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來源:行(xing)業動(dong)態 閱(yue)讀(du):109526 發布時間(jian):2019-07-05
導讀(du):由(you)于(yu)生產銅(tong)桿的兩者的工藝不同(tong),所生產的銅(tong)桿中的含氧(yang)量及外觀就(jiu)不同(tong)。上引生產的銅(tong)桿,工藝得(de)當(dang)氧(yang)含量在(zai)10ppm以下(xia)(xia),叫無氧(yang)銅(tong)桿;連(lian)(lian)鑄連(lian)(lian)鑄生產的銅(tong)桿 是在(zai)保護條件(jian)下(xia)(xia)的熱軋,氧(yang)含量在(zai)200-500ppm范圍內,但有時(shi)也(ye)高達700ppm以上,一般情況下(xia)(xia),此(ci)種(zhong)方法生產的銅(tong)外表(biao)光亮,低(di)氧(yang)銅(tong)桿,有時(shi)也(ye)叫光桿。
銅(tong)桿是電纜行(xing)(xing)業的主(zhu)要原料,生產(chan)(chan)的方式(shi)(shi)主(zhu)要有兩(liang)種——連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)(ya)(ya)法和上引(yin)連(lian)(lian)鑄(zhu)法。連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)(ya)(ya)低氧(yang)銅(tong)桿的生產(chan)(chan)方法較多(duo),其(qi)特點是金屬(shu)在豎爐(lu)中融化后(hou),銅(tong)液(ye)通過保溫爐(lu)、溜槽(cao)、中間包,從(cong)澆管(guan)進(jin)入封閉的模腔內(nei),采用(yong)較大的冷(leng)卻(que)強(qiang)度進(jin)行(xing)(xing)冷(leng)卻(que),形成(cheng)鑄(zhu)坯,然后(hou)進(jin)行(xing)(xing)多(duo)道次(ci)軋(ya)(ya)(ya)制,生產(chan)(chan)的低氧(yang)銅(tong)桿為熱加工組織(zhi),原來的鑄(zhu)造(zao)(zao)組織(zhi)已經破碎,含氧(yang)量一(yi)般(ban)為200~400ppm之間。無氧(yang)銅(tong)桿國內(nei)基本全部采用(yong)上引(yin)連(lian)(lian)鑄(zhu)法生產(chan)(chan),金屬(shu)在感應電爐(lu)中融化后(hou)通過石墨模進(jin)行(xing)(xing)上引(yin)連(lian)(lian)續鑄(zhu)造(zao)(zao),之后(hou)進(jin)行(xing)(xing)冷(leng)軋(ya)(ya)(ya)或(huo)冷(leng)加工,生產(chan)(chan)的無氧(yang)銅(tong)桿為鑄(zhu)造(zao)(zao)組織(zhi),含氧(yang)量一(yi)般(ban)在20ppm以下。由(you)于制造(zao)(zao)工藝(yi)的不同,所以在組織(zhi)結構、氧(yang)含量分布(bu)、雜質的形式(shi)(shi)及分布(bu)等諸多(duo)方面有較大差別。
一、拉制性能
銅(tong)桿(gan)(gan)的(de)拉制(zhi)性能跟很多(duo)因(yin)素有關(guan),如雜質的(de)含(han)量(liang)、氧含(han)量(liang)及分(fen)布、工藝控制(zhi)等。下面(mian)分(fen)別(bie)從以上(shang)幾個(ge)方面(mian)對銅(tong)桿(gan)(gan)的(de)拉制(zhi)性能進(jin)行分(fen)析。
1、熔化方式(shi)對S等雜(za)質的影響
連(lian)鑄連(lian)軋生產銅(tong)(tong)桿主要是通過氣(qi)體的(de)燃(ran)燒使(shi)銅(tong)(tong)桿熔化,在燃(ran)燒的(de)過程(cheng)(cheng)中(zhong)(zhong),通過氧化和(he)揮發作用(yong),可一(yi)(yi)定(ding)程(cheng)(cheng)度減(jian)少部分雜質進入銅(tong)(tong)液,因此連(lian)鑄連(lian)軋法對(dui)原(yuan)料要求(qiu)相對(dui)低(di)一(yi)(yi)些(xie)。上(shang)引連(lian)鑄生產無(wu)氧銅(tong)(tong)桿,由于是用(yong)感應電爐(lu)熔化,電解銅(tong)(tong)表面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都(dou)熔入到銅(tong)(tong)液中(zhong)(zhong)。其(qi)中(zhong)(zhong)熔入的(de)S對(dui)無(wu)氧銅(tong)(tong)桿塑(su)性影響極大,會增(zeng)加拉絲斷線率。
2、鑄造過程中雜質的進入
在生產(chan)(chan)過(guo)(guo)(guo)程(cheng)中(zhong)(zhong),連(lian)鑄連(lian)軋(ya)工藝(yi)(yi)需通過(guo)(guo)(guo)保(bao)溫爐、溜槽、中(zhong)(zhong)間包轉運銅(tong)液,相對容易造成耐火材料的(de)(de)剝落(luo),在軋(ya)制過(guo)(guo)(guo)程(cheng)中(zhong)(zhong)需要通過(guo)(guo)(guo)軋(ya)輥(gun),造成鐵質的(de)(de)脫落(luo),會給銅(tong)桿造成外部夾(jia)雜。而熱軋(ya)中(zhong)(zhong)皮上和皮下氧化物的(de)(de)軋(ya)入,會給低氧桿的(de)(de)拉絲造成不利的(de)(de)影響。上引連(lian)鑄法生產(chan)(chan)工藝(yi)(yi)流(liu)程(cheng)較(jiao)短,銅(tong)液是通過(guo)(guo)(guo)聯體(ti)爐內潛(qian)流(liu)式(shi)完成,對耐火材料的(de)(de)沖(chong)擊不大,結晶(jing)是通過(guo)(guo)(guo)石墨模內進行,所(suo)以過(guo)(guo)(guo)程(cheng)中(zhong)(zhong)可能產(chan)(chan)生的(de)(de)污染源較(jiao)少(shao),雜質進入的(de)(de)機會較(jiao)少(shao)。
O、S、P是與銅會生產化合物(wu)的(de)元素。在熔態銅中(zhong),氧(yang)(yang)可(ke)以(yi)溶解一部(bu)分,但當銅冷(leng)凝時,氧(yang)(yang)幾乎不(bu)溶解于銅中(zhong)。熔態時所(suo)溶解的(de)氧(yang)(yang),以(yi)銅=氧(yang)(yang)化亞(ya)銅共晶(jing)體(ti)析出(chu),分布在晶(jing)粒晶(jing)界處。銅-氧(yang)(yang)化亞(ya)銅共晶(jing)體(ti)的(de)出(chu)現,顯著降低了銅的(de)塑性。
硫可以溶解(jie)在熔體(ti)的銅中,但在室(shi)溫下(xia),其溶解(jie)度(du)幾乎(hu)降低到零,它(ta)以硫化亞銅的形式出(chu)現在晶粒晶界處(chu),會顯(xian)著(zhu)降低銅的塑性。
3、氧(yang)(yang)在(zai)低氧(yang)(yang)銅桿(gan)和無氧(yang)(yang)銅桿(gan)中(zhong)分布形式及其影響
氧(yang)含(han)量對低氧(yang)銅(tong)(tong)桿的(de)(de)拉線(xian)(xian)性能有著明顯的(de)(de)影響。當(dang)氧(yang)含(han)量增(zeng)加(jia)到(dao)最(zui)(zui)佳值(zhi)時,銅(tong)(tong)桿的(de)(de)斷線(xian)(xian)率最(zui)(zui)低。這是因為(wei)氧(yang)在與大部(bu)分(fen)雜質反(fan)應的(de)(de)過程中(zhong)都(dou)起到(dao)了清除器的(de)(de)作(zuo)用。適度的(de)(de)氧(yang)還有利(li)于去除銅(tong)(tong)液中(zhong)的(de)(de)氫,生成水(shui)蒸氣溢出(chu),減少氣孔的(de)(de)形成。最(zui)(zui)佳的(de)(de)氧(yang)含(han)量為(wei)拉線(xian)(xian)工藝提供了最(zui)(zui)好的(de)(de)條件。
低(di)氧(yang)(yang)銅(tong)(tong)桿(gan)氧(yang)(yang)化(hua)(hua)(hua)物的(de)(de)(de)分(fen)(fen)布(bu):在(zai)連續(xu)澆鑄中(zhong)凝固的(de)(de)(de)最初階(jie)段(duan),散熱速率和均勻冷卻(que)是決定銅(tong)(tong)桿(gan)氧(yang)(yang)化(hua)(hua)(hua)物分(fen)(fen)布(bu)的(de)(de)(de)主要(yao)因素。不(bu)均勻冷卻(que)會(hui)引起銅(tong)(tong)桿(gan)內部(bu)結(jie)構本(ben)質上的(de)(de)(de)差異,但(dan)后(hou)續(xu)的(de)(de)(de)熱加工,柱狀晶(jing)通常會(hui)遭到破壞,使氧(yang)(yang)化(hua)(hua)(hua)亞銅(tong)(tong)顆粒細微化(hua)(hua)(hua)和均勻分(fen)(fen)布(bu)。氧(yang)(yang)化(hua)(hua)(hua)物顆粒聚集而產生的(de)(de)(de)典型情況是中(zhong)心爆裂。除氧(yang)(yang)化(hua)(hua)(hua)物顆粒分(fen)(fen)布(bu)的(de)(de)(de)影(ying)響外,具有較(jiao)(jiao)小氧(yang)(yang)化(hua)(hua)(hua)物顆粒的(de)(de)(de)銅(tong)(tong)桿(gan)顯示出(chu)較(jiao)(jiao)好的(de)(de)(de)拉線特性,較(jiao)(jiao)大的(de)(de)(de)Cu2O顆粒容易造成應力(li)集中(zhong)點(dian)而斷裂。
無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)含氧(yang)(yang)量(liang)(liang)超(chao)標(biao),銅(tong)(tong)(tong)(tong)桿變脆,延伸(shen)(shen)率(lv)下(xia)降,拉(la)伸(shen)(shen)式樣端口顯(xian)暗紅色,結晶(jing)組(zu)織疏松。當(dang)氧(yang)(yang)含量(liang)(liang)超(chao)出8ppm時,工藝性能變差(cha),表現(xian)為鑄造及(ji)拉(la)伸(shen)(shen)過(guo)程中(zhong)斷(duan)桿及(ji)斷(duan)線率(lv)極具增高。這是由(you)于氧(yang)(yang)能與銅(tong)(tong)(tong)(tong)生成(cheng)(cheng)氧(yang)(yang)化亞銅(tong)(tong)(tong)(tong)脆性相,形成(cheng)(cheng)銅(tong)(tong)(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)(tong)(tong)共晶(jing)體(ti),以網狀(zhuang)組(zu)織分布在境界上(shang)。這種脆性相硬度高,在冷(leng)變形時將會與銅(tong)(tong)(tong)(tong)機體(ti)脫離(li),導致(zhi)銅(tong)(tong)(tong)(tong)桿的(de)機械性能下(xia)降,在后(hou)續加工中(zhong)容易造成(cheng)(cheng)斷(duan)裂現(xian)象。氧(yang)(yang)含量(liang)(liang)高還能導致(zhi)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿導電(dian)率(lv)下(xia)降。因此,必須嚴格控(kong)制(zhi)上(shang)引連鑄工藝及(ji)產品質量(liang)(liang)。
4、氫的影響
在上引連鑄中,氧含量控制較低(di),氧化物的(de)副作用唄**降低(di),但氫的(de)影響(xiang)成為較顯著的(de)問題(ti)。吸氣后熔(rong)體中存在平衡反(fan)應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)(qi)體及疏(shu)(shu)松是(shi)(shi)在(zai)結(jie)晶(jing)(jing)(jing)(jing)的(de)(de)(de)過(guo)程中(zhong),氫(qing)(qing)從過(guo)飽和的(de)(de)(de)溶液中(zhong)析(xi)(xi)出(chu)(chu)并聚(ju)集(ji)而(er)形(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)。在(zai)結(jie)晶(jing)(jing)(jing)(jing)前(qian)析(xi)(xi)出(chu)(chu)的(de)(de)(de)氫(qing)(qing)又(you)可(ke)還(huan)原(yuan)氧化亞銅(tong)而(er)生成(cheng)(cheng)(cheng)水氣(qi)(qi)(qi)(qi)泡。由于上(shang)引鑄(zhu)造的(de)(de)(de)特(te)點是(shi)(shi)銅(tong)液自上(shang)而(er)下的(de)(de)(de)結(jie)晶(jing)(jing)(jing)(jing),形(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)液**形(xing)狀(zhuang)近似錐型(xing)。銅(tong)液結(jie)晶(jing)(jing)(jing)(jing)前(qian)析(xi)(xi)出(chu)(chu)的(de)(de)(de)氣(qi)(qi)(qi)(qi)體在(zai)上(shang)浮(fu)過(guo)程中(zhong)被堵在(zai)凝固組織內(nei),結(jie)晶(jing)(jing)(jing)(jing)時(shi)在(zai)鑄(zhu)桿內(nei)形(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔。上(shang)引的(de)(de)(de)含氣(qi)(qi)(qi)(qi)量少時(shi),析(xi)(xi)出(chu)(chu)的(de)(de)(de)氫(qing)(qing)存在(zai)于晶(jing)(jing)(jing)(jing)界處,形(xing)成(cheng)(cheng)(cheng)疏(shu)(shu)松;含氣(qi)(qi)(qi)(qi)量多時(shi),則(ze)聚(ju)集(ji)成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)(qi)孔和疏(shu)(shu)松是(shi)(shi)氫(qing)(qing)氣(qi)(qi)(qi)(qi)和水蒸(zheng)氣(qi)(qi)(qi)(qi)兩(liang)者形(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)。
氫來源于上引生(sheng)產過程中的(de)(de)各(ge)個(ge)工藝環節,如原料電解銅(tong)的(de)(de)“銅(tong)綠(lv)”、輔料木(mu)炭(tan)**、氣候(hou)環境**、石墨結晶器未(wei)干燥(zao)等。因(yin)此(ci),熔化爐中的(de)(de)銅(tong)液表面(mian)應覆蓋經烘烤的(de)(de)木(mu)炭(tan),電解銅(tong)應盡量(liang)去除“銅(tong)綠(lv)”、“銅(tong)豆”“耳朵”,對提高無氧銅(tong)桿質量(liang)非常(chang)重要。
在(zai)連鑄(zhu)連軋工藝(yi)中(zhong),往(wang)往(wang)采用適度(du)控制氧含(han)量來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液(ye)在(zai)鑄造過(guo)程(cheng)中(zhong)(zhong)是自(zi)下而上結(jie)晶,銅(tong)液(ye)中(zhong)(zhong)的(de)(de)氧和氫(qing)所產(chan)生的(de)(de)水蒸氣很(hen)容(rong)易上浮跑(pao)出,銅(tong)液(ye)中(zhong)(zhong)的(de)(de)氫(qing)大部分能被有效去除(chu),因(yin)而對銅(tong)桿的(de)(de)影響較小。
二、表面質量
在生產電磁(ci)線(xian)等產品的過(guo)程中,對銅(tong)桿的表(biao)面質量也需(xu)提出要求。需(xu)要拉制后(hou)的銅(tong)絲表(biao)面無毛刺、銅(tong)粉少(shao)、無油污。并通(tong)過(guo)扭(niu)轉(zhuan)試驗測量表(biao)面銅(tong)粉的質量和扭(niu)轉(zhuan)后(hou)觀察(cha)銅(tong)桿的復原(yuan)情況來判定其好壞。
在(zai)連(lian)鑄連(lian)軋過程中,從鑄造(zao)到(dao)軋制前,溫度高,完全暴露于空氣中,使鑄坯(pi)表(biao)面形成(cheng)較厚的(de)(de)氧(yang)化(hua)(hua)層,在(zai)軋制過程中,隨著軋輥的(de)(de)轉動,氧(yang)化(hua)(hua)物顆粒軋入銅(tong)(tong)線表(biao)面。由于氧(yang)化(hua)(hua)亞銅(tong)(tong)是(shi)高熔點脆性(xing)化(hua)(hua)合物,對(dui)于軋入較深的(de)(de)氧(yang)化(hua)(hua)亞銅(tong)(tong),當成(cheng)條狀(zhuang)的(de)(de)聚(ju)集物遇模(mo)具拉伸時,就會是(shi)銅(tong)(tong)桿外表(biao)面產生毛刺(ci),給后續的(de)(de)涂漆造(zao)成(cheng)麻煩。
而上(shang)引連鑄工(gong)藝制造的(de)無(wu)氧銅(tong)桿(gan),由(you)于鑄造和冷卻(que)完全(quan)與氧隔絕,后續亦(yi)無(wu)熱軋(ya)過(guo)程,銅(tong)桿(gan)表面(mian)無(wu)軋(ya)入表面(mian)的(de)氧化物,質量較好,拉制后銅(tong)粉少,上(shang)述問題(ti)較少存在。
無氧銅桿也(ye)分進口設(she)備做的(de)(de)和國產設(she)備做的(de)(de),但目前進口產品已無明顯優勢,銅桿產品出來后區別(bie)不是很大,只(zhi)要銅板選的(de)(de)好,生(sheng)產控制(zhi)比較穩定,國產設(she)備也(ye)能產出可(ke)拉(la)伸0.05的(de)(de)銅桿.進口設(she)備一般是芬(fen)蘭奧(ao)托(tuo)昆(kun)普的(de)(de)設(she)備,國產設(she)備最(zui)好的(de)(de)應該是上海的(de)(de)海軍(jun)廠的(de)(de)了,生(sheng)產時(shi)間最(zui)長,軍(jun)工企業,質量可(ke)靠。
低(di)氧(yang)銅(tong)桿進口設備(bei)(bei)國際主要有兩種(zhong),一(yi)種(zhong)是(shi)(shi)美國南(nan)線設備(bei)(bei),英文(wen)是(shi)(shi)SOUTHWIRE,國內廠(chang)(chang)家是(shi)(shi)南(nan)京華(hua)新,江西(xi)銅(tong)業,另一(yi)種(zhong)是(shi)(shi)德國CONTIROD設備(bei)(bei),國內廠(chang)(chang)家是(shi)(shi)常州金源(yuan),天(tian)津大無縫。
無(wu)氧(yang)(yang)(yang)及(ji)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上(shang)容易區別,無(wu)氧(yang)(yang)(yang)銅(tong)是含氧(yang)(yang)(yang)量在(zai)10-20個(ge)PPM以(yi)下,但(dan)(dan)目前有的(de)(de)(de)廠家(jia)只(zhi)能做到50個(ge)PPM以(yi)下.低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子一般(ban)含氧(yang)(yang)(yang)量控制(zhi)在(zai)250個(ge)PPM左右(you),無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)一般(ban)采取(qu)的(de)(de)(de)是上(shang)引法(fa),低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)是連(lian)鑄連(lian)軋,兩種(zhong)產品(pin)相對(dui)而言低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對(dui)漆(qi)包線(xian)(xian)(xian)性 能更適(shi)應(ying)些,如(ru)柔軟性,回彈角,繞線(xian)(xian)(xian)性能.但(dan)(dan)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對(dui)拉(la)(la)絲條件(jian)(jian)相對(dui)要苛刻些,同樣拉(la)(la)伸(shen)0.2的(de)(de)(de)細(xi)(xi)絲,如(ru)果(guo)伸(shen)線(xian)(xian)(xian)條件(jian)(jian)不(bu)好,普通的(de)(de)(de)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)可拉(la)(la)而好的(de)(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)就(jiu)斷 線(xian)(xian)(xian),但(dan)(dan)如(ru)果(guo)放(fang)在(zai)好的(de)(de)(de)伸(shen)線(xian)(xian)(xian)條件(jian)(jian),同樣的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)說不(bu)定就(jiu)能拉(la)(la)到雙(shuang)(shuang)零五,而普通無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)最多只(zhi)能拉(la)(la)伸(shen)到0.1而已,當然做的(de)(de)(de)最細(xi)(xi)的(de)(de)(de)如(ru)雙(shuang)(shuang)零二卻非得依(yi)靠進口的(de)(de)(de) 無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)了.目前有企業嘗試用剝皮的(de)(de)(de)方式(shi)來處理(li)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)來伸(shen)0.03線(xian)(xian)(xian).但(dan)(dan)有關(guan)這方面的(de)(de)(de)內容我還不(bu)是很(hen)清楚。
音(yin)響(xiang)線一般(ban)反而喜(xi)歡用(yong)無(wu)(wu)氧桿,這和無(wu)(wu)氧桿是單(dan)晶(jing)銅,低氧桿是多晶(jing)銅有關。
氧(yang)銅桿和(he)無(wu)氧(yang)銅桿由于制(zhi)造方法(fa)的(de)不同,致使存在差別,具有各(ge)自的(de)特點。
一、關(guan)于氧的吸入和脫(tuo)去(qu)以及它的存在狀態
生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)陰極銅(tong)(tong)(tong)(tong)的(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)10—50ppm,在(zai)常溫下氧(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)固溶度約2ppm。低(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)進入是在(zai)銅(tong)(tong)(tong)(tong)的(de)液態(tai)下吸入的(de),而(er)上(shang)引法無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則相(xiang)(xiang)反,氧(yang)(yang)(yang)(yang)(yang)在(zai)液態(tai)銅(tong)(tong)(tong)(tong)下保持相(xiang)(xiang)當(dang)時間后,被還原而(er)脫去,通常這種桿(gan)(gan)(gan)(gan)的(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)10—50ppm以(yi)下,最低(di)(di)可達1-2ppm,從組(zu)(zu)織上(shang)看(kan),低(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態(tai),存在(zai)于晶粒邊界附近(jin),這對低(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)而(er)言可以(yi)說是常見(jian)的(de)但(dan)對無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則很少見(jian)。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾(jia)雜形式在(zai)晶界出(chu)現對材料的(de)韌(ren)性產生負(fu)面影響。而(er)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)氧(yang)(yang)(yang)(yang)(yang)很低(di)(di),所(suo)以(yi)這種銅(tong)(tong)(tong)(tong)的(de)組(zu)(zu)織是均勻的(de)單相(xiang)(xiang)組(zu)(zu)織對韌(ren)性有(you)利(li)。在(zai)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中(zhong)的(de)多孔性是不常見(jian)的(de),而(er)在(zai)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中(zhong)則是常見(jian)的(de)一(yi)種缺陷。
二、熱軋組(zu)織和鑄造組(zu)織的區別
低(di)氧(yang)(yang)(yang)銅(tong)桿由(you)于經過熱軋,所(suo)以其組織(zhi)(zhi)(zhi)(zhi)屬熱加工(gong)組織(zhi)(zhi)(zhi)(zhi),原來(lai)的(de)(de)(de)鑄造組織(zhi)(zhi)(zhi)(zhi)已經破碎,在(zai)8mm的(de)(de)(de)桿時已有(you)再結晶(jing)(jing)(jing)的(de)(de)(de)形式出現(xian),而(er)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)桿屬鑄造組織(zhi)(zhi)(zhi)(zhi),晶(jing)(jing)(jing)粒粗大,這(zhe)是為什(shen)么,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)的(de)(de)(de)再結晶(jing)(jing)(jing)溫度(du)較高(gao)(gao),需(xu)要較高(gao)(gao)退火溫度(du)的(de)(de)(de)固有(you)原因。這(zhe)是因為,再結晶(jing)(jing)(jing)發生在(zai)晶(jing)(jing)(jing)粒邊界附近,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)桿組織(zhi)(zhi)(zhi)(zhi)晶(jing)(jing)(jing)粒粗大,晶(jing)(jing)(jing)粒尺寸甚至能達(da)幾個毫米,因而(er)晶(jing)(jing)(jing)粒邊界少,即(ji)使通(tong)過拉制變形,但晶(jing)(jing)(jing)粒邊界相(xiang)對(dui)低(di)氧(yang)(yang)(yang)銅(tong)桿還是較少,所(suo)以需(xu)要較高(gao)(gao)的(de)(de)(de)退火功率(lv)。對(dui)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)成(cheng)功的(de)(de)(de)退火要求是:由(you)桿經拉制,但尚未鑄造組織(zhi)(zhi)(zhi)(zhi)的(de)(de)(de)線時的(de)(de)(de)第一次(ci)退火,其退火功率(lv)應比同(tong)樣情況的(de)(de)(de)低(di)氧(yang)(yang)(yang)銅(tong)高(gao)(gao)10——15%。經繼(ji)續拉制,在(zai)以后(hou)階段(duan)的(de)(de)(de)退火功率(lv)應留有(you)足(zu)夠的(de)(de)(de)余量和(he)對(dui)低(di)氧(yang)(yang)(yang)銅(tong)和(he)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)切實(shi)區別(bie)執(zhi)行不同(tong)的(de)(de)(de)退火工(gong)藝,以保證在(zai)制品(pin)和(he)成(cheng)品(pin)導(dao)線的(de)(de)(de)柔軟性。
三、夾(jia)雜,氧含量波動,表面(mian)氧化物和可(ke)能存在的熱軋缺陷(xian)的差別(bie)
無氧銅(tong)桿(gan)(gan)的(de)(de)可(ke)(ke)拉性在(zai)(zai)(zai)所(suo)有線(xian)(xian)徑里與低氧銅(tong)桿(gan)(gan)相比(bi)(bi)都是優越的(de)(de),除上述組織原因(yin)外(wai),無氧銅(tong)桿(gan)(gan)夾雜少,含(han)氧量穩定,無熱軋可(ke)(ke)能(neng)產(chan)生的(de)(de)缺陷,桿(gan)(gan)表(biao)(biao)氧化(hua)物(wu)厚(hou)度可(ke)(ke)達≤15A。在(zai)(zai)(zai)連鑄連軋生產(chan)過(guo)程中如(ru)果工藝不(bu)穩定,對氧監(jian)控不(bu)嚴,含(han)氧量不(bu)穩定將直(zhi)接影響桿(gan)(gan)的(de)(de)性能(neng)。如(ru)果桿(gan)(gan)的(de)(de)表(biao)(biao)面氧化(hua)物(wu)能(neng)在(zai)(zai)(zai)后(hou)工序的(de)(de)連續清洗中得以彌補外(wai),但比(bi)(bi)較麻煩的(de)(de)是有相當(dang)多(duo)的(de)(de)氧化(hua)物(wu)存在(zai)(zai)(zai)于“皮(pi)下”,對拉線(xian)(xian)斷(duan)線(xian)(xian)影響更直(zhi)接,故而(er)在(zai)(zai)(zai)拉制微細線(xian)(xian),超微細線(xian)(xian)時(shi),為(wei)了(le)減少斷(duan)線(xian)(xian),有時(shi)要對銅(tong)桿(gan)(gan)采取(qu)不(bu)得已(yi)的(de)(de)辦法——剝(bo)皮(pi),甚(shen)至二次剝(bo)皮(pi)的(de)(de)原因(yin)所(suo)在(zai)(zai)(zai),目的(de)(de)要除去皮(pi)下氧化(hua)物(wu)。
四、低氧銅(tong)桿和無(wu)氧銅(tong)桿的韌性有差別
兩者都可以(yi)拉到0.015mm,但在低(di)溫(wen)(wen)超導(dao)線(xian)中(zhong)的(de)低(di)溫(wen)(wen)級(ji)無氧銅,其細絲間(jian)的(de)間(jian)距只有0.001mm.
五、從制(zhi)桿(gan)的(de)原材料到制(zhi)線的(de)經(jing)濟性有(you)差別。
制(zhi)造(zao)無氧銅桿(gan)要求質量較高(gao)的(de)原材料。一般,拉制(zhi)直徑(jing)>1mm的(de)銅線時,低(di)氧銅桿(gan)的(de)優點比較明顯,而(er)無氧銅桿(gan)顯得更為優越的(de)是拉制(zhi)直徑(jing)<0.5mm的(de)銅線。
六、低(di)氧銅(tong)桿(gan)的制線工藝與無氧銅(tong)桿(gan)的有所(suo)不(bu)同。
低(di)(di)氧(yang)銅桿的(de)制線(xian)工藝(yi)不(bu)(bu)能(neng)照搬到(dao)無氧(yang)銅桿的(de)制線(xian)工藝(yi)上來(lai),至少兩者的(de)退(tui)火(huo)工藝(yi)是不(bu)(bu)同的(de)。因為線(xian)的(de)柔軟性深受材料(liao)成份和制桿,制線(xian)和退(tui)火(huo)工藝(yi)的(de)影響(xiang),不(bu)(bu)能(neng)簡單(dan)地說低(di)(di)氧(yang)銅或無氧(yang)銅誰(shui)軟誰(shui)硬。
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