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遼中電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱(yue)讀:109336 發(fa)布時間:2019-07-05

導(dao)讀(du):由于生(sheng)(sheng)(sheng)產(chan)(chan)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)兩(liang)者的(de)(de)(de)(de)工(gong)藝(yi)不(bu)同,所生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)(de)銅(tong)(tong)桿(gan)中的(de)(de)(de)(de)含氧(yang)量及外觀就(jiu)不(bu)同。上引(yin)生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)(de)銅(tong)(tong)桿(gan),工(gong)藝(yi)得當氧(yang)含量在10ppm以下(xia)(xia),叫無(wu)氧(yang)銅(tong)(tong)桿(gan);連(lian)鑄(zhu)連(lian)鑄(zhu)生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)(de)銅(tong)(tong)桿(gan) 是在保護條件下(xia)(xia)的(de)(de)(de)(de)熱軋,氧(yang)含量在200-500ppm范圍內,但有時也(ye)高達700ppm以上,一般情況(kuang)下(xia)(xia),此種方法生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)(de)銅(tong)(tong)外表光(guang)(guang)亮(liang),低氧(yang)銅(tong)(tong)桿(gan),有時也(ye)叫光(guang)(guang)桿(gan)。

銅(tong)(tong)(tong)桿是(shi)(shi)電(dian)(dian)纜行(xing)業的(de)(de)主(zhu)要(yao)原料,生(sheng)產的(de)(de)方(fang)式主(zhu)要(yao)有兩種——連(lian)(lian)鑄連(lian)(lian)軋法(fa)(fa)和上(shang)引(yin)連(lian)(lian)鑄法(fa)(fa)。連(lian)(lian)鑄連(lian)(lian)軋低(di)氧銅(tong)(tong)(tong)桿的(de)(de)生(sheng)產方(fang)法(fa)(fa)較多(duo),其特點(dian)是(shi)(shi)金屬(shu)在(zai)豎爐(lu)中(zhong)融化(hua)后(hou),銅(tong)(tong)(tong)液通過(guo)保溫爐(lu)、溜槽(cao)、中(zhong)間包(bao),從澆管進入(ru)封閉的(de)(de)模腔內(nei),采用較大的(de)(de)冷卻強度進行(xing)冷卻,形成鑄坯,然(ran)后(hou)進行(xing)多(duo)道次(ci)軋制(zhi),生(sheng)產的(de)(de)低(di)氧銅(tong)(tong)(tong)桿為熱加(jia)工(gong)組(zu)織(zhi)(zhi),原來的(de)(de)鑄造組(zu)織(zhi)(zhi)已經破碎,含氧量一(yi)般(ban)為200~400ppm之間。無氧銅(tong)(tong)(tong)桿國內(nei)基本全部采用上(shang)引(yin)連(lian)(lian)鑄法(fa)(fa)生(sheng)產,金屬(shu)在(zai)感(gan)應(ying)電(dian)(dian)爐(lu)中(zhong)融化(hua)后(hou)通過(guo)石墨(mo)模進行(xing)上(shang)引(yin)連(lian)(lian)續鑄造,之后(hou)進行(xing)冷軋或冷加(jia)工(gong),生(sheng)產的(de)(de)無氧銅(tong)(tong)(tong)桿為鑄造組(zu)織(zhi)(zhi),含氧量一(yi)般(ban)在(zai)20ppm以下。由于制(zhi)造工(gong)藝的(de)(de)不同,所以在(zai)組(zu)織(zhi)(zhi)結構、氧含量分(fen)布(bu)、雜(za)質(zhi)的(de)(de)形式及分(fen)布(bu)等諸多(duo)方(fang)面有較大差別。

一、拉制性能

銅桿的拉制(zhi)(zhi)性能跟(gen)很多因素(su)有關,如(ru)雜質(zhi)的含(han)量、氧含(han)量及(ji)分(fen)(fen)布、工藝(yi)控(kong)制(zhi)(zhi)等。下面分(fen)(fen)別從(cong)以上(shang)幾(ji)個方面對銅桿的拉制(zhi)(zhi)性能進行分(fen)(fen)析。

1、熔化(hua)方(fang)式對S等雜質的(de)影(ying)響

連(lian)鑄連(lian)軋(ya)生產(chan)銅桿(gan)主要是(shi)通過(guo)氣體的燃(ran)燒(shao)使銅桿(gan)熔(rong)化,在(zai)燃(ran)燒(shao)的過(guo)程中(zhong)(zhong),通過(guo)氧(yang)化和揮發(fa)作用,可一(yi)定程度(du)減少(shao)部(bu)分雜質進入(ru)銅液,因(yin)此連(lian)鑄連(lian)軋(ya)法(fa)對(dui)(dui)原(yuan)料要求(qiu)相對(dui)(dui)低一(yi)些。上(shang)引(yin)連(lian)鑄生產(chan)無氧(yang)銅桿(gan),由于是(shi)用感應電爐(lu)熔(rong)化,電解銅表面的“銅綠”“銅豆(dou)”基本(ben)都熔(rong)入(ru)到銅液中(zhong)(zhong)。其中(zhong)(zhong)熔(rong)入(ru)的S對(dui)(dui)無氧(yang)銅桿(gan)塑性影響(xiang)極大,會(hui)增加(jia)拉絲斷線率。

2、鑄造過程中雜質的進入

在生(sheng)產過程中(zhong),連(lian)鑄連(lian)軋(ya)(ya)工藝(yi)需(xu)通(tong)過保(bao)溫爐、溜槽(cao)、中(zhong)間包轉(zhuan)運銅液,相對(dui)容易(yi)造成耐(nai)火材料(liao)的(de)(de)(de)剝落,在軋(ya)(ya)制過程中(zhong)需(xu)要通(tong)過軋(ya)(ya)輥(gun),造成鐵質的(de)(de)(de)脫(tuo)落,會給(gei)銅桿造成外部夾雜。而熱軋(ya)(ya)中(zhong)皮(pi)上和皮(pi)下氧(yang)(yang)化物的(de)(de)(de)軋(ya)(ya)入(ru),會給(gei)低氧(yang)(yang)桿的(de)(de)(de)拉絲造成不利的(de)(de)(de)影(ying)響。上引(yin)連(lian)鑄法(fa)生(sheng)產工藝(yi)流程較短,銅液是通(tong)過聯(lian)體爐內(nei)潛流式完成,對(dui)耐(nai)火材料(liao)的(de)(de)(de)沖(chong)擊(ji)不大,結晶(jing)是通(tong)過石墨模內(nei)進(jin)行,所(suo)以過程中(zhong)可(ke)能產生(sheng)的(de)(de)(de)污(wu)染源(yuan)較少(shao),雜質進(jin)入(ru)的(de)(de)(de)機(ji)會較少(shao)。

O、S、P是(shi)與銅(tong)(tong)(tong)會生(sheng)產(chan)化(hua)合物的(de)(de)元素。在(zai)熔態銅(tong)(tong)(tong)中(zhong),氧(yang)(yang)可(ke)以溶(rong)解一部分(fen)(fen),但(dan)當銅(tong)(tong)(tong)冷凝時(shi),氧(yang)(yang)幾乎不(bu)溶(rong)解于銅(tong)(tong)(tong)中(zhong)。熔態時(shi)所(suo)溶(rong)解的(de)(de)氧(yang)(yang),以銅(tong)(tong)(tong)=氧(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共晶(jing)體析出(chu),分(fen)(fen)布在(zai)晶(jing)粒晶(jing)界處。銅(tong)(tong)(tong)-氧(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共晶(jing)體的(de)(de)出(chu)現,顯著(zhu)降(jiang)低了銅(tong)(tong)(tong)的(de)(de)塑性。

硫(liu)可以溶解在(zai)熔體(ti)的銅中,但在(zai)室溫下,其(qi)溶解度(du)幾(ji)乎降低(di)到(dao)零,它以硫(liu)化亞銅的形(xing)式出現在(zai)晶粒晶界(jie)處,會顯著(zhu)降低(di)銅的塑性。

3、氧(yang)在(zai)低氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)中分(fen)布(bu)形式(shi)及(ji)其影響

氧(yang)含量對(dui)低氧(yang)銅桿(gan)的(de)(de)拉(la)線(xian)性能有(you)著明顯的(de)(de)影響。當氧(yang)含量增(zeng)加到最(zui)佳值時,銅桿(gan)的(de)(de)斷(duan)線(xian)率最(zui)低。這(zhe)是因為氧(yang)在與大部分雜質反應的(de)(de)過程中(zhong)都起到了清除(chu)器的(de)(de)作用。適度的(de)(de)氧(yang)還有(you)利于去除(chu)銅液中(zhong)的(de)(de)氫,生成水蒸氣(qi)溢出,減少氣(qi)孔的(de)(de)形成。最(zui)佳的(de)(de)氧(yang)含量為拉(la)線(xian)工藝提(ti)供了最(zui)好的(de)(de)條件(jian)。

低(di)氧(yang)(yang)(yang)銅(tong)桿氧(yang)(yang)(yang)化物(wu)(wu)的(de)(de)分(fen)(fen)布:在連(lian)續澆鑄中凝固的(de)(de)最初階段,散(san)熱(re)速率和(he)均勻(yun)(yun)冷卻是(shi)決定銅(tong)桿氧(yang)(yang)(yang)化物(wu)(wu)分(fen)(fen)布的(de)(de)主要(yao)因素。不均勻(yun)(yun)冷卻會引(yin)起銅(tong)桿內部結構本質上(shang)的(de)(de)差(cha)異,但后續的(de)(de)熱(re)加工,柱狀晶通常會遭到破壞,使(shi)氧(yang)(yang)(yang)化亞銅(tong)顆粒細微化和(he)均勻(yun)(yun)分(fen)(fen)布。氧(yang)(yang)(yang)化物(wu)(wu)顆粒聚集(ji)而產生(sheng)的(de)(de)典(dian)型情況是(shi)中心(xin)爆裂。除氧(yang)(yang)(yang)化物(wu)(wu)顆粒分(fen)(fen)布的(de)(de)影(ying)響(xiang)外,具有較小(xiao)氧(yang)(yang)(yang)化物(wu)(wu)顆粒的(de)(de)銅(tong)桿顯示出較好的(de)(de)拉(la)線特性,較大的(de)(de)Cu2O顆粒容易造成應(ying)力集(ji)中點而斷裂。

無(wu)氧(yang)(yang)銅(tong)(tong)含(han)氧(yang)(yang)量(liang)(liang)超標,銅(tong)(tong)桿(gan)(gan)變(bian)(bian)脆(cui),延伸率(lv)下降(jiang),拉伸式樣(yang)端(duan)口顯暗紅色(se),結晶組織疏(shu)松。當(dang)氧(yang)(yang)含(han)量(liang)(liang)超出(chu)8ppm時(shi)(shi),工(gong)藝(yi)性(xing)能變(bian)(bian)差,表現為鑄造(zao)及拉伸過(guo)程(cheng)中斷(duan)桿(gan)(gan)及斷(duan)線率(lv)極具(ju)增高。這是(shi)由于氧(yang)(yang)能與銅(tong)(tong)生成(cheng)氧(yang)(yang)化亞銅(tong)(tong)脆(cui)性(xing)相(xiang),形成(cheng)銅(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)共晶體,以網(wang)狀(zhuang)組織分布(bu)在境界上(shang)。這種脆(cui)性(xing)相(xiang)硬度高,在冷變(bian)(bian)形時(shi)(shi)將會(hui)與銅(tong)(tong)機體脫離(li),導致銅(tong)(tong)桿(gan)(gan)的機械性(xing)能下降(jiang),在后續加工(gong)中容易造(zao)成(cheng)斷(duan)裂現象。氧(yang)(yang)含(han)量(liang)(liang)高還能導致無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)導電率(lv)下降(jiang)。因此,必須嚴格控制上(shang)引連鑄工(gong)藝(yi)及產品質量(liang)(liang)。

4、氫的影響

在(zai)上引連鑄中,氧含量控(kong)制較(jiao)(jiao)低,氧化物的副作用唄**降低,但氫的影響成為較(jiao)(jiao)顯著的問(wen)題。吸氣后熔體中存在(zai)平衡反(fan)應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)體(ti)及疏(shu)松是(shi)在結晶(jing)的(de)過(guo)程中(zhong),氫(qing)從過(guo)飽和的(de)溶(rong)液中(zhong)析(xi)出(chu)并聚集而形(xing)成(cheng)(cheng)(cheng)的(de)。在結晶(jing)前析(xi)出(chu)的(de)氫(qing)又可(ke)還原氧化亞銅而生成(cheng)(cheng)(cheng)水氣(qi)(qi)(qi)泡。由(you)于(yu)上(shang)引(yin)(yin)鑄(zhu)(zhu)造(zao)的(de)特點是(shi)銅液自上(shang)而下的(de)結晶(jing),形(xing)成(cheng)(cheng)(cheng)的(de)液**形(xing)狀近(jin)似錐型。銅液結晶(jing)前析(xi)出(chu)的(de)氣(qi)(qi)(qi)體(ti)在上(shang)浮過(guo)程中(zhong)被堵(du)在凝(ning)固組(zu)織內,結晶(jing)時在鑄(zhu)(zhu)桿內形(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔(kong)。上(shang)引(yin)(yin)的(de)含(han)氣(qi)(qi)(qi)量少時,析(xi)出(chu)的(de)氫(qing)存在于(yu)晶(jing)界處,形(xing)成(cheng)(cheng)(cheng)疏(shu)松;含(han)氣(qi)(qi)(qi)量多時,則聚集成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔(kong),因此,氣(qi)(qi)(qi)孔(kong)和疏(shu)松是(shi)氫(qing)氣(qi)(qi)(qi)和水蒸氣(qi)(qi)(qi)兩者形(xing)成(cheng)(cheng)(cheng)的(de)。

氫來源(yuan)于上(shang)引生(sheng)產過(guo)程中的各個工藝(yi)環(huan)節(jie),如原料電解(jie)銅(tong)的“銅(tong)綠(lv)”、輔料木(mu)炭**、氣(qi)候環(huan)境**、石墨結晶(jing)器未干燥等。因此,熔化爐中的銅(tong)液表面應(ying)覆蓋(gai)經烘(hong)烤的木(mu)炭,電解(jie)銅(tong)應(ying)盡量去除“銅(tong)綠(lv)”、“銅(tong)豆”“耳朵”,對(dui)提(ti)高無氧(yang)銅(tong)桿質量非常重要。

在連(lian)鑄連(lian)軋(ya)工藝中(zhong),往(wang)往(wang)采用適度控制氧含(han)量(liang)來(lai)控制氫。Cu2O+ H2= 2Cu+ H2O

由(you)于銅(tong)液在(zai)鑄造(zao)過程(cheng)中(zhong)是自(zi)下而上結晶,銅(tong)液中(zhong)的氧和氫(qing)(qing)所產(chan)生的水蒸氣很容易(yi)上浮跑出(chu),銅(tong)液中(zhong)的氫(qing)(qing)大部分能(neng)被有效去除,因而對銅(tong)桿(gan)的影響(xiang)較小。

二、表面質量

在生(sheng)產電磁線等產品的(de)過程中,對銅(tong)桿的(de)表面質量也(ye)需提出要求。需要拉(la)制后(hou)的(de)銅(tong)絲表面無毛刺、銅(tong)粉少、無油(you)污。并通過扭轉(zhuan)(zhuan)試驗測量表面銅(tong)粉的(de)質量和扭轉(zhuan)(zhuan)后(hou)觀察(cha)銅(tong)桿的(de)復原情況來判定其好壞。

在連(lian)鑄(zhu)連(lian)軋(ya)過(guo)程中(zhong),從鑄(zhu)造到軋(ya)制前,溫(wen)度高,完全暴露于空氣(qi)中(zhong),使(shi)鑄(zhu)坯(pi)表面形成(cheng)較厚的(de)氧(yang)化層(ceng),在軋(ya)制過(guo)程中(zhong),隨著軋(ya)輥的(de)轉動,氧(yang)化物(wu)顆(ke)粒軋(ya)入銅線(xian)表面。由于氧(yang)化亞(ya)銅是高熔點(dian)脆性化合物(wu),對于軋(ya)入較深的(de)氧(yang)化亞(ya)銅,當成(cheng)條(tiao)狀的(de)聚(ju)集物(wu)遇模具拉伸時,就(jiu)會(hui)是銅桿外表面產生毛刺,給后續的(de)涂漆造成(cheng)麻煩。

而上引連鑄工藝制(zhi)造的(de)無氧(yang)銅(tong)桿,由(you)于鑄造和(he)冷卻完全與氧(yang)隔絕,后(hou)續亦(yi)無熱軋過(guo)程,銅(tong)桿表(biao)面無軋入(ru)表(biao)面的(de)氧(yang)化物,質(zhi)量較(jiao)好,拉制(zhi)后(hou)銅(tong)粉(fen)少,上述問(wen)題較(jiao)少存在。

無氧銅(tong)(tong)桿(gan)也分進口設(she)(she)備(bei)(bei)做的(de)和國(guo)產設(she)(she)備(bei)(bei)做的(de),但目前(qian)進口產品(pin)已無明顯優勢,銅(tong)(tong)桿(gan)產品(pin)出來后區別不(bu)是(shi)很大,只(zhi)要銅(tong)(tong)板選的(de)好,生產控(kong)制比(bi)較穩定,國(guo)產設(she)(she)備(bei)(bei)也能產出可拉伸0.05的(de)銅(tong)(tong)桿(gan).進口設(she)(she)備(bei)(bei)一般(ban)是(shi)芬(fen)蘭奧托昆普(pu)的(de)設(she)(she)備(bei)(bei),國(guo)產設(she)(she)備(bei)(bei)最好的(de)應該(gai)是(shi)上海(hai)的(de)海(hai)軍廠的(de)了,生產時間最長(chang),軍工企業,質量可靠。

低(di)氧銅(tong)桿(gan)進口(kou)設備(bei)(bei)國(guo)際(ji)主要有兩種(zhong)(zhong),一(yi)(yi)種(zhong)(zhong)是美國(guo)南線(xian)設備(bei)(bei),英文(wen)是SOUTHWIRE,國(guo)內廠家是南京華新(xin),江(jiang)西銅(tong)業,另一(yi)(yi)種(zhong)(zhong)是德(de)國(guo)CONTIROD設備(bei)(bei),國(guo)內廠家是常州金源,天(tian)津(jin)大無縫(feng)。

無(wu)氧(yang)(yang)(yang)(yang)及(ji)低(di)(di)氧(yang)(yang)(yang)(yang)桿從含(han)(han)氧(yang)(yang)(yang)(yang)量上(shang)容易區別,無(wu)氧(yang)(yang)(yang)(yang)銅是含(han)(han)氧(yang)(yang)(yang)(yang)量在10-20個(ge)PPM以下,但(dan)(dan)目前有(you)的(de)(de)廠(chang)家只能(neng)(neng)做(zuo)到(dao)50個(ge)PPM以下.低(di)(di)氧(yang)(yang)(yang)(yang)銅桿在 200-400個(ge)PPM,好的(de)(de)桿子(zi)一(yi)般(ban)含(han)(han)氧(yang)(yang)(yang)(yang)量控(kong)制在250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)桿一(yi)般(ban)采取的(de)(de)是上(shang)引法,低(di)(di)氧(yang)(yang)(yang)(yang)桿是連鑄連軋,兩種產品相對(dui)(dui)(dui)而(er)(er)言低(di)(di)氧(yang)(yang)(yang)(yang)桿對(dui)(dui)(dui)漆包線性 能(neng)(neng)更適應(ying)些,如柔軟性,回彈角(jiao),繞線性能(neng)(neng).但(dan)(dan)低(di)(di)氧(yang)(yang)(yang)(yang)桿對(dui)(dui)(dui)拉(la)(la)絲(si)(si)條(tiao)件(jian)(jian)相對(dui)(dui)(dui)要苛刻(ke)些,同樣拉(la)(la)伸(shen)0.2的(de)(de)細絲(si)(si),如果伸(shen)線條(tiao)件(jian)(jian)不(bu)好,普(pu)通(tong)的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)桿可(ke)拉(la)(la)而(er)(er)好的(de)(de)低(di)(di)氧(yang)(yang)(yang)(yang)桿就斷 線,但(dan)(dan)如果放在好的(de)(de)伸(shen)線條(tiao)件(jian)(jian),同樣的(de)(de)桿子(zi),低(di)(di)氧(yang)(yang)(yang)(yang)桿說不(bu)定就能(neng)(neng)拉(la)(la)到(dao)雙零(ling)五(wu),而(er)(er)普(pu)通(tong)無(wu)氧(yang)(yang)(yang)(yang)桿最(zui)多只能(neng)(neng)拉(la)(la)伸(shen)到(dao)0.1而(er)(er)已,當然做(zuo)的(de)(de)最(zui)細的(de)(de)如雙零(ling)二卻非得依靠(kao)進口的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)銅桿了.目前有(you)企業嘗試用剝(bo)皮的(de)(de)方(fang)式(shi)來(lai)處(chu)理低(di)(di)氧(yang)(yang)(yang)(yang)桿來(lai)伸(shen)0.03線.但(dan)(dan)有(you)關這方(fang)面(mian)的(de)(de)內容我還不(bu)是很(hen)清楚。

音響線一般反而喜歡(huan)用(yong)無氧桿,這和無氧桿是(shi)單晶銅,低氧桿是(shi)多晶銅有關。

氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿由于制造方法的不同,致使(shi)存在差(cha)別,具有各(ge)自的特點。

一(yi)、關(guan)于氧的(de)吸入(ru)和脫(tuo)去以及它的(de)存在狀態

生產(chan)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)(yi)般(ban)(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)(yi)般(ban)(ban)在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)進入是在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)液態(tai)下吸入的(de)(de),而上(shang)引法無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則相反,氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)下保持相當時間(jian)后(hou),被還原而脫去,通常(chang)(chang)這(zhe)種桿(gan)的(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)10—50ppm以(yi)下,最(zui)低(di)可達1-2ppm,從組(zu)(zu)織(zhi)(zhi)上(shang)看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)于晶粒邊界附近,這(zhe)對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)而言(yan)可以(yi)說是常(chang)(chang)見的(de)(de)但(dan)對(dui)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則很少見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)以(yi)夾雜形式(shi)在(zai)(zai)晶界出(chu)現對(dui)材料的(de)(de)韌性(xing)產(chan)生負(fu)面(mian)影響。而無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所(suo)以(yi)這(zhe)種銅(tong)(tong)(tong)(tong)(tong)的(de)(de)組(zu)(zu)織(zhi)(zhi)是均勻的(de)(de)單相組(zu)(zu)織(zhi)(zhi)對(dui)韌性(xing)有(you)利。在(zai)(zai)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)多(duo)孔性(xing)是不常(chang)(chang)見的(de)(de),而在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中則是常(chang)(chang)見的(de)(de)一(yi)(yi)種缺陷(xian)。

二、熱軋組織和鑄造組織的區別(bie)

低氧(yang)(yang)(yang)銅(tong)桿由于(yu)經過(guo)熱(re)軋,所(suo)以(yi)(yi)其(qi)組(zu)(zu)織屬熱(re)加工組(zu)(zu)織,原(yuan)來的(de)(de)(de)(de)(de)鑄造(zao)組(zu)(zu)織已經破碎,在8mm的(de)(de)(de)(de)(de)桿時已有(you)再(zai)結晶(jing)(jing)的(de)(de)(de)(de)(de)形式(shi)出現,而(er)無氧(yang)(yang)(yang)銅(tong)桿屬鑄造(zao)組(zu)(zu)織,晶(jing)(jing)粒(li)粗(cu)大,這是為什(shen)么,無氧(yang)(yang)(yang)銅(tong)的(de)(de)(de)(de)(de)再(zai)結晶(jing)(jing)溫度較(jiao)(jiao)(jiao)高(gao),需要(yao)較(jiao)(jiao)(jiao)高(gao)退(tui)火溫度的(de)(de)(de)(de)(de)固有(you)原(yuan)因(yin)。這是因(yin)為,再(zai)結晶(jing)(jing)發生在晶(jing)(jing)粒(li)邊(bian)界(jie)附近,無氧(yang)(yang)(yang)銅(tong)桿組(zu)(zu)織晶(jing)(jing)粒(li)粗(cu)大,晶(jing)(jing)粒(li)尺寸(cun)甚至能達幾個毫米,因(yin)而(er)晶(jing)(jing)粒(li)邊(bian)界(jie)少,即使通過(guo)拉制(zhi)變形,但晶(jing)(jing)粒(li)邊(bian)界(jie)相對低氧(yang)(yang)(yang)銅(tong)桿還是較(jiao)(jiao)(jiao)少,所(suo)以(yi)(yi)需要(yao)較(jiao)(jiao)(jiao)高(gao)的(de)(de)(de)(de)(de)退(tui)火功(gong)率。對無氧(yang)(yang)(yang)銅(tong)成(cheng)功(gong)的(de)(de)(de)(de)(de)退(tui)火要(yao)求是:由桿經拉制(zhi),但尚未鑄造(zao)組(zu)(zu)織的(de)(de)(de)(de)(de)線(xian)時的(de)(de)(de)(de)(de)第一(yi)次退(tui)火,其(qi)退(tui)火功(gong)率應比同樣(yang)情況(kuang)的(de)(de)(de)(de)(de)低氧(yang)(yang)(yang)銅(tong)高(gao)10——15%。經繼續拉制(zhi),在以(yi)(yi)后階段的(de)(de)(de)(de)(de)退(tui)火功(gong)率應留有(you)足夠的(de)(de)(de)(de)(de)余量和(he)對低氧(yang)(yang)(yang)銅(tong)和(he)無氧(yang)(yang)(yang)銅(tong)切實(shi)區別執行不同的(de)(de)(de)(de)(de)退(tui)火工藝,以(yi)(yi)保(bao)證在制(zhi)品(pin)和(he)成(cheng)品(pin)導(dao)線(xian)的(de)(de)(de)(de)(de)柔軟性。

三(san)、夾雜,氧(yang)含量(liang)波(bo)動(dong),表面氧(yang)化物和可能(neng)存在的熱軋缺陷的差別

無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)可(ke)拉(la)性在(zai)所有線徑里與低氧(yang)(yang)(yang)銅(tong)桿(gan)相比(bi)都(dou)是優(you)越的(de),除(chu)上述組(zu)織原(yuan)因外,無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)夾雜(za)少(shao),含氧(yang)(yang)(yang)量穩定,無(wu)熱軋可(ke)能產生的(de)缺(que)陷,桿(gan)表(biao)氧(yang)(yang)(yang)化物(wu)(wu)厚度可(ke)達≤15A。在(zai)連鑄連軋生產過程中如果(guo)工藝不穩定,對(dui)氧(yang)(yang)(yang)監控不嚴,含氧(yang)(yang)(yang)量不穩定將直(zhi)接(jie)影(ying)(ying)響桿(gan)的(de)性能。如果(guo)桿(gan)的(de)表(biao)面(mian)氧(yang)(yang)(yang)化物(wu)(wu)能在(zai)后工序(xu)的(de)連續清洗中得以彌補外,但比(bi)較麻煩(fan)的(de)是有相當(dang)多的(de)氧(yang)(yang)(yang)化物(wu)(wu)存在(zai)于“皮(pi)下”,對(dui)拉(la)線斷(duan)(duan)線影(ying)(ying)響更直(zhi)接(jie),故而在(zai)拉(la)制微細線,超微細線時,為了(le)減少(shao)斷(duan)(duan)線,有時要(yao)對(dui)銅(tong)桿(gan)采取不得已的(de)辦法——剝(bo)皮(pi),甚至二次剝(bo)皮(pi)的(de)原(yuan)因所在(zai),目的(de)要(yao)除(chu)去(qu)皮(pi)下氧(yang)(yang)(yang)化物(wu)(wu)。

四、低氧銅桿和無氧銅桿的韌性有差(cha)別

兩者(zhe)都可以拉到0.015mm,但(dan)在低溫超導線中的低溫級無(wu)氧銅,其(qi)細絲間的間距只有0.001mm.

五、從制桿的原材(cai)料到制線的經濟性有差別。

制(zhi)造無(wu)氧(yang)銅桿(gan)要求質(zhi)量較高的原(yuan)材(cai)料(liao)。一(yi)般,拉制(zhi)直徑>1mm的銅線時,低氧(yang)銅桿(gan)的優(you)(you)點(dian)比較明顯(xian)(xian),而無(wu)氧(yang)銅桿(gan)顯(xian)(xian)得更(geng)為(wei)優(you)(you)越的是拉制(zhi)直徑<0.5mm的銅線。

六、低氧銅桿的制線工(gong)藝(yi)與無(wu)氧銅桿的有所不同。

低氧(yang)(yang)銅桿(gan)的(de)制線(xian)工藝不能照(zhao)搬到無氧(yang)(yang)銅桿(gan)的(de)制線(xian)工藝上來(lai),至少兩者的(de)退(tui)火工藝是不同的(de)。因(yin)為(wei)線(xian)的(de)柔軟性深(shen)受材料成份和(he)制桿(gan),制線(xian)和(he)退(tui)火工藝的(de)影(ying)響,不能簡單地說低氧(yang)(yang)銅或無氧(yang)(yang)銅誰軟誰硬。