熱門關(guan)鍵詞:
來(lai)源:行業動態 閱讀:109540 發布(bu)時(shi)間:2019-07-05
導讀:由于生(sheng)(sheng)產銅桿的兩者的工藝不(bu)同,所(suo)生(sheng)(sheng)產的銅桿中的含氧(yang)(yang)量(liang)及外(wai)觀就不(bu)同。上(shang)引生(sheng)(sheng)產的銅桿,工藝得(de)當氧(yang)(yang)含量(liang)在10ppm以(yi)下,叫無氧(yang)(yang)銅桿;連(lian)(lian)鑄連(lian)(lian)鑄生(sheng)(sheng)產的銅桿 是(shi)在保護條件下的熱軋,氧(yang)(yang)含量(liang)在200-500ppm范圍內,但有時也高達700ppm以(yi)上(shang),一般(ban)情況下,此種(zhong)方法(fa)生(sheng)(sheng)產的銅外(wai)表光(guang)亮,低(di)氧(yang)(yang)銅桿,有時也叫光(guang)桿。
銅(tong)(tong)桿是電(dian)纜行(xing)(xing)業的(de)主要原料,生(sheng)(sheng)產的(de)方(fang)式主要有(you)兩種——連(lian)(lian)鑄(zhu)連(lian)(lian)軋法和上引(yin)連(lian)(lian)鑄(zhu)法。連(lian)(lian)鑄(zhu)連(lian)(lian)軋低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿的(de)生(sheng)(sheng)產方(fang)法較多(duo),其特點(dian)是金屬在(zai)豎爐(lu)(lu)中融化后(hou),銅(tong)(tong)液(ye)通過(guo)保(bao)溫爐(lu)(lu)、溜槽(cao)、中間包,從(cong)澆管(guan)進(jin)(jin)入封閉的(de)模(mo)腔內,采用(yong)較大的(de)冷(leng)卻(que)強度進(jin)(jin)行(xing)(xing)冷(leng)卻(que),形(xing)成鑄(zhu)坯,然后(hou)進(jin)(jin)行(xing)(xing)多(duo)道次軋制,生(sheng)(sheng)產的(de)低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿為(wei)熱加工組(zu)(zu)(zu)織(zhi)(zhi),原來的(de)鑄(zhu)造(zao)組(zu)(zu)(zu)織(zhi)(zhi)已(yi)經(jing)破碎,含(han)氧(yang)(yang)(yang)量(liang)一般為(wei)200~400ppm之間。無氧(yang)(yang)(yang)銅(tong)(tong)桿國內基本全部(bu)采用(yong)上引(yin)連(lian)(lian)鑄(zhu)法生(sheng)(sheng)產,金屬在(zai)感應電(dian)爐(lu)(lu)中融化后(hou)通過(guo)石墨(mo)模(mo)進(jin)(jin)行(xing)(xing)上引(yin)連(lian)(lian)續鑄(zhu)造(zao),之后(hou)進(jin)(jin)行(xing)(xing)冷(leng)軋或冷(leng)加工,生(sheng)(sheng)產的(de)無氧(yang)(yang)(yang)銅(tong)(tong)桿為(wei)鑄(zhu)造(zao)組(zu)(zu)(zu)織(zhi)(zhi),含(han)氧(yang)(yang)(yang)量(liang)一般在(zai)20ppm以下。由于制造(zao)工藝的(de)不同(tong),所以在(zai)組(zu)(zu)(zu)織(zhi)(zhi)結構(gou)、氧(yang)(yang)(yang)含(han)量(liang)分(fen)布、雜質的(de)形(xing)式及分(fen)布等諸多(duo)方(fang)面有(you)較大差別。
一、拉制性能
銅(tong)桿(gan)的(de)拉制(zhi)性能(neng)跟很多(duo)因素有關,如雜質(zhi)的(de)含(han)量、氧含(han)量及分(fen)布、工(gong)藝控(kong)制(zhi)等。下面(mian)分(fen)別從以上幾個(ge)方面(mian)對銅(tong)桿(gan)的(de)拉制(zhi)性能(neng)進行分(fen)析。
1、熔(rong)化方(fang)式對S等雜(za)質的影響
連(lian)鑄連(lian)軋(ya)生(sheng)產銅(tong)(tong)桿主(zhu)要是(shi)通(tong)過(guo)(guo)氣體的(de)燃燒(shao)使銅(tong)(tong)桿熔化,在(zai)燃燒(shao)的(de)過(guo)(guo)程中,通(tong)過(guo)(guo)氧化和揮發(fa)作用(yong),可(ke)一定程度(du)減少部分雜質進入銅(tong)(tong)液(ye),因此(ci)連(lian)鑄連(lian)軋(ya)法(fa)對(dui)原料(liao)要求(qiu)相(xiang)對(dui)低一些。上(shang)引連(lian)鑄生(sheng)產無(wu)氧銅(tong)(tong)桿,由(you)于是(shi)用(yong)感應電(dian)爐熔化,電(dian)解銅(tong)(tong)表(biao)面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基(ji)本都熔入到銅(tong)(tong)液(ye)中。其(qi)中熔入的(de)S對(dui)無(wu)氧銅(tong)(tong)桿塑性(xing)影響極大(da),會增加拉絲斷線率。
2、鑄造(zao)過程中雜(za)質的進(jin)入
在(zai)生(sheng)(sheng)產(chan)過(guo)(guo)程(cheng)中,連鑄(zhu)連軋工(gong)藝需通過(guo)(guo)保溫爐、溜槽、中間包轉運銅液,相對(dui)容易(yi)造(zao)成耐火(huo)材料(liao)的(de)(de)剝(bo)落(luo),在(zai)軋制過(guo)(guo)程(cheng)中需要通過(guo)(guo)軋輥,造(zao)成鐵質的(de)(de)脫落(luo),會(hui)給(gei)銅桿(gan)造(zao)成外部夾雜(za)。而熱(re)軋中皮上和皮下氧(yang)化物的(de)(de)軋入,會(hui)給(gei)低氧(yang)桿(gan)的(de)(de)拉絲造(zao)成不利的(de)(de)影響。上引連鑄(zhu)法生(sheng)(sheng)產(chan)工(gong)藝流程(cheng)較短(duan),銅液是(shi)通過(guo)(guo)聯體爐內潛流式完成,對(dui)耐火(huo)材料(liao)的(de)(de)沖擊不大,結晶(jing)是(shi)通過(guo)(guo)石墨模(mo)內進(jin)行,所以過(guo)(guo)程(cheng)中可能產(chan)生(sheng)(sheng)的(de)(de)污染源較少,雜(za)質進(jin)入的(de)(de)機會(hui)較少。
O、S、P是與銅(tong)會生產化合物的(de)元素。在(zai)熔態銅(tong)中,氧(yang)可以溶解一部分,但當銅(tong)冷凝時(shi)(shi),氧(yang)幾乎(hu)不溶解于銅(tong)中。熔態時(shi)(shi)所(suo)溶解的(de)氧(yang),以銅(tong)=氧(yang)化亞銅(tong)共晶(jing)體析(xi)出,分布在(zai)晶(jing)粒(li)晶(jing)界處。銅(tong)-氧(yang)化亞銅(tong)共晶(jing)體的(de)出現(xian),顯著(zhu)降低(di)了銅(tong)的(de)塑性。
硫(liu)可以(yi)溶(rong)(rong)解在熔體(ti)的銅中,但在室溫(wen)下,其溶(rong)(rong)解度幾乎降低(di)(di)到零,它以(yi)硫(liu)化亞銅的形式出現(xian)在晶粒(li)晶界處,會(hui)顯(xian)著降低(di)(di)銅的塑性。
3、氧(yang)在(zai)低氧(yang)銅桿和無(wu)氧(yang)銅桿中(zhong)分布形(xing)式(shi)及其影響
氧(yang)(yang)含量對低氧(yang)(yang)銅桿(gan)的(de)拉線(xian)(xian)性能有著明顯的(de)影響。當氧(yang)(yang)含量增加到(dao)(dao)最佳值時,銅桿(gan)的(de)斷線(xian)(xian)率最低。這是因為(wei)氧(yang)(yang)在(zai)與大部分(fen)雜質反應(ying)的(de)過程(cheng)中(zhong)都起(qi)到(dao)(dao)了(le)清除(chu)器的(de)作(zuo)用。適度的(de)氧(yang)(yang)還有利于去除(chu)銅液中(zhong)的(de)氫,生(sheng)成水蒸氣(qi)溢出,減少氣(qi)孔的(de)形成。最佳的(de)氧(yang)(yang)含量為(wei)拉線(xian)(xian)工藝提供了(le)最好的(de)條件。
低氧(yang)(yang)銅(tong)桿(gan)氧(yang)(yang)化(hua)物(wu)(wu)的(de)分布(bu):在連(lian)續(xu)澆鑄中(zhong)凝固的(de)最初(chu)階段,散(san)熱速(su)率和均(jun)勻冷卻是決定(ding)銅(tong)桿(gan)氧(yang)(yang)化(hua)物(wu)(wu)分布(bu)的(de)主(zhu)要因(yin)素。不均(jun)勻冷卻會(hui)引(yin)起銅(tong)桿(gan)內部結構本質上(shang)的(de)差異,但后續(xu)的(de)熱加工,柱狀晶(jing)通(tong)常會(hui)遭(zao)到破(po)壞(huai),使氧(yang)(yang)化(hua)亞銅(tong)顆(ke)(ke)(ke)粒(li)細微化(hua)和均(jun)勻分布(bu)。氧(yang)(yang)化(hua)物(wu)(wu)顆(ke)(ke)(ke)粒(li)聚集而產生的(de)典型(xing)情況是中(zhong)心爆(bao)裂(lie)。除氧(yang)(yang)化(hua)物(wu)(wu)顆(ke)(ke)(ke)粒(li)分布(bu)的(de)影響外,具有較小氧(yang)(yang)化(hua)物(wu)(wu)顆(ke)(ke)(ke)粒(li)的(de)銅(tong)桿(gan)顯示出較好(hao)的(de)拉線特性,較大的(de)Cu2O顆(ke)(ke)(ke)粒(li)容易造(zao)成(cheng)應(ying)力集中(zhong)點而斷(duan)裂(lie)。
無(wu)氧(yang)銅(tong)(tong)含(han)氧(yang)量(liang)超(chao)(chao)標,銅(tong)(tong)桿變(bian)脆,延伸(shen)率下(xia)降(jiang),拉伸(shen)式(shi)樣端(duan)口顯暗紅(hong)色,結晶組織(zhi)疏松。當氧(yang)含(han)量(liang)超(chao)(chao)出8ppm時,工(gong)藝性能(neng)(neng)(neng)變(bian)差,表現(xian)(xian)為(wei)鑄(zhu)造及(ji)拉伸(shen)過程中(zhong)斷桿及(ji)斷線率極具(ju)增高(gao)。這是由于(yu)氧(yang)能(neng)(neng)(neng)與銅(tong)(tong)生成(cheng)氧(yang)化(hua)亞銅(tong)(tong)脆性相,形成(cheng)銅(tong)(tong)-氧(yang)化(hua)亞銅(tong)(tong)共晶體,以網狀組織(zhi)分布在境界上。這種(zhong)脆性相硬度(du)高(gao),在冷變(bian)形時將會與銅(tong)(tong)機(ji)體脫離,導(dao)(dao)致銅(tong)(tong)桿的機(ji)械性能(neng)(neng)(neng)下(xia)降(jiang),在后續加工(gong)中(zhong)容易(yi)造成(cheng)斷裂現(xian)(xian)象。氧(yang)含(han)量(liang)高(gao)還能(neng)(neng)(neng)導(dao)(dao)致無(wu)氧(yang)銅(tong)(tong)桿導(dao)(dao)電率下(xia)降(jiang)。因(yin)此,必須嚴格控制(zhi)上引連鑄(zhu)工(gong)藝及(ji)產(chan)品質量(liang)。
4、氫的影響
在(zai)上(shang)引連鑄中(zhong)(zhong),氧含(han)量控制較(jiao)低(di),氧化物(wu)的(de)(de)副作用唄**降低(di),但氫的(de)(de)影響成為較(jiao)顯著的(de)(de)問題。吸(xi)氣后熔(rong)體中(zhong)(zhong)存在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)體及疏松是(shi)在(zai)(zai)結晶(jing)(jing)的(de)過(guo)程中(zhong),氫從過(guo)飽(bao)和的(de)溶(rong)液(ye)中(zhong)析(xi)出并(bing)聚集(ji)而形(xing)成(cheng)(cheng)的(de)。在(zai)(zai)結晶(jing)(jing)前(qian)析(xi)出的(de)氫又可還原氧化(hua)亞銅(tong)而生成(cheng)(cheng)水氣(qi)(qi)泡。由于(yu)上(shang)引(yin)鑄造的(de)特(te)點是(shi)銅(tong)液(ye)自上(shang)而下(xia)的(de)結晶(jing)(jing),形(xing)成(cheng)(cheng)的(de)液(ye)**形(xing)狀近(jin)似錐型。銅(tong)液(ye)結晶(jing)(jing)前(qian)析(xi)出的(de)氣(qi)(qi)體在(zai)(zai)上(shang)浮過(guo)程中(zhong)被堵在(zai)(zai)凝固(gu)組織內,結晶(jing)(jing)時(shi)在(zai)(zai)鑄桿內形(xing)成(cheng)(cheng)氣(qi)(qi)孔。上(shang)引(yin)的(de)含(han)氣(qi)(qi)量少時(shi),析(xi)出的(de)氫存在(zai)(zai)于(yu)晶(jing)(jing)界處(chu),形(xing)成(cheng)(cheng)疏松;含(han)氣(qi)(qi)量多時(shi),則聚集(ji)成(cheng)(cheng)氣(qi)(qi)孔,因此,氣(qi)(qi)孔和疏松是(shi)氫氣(qi)(qi)和水蒸氣(qi)(qi)兩(liang)者形(xing)成(cheng)(cheng)的(de)。
氫來源(yuan)于(yu)上(shang)引生產過程中(zhong)(zhong)的(de)各(ge)個(ge)工(gong)藝(yi)環節,如原料電解(jie)(jie)銅(tong)的(de)“銅(tong)綠(lv)(lv)”、輔(fu)料木炭**、氣(qi)候環境**、石墨結晶器(qi)未干(gan)燥等(deng)。因此,熔化(hua)爐(lu)中(zhong)(zhong)的(de)銅(tong)液表面應覆蓋經烘烤的(de)木炭,電解(jie)(jie)銅(tong)應盡(jin)量去除“銅(tong)綠(lv)(lv)”、“銅(tong)豆”“耳朵(duo)”,對提高無氧銅(tong)桿(gan)質(zhi)量非常重(zhong)要。
在連鑄連軋工(gong)藝中,往往采(cai)用適(shi)度控(kong)制氧含量來控(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅(tong)液在鑄造過程中(zhong)是自下(xia)而(er)上(shang)結(jie)晶,銅(tong)液中(zhong)的氧(yang)和氫所產生(sheng)的水蒸氣很容(rong)易(yi)上(shang)浮跑出,銅(tong)液中(zhong)的氫大部分能(neng)被(bei)有(you)效去除,因而(er)對銅(tong)桿的影響較小。
二、表面質量
在生(sheng)產電磁線等產品的(de)過程中,對(dui)銅(tong)桿(gan)的(de)表面(mian)質量也需(xu)提出要(yao)求。需(xu)要(yao)拉制后的(de)銅(tong)絲表面(mian)無(wu)毛刺、銅(tong)粉(fen)少、無(wu)油污。并(bing)通過扭轉試驗測(ce)量表面(mian)銅(tong)粉(fen)的(de)質量和扭轉后觀察(cha)銅(tong)桿(gan)的(de)復(fu)原情(qing)況(kuang)來判(pan)定其好壞(huai)。
在(zai)連鑄連軋(ya)(ya)過(guo)程(cheng)中,從(cong)鑄造到軋(ya)(ya)制(zhi)前(qian),溫度高,完全暴露于空氣中,使鑄坯表面形成較(jiao)厚(hou)的(de)(de)氧(yang)化層,在(zai)軋(ya)(ya)制(zhi)過(guo)程(cheng)中,隨著軋(ya)(ya)輥的(de)(de)轉動,氧(yang)化物(wu)顆粒軋(ya)(ya)入銅(tong)線表面。由于氧(yang)化亞銅(tong)是高熔(rong)點脆性化合物(wu),對于軋(ya)(ya)入較(jiao)深的(de)(de)氧(yang)化亞銅(tong),當成條狀的(de)(de)聚(ju)集(ji)物(wu)遇模具拉伸時,就會是銅(tong)桿外(wai)表面產生毛刺,給后續的(de)(de)涂漆(qi)造成麻(ma)煩。
而上引(yin)連鑄工藝制造的(de)無氧銅(tong)桿(gan),由(you)于(yu)鑄造和冷卻完全與氧隔絕,后(hou)續(xu)亦無熱軋過程,銅(tong)桿(gan)表面無軋入(ru)表面的(de)氧化(hua)物,質量(liang)較好,拉制后(hou)銅(tong)粉少(shao),上述問題較少(shao)存(cun)在(zai)。
無氧銅(tong)(tong)桿也(ye)分進(jin)口(kou)設(she)備(bei)做的(de)(de)(de)和(he)國(guo)產設(she)備(bei)做的(de)(de)(de),但目前進(jin)口(kou)產品(pin)(pin)已無明顯優勢,銅(tong)(tong)桿產品(pin)(pin)出來(lai)后區別不是(shi)(shi)很(hen)大,只要(yao)銅(tong)(tong)板選的(de)(de)(de)好,生(sheng)產控制比較(jiao)穩定,國(guo)產設(she)備(bei)也(ye)能產出可拉伸0.05的(de)(de)(de)銅(tong)(tong)桿.進(jin)口(kou)設(she)備(bei)一(yi)般是(shi)(shi)芬(fen)蘭奧托(tuo)昆(kun)普的(de)(de)(de)設(she)備(bei),國(guo)產設(she)備(bei)最好的(de)(de)(de)應該(gai)是(shi)(shi)上海的(de)(de)(de)海軍廠的(de)(de)(de)了(le),生(sheng)產時間最長(chang),軍工(gong)企(qi)業,質量可靠。
低氧銅(tong)桿進口設備(bei)(bei)國際主要有(you)兩(liang)種,一(yi)種是美國南線設備(bei)(bei),英文是SOUTHWIRE,國內廠(chang)家是南京(jing)華新,江(jiang)西銅(tong)業,另一(yi)種是德國CONTIROD設備(bei)(bei),國內廠(chang)家是常州金源,天(tian)津大無縫。
無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)上容(rong)易區別(bie),無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅是(shi)含(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)PPM以(yi)下,但(dan)目前有(you)的廠(chang)家只(zhi)能(neng)做到(dao)50個(ge)PPM以(yi)下.低(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好(hao)(hao)的桿(gan)(gan)子一(yi)般含(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個(ge)PPM左右,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)一(yi)般采(cai)取(qu)的是(shi)上引(yin)法,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)是(shi)連(lian)鑄(zhu)連(lian)軋,兩(liang)種產品(pin)相對而言低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對漆包線(xian)性 能(neng)更適應些,如柔軟性,回彈角,繞線(xian)性能(neng).但(dan)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對拉(la)(la)絲(si)條件(jian)(jian)相對要苛刻些,同樣拉(la)(la)伸(shen)(shen)(shen)0.2的細絲(si),如果伸(shen)(shen)(shen)線(xian)條件(jian)(jian)不(bu)好(hao)(hao),普(pu)(pu)通的無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)可拉(la)(la)而好(hao)(hao)的低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)就斷 線(xian),但(dan)如果放在(zai)(zai)好(hao)(hao)的伸(shen)(shen)(shen)線(xian)條件(jian)(jian),同樣的桿(gan)(gan)子,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)說不(bu)定就能(neng)拉(la)(la)到(dao)雙零五,而普(pu)(pu)通無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)最(zui)多只(zhi)能(neng)拉(la)(la)伸(shen)(shen)(shen)到(dao)0.1而已,當然做的最(zui)細的如雙零二卻(que)非得(de)依(yi)靠進(jin)口(kou)的 無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)了.目前有(you)企業嘗試用剝皮的方式(shi)來(lai)處(chu)理低(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)來(lai)伸(shen)(shen)(shen)0.03線(xian).但(dan)有(you)關這(zhe)方面的內容(rong)我還不(bu)是(shi)很清楚。
音(yin)響線一般(ban)反而喜(xi)歡用無氧桿(gan),這和無氧桿(gan)是(shi)單晶銅,低氧桿(gan)是(shi)多晶銅有關。
氧(yang)銅桿(gan)和(he)無氧(yang)銅桿(gan)由于制(zhi)造方法的(de)不同(tong),致使存(cun)在差別,具有各自的(de)特點。
一、關于氧的(de)吸入和(he)脫去以及它的(de)存在狀態(tai)
生產(chan)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)量(liang)一般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)溫下(xia)氧(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)(de)固(gu)溶度約2ppm。低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)量(liang)一般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)(de)(de)(de)(de)進入是在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)液態(tai)下(xia)吸(xi)入的(de)(de)(de)(de)(de)(de),而(er)上(shang)引法(fa)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則(ze)相反,氧(yang)(yang)在(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)下(xia)保持相當(dang)時(shi)間(jian)后,被還(huan)原而(er)脫去,通常(chang)這(zhe)種(zhong)桿(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)量(liang)都在(zai)(zai)(zai)10—50ppm以(yi)下(xia),最低(di)(di)可達1-2ppm,從組(zu)織上(shang)看,低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)(de)氧(yang)(yang),以(yi)氧(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)于晶(jing)粒邊界(jie)附近,這(zhe)對(dui)低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)而(er)言(yan)可以(yi)說(shuo)是常(chang)見(jian)(jian)的(de)(de)(de)(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則(ze)很(hen)(hen)少(shao)見(jian)(jian)。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)晶(jing)界(jie)出現對(dui)材料的(de)(de)(de)(de)(de)(de)韌(ren)性(xing)產(chan)生負面影響。而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)(de)氧(yang)(yang)很(hen)(hen)低(di)(di),所(suo)以(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)組(zu)織是均(jun)勻的(de)(de)(de)(de)(de)(de)單相組(zu)織對(dui)韌(ren)性(xing)有利。在(zai)(zai)(zai)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)(de)(de)(de)(de)多孔(kong)性(xing)是不常(chang)見(jian)(jian)的(de)(de)(de)(de)(de)(de),而(er)在(zai)(zai)(zai)低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中則(ze)是常(chang)見(jian)(jian)的(de)(de)(de)(de)(de)(de)一種(zhong)缺陷。
二、熱軋組織和鑄造組織的區別
低氧銅(tong)桿(gan)由(you)于經過(guo)(guo)熱軋,所以(yi)其組(zu)織(zhi)屬熱加工組(zu)織(zhi),原來的(de)鑄造(zao)組(zu)織(zhi)已經破(po)碎,在(zai)(zai)8mm的(de)桿(gan)時已有(you)再結晶的(de)形式出現,而無(wu)氧銅(tong)桿(gan)屬鑄造(zao)組(zu)織(zhi),晶粒粗大(da),這是為(wei)什么,無(wu)氧銅(tong)的(de)再結晶溫度(du)較(jiao)高(gao)(gao),需要(yao)較(jiao)高(gao)(gao)退(tui)(tui)火(huo)溫度(du)的(de)固有(you)原因。這是因為(wei),再結晶發生在(zai)(zai)晶粒邊界附近,無(wu)氧銅(tong)桿(gan)組(zu)織(zhi)晶粒粗大(da),晶粒尺寸甚(shen)至能達幾個毫米(mi),因而晶粒邊界少,即使通過(guo)(guo)拉制(zhi)變(bian)形,但晶粒邊界相對低氧銅(tong)桿(gan)還(huan)是較(jiao)少,所以(yi)需要(yao)較(jiao)高(gao)(gao)的(de)退(tui)(tui)火(huo)功(gong)(gong)率(lv)。對無(wu)氧銅(tong)成功(gong)(gong)的(de)退(tui)(tui)火(huo)要(yao)求是:由(you)桿(gan)經拉制(zhi),但尚未鑄造(zao)組(zu)織(zhi)的(de)線(xian)時的(de)第一(yi)次退(tui)(tui)火(huo),其退(tui)(tui)火(huo)功(gong)(gong)率(lv)應比同(tong)樣情況(kuang)的(de)低氧銅(tong)高(gao)(gao)10——15%。經繼續拉制(zhi),在(zai)(zai)以(yi)后(hou)階(jie)段的(de)退(tui)(tui)火(huo)功(gong)(gong)率(lv)應留有(you)足夠的(de)余量和(he)(he)對低氧銅(tong)和(he)(he)無(wu)氧銅(tong)切(qie)實區(qu)別(bie)執行不同(tong)的(de)退(tui)(tui)火(huo)工藝,以(yi)保證在(zai)(zai)制(zhi)品和(he)(he)成品導線(xian)的(de)柔軟性。
三(san)、夾(jia)雜,氧(yang)含(han)量(liang)波動,表(biao)面氧(yang)化物和可能存在的(de)熱軋缺陷的(de)差別
無(wu)氧(yang)銅(tong)(tong)桿(gan)的(de)可(ke)拉性在(zai)所有(you)線(xian)徑里與(yu)低氧(yang)銅(tong)(tong)桿(gan)相(xiang)比都是優越的(de),除(chu)上述組(zu)織原因外,無(wu)氧(yang)銅(tong)(tong)桿(gan)夾雜少(shao),含氧(yang)量穩(wen)(wen)定(ding),無(wu)熱(re)軋可(ke)能產生的(de)缺(que)陷,桿(gan)表(biao)氧(yang)化(hua)物(wu)(wu)厚度可(ke)達(da)≤15A。在(zai)連(lian)鑄連(lian)軋生產過(guo)程中(zhong)如(ru)果工藝不穩(wen)(wen)定(ding),對氧(yang)監控不嚴,含氧(yang)量不穩(wen)(wen)定(ding)將直接影響桿(gan)的(de)性能。如(ru)果桿(gan)的(de)表(biao)面氧(yang)化(hua)物(wu)(wu)能在(zai)后工序的(de)連(lian)續清洗(xi)中(zhong)得以彌(mi)補(bu)外,但比較麻(ma)煩(fan)的(de)是有(you)相(xiang)當多的(de)氧(yang)化(hua)物(wu)(wu)存在(zai)于“皮下”,對拉線(xian)斷(duan)(duan)線(xian)影響更直接,故而在(zai)拉制微(wei)細線(xian),超(chao)微(wei)細線(xian)時(shi),為了減(jian)少(shao)斷(duan)(duan)線(xian),有(you)時(shi)要對銅(tong)(tong)桿(gan)采取不得已的(de)辦法——剝(bo)皮,甚至二(er)次剝(bo)皮的(de)原因所在(zai),目的(de)要除(chu)去皮下氧(yang)化(hua)物(wu)(wu)。
四(si)、低氧(yang)銅桿和無氧(yang)銅桿的韌性有(you)差別
兩者都(dou)可以(yi)拉到0.015mm,但在低溫超導線中(zhong)的低溫級無氧銅,其細絲間的間距只有(you)0.001mm.
五(wu)、從制桿的原(yuan)材料到(dao)制線的經(jing)濟性有(you)差別(bie)。
制造無氧銅(tong)桿(gan)要求質量較高的原(yuan)材料。一般(ban),拉制直徑(jing)>1mm的銅(tong)線時,低氧銅(tong)桿(gan)的優點比較明顯,而無氧銅(tong)桿(gan)顯得(de)更為優越的是拉制直徑(jing)<0.5mm的銅(tong)線。
六、低氧(yang)(yang)銅桿的(de)制線工藝(yi)與無氧(yang)(yang)銅桿的(de)有(you)所不同(tong)。
低(di)氧銅桿(gan)的(de)制線工藝(yi)不能照搬(ban)到無氧銅桿(gan)的(de)制線工藝(yi)上(shang)來,至少兩者(zhe)的(de)退火工藝(yi)是不同(tong)的(de)。因(yin)為線的(de)柔軟性深受材料成份和制桿(gan),制線和退火工藝(yi)的(de)影響,不能簡(jian)單地說低(di)氧銅或無氧銅誰軟誰硬(ying)。
上一條(tiao)綠園絕緣層厚度不合格對電線電纜有何影響
下一(yi)條綠園如何分辨劣質線纜(電纜人必備)