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來源:行業動態 閱讀:109283 發布時間:2019-07-05
導讀:由于生產(chan)(chan)(chan)銅(tong)桿(gan)的(de)兩者的(de)工藝不(bu)同(tong)(tong),所生產(chan)(chan)(chan)的(de)銅(tong)桿(gan)中(zhong)的(de)含(han)氧(yang)量及外(wai)觀就不(bu)同(tong)(tong)。上(shang)引(yin)生產(chan)(chan)(chan)的(de)銅(tong)桿(gan),工藝得當氧(yang)含(han)量在(zai)10ppm以下(xia),叫(jiao)無氧(yang)銅(tong)桿(gan);連鑄連鑄生產(chan)(chan)(chan)的(de)銅(tong)桿(gan) 是(shi)在(zai)保護條件(jian)下(xia)的(de)熱軋,氧(yang)含(han)量在(zai)200-500ppm范圍(wei)內(nei),但有(you)時也高達700ppm以上(shang),一般情況下(xia),此種方法生產(chan)(chan)(chan)的(de)銅(tong)外(wai)表光亮,低氧(yang)銅(tong)桿(gan),有(you)時也叫(jiao)光桿(gan)。
銅桿是電纜行(xing)業(ye)的主(zhu)要原料,生產(chan)的方式主(zhu)要有兩種——連(lian)(lian)鑄連(lian)(lian)軋法和上引(yin)連(lian)(lian)鑄法。連(lian)(lian)鑄連(lian)(lian)軋低氧(yang)銅桿的生產(chan)方法較(jiao)多,其特點是金屬在(zai)豎爐(lu)中融化后(hou),銅液通(tong)過保溫爐(lu)、溜槽(cao)、中間(jian)(jian)包,從(cong)澆管進(jin)(jin)入封(feng)閉的模腔內,采用較(jiao)大的冷(leng)卻強(qiang)度(du)進(jin)(jin)行(xing)冷(leng)卻,形(xing)成鑄坯,然后(hou)進(jin)(jin)行(xing)多道(dao)次軋制,生產(chan)的低氧(yang)銅桿為(wei)熱加(jia)工組(zu)織(zhi),原來(lai)的鑄造組(zu)織(zhi)已經破碎,含(han)氧(yang)量(liang)一般為(wei)200~400ppm之間(jian)(jian)。無氧(yang)銅桿國(guo)內基本全部采用上引(yin)連(lian)(lian)鑄法生產(chan),金屬在(zai)感應電爐(lu)中融化后(hou)通(tong)過石(shi)墨(mo)模進(jin)(jin)行(xing)上引(yin)連(lian)(lian)續鑄造,之后(hou)進(jin)(jin)行(xing)冷(leng)軋或冷(leng)加(jia)工,生產(chan)的無氧(yang)銅桿為(wei)鑄造組(zu)織(zhi),含(han)氧(yang)量(liang)一般在(zai)20ppm以下(xia)。由于(yu)制造工藝的不(bu)同(tong),所以在(zai)組(zu)織(zhi)結構、氧(yang)含(han)量(liang)分布(bu)、雜質的形(xing)式及分布(bu)等諸多方面(mian)有較(jiao)大差別。
一、拉制性能
銅桿的(de)拉制性能跟很多因素有關(guan),如(ru)雜質的(de)含(han)量、氧含(han)量及分布、工藝控制等。下面分別從以上幾個方面對(dui)銅桿的(de)拉制性能進(jin)行分析。
1、熔化方式(shi)對(dui)S等(deng)雜質的影(ying)響
連(lian)鑄(zhu)連(lian)軋生產銅(tong)桿(gan)主要是(shi)通過氣體的(de)燃(ran)燒使銅(tong)桿(gan)熔(rong)化(hua),在(zai)燃(ran)燒的(de)過程中(zhong),通過氧化(hua)和(he)揮(hui)發作(zuo)用,可一定程度減(jian)少部分雜質進入(ru)銅(tong)液(ye),因此連(lian)鑄(zhu)連(lian)軋法對原料要求相對低一些。上引連(lian)鑄(zhu)生產無氧銅(tong)桿(gan),由于是(shi)用感應電(dian)(dian)爐熔(rong)化(hua),電(dian)(dian)解銅(tong)表(biao)面的(de)“銅(tong)綠”“銅(tong)豆”基本都熔(rong)入(ru)到銅(tong)液(ye)中(zhong)。其中(zhong)熔(rong)入(ru)的(de)S對無氧銅(tong)桿(gan)塑性影響(xiang)極大,會增加拉(la)絲斷線率(lv)。
2、鑄造過程中雜質的進入
在生產(chan)過(guo)(guo)程(cheng)中,連(lian)鑄(zhu)連(lian)軋(ya)(ya)工藝需通(tong)(tong)過(guo)(guo)保溫爐、溜槽、中間包轉運銅(tong)液(ye),相對容易造成耐(nai)火材料(liao)(liao)的(de)(de)(de)剝落,在軋(ya)(ya)制(zhi)過(guo)(guo)程(cheng)中需要通(tong)(tong)過(guo)(guo)軋(ya)(ya)輥,造成鐵(tie)質(zhi)的(de)(de)(de)脫落,會給銅(tong)桿造成外部夾雜(za)。而熱軋(ya)(ya)中皮上(shang)和皮下氧化物的(de)(de)(de)軋(ya)(ya)入,會給低(di)氧桿的(de)(de)(de)拉絲造成不利的(de)(de)(de)影響(xiang)。上(shang)引連(lian)鑄(zhu)法生產(chan)工藝流(liu)(liu)程(cheng)較(jiao)短,銅(tong)液(ye)是通(tong)(tong)過(guo)(guo)聯體爐內潛流(liu)(liu)式完成,對耐(nai)火材料(liao)(liao)的(de)(de)(de)沖擊不大,結晶是通(tong)(tong)過(guo)(guo)石墨模內進行,所以過(guo)(guo)程(cheng)中可能產(chan)生的(de)(de)(de)污(wu)染源較(jiao)少,雜(za)質(zhi)進入的(de)(de)(de)機會較(jiao)少。
O、S、P是與(yu)銅(tong)會生產(chan)化(hua)(hua)合物的元素。在熔態(tai)銅(tong)中,氧(yang)可(ke)以溶解一部分,但當銅(tong)冷凝(ning)時(shi),氧(yang)幾乎不溶解于銅(tong)中。熔態(tai)時(shi)所溶解的氧(yang),以銅(tong)=氧(yang)化(hua)(hua)亞(ya)銅(tong)共晶體(ti)析出,分布在晶粒晶界(jie)處。銅(tong)-氧(yang)化(hua)(hua)亞(ya)銅(tong)共晶體(ti)的出現,顯著(zhu)降(jiang)低了銅(tong)的塑(su)性。
硫(liu)可以溶解(jie)在(zai)(zai)熔體的銅(tong)(tong)中,但在(zai)(zai)室(shi)溫下,其溶解(jie)度(du)幾乎降低(di)到零(ling),它以硫(liu)化亞銅(tong)(tong)的形式出現在(zai)(zai)晶(jing)(jing)粒晶(jing)(jing)界處(chu),會顯著降低(di)銅(tong)(tong)的塑性。
3、氧(yang)在低氧(yang)銅(tong)桿和(he)無氧(yang)銅(tong)桿中(zhong)分布形式及其影響
氧(yang)(yang)含量對(dui)低氧(yang)(yang)銅桿的(de)(de)拉線(xian)性能有著明(ming)顯的(de)(de)影響。當(dang)氧(yang)(yang)含量增加(jia)到(dao)最佳值時(shi),銅桿的(de)(de)斷線(xian)率最低。這是因(yin)為氧(yang)(yang)在與大部分(fen)雜質反應的(de)(de)過程中都起到(dao)了(le)(le)清除器的(de)(de)作用(yong)。適度的(de)(de)氧(yang)(yang)還有利(li)于(yu)去除銅液(ye)中的(de)(de)氫,生成(cheng)水蒸(zheng)氣溢(yi)出(chu),減少氣孔的(de)(de)形(xing)成(cheng)。最佳的(de)(de)氧(yang)(yang)含量為拉線(xian)工藝提(ti)供了(le)(le)最好(hao)的(de)(de)條件。
低氧(yang)(yang)銅(tong)(tong)桿(gan)氧(yang)(yang)化(hua)(hua)(hua)物(wu)的(de)(de)分(fen)布:在連續澆鑄(zhu)中凝固的(de)(de)最初階段,散熱速率和均勻冷(leng)(leng)卻(que)是(shi)決定銅(tong)(tong)桿(gan)氧(yang)(yang)化(hua)(hua)(hua)物(wu)分(fen)布的(de)(de)主要因素。不(bu)均勻冷(leng)(leng)卻(que)會引(yin)起(qi)銅(tong)(tong)桿(gan)內部結構(gou)本質上的(de)(de)差異,但(dan)后續的(de)(de)熱加工,柱狀晶(jing)通(tong)常會遭到破(po)壞(huai),使氧(yang)(yang)化(hua)(hua)(hua)亞銅(tong)(tong)顆(ke)粒(li)細微化(hua)(hua)(hua)和均勻分(fen)布。氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆(ke)粒(li)聚集而產生(sheng)的(de)(de)典型情(qing)況是(shi)中心爆(bao)裂。除氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆(ke)粒(li)分(fen)布的(de)(de)影響外,具有較(jiao)小氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆(ke)粒(li)的(de)(de)銅(tong)(tong)桿(gan)顯示出較(jiao)好的(de)(de)拉線特性,較(jiao)大的(de)(de)Cu2O顆(ke)粒(li)容易(yi)造成應力集中點而斷裂。
無氧(yang)銅(tong)(tong)(tong)(tong)含(han)氧(yang)量(liang)超標,銅(tong)(tong)(tong)(tong)桿變脆(cui)(cui),延伸率(lv)下(xia)降(jiang),拉(la)伸式(shi)樣(yang)端口顯暗紅色(se),結晶組(zu)織疏松(song)。當(dang)氧(yang)含(han)量(liang)超出8ppm時,工藝性(xing)(xing)能變差,表現為鑄造及拉(la)伸過(guo)程中斷桿及斷線率(lv)極(ji)具增高(gao)。這是由于氧(yang)能與銅(tong)(tong)(tong)(tong)生(sheng)成(cheng)氧(yang)化(hua)亞(ya)銅(tong)(tong)(tong)(tong)脆(cui)(cui)性(xing)(xing)相,形成(cheng)銅(tong)(tong)(tong)(tong)-氧(yang)化(hua)亞(ya)銅(tong)(tong)(tong)(tong)共晶體,以(yi)網狀組(zu)織分(fen)布在境界上(shang)。這種脆(cui)(cui)性(xing)(xing)相硬(ying)度高(gao),在冷變形時將會與銅(tong)(tong)(tong)(tong)機體脫離,導致銅(tong)(tong)(tong)(tong)桿的機械性(xing)(xing)能下(xia)降(jiang),在后續加工中容易造成(cheng)斷裂現象(xiang)。氧(yang)含(han)量(liang)高(gao)還能導致無氧(yang)銅(tong)(tong)(tong)(tong)桿導電率(lv)下(xia)降(jiang)。因此,必須(xu)嚴(yan)格控制上(shang)引連鑄工藝及產品質量(liang)。
4、氫的影響
在(zai)上引連鑄中(zhong),氧含量控制較低(di),氧化(hua)物的(de)副作用唄**降低(di),但氫的(de)影響成(cheng)為(wei)較顯著的(de)問題。吸(xi)氣后熔體中(zhong)存(cun)在(zai)平衡(heng)反應:H2O(g)=[O]+2[H];
氣(qi)體及疏松(song)(song)是(shi)在(zai)(zai)(zai)結晶(jing)的(de)(de)過程(cheng)中(zhong),氫從過飽和的(de)(de)溶液(ye)中(zhong)析(xi)出(chu)并聚集而(er)形(xing)(xing)成(cheng)的(de)(de)。在(zai)(zai)(zai)結晶(jing)前(qian)析(xi)出(chu)的(de)(de)氫又可還原氧化亞(ya)銅(tong)而(er)生成(cheng)水氣(qi)泡。由于(yu)上(shang)引鑄造的(de)(de)特點是(shi)銅(tong)液(ye)自上(shang)而(er)下(xia)的(de)(de)結晶(jing),形(xing)(xing)成(cheng)的(de)(de)液(ye)**形(xing)(xing)狀(zhuang)近似錐型(xing)。銅(tong)液(ye)結晶(jing)前(qian)析(xi)出(chu)的(de)(de)氣(qi)體在(zai)(zai)(zai)上(shang)浮過程(cheng)中(zhong)被堵在(zai)(zai)(zai)凝固(gu)組(zu)織內,結晶(jing)時在(zai)(zai)(zai)鑄桿內形(xing)(xing)成(cheng)氣(qi)孔。上(shang)引的(de)(de)含氣(qi)量少時,析(xi)出(chu)的(de)(de)氫存在(zai)(zai)(zai)于(yu)晶(jing)界(jie)處(chu),形(xing)(xing)成(cheng)疏松(song)(song);含氣(qi)量多(duo)時,則聚集成(cheng)氣(qi)孔,因此,氣(qi)孔和疏松(song)(song)是(shi)氫氣(qi)和水蒸氣(qi)兩者形(xing)(xing)成(cheng)的(de)(de)。
氫來源(yuan)于上(shang)引(yin)生產過(guo)程中的各(ge)個工藝環節,如原料電解銅(tong)(tong)(tong)(tong)(tong)的“銅(tong)(tong)(tong)(tong)(tong)綠(lv)”、輔(fu)料木(mu)炭(tan)**、氣候環境**、石墨結(jie)晶(jing)器未干燥(zao)等。因此,熔化(hua)爐中的銅(tong)(tong)(tong)(tong)(tong)液表面應覆蓋經烘烤的木(mu)炭(tan),電解銅(tong)(tong)(tong)(tong)(tong)應盡量去除“銅(tong)(tong)(tong)(tong)(tong)綠(lv)”、“銅(tong)(tong)(tong)(tong)(tong)豆”“耳朵(duo)”,對提高無氧(yang)銅(tong)(tong)(tong)(tong)(tong)桿質(zhi)量非常重要。
在連鑄連軋工藝中(zhong),往(wang)往(wang)采(cai)用適度控制氧(yang)含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液(ye)在鑄(zhu)造過程中(zhong)(zhong)是自下而(er)上結晶,銅(tong)液(ye)中(zhong)(zhong)的(de)氧和氫(qing)所產生的(de)水(shui)蒸氣很容(rong)易上浮跑出,銅(tong)液(ye)中(zhong)(zhong)的(de)氫(qing)大部分能被有效去(qu)除,因而(er)對銅(tong)桿(gan)的(de)影響(xiang)較小。
二、表面質量
在生產電磁(ci)線(xian)等產品(pin)的過(guo)程中,對(dui)銅桿(gan)的表面(mian)質(zhi)量(liang)(liang)也需(xu)提出要(yao)求。需(xu)要(yao)拉制后的銅絲表面(mian)無毛(mao)刺、銅粉(fen)少、無油污。并通過(guo)扭(niu)(niu)轉(zhuan)試驗(yan)測(ce)量(liang)(liang)表面(mian)銅粉(fen)的質(zhi)量(liang)(liang)和扭(niu)(niu)轉(zhuan)后觀察銅桿(gan)的復原情況來(lai)判定其好壞。
在(zai)(zai)連鑄連軋(ya)(ya)過(guo)(guo)程中(zhong),從鑄造到軋(ya)(ya)制(zhi)前,溫(wen)度高,完全暴露于(yu)空氣(qi)中(zhong),使鑄坯表面形成(cheng)較(jiao)厚的氧(yang)(yang)化(hua)層,在(zai)(zai)軋(ya)(ya)制(zhi)過(guo)(guo)程中(zhong),隨著軋(ya)(ya)輥的轉動,氧(yang)(yang)化(hua)物顆粒軋(ya)(ya)入銅線表面。由于(yu)氧(yang)(yang)化(hua)亞(ya)銅是(shi)高熔(rong)點脆(cui)性化(hua)合物,對于(yu)軋(ya)(ya)入較(jiao)深的氧(yang)(yang)化(hua)亞(ya)銅,當成(cheng)條狀的聚集物遇模(mo)具(ju)拉伸(shen)時,就會是(shi)銅桿外表面產生毛(mao)刺,給(gei)后續的涂漆造成(cheng)麻煩。
而上(shang)引連(lian)鑄工藝(yi)制造的(de)無(wu)氧(yang)(yang)(yang)銅桿(gan),由于(yu)鑄造和冷卻(que)完全與氧(yang)(yang)(yang)隔絕,后(hou)續亦無(wu)熱軋過程,銅桿(gan)表面(mian)無(wu)軋入表面(mian)的(de)氧(yang)(yang)(yang)化物,質量(liang)較好,拉制后(hou)銅粉少(shao)(shao),上(shang)述問題較少(shao)(shao)存在。
無氧銅(tong)桿也分進口(kou)設備(bei)做的和國產(chan)(chan)設備(bei)做的,但目前進口(kou)產(chan)(chan)品(pin)已無明(ming)顯優勢,銅(tong)桿產(chan)(chan)品(pin)出(chu)來后區別(bie)不是很大,只(zhi)要銅(tong)板(ban)選的好,生產(chan)(chan)控(kong)制比(bi)較穩定(ding),國產(chan)(chan)設備(bei)也能產(chan)(chan)出(chu)可拉伸0.05的銅(tong)桿.進口(kou)設備(bei)一(yi)般是芬蘭奧(ao)托昆普的設備(bei),國產(chan)(chan)設備(bei)最(zui)好的應該是上(shang)海的海軍廠的了,生產(chan)(chan)時間(jian)最(zui)長,軍工企業,質量可靠。
低氧銅桿進(jin)口設備國際(ji)主要(yao)有兩種(zhong)(zhong),一種(zhong)(zhong)是(shi)(shi)(shi)美國南線設備,英(ying)文(wen)是(shi)(shi)(shi)SOUTHWIRE,國內廠(chang)家是(shi)(shi)(shi)南京(jing)華新(xin),江西銅業,另一種(zhong)(zhong)是(shi)(shi)(shi)德(de)國CONTIROD設備,國內廠(chang)家是(shi)(shi)(shi)常州金源,天津大無(wu)縫。
無氧(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)量(liang)上容(rong)易區別,無氧(yang)(yang)(yang)銅(tong)是含(han)氧(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)(ge)PPM以(yi)下(xia)(xia),但(dan)(dan)目(mu)前(qian)有的(de)(de)(de)廠家只能做到50個(ge)(ge)PPM以(yi)下(xia)(xia).低(di)(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)(ge)PPM,好(hao)的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子(zi)一(yi)般含(han)氧(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個(ge)(ge)PPM左右,無氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)一(yi)般采取的(de)(de)(de)是上引法,低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)是連(lian)鑄(zhu)連(lian)軋,兩種產(chan)品相(xiang)對(dui)(dui)而(er)言低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對(dui)(dui)漆(qi)包線(xian)(xian)(xian)性(xing) 能更(geng)適應些,如(ru)柔軟性(xing),回彈角,繞線(xian)(xian)(xian)性(xing)能.但(dan)(dan)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對(dui)(dui)拉(la)(la)絲條(tiao)(tiao)件相(xiang)對(dui)(dui)要(yao)苛(ke)刻些,同樣拉(la)(la)伸0.2的(de)(de)(de)細(xi)絲,如(ru)果伸線(xian)(xian)(xian)條(tiao)(tiao)件不好(hao),普(pu)通的(de)(de)(de)無氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)可拉(la)(la)而(er)好(hao)的(de)(de)(de)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)就斷 線(xian)(xian)(xian),但(dan)(dan)如(ru)果放在(zai)(zai)好(hao)的(de)(de)(de)伸線(xian)(xian)(xian)條(tiao)(tiao)件,同樣的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子(zi),低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)說不定就能拉(la)(la)到雙零(ling)五(wu),而(er)普(pu)通無氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)最多(duo)只能拉(la)(la)伸到0.1而(er)已(yi),當然做的(de)(de)(de)最細(xi)的(de)(de)(de)如(ru)雙零(ling)二卻非得依靠(kao)進口的(de)(de)(de) 無氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)了.目(mu)前(qian)有企業嘗試用(yong)剝皮的(de)(de)(de)方式來處理低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)來伸0.03線(xian)(xian)(xian).但(dan)(dan)有關這方面的(de)(de)(de)內容(rong)我還不是很清楚。
音響(xiang)線(xian)一般反而喜(xi)歡(huan)用(yong)無氧(yang)(yang)(yang)桿(gan),這和無氧(yang)(yang)(yang)桿(gan)是(shi)單晶(jing)銅(tong),低氧(yang)(yang)(yang)桿(gan)是(shi)多晶(jing)銅(tong)有關(guan)。
氧銅(tong)桿(gan)和(he)無氧銅(tong)桿(gan)由于(yu)制造方法的不同,致使存在差別(bie),具(ju)有各(ge)自的特(te)點。
一、關于氧的吸入和脫去以(yi)及它的存在狀(zhuang)態(tai)
生產(chan)(chan)銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)量一(yi)般在(zai)10—50ppm,在(zai)常溫下(xia)氧(yang)(yang)在(zai)銅(tong)(tong)中的(de)(de)(de)(de)(de)(de)固溶度約2ppm。低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)量一(yi)般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)(de)(de)(de)(de)進入(ru)是(shi)在(zai)銅(tong)(tong)的(de)(de)(de)(de)(de)(de)液(ye)態(tai)下(xia)吸入(ru)的(de)(de)(de)(de)(de)(de),而上(shang)引(yin)法無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)則(ze)相(xiang)(xiang)反,氧(yang)(yang)在(zai)液(ye)態(tai)銅(tong)(tong)下(xia)保持相(xiang)(xiang)當時間(jian)后,被還原而脫去,通(tong)常這種桿(gan)(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)量都(dou)在(zai)10—50ppm以下(xia),最低可達(da)1-2ppm,從組織(zhi)(zhi)上(shang)看,低氧(yang)(yang)銅(tong)(tong)中的(de)(de)(de)(de)(de)(de)氧(yang)(yang),以氧(yang)(yang)化銅(tong)(tong)狀態(tai),存(cun)在(zai)于晶粒邊界(jie)附近,這對低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)而言可以說是(shi)常見的(de)(de)(de)(de)(de)(de)但對無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)則(ze)很(hen)少見。氧(yang)(yang)化銅(tong)(tong)以夾雜形(xing)式在(zai)晶界(jie)出現對材料(liao)的(de)(de)(de)(de)(de)(de)韌(ren)性產(chan)(chan)生負面影(ying)響。而無(wu)氧(yang)(yang)銅(tong)(tong)中的(de)(de)(de)(de)(de)(de)氧(yang)(yang)很(hen)低,所以這種銅(tong)(tong)的(de)(de)(de)(de)(de)(de)組織(zhi)(zhi)是(shi)均勻(yun)的(de)(de)(de)(de)(de)(de)單相(xiang)(xiang)組織(zhi)(zhi)對韌(ren)性有(you)利。在(zai)無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)(de)(de)多孔(kong)性是(shi)不常見的(de)(de)(de)(de)(de)(de),而在(zai)低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)中則(ze)是(shi)常見的(de)(de)(de)(de)(de)(de)一(yi)種缺(que)陷。
二、熱軋(ya)組(zu)(zu)織(zhi)和鑄造組(zu)(zu)織(zhi)的區別
低(di)氧(yang)(yang)銅(tong)(tong)(tong)桿由(you)于經過熱(re)軋,所以其組(zu)(zu)(zu)織(zhi)屬(shu)熱(re)加工(gong)組(zu)(zu)(zu)織(zhi),原來的(de)(de)(de)(de)鑄(zhu)造組(zu)(zu)(zu)織(zhi)已經破碎(sui),在(zai)(zai)8mm的(de)(de)(de)(de)桿時已有再結晶(jing)(jing)(jing)的(de)(de)(de)(de)形式出現(xian),而無(wu)(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿屬(shu)鑄(zhu)造組(zu)(zu)(zu)織(zhi),晶(jing)(jing)(jing)粒(li)粗大(da),這是為(wei)什么,無(wu)(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)的(de)(de)(de)(de)再結晶(jing)(jing)(jing)溫度較(jiao)高,需要(yao)較(jiao)高退(tui)(tui)(tui)火溫度的(de)(de)(de)(de)固有原因(yin)(yin)。這是因(yin)(yin)為(wei),再結晶(jing)(jing)(jing)發生在(zai)(zai)晶(jing)(jing)(jing)粒(li)邊界附近(jin),無(wu)(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿組(zu)(zu)(zu)織(zhi)晶(jing)(jing)(jing)粒(li)粗大(da),晶(jing)(jing)(jing)粒(li)尺寸甚(shen)至能達幾個毫米,因(yin)(yin)而晶(jing)(jing)(jing)粒(li)邊界少,即使通過拉(la)(la)制變形,但晶(jing)(jing)(jing)粒(li)邊界相對(dui)低(di)氧(yang)(yang)銅(tong)(tong)(tong)桿還是較(jiao)少,所以需要(yao)較(jiao)高的(de)(de)(de)(de)退(tui)(tui)(tui)火功(gong)率。對(dui)無(wu)(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)成功(gong)的(de)(de)(de)(de)退(tui)(tui)(tui)火要(yao)求是:由(you)桿經拉(la)(la)制,但尚未鑄(zhu)造組(zu)(zu)(zu)織(zhi)的(de)(de)(de)(de)線(xian)時的(de)(de)(de)(de)第(di)一次退(tui)(tui)(tui)火,其退(tui)(tui)(tui)火功(gong)率應比同樣情況(kuang)的(de)(de)(de)(de)低(di)氧(yang)(yang)銅(tong)(tong)(tong)高10——15%。經繼續拉(la)(la)制,在(zai)(zai)以后(hou)階段的(de)(de)(de)(de)退(tui)(tui)(tui)火功(gong)率應留有足夠(gou)的(de)(de)(de)(de)余量(liang)和對(dui)低(di)氧(yang)(yang)銅(tong)(tong)(tong)和無(wu)(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)切(qie)實區別執行不(bu)同的(de)(de)(de)(de)退(tui)(tui)(tui)火工(gong)藝,以保證在(zai)(zai)制品和成品導線(xian)的(de)(de)(de)(de)柔(rou)軟性。
三、夾(jia)雜,氧(yang)含量波動,表面氧(yang)化物和可能存(cun)在(zai)的熱軋缺陷(xian)的差別
無氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)(de)(de)可(ke)拉性在(zai)(zai)所有(you)線徑里與低氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)相(xiang)比都是優越的(de)(de)(de)(de),除(chu)上述組織原因外,無氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)夾雜少,含氧(yang)(yang)(yang)量(liang)穩定,無熱軋(ya)可(ke)能(neng)產生(sheng)的(de)(de)(de)(de)缺(que)陷(xian),桿(gan)(gan)表氧(yang)(yang)(yang)化(hua)(hua)物(wu)厚(hou)度可(ke)達≤15A。在(zai)(zai)連鑄(zhu)連軋(ya)生(sheng)產過程中如(ru)果(guo)工藝不(bu)穩定,對氧(yang)(yang)(yang)監控(kong)不(bu)嚴(yan),含氧(yang)(yang)(yang)量(liang)不(bu)穩定將直接(jie)影響(xiang)桿(gan)(gan)的(de)(de)(de)(de)性能(neng)。如(ru)果(guo)桿(gan)(gan)的(de)(de)(de)(de)表面氧(yang)(yang)(yang)化(hua)(hua)物(wu)能(neng)在(zai)(zai)后工序的(de)(de)(de)(de)連續清洗中得以(yi)彌(mi)補外,但比較麻(ma)煩的(de)(de)(de)(de)是有(you)相(xiang)當多的(de)(de)(de)(de)氧(yang)(yang)(yang)化(hua)(hua)物(wu)存在(zai)(zai)于“皮下(xia)”,對拉線斷(duan)線影響(xiang)更直接(jie),故而在(zai)(zai)拉制微(wei)細線,超微(wei)細線時(shi),為了減少斷(duan)線,有(you)時(shi)要(yao)對銅(tong)桿(gan)(gan)采取不(bu)得已的(de)(de)(de)(de)辦法——剝(bo)皮,甚至二次剝(bo)皮的(de)(de)(de)(de)原因所在(zai)(zai),目的(de)(de)(de)(de)要(yao)除(chu)去皮下(xia)氧(yang)(yang)(yang)化(hua)(hua)物(wu)。
四、低氧銅(tong)桿(gan)和無氧銅(tong)桿(gan)的韌性有差(cha)別
兩者都可以拉到(dao)0.015mm,但在低溫(wen)超導線中的低溫(wen)級無氧銅,其細(xi)絲間的間距只有0.001mm.
五、從制(zhi)桿(gan)的原材料到制(zhi)線(xian)的經濟(ji)性(xing)有差(cha)別。
制造無氧銅桿(gan)要求質量(liang)較高(gao)的(de)原材料。一般,拉制直(zhi)徑>1mm的(de)銅線時(shi),低氧銅桿(gan)的(de)優(you)點(dian)比(bi)較明顯,而無氧銅桿(gan)顯得更為優(you)越(yue)的(de)是拉制直(zhi)徑<0.5mm的(de)銅線。
六、低氧銅(tong)桿的制線工藝與無氧銅(tong)桿的有所不同。
低(di)氧銅桿的(de)(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)(yi)不能照搬到無氧銅桿的(de)(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)(yi)上來,至(zhi)少(shao)兩(liang)者(zhe)的(de)(de)退火(huo)工(gong)(gong)藝(yi)(yi)是不同(tong)的(de)(de)。因為線(xian)的(de)(de)柔軟性深受材料成份和制(zhi)(zhi)桿,制(zhi)(zhi)線(xian)和退火(huo)工(gong)(gong)藝(yi)(yi)的(de)(de)影響,不能簡單地說低(di)氧銅或(huo)無氧銅誰軟誰硬(ying)。