熱門關鍵(jian)詞:
來源:行業動(dong)態 閱讀:109262 發布時間:2019-07-05
導(dao)讀(du):由于生(sheng)(sheng)產(chan)銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)兩(liang)者的(de)(de)工藝(yi)不(bu)同,所(suo)生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)含氧(yang)量(liang)(liang)及(ji)外觀就不(bu)同。上(shang)引生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)桿(gan)(gan),工藝(yi)得(de)當氧(yang)含量(liang)(liang)在10ppm以(yi)下,叫無氧(yang)銅(tong)(tong)(tong)桿(gan)(gan);連鑄(zhu)(zhu)連鑄(zhu)(zhu)生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)桿(gan)(gan) 是在保護條件(jian)下的(de)(de)熱軋,氧(yang)含量(liang)(liang)在200-500ppm范圍內,但有(you)時(shi)也高達700ppm以(yi)上(shang),一般(ban)情(qing)況下,此種(zhong)方(fang)法(fa)生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)外表光(guang)亮,低氧(yang)銅(tong)(tong)(tong)桿(gan)(gan),有(you)時(shi)也叫光(guang)桿(gan)(gan)。
銅桿是(shi)電纜行業的(de)(de)(de)主要原(yuan)料,生產(chan)(chan)的(de)(de)(de)方式主要有(you)兩種——連鑄(zhu)(zhu)(zhu)連軋法和(he)上(shang)(shang)引連鑄(zhu)(zhu)(zhu)法。連鑄(zhu)(zhu)(zhu)連軋低氧(yang)銅桿的(de)(de)(de)生產(chan)(chan)方法較多,其特點是(shi)金屬在(zai)(zai)(zai)豎爐(lu)(lu)中(zhong)融(rong)化后,銅液(ye)通過保(bao)溫爐(lu)(lu)、溜槽、中(zhong)間(jian)包,從(cong)澆(jiao)管進(jin)(jin)入(ru)封閉的(de)(de)(de)模腔(qiang)內(nei),采用(yong)較大的(de)(de)(de)冷(leng)卻強度(du)進(jin)(jin)行冷(leng)卻,形(xing)成鑄(zhu)(zhu)(zhu)坯,然后進(jin)(jin)行多道次軋制,生產(chan)(chan)的(de)(de)(de)低氧(yang)銅桿為熱加工組織(zhi),原(yuan)來的(de)(de)(de)鑄(zhu)(zhu)(zhu)造(zao)組織(zhi)已經破碎,含(han)氧(yang)量一般(ban)為200~400ppm之間(jian)。無氧(yang)銅桿國內(nei)基本(ben)全部采用(yong)上(shang)(shang)引連鑄(zhu)(zhu)(zhu)法生產(chan)(chan),金屬在(zai)(zai)(zai)感(gan)應電爐(lu)(lu)中(zhong)融(rong)化后通過石(shi)墨模進(jin)(jin)行上(shang)(shang)引連續鑄(zhu)(zhu)(zhu)造(zao),之后進(jin)(jin)行冷(leng)軋或冷(leng)加工,生產(chan)(chan)的(de)(de)(de)無氧(yang)銅桿為鑄(zhu)(zhu)(zhu)造(zao)組織(zhi),含(han)氧(yang)量一般(ban)在(zai)(zai)(zai)20ppm以下。由(you)于制造(zao)工藝的(de)(de)(de)不同,所以在(zai)(zai)(zai)組織(zhi)結構(gou)、氧(yang)含(han)量分布、雜質的(de)(de)(de)形(xing)式及分布等(deng)諸多方面有(you)較大差別。
一、拉制性能
銅(tong)桿(gan)的(de)拉制性(xing)能(neng)(neng)跟很多(duo)因(yin)素(su)有關,如雜(za)質(zhi)的(de)含量(liang)、氧含量(liang)及(ji)分布、工(gong)藝控制等(deng)。下面分別從以上(shang)幾個(ge)方面對銅(tong)桿(gan)的(de)拉制性(xing)能(neng)(neng)進行分析。
1、熔化(hua)方(fang)式對S等雜質的影響
連鑄(zhu)(zhu)連軋生產銅(tong)(tong)桿主要是通過氣體的(de)燃燒使(shi)銅(tong)(tong)桿熔化,在(zai)燃燒的(de)過程(cheng)中,通過氧(yang)化和揮發作(zuo)用(yong),可(ke)一(yi)定(ding)程(cheng)度減少部分雜(za)質進入銅(tong)(tong)液,因此連鑄(zhu)(zhu)連軋法對原(yuan)料(liao)要求相對低(di)一(yi)些。上引連鑄(zhu)(zhu)生產無氧(yang)銅(tong)(tong)桿,由(you)于是用(yong)感(gan)應(ying)電(dian)(dian)爐熔化,電(dian)(dian)解銅(tong)(tong)表面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆(dou)”基本都(dou)熔入到(dao)銅(tong)(tong)液中。其(qi)中熔入的(de)S對無氧(yang)銅(tong)(tong)桿塑性影響極大,會增加拉絲斷線(xian)率。
2、鑄造過程(cheng)中雜(za)質的(de)進入(ru)
在生(sheng)(sheng)產過程(cheng)中(zhong),連(lian)鑄連(lian)軋(ya)工(gong)藝(yi)需通過保溫爐(lu)、溜(liu)槽、中(zhong)間包轉運銅液(ye),相對(dui)容易(yi)造(zao)成耐(nai)火(huo)材(cai)料的(de)(de)(de)(de)剝落,在軋(ya)制(zhi)過程(cheng)中(zhong)需要通過軋(ya)輥,造(zao)成鐵質的(de)(de)(de)(de)脫落,會(hui)給銅桿造(zao)成外部夾雜。而熱軋(ya)中(zhong)皮上和皮下氧(yang)化物(wu)的(de)(de)(de)(de)軋(ya)入,會(hui)給低氧(yang)桿的(de)(de)(de)(de)拉(la)絲造(zao)成不利的(de)(de)(de)(de)影響。上引(yin)連(lian)鑄法生(sheng)(sheng)產工(gong)藝(yi)流程(cheng)較(jiao)短,銅液(ye)是通過聯體爐(lu)內潛流式完成,對(dui)耐(nai)火(huo)材(cai)料的(de)(de)(de)(de)沖擊不大(da),結(jie)晶是通過石墨模內進(jin)行(xing),所以過程(cheng)中(zhong)可能產生(sheng)(sheng)的(de)(de)(de)(de)污染源(yuan)較(jiao)少(shao),雜質進(jin)入的(de)(de)(de)(de)機(ji)會(hui)較(jiao)少(shao)。
O、S、P是與銅(tong)會生產(chan)化(hua)(hua)合物的元(yuan)素(su)。在熔態(tai)銅(tong)中(zhong),氧(yang)(yang)可以(yi)溶(rong)解一部分,但當銅(tong)冷凝時,氧(yang)(yang)幾乎不(bu)溶(rong)解于銅(tong)中(zhong)。熔態(tai)時所溶(rong)解的氧(yang)(yang),以(yi)銅(tong)=氧(yang)(yang)化(hua)(hua)亞(ya)銅(tong)共(gong)晶體析出,分布在晶粒(li)晶界處。銅(tong)-氧(yang)(yang)化(hua)(hua)亞(ya)銅(tong)共(gong)晶體的出現,顯著降(jiang)低了銅(tong)的塑性。
硫可以(yi)(yi)溶解(jie)在熔體的銅中,但在室溫下,其溶解(jie)度幾乎降低(di)到零(ling),它(ta)以(yi)(yi)硫化亞銅的形(xing)式出現在晶粒(li)晶界處,會顯著降低(di)銅的塑性。
3、氧在低氧銅桿和無(wu)氧銅桿中分(fen)布形式及其影響
氧(yang)(yang)含(han)量(liang)對低(di)氧(yang)(yang)銅桿的(de)(de)拉線(xian)性能有(you)著明顯的(de)(de)影響(xiang)。當(dang)氧(yang)(yang)含(han)量(liang)增加(jia)到最佳值(zhi)時,銅桿的(de)(de)斷線(xian)率最低(di)。這(zhe)是(shi)因為氧(yang)(yang)在與大部分雜(za)質(zhi)反應的(de)(de)過程中(zhong)都(dou)起到了清除(chu)器的(de)(de)作(zuo)用。適度(du)的(de)(de)氧(yang)(yang)還有(you)利于(yu)去除(chu)銅液中(zhong)的(de)(de)氫(qing),生成水蒸氣溢(yi)出(chu),減少氣孔的(de)(de)形成。最佳的(de)(de)氧(yang)(yang)含(han)量(liang)為拉線(xian)工藝提供了最好的(de)(de)條件。
低(di)氧(yang)銅桿(gan)氧(yang)化(hua)(hua)(hua)物的(de)(de)(de)分(fen)布(bu):在連續(xu)(xu)澆鑄中凝固(gu)的(de)(de)(de)最初階段,散熱(re)速率(lv)和(he)均勻(yun)冷卻是決定銅桿(gan)氧(yang)化(hua)(hua)(hua)物分(fen)布(bu)的(de)(de)(de)主(zhu)要因素。不均勻(yun)冷卻會引起(qi)銅桿(gan)內部結構本質上的(de)(de)(de)差異(yi),但(dan)后續(xu)(xu)的(de)(de)(de)熱(re)加工,柱狀晶通常會遭(zao)到破壞,使氧(yang)化(hua)(hua)(hua)亞(ya)銅顆粒(li)(li)細(xi)微(wei)化(hua)(hua)(hua)和(he)均勻(yun)分(fen)布(bu)。氧(yang)化(hua)(hua)(hua)物顆粒(li)(li)聚集而(er)產生(sheng)的(de)(de)(de)典型情況是中心爆(bao)裂(lie)。除氧(yang)化(hua)(hua)(hua)物顆粒(li)(li)分(fen)布(bu)的(de)(de)(de)影響外(wai),具有較小氧(yang)化(hua)(hua)(hua)物顆粒(li)(li)的(de)(de)(de)銅桿(gan)顯示(shi)出較好的(de)(de)(de)拉線(xian)特性(xing),較大的(de)(de)(de)Cu2O顆粒(li)(li)容(rong)易(yi)造成應力集中點而(er)斷裂(lie)。
無(wu)氧(yang)銅含氧(yang)量超(chao)標,銅桿(gan)變脆(cui),延伸率(lv)下降(jiang),拉伸式樣端口顯暗紅(hong)色,結晶(jing)組織疏松。當氧(yang)含量超(chao)出(chu)8ppm時(shi),工藝性能變差,表現為鑄造(zao)及拉伸過程中斷(duan)桿(gan)及斷(duan)線率(lv)極具增高。這(zhe)是(shi)由于(yu)氧(yang)能與銅生成氧(yang)化(hua)亞(ya)銅脆(cui)性相(xiang),形成銅-氧(yang)化(hua)亞(ya)銅共晶(jing)體,以網狀組織分布在境界上。這(zhe)種脆(cui)性相(xiang)硬度高,在冷變形時(shi)將會與銅機(ji)體脫離,導致銅桿(gan)的機(ji)械性能下降(jiang),在后續加工中容(rong)易造(zao)成斷(duan)裂現象。氧(yang)含量高還能導致無(wu)氧(yang)銅桿(gan)導電率(lv)下降(jiang)。因此(ci),必(bi)須嚴格控制上引連(lian)鑄工藝及產品質量。
4、氫的影響
在上引連鑄中(zhong),氧含量控制較低,氧化物的(de)副作(zuo)用(yong)唄**降低,但氫的(de)影響(xiang)成(cheng)為較顯著的(de)問題(ti)。吸氣后熔體中(zhong)存在平衡(heng)反應:H2O(g)=[O]+2[H];
氣(qi)(qi)體及疏(shu)松是在(zai)(zai)結晶(jing)的(de)(de)過(guo)程中,氫(qing)從過(guo)飽和的(de)(de)溶(rong)液(ye)中析出(chu)并(bing)聚集而(er)形(xing)成(cheng)(cheng)的(de)(de)。在(zai)(zai)結晶(jing)前析出(chu)的(de)(de)氫(qing)又可還(huan)原氧(yang)化(hua)亞銅而(er)生成(cheng)(cheng)水氣(qi)(qi)泡(pao)。由(you)于上(shang)引鑄造的(de)(de)特點是銅液(ye)自上(shang)而(er)下(xia)的(de)(de)結晶(jing),形(xing)成(cheng)(cheng)的(de)(de)液(ye)**形(xing)狀近似錐型。銅液(ye)結晶(jing)前析出(chu)的(de)(de)氣(qi)(qi)體在(zai)(zai)上(shang)浮過(guo)程中被堵在(zai)(zai)凝固組織內(nei),結晶(jing)時(shi)(shi)(shi)在(zai)(zai)鑄桿內(nei)形(xing)成(cheng)(cheng)氣(qi)(qi)孔。上(shang)引的(de)(de)含氣(qi)(qi)量少時(shi)(shi)(shi),析出(chu)的(de)(de)氫(qing)存(cun)在(zai)(zai)于晶(jing)界處(chu),形(xing)成(cheng)(cheng)疏(shu)松;含氣(qi)(qi)量多時(shi)(shi)(shi),則聚集成(cheng)(cheng)氣(qi)(qi)孔,因此,氣(qi)(qi)孔和疏(shu)松是氫(qing)氣(qi)(qi)和水蒸氣(qi)(qi)兩者形(xing)成(cheng)(cheng)的(de)(de)。
氫來源于上(shang)引生產過程中的各個工藝環節,如原料電(dian)解銅的“銅綠”、輔(fu)料木炭**、氣(qi)候環境(jing)**、石墨結晶(jing)器未干(gan)燥等(deng)。因此,熔化爐中的銅液表面應(ying)覆蓋經烘烤(kao)的木炭,電(dian)解銅應(ying)盡(jin)量(liang)去除“銅綠”、“銅豆”“耳(er)朵”,對(dui)提高無氧(yang)銅桿質(zhi)量(liang)非常重要。
在連(lian)鑄連(lian)軋工藝中,往(wang)(wang)往(wang)(wang)采(cai)用適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅(tong)液(ye)在鑄造過(guo)程中是自下而(er)(er)上結晶,銅(tong)液(ye)中的氧(yang)和氫(qing)所(suo)產生的水蒸氣很容(rong)易上浮跑出,銅(tong)液(ye)中的氫(qing)大部(bu)分能被有(you)效去除,因而(er)(er)對銅(tong)桿的影響較(jiao)小。
二、表面質量
在(zai)生(sheng)產電(dian)磁(ci)線等產品的過程中,對銅桿的表(biao)面質量也需提出要求。需要拉制后的銅絲表(biao)面無毛(mao)刺(ci)、銅粉(fen)少、無油污。并通過扭轉(zhuan)試驗測量表(biao)面銅粉(fen)的質量和扭轉(zhuan)后觀察銅桿的復原情(qing)況來判(pan)定其(qi)好壞。
在連(lian)鑄(zhu)連(lian)軋(ya)(ya)過(guo)程(cheng)中,從鑄(zhu)造到軋(ya)(ya)制(zhi)(zhi)前,溫(wen)度高(gao)(gao),完全暴(bao)露于空氣(qi)中,使鑄(zhu)坯表面形(xing)成(cheng)較厚的(de)氧化(hua)層,在軋(ya)(ya)制(zhi)(zhi)過(guo)程(cheng)中,隨著軋(ya)(ya)輥的(de)轉動(dong),氧化(hua)物顆粒軋(ya)(ya)入銅(tong)線表面。由于氧化(hua)亞(ya)(ya)銅(tong)是(shi)高(gao)(gao)熔點(dian)脆性化(hua)合物,對于軋(ya)(ya)入較深的(de)氧化(hua)亞(ya)(ya)銅(tong),當成(cheng)條(tiao)狀的(de)聚(ju)集物遇模具(ju)拉伸時,就會是(shi)銅(tong)桿外表面產(chan)生(sheng)毛刺,給(gei)后續的(de)涂漆造成(cheng)麻(ma)煩。
而上引連鑄工藝制造的無(wu)氧(yang)銅桿(gan),由于鑄造和冷卻完全與氧(yang)隔絕,后(hou)續亦(yi)無(wu)熱(re)軋過程,銅桿(gan)表面無(wu)軋入表面的氧(yang)化物(wu),質量較(jiao)好,拉(la)制后(hou)銅粉少,上述問題較(jiao)少存(cun)在(zai)。
無氧銅(tong)桿也分進(jin)口(kou)設(she)(she)備做(zuo)的(de)和國產(chan)(chan)設(she)(she)備做(zuo)的(de),但目前進(jin)口(kou)產(chan)(chan)品已無明顯優(you)勢,銅(tong)桿產(chan)(chan)品出(chu)(chu)來后區別不是很大,只要(yao)銅(tong)板選的(de)好,生(sheng)產(chan)(chan)控制(zhi)比較穩定,國產(chan)(chan)設(she)(she)備也能(neng)產(chan)(chan)出(chu)(chu)可拉伸0.05的(de)銅(tong)桿.進(jin)口(kou)設(she)(she)備一般是芬蘭奧托昆普的(de)設(she)(she)備,國產(chan)(chan)設(she)(she)備最好的(de)應該是上海的(de)海軍廠的(de)了,生(sheng)產(chan)(chan)時間最長,軍工企業,質量可靠。
低(di)氧銅(tong)桿進口設(she)備國(guo)(guo)際主要(yao)有兩種(zhong),一種(zhong)是美國(guo)(guo)南線(xian)設(she)備,英文是SOUTHWIRE,國(guo)(guo)內(nei)廠(chang)家(jia)是南京(jing)華新,江西銅(tong)業,另一種(zhong)是德(de)國(guo)(guo)CONTIROD設(she)備,國(guo)(guo)內(nei)廠(chang)家(jia)是常(chang)州金源(yuan),天津大無縫。
無(wu)氧(yang)(yang)(yang)(yang)(yang)及(ji)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)從含氧(yang)(yang)(yang)(yang)(yang)量上(shang)容易(yi)區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)銅是(shi)(shi)含氧(yang)(yang)(yang)(yang)(yang)量在10-20個(ge)PPM以(yi)下(xia),但(dan)目(mu)前有(you)的(de)廠家(jia)只(zhi)能(neng)做(zuo)到(dao)(dao)50個(ge)PPM以(yi)下(xia).低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)在 200-400個(ge)PPM,好(hao)的(de)桿(gan)子(zi)一般(ban)含氧(yang)(yang)(yang)(yang)(yang)量控制在250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)一般(ban)采(cai)取的(de)是(shi)(shi)上(shang)引法,低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)是(shi)(shi)連(lian)鑄連(lian)軋,兩種(zhong)產品相(xiang)對而言低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)對漆包線(xian)(xian)(xian)性 能(neng)更適(shi)應些(xie),如柔軟(ruan)性,回彈(dan)角,繞線(xian)(xian)(xian)性能(neng).但(dan)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)對拉(la)(la)(la)絲條(tiao)件(jian)相(xiang)對要苛(ke)刻(ke)些(xie),同樣拉(la)(la)(la)伸(shen)(shen)0.2的(de)細絲,如果伸(shen)(shen)線(xian)(xian)(xian)條(tiao)件(jian)不(bu)好(hao),普(pu)通(tong)的(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)可拉(la)(la)(la)而好(hao)的(de)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)就斷 線(xian)(xian)(xian),但(dan)如果放在好(hao)的(de)伸(shen)(shen)線(xian)(xian)(xian)條(tiao)件(jian),同樣的(de)桿(gan)子(zi),低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)說不(bu)定就能(neng)拉(la)(la)(la)到(dao)(dao)雙零五,而普(pu)通(tong)無(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)最多只(zhi)能(neng)拉(la)(la)(la)伸(shen)(shen)到(dao)(dao)0.1而已,當(dang)然做(zuo)的(de)最細的(de)如雙零二卻非得依靠進口的(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)了(le).目(mu)前有(you)企業(ye)嘗(chang)試(shi)用剝皮的(de)方式來(lai)處理低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)來(lai)伸(shen)(shen)0.03線(xian)(xian)(xian).但(dan)有(you)關這方面的(de)內容我還(huan)不(bu)是(shi)(shi)很清楚(chu)。
音(yin)響線(xian)一般反而喜歡用(yong)無氧桿,這和無氧桿是(shi)單晶銅,低(di)氧桿是(shi)多晶銅有關。
氧銅(tong)桿(gan)和無(wu)氧銅(tong)桿(gan)由于制造方法(fa)的不同,致使(shi)存(cun)在(zai)差(cha)別,具(ju)有(you)各自(zi)的特(te)點。
一、關于氧的吸入和脫去以(yi)及它的存在狀態
生產銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)(yi)般(ban)在10—50ppm,在常(chang)溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在銅(tong)(tong)(tong)(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)固溶度(du)約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)(yi)般(ban)在200(175)—400(450)ppm,因此(ci)氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是(shi)(shi)在銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)液(ye)態下(xia)吸入的(de)(de)(de)(de)(de),而(er)上引法無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則(ze)相(xiang)反(fan),氧(yang)(yang)(yang)(yang)(yang)在液(ye)態銅(tong)(tong)(tong)(tong)(tong)(tong)下(xia)保(bao)持相(xiang)當時間后,被還(huan)原而(er)脫去,通常(chang)這(zhe)種(zhong)(zhong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在10—50ppm以(yi)下(xia),最低(di)可(ke)達(da)1-2ppm,從組織上看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)(tong)狀(zhuang)態,存(cun)在于晶(jing)(jing)粒邊(bian)界附近,這(zhe)對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)而(er)言可(ke)以(yi)說(shuo)是(shi)(shi)常(chang)見的(de)(de)(de)(de)(de)但對(dui)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則(ze)很(hen)少見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)(tong)以(yi)夾雜形式在晶(jing)(jing)界出現對(dui)材料的(de)(de)(de)(de)(de)韌(ren)性(xing)產生負(fu)面影響(xiang)。而(er)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很(hen)低(di),所(suo)以(yi)這(zhe)種(zhong)(zhong)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)組織是(shi)(shi)均勻的(de)(de)(de)(de)(de)單相(xiang)組織對(dui)韌(ren)性(xing)有(you)利。在無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)的(de)(de)(de)(de)(de)多孔性(xing)是(shi)(shi)不常(chang)見的(de)(de)(de)(de)(de),而(er)在低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)則(ze)是(shi)(shi)常(chang)見的(de)(de)(de)(de)(de)一(yi)(yi)種(zhong)(zhong)缺陷。
二、熱軋組織和(he)鑄造組織的區(qu)別
低氧(yang)銅(tong)(tong)桿(gan)(gan)由(you)于(yu)經(jing)過熱軋(ya),所以其(qi)組織(zhi)屬熱加工組織(zhi),原來的(de)(de)(de)(de)(de)鑄造(zao)組織(zhi)已經(jing)破(po)碎(sui),在8mm的(de)(de)(de)(de)(de)桿(gan)(gan)時(shi)已有(you)再(zai)結晶(jing)(jing)(jing)的(de)(de)(de)(de)(de)形(xing)式出現,而無氧(yang)銅(tong)(tong)桿(gan)(gan)屬鑄造(zao)組織(zhi),晶(jing)(jing)(jing)粒(li)(li)粗(cu)大,這(zhe)是(shi)為什么,無氧(yang)銅(tong)(tong)的(de)(de)(de)(de)(de)再(zai)結晶(jing)(jing)(jing)溫(wen)度較(jiao)高(gao)(gao)(gao),需(xu)要(yao)(yao)較(jiao)高(gao)(gao)(gao)退(tui)(tui)火(huo)溫(wen)度的(de)(de)(de)(de)(de)固有(you)原因。這(zhe)是(shi)因為,再(zai)結晶(jing)(jing)(jing)發(fa)生在晶(jing)(jing)(jing)粒(li)(li)邊界附近,無氧(yang)銅(tong)(tong)桿(gan)(gan)組織(zhi)晶(jing)(jing)(jing)粒(li)(li)粗(cu)大,晶(jing)(jing)(jing)粒(li)(li)尺寸甚至(zhi)能達幾個(ge)毫(hao)米,因而晶(jing)(jing)(jing)粒(li)(li)邊界少(shao),即使通過拉(la)制變形(xing),但晶(jing)(jing)(jing)粒(li)(li)邊界相(xiang)對低氧(yang)銅(tong)(tong)桿(gan)(gan)還是(shi)較(jiao)少(shao),所以需(xu)要(yao)(yao)較(jiao)高(gao)(gao)(gao)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)功(gong)(gong)率。對無氧(yang)銅(tong)(tong)成(cheng)功(gong)(gong)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)要(yao)(yao)求(qiu)是(shi):由(you)桿(gan)(gan)經(jing)拉(la)制,但尚未鑄造(zao)組織(zhi)的(de)(de)(de)(de)(de)線時(shi)的(de)(de)(de)(de)(de)第一次退(tui)(tui)火(huo),其(qi)退(tui)(tui)火(huo)功(gong)(gong)率應(ying)比同樣(yang)情況的(de)(de)(de)(de)(de)低氧(yang)銅(tong)(tong)高(gao)(gao)(gao)10——15%。經(jing)繼續拉(la)制,在以后階段的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)功(gong)(gong)率應(ying)留有(you)足夠的(de)(de)(de)(de)(de)余量和(he)對低氧(yang)銅(tong)(tong)和(he)無氧(yang)銅(tong)(tong)切實區(qu)別執行不同的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)工藝,以保證(zheng)在制品和(he)成(cheng)品導線的(de)(de)(de)(de)(de)柔(rou)軟性。
三、夾雜,氧(yang)含量波動,表面氧(yang)化物和可能存在的熱軋缺陷的差別
無(wu)氧(yang)銅(tong)(tong)桿(gan)的(de)可拉(la)性在(zai)(zai)(zai)所有線(xian)(xian)徑里與低氧(yang)銅(tong)(tong)桿(gan)相比都是(shi)優(you)越的(de),除(chu)上述組(zu)織原(yuan)因(yin)外,無(wu)氧(yang)銅(tong)(tong)桿(gan)夾雜少(shao),含氧(yang)量(liang)穩定,無(wu)熱軋可能產(chan)生的(de)缺陷,桿(gan)表氧(yang)化(hua)物厚度可達≤15A。在(zai)(zai)(zai)連鑄(zhu)連軋生產(chan)過程中如(ru)果工藝不穩定,對氧(yang)監控不嚴,含氧(yang)量(liang)不穩定將(jiang)直(zhi)接影(ying)響桿(gan)的(de)性能。如(ru)果桿(gan)的(de)表面氧(yang)化(hua)物能在(zai)(zai)(zai)后工序(xu)的(de)連續清洗(xi)中得以彌(mi)補外,但比較麻煩的(de)是(shi)有相當多的(de)氧(yang)化(hua)物存在(zai)(zai)(zai)于“皮下”,對拉(la)線(xian)(xian)斷(duan)(duan)線(xian)(xian)影(ying)響更直(zhi)接,故而在(zai)(zai)(zai)拉(la)制微(wei)細(xi)線(xian)(xian),超(chao)微(wei)細(xi)線(xian)(xian)時(shi)(shi),為了(le)減少(shao)斷(duan)(duan)線(xian)(xian),有時(shi)(shi)要(yao)對銅(tong)(tong)桿(gan)采取不得已(yi)的(de)辦法(fa)——剝(bo)皮,甚至(zhi)二次剝(bo)皮的(de)原(yuan)因(yin)所在(zai)(zai)(zai),目的(de)要(yao)除(chu)去皮下氧(yang)化(hua)物。
四、低氧(yang)銅桿和無氧(yang)銅桿的韌性有差別
兩者都可(ke)以拉到(dao)0.015mm,但(dan)在低溫(wen)超導線中的低溫(wen)級無氧銅,其細絲間的間距只(zhi)有0.001mm.
五、從制桿的原材料(liao)到制線的經濟性有差別(bie)。
制(zhi)造(zao)無氧銅桿要求(qiu)質量較高的原材料。一般(ban),拉(la)制(zhi)直徑(jing)>1mm的銅線時,低(di)氧銅桿的優(you)點比較明顯,而無氧銅桿顯得更為優(you)越的是(shi)拉(la)制(zhi)直徑(jing)<0.5mm的銅線。
六、低(di)氧銅(tong)桿(gan)的制線(xian)工藝與無氧銅(tong)桿(gan)的有所不同(tong)。
低氧(yang)銅桿的(de)制(zhi)線工(gong)藝(yi)不(bu)能(neng)照(zhao)搬到無氧(yang)銅桿的(de)制(zhi)線工(gong)藝(yi)上來,至少兩者的(de)退(tui)火工(gong)藝(yi)是(shi)不(bu)同的(de)。因(yin)為(wei)線的(de)柔(rou)軟(ruan)(ruan)性(xing)深受材料成份和(he)制(zhi)桿,制(zhi)線和(he)退(tui)火工(gong)藝(yi)的(de)影響,不(bu)能(neng)簡單地說低氧(yang)銅或無氧(yang)銅誰軟(ruan)(ruan)誰硬。
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