熱門(men)關鍵(jian)詞:
來源(yuan):行業動態 閱讀(du):109319 發布時間:2019-07-05
導讀:由于生(sheng)產(chan)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)兩(liang)者的(de)(de)工藝不(bu)(bu)同,所生(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)含氧(yang)(yang)量及外觀就不(bu)(bu)同。上(shang)引(yin)生(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)桿(gan),工藝得(de)當(dang)氧(yang)(yang)含量在10ppm以(yi)下(xia),叫(jiao)無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan);連(lian)鑄連(lian)鑄生(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)桿(gan) 是在保(bao)護(hu)條件下(xia)的(de)(de)熱(re)軋,氧(yang)(yang)含量在200-500ppm范圍(wei)內,但有(you)時(shi)(shi)也高達700ppm以(yi)上(shang),一般情(qing)況下(xia),此種(zhong)方(fang)法(fa)生(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)外表光亮,低氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan),有(you)時(shi)(shi)也叫(jiao)光桿(gan)。
銅(tong)(tong)桿(gan)(gan)是電纜(lan)行(xing)業的(de)(de)主要原(yuan)料(liao),生產(chan)的(de)(de)方式主要有(you)兩種(zhong)——連(lian)鑄(zhu)(zhu)連(lian)軋法和上引連(lian)鑄(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)連(lian)軋低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)(de)生產(chan)方法較多(duo),其特(te)點是金屬在(zai)豎爐(lu)中(zhong)融化后(hou),銅(tong)(tong)液通過保(bao)溫爐(lu)、溜(liu)槽、中(zhong)間包,從澆管進入(ru)封閉的(de)(de)模腔內(nei),采(cai)用較大的(de)(de)冷卻(que)強度進行(xing)冷卻(que),形成(cheng)鑄(zhu)(zhu)坯,然后(hou)進行(xing)多(duo)道(dao)次軋制,生產(chan)的(de)(de)低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)為熱加工(gong)(gong)組(zu)織(zhi),原(yuan)來的(de)(de)鑄(zhu)(zhu)造組(zu)織(zhi)已經破(po)碎,含氧(yang)(yang)量(liang)一(yi)般(ban)為200~400ppm之(zhi)間。無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)國內(nei)基本全部(bu)采(cai)用上引連(lian)鑄(zhu)(zhu)法生產(chan),金屬在(zai)感應電爐(lu)中(zhong)融化后(hou)通過石墨(mo)模進行(xing)上引連(lian)續鑄(zhu)(zhu)造,之(zhi)后(hou)進行(xing)冷軋或冷加工(gong)(gong),生產(chan)的(de)(de)無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)為鑄(zhu)(zhu)造組(zu)織(zhi),含氧(yang)(yang)量(liang)一(yi)般(ban)在(zai)20ppm以(yi)下(xia)。由(you)于制造工(gong)(gong)藝的(de)(de)不同,所以(yi)在(zai)組(zu)織(zhi)結構(gou)、氧(yang)(yang)含量(liang)分(fen)布(bu)、雜(za)質的(de)(de)形式及分(fen)布(bu)等諸多(duo)方面有(you)較大差別。
一、拉制性能
銅(tong)桿(gan)的(de)(de)拉(la)制(zhi)性(xing)能跟很多(duo)因(yin)素(su)有(you)關(guan),如(ru)雜質(zhi)的(de)(de)含量、氧含量及分(fen)布、工藝(yi)控制(zhi)等。下(xia)面分(fen)別(bie)從以上幾個方面對銅(tong)桿(gan)的(de)(de)拉(la)制(zhi)性(xing)能進(jin)行分(fen)析。
1、熔化方式對S等雜質的影響(xiang)
連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)生(sheng)產銅(tong)(tong)(tong)桿(gan)主(zhu)要是(shi)通(tong)過氣體的燃燒(shao)使銅(tong)(tong)(tong)桿(gan)熔化,在燃燒(shao)的過程中,通(tong)過氧(yang)化和(he)揮發作(zuo)用,可一(yi)定程度減少部(bu)分雜質進入銅(tong)(tong)(tong)液,因此(ci)連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)法(fa)對(dui)原料要求相對(dui)低一(yi)些(xie)。上引連(lian)(lian)鑄(zhu)生(sheng)產無氧(yang)銅(tong)(tong)(tong)桿(gan),由于是(shi)用感(gan)應(ying)電(dian)爐(lu)熔化,電(dian)解銅(tong)(tong)(tong)表面(mian)的“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基(ji)本(ben)都熔入到銅(tong)(tong)(tong)液中。其中熔入的S對(dui)無氧(yang)銅(tong)(tong)(tong)桿(gan)塑性(xing)影響極大,會(hui)增(zeng)加拉絲斷線率。
2、鑄造過程(cheng)中雜質的進入
在生(sheng)產過(guo)程中(zhong),連(lian)鑄連(lian)軋工(gong)藝需(xu)通(tong)過(guo)保溫爐(lu)、溜槽、中(zhong)間包轉運(yun)銅(tong)液,相對(dui)容(rong)易造(zao)成(cheng)耐(nai)火材料的(de)剝(bo)落,在軋制過(guo)程中(zhong)需(xu)要通(tong)過(guo)軋輥,造(zao)成(cheng)鐵質的(de)脫落,會給銅(tong)桿(gan)造(zao)成(cheng)外部(bu)夾雜。而熱(re)軋中(zhong)皮(pi)上(shang)和皮(pi)下氧(yang)(yang)化物的(de)軋入,會給低氧(yang)(yang)桿(gan)的(de)拉絲造(zao)成(cheng)不利的(de)影響。上(shang)引連(lian)鑄法(fa)生(sheng)產工(gong)藝流程較短,銅(tong)液是通(tong)過(guo)聯(lian)體爐(lu)內潛流式(shi)完(wan)成(cheng),對(dui)耐(nai)火材料的(de)沖(chong)擊不大,結晶是通(tong)過(guo)石墨模內進行,所以過(guo)程中(zhong)可(ke)能產生(sheng)的(de)污染源(yuan)較少,雜質進入的(de)機會較少。
O、S、P是與銅(tong)(tong)(tong)會生產化合(he)物的(de)元素。在熔態銅(tong)(tong)(tong)中,氧可(ke)以溶解一部分(fen),但當(dang)銅(tong)(tong)(tong)冷(leng)凝時,氧幾乎不溶解于銅(tong)(tong)(tong)中。熔態時所溶解的(de)氧,以銅(tong)(tong)(tong)=氧化亞(ya)銅(tong)(tong)(tong)共晶體(ti)(ti)析(xi)出(chu),分(fen)布在晶粒晶界處(chu)。銅(tong)(tong)(tong)-氧化亞(ya)銅(tong)(tong)(tong)共晶體(ti)(ti)的(de)出(chu)現(xian),顯著降低了銅(tong)(tong)(tong)的(de)塑性。
硫可以溶解在(zai)熔體(ti)的銅(tong)中,但(dan)在(zai)室溫下,其溶解度(du)幾乎降低到零,它以硫化亞銅(tong)的形(xing)式出現在(zai)晶(jing)粒晶(jing)界處,會(hui)顯著(zhu)降低銅(tong)的塑性。
3、氧在低(di)氧銅桿和無(wu)氧銅桿中分布形式(shi)及其影響
氧含(han)量對低(di)氧銅(tong)桿的(de)(de)(de)拉線性(xing)能有著明顯的(de)(de)(de)影響。當氧含(han)量增加到(dao)最佳(jia)值時(shi),銅(tong)桿的(de)(de)(de)斷線率最低(di)。這是因為氧在與大(da)部分雜質反應的(de)(de)(de)過程中都起到(dao)了清除器的(de)(de)(de)作(zuo)用(yong)。適度的(de)(de)(de)氧還有利于去(qu)除銅(tong)液中的(de)(de)(de)氫,生(sheng)成水蒸氣溢出(chu),減少氣孔的(de)(de)(de)形成。最佳(jia)的(de)(de)(de)氧含(han)量為拉線工藝提供了最好的(de)(de)(de)條件。
低(di)氧銅(tong)桿氧化物的(de)分布:在連(lian)續澆鑄(zhu)中(zhong)(zhong)凝固的(de)最初階段,散熱速(su)率和(he)均(jun)(jun)(jun)勻(yun)冷(leng)卻(que)是決定銅(tong)桿氧化物分布的(de)主要因(yin)素。不均(jun)(jun)(jun)勻(yun)冷(leng)卻(que)會(hui)引起銅(tong)桿內部結構本質(zhi)上的(de)差異,但后續的(de)熱加工,柱狀(zhuang)晶通常會(hui)遭到破(po)壞,使氧化亞(ya)銅(tong)顆(ke)粒(li)細微化和(he)均(jun)(jun)(jun)勻(yun)分布。氧化物顆(ke)粒(li)聚(ju)集(ji)而產生的(de)典(dian)型(xing)情況是中(zhong)(zhong)心爆(bao)裂。除(chu)氧化物顆(ke)粒(li)分布的(de)影(ying)響外,具有較(jiao)小氧化物顆(ke)粒(li)的(de)銅(tong)桿顯示(shi)出較(jiao)好的(de)拉線(xian)特性,較(jiao)大的(de)Cu2O顆(ke)粒(li)容易造成應力集(ji)中(zhong)(zhong)點而斷裂。
無(wu)氧(yang)(yang)銅(tong)含氧(yang)(yang)量超(chao)標,銅(tong)桿(gan)變(bian)脆(cui),延伸率(lv)下降(jiang),拉伸式樣(yang)端口(kou)顯暗紅色,結晶(jing)組織疏松(song)。當氧(yang)(yang)含量超(chao)出(chu)8ppm時(shi),工(gong)藝性(xing)能(neng)變(bian)差,表現為鑄造及拉伸過(guo)程中斷桿(gan)及斷線率(lv)極具增高(gao)。這(zhe)是由(you)于氧(yang)(yang)能(neng)與銅(tong)生(sheng)成(cheng)(cheng)氧(yang)(yang)化亞銅(tong)脆(cui)性(xing)相,形成(cheng)(cheng)銅(tong)-氧(yang)(yang)化亞銅(tong)共晶(jing)體(ti),以網狀組織分布在境界上。這(zhe)種(zhong)脆(cui)性(xing)相硬度高(gao),在冷變(bian)形時(shi)將會與銅(tong)機(ji)體(ti)脫離,導致銅(tong)桿(gan)的機(ji)械(xie)性(xing)能(neng)下降(jiang),在后續(xu)加工(gong)中容易造成(cheng)(cheng)斷裂現象。氧(yang)(yang)含量高(gao)還能(neng)導致無(wu)氧(yang)(yang)銅(tong)桿(gan)導電(dian)率(lv)下降(jiang)。因此,必須嚴格(ge)控制上引連鑄工(gong)藝及產品質量。
4、氫的影響
在(zai)上(shang)引連鑄中,氧(yang)含(han)量(liang)控制較低(di)(di),氧(yang)化物的副作用唄**降低(di)(di),但氫(qing)的影響成為較顯著(zhu)的問題(ti)。吸(xi)氣后熔體中存在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)體(ti)及疏(shu)松(song)是在(zai)(zai)結(jie)(jie)晶的(de)(de)(de)(de)(de)過(guo)程(cheng)中,氫從過(guo)飽和的(de)(de)(de)(de)(de)溶液(ye)(ye)中析(xi)(xi)出并(bing)聚集(ji)而(er)(er)形成(cheng)的(de)(de)(de)(de)(de)。在(zai)(zai)結(jie)(jie)晶前析(xi)(xi)出的(de)(de)(de)(de)(de)氫又可還原氧化亞銅而(er)(er)生成(cheng)水(shui)氣(qi)泡。由于上(shang)引鑄造的(de)(de)(de)(de)(de)特點是銅液(ye)(ye)自上(shang)而(er)(er)下的(de)(de)(de)(de)(de)結(jie)(jie)晶,形成(cheng)的(de)(de)(de)(de)(de)液(ye)(ye)**形狀近似錐型(xing)。銅液(ye)(ye)結(jie)(jie)晶前析(xi)(xi)出的(de)(de)(de)(de)(de)氣(qi)體(ti)在(zai)(zai)上(shang)浮(fu)過(guo)程(cheng)中被堵在(zai)(zai)凝(ning)固組織內,結(jie)(jie)晶時(shi)(shi)在(zai)(zai)鑄桿內形成(cheng)氣(qi)孔。上(shang)引的(de)(de)(de)(de)(de)含氣(qi)量少時(shi)(shi),析(xi)(xi)出的(de)(de)(de)(de)(de)氫存在(zai)(zai)于晶界(jie)處,形成(cheng)疏(shu)松(song);含氣(qi)量多(duo)時(shi)(shi),則聚集(ji)成(cheng)氣(qi)孔,因(yin)此(ci),氣(qi)孔和疏(shu)松(song)是氫氣(qi)和水(shui)蒸氣(qi)兩者形成(cheng)的(de)(de)(de)(de)(de)。
氫來源于上引生產過(guo)程中的(de)各個工藝環節,如原料電解銅(tong)的(de)“銅(tong)綠”、輔料木炭**、氣(qi)候環境**、石墨(mo)結晶器未(wei)干燥等。因(yin)此(ci),熔化(hua)爐中的(de)銅(tong)液表面應(ying)覆蓋經烘烤的(de)木炭,電解銅(tong)應(ying)盡量去除“銅(tong)綠”、“銅(tong)豆”“耳朵(duo)”,對提高無(wu)氧(yang)銅(tong)桿質量非(fei)常重要。
在連鑄連軋工(gong)藝中,往(wang)往(wang)采用適(shi)度控(kong)制氧(yang)含量來(lai)控(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅液(ye)在鑄造過程中(zhong)是自(zi)下而上(shang)結(jie)晶(jing),銅液(ye)中(zhong)的(de)氧和氫(qing)所產生(sheng)的(de)水蒸氣很(hen)容易上(shang)浮跑出,銅液(ye)中(zhong)的(de)氫(qing)大部分能被有效去除,因而對銅桿(gan)的(de)影響較(jiao)小(xiao)。
二、表面質量
在生(sheng)產電(dian)磁線等產品的(de)過程(cheng)中,對銅(tong)(tong)(tong)桿的(de)表面質量也需(xu)提出(chu)要求。需(xu)要拉制(zhi)后的(de)銅(tong)(tong)(tong)絲表面無毛刺、銅(tong)(tong)(tong)粉少、無油(you)污。并通過扭(niu)(niu)轉試驗測(ce)量表面銅(tong)(tong)(tong)粉的(de)質量和扭(niu)(niu)轉后觀察銅(tong)(tong)(tong)桿的(de)復(fu)原情況來判(pan)定(ding)其好壞。
在連鑄(zhu)連軋(ya)過程中(zhong),從鑄(zhu)造(zao)到軋(ya)制前,溫度高,完全暴(bao)露于空氣中(zhong),使鑄(zhu)坯(pi)表(biao)(biao)(biao)面(mian)形成(cheng)較厚的氧(yang)(yang)化層,在軋(ya)制過程中(zhong),隨著(zhu)軋(ya)輥的轉(zhuan)動,氧(yang)(yang)化物顆(ke)粒軋(ya)入銅(tong)線表(biao)(biao)(biao)面(mian)。由于氧(yang)(yang)化亞(ya)(ya)銅(tong)是高熔點脆(cui)性化合物,對于軋(ya)入較深的氧(yang)(yang)化亞(ya)(ya)銅(tong),當成(cheng)條狀的聚集物遇模(mo)具拉伸(shen)時,就會是銅(tong)桿外(wai)表(biao)(biao)(biao)面(mian)產生(sheng)毛刺,給后續的涂(tu)漆造(zao)成(cheng)麻煩。
而上引連(lian)鑄工(gong)藝制造的無氧銅桿,由于(yu)鑄造和冷卻完全與氧隔絕,后續亦無熱軋過程,銅桿表面無軋入表面的氧化(hua)物,質量較(jiao)好,拉制后銅粉少,上述問題較(jiao)少存在(zai)。
無氧(yang)銅桿也分(fen)進口設備(bei)做的(de)和國(guo)產設備(bei)做的(de),但目前進口產品已無明顯優勢(shi),銅桿產品出(chu)來后區別不(bu)是很大(da),只(zhi)要銅板選(xuan)的(de)好(hao),生產控制比較(jiao)穩定,國(guo)產設備(bei)也能產出(chu)可拉伸0.05的(de)銅桿.進口設備(bei)一(yi)般是芬蘭(lan)奧托昆普的(de)設備(bei),國(guo)產設備(bei)最(zui)好(hao)的(de)應該(gai)是上海(hai)的(de)海(hai)軍廠(chang)的(de)了,生產時間最(zui)長(chang),軍工企業(ye),質量可靠。
低氧銅桿(gan)進口設備(bei)國際主要有(you)兩種,一種是美國南(nan)線設備(bei),英文(wen)是SOUTHWIRE,國內廠(chang)(chang)家是南(nan)京華新(xin),江西銅業,另一種是德國CONTIROD設備(bei),國內廠(chang)(chang)家是常州金源,天津大無縫。
無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)及(ji)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)從含氧(yang)(yang)(yang)(yang)(yang)(yang)量上容(rong)易區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)是(shi)含氧(yang)(yang)(yang)(yang)(yang)(yang)量在(zai)(zai)10-20個(ge)PPM以下,但(dan)目前(qian)有(you)的(de)(de)(de)廠家只能(neng)做(zuo)到50個(ge)PPM以下.低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)(de)桿(gan)(gan)子一(yi)般(ban)含氧(yang)(yang)(yang)(yang)(yang)(yang)量控制在(zai)(zai)250個(ge)PPM左(zuo)右,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)一(yi)般(ban)采取的(de)(de)(de)是(shi)上引法,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)是(shi)連(lian)鑄(zhu)連(lian)軋,兩種(zhong)產品相對(dui)而(er)言低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)漆(qi)包線性(xing) 能(neng)更適應(ying)些,如(ru)(ru)柔軟性(xing),回彈角,繞線性(xing)能(neng).但(dan)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)拉(la)絲條(tiao)件(jian)(jian)相對(dui)要苛刻(ke)些,同樣(yang)拉(la)伸0.2的(de)(de)(de)細絲,如(ru)(ru)果(guo)伸線條(tiao)件(jian)(jian)不好,普通(tong)的(de)(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)可(ke)拉(la)而(er)好的(de)(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)就斷 線,但(dan)如(ru)(ru)果(guo)放在(zai)(zai)好的(de)(de)(de)伸線條(tiao)件(jian)(jian),同樣(yang)的(de)(de)(de)桿(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)說不定就能(neng)拉(la)到雙零五,而(er)普通(tong)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)最多只能(neng)拉(la)伸到0.1而(er)已,當(dang)然(ran)做(zuo)的(de)(de)(de)最細的(de)(de)(de)如(ru)(ru)雙零二卻非得依靠進口的(de)(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)了(le).目前(qian)有(you)企業(ye)嘗(chang)試用剝皮的(de)(de)(de)方(fang)式來(lai)處(chu)理低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)來(lai)伸0.03線.但(dan)有(you)關這方(fang)面(mian)的(de)(de)(de)內容(rong)我(wo)還不是(shi)很(hen)清楚(chu)。
音響線一般反而喜(xi)歡用無氧桿(gan)(gan),這和無氧桿(gan)(gan)是(shi)單晶(jing)銅(tong),低(di)氧桿(gan)(gan)是(shi)多(duo)晶(jing)銅(tong)有關。
氧(yang)銅桿和無氧(yang)銅桿由于(yu)制造方法的(de)不(bu)同,致(zhi)使存在差別,具有各自的(de)特(te)點。
一、關于氧的(de)吸入和(he)脫去以及它的(de)存在狀態
生產銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)含(han)氧(yang)量一般(ban)在10—50ppm,在常(chang)(chang)溫下氧(yang)在銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)固溶度約2ppm。低氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)(de)(de)(de)含(han)氧(yang)量一般(ban)在200(175)—400(450)ppm,因此氧(yang)的(de)(de)(de)(de)(de)(de)(de)(de)(de)進入(ru)(ru)是(shi)在銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)液態(tai)下吸入(ru)(ru)的(de)(de)(de)(de)(de)(de)(de)(de)(de),而(er)(er)(er)上(shang)引法無(wu)(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)則相(xiang)反(fan),氧(yang)在液態(tai)銅(tong)(tong)(tong)下保持相(xiang)當時間后,被還原(yuan)而(er)(er)(er)脫去,通常(chang)(chang)這(zhe)種(zhong)(zhong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)(de)(de)(de)含(han)氧(yang)量都在10—50ppm以(yi)下,最低可達1-2ppm,從組織上(shang)看,低氧(yang)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)氧(yang),以(yi)氧(yang)化(hua)銅(tong)(tong)(tong)狀態(tai),存在于(yu)晶(jing)粒(li)邊界附近,這(zhe)對低氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)而(er)(er)(er)言可以(yi)說是(shi)常(chang)(chang)見(jian)的(de)(de)(de)(de)(de)(de)(de)(de)(de)但(dan)對無(wu)(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)則很少(shao)見(jian)。氧(yang)化(hua)銅(tong)(tong)(tong)以(yi)夾雜形式在晶(jing)界出現對材料(liao)的(de)(de)(de)(de)(de)(de)(de)(de)(de)韌性(xing)產生負面影響(xiang)。而(er)(er)(er)無(wu)(wu)氧(yang)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)氧(yang)很低,所以(yi)這(zhe)種(zhong)(zhong)銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)組織是(shi)均(jun)勻的(de)(de)(de)(de)(de)(de)(de)(de)(de)單相(xiang)組織對韌性(xing)有(you)利。在無(wu)(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)中(zhong)的(de)(de)(de)(de)(de)(de)(de)(de)(de)多孔性(xing)是(shi)不常(chang)(chang)見(jian)的(de)(de)(de)(de)(de)(de)(de)(de)(de),而(er)(er)(er)在低氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)中(zhong)則是(shi)常(chang)(chang)見(jian)的(de)(de)(de)(de)(de)(de)(de)(de)(de)一種(zhong)(zhong)缺(que)陷。
二(er)、熱軋(ya)組(zu)織(zhi)和鑄造組(zu)織(zhi)的區別
低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)由(you)于(yu)經過熱(re)軋,所以其組織(zhi)屬(shu)熱(re)加工組織(zhi),原(yuan)來的鑄造(zao)組織(zhi)已經破碎,在(zai)8mm的桿(gan)時已有再結晶(jing)(jing)(jing)的形(xing)式出(chu)現,而(er)無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)屬(shu)鑄造(zao)組織(zhi),晶(jing)(jing)(jing)粒(li)粗(cu)大,這(zhe)是(shi)為什么(me),無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)的再結晶(jing)(jing)(jing)溫度較(jiao)(jiao)高(gao),需(xu)要(yao)較(jiao)(jiao)高(gao)退(tui)火(huo)溫度的固有原(yuan)因。這(zhe)是(shi)因為,再結晶(jing)(jing)(jing)發生在(zai)晶(jing)(jing)(jing)粒(li)邊(bian)界(jie)附(fu)近,無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)組織(zhi)晶(jing)(jing)(jing)粒(li)粗(cu)大,晶(jing)(jing)(jing)粒(li)尺寸甚(shen)至(zhi)能達幾個毫米,因而(er)晶(jing)(jing)(jing)粒(li)邊(bian)界(jie)少(shao),即使通過拉制(zhi)(zhi)變形(xing),但晶(jing)(jing)(jing)粒(li)邊(bian)界(jie)相對低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)還是(shi)較(jiao)(jiao)少(shao),所以需(xu)要(yao)較(jiao)(jiao)高(gao)的退(tui)火(huo)功率。對無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)成功的退(tui)火(huo)要(yao)求是(shi):由(you)桿(gan)經拉制(zhi)(zhi),但尚(shang)未(wei)鑄造(zao)組織(zhi)的線時的第一次退(tui)火(huo),其退(tui)火(huo)功率應比(bi)同樣(yang)情況的低(di)氧(yang)(yang)(yang)銅(tong)(tong)高(gao)10——15%。經繼續(xu)拉制(zhi)(zhi),在(zai)以后階段的退(tui)火(huo)功率應留有足夠的余(yu)量和對低(di)氧(yang)(yang)(yang)銅(tong)(tong)和無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)切實區別執(zhi)行不同的退(tui)火(huo)工藝,以保證(zheng)在(zai)制(zhi)(zhi)品(pin)和成品(pin)導線的柔軟性(xing)。
三、夾雜(za),氧含量波動,表面氧化物(wu)和可能(neng)存在的(de)熱軋(ya)缺(que)陷的(de)差別
無(wu)氧(yang)銅(tong)桿的(de)可(ke)拉(la)性在所有線(xian)徑里(li)與(yu)低氧(yang)銅(tong)桿相(xiang)比都是優越的(de),除上述組織原因外,無(wu)氧(yang)銅(tong)桿夾(jia)雜少(shao)(shao),含氧(yang)量穩定(ding),無(wu)熱軋可(ke)能(neng)產生的(de)缺陷,桿表氧(yang)化(hua)物厚度可(ke)達≤15A。在連(lian)(lian)(lian)鑄(zhu)連(lian)(lian)(lian)軋生產過(guo)程中(zhong)(zhong)如果工藝(yi)不(bu)穩定(ding),對氧(yang)監控不(bu)嚴(yan),含氧(yang)量不(bu)穩定(ding)將(jiang)直接影響桿的(de)性能(neng)。如果桿的(de)表面氧(yang)化(hua)物能(neng)在后工序的(de)連(lian)(lian)(lian)續清洗中(zhong)(zhong)得以彌補外,但比較麻煩的(de)是有相(xiang)當多的(de)氧(yang)化(hua)物存在于“皮(pi)(pi)下”,對拉(la)線(xian)斷線(xian)影響更直接,故而在拉(la)制微細線(xian),超微細線(xian)時,為了減少(shao)(shao)斷線(xian),有時要對銅(tong)桿采取不(bu)得已的(de)辦法——剝皮(pi)(pi),甚至二次(ci)剝皮(pi)(pi)的(de)原因所在,目的(de)要除去皮(pi)(pi)下氧(yang)化(hua)物。
四、低氧銅(tong)桿和無氧銅(tong)桿的韌性有(you)差別
兩者都可以拉到0.015mm,但在低(di)溫超導(dao)線中的(de)低(di)溫級(ji)無氧銅,其細(xi)絲(si)間的(de)間距只有0.001mm.
五、從制(zhi)桿(gan)的原材料到制(zhi)線的經濟性有差別。
制(zhi)造無氧銅桿要求質(zhi)量較(jiao)高的原(yuan)材料。一般(ban),拉制(zhi)直徑>1mm的銅線(xian)時,低氧銅桿的優點比(bi)較(jiao)明顯(xian),而無氧銅桿顯(xian)得(de)更為優越的是(shi)拉制(zhi)直徑<0.5mm的銅線(xian)。
六、低氧(yang)銅桿(gan)的制(zhi)線工藝與(yu)無氧(yang)銅桿(gan)的有所不同。
低(di)氧銅桿的(de)制(zhi)(zhi)(zhi)線工(gong)藝不能(neng)照(zhao)搬到無氧銅桿的(de)制(zhi)(zhi)(zhi)線工(gong)藝上(shang)來,至少(shao)兩者的(de)退(tui)火工(gong)藝是不同的(de)。因為(wei)線的(de)柔軟性深(shen)受材料成份和制(zhi)(zhi)(zhi)桿,制(zhi)(zhi)(zhi)線和退(tui)火工(gong)藝的(de)影響,不能(neng)簡單地說低(di)氧銅或無氧銅誰(shui)軟誰(shui)硬(ying)。
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