(de)(de)(de)(de)(de)銅(tong)(tong)桿顯(xian)示出較好的(de)(de)(de)(de)(de)(de)拉線特性(xing),較大的(de)(de)(de)(de)(de)(de)Cu2O顆(ke)(ke)粒(li)(li)容易造成應力集(ji)中點而斷裂。
無(wu)氧(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)量超標,銅(tong)(tong)(tong)桿變脆,延(yan)伸(shen)率(lv)下(xia)降,拉伸(shen)式樣端口顯暗紅色,結晶組織疏(shu)松。當氧(yang)(yang)含量超出(chu)8ppm時,工藝性(xing)能(neng)變差,表現為鑄造及(ji)(ji)拉伸(shen)過程(cheng)中斷桿及(ji)(ji)斷線(xian)率(lv)極具(ju)增(zeng)高(gao)。這是由于氧(yang)(yang)能(neng)與銅(tong)(tong)(tong)生成氧(yang)(yang)化亞銅(tong)(tong)(tong)脆性(xing)相,形成銅(tong)(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)(tong)共晶體(ti),以網狀組織分布在(zai)境界上。這種脆性(xing)相硬度高(gao),在(zai)冷(leng)變形時將會(hui)與銅(tong)(tong)(tong)機(ji)體(ti)脫離,導(dao)致(zhi)(zhi)銅(tong)(tong)(tong)桿的機(ji)械性(xing)能(neng)下(xia)降,在(zai)后(hou)續加(jia)工中容易造成斷裂現象。氧(yang)(yang)含量高(gao)還能(neng)導(dao)致(zhi)(zhi)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿導(dao)電率(lv)下(xia)降。因此,必須嚴格控制上引連鑄工藝及(ji)(ji)產品(pin)質量。
4、氫的影響
在上引連鑄(zhu)中,氧(yang)含量控制較低,氧(yang)化物的(de)副作用(yong)唄**降低,但(dan)氫的(de)影響成為(wei)較顯著(zhu)的(de)問(wen)題。吸氣(qi)后熔體(ti)中存在平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)體(ti)及疏松(song)是(shi)在(zai)結(jie)晶的過程中,氫(qing)(qing)從過飽和的溶液(ye)中析(xi)出(chu)(chu)并聚集(ji)而形(xing)成(cheng)的。在(zai)結(jie)晶前析(xi)出(chu)(chu)的氫(qing)(qing)又(you)可(ke)還原氧(yang)化亞銅而生成(cheng)水(shui)氣(qi)(qi)泡。由于(yu)上引(yin)鑄造的特點是(shi)銅液(ye)自上而下(xia)的結(jie)晶,形(xing)成(cheng)的液(ye)**形(xing)狀(zhuang)近似錐型。銅液(ye)結(jie)晶前析(xi)出(chu)(chu)的氣(qi)(qi)體(ti)在(zai)上浮過程中被堵在(zai)凝(ning)固組織內(nei),結(jie)晶時(shi)(shi)在(zai)鑄桿內(nei)形(xing)成(cheng)氣(qi)(qi)孔。上引(yin)的含(han)氣(qi)(qi)量(liang)少時(shi)(shi),析(xi)出(chu)(chu)的氫(qing)(qing)存在(zai)于(yu)晶界(jie)處(chu),形(xing)成(cheng)疏松(song);含(han)氣(qi)(qi)量(liang)多時(shi)(shi),則聚集(ji)成(cheng)氣(qi)(qi)孔,因此,氣(qi)(qi)孔和疏松(song)是(shi)氫(qing)(qing)氣(qi)(qi)和水(shui)蒸氣(qi)(qi)兩(liang)者形(xing)成(cheng)的。
氫來源(yuan)于上引生產過程中的(de)各個工藝環節,如原料電解銅(tong)的(de)“銅(tong)綠(lv)”、輔料木(mu)炭(tan)(tan)**、氣候環境(jing)**、石墨結晶器(qi)未干燥等。因此,熔化爐(lu)中的(de)銅(tong)液表(biao)面應覆(fu)蓋經烘烤的(de)木(mu)炭(tan)(tan),電解銅(tong)應盡(jin)量(liang)(liang)去(qu)除(chu)“銅(tong)綠(lv)”、“銅(tong)豆”“耳朵”,對提高(gao)無氧銅(tong)桿質量(liang)(liang)非常重要。
在連鑄(zhu)連軋工藝中,往(wang)往(wang)采(cai)用適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液在鑄造過程(cheng)中是自下而上(shang)(shang)結晶,銅(tong)液中的氧和氫(qing)所產生的水蒸氣很(hen)容易上(shang)(shang)浮跑出(chu),銅(tong)液中的氫(qing)大部分能被有效去除,因而對(dui)銅(tong)桿(gan)的影響(xiang)較小。
二、表面質量
在(zai)生產(chan)電磁線(xian)等產(chan)品的(de)過程中,對銅(tong)桿的(de)表(biao)面質量也需提出要(yao)求(qiu)。需要(yao)拉制(zhi)后的(de)銅(tong)絲(si)表(biao)面無(wu)毛刺、銅(tong)粉(fen)少、無(wu)油污。并通過扭轉試(shi)驗測量表(biao)面銅(tong)粉(fen)的(de)質量和扭轉后觀察銅(tong)桿的(de)復原情況來判定其(qi)好壞。
在連鑄(zhu)連軋(ya)(ya)過程中,從鑄(zhu)造(zao)到(dao)軋(ya)(ya)制(zhi)前,溫度高(gao)(gao),完全暴露于空氣中,使鑄(zhu)坯表(biao)面形(xing)成(cheng)較厚的(de)氧(yang)化(hua)(hua)層,在軋(ya)(ya)制(zhi)過程中,隨著(zhu)軋(ya)(ya)輥的(de)轉動,氧(yang)化(hua)(hua)物(wu)顆粒軋(ya)(ya)入(ru)銅線表(biao)面。由于氧(yang)化(hua)(hua)亞銅是(shi)高(gao)(gao)熔點脆(cui)性化(hua)(hua)合(he)物(wu),對于軋(ya)(ya)入(ru)較深的(de)氧(yang)化(hua)(hua)亞銅,當成(cheng)條(tiao)狀(zhuang)的(de)聚集物(wu)遇模具拉伸時,就會是(shi)銅桿外表(biao)面產(chan)生毛刺,給(gei)后續(xu)的(de)涂(tu)漆造(zao)成(cheng)麻煩。
而上引(yin)連鑄(zhu)工藝制(zhi)造(zao)的無氧(yang)銅桿(gan),由于(yu)鑄(zhu)造(zao)和冷(leng)卻(que)完全與氧(yang)隔(ge)絕,后續亦(yi)無熱軋過程,銅桿(gan)表面無軋入表面的氧(yang)化物,質量較(jiao)好,拉制(zhi)后銅粉(fen)少,上述問題較(jiao)少存在(zai)。
無(wu)氧銅(tong)桿(gan)(gan)也(ye)分(fen)進口設(she)(she)備做(zuo)的(de)(de)(de)(de)和國(guo)產(chan)(chan)(chan)設(she)(she)備做(zuo)的(de)(de)(de)(de),但目前進口產(chan)(chan)(chan)品已無(wu)明顯(xian)優勢,銅(tong)桿(gan)(gan)產(chan)(chan)(chan)品出來后區別不是很大,只(zhi)要(yao)銅(tong)板(ban)選的(de)(de)(de)(de)好(hao),生產(chan)(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)(chan)設(she)(she)備也(ye)能(neng)產(chan)(chan)(chan)出可拉(la)伸0.05的(de)(de)(de)(de)銅(tong)桿(gan)(gan).進口設(she)(she)備一般是芬蘭奧托(tuo)昆普(pu)的(de)(de)(de)(de)設(she)(she)備,國(guo)產(chan)(chan)(chan)設(she)(she)備最好(hao)的(de)(de)(de)(de)應該(gai)是上海的(de)(de)(de)(de)海軍廠的(de)(de)(de)(de)了,生產(chan)(chan)(chan)時間最長,軍工企業,質量(liang)可靠(kao)。
低(di)氧銅桿(gan)進(jin)口設(she)備(bei)國(guo)際(ji)主要有兩(liang)種,一(yi)種是(shi)美國(guo)南線設(she)備(bei),英(ying)文是(shi)SOUTHWIRE,國(guo)內廠家是(shi)南京華新,江西銅業(ye),另一(yi)種是(shi)德國(guo)CONTIROD設(she)備(bei),國(guo)內廠家是(shi)常州(zhou)金(jin)源,天(tian)津大(da)無(wu)縫。
無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)及低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量上(shang)(shang)容易區別,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅是含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量在(zai)10-20個PPM以下(xia),但(dan)目(mu)前有(you)的(de)(de)(de)(de)廠(chang)家只(zhi)(zhi)能做到(dao)50個PPM以下(xia).低氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)(de)(de)(de)桿(gan)(gan)子一般含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量控(kong)制在(zai)250個PPM左右,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)一般采取(qu)的(de)(de)(de)(de)是上(shang)(shang)引法,低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)是連鑄連軋,兩(liang)種(zhong)產品相(xiang)對而(er)(er)言低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對漆包線(xian)性 能更適應些,如(ru)柔軟性,回(hui)彈角,繞線(xian)性能.但(dan)低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對拉絲條件(jian)(jian)相(xiang)對要苛(ke)刻些,同(tong)樣(yang)拉伸0.2的(de)(de)(de)(de)細絲,如(ru)果(guo)伸線(xian)條件(jian)(jian)不(bu)好(hao),普通(tong)的(de)(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)可拉而(er)(er)好(hao)的(de)(de)(de)(de)低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)就斷 線(xian),但(dan)如(ru)果(guo)放(fang)在(zai)好(hao)的(de)(de)(de)(de)伸線(xian)條件(jian)(jian),同(tong)樣(yang)的(de)(de)(de)(de)桿(gan)(gan)子,低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)說不(bu)定就能拉到(dao)雙零五,而(er)(er)普通(tong)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)最(zui)多只(zhi)(zhi)能拉伸到(dao)0.1而(er)(er)已,當然做的(de)(de)(de)(de)最(zui)細的(de)(de)(de)(de)如(ru)雙零二卻(que)非得依靠進口的(de)(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)了(le).目(mu)前有(you)企(qi)業(ye)嘗試用剝皮的(de)(de)(de)(de)方式來處理低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)來伸0.03線(xian).但(dan)有(you)關這方面的(de)(de)(de)(de)內容我還(huan)不(bu)是很清(qing)楚。
音(yin)響(xiang)線一般反(fan)而喜歡用無氧(yang)桿,這和(he)無氧(yang)桿是(shi)單晶(jing)銅,低(di)氧(yang)桿是(shi)多晶(jing)銅有(you)關。
氧銅(tong)桿和無氧銅(tong)桿由于制造方法的(de)不同,致使存(cun)在差別(bie),具有各自的(de)特點。
一、關于氧的吸入和脫去以及它的存在狀態(tai)
生產銅(tong)(tong)(tong)(tong)(tong)桿的(de)(de)陰(yin)極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)含氧(yang)(yang)量(liang)一般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)(chang)溫下(xia)氧(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿的(de)(de)含氧(yang)(yang)量(liang)一般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)進入是在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)液態(tai)下(xia)吸(xi)入的(de)(de),而(er)上(shang)引法無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿則(ze)(ze)相(xiang)反,氧(yang)(yang)在(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)下(xia)保持相(xiang)當時間(jian)后,被還原而(er)脫去,通(tong)常(chang)(chang)這種(zhong)(zhong)桿的(de)(de)含氧(yang)(yang)量(liang)都在(zai)(zai)(zai)10—50ppm以下(xia),最(zui)低(di)可達(da)1-2ppm,從組織上(shang)看,低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang),以氧(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)于晶(jing)(jing)粒(li)邊(bian)界附近,這對(dui)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿而(er)言可以說(shuo)是常(chang)(chang)見(jian)的(de)(de)但對(dui)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿則(ze)(ze)很少見(jian)。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)以夾雜(za)形式在(zai)(zai)(zai)晶(jing)(jing)界出現對(dui)材料的(de)(de)韌性(xing)產生負面影響。而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)很低(di),所(suo)以這種(zhong)(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)組織是均勻的(de)(de)單相(xiang)組織對(dui)韌性(xing)有利。在(zai)(zai)(zai)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿中的(de)(de)多孔(kong)性(xing)是不常(chang)(chang)見(jian)的(de)(de),而(er)在(zai)(zai)(zai)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿中則(ze)(ze)是常(chang)(chang)見(jian)的(de)(de)一種(zhong)(zhong)缺(que)陷。
二、熱(re)軋組織(zhi)和(he)鑄造組織(zhi)的區別(bie)
低(di)氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)由于經(jing)過熱(re)軋,所以(yi)其(qi)組織屬熱(re)加(jia)工組織,原(yuan)來(lai)的(de)(de)(de)(de)鑄(zhu)造(zao)(zao)組織已(yi)經(jing)破(po)碎(sui),在(zai)8mm的(de)(de)(de)(de)桿(gan)(gan)(gan)(gan)時(shi)已(yi)有再結(jie)晶(jing)的(de)(de)(de)(de)形式出現,而無(wu)(wu)氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)屬鑄(zhu)造(zao)(zao)組織,晶(jing)粒(li)粗大(da),這是為(wei)什么,無(wu)(wu)氧(yang)銅(tong)(tong)的(de)(de)(de)(de)再結(jie)晶(jing)溫度較(jiao)(jiao)高(gao),需要較(jiao)(jiao)高(gao)退(tui)火(huo)溫度的(de)(de)(de)(de)固有原(yuan)因(yin)。這是因(yin)為(wei),再結(jie)晶(jing)發生在(zai)晶(jing)粒(li)邊界(jie)(jie)附(fu)近(jin),無(wu)(wu)氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)組織晶(jing)粒(li)粗大(da),晶(jing)粒(li)尺寸甚至能達幾個毫米,因(yin)而晶(jing)粒(li)邊界(jie)(jie)少(shao),即使通過拉制(zhi)變形,但晶(jing)粒(li)邊界(jie)(jie)相對低(di)氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)還是較(jiao)(jiao)少(shao),所以(yi)需要較(jiao)(jiao)高(gao)的(de)(de)(de)(de)退(tui)火(huo)功(gong)率(lv)(lv)(lv)。對無(wu)(wu)氧(yang)銅(tong)(tong)成(cheng)(cheng)功(gong)的(de)(de)(de)(de)退(tui)火(huo)要求是:由桿(gan)(gan)(gan)(gan)經(jing)拉制(zhi),但尚未鑄(zhu)造(zao)(zao)組織的(de)(de)(de)(de)線(xian)時(shi)的(de)(de)(de)(de)第一次退(tui)火(huo),其(qi)退(tui)火(huo)功(gong)率(lv)(lv)(lv)應(ying)(ying)比同(tong)樣情況的(de)(de)(de)(de)低(di)氧(yang)銅(tong)(tong)高(gao)10——15%。經(jing)繼續拉制(zhi),在(zai)以(yi)后階(jie)段(duan)的(de)(de)(de)(de)退(tui)火(huo)功(gong)率(lv)(lv)(lv)應(ying)(ying)留有足(zu)夠的(de)(de)(de)(de)余量和對低(di)氧(yang)銅(tong)(tong)和無(wu)(wu)氧(yang)銅(tong)(tong)切實區別執行不同(tong)的(de)(de)(de)(de)退(tui)火(huo)工藝,以(yi)保證在(zai)制(zhi)品(pin)和成(cheng)(cheng)品(pin)導線(xian)的(de)(de)(de)(de)柔(rou)軟(ruan)性。
三(san)、夾(jia)雜,氧含量(liang)波動,表(biao)面(mian)氧化(hua)物和可能存在的熱軋(ya)缺陷的差(cha)別
無氧(yang)(yang)銅(tong)桿(gan)(gan)的(de)可(ke)拉性在所(suo)有(you)線徑里與低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)相比都是優越的(de),除上(shang)述組織(zhi)原因外(wai),無氧(yang)(yang)銅(tong)桿(gan)(gan)夾雜少(shao),含(han)氧(yang)(yang)量穩定(ding),無熱軋可(ke)能(neng)產生(sheng)的(de)缺陷(xian),桿(gan)(gan)表氧(yang)(yang)化(hua)物(wu)(wu)厚度可(ke)達≤15A。在連(lian)(lian)鑄連(lian)(lian)軋生(sheng)產過程中如果工(gong)藝不穩定(ding),對(dui)氧(yang)(yang)監控不嚴,含(han)氧(yang)(yang)量不穩定(ding)將直接影響桿(gan)(gan)的(de)性能(neng)。如果桿(gan)(gan)的(de)表面氧(yang)(yang)化(hua)物(wu)(wu)能(neng)在后工(gong)序的(de)連(lian)(lian)續清洗中得以(yi)彌補外(wai),但比較麻煩的(de)是有(you)相當(dang)多的(de)氧(yang)(yang)化(hua)物(wu)(wu)存在于“皮下”,對(dui)拉線斷(duan)線影響更直接,故(gu)而在拉制(zhi)微細線,超微細線時,為了(le)減少(shao)斷(duan)線,有(you)時要(yao)對(dui)銅(tong)桿(gan)(gan)采取不得已(yi)的(de)辦法——剝(bo)皮,甚至(zhi)二次剝(bo)皮的(de)原因所(suo)在,目(mu)的(de)要(yao)除去皮下氧(yang)(yang)化(hua)物(wu)(wu)。
四、低氧(yang)銅(tong)桿(gan)和無氧(yang)銅(tong)桿(gan)的韌性(xing)有差別
兩者(zhe)都可以拉到0.015mm,但在低(di)溫超(chao)導線(xian)中的(de)低(di)溫級(ji)無氧銅,其細絲間的(de)間距只有(you)0.001mm.
五、從制桿的原材料到制線(xian)的經濟性有差別。
制造(zao)無氧(yang)銅(tong)桿要求質量較高的(de)原材料。一般(ban),拉制直徑(jing)>1mm的(de)銅(tong)線時,低氧(yang)銅(tong)桿的(de)優(you)點比較明(ming)顯,而無氧(yang)銅(tong)桿顯得(de)更為(wei)優(you)越的(de)是(shi)拉制直徑(jing)<0.5mm的(de)銅(tong)線。
六、低(di)氧(yang)銅(tong)桿(gan)的制線工藝(yi)與無(wu)氧(yang)銅(tong)桿(gan)的有所不同(tong)。
低氧(yang)銅(tong)桿的制(zhi)(zhi)線(xian)(xian)工(gong)藝不(bu)能照搬到無氧(yang)銅(tong)桿的制(zhi)(zhi)線(xian)(xian)工(gong)藝上來,至少兩者的退火(huo)工(gong)藝是(shi)不(bu)同的。因為(wei)線(xian)(xian)的柔(rou)軟(ruan)性深(shen)受材(cai)料成份和制(zhi)(zhi)桿,制(zhi)(zhi)線(xian)(xian)和退火(huo)工(gong)藝的影(ying)響,不(bu)能簡單地說低氧(yang)銅(tong)或(huo)無氧(yang)銅(tong)誰軟(ruan)誰硬。
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