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梅里斯達斡爾族電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業動態 閱讀(du):109244 發布(bu)時間(jian):2019-07-05

導(dao)讀:由于生(sheng)(sheng)產(chan)銅(tong)桿的(de)兩者的(de)工藝(yi)不(bu)同,所生(sheng)(sheng)產(chan)的(de)銅(tong)桿中的(de)含氧量(liang)及外(wai)觀就不(bu)同。上引生(sheng)(sheng)產(chan)的(de)銅(tong)桿,工藝(yi)得當氧含量(liang)在10ppm以下,叫無氧銅(tong)桿;連鑄連鑄生(sheng)(sheng)產(chan)的(de)銅(tong)桿 是在保護條件下的(de)熱軋,氧含量(liang)在200-500ppm范圍內,但有(you)時也高達700ppm以上,一般情(qing)況下,此種方(fang)法生(sheng)(sheng)產(chan)的(de)銅(tong)外(wai)表光亮,低氧銅(tong)桿,有(you)時也叫光桿。

銅(tong)桿(gan)是電纜行(xing)業的(de)主要原料(liao),生(sheng)產(chan)的(de)方(fang)(fang)式主要有兩種——連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)法(fa)和上引連(lian)(lian)鑄(zhu)(zhu)(zhu)法(fa)。連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)低氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)的(de)生(sheng)產(chan)方(fang)(fang)法(fa)較多,其特點是金(jin)屬在(zai)(zai)(zai)豎爐(lu)中(zhong)(zhong)融化后(hou),銅(tong)液通(tong)(tong)過(guo)保溫爐(lu)、溜槽(cao)、中(zhong)(zhong)間包,從(cong)澆管進入封(feng)閉的(de)模腔(qiang)內(nei),采(cai)用較大(da)的(de)冷卻強度進行(xing)冷卻,形(xing)(xing)成鑄(zhu)(zhu)(zhu)坯(pi),然后(hou)進行(xing)多道(dao)次軋(ya)制(zhi),生(sheng)產(chan)的(de)低氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)為(wei)熱加工組織,原來(lai)的(de)鑄(zhu)(zhu)(zhu)造組織已(yi)經破碎,含氧(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般(ban)為(wei)200~400ppm之(zhi)間。無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)國內(nei)基(ji)本全部采(cai)用上引連(lian)(lian)鑄(zhu)(zhu)(zhu)法(fa)生(sheng)產(chan),金(jin)屬在(zai)(zai)(zai)感應電爐(lu)中(zhong)(zhong)融化后(hou)通(tong)(tong)過(guo)石墨模進行(xing)上引連(lian)(lian)續鑄(zhu)(zhu)(zhu)造,之(zhi)后(hou)進行(xing)冷軋(ya)或冷加工,生(sheng)產(chan)的(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)為(wei)鑄(zhu)(zhu)(zhu)造組織,含氧(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般(ban)在(zai)(zai)(zai)20ppm以(yi)下。由于(yu)制(zhi)造工藝的(de)不(bu)同,所以(yi)在(zai)(zai)(zai)組織結構、氧(yang)(yang)(yang)(yang)含量(liang)分(fen)(fen)布、雜(za)質的(de)形(xing)(xing)式及分(fen)(fen)布等諸多方(fang)(fang)面有較大(da)差別。

一、拉制性能

銅桿(gan)的(de)拉(la)制(zhi)性能跟很多因(yin)素有關,如雜質的(de)含(han)量(liang)、氧含(han)量(liang)及分布(bu)、工藝控(kong)制(zhi)等。下面分別從以上(shang)幾(ji)個方面對銅桿(gan)的(de)拉(la)制(zhi)性能進(jin)行分析。

1、熔化方式對(dui)S等雜質的影響(xiang)

連(lian)(lian)鑄連(lian)(lian)軋(ya)生產銅(tong)(tong)桿(gan)主要(yao)是通過(guo)氣(qi)體的(de)(de)燃燒使銅(tong)(tong)桿(gan)熔(rong)化,在燃燒的(de)(de)過(guo)程中,通過(guo)氧化和揮發(fa)作用,可一定程度減少部分雜質(zhi)進入銅(tong)(tong)液(ye),因此連(lian)(lian)鑄連(lian)(lian)軋(ya)法對原料要(yao)求相對低一些。上(shang)引連(lian)(lian)鑄生產無氧銅(tong)(tong)桿(gan),由(you)于是用感應電爐熔(rong)化,電解(jie)銅(tong)(tong)表面的(de)(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本(ben)都熔(rong)入到(dao)銅(tong)(tong)液(ye)中。其中熔(rong)入的(de)(de)S對無氧銅(tong)(tong)桿(gan)塑性影響極(ji)大,會增加(jia)拉絲斷線率(lv)。

2、鑄造(zao)過(guo)程中(zhong)雜質(zhi)的進入

在生(sheng)產過程中(zhong)(zhong),連鑄連軋(ya)工藝需通(tong)過保溫爐(lu)、溜槽、中(zhong)(zhong)間包轉運銅液,相對(dui)容易造成(cheng)耐火材(cai)料(liao)(liao)的(de)(de)剝落(luo),在軋(ya)制過程中(zhong)(zhong)需要通(tong)過軋(ya)輥,造成(cheng)鐵質(zhi)的(de)(de)脫(tuo)落(luo),會給銅桿造成(cheng)外部夾雜。而熱(re)軋(ya)中(zhong)(zhong)皮上(shang)和皮下(xia)氧化物的(de)(de)軋(ya)入,會給低氧桿的(de)(de)拉(la)絲造成(cheng)不利的(de)(de)影響(xiang)。上(shang)引連鑄法生(sheng)產工藝流程較(jiao)短,銅液是通(tong)過聯體(ti)爐(lu)內潛流式完成(cheng),對(dui)耐火材(cai)料(liao)(liao)的(de)(de)沖擊不大,結晶是通(tong)過石墨(mo)模內進(jin)行,所以(yi)過程中(zhong)(zhong)可(ke)能產生(sheng)的(de)(de)污染源較(jiao)少(shao),雜質(zhi)進(jin)入的(de)(de)機會較(jiao)少(shao)。

O、S、P是與銅(tong)(tong)(tong)會生產化合物的元素。在熔態銅(tong)(tong)(tong)中,氧(yang)可(ke)以(yi)(yi)溶(rong)(rong)解(jie)一部分,但(dan)當銅(tong)(tong)(tong)冷(leng)凝(ning)時(shi),氧(yang)幾乎不(bu)溶(rong)(rong)解(jie)于銅(tong)(tong)(tong)中。熔態時(shi)所(suo)溶(rong)(rong)解(jie)的氧(yang),以(yi)(yi)銅(tong)(tong)(tong)=氧(yang)化亞銅(tong)(tong)(tong)共晶(jing)(jing)體析(xi)出,分布在晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)(tong)(tong)-氧(yang)化亞銅(tong)(tong)(tong)共晶(jing)(jing)體的出現,顯著(zhu)降低了銅(tong)(tong)(tong)的塑性。

硫(liu)可以溶(rong)解在(zai)熔(rong)體(ti)的銅(tong)中(zhong),但在(zai)室溫下(xia),其溶(rong)解度幾乎降低(di)到(dao)零(ling),它以硫(liu)化亞銅(tong)的形式出現在(zai)晶粒晶界處,會顯(xian)著降低(di)銅(tong)的塑性。

3、氧(yang)(yang)在低氧(yang)(yang)銅(tong)(tong)桿(gan)和無氧(yang)(yang)銅(tong)(tong)桿(gan)中分布(bu)形式及其影響

氧含(han)量(liang)對低(di)氧銅桿的(de)(de)拉(la)線(xian)性(xing)能有著明(ming)顯的(de)(de)影響。當氧含(han)量(liang)增加到最(zui)(zui)佳(jia)值時,銅桿的(de)(de)斷線(xian)率最(zui)(zui)低(di)。這(zhe)是因為氧在與大部分雜(za)質反應的(de)(de)過程中都起到了清除(chu)(chu)器的(de)(de)作用。適度的(de)(de)氧還有利于去(qu)除(chu)(chu)銅液中的(de)(de)氫,生成(cheng)水蒸(zheng)氣溢出,減少(shao)氣孔的(de)(de)形成(cheng)。最(zui)(zui)佳(jia)的(de)(de)氧含(han)量(liang)為拉(la)線(xian)工(gong)藝(yi)提供了最(zui)(zui)好的(de)(de)條件(jian)。

低氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)氧(yang)(yang)(yang)(yang)化物(wu)的(de)(de)分(fen)(fen)布(bu)(bu):在連續澆鑄(zhu)中(zhong)凝固(gu)的(de)(de)最初階段,散熱速率和均勻(yun)(yun)冷(leng)卻是決定銅(tong)桿(gan)氧(yang)(yang)(yang)(yang)化物(wu)分(fen)(fen)布(bu)(bu)的(de)(de)主要因(yin)素。不(bu)均勻(yun)(yun)冷(leng)卻會引起(qi)銅(tong)桿(gan)內部結構本質上的(de)(de)差異,但后續的(de)(de)熱加工,柱狀晶通(tong)常會遭到破壞,使氧(yang)(yang)(yang)(yang)化亞銅(tong)顆粒(li)(li)細微化和均勻(yun)(yun)分(fen)(fen)布(bu)(bu)。氧(yang)(yang)(yang)(yang)化物(wu)顆粒(li)(li)聚集而產生的(de)(de)典型情況是中(zhong)心爆裂(lie)。除(chu)氧(yang)(yang)(yang)(yang)化物(wu)顆粒(li)(li)分(fen)(fen)布(bu)(bu)的(de)(de)影(ying)響外(wai),具(ju)有較小(xiao)氧(yang)(yang)(yang)(yang)化物(wu)顆粒(li)(li)的(de)(de)銅(tong)桿(gan)顯(xian)示出較好的(de)(de)拉線特性,較大的(de)(de)Cu2O顆粒(li)(li)容(rong)易造成應力集中(zhong)點而斷裂(lie)。

無(wu)(wu)氧(yang)(yang)(yang)銅含氧(yang)(yang)(yang)量超標,銅桿變脆(cui),延伸(shen)(shen)率下(xia)降(jiang),拉伸(shen)(shen)式樣端口(kou)顯暗紅色,結晶組織(zhi)疏松(song)。當(dang)氧(yang)(yang)(yang)含量超出8ppm時,工(gong)藝性能(neng)變差,表現為鑄造(zao)及(ji)拉伸(shen)(shen)過程中斷(duan)桿及(ji)斷(duan)線(xian)率極具增(zeng)高(gao)。這是由于氧(yang)(yang)(yang)能(neng)與(yu)銅生成氧(yang)(yang)(yang)化(hua)亞銅脆(cui)性相,形成銅-氧(yang)(yang)(yang)化(hua)亞銅共(gong)晶體,以網狀組織(zhi)分布(bu)在(zai)(zai)境界(jie)上。這種脆(cui)性相硬(ying)度(du)高(gao),在(zai)(zai)冷變形時將會與(yu)銅機(ji)體脫離,導致(zhi)(zhi)銅桿的機(ji)械性能(neng)下(xia)降(jiang),在(zai)(zai)后續加(jia)工(gong)中容(rong)易(yi)造(zao)成斷(duan)裂現象。氧(yang)(yang)(yang)含量高(gao)還能(neng)導致(zhi)(zhi)無(wu)(wu)氧(yang)(yang)(yang)銅桿導電(dian)率下(xia)降(jiang)。因此,必須嚴(yan)格控制上引連鑄工(gong)藝及(ji)產品質量。

4、氫的影響

在上(shang)引連鑄中,氧含量(liang)控(kong)制較低,氧化物(wu)的副(fu)作用唄**降低,但氫的影響成(cheng)為較顯著(zhu)的問(wen)題。吸氣后(hou)熔體中存(cun)在平衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)體及疏(shu)松(song)(song)是在(zai)(zai)結(jie)晶的(de)(de)(de)過(guo)程中(zhong),氫從(cong)過(guo)飽和的(de)(de)(de)溶液中(zhong)析出(chu)(chu)并聚集(ji)而形(xing)(xing)(xing)成(cheng)的(de)(de)(de)。在(zai)(zai)結(jie)晶前(qian)析出(chu)(chu)的(de)(de)(de)氫又可還(huan)原氧化亞銅而生(sheng)成(cheng)水氣(qi)(qi)泡。由于上引(yin)鑄(zhu)造的(de)(de)(de)特點(dian)是銅液自上而下的(de)(de)(de)結(jie)晶,形(xing)(xing)(xing)成(cheng)的(de)(de)(de)液**形(xing)(xing)(xing)狀近(jin)似錐型。銅液結(jie)晶前(qian)析出(chu)(chu)的(de)(de)(de)氣(qi)(qi)體在(zai)(zai)上浮過(guo)程中(zhong)被堵在(zai)(zai)凝(ning)固組織內,結(jie)晶時(shi)(shi)在(zai)(zai)鑄(zhu)桿(gan)內形(xing)(xing)(xing)成(cheng)氣(qi)(qi)孔(kong)。上引(yin)的(de)(de)(de)含氣(qi)(qi)量(liang)少時(shi)(shi),析出(chu)(chu)的(de)(de)(de)氫存在(zai)(zai)于晶界處,形(xing)(xing)(xing)成(cheng)疏(shu)松(song)(song);含氣(qi)(qi)量(liang)多時(shi)(shi),則聚集(ji)成(cheng)氣(qi)(qi)孔(kong),因此,氣(qi)(qi)孔(kong)和疏(shu)松(song)(song)是氫氣(qi)(qi)和水蒸氣(qi)(qi)兩者(zhe)形(xing)(xing)(xing)成(cheng)的(de)(de)(de)。

氫來源于(yu)上引生產過程中(zhong)的各個工藝(yi)環節,如原料(liao)(liao)電解(jie)銅(tong)(tong)的“銅(tong)(tong)綠(lv)”、輔料(liao)(liao)木炭(tan)**、氣(qi)候環境(jing)**、石墨結晶器未干燥等(deng)。因此,熔化爐(lu)中(zhong)的銅(tong)(tong)液表面應(ying)覆蓋經烘烤的木炭(tan),電解(jie)銅(tong)(tong)應(ying)盡量去除“銅(tong)(tong)綠(lv)”、“銅(tong)(tong)豆”“耳朵”,對提高無(wu)氧銅(tong)(tong)桿(gan)質量非常重要(yao)。

在(zai)連(lian)鑄連(lian)軋工藝(yi)中,往往采用適(shi)度控制(zhi)氧含量(liang)來控制(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于銅液(ye)在鑄(zhu)造過程中(zhong)是自下而(er)上(shang)(shang)結晶,銅液(ye)中(zhong)的(de)氧和氫(qing)所產生的(de)水(shui)蒸氣很容易上(shang)(shang)浮跑出,銅液(ye)中(zhong)的(de)氫(qing)大部(bu)分能被有(you)效去除,因而(er)對(dui)銅桿的(de)影響較(jiao)小。

二、表面質量

在生產(chan)(chan)電(dian)磁線(xian)等產(chan)(chan)品的(de)(de)過程(cheng)中,對銅(tong)桿(gan)(gan)的(de)(de)表面(mian)(mian)質量(liang)也需提出(chu)要求。需要拉制后的(de)(de)銅(tong)絲表面(mian)(mian)無(wu)毛刺、銅(tong)粉(fen)少、無(wu)油污(wu)。并通過扭(niu)(niu)轉(zhuan)試(shi)驗測量(liang)表面(mian)(mian)銅(tong)粉(fen)的(de)(de)質量(liang)和(he)扭(niu)(niu)轉(zhuan)后觀察銅(tong)桿(gan)(gan)的(de)(de)復原情(qing)況(kuang)來判(pan)定其好壞。

在連(lian)鑄連(lian)軋(ya)(ya)過程中(zhong)(zhong),從(cong)鑄造到軋(ya)(ya)制前,溫(wen)度(du)高,完全暴露于空(kong)氣中(zhong)(zhong),使鑄坯表面形(xing)成較(jiao)厚的氧(yang)化(hua)層,在軋(ya)(ya)制過程中(zhong)(zhong),隨著軋(ya)(ya)輥的轉動(dong),氧(yang)化(hua)物顆粒軋(ya)(ya)入(ru)銅線表面。由于氧(yang)化(hua)亞銅是高熔點脆(cui)性(xing)化(hua)合物,對于軋(ya)(ya)入(ru)較(jiao)深的氧(yang)化(hua)亞銅,當成條狀(zhuang)的聚集(ji)物遇模具拉(la)伸時,就會(hui)是銅桿外表面產生毛(mao)刺,給后續的涂漆造成麻煩。

而上(shang)引連鑄(zhu)工藝(yi)制(zhi)造(zao)的無氧(yang)銅(tong)(tong)(tong)桿,由于(yu)鑄(zhu)造(zao)和冷(leng)卻完全與(yu)氧(yang)隔絕,后續亦無熱軋(ya)過(guo)程,銅(tong)(tong)(tong)桿表面(mian)(mian)無軋(ya)入表面(mian)(mian)的氧(yang)化物,質(zhi)量較(jiao)好,拉(la)制(zhi)后銅(tong)(tong)(tong)粉少,上(shang)述問題(ti)較(jiao)少存在(zai)。

無氧(yang)銅桿(gan)也(ye)分進口設備做(zuo)的(de)(de)和國產(chan)設備做(zuo)的(de)(de),但目(mu)前(qian)進口產(chan)品(pin)已無明顯優(you)勢,銅桿(gan)產(chan)品(pin)出來后(hou)區別(bie)不(bu)是(shi)很大,只(zhi)要銅板選的(de)(de)好(hao),生(sheng)(sheng)產(chan)控制比較穩(wen)定,國產(chan)設備也(ye)能產(chan)出可拉伸0.05的(de)(de)銅桿(gan).進口設備一般是(shi)芬蘭(lan)奧托昆(kun)普的(de)(de)設備,國產(chan)設備最好(hao)的(de)(de)應該是(shi)上海的(de)(de)海軍廠的(de)(de)了,生(sheng)(sheng)產(chan)時間最長,軍工(gong)企(qi)業,質量(liang)可靠。

低氧銅桿進(jin)口設備國(guo)(guo)際(ji)主要有兩種(zhong),一(yi)種(zhong)是(shi)(shi)美國(guo)(guo)南(nan)(nan)線設備,英文是(shi)(shi)SOUTHWIRE,國(guo)(guo)內(nei)廠(chang)家是(shi)(shi)南(nan)(nan)京華新,江(jiang)西銅業,另一(yi)種(zhong)是(shi)(shi)德國(guo)(guo)CONTIROD設備,國(guo)(guo)內(nei)廠(chang)家是(shi)(shi)常州(zhou)金源,天津(jin)大無縫。

無(wu)氧(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)從含氧(yang)(yang)(yang)量上容易區別(bie),無(wu)氧(yang)(yang)(yang)銅是含氧(yang)(yang)(yang)量在10-20個(ge)PPM以下,但目(mu)前有(you)的(de)(de)(de)(de)廠家只能(neng)做(zuo)到50個(ge)PPM以下.低(di)(di)氧(yang)(yang)(yang)銅桿(gan)(gan)在 200-400個(ge)PPM,好(hao)(hao)的(de)(de)(de)(de)桿(gan)(gan)子(zi)一(yi)(yi)般含氧(yang)(yang)(yang)量控制在250個(ge)PPM左(zuo)右(you),無(wu)氧(yang)(yang)(yang)桿(gan)(gan)一(yi)(yi)般采取的(de)(de)(de)(de)是上引(yin)法,低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)是連鑄連軋,兩種產品相(xiang)對(dui)而(er)(er)言低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)對(dui)漆(qi)包線(xian)(xian)性 能(neng)更適應些(xie),如柔軟性,回(hui)彈角,繞線(xian)(xian)性能(neng).但低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)對(dui)拉絲條件相(xiang)對(dui)要苛刻些(xie),同(tong)樣拉伸(shen)0.2的(de)(de)(de)(de)細(xi)絲,如果(guo)伸(shen)線(xian)(xian)條件不好(hao)(hao),普通的(de)(de)(de)(de)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)可拉而(er)(er)好(hao)(hao)的(de)(de)(de)(de)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)就(jiu)斷(duan) 線(xian)(xian),但如果(guo)放(fang)在好(hao)(hao)的(de)(de)(de)(de)伸(shen)線(xian)(xian)條件,同(tong)樣的(de)(de)(de)(de)桿(gan)(gan)子(zi),低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)說不定(ding)就(jiu)能(neng)拉到雙零五,而(er)(er)普通無(wu)氧(yang)(yang)(yang)桿(gan)(gan)最多只能(neng)拉伸(shen)到0.1而(er)(er)已(yi),當然做(zuo)的(de)(de)(de)(de)最細(xi)的(de)(de)(de)(de)如雙零二(er)卻非得依(yi)靠進(jin)口的(de)(de)(de)(de) 無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)了.目(mu)前有(you)企業嘗(chang)試(shi)用(yong)剝皮的(de)(de)(de)(de)方式來處(chu)理低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)來伸(shen)0.03線(xian)(xian).但有(you)關這方面(mian)的(de)(de)(de)(de)內容我還不是很清(qing)楚。

音響線一般反而喜歡用無氧(yang)桿,這和無氧(yang)桿是單晶銅(tong),低氧(yang)桿是多(duo)晶銅(tong)有關。

氧(yang)銅桿和(he)無氧(yang)銅桿由(you)于制造方法的不同,致使存在差(cha)別(bie),具有(you)各自的特點。

一、關于氧的吸入和(he)脫去以及它的存在狀(zhuang)態

生產銅(tong)(tong)桿(gan)的(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)含(han)氧(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)(zai)常(chang)溫下(xia)氧(yang)(yang)(yang)在(zai)(zai)(zai)(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)固溶度約(yue)2ppm。低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)含(han)氧(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)進入是(shi)在(zai)(zai)(zai)(zai)(zai)銅(tong)(tong)的(de)(de)(de)液態下(xia)吸入的(de)(de)(de),而(er)上引法無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)(ze)相反(fan),氧(yang)(yang)(yang)在(zai)(zai)(zai)(zai)(zai)液態銅(tong)(tong)下(xia)保(bao)持相當(dang)時(shi)間后,被還原而(er)脫去(qu),通常(chang)這種桿(gan)的(de)(de)(de)含(han)氧(yang)(yang)(yang)量(liang)都(dou)在(zai)(zai)(zai)(zai)(zai)10—50ppm以下(xia),最低可(ke)達1-2ppm,從組(zu)織上看,低氧(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang),以氧(yang)(yang)(yang)化銅(tong)(tong)狀(zhuang)態,存在(zai)(zai)(zai)(zai)(zai)于晶粒邊(bian)界附近,這對(dui)低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)而(er)言可(ke)以說是(shi)常(chang)見(jian)(jian)的(de)(de)(de)但對(dui)無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)(ze)很少見(jian)(jian)。氧(yang)(yang)(yang)化銅(tong)(tong)以夾雜形式在(zai)(zai)(zai)(zai)(zai)晶界出現對(dui)材料(liao)的(de)(de)(de)韌(ren)性(xing)產生負面影響(xiang)。而(er)無氧(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)(yang)很低,所(suo)以這種銅(tong)(tong)的(de)(de)(de)組(zu)織是(shi)均勻(yun)的(de)(de)(de)單相組(zu)織對(dui)韌(ren)性(xing)有利(li)。在(zai)(zai)(zai)(zai)(zai)無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)多孔性(xing)是(shi)不常(chang)見(jian)(jian)的(de)(de)(de),而(er)在(zai)(zai)(zai)(zai)(zai)低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)則(ze)(ze)是(shi)常(chang)見(jian)(jian)的(de)(de)(de)一(yi)種缺陷。

二、熱軋組織和鑄造(zao)組織的(de)區別(bie)

低氧(yang)(yang)銅(tong)桿由(you)于經(jing)過熱(re)軋,所以(yi)其組(zu)(zu)織(zhi)(zhi)屬(shu)(shu)熱(re)加工(gong)組(zu)(zu)織(zhi)(zhi),原來的(de)(de)(de)鑄造組(zu)(zu)織(zhi)(zhi)已(yi)經(jing)破碎,在(zai)8mm的(de)(de)(de)桿時已(yi)有再結(jie)晶(jing)(jing)(jing)的(de)(de)(de)形式出現,而(er)無(wu)(wu)氧(yang)(yang)銅(tong)桿屬(shu)(shu)鑄造組(zu)(zu)織(zhi)(zhi),晶(jing)(jing)(jing)粒(li)(li)粗大,這(zhe)是(shi)為(wei)什(shen)么,無(wu)(wu)氧(yang)(yang)銅(tong)的(de)(de)(de)再結(jie)晶(jing)(jing)(jing)溫度較高(gao)(gao),需要(yao)(yao)較高(gao)(gao)退(tui)(tui)火(huo)(huo)溫度的(de)(de)(de)固(gu)有原因。這(zhe)是(shi)因為(wei),再結(jie)晶(jing)(jing)(jing)發生在(zai)晶(jing)(jing)(jing)粒(li)(li)邊(bian)界(jie)附近,無(wu)(wu)氧(yang)(yang)銅(tong)桿組(zu)(zu)織(zhi)(zhi)晶(jing)(jing)(jing)粒(li)(li)粗大,晶(jing)(jing)(jing)粒(li)(li)尺寸甚至能達(da)幾(ji)個(ge)毫米,因而(er)晶(jing)(jing)(jing)粒(li)(li)邊(bian)界(jie)少,即使(shi)通(tong)過拉制變(bian)形,但晶(jing)(jing)(jing)粒(li)(li)邊(bian)界(jie)相對低氧(yang)(yang)銅(tong)桿還是(shi)較少,所以(yi)需要(yao)(yao)較高(gao)(gao)的(de)(de)(de)退(tui)(tui)火(huo)(huo)功(gong)(gong)率(lv)。對無(wu)(wu)氧(yang)(yang)銅(tong)成功(gong)(gong)的(de)(de)(de)退(tui)(tui)火(huo)(huo)要(yao)(yao)求是(shi):由(you)桿經(jing)拉制,但尚未鑄造組(zu)(zu)織(zhi)(zhi)的(de)(de)(de)線(xian)時的(de)(de)(de)第一次退(tui)(tui)火(huo)(huo),其退(tui)(tui)火(huo)(huo)功(gong)(gong)率(lv)應(ying)(ying)比同(tong)樣情況的(de)(de)(de)低氧(yang)(yang)銅(tong)高(gao)(gao)10——15%。經(jing)繼續拉制,在(zai)以(yi)后階段的(de)(de)(de)退(tui)(tui)火(huo)(huo)功(gong)(gong)率(lv)應(ying)(ying)留有足夠的(de)(de)(de)余(yu)量和對低氧(yang)(yang)銅(tong)和無(wu)(wu)氧(yang)(yang)銅(tong)切實區別執行不同(tong)的(de)(de)(de)退(tui)(tui)火(huo)(huo)工(gong)藝(yi),以(yi)保(bao)證在(zai)制品(pin)和成品(pin)導(dao)線(xian)的(de)(de)(de)柔軟性(xing)。

三、夾雜,氧含(han)量波動,表面氧化物和可能存在的熱(re)軋缺陷的差別

無(wu)氧(yang)(yang)(yang)銅桿(gan)的(de)(de)(de)可(ke)拉(la)性(xing)在所有線(xian)徑里與(yu)低(di)氧(yang)(yang)(yang)銅桿(gan)相比都是(shi)優(you)越的(de)(de)(de),除上述組織原因(yin)外(wai),無(wu)氧(yang)(yang)(yang)銅桿(gan)夾雜(za)少(shao),含氧(yang)(yang)(yang)量穩定(ding),無(wu)熱軋(ya)可(ke)能產生(sheng)的(de)(de)(de)缺陷,桿(gan)表(biao)氧(yang)(yang)(yang)化物厚度(du)可(ke)達≤15A。在連鑄連軋(ya)生(sheng)產過(guo)程(cheng)中如(ru)果工藝不(bu)穩定(ding),對氧(yang)(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)(yang)量不(bu)穩定(ding)將(jiang)直(zhi)接影響桿(gan)的(de)(de)(de)性(xing)能。如(ru)果桿(gan)的(de)(de)(de)表(biao)面氧(yang)(yang)(yang)化物能在后工序的(de)(de)(de)連續清(qing)洗(xi)中得以彌補外(wai),但比較(jiao)麻煩的(de)(de)(de)是(shi)有相當多的(de)(de)(de)氧(yang)(yang)(yang)化物存在于“皮下(xia)”,對拉(la)線(xian)斷線(xian)影響更直(zhi)接,故而(er)在拉(la)制微(wei)細(xi)線(xian),超微(wei)細(xi)線(xian)時,為了減(jian)少(shao)斷線(xian),有時要對銅桿(gan)采取不(bu)得已的(de)(de)(de)辦法——剝皮,甚至二次剝皮的(de)(de)(de)原因(yin)所在,目的(de)(de)(de)要除去皮下(xia)氧(yang)(yang)(yang)化物。

四、低氧銅桿和(he)無氧銅桿的韌性(xing)有差別

兩者都可以拉(la)到0.015mm,但在低(di)溫(wen)(wen)超導線中的低(di)溫(wen)(wen)級(ji)無氧銅(tong),其細絲間(jian)的間(jian)距只有0.001mm.

五、從(cong)制(zhi)桿的原材料到制(zhi)線的經濟性有(you)差別。

制(zhi)造(zao)無氧(yang)銅(tong)桿要求質量較高的(de)(de)(de)(de)原材料。一般,拉制(zhi)直(zhi)徑(jing)>1mm的(de)(de)(de)(de)銅(tong)線時(shi),低氧(yang)銅(tong)桿的(de)(de)(de)(de)優(you)點比(bi)較明顯,而無氧(yang)銅(tong)桿顯得更為(wei)優(you)越的(de)(de)(de)(de)是拉制(zhi)直(zhi)徑(jing)<0.5mm的(de)(de)(de)(de)銅(tong)線。

六、低(di)氧銅桿的制線工(gong)藝與無氧銅桿的有(you)所不同。

低氧(yang)銅(tong)桿(gan)(gan)的(de)制(zhi)線(xian)(xian)(xian)工(gong)藝(yi)不(bu)(bu)能照搬到無氧(yang)銅(tong)桿(gan)(gan)的(de)制(zhi)線(xian)(xian)(xian)工(gong)藝(yi)上來(lai),至少兩者的(de)退火(huo)工(gong)藝(yi)是不(bu)(bu)同的(de)。因為線(xian)(xian)(xian)的(de)柔軟性深受材料成(cheng)份和制(zhi)桿(gan)(gan),制(zhi)線(xian)(xian)(xian)和退火(huo)工(gong)藝(yi)的(de)影響,不(bu)(bu)能簡單地(di)說(shuo)低氧(yang)銅(tong)或無氧(yang)銅(tong)誰軟誰硬。