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凌海電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行(xing)業動態 閱(yue)讀:109450 發布時間:2019-07-05

導讀:由于生(sheng)(sheng)產銅桿(gan)(gan)(gan)的(de)(de)兩者(zhe)的(de)(de)工藝(yi)不(bu)同,所生(sheng)(sheng)產的(de)(de)銅桿(gan)(gan)(gan)中的(de)(de)含(han)氧(yang)量及(ji)外(wai)觀就不(bu)同。上引生(sheng)(sheng)產的(de)(de)銅桿(gan)(gan)(gan),工藝(yi)得當氧(yang)含(han)量在10ppm以下,叫(jiao)無(wu)氧(yang)銅桿(gan)(gan)(gan);連鑄(zhu)連鑄(zhu)生(sheng)(sheng)產的(de)(de)銅桿(gan)(gan)(gan) 是在保(bao)護條(tiao)件下的(de)(de)熱(re)軋,氧(yang)含(han)量在200-500ppm范圍內,但有(you)時(shi)也高達700ppm以上,一(yi)般情況下,此種方法生(sheng)(sheng)產的(de)(de)銅外(wai)表光亮,低氧(yang)銅桿(gan)(gan)(gan),有(you)時(shi)也叫(jiao)光桿(gan)(gan)(gan)。

銅(tong)(tong)桿是(shi)電纜行(xing)業的(de)(de)主要原料,生產的(de)(de)方式主要有兩種——連(lian)鑄(zhu)(zhu)連(lian)軋法(fa)(fa)和上(shang)引連(lian)鑄(zhu)(zhu)法(fa)(fa)。連(lian)鑄(zhu)(zhu)連(lian)軋低(di)氧(yang)(yang)銅(tong)(tong)桿的(de)(de)生產方法(fa)(fa)較多(duo)(duo),其特點是(shi)金(jin)屬在豎爐(lu)中(zhong)融化后(hou),銅(tong)(tong)液(ye)通過保溫爐(lu)、溜槽(cao)、中(zhong)間包,從澆管進入封閉(bi)的(de)(de)模腔內,采用較大的(de)(de)冷卻強(qiang)度進行(xing)冷卻,形成鑄(zhu)(zhu)坯,然(ran)后(hou)進行(xing)多(duo)(duo)道次軋制,生產的(de)(de)低(di)氧(yang)(yang)銅(tong)(tong)桿為熱加工(gong)(gong)(gong)組織(zhi),原來的(de)(de)鑄(zhu)(zhu)造(zao)(zao)組織(zhi)已經破碎,含氧(yang)(yang)量(liang)(liang)(liang)一(yi)般為200~400ppm之間。無(wu)氧(yang)(yang)銅(tong)(tong)桿國內基本(ben)全部(bu)采用上(shang)引連(lian)鑄(zhu)(zhu)法(fa)(fa)生產,金(jin)屬在感(gan)應(ying)電爐(lu)中(zhong)融化后(hou)通過石墨(mo)模進行(xing)上(shang)引連(lian)續鑄(zhu)(zhu)造(zao)(zao),之后(hou)進行(xing)冷軋或冷加工(gong)(gong)(gong),生產的(de)(de)無(wu)氧(yang)(yang)銅(tong)(tong)桿為鑄(zhu)(zhu)造(zao)(zao)組織(zhi),含氧(yang)(yang)量(liang)(liang)(liang)一(yi)般在20ppm以下。由于制造(zao)(zao)工(gong)(gong)(gong)藝的(de)(de)不同,所以在組織(zhi)結構(gou)、氧(yang)(yang)含量(liang)(liang)(liang)分布、雜(za)質(zhi)的(de)(de)形式及(ji)分布等諸(zhu)多(duo)(duo)方面有較大差別。

一、拉制性能

銅(tong)桿的(de)拉(la)制(zhi)性能跟很多(duo)因素有關,如(ru)雜(za)質的(de)含(han)量、氧含(han)量及(ji)分(fen)布(bu)、工藝(yi)控制(zhi)等(deng)。下面分(fen)別(bie)從以上幾個方面對(dui)銅(tong)桿的(de)拉(la)制(zhi)性能進行分(fen)析。

1、熔化方式對S等雜質的(de)影響

連鑄(zhu)連軋生產銅桿主要是通過(guo)(guo)氣體的(de)燃燒使銅桿熔化,在燃燒的(de)過(guo)(guo)程中(zhong),通過(guo)(guo)氧化和揮發(fa)作用(yong)(yong),可(ke)一(yi)定程度減(jian)少部(bu)分(fen)雜質進入銅液,因(yin)此連鑄(zhu)連軋法對原(yuan)料(liao)要求相對低一(yi)些(xie)。上引連鑄(zhu)生產無氧銅桿,由于是用(yong)(yong)感應電爐(lu)熔化,電解銅表面的(de)“銅綠”“銅豆”基本都熔入到銅液中(zhong)。其中(zhong)熔入的(de)S對無氧銅桿塑性影響極大,會增加拉絲斷(duan)線率。

2、鑄造過程中(zhong)雜質的進入

在生(sheng)產過(guo)(guo)(guo)程中(zhong),連鑄(zhu)(zhu)連軋(ya)工藝需(xu)(xu)通(tong)過(guo)(guo)(guo)保溫爐、溜槽、中(zhong)間(jian)包轉運(yun)銅液,相(xiang)對(dui)容易造成(cheng)耐(nai)火(huo)材料(liao)的(de)(de)(de)剝落(luo),在軋(ya)制過(guo)(guo)(guo)程中(zhong)需(xu)(xu)要通(tong)過(guo)(guo)(guo)軋(ya)輥(gun),造成(cheng)鐵質的(de)(de)(de)脫(tuo)落(luo),會給(gei)銅桿造成(cheng)外(wai)部夾雜。而(er)熱軋(ya)中(zhong)皮上(shang)(shang)和皮下氧(yang)(yang)化物(wu)的(de)(de)(de)軋(ya)入,會給(gei)低氧(yang)(yang)桿的(de)(de)(de)拉絲造成(cheng)不利的(de)(de)(de)影響。上(shang)(shang)引(yin)連鑄(zhu)(zhu)法(fa)生(sheng)產工藝流(liu)程較短,銅液是通(tong)過(guo)(guo)(guo)聯(lian)體爐內潛流(liu)式完成(cheng),對(dui)耐(nai)火(huo)材料(liao)的(de)(de)(de)沖擊不大,結(jie)晶是通(tong)過(guo)(guo)(guo)石墨模內進(jin)行,所以過(guo)(guo)(guo)程中(zhong)可能產生(sheng)的(de)(de)(de)污染(ran)源較少,雜質進(jin)入的(de)(de)(de)機會較少。

O、S、P是與銅(tong)會生(sheng)產化合物的(de)元素。在(zai)熔(rong)態(tai)銅(tong)中,氧(yang)可以(yi)溶(rong)解(jie)(jie)(jie)一部(bu)分(fen),但當銅(tong)冷凝時(shi),氧(yang)幾(ji)乎不溶(rong)解(jie)(jie)(jie)于銅(tong)中。熔(rong)態(tai)時(shi)所溶(rong)解(jie)(jie)(jie)的(de)氧(yang),以(yi)銅(tong)=氧(yang)化亞銅(tong)共晶(jing)(jing)體(ti)析出,分(fen)布在(zai)晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)-氧(yang)化亞銅(tong)共晶(jing)(jing)體(ti)的(de)出現,顯(xian)著(zhu)降低了(le)銅(tong)的(de)塑性。

硫(liu)可以溶解(jie)在熔體的銅(tong)中,但在室溫(wen)下,其溶解(jie)度幾乎(hu)降低到(dao)零,它以硫(liu)化亞銅(tong)的形式(shi)出現在晶(jing)粒晶(jing)界處,會(hui)顯著降低銅(tong)的塑性。

3、氧(yang)在低(di)氧(yang)銅桿(gan)和(he)無氧(yang)銅桿(gan)中分布形式及其影(ying)響

氧(yang)(yang)含(han)量(liang)對低氧(yang)(yang)銅(tong)桿的(de)(de)拉線性(xing)能有著明顯的(de)(de)影(ying)響。當氧(yang)(yang)含(han)量(liang)增加到(dao)最(zui)(zui)(zui)佳值(zhi)時,銅(tong)桿的(de)(de)斷線率最(zui)(zui)(zui)低。這是因為氧(yang)(yang)在與大(da)部分雜質反應(ying)的(de)(de)過程中都起到(dao)了清除器(qi)的(de)(de)作用。適度的(de)(de)氧(yang)(yang)還有利(li)于去(qu)除銅(tong)液中的(de)(de)氫,生成(cheng)(cheng)水蒸氣溢(yi)出(chu),減少(shao)氣孔的(de)(de)形(xing)成(cheng)(cheng)。最(zui)(zui)(zui)佳的(de)(de)氧(yang)(yang)含(han)量(liang)為拉線工藝提供(gong)了最(zui)(zui)(zui)好(hao)的(de)(de)條(tiao)件。

低(di)氧(yang)(yang)銅(tong)桿氧(yang)(yang)化物(wu)(wu)的(de)分(fen)布(bu):在連續澆(jiao)鑄中(zhong)凝固的(de)最初階段,散(san)熱速率和均(jun)勻冷卻是(shi)決(jue)定銅(tong)桿氧(yang)(yang)化物(wu)(wu)分(fen)布(bu)的(de)主要因素(su)。不均(jun)勻冷卻會引起銅(tong)桿內部結構本(ben)質(zhi)上(shang)的(de)差異,但后續的(de)熱加工,柱狀晶(jing)通(tong)常會遭到破壞(huai),使氧(yang)(yang)化亞銅(tong)顆(ke)粒(li)(li)細微化和均(jun)勻分(fen)布(bu)。氧(yang)(yang)化物(wu)(wu)顆(ke)粒(li)(li)聚(ju)集(ji)而(er)產(chan)生的(de)典型(xing)情況是(shi)中(zhong)心(xin)爆裂。除氧(yang)(yang)化物(wu)(wu)顆(ke)粒(li)(li)分(fen)布(bu)的(de)影響外,具有較小氧(yang)(yang)化物(wu)(wu)顆(ke)粒(li)(li)的(de)銅(tong)桿顯示出較好(hao)的(de)拉線特性(xing),較大的(de)Cu2O顆(ke)粒(li)(li)容易造成應(ying)力集(ji)中(zhong)點(dian)而(er)斷裂。

無氧銅含氧量(liang)(liang)超標,銅桿變(bian)脆(cui),延伸率(lv)(lv)(lv)下降(jiang),拉伸式樣端口顯暗紅色,結晶組織疏松。當氧含量(liang)(liang)超出(chu)8ppm時,工藝性(xing)能(neng)變(bian)差,表現為鑄(zhu)造(zao)及(ji)拉伸過程中斷(duan)桿及(ji)斷(duan)線率(lv)(lv)(lv)極具增高(gao)。這是由于氧能(neng)與銅生成氧化(hua)亞(ya)銅脆(cui)性(xing)相,形成銅-氧化(hua)亞(ya)銅共晶體,以網狀組織分(fen)布(bu)在(zai)境界上(shang)。這種(zhong)脆(cui)性(xing)相硬度高(gao),在(zai)冷變(bian)形時將會與銅機體脫(tuo)離,導(dao)致(zhi)銅桿的機械(xie)性(xing)能(neng)下降(jiang),在(zai)后續加工中容易造(zao)成斷(duan)裂現象。氧含量(liang)(liang)高(gao)還(huan)能(neng)導(dao)致(zhi)無氧銅桿導(dao)電率(lv)(lv)(lv)下降(jiang)。因(yin)此(ci),必須嚴格控制上(shang)引連鑄(zhu)工藝及(ji)產品質量(liang)(liang)。

4、氫的影響

在(zai)上(shang)引(yin)連鑄(zhu)中,氧(yang)含量控制較(jiao)低,氧(yang)化物(wu)的副作用唄**降低,但氫(qing)的影響成為較(jiao)顯著(zhu)的問題。吸(xi)氣后熔體中存在(zai)平(ping)衡(heng)反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)體及疏(shu)松(song)(song)是(shi)在(zai)(zai)結(jie)晶(jing)的(de)(de)(de)過(guo)程中,氫從過(guo)飽(bao)和的(de)(de)(de)溶液(ye)中析出并(bing)聚集而形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)。在(zai)(zai)結(jie)晶(jing)前析出的(de)(de)(de)氫又可還原氧化亞(ya)銅(tong)而生成(cheng)(cheng)水(shui)氣(qi)(qi)(qi)泡。由于上引鑄造(zao)的(de)(de)(de)特點是(shi)銅(tong)液(ye)自上而下的(de)(de)(de)結(jie)晶(jing),形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)液(ye)**形(xing)(xing)狀近似錐型。銅(tong)液(ye)結(jie)晶(jing)前析出的(de)(de)(de)氣(qi)(qi)(qi)體在(zai)(zai)上浮過(guo)程中被堵在(zai)(zai)凝固組織內,結(jie)晶(jing)時(shi)在(zai)(zai)鑄桿(gan)內形(xing)(xing)成(cheng)(cheng)氣(qi)(qi)(qi)孔。上引的(de)(de)(de)含(han)氣(qi)(qi)(qi)量(liang)少時(shi),析出的(de)(de)(de)氫存在(zai)(zai)于晶(jing)界處,形(xing)(xing)成(cheng)(cheng)疏(shu)松(song)(song);含(han)氣(qi)(qi)(qi)量(liang)多時(shi),則(ze)聚集成(cheng)(cheng)氣(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)孔和疏(shu)松(song)(song)是(shi)氫氣(qi)(qi)(qi)和水(shui)蒸氣(qi)(qi)(qi)兩者形(xing)(xing)成(cheng)(cheng)的(de)(de)(de)。

氫來源于上引生產過程(cheng)中的(de)各個(ge)工藝環(huan)節,如原料電解(jie)銅(tong)的(de)“銅(tong)綠”、輔料木(mu)炭**、氣候(hou)環(huan)境**、石墨(mo)結晶器未干(gan)燥(zao)等。因此,熔化(hua)爐中的(de)銅(tong)液表面應覆蓋經烘烤(kao)的(de)木(mu)炭,電解(jie)銅(tong)應盡(jin)量去(qu)除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對(dui)提(ti)高無氧銅(tong)桿質量非常重要。

在連鑄連軋(ya)工藝中,往(wang)往(wang)采用適度控(kong)制氧(yang)含量來控(kong)制氫。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅(tong)(tong)液在鑄造過程中是(shi)自下而上結晶,銅(tong)(tong)液中的(de)(de)氧和氫所(suo)產生的(de)(de)水蒸(zheng)氣很容(rong)易上浮(fu)跑出(chu),銅(tong)(tong)液中的(de)(de)氫大部分能被有效去除(chu),因而對(dui)銅(tong)(tong)桿的(de)(de)影響較(jiao)小。

二、表面質量

在生(sheng)產電(dian)磁線等產品的過程中,對(dui)銅(tong)桿(gan)的表面質(zhi)量也需提(ti)出要求。需要拉制后(hou)的銅(tong)絲表面無毛刺、銅(tong)粉少、無油(you)污。并通過扭轉(zhuan)試驗(yan)測量表面銅(tong)粉的質(zhi)量和扭轉(zhuan)后(hou)觀(guan)察銅(tong)桿(gan)的復原(yuan)情(qing)況來判定(ding)其好壞。

在(zai)連鑄連軋(ya)(ya)(ya)過(guo)程(cheng)中(zhong),從鑄造到軋(ya)(ya)(ya)制前(qian),溫度高,完全暴露于空(kong)氣中(zhong),使鑄坯表面形成(cheng)較厚的氧化(hua)(hua)層,在(zai)軋(ya)(ya)(ya)制過(guo)程(cheng)中(zhong),隨(sui)著軋(ya)(ya)(ya)輥(gun)的轉動,氧化(hua)(hua)物顆粒軋(ya)(ya)(ya)入銅線表面。由于氧化(hua)(hua)亞銅是(shi)高熔點脆(cui)性化(hua)(hua)合物,對于軋(ya)(ya)(ya)入較深的氧化(hua)(hua)亞銅,當成(cheng)條狀的聚集(ji)物遇模具拉伸時,就會是(shi)銅桿外表面產生毛(mao)刺,給后續(xu)的涂(tu)漆造成(cheng)麻煩。

而上引連鑄工(gong)藝制(zhi)造的(de)(de)無氧(yang)銅桿,由于鑄造和冷卻完(wan)全與氧(yang)隔絕(jue),后(hou)續亦無熱軋過程,銅桿表面(mian)(mian)無軋入(ru)表面(mian)(mian)的(de)(de)氧(yang)化物,質量較好,拉制(zhi)后(hou)銅粉少,上述問題較少存在。

無氧銅(tong)桿也分進(jin)口設(she)備(bei)(bei)做(zuo)的(de)(de)和國(guo)產(chan)(chan)設(she)備(bei)(bei)做(zuo)的(de)(de),但目前(qian)進(jin)口產(chan)(chan)品已無明顯優勢,銅(tong)桿產(chan)(chan)品出來后區(qu)別不是很(hen)大(da),只要銅(tong)板選的(de)(de)好,生(sheng)(sheng)產(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)設(she)備(bei)(bei)也能產(chan)(chan)出可拉伸0.05的(de)(de)銅(tong)桿.進(jin)口設(she)備(bei)(bei)一(yi)般是芬蘭奧托昆(kun)普的(de)(de)設(she)備(bei)(bei),國(guo)產(chan)(chan)設(she)備(bei)(bei)最好的(de)(de)應該是上海(hai)的(de)(de)海(hai)軍廠(chang)的(de)(de)了,生(sheng)(sheng)產(chan)(chan)時間最長,軍工企業,質量可靠(kao)。

低(di)氧(yang)銅(tong)桿進口設(she)(she)備國(guo)(guo)(guo)際主要(yao)有兩種,一種是(shi)(shi)美(mei)國(guo)(guo)(guo)南線(xian)設(she)(she)備,英(ying)文(wen)是(shi)(shi)SOUTHWIRE,國(guo)(guo)(guo)內廠家是(shi)(shi)南京華(hua)新,江西銅(tong)業,另(ling)一種是(shi)(shi)德國(guo)(guo)(guo)CONTIROD設(she)(she)備,國(guo)(guo)(guo)內廠家是(shi)(shi)常州金源(yuan),天津大無(wu)縫(feng)。

無(wu)(wu)氧(yang)(yang)(yang)及低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)從含氧(yang)(yang)(yang)量(liang)上(shang)容易區別(bie),無(wu)(wu)氧(yang)(yang)(yang)銅是(shi)含氧(yang)(yang)(yang)量(liang)在10-20個PPM以下,但(dan)目前有的(de)(de)(de)廠(chang)家(jia)只能(neng)做到50個PPM以下.低(di)(di)(di)氧(yang)(yang)(yang)銅桿(gan)在 200-400個PPM,好的(de)(de)(de)桿(gan)子一(yi)般含氧(yang)(yang)(yang)量(liang)控(kong)制在250個PPM左右(you),無(wu)(wu)氧(yang)(yang)(yang)桿(gan)一(yi)般采取的(de)(de)(de)是(shi)上(shang)引(yin)法(fa),低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)是(shi)連鑄(zhu)連軋(ya),兩(liang)種產(chan)品相對而言低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)對漆包線(xian)(xian)(xian)(xian)性 能(neng)更適應(ying)些,如柔軟性,回彈角,繞線(xian)(xian)(xian)(xian)性能(neng).但(dan)低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)對拉(la)絲條(tiao)件(jian)(jian)相對要苛刻些,同樣(yang)拉(la)伸(shen)(shen)0.2的(de)(de)(de)細(xi)絲,如果伸(shen)(shen)線(xian)(xian)(xian)(xian)條(tiao)件(jian)(jian)不(bu)好,普通的(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)可拉(la)而好的(de)(de)(de)低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)就斷(duan) 線(xian)(xian)(xian)(xian),但(dan)如果放在好的(de)(de)(de)伸(shen)(shen)線(xian)(xian)(xian)(xian)條(tiao)件(jian)(jian),同樣(yang)的(de)(de)(de)桿(gan)子,低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)說不(bu)定就能(neng)拉(la)到雙零五,而普通無(wu)(wu)氧(yang)(yang)(yang)桿(gan)最多(duo)只能(neng)拉(la)伸(shen)(shen)到0.1而已,當然做的(de)(de)(de)最細(xi)的(de)(de)(de)如雙零二卻非得依靠進(jin)口的(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)了.目前有企業嘗(chang)試用剝皮(pi)的(de)(de)(de)方(fang)式來處(chu)理低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)來伸(shen)(shen)0.03線(xian)(xian)(xian)(xian).但(dan)有關(guan)這方(fang)面(mian)的(de)(de)(de)內容我還(huan)不(bu)是(shi)很清楚。

音響線(xian)一般反而喜歡用無氧(yang)(yang)桿(gan),這和無氧(yang)(yang)桿(gan)是單晶銅,低氧(yang)(yang)桿(gan)是多(duo)晶銅有關。

氧銅桿和無氧銅桿由于制造方(fang)法(fa)的(de)不(bu)同,致使存在差(cha)別,具有(you)各自(zi)的(de)特點(dian)。

一、關于氧(yang)的吸入和(he)脫(tuo)去以及它的存(cun)在(zai)狀態(tai)

生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)一(yi)(yi)般在(zai)10—50ppm,在(zai)常(chang)溫下(xia)(xia)氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)固(gu)溶度約2ppm。低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)一(yi)(yi)般在(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)進入是(shi)(shi)在(zai)銅(tong)(tong)(tong)(tong)的(de)(de)液(ye)態(tai)下(xia)(xia)吸入的(de)(de),而(er)(er)上(shang)引法無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)相反(fan),氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液(ye)態(tai)銅(tong)(tong)(tong)(tong)下(xia)(xia)保(bao)持(chi)相當(dang)時(shi)間后,被(bei)還原而(er)(er)脫去,通常(chang)這(zhe)(zhe)種桿(gan)(gan)的(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)都在(zai)10—50ppm以(yi)(yi)(yi)下(xia)(xia),最低可達1-2ppm,從組織(zhi)上(shang)看(kan),低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang),以(yi)(yi)(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態(tai),存在(zai)于晶(jing)(jing)粒邊(bian)界附近,這(zhe)(zhe)對(dui)低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)而(er)(er)言可以(yi)(yi)(yi)說是(shi)(shi)常(chang)見(jian)(jian)(jian)的(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)很少(shao)見(jian)(jian)(jian)。氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)(yi)(yi)夾雜形式(shi)在(zai)晶(jing)(jing)界出現對(dui)材料的(de)(de)韌性產生負面(mian)影(ying)響。而(er)(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)很低,所以(yi)(yi)(yi)這(zhe)(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)組織(zhi)是(shi)(shi)均勻的(de)(de)單相組織(zhi)對(dui)韌性有利(li)。在(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)的(de)(de)多孔性是(shi)(shi)不(bu)常(chang)見(jian)(jian)(jian)的(de)(de),而(er)(er)在(zai)低氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)則(ze)是(shi)(shi)常(chang)見(jian)(jian)(jian)的(de)(de)一(yi)(yi)種缺陷(xian)。

二(er)、熱(re)軋組織和(he)鑄造(zao)組織的區別

低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)由于(yu)經(jing)過(guo)(guo)熱(re)軋(ya),所以(yi)其組(zu)(zu)織屬熱(re)加工組(zu)(zu)織,原(yuan)來的(de)(de)(de)鑄(zhu)造組(zu)(zu)織已(yi)經(jing)破(po)碎,在(zai)8mm的(de)(de)(de)桿(gan)(gan)時(shi)已(yi)有(you)再結(jie)晶的(de)(de)(de)形(xing)式出現,而無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)屬鑄(zhu)造組(zu)(zu)織,晶粒(li)(li)粗(cu)大(da),這是(shi)為(wei)(wei)什(shen)么,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)的(de)(de)(de)再結(jie)晶溫度(du)較高(gao),需(xu)要較高(gao)退火(huo)溫度(du)的(de)(de)(de)固有(you)原(yuan)因。這是(shi)因為(wei)(wei),再結(jie)晶發生在(zai)晶粒(li)(li)邊(bian)(bian)界附近,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)組(zu)(zu)織晶粒(li)(li)粗(cu)大(da),晶粒(li)(li)尺寸甚至(zhi)能達幾個毫米,因而晶粒(li)(li)邊(bian)(bian)界少,即使(shi)通(tong)過(guo)(guo)拉制(zhi)變形(xing),但晶粒(li)(li)邊(bian)(bian)界相(xiang)對低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)還是(shi)較少,所以(yi)需(xu)要較高(gao)的(de)(de)(de)退火(huo)功率(lv)(lv)。對無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)成功的(de)(de)(de)退火(huo)要求是(shi):由桿(gan)(gan)經(jing)拉制(zhi),但尚未鑄(zhu)造組(zu)(zu)織的(de)(de)(de)線時(shi)的(de)(de)(de)第一次退火(huo),其退火(huo)功率(lv)(lv)應比同樣(yang)情況的(de)(de)(de)低(di)氧(yang)(yang)(yang)銅(tong)(tong)高(gao)10——15%。經(jing)繼(ji)續拉制(zhi),在(zai)以(yi)后階(jie)段的(de)(de)(de)退火(huo)功率(lv)(lv)應留有(you)足夠的(de)(de)(de)余量(liang)和對低(di)氧(yang)(yang)(yang)銅(tong)(tong)和無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)切實區別(bie)執行(xing)不(bu)同的(de)(de)(de)退火(huo)工藝,以(yi)保證(zheng)在(zai)制(zhi)品(pin)(pin)和成品(pin)(pin)導線的(de)(de)(de)柔軟(ruan)性。

三(san)、夾雜,氧含量波動,表面氧化物和可能存在的熱(re)軋缺陷的差(cha)別

無氧(yang)(yang)(yang)(yang)銅桿的可(ke)拉(la)性(xing)在(zai)(zai)所有(you)線(xian)(xian)徑里與低氧(yang)(yang)(yang)(yang)銅桿相比都是(shi)優越(yue)的,除上述組織原因外,無氧(yang)(yang)(yang)(yang)銅桿夾雜少,含氧(yang)(yang)(yang)(yang)量(liang)穩(wen)定,無熱軋(ya)可(ke)能產生的缺(que)陷,桿表氧(yang)(yang)(yang)(yang)化(hua)物(wu)厚度可(ke)達(da)≤15A。在(zai)(zai)連(lian)(lian)鑄連(lian)(lian)軋(ya)生產過程中如(ru)果(guo)(guo)工藝不(bu)(bu)(bu)穩(wen)定,對(dui)氧(yang)(yang)(yang)(yang)監控不(bu)(bu)(bu)嚴,含氧(yang)(yang)(yang)(yang)量(liang)不(bu)(bu)(bu)穩(wen)定將直(zhi)接(jie)(jie)影響(xiang)桿的性(xing)能。如(ru)果(guo)(guo)桿的表面氧(yang)(yang)(yang)(yang)化(hua)物(wu)能在(zai)(zai)后工序的連(lian)(lian)續清洗中得以(yi)彌補外,但比較麻煩的是(shi)有(you)相當多(duo)的氧(yang)(yang)(yang)(yang)化(hua)物(wu)存在(zai)(zai)于“皮(pi)下(xia)”,對(dui)拉(la)線(xian)(xian)斷(duan)線(xian)(xian)影響(xiang)更直(zhi)接(jie)(jie),故而(er)在(zai)(zai)拉(la)制微(wei)細(xi)線(xian)(xian),超微(wei)細(xi)線(xian)(xian)時,為了減少斷(duan)線(xian)(xian),有(you)時要對(dui)銅桿采取(qu)不(bu)(bu)(bu)得已的辦法(fa)——剝皮(pi),甚至二(er)次剝皮(pi)的原因所在(zai)(zai),目(mu)的要除去皮(pi)下(xia)氧(yang)(yang)(yang)(yang)化(hua)物(wu)。

四(si)、低氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿的韌性(xing)有(you)差別

兩者都可以拉(la)到(dao)0.015mm,但(dan)在低溫(wen)超導線中的(de)低溫(wen)級無氧銅(tong),其(qi)細絲間的(de)間距只(zhi)有(you)0.001mm.

五、從制桿的(de)原材料到制線的(de)經濟性有(you)差別。

制造(zao)無氧銅(tong)(tong)桿要(yao)求質量較(jiao)高的(de)原材料(liao)。一般,拉制直徑(jing)>1mm的(de)銅(tong)(tong)線時,低氧銅(tong)(tong)桿的(de)優點比較(jiao)明顯,而無氧銅(tong)(tong)桿顯得更為優越的(de)是拉制直徑(jing)<0.5mm的(de)銅(tong)(tong)線。

六、低氧銅桿(gan)(gan)的制線工藝與無(wu)氧銅桿(gan)(gan)的有所不同。

低氧(yang)銅(tong)(tong)桿的制線(xian)(xian)(xian)工(gong)藝不能(neng)照搬到無氧(yang)銅(tong)(tong)桿的制線(xian)(xian)(xian)工(gong)藝上(shang)來,至少兩者的退火(huo)工(gong)藝是(shi)不同的。因為線(xian)(xian)(xian)的柔軟性深受(shou)材料成份和(he)制桿,制線(xian)(xian)(xian)和(he)退火(huo)工(gong)藝的影響,不能(neng)簡單地說低氧(yang)銅(tong)(tong)或(huo)無氧(yang)銅(tong)(tong)誰(shui)(shui)軟誰(shui)(shui)硬。