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梅河口電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業動態 閱讀:109367 發(fa)布時間:2019-07-05

導讀:由(you)于生產(chan)銅(tong)桿(gan)(gan)(gan)的(de)(de)兩者的(de)(de)工(gong)藝(yi)不同(tong),所(suo)生產(chan)的(de)(de)銅(tong)桿(gan)(gan)(gan)中的(de)(de)含(han)氧量及外(wai)觀就不同(tong)。上引生產(chan)的(de)(de)銅(tong)桿(gan)(gan)(gan),工(gong)藝(yi)得當氧含(han)量在(zai)10ppm以(yi)下,叫無(wu)氧銅(tong)桿(gan)(gan)(gan);連(lian)鑄連(lian)鑄生產(chan)的(de)(de)銅(tong)桿(gan)(gan)(gan) 是在(zai)保護條件下的(de)(de)熱軋,氧含(han)量在(zai)200-500ppm范圍(wei)內,但有(you)時(shi)(shi)也高(gao)達700ppm以(yi)上,一般情況下,此種方(fang)法生產(chan)的(de)(de)銅(tong)外(wai)表光亮,低氧銅(tong)桿(gan)(gan)(gan),有(you)時(shi)(shi)也叫光桿(gan)(gan)(gan)。

銅(tong)(tong)桿(gan)是電(dian)纜行(xing)業的(de)主(zhu)要原(yuan)料,生產(chan)的(de)方(fang)式主(zhu)要有兩種——連鑄(zhu)連軋法(fa)和上引連鑄(zhu)法(fa)。連鑄(zhu)連軋低氧(yang)(yang)銅(tong)(tong)桿(gan)的(de)生產(chan)方(fang)法(fa)較多,其特點是金屬在(zai)豎爐中融化后,銅(tong)(tong)液(ye)通過(guo)保溫爐、溜(liu)槽、中間(jian)包,從澆管進(jin)(jin)入封閉的(de)模(mo)腔內,采(cai)用較大(da)的(de)冷卻強度(du)進(jin)(jin)行(xing)冷卻,形成鑄(zhu)坯(pi),然后進(jin)(jin)行(xing)多道次軋制,生產(chan)的(de)低氧(yang)(yang)銅(tong)(tong)桿(gan)為熱加工(gong)組(zu)織(zhi)(zhi),原(yuan)來的(de)鑄(zhu)造(zao)組(zu)織(zhi)(zhi)已經破碎,含氧(yang)(yang)量一般為200~400ppm之間(jian)。無氧(yang)(yang)銅(tong)(tong)桿(gan)國內基本全部采(cai)用上引連鑄(zhu)法(fa)生產(chan),金屬在(zai)感應電(dian)爐中融化后通過(guo)石墨模(mo)進(jin)(jin)行(xing)上引連續(xu)鑄(zhu)造(zao),之后進(jin)(jin)行(xing)冷軋或冷加工(gong),生產(chan)的(de)無氧(yang)(yang)銅(tong)(tong)桿(gan)為鑄(zhu)造(zao)組(zu)織(zhi)(zhi),含氧(yang)(yang)量一般在(zai)20ppm以(yi)下。由于制造(zao)工(gong)藝(yi)的(de)不同,所以(yi)在(zai)組(zu)織(zhi)(zhi)結構、氧(yang)(yang)含量分布、雜質(zhi)的(de)形式及分布等諸多方(fang)面有較大(da)差(cha)別。

一、拉制性能

銅桿的(de)(de)拉(la)(la)制性(xing)能跟很多因(yin)素有關,如雜質(zhi)的(de)(de)含量、氧含量及分(fen)布、工(gong)藝控制等。下面(mian)分(fen)別從以上幾個方面(mian)對銅桿的(de)(de)拉(la)(la)制性(xing)能進行分(fen)析(xi)。

1、熔化(hua)方(fang)式(shi)對(dui)S等雜質(zhi)的(de)影響(xiang)

連(lian)(lian)(lian)鑄連(lian)(lian)(lian)軋(ya)生(sheng)產(chan)銅(tong)桿主要(yao)是(shi)通過氣體的燃燒使(shi)銅(tong)桿熔(rong)(rong)化,在燃燒的過程中(zhong),通過氧(yang)化和(he)揮(hui)發作用(yong)(yong),可(ke)一(yi)定程度減(jian)少部分雜質進(jin)入銅(tong)液(ye),因此(ci)連(lian)(lian)(lian)鑄連(lian)(lian)(lian)軋(ya)法對原料要(yao)求相對低一(yi)些。上(shang)引連(lian)(lian)(lian)鑄生(sheng)產(chan)無氧(yang)銅(tong)桿,由于是(shi)用(yong)(yong)感應電爐熔(rong)(rong)化,電解(jie)銅(tong)表面的“銅(tong)綠”“銅(tong)豆”基本都熔(rong)(rong)入到(dao)銅(tong)液(ye)中(zhong)。其中(zhong)熔(rong)(rong)入的S對無氧(yang)銅(tong)桿塑性影響極(ji)大(da),會增加拉絲斷線率。

2、鑄造(zao)過(guo)程中雜質的進入(ru)

在生(sheng)產過(guo)程中(zhong)(zhong),連(lian)鑄連(lian)軋(ya)工(gong)藝需(xu)通過(guo)保溫爐(lu)、溜(liu)槽、中(zhong)(zhong)間包轉運(yun)銅(tong)液,相對容(rong)易造(zao)(zao)成耐(nai)(nai)火(huo)(huo)材(cai)料(liao)的(de)(de)剝落(luo),在軋(ya)制過(guo)程中(zhong)(zhong)需(xu)要通過(guo)軋(ya)輥,造(zao)(zao)成鐵(tie)質的(de)(de)脫(tuo)落(luo),會(hui)給(gei)銅(tong)桿造(zao)(zao)成外(wai)部(bu)夾雜。而熱軋(ya)中(zhong)(zhong)皮上(shang)和皮下氧(yang)化物的(de)(de)軋(ya)入,會(hui)給(gei)低氧(yang)桿的(de)(de)拉絲造(zao)(zao)成不利的(de)(de)影響。上(shang)引連(lian)鑄法(fa)生(sheng)產工(gong)藝流程較短(duan),銅(tong)液是通過(guo)聯(lian)體爐(lu)內(nei)潛(qian)流式(shi)完(wan)成,對耐(nai)(nai)火(huo)(huo)材(cai)料(liao)的(de)(de)沖擊(ji)不大,結晶是通過(guo)石墨模(mo)內(nei)進行,所以過(guo)程中(zhong)(zhong)可能產生(sheng)的(de)(de)污染源較少(shao)(shao),雜質進入的(de)(de)機會(hui)較少(shao)(shao)。

O、S、P是與銅(tong)會生(sheng)產化(hua)合(he)物的(de)元(yuan)素。在熔(rong)(rong)態銅(tong)中,氧可以溶解(jie)一部分(fen),但當銅(tong)冷凝時,氧幾乎不溶解(jie)于銅(tong)中。熔(rong)(rong)態時所溶解(jie)的(de)氧,以銅(tong)=氧化(hua)亞(ya)銅(tong)共晶體(ti)析出(chu),分(fen)布(bu)在晶粒晶界(jie)處(chu)。銅(tong)-氧化(hua)亞(ya)銅(tong)共晶體(ti)的(de)出(chu)現,顯著降低了銅(tong)的(de)塑(su)性。

硫可以(yi)溶(rong)(rong)解(jie)在(zai)熔(rong)體的銅中,但在(zai)室溫下,其溶(rong)(rong)解(jie)度(du)幾乎降低到零,它以(yi)硫化亞(ya)銅的形式出現在(zai)晶粒晶界處,會顯著降低銅的塑(su)性。

3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中分布形式及其影響

氧(yang)(yang)(yang)含(han)量對低氧(yang)(yang)(yang)銅桿的(de)(de)(de)拉(la)線(xian)性能有(you)(you)著明顯的(de)(de)(de)影響。當氧(yang)(yang)(yang)含(han)量增加到(dao)最佳值時,銅桿的(de)(de)(de)斷線(xian)率最低。這是因為氧(yang)(yang)(yang)在與大部(bu)分雜質反應的(de)(de)(de)過程中都起到(dao)了(le)(le)清除器的(de)(de)(de)作用。適(shi)度的(de)(de)(de)氧(yang)(yang)(yang)還有(you)(you)利于(yu)去除銅液中的(de)(de)(de)氫,生成(cheng)水蒸氣溢出,減少氣孔(kong)的(de)(de)(de)形成(cheng)。最佳的(de)(de)(de)氧(yang)(yang)(yang)含(han)量為拉(la)線(xian)工藝提供了(le)(le)最好的(de)(de)(de)條件。

低氧銅桿(gan)氧化物(wu)的(de)分(fen)布:在連續(xu)澆鑄中凝固的(de)最初階段,散熱速率和均(jun)(jun)勻(yun)冷(leng)卻是決定銅桿(gan)氧化物(wu)分(fen)布的(de)主要因素。不均(jun)(jun)勻(yun)冷(leng)卻會(hui)(hui)引起銅桿(gan)內部結構本質上的(de)差異(yi),但后(hou)續(xu)的(de)熱加工(gong),柱(zhu)狀(zhuang)晶通常(chang)會(hui)(hui)遭到破壞(huai),使氧化亞(ya)銅顆粒(li)細微(wei)化和均(jun)(jun)勻(yun)分(fen)布。氧化物(wu)顆粒(li)聚集而產生的(de)典型情況是中心爆裂(lie)。除氧化物(wu)顆粒(li)分(fen)布的(de)影響(xiang)外,具有(you)較小氧化物(wu)顆粒(li)的(de)銅桿(gan)顯示出(chu)較好(hao)的(de)拉線(xian)特(te)性(xing),較大的(de)Cu2O顆粒(li)容易造成應力集中點而斷(duan)裂(lie)。

無氧銅(tong)(tong)(tong)含(han)氧量(liang)(liang)(liang)超標,銅(tong)(tong)(tong)桿(gan)變(bian)脆(cui),延伸率下(xia)降(jiang),拉(la)(la)伸式樣端口顯暗紅色,結(jie)晶(jing)組織(zhi)疏(shu)松。當氧含(han)量(liang)(liang)(liang)超出8ppm時(shi),工(gong)(gong)藝性能變(bian)差(cha),表現為鑄造及拉(la)(la)伸過程中(zhong)斷桿(gan)及斷線(xian)率極具增(zeng)高。這是由于(yu)氧能與(yu)銅(tong)(tong)(tong)生成(cheng)氧化亞銅(tong)(tong)(tong)脆(cui)性相,形成(cheng)銅(tong)(tong)(tong)-氧化亞銅(tong)(tong)(tong)共(gong)晶(jing)體(ti)(ti),以網狀組織(zhi)分布在(zai)境界(jie)上。這種脆(cui)性相硬度高,在(zai)冷(leng)變(bian)形時(shi)將會(hui)與(yu)銅(tong)(tong)(tong)機(ji)體(ti)(ti)脫離(li),導(dao)(dao)致銅(tong)(tong)(tong)桿(gan)的機(ji)械(xie)性能下(xia)降(jiang),在(zai)后續(xu)加工(gong)(gong)中(zhong)容易造成(cheng)斷裂(lie)現象(xiang)。氧含(han)量(liang)(liang)(liang)高還能導(dao)(dao)致無氧銅(tong)(tong)(tong)桿(gan)導(dao)(dao)電(dian)率下(xia)降(jiang)。因此(ci),必須嚴格控(kong)制上引連鑄工(gong)(gong)藝及產品質量(liang)(liang)(liang)。

4、氫的影響

在(zai)上引連鑄(zhu)中,氧含量控制較低,氧化物的(de)副作用(yong)唄**降低,但氫(qing)的(de)影(ying)響成為較顯著的(de)問題。吸氣后熔體中存在(zai)平衡反應(ying):H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)體及(ji)疏(shu)松是在(zai)結(jie)晶(jing)的(de)(de)(de)(de)(de)過程中,氫從(cong)過飽和(he)的(de)(de)(de)(de)(de)溶液中析出(chu)(chu)并(bing)聚集(ji)而(er)形(xing)成(cheng)的(de)(de)(de)(de)(de)。在(zai)結(jie)晶(jing)前析出(chu)(chu)的(de)(de)(de)(de)(de)氫又(you)可還原氧化亞(ya)銅而(er)生成(cheng)水氣(qi)(qi)(qi)泡。由于上(shang)(shang)引鑄(zhu)造的(de)(de)(de)(de)(de)特點是銅液自上(shang)(shang)而(er)下的(de)(de)(de)(de)(de)結(jie)晶(jing),形(xing)成(cheng)的(de)(de)(de)(de)(de)液**形(xing)狀近似錐型。銅液結(jie)晶(jing)前析出(chu)(chu)的(de)(de)(de)(de)(de)氣(qi)(qi)(qi)體在(zai)上(shang)(shang)浮過程中被堵在(zai)凝(ning)固組織內,結(jie)晶(jing)時在(zai)鑄(zhu)桿內形(xing)成(cheng)氣(qi)(qi)(qi)孔(kong)。上(shang)(shang)引的(de)(de)(de)(de)(de)含氣(qi)(qi)(qi)量少時,析出(chu)(chu)的(de)(de)(de)(de)(de)氫存在(zai)于晶(jing)界處(chu),形(xing)成(cheng)疏(shu)松;含氣(qi)(qi)(qi)量多時,則聚集(ji)成(cheng)氣(qi)(qi)(qi)孔(kong),因(yin)此,氣(qi)(qi)(qi)孔(kong)和(he)疏(shu)松是氫氣(qi)(qi)(qi)和(he)水蒸氣(qi)(qi)(qi)兩者(zhe)形(xing)成(cheng)的(de)(de)(de)(de)(de)。

氫來源(yuan)于上引生產(chan)過程中(zhong)的各個工藝(yi)環節,如原(yuan)料電(dian)解銅的“銅綠”、輔料木炭(tan)**、氣候環境**、石墨(mo)結晶器未干燥等(deng)。因此,熔化爐中(zhong)的銅液表面(mian)應覆蓋經烘烤的木炭(tan),電(dian)解銅應盡量去除“銅綠”、“銅豆”“耳朵(duo)”,對提高無氧銅桿質(zhi)量非常(chang)重(zhong)要(yao)。

在連鑄連軋工(gong)藝中,往(wang)往(wang)采(cai)用適(shi)度控(kong)制(zhi)氧含(han)量來控(kong)制(zhi)氫。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)(tong)液(ye)在鑄(zhu)造過程(cheng)中(zhong)(zhong)是(shi)自下(xia)而(er)上結晶(jing),銅(tong)(tong)液(ye)中(zhong)(zhong)的(de)氧和(he)氫所產生的(de)水蒸(zheng)氣(qi)很容易上浮跑出,銅(tong)(tong)液(ye)中(zhong)(zhong)的(de)氫大部分能被有效(xiao)去除,因(yin)而(er)對銅(tong)(tong)桿的(de)影(ying)響(xiang)較(jiao)小。

二、表面質量

在生產(chan)電磁(ci)線等產(chan)品的(de)(de)(de)過(guo)程中,對銅(tong)(tong)桿的(de)(de)(de)表(biao)面(mian)質量(liang)也需(xu)提出要求(qiu)。需(xu)要拉(la)制(zhi)后的(de)(de)(de)銅(tong)(tong)絲表(biao)面(mian)無毛刺(ci)、銅(tong)(tong)粉少、無油(you)污。并通過(guo)扭(niu)(niu)轉試驗測(ce)量(liang)表(biao)面(mian)銅(tong)(tong)粉的(de)(de)(de)質量(liang)和扭(niu)(niu)轉后觀察銅(tong)(tong)桿的(de)(de)(de)復(fu)原情況(kuang)來判定其好壞(huai)。

在連鑄連軋(ya)(ya)過(guo)程中(zhong)(zhong)(zhong),從(cong)鑄造(zao)到軋(ya)(ya)制前,溫度高,完全暴露于(yu)空氣中(zhong)(zhong)(zhong),使鑄坯表(biao)(biao)面(mian)形成較(jiao)厚的(de)(de)氧(yang)化層,在軋(ya)(ya)制過(guo)程中(zhong)(zhong)(zhong),隨著軋(ya)(ya)輥的(de)(de)轉動,氧(yang)化物顆粒軋(ya)(ya)入銅線表(biao)(biao)面(mian)。由于(yu)氧(yang)化亞銅是高熔點(dian)脆性化合(he)物,對于(yu)軋(ya)(ya)入較(jiao)深(shen)的(de)(de)氧(yang)化亞銅,當成條狀的(de)(de)聚集物遇模(mo)具拉伸時,就會是銅桿(gan)外(wai)表(biao)(biao)面(mian)產(chan)生毛(mao)刺,給后(hou)續的(de)(de)涂(tu)漆造(zao)成麻煩。

而上(shang)引連鑄工藝制(zhi)造(zao)的無(wu)氧銅(tong)桿,由于鑄造(zao)和冷卻完全與氧隔絕,后續亦(yi)無(wu)熱(re)軋(ya)過程,銅(tong)桿表面無(wu)軋(ya)入表面的氧化物,質(zhi)量(liang)較(jiao)(jiao)好,拉制(zhi)后銅(tong)粉(fen)少,上(shang)述問題較(jiao)(jiao)少存在。

無氧銅桿也分進口(kou)設備(bei)做的(de)和國(guo)產(chan)(chan)(chan)設備(bei)做的(de),但目前進口(kou)產(chan)(chan)(chan)品(pin)已無明顯優勢,銅桿產(chan)(chan)(chan)品(pin)出(chu)來后區別不是(shi)很大(da),只要銅板(ban)選的(de)好(hao),生產(chan)(chan)(chan)控制(zhi)比較穩定,國(guo)產(chan)(chan)(chan)設備(bei)也能產(chan)(chan)(chan)出(chu)可拉伸0.05的(de)銅桿.進口(kou)設備(bei)一般是(shi)芬(fen)蘭奧托昆普的(de)設備(bei),國(guo)產(chan)(chan)(chan)設備(bei)最好(hao)的(de)應該是(shi)上海(hai)的(de)海(hai)軍廠的(de)了,生產(chan)(chan)(chan)時(shi)間(jian)最長(chang),軍工(gong)企業,質量可靠。

低(di)氧(yang)銅桿進口設(she)備國際主要有兩種,一種是美國南線(xian)設(she)備,英(ying)文是SOUTHWIRE,國內廠家是南京華新,江(jiang)西(xi)銅業,另一種是德國CONTIROD設(she)備,國內廠家是常州金源,天津(jin)大無縫。

無氧(yang)(yang)(yang)及低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從(cong)含(han)氧(yang)(yang)(yang)量(liang)上(shang)容易區別,無氧(yang)(yang)(yang)銅是(shi)含(han)氧(yang)(yang)(yang)量(liang)在10-20個PPM以下,但目前有的(de)(de)廠(chang)家只能做(zuo)到(dao)50個PPM以下.低(di)(di)(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)在 200-400個PPM,好(hao)(hao)(hao)的(de)(de)桿(gan)(gan)(gan)子一(yi)(yi)般含(han)氧(yang)(yang)(yang)量(liang)控制在250個PPM左右,無氧(yang)(yang)(yang)桿(gan)(gan)(gan)一(yi)(yi)般采(cai)取的(de)(de)是(shi)上(shang)引法,低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)連(lian)(lian)鑄連(lian)(lian)軋(ya),兩種(zhong)產品相(xiang)對而言低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對漆包線(xian)性(xing) 能更適應些,如(ru)(ru)柔軟性(xing),回彈角,繞線(xian)性(xing)能.但低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對拉(la)(la)(la)(la)絲(si)條(tiao)件(jian)(jian)相(xiang)對要苛刻(ke)些,同(tong)樣拉(la)(la)(la)(la)伸(shen)(shen)(shen)0.2的(de)(de)細絲(si),如(ru)(ru)果伸(shen)(shen)(shen)線(xian)條(tiao)件(jian)(jian)不好(hao)(hao)(hao),普通的(de)(de)無氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)(la)(la)(la)而好(hao)(hao)(hao)的(de)(de)低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就(jiu)斷 線(xian),但如(ru)(ru)果放在好(hao)(hao)(hao)的(de)(de)伸(shen)(shen)(shen)線(xian)條(tiao)件(jian)(jian),同(tong)樣的(de)(de)桿(gan)(gan)(gan)子,低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不定就(jiu)能拉(la)(la)(la)(la)到(dao)雙(shuang)零五,而普通無氧(yang)(yang)(yang)桿(gan)(gan)(gan)最(zui)多只能拉(la)(la)(la)(la)伸(shen)(shen)(shen)到(dao)0.1而已(yi),當(dang)然做(zuo)的(de)(de)最(zui)細的(de)(de)如(ru)(ru)雙(shuang)零二卻(que)非得依靠(kao)進口的(de)(de) 無氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)了.目前有企業嘗試(shi)用剝(bo)皮的(de)(de)方(fang)式來(lai)處理(li)低(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來(lai)伸(shen)(shen)(shen)0.03線(xian).但有關這方(fang)面(mian)的(de)(de)內(nei)容我還不是(shi)很清楚。

音響線一(yi)般反而喜歡(huan)用(yong)無氧桿,這和無氧桿是(shi)單(dan)晶銅,低氧桿是(shi)多晶銅有關。

氧(yang)銅桿(gan)和無(wu)氧(yang)銅桿(gan)由于(yu)制造(zao)方法的不同,致使存在差別,具有各自的特點。

一、關于氧的(de)吸入和脫去(qu)以及(ji)它的(de)存在狀(zhuang)態

生產銅(tong)(tong)(tong)(tong)(tong)桿的(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)(zai)(zai)常(chang)(chang)溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)固(gu)溶(rong)度約(yue)2ppm。低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)進(jin)入是(shi)在(zai)(zai)(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)液態(tai)下(xia)吸入的(de)(de)(de),而上(shang)引法無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿則相反(fan),氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)下(xia)保持相當時間后(hou),被還原而脫去,通常(chang)(chang)這(zhe)(zhe)種(zhong)桿的(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)(zai)(zai)(zai)(zai)10—50ppm以下(xia),最低可達1-2ppm,從組(zu)織上(shang)看(kan),低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)(zai)(zai)(zai)于晶(jing)粒邊界附近,這(zhe)(zhe)對(dui)低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿而言可以說是(shi)常(chang)(chang)見(jian)(jian)的(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿則很(hen)少見(jian)(jian)。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)以夾雜(za)形(xing)式在(zai)(zai)(zai)(zai)(zai)(zai)晶(jing)界出現對(dui)材料的(de)(de)(de)韌性(xing)產生負(fu)面影響(xiang)。而無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很(hen)低,所以這(zhe)(zhe)種(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)組(zu)織是(shi)均勻的(de)(de)(de)單相組(zu)織對(dui)韌性(xing)有利(li)。在(zai)(zai)(zai)(zai)(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿中的(de)(de)(de)多孔性(xing)是(shi)不常(chang)(chang)見(jian)(jian)的(de)(de)(de),而在(zai)(zai)(zai)(zai)(zai)(zai)低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿中則是(shi)常(chang)(chang)見(jian)(jian)的(de)(de)(de)一種(zhong)缺陷。

二、熱軋組(zu)織(zhi)和鑄造(zao)組(zu)織(zhi)的區(qu)別

低(di)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)由于經(jing)過熱(re)軋(ya),所以(yi)其組(zu)(zu)織(zhi)(zhi)(zhi)屬熱(re)加工組(zu)(zu)織(zhi)(zhi)(zhi),原(yuan)來的(de)鑄(zhu)造(zao)組(zu)(zu)織(zhi)(zhi)(zhi)已經(jing)破碎,在(zai)8mm的(de)桿(gan)(gan)時(shi)(shi)已有(you)再(zai)結(jie)晶(jing)(jing)的(de)形式出現,而(er)無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)屬鑄(zhu)造(zao)組(zu)(zu)織(zhi)(zhi)(zhi),晶(jing)(jing)粒(li)粗大(da)(da),這(zhe)是為什(shen)么,無(wu)氧(yang)(yang)銅(tong)(tong)的(de)再(zai)結(jie)晶(jing)(jing)溫度較高,需(xu)要較高退(tui)火溫度的(de)固有(you)原(yuan)因(yin)。這(zhe)是因(yin)為,再(zai)結(jie)晶(jing)(jing)發(fa)生在(zai)晶(jing)(jing)粒(li)邊(bian)(bian)界(jie)(jie)附近,無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)組(zu)(zu)織(zhi)(zhi)(zhi)晶(jing)(jing)粒(li)粗大(da)(da),晶(jing)(jing)粒(li)尺寸甚至能(neng)達幾個(ge)毫米,因(yin)而(er)晶(jing)(jing)粒(li)邊(bian)(bian)界(jie)(jie)少,即使通過拉(la)制(zhi)變形,但晶(jing)(jing)粒(li)邊(bian)(bian)界(jie)(jie)相對(dui)低(di)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)還是較少,所以(yi)需(xu)要較高的(de)退(tui)火功率(lv)(lv)。對(dui)無(wu)氧(yang)(yang)銅(tong)(tong)成(cheng)功的(de)退(tui)火要求是:由桿(gan)(gan)經(jing)拉(la)制(zhi),但尚(shang)未鑄(zhu)造(zao)組(zu)(zu)織(zhi)(zhi)(zhi)的(de)線時(shi)(shi)的(de)第一次退(tui)火,其退(tui)火功率(lv)(lv)應(ying)比同樣情(qing)況的(de)低(di)氧(yang)(yang)銅(tong)(tong)高10——15%。經(jing)繼續拉(la)制(zhi),在(zai)以(yi)后(hou)階(jie)段的(de)退(tui)火功率(lv)(lv)應(ying)留有(you)足夠的(de)余(yu)量(liang)和對(dui)低(di)氧(yang)(yang)銅(tong)(tong)和無(wu)氧(yang)(yang)銅(tong)(tong)切實區別(bie)執行不同的(de)退(tui)火工藝,以(yi)保(bao)證在(zai)制(zhi)品和成(cheng)品導線的(de)柔軟性(xing)。

三、夾(jia)雜(za),氧(yang)含量波(bo)動,表面氧(yang)化(hua)物和可能存(cun)在的熱軋缺陷的差別

無氧(yang)(yang)(yang)銅桿的(de)可拉(la)性在所(suo)有(you)線(xian)(xian)徑里與低(di)氧(yang)(yang)(yang)銅桿相比都是優越的(de),除(chu)上述組織原因(yin)外,無氧(yang)(yang)(yang)銅桿夾雜少(shao),含氧(yang)(yang)(yang)量穩定(ding),無熱軋(ya)可能產生的(de)缺陷,桿表(biao)氧(yang)(yang)(yang)化物(wu)(wu)厚度可達(da)≤15A。在連(lian)鑄連(lian)軋(ya)生產過(guo)程中如果(guo)工藝(yi)不(bu)穩定(ding),對(dui)氧(yang)(yang)(yang)監(jian)控不(bu)嚴,含氧(yang)(yang)(yang)量不(bu)穩定(ding)將直接(jie)影響桿的(de)性能。如果(guo)桿的(de)表(biao)面氧(yang)(yang)(yang)化物(wu)(wu)能在后(hou)工序(xu)的(de)連(lian)續(xu)清(qing)洗中得以(yi)彌補外,但比較麻煩的(de)是有(you)相當多的(de)氧(yang)(yang)(yang)化物(wu)(wu)存(cun)在于“皮(pi)下(xia)”,對(dui)拉(la)線(xian)(xian)斷線(xian)(xian)影響更直接(jie),故而在拉(la)制微細(xi)線(xian)(xian),超微細(xi)線(xian)(xian)時,為了減少(shao)斷線(xian)(xian),有(you)時要對(dui)銅桿采取不(bu)得已的(de)辦(ban)法——剝皮(pi),甚(shen)至二次剝皮(pi)的(de)原因(yin)所(suo)在,目的(de)要除(chu)去(qu)皮(pi)下(xia)氧(yang)(yang)(yang)化物(wu)(wu)。

四、低氧銅桿(gan)和無氧銅桿(gan)的韌性有差別

兩者都可以拉(la)到0.015mm,但在低溫(wen)超(chao)導線中的低溫(wen)級無氧銅(tong),其細絲(si)間的間距只(zhi)有0.001mm.

五、從(cong)制桿(gan)的(de)原材料(liao)到制線的(de)經濟性有差別。

制(zhi)造無氧(yang)銅桿(gan)(gan)要求質量(liang)較高的原材料(liao)。一般,拉(la)制(zhi)直徑>1mm的銅線(xian)時,低氧(yang)銅桿(gan)(gan)的優(you)點(dian)比較明顯,而無氧(yang)銅桿(gan)(gan)顯得更為優(you)越的是(shi)拉(la)制(zhi)直徑<0.5mm的銅線(xian)。

六(liu)、低氧(yang)銅桿的(de)制(zhi)線工藝與無氧(yang)銅桿的(de)有所不同。

低(di)氧(yang)銅桿的(de)制(zhi)線(xian)工藝(yi)不能照搬到無(wu)氧(yang)銅桿的(de)制(zhi)線(xian)工藝(yi)上來,至少兩者(zhe)的(de)退火工藝(yi)是(shi)不同的(de)。因為(wei)線(xian)的(de)柔軟性(xing)深受材料成份(fen)和(he)制(zhi)桿,制(zhi)線(xian)和(he)退火工藝(yi)的(de)影響,不能簡單(dan)地說低(di)氧(yang)銅或無(wu)氧(yang)銅誰軟誰硬。