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來源:行(xing)業動態 閱讀:109600 發布時(shi)間(jian):2019-07-05
導讀(du):由于(yu)生產(chan)銅(tong)桿(gan)(gan)的(de)兩者的(de)工(gong)藝不(bu)同,所(suo)生產(chan)的(de)銅(tong)桿(gan)(gan)中(zhong)的(de)含氧(yang)(yang)(yang)量(liang)及外(wai)觀就不(bu)同。上引生產(chan)的(de)銅(tong)桿(gan)(gan),工(gong)藝得當氧(yang)(yang)(yang)含量(liang)在(zai)(zai)10ppm以(yi)下,叫無氧(yang)(yang)(yang)銅(tong)桿(gan)(gan);連鑄連鑄生產(chan)的(de)銅(tong)桿(gan)(gan) 是在(zai)(zai)保護(hu)條件下的(de)熱(re)軋,氧(yang)(yang)(yang)含量(liang)在(zai)(zai)200-500ppm范(fan)圍(wei)內,但有(you)時(shi)也高達700ppm以(yi)上,一般情況下,此種(zhong)方(fang)法生產(chan)的(de)銅(tong)外(wai)表(biao)光亮,低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan),有(you)時(shi)也叫光桿(gan)(gan)。
銅(tong)(tong)(tong)(tong)桿(gan)是電纜行(xing)(xing)業的(de)(de)(de)(de)(de)主要(yao)原料,生(sheng)產的(de)(de)(de)(de)(de)方(fang)(fang)式主要(yao)有兩種——連鑄(zhu)連軋法(fa)和上引連鑄(zhu)法(fa)。連鑄(zhu)連軋低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)生(sheng)產方(fang)(fang)法(fa)較(jiao)多(duo),其特點是金屬在豎爐(lu)中(zhong)(zhong)融化后(hou),銅(tong)(tong)(tong)(tong)液通(tong)過保溫(wen)爐(lu)、溜槽、中(zhong)(zhong)間包,從澆(jiao)管(guan)進入封閉的(de)(de)(de)(de)(de)模(mo)腔內,采用較(jiao)大的(de)(de)(de)(de)(de)冷卻強(qiang)度(du)進行(xing)(xing)冷卻,形(xing)成(cheng)鑄(zhu)坯,然后(hou)進行(xing)(xing)多(duo)道(dao)次軋制(zhi)(zhi),生(sheng)產的(de)(de)(de)(de)(de)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)為(wei)熱加工(gong)組織,原來(lai)的(de)(de)(de)(de)(de)鑄(zhu)造組織已經(jing)破碎,含(han)氧(yang)(yang)(yang)量(liang)一般為(wei)200~400ppm之(zhi)間。無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)國(guo)內基本全部采用上引連鑄(zhu)法(fa)生(sheng)產,金屬在感應電爐(lu)中(zhong)(zhong)融化后(hou)通(tong)過石(shi)墨模(mo)進行(xing)(xing)上引連續鑄(zhu)造,之(zhi)后(hou)進行(xing)(xing)冷軋或冷加工(gong),生(sheng)產的(de)(de)(de)(de)(de)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)為(wei)鑄(zhu)造組織,含(han)氧(yang)(yang)(yang)量(liang)一般在20ppm以下。由(you)于制(zhi)(zhi)造工(gong)藝的(de)(de)(de)(de)(de)不(bu)同,所(suo)以在組織結構、氧(yang)(yang)(yang)含(han)量(liang)分布(bu)、雜(za)質(zhi)的(de)(de)(de)(de)(de)形(xing)式及(ji)分布(bu)等諸(zhu)多(duo)方(fang)(fang)面有較(jiao)大差別(bie)。
一、拉制性能
銅(tong)桿的拉制性(xing)能跟很多(duo)因素(su)有關,如雜質的含量、氧含量及分(fen)布、工(gong)藝控制等。下面分(fen)別從以上幾個方面對銅(tong)桿的拉制性(xing)能進(jin)行分(fen)析。
1、熔化(hua)方(fang)式對S等雜質的影響
連鑄(zhu)連軋(ya)生產銅(tong)(tong)(tong)桿主(zhu)要(yao)是通過(guo)(guo)氣(qi)體的(de)燃(ran)(ran)燒(shao)使銅(tong)(tong)(tong)桿熔化,在燃(ran)(ran)燒(shao)的(de)過(guo)(guo)程中,通過(guo)(guo)氧化和揮發作用,可(ke)一定程度減少部分雜質進入(ru)銅(tong)(tong)(tong)液(ye),因此連鑄(zhu)連軋(ya)法對(dui)原料要(yao)求(qiu)相對(dui)低(di)一些(xie)。上(shang)引連鑄(zhu)生產無氧銅(tong)(tong)(tong)桿,由于是用感應(ying)電(dian)爐熔化,電(dian)解(jie)銅(tong)(tong)(tong)表(biao)面的(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基本(ben)都熔入(ru)到銅(tong)(tong)(tong)液(ye)中。其中熔入(ru)的(de)S對(dui)無氧銅(tong)(tong)(tong)桿塑性(xing)影響極(ji)大,會增(zeng)加拉絲斷線率。
2、鑄造過程中雜質的進入
在(zai)生(sheng)產過(guo)程(cheng)中(zhong),連(lian)鑄連(lian)軋(ya)工藝(yi)需通過(guo)保溫爐(lu)、溜槽、中(zhong)間包轉運銅(tong)液,相對(dui)容易造成耐火(huo)材料(liao)的剝落,在(zai)軋(ya)制(zhi)過(guo)程(cheng)中(zhong)需要通過(guo)軋(ya)輥,造成鐵質的脫落,會(hui)給(gei)銅(tong)桿(gan)造成外(wai)部夾雜。而(er)熱軋(ya)中(zhong)皮上(shang)和(he)皮下氧化物的軋(ya)入(ru),會(hui)給(gei)低氧桿(gan)的拉絲造成不(bu)利的影響。上(shang)引連(lian)鑄法生(sheng)產工藝(yi)流(liu)程(cheng)較(jiao)(jiao)短,銅(tong)液是通過(guo)聯體爐(lu)內潛(qian)流(liu)式完成,對(dui)耐火(huo)材料(liao)的沖(chong)擊不(bu)大,結(jie)晶是通過(guo)石(shi)墨模(mo)內進行,所以過(guo)程(cheng)中(zhong)可能(neng)產生(sheng)的污染源較(jiao)(jiao)少(shao),雜質進入(ru)的機會(hui)較(jiao)(jiao)少(shao)。
O、S、P是與銅(tong)會生產化(hua)(hua)合物的(de)元(yuan)素。在熔(rong)態銅(tong)中,氧可以(yi)溶(rong)解一(yi)部分,但當銅(tong)冷凝時,氧幾乎不溶(rong)解于銅(tong)中。熔(rong)態時所溶(rong)解的(de)氧,以(yi)銅(tong)=氧化(hua)(hua)亞(ya)銅(tong)共晶(jing)體(ti)析出(chu),分布(bu)在晶(jing)粒(li)晶(jing)界(jie)處。銅(tong)-氧化(hua)(hua)亞(ya)銅(tong)共晶(jing)體(ti)的(de)出(chu)現,顯著降(jiang)低了(le)銅(tong)的(de)塑性。
硫可以溶(rong)解在(zai)熔體的(de)銅(tong)中,但(dan)在(zai)室(shi)溫下,其溶(rong)解度(du)幾乎降低到零,它以硫化亞銅(tong)的(de)形式出(chu)現在(zai)晶(jing)粒(li)晶(jing)界處,會(hui)顯著降低銅(tong)的(de)塑(su)性。
3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中分布形式及其影響
氧(yang)(yang)含(han)量對低氧(yang)(yang)銅(tong)桿的(de)拉(la)(la)線性能有著明顯(xian)的(de)影響。當氧(yang)(yang)含(han)量增加到最(zui)佳值(zhi)時,銅(tong)桿的(de)斷線率最(zui)低。這是因為(wei)氧(yang)(yang)在與大部分(fen)雜(za)質反應(ying)的(de)過(guo)程中都起(qi)到了清除器(qi)的(de)作(zuo)用。適(shi)度的(de)氧(yang)(yang)還有利于去除銅(tong)液中的(de)氫,生成(cheng)水蒸(zheng)氣溢(yi)出,減(jian)少氣孔的(de)形成(cheng)。最(zui)佳的(de)氧(yang)(yang)含(han)量為(wei)拉(la)(la)線工(gong)藝提供了最(zui)好(hao)的(de)條件。
低氧(yang)(yang)(yang)銅桿(gan)(gan)氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)的(de)(de)(de)分布(bu):在連(lian)續(xu)澆鑄中(zhong)凝固的(de)(de)(de)最(zui)初階段,散熱速率(lv)和(he)均勻(yun)(yun)冷卻(que)是(shi)決定銅桿(gan)(gan)氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)分布(bu)的(de)(de)(de)主要因素。不均勻(yun)(yun)冷卻(que)會引起銅桿(gan)(gan)內(nei)部結構本質上的(de)(de)(de)差異,但后續(xu)的(de)(de)(de)熱加工,柱(zhu)狀晶通常會遭到破壞(huai),使氧(yang)(yang)(yang)化(hua)(hua)(hua)亞銅顆(ke)粒細微化(hua)(hua)(hua)和(he)均勻(yun)(yun)分布(bu)。氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)顆(ke)粒聚集而產生的(de)(de)(de)典(dian)型情況是(shi)中(zhong)心(xin)爆(bao)裂。除氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)顆(ke)粒分布(bu)的(de)(de)(de)影響外,具(ju)有較(jiao)(jiao)小氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)顆(ke)粒的(de)(de)(de)銅桿(gan)(gan)顯示出較(jiao)(jiao)好(hao)的(de)(de)(de)拉(la)線(xian)特性,較(jiao)(jiao)大(da)的(de)(de)(de)Cu2O顆(ke)粒容(rong)易造成應力集中(zhong)點而斷裂。
無氧(yang)銅含氧(yang)量超(chao)標,銅桿變脆,延伸(shen)率(lv)下降,拉(la)伸(shen)式(shi)樣端口(kou)顯暗紅(hong)色(se),結晶組織疏松。當氧(yang)含量超(chao)出8ppm時,工(gong)藝性(xing)(xing)能(neng)變差,表現(xian)為鑄造及拉(la)伸(shen)過程中(zhong)斷桿及斷線率(lv)極(ji)具增高(gao)。這是由于(yu)氧(yang)能(neng)與(yu)銅生成氧(yang)化亞銅脆性(xing)(xing)相(xiang)(xiang),形成銅-氧(yang)化亞銅共晶體,以網狀組織分(fen)布(bu)在(zai)境界上(shang)。這種脆性(xing)(xing)相(xiang)(xiang)硬(ying)度(du)高(gao),在(zai)冷變形時將會與(yu)銅機體脫離,導致銅桿的機械性(xing)(xing)能(neng)下降,在(zai)后續加工(gong)中(zhong)容易造成斷裂(lie)現(xian)象。氧(yang)含量高(gao)還能(neng)導致無氧(yang)銅桿導電率(lv)下降。因(yin)此(ci),必須嚴格控制上(shang)引(yin)連鑄工(gong)藝及產品質量。
4、氫的影響
在上引(yin)連(lian)鑄(zhu)中(zhong),氧含量控制較低,氧化物(wu)的副作用唄**降低,但氫(qing)的影響成為(wei)較顯著的問題。吸氣后熔(rong)體中(zhong)存在平(ping)衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體及疏松(song)是(shi)在(zai)(zai)結(jie)晶(jing)(jing)的過程(cheng)中,氫(qing)(qing)從過飽和(he)的溶液(ye)中析出(chu)(chu)并(bing)聚(ju)集而形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)的。在(zai)(zai)結(jie)晶(jing)(jing)前(qian)析出(chu)(chu)的氫(qing)(qing)又可還原氧化(hua)亞(ya)銅(tong)而生成(cheng)(cheng)(cheng)(cheng)水氣(qi)(qi)(qi)泡。由(you)于上(shang)引鑄(zhu)造的特(te)點是(shi)銅(tong)液(ye)自上(shang)而下的結(jie)晶(jing)(jing),形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)的液(ye)**形(xing)(xing)狀近似(si)錐型。銅(tong)液(ye)結(jie)晶(jing)(jing)前(qian)析出(chu)(chu)的氣(qi)(qi)(qi)體在(zai)(zai)上(shang)浮過程(cheng)中被堵在(zai)(zai)凝固(gu)組織內,結(jie)晶(jing)(jing)時(shi)在(zai)(zai)鑄(zhu)桿內形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔(kong)。上(shang)引的含(han)氣(qi)(qi)(qi)量少時(shi),析出(chu)(chu)的氫(qing)(qing)存(cun)在(zai)(zai)于晶(jing)(jing)界處,形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)疏松(song);含(han)氣(qi)(qi)(qi)量多時(shi),則聚(ju)集成(cheng)(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔(kong),因此(ci),氣(qi)(qi)(qi)孔(kong)和(he)疏松(song)是(shi)氫(qing)(qing)氣(qi)(qi)(qi)和(he)水蒸氣(qi)(qi)(qi)兩者形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)的。
氫(qing)來源(yuan)于上(shang)引生產過程中(zhong)的各個(ge)工藝環(huan)節,如原料電解銅(tong)(tong)的“銅(tong)(tong)綠”、輔料木炭**、氣候環(huan)境**、石墨結晶器未干燥等(deng)。因此,熔化爐(lu)中(zhong)的銅(tong)(tong)液表面應覆蓋經烘烤的木炭,電解銅(tong)(tong)應盡量去(qu)除“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳朵”,對提高無氧銅(tong)(tong)桿(gan)質(zhi)量非(fei)常重要。
在連鑄連軋工藝中,往(wang)往(wang)采(cai)用適(shi)度(du)控(kong)制(zhi)(zhi)氧含量來控(kong)制(zhi)(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于銅液在鑄造過程中是自下而上(shang)結晶(jing),銅液中的氧和氫所產生的水蒸(zheng)氣很(hen)容易上(shang)浮(fu)跑出(chu),銅液中的氫大部分能(neng)被有效去除(chu),因而對銅桿的影響較小。
二、表面質量
在(zai)生產電磁(ci)線等(deng)產品的過程中,對銅(tong)桿的表(biao)(biao)面質(zhi)量也(ye)需提出要(yao)求。需要(yao)拉(la)制后的銅(tong)絲表(biao)(biao)面無毛(mao)刺、銅(tong)粉少(shao)、無油污。并通過扭轉(zhuan)試驗(yan)測量表(biao)(biao)面銅(tong)粉的質(zhi)量和(he)扭轉(zhuan)后觀察銅(tong)桿的復原(yuan)情(qing)況(kuang)來判(pan)定(ding)其好壞。
在(zai)連鑄連軋(ya)過程中,從鑄造到軋(ya)制前,溫度高,完全(quan)暴露于(yu)(yu)空(kong)氣中,使鑄坯表(biao)面形成(cheng)較(jiao)厚的(de)氧(yang)化(hua)層,在(zai)軋(ya)制過程中,隨著軋(ya)輥的(de)轉動,氧(yang)化(hua)物(wu)顆粒(li)軋(ya)入(ru)(ru)銅(tong)線(xian)表(biao)面。由于(yu)(yu)氧(yang)化(hua)亞(ya)銅(tong)是(shi)高熔點脆性化(hua)合(he)物(wu),對于(yu)(yu)軋(ya)入(ru)(ru)較(jiao)深的(de)氧(yang)化(hua)亞(ya)銅(tong),當成(cheng)條狀的(de)聚集物(wu)遇模具拉伸時,就會是(shi)銅(tong)桿外表(biao)面產生毛(mao)刺,給后續(xu)的(de)涂漆造成(cheng)麻煩。
而上(shang)引連鑄工藝制(zhi)造的無(wu)氧(yang)銅桿(gan),由于鑄造和(he)冷卻完全與氧(yang)隔絕(jue),后(hou)續亦無(wu)熱軋過程,銅桿(gan)表(biao)面(mian)無(wu)軋入(ru)表(biao)面(mian)的氧(yang)化物,質量較好,拉制(zhi)后(hou)銅粉(fen)少(shao)(shao),上(shang)述問題(ti)較少(shao)(shao)存在。
無(wu)氧銅桿也(ye)分進口(kou)設(she)備(bei)(bei)做的(de)(de)(de)和國產(chan)(chan)設(she)備(bei)(bei)做的(de)(de)(de),但目(mu)前(qian)進口(kou)產(chan)(chan)品(pin)已無(wu)明顯優(you)勢,銅桿產(chan)(chan)品(pin)出來后區別不(bu)是(shi)很大,只要銅板(ban)選的(de)(de)(de)好(hao),生產(chan)(chan)控(kong)制比較穩定,國產(chan)(chan)設(she)備(bei)(bei)也(ye)能產(chan)(chan)出可拉伸0.05的(de)(de)(de)銅桿.進口(kou)設(she)備(bei)(bei)一般(ban)是(shi)芬蘭奧(ao)托(tuo)昆(kun)普的(de)(de)(de)設(she)備(bei)(bei),國產(chan)(chan)設(she)備(bei)(bei)最好(hao)的(de)(de)(de)應該是(shi)上海的(de)(de)(de)海軍廠的(de)(de)(de)了,生產(chan)(chan)時間(jian)最長,軍工企業(ye),質量可靠。
低(di)氧銅桿進口(kou)設備(bei)國際主要有兩(liang)種,一種是(shi)美國南線設備(bei),英文(wen)是(shi)SOUTHWIRE,國內(nei)廠家是(shi)南京華新,江西銅業,另一種是(shi)德國CONTIROD設備(bei),國內(nei)廠家是(shi)常州金源,天津大無縫(feng)。
無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)及低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)從含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)上(shang)(shang)容易區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅是(shi)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)10-20個(ge)PPM以下(xia),但目(mu)前有的(de)(de)(de)(de)(de)廠(chang)家(jia)只能做(zuo)到(dao)50個(ge)PPM以下(xia).低氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)在(zai) 200-400個(ge)PPM,好(hao)的(de)(de)(de)(de)(de)桿(gan)子(zi)(zi)一般含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)控制在(zai)250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)一般采取的(de)(de)(de)(de)(de)是(shi)上(shang)(shang)引法,低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)是(shi)連鑄連軋,兩種(zhong)產品相對(dui)(dui)而(er)言低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)對(dui)(dui)漆包(bao)線(xian)性 能更適應些,如(ru)柔軟(ruan)性,回(hui)彈角(jiao),繞線(xian)性能.但低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)對(dui)(dui)拉絲(si)條件(jian)相對(dui)(dui)要苛刻些,同(tong)樣拉伸(shen)0.2的(de)(de)(de)(de)(de)細絲(si),如(ru)果伸(shen)線(xian)條件(jian)不好(hao),普通的(de)(de)(de)(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)可拉而(er)好(hao)的(de)(de)(de)(de)(de)低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)就(jiu)斷 線(xian),但如(ru)果放在(zai)好(hao)的(de)(de)(de)(de)(de)伸(shen)線(xian)條件(jian),同(tong)樣的(de)(de)(de)(de)(de)桿(gan)子(zi)(zi),低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)說不定就(jiu)能拉到(dao)雙零五,而(er)普通無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)最(zui)(zui)多(duo)只能拉伸(shen)到(dao)0.1而(er)已,當然做(zuo)的(de)(de)(de)(de)(de)最(zui)(zui)細的(de)(de)(de)(de)(de)如(ru)雙零二卻(que)非得依靠進口的(de)(de)(de)(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)了.目(mu)前有企(qi)業嘗試用剝皮的(de)(de)(de)(de)(de)方式來(lai)處理低氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)來(lai)伸(shen)0.03線(xian).但有關這方面的(de)(de)(de)(de)(de)內容我(wo)還不是(shi)很清楚。
音響線一般(ban)反而喜歡用無氧桿(gan),這和無氧桿(gan)是單晶(jing)銅,低氧桿(gan)是多(duo)晶(jing)銅有(you)關(guan)。
氧銅桿和無(wu)氧銅桿由于制造方(fang)法的(de)不同,致(zhi)使存在差別(bie),具有各自的(de)特(te)點。
一、關于氧的吸入(ru)和脫去以及它(ta)的存在(zai)狀態
生(sheng)產銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)溫(wen)下氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)固溶度約2ppm。低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是(shi)在(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)(de)液態下吸入的(de)(de)(de)(de)(de),而(er)上引法無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)相(xiang)(xiang)反,氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態銅(tong)(tong)下保(bao)持相(xiang)(xiang)當時(shi)間后(hou),被還(huan)原而(er)脫去,通(tong)常(chang)這種桿(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量都(dou)在(zai)(zai)10—50ppm以(yi)(yi)(yi)下,最(zui)低(di)(di)可達1-2ppm,從組織上看,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang),以(yi)(yi)(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)狀態,存在(zai)(zai)于(yu)晶粒邊界附近,這對(dui)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)而(er)言(yan)可以(yi)(yi)(yi)說是(shi)常(chang)見(jian)(jian)的(de)(de)(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)很少見(jian)(jian)。氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)以(yi)(yi)(yi)夾雜(za)形式在(zai)(zai)晶界出現對(dui)材料的(de)(de)(de)(de)(de)韌(ren)性產生(sheng)負面(mian)影響。而(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)很低(di)(di),所以(yi)(yi)(yi)這種銅(tong)(tong)的(de)(de)(de)(de)(de)組織是(shi)均(jun)勻的(de)(de)(de)(de)(de)單相(xiang)(xiang)組織對(dui)韌(ren)性有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)(zhong)的(de)(de)(de)(de)(de)多孔性是(shi)不常(chang)見(jian)(jian)的(de)(de)(de)(de)(de),而(er)在(zai)(zai)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)(zhong)則(ze)是(shi)常(chang)見(jian)(jian)的(de)(de)(de)(de)(de)一種缺陷。
二、熱軋組織和鑄(zhu)造組織的區別
低(di)氧銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)由(you)于經(jing)過熱軋,所以(yi)其組(zu)織(zhi)(zhi)(zhi)屬(shu)熱加工組(zu)織(zhi)(zhi)(zhi),原來的(de)(de)(de)鑄造(zao)組(zu)織(zhi)(zhi)(zhi)已(yi)經(jing)破碎,在8mm的(de)(de)(de)桿(gan)(gan)(gan)時(shi)已(yi)有再結晶(jing)的(de)(de)(de)形式出現,而無氧銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)屬(shu)鑄造(zao)組(zu)織(zhi)(zhi)(zhi),晶(jing)粒(li)粗大,這(zhe)是為什么(me),無氧銅(tong)(tong)(tong)(tong)的(de)(de)(de)再結晶(jing)溫(wen)度較(jiao)(jiao)高,需要(yao)較(jiao)(jiao)高退(tui)火(huo)(huo)溫(wen)度的(de)(de)(de)固有原因。這(zhe)是因為,再結晶(jing)發生在晶(jing)粒(li)邊(bian)(bian)界附近,無氧銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)組(zu)織(zhi)(zhi)(zhi)晶(jing)粒(li)粗大,晶(jing)粒(li)尺寸甚至能達幾個毫米(mi),因而晶(jing)粒(li)邊(bian)(bian)界少,即使通(tong)過拉制變形,但晶(jing)粒(li)邊(bian)(bian)界相對(dui)低(di)氧銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)還(huan)是較(jiao)(jiao)少,所以(yi)需要(yao)較(jiao)(jiao)高的(de)(de)(de)退(tui)火(huo)(huo)功率。對(dui)無氧銅(tong)(tong)(tong)(tong)成功的(de)(de)(de)退(tui)火(huo)(huo)要(yao)求是:由(you)桿(gan)(gan)(gan)經(jing)拉制,但尚未(wei)鑄造(zao)組(zu)織(zhi)(zhi)(zhi)的(de)(de)(de)線時(shi)的(de)(de)(de)第一次退(tui)火(huo)(huo),其退(tui)火(huo)(huo)功率應(ying)比同樣情況的(de)(de)(de)低(di)氧銅(tong)(tong)(tong)(tong)高10——15%。經(jing)繼(ji)續拉制,在以(yi)后階(jie)段的(de)(de)(de)退(tui)火(huo)(huo)功率應(ying)留有足夠(gou)的(de)(de)(de)余量和對(dui)低(di)氧銅(tong)(tong)(tong)(tong)和無氧銅(tong)(tong)(tong)(tong)切實區別(bie)執行不同的(de)(de)(de)退(tui)火(huo)(huo)工藝(yi),以(yi)保證在制品和成品導線的(de)(de)(de)柔軟(ruan)性。
三、夾雜,氧含(han)量波動,表(biao)面氧化物和可能存在的(de)熱軋缺陷的(de)差別
無(wu)氧(yang)銅(tong)桿(gan)的(de)(de)(de)可拉性在(zai)所有(you)線(xian)(xian)(xian)徑里(li)與低(di)氧(yang)銅(tong)桿(gan)相(xiang)比(bi)都是優越(yue)的(de)(de)(de),除(chu)上述組織(zhi)原因外(wai),無(wu)氧(yang)銅(tong)桿(gan)夾雜少,含(han)氧(yang)量穩(wen)(wen)定(ding),無(wu)熱軋(ya)可能產(chan)生的(de)(de)(de)缺陷(xian),桿(gan)表氧(yang)化(hua)物(wu)厚度可達≤15A。在(zai)連(lian)(lian)鑄連(lian)(lian)軋(ya)生產(chan)過程中如果工藝不穩(wen)(wen)定(ding),對(dui)(dui)氧(yang)監控(kong)不嚴,含(han)氧(yang)量不穩(wen)(wen)定(ding)將直接影(ying)響桿(gan)的(de)(de)(de)性能。如果桿(gan)的(de)(de)(de)表面氧(yang)化(hua)物(wu)能在(zai)后工序(xu)的(de)(de)(de)連(lian)(lian)續(xu)清洗中得以彌補外(wai),但比(bi)較麻煩的(de)(de)(de)是有(you)相(xiang)當(dang)多的(de)(de)(de)氧(yang)化(hua)物(wu)存在(zai)于“皮(pi)(pi)(pi)(pi)下”,對(dui)(dui)拉線(xian)(xian)(xian)斷(duan)線(xian)(xian)(xian)影(ying)響更直接,故而在(zai)拉制微細線(xian)(xian)(xian),超微細線(xian)(xian)(xian)時(shi),為了減(jian)少斷(duan)線(xian)(xian)(xian),有(you)時(shi)要對(dui)(dui)銅(tong)桿(gan)采取不得已的(de)(de)(de)辦法——剝(bo)皮(pi)(pi)(pi)(pi),甚至二次剝(bo)皮(pi)(pi)(pi)(pi)的(de)(de)(de)原因所在(zai),目的(de)(de)(de)要除(chu)去皮(pi)(pi)(pi)(pi)下氧(yang)化(hua)物(wu)。
四、低氧銅(tong)(tong)桿和無氧銅(tong)(tong)桿的(de)韌性有差(cha)別
兩者(zhe)都可以(yi)拉(la)到0.015mm,但在低(di)溫超(chao)導線中的低(di)溫級無氧銅,其細絲間的間距只有0.001mm.
五、從(cong)制桿的原材料到制線的經濟性(xing)有差別。
制造無(wu)氧銅(tong)桿(gan)要求質量較高的原材料。一般,拉制直(zhi)(zhi)徑(jing)>1mm的銅(tong)線(xian)時,低(di)氧銅(tong)桿(gan)的優(you)點比較明顯,而無(wu)氧銅(tong)桿(gan)顯得更為優(you)越的是拉制直(zhi)(zhi)徑(jing)<0.5mm的銅(tong)線(xian)。
六、低氧銅桿(gan)的制線工(gong)藝(yi)與無氧銅桿(gan)的有所不同。
低氧銅(tong)(tong)桿(gan)的(de)制線工(gong)藝不能照搬到無氧銅(tong)(tong)桿(gan)的(de)制線工(gong)藝上(shang)來,至少(shao)兩者的(de)退火(huo)工(gong)藝是不同的(de)。因為線的(de)柔軟性深受材料成份和制桿(gan),制線和退火(huo)工(gong)藝的(de)影響,不能簡單地說低氧銅(tong)(tong)或(huo)無氧銅(tong)(tong)誰軟誰硬(ying)。
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