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來源(yuan):行業動(dong)態 閱讀:109494 發布時間(jian):2019-07-05
導讀:由(you)于生(sheng)(sheng)產(chan)(chan)銅桿(gan)的(de)兩者的(de)工(gong)藝(yi)不同,所生(sheng)(sheng)產(chan)(chan)的(de)銅桿(gan)中的(de)含(han)氧(yang)量(liang)及外觀就(jiu)不同。上(shang)(shang)引生(sheng)(sheng)產(chan)(chan)的(de)銅桿(gan),工(gong)藝(yi)得當氧(yang)含(han)量(liang)在10ppm以下(xia),叫無氧(yang)銅桿(gan);連鑄連鑄生(sheng)(sheng)產(chan)(chan)的(de)銅桿(gan) 是在保護(hu)條件下(xia)的(de)熱軋(ya),氧(yang)含(han)量(liang)在200-500ppm范圍內,但有(you)時也高達(da)700ppm以上(shang)(shang),一般情(qing)況下(xia),此種方法生(sheng)(sheng)產(chan)(chan)的(de)銅外表光亮,低氧(yang)銅桿(gan),有(you)時也叫光桿(gan)。
銅(tong)(tong)(tong)桿(gan)是(shi)電纜行(xing)業的(de)主要原料,生(sheng)產(chan)的(de)方式(shi)主要有兩種——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)法和上引連(lian)鑄(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)低氧(yang)銅(tong)(tong)(tong)桿(gan)的(de)生(sheng)產(chan)方法較多,其特點是(shi)金(jin)屬(shu)在(zai)(zai)(zai)豎爐(lu)(lu)中(zhong)融化后(hou),銅(tong)(tong)(tong)液通過保溫爐(lu)(lu)、溜槽、中(zhong)間包,從澆管進(jin)(jin)(jin)入封閉的(de)模腔內(nei),采(cai)用(yong)較大的(de)冷(leng)卻強度進(jin)(jin)(jin)行(xing)冷(leng)卻,形成鑄(zhu)(zhu)坯,然后(hou)進(jin)(jin)(jin)行(xing)多道次軋(ya)(ya)制(zhi),生(sheng)產(chan)的(de)低氧(yang)銅(tong)(tong)(tong)桿(gan)為熱加(jia)工組(zu)織(zhi)(zhi),原來的(de)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi)已經破碎,含氧(yang)量(liang)一般為200~400ppm之間。無氧(yang)銅(tong)(tong)(tong)桿(gan)國(guo)內(nei)基本全部采(cai)用(yong)上引連(lian)鑄(zhu)(zhu)法生(sheng)產(chan),金(jin)屬(shu)在(zai)(zai)(zai)感應電爐(lu)(lu)中(zhong)融化后(hou)通過石墨(mo)模進(jin)(jin)(jin)行(xing)上引連(lian)續鑄(zhu)(zhu)造(zao),之后(hou)進(jin)(jin)(jin)行(xing)冷(leng)軋(ya)(ya)或冷(leng)加(jia)工,生(sheng)產(chan)的(de)無氧(yang)銅(tong)(tong)(tong)桿(gan)為鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi),含氧(yang)量(liang)一般在(zai)(zai)(zai)20ppm以下。由于(yu)制(zhi)造(zao)工藝(yi)的(de)不同(tong),所以在(zai)(zai)(zai)組(zu)織(zhi)(zhi)結構、氧(yang)含量(liang)分布、雜(za)質的(de)形式(shi)及分布等諸多方面有較大差別(bie)。
一、拉制性能
銅(tong)桿(gan)的(de)拉制性能(neng)(neng)跟很(hen)多因素(su)有關(guan),如雜質的(de)含(han)量、氧含(han)量及分布、工藝控制等。下面分別(bie)從以上幾個方(fang)面對銅(tong)桿(gan)的(de)拉制性能(neng)(neng)進行分析(xi)。
1、熔化方式對S等雜質的影響
連鑄連軋(ya)生(sheng)產(chan)銅(tong)(tong)桿(gan)主要(yao)是通過(guo)氣(qi)體的(de)燃燒使銅(tong)(tong)桿(gan)熔(rong)化,在燃燒的(de)過(guo)程中,通過(guo)氧(yang)化和揮發(fa)作用,可一定程度減少部分雜質進入(ru)銅(tong)(tong)液,因此連鑄連軋(ya)法對原料要(yao)求相(xiang)對低一些。上引連鑄生(sheng)產(chan)無氧(yang)銅(tong)(tong)桿(gan),由于是用感應(ying)電爐熔(rong)化,電解(jie)銅(tong)(tong)表(biao)面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆(dou)”基本都熔(rong)入(ru)到銅(tong)(tong)液中。其中熔(rong)入(ru)的(de)S對無氧(yang)銅(tong)(tong)桿(gan)塑性影響極大,會增加拉絲斷線(xian)率。
2、鑄造過程中(zhong)雜(za)質(zhi)的進入
在生產過(guo)(guo)(guo)(guo)程(cheng)中(zhong)(zhong),連(lian)鑄連(lian)軋(ya)(ya)工(gong)藝需通過(guo)(guo)(guo)(guo)保溫爐、溜槽(cao)、中(zhong)(zhong)間包轉(zhuan)運銅(tong)液,相對(dui)容易造成(cheng)耐(nai)火材料(liao)的(de)(de)剝落,在軋(ya)(ya)制過(guo)(guo)(guo)(guo)程(cheng)中(zhong)(zhong)需要(yao)通過(guo)(guo)(guo)(guo)軋(ya)(ya)輥,造成(cheng)鐵(tie)質的(de)(de)脫落,會給(gei)銅(tong)桿(gan)造成(cheng)外部夾(jia)雜(za)。而熱軋(ya)(ya)中(zhong)(zhong)皮上(shang)和皮下氧化物(wu)的(de)(de)軋(ya)(ya)入,會給(gei)低氧桿(gan)的(de)(de)拉絲(si)造成(cheng)不利的(de)(de)影(ying)響。上(shang)引連(lian)鑄法生產工(gong)藝流程(cheng)較(jiao)(jiao)短,銅(tong)液是(shi)通過(guo)(guo)(guo)(guo)聯(lian)體(ti)爐內(nei)潛流式完成(cheng),對(dui)耐(nai)火材料(liao)的(de)(de)沖擊不大,結晶是(shi)通過(guo)(guo)(guo)(guo)石墨模內(nei)進行,所以過(guo)(guo)(guo)(guo)程(cheng)中(zhong)(zhong)可能產生的(de)(de)污染(ran)源較(jiao)(jiao)少,雜(za)質進入的(de)(de)機會較(jiao)(jiao)少。
O、S、P是(shi)與(yu)銅(tong)會生產(chan)化(hua)合物的(de)(de)元素。在熔態銅(tong)中(zhong),氧(yang)(yang)可(ke)以(yi)溶(rong)解(jie)一(yi)部分,但當銅(tong)冷凝時,氧(yang)(yang)幾乎不溶(rong)解(jie)于(yu)銅(tong)中(zhong)。熔態時所(suo)溶(rong)解(jie)的(de)(de)氧(yang)(yang),以(yi)銅(tong)=氧(yang)(yang)化(hua)亞(ya)銅(tong)共晶體(ti)析(xi)出,分布(bu)在晶粒晶界處(chu)。銅(tong)-氧(yang)(yang)化(hua)亞(ya)銅(tong)共晶體(ti)的(de)(de)出現,顯著降低了銅(tong)的(de)(de)塑(su)性。
硫可(ke)以溶解在熔體(ti)的銅(tong)中,但在室溫下,其溶解度幾乎降(jiang)低到零,它(ta)以硫化(hua)亞銅(tong)的形(xing)式出現在晶粒晶界處,會(hui)顯著降(jiang)低銅(tong)的塑性。
3、氧在(zai)低(di)氧銅(tong)桿和無氧銅(tong)桿中分布形式(shi)及其影(ying)響
氧(yang)含(han)量對低氧(yang)銅桿的(de)拉線性能有著明顯的(de)影(ying)響。當氧(yang)含(han)量增加(jia)到最(zui)佳值(zhi)時,銅桿的(de)斷線率最(zui)低。這是因為(wei)氧(yang)在與大部分雜質反應的(de)過(guo)程中都起到了清除器的(de)作用。適度的(de)氧(yang)還有利于去(qu)除銅液中的(de)氫,生(sheng)成水蒸氣溢出,減少氣孔的(de)形(xing)成。最(zui)佳的(de)氧(yang)含(han)量為(wei)拉線工藝提供了最(zui)好(hao)的(de)條件。
低氧(yang)銅(tong)桿氧(yang)化物的(de)(de)(de)(de)分(fen)布(bu):在連續澆鑄中凝固的(de)(de)(de)(de)最(zui)初(chu)階段,散(san)熱速率和(he)均勻冷卻是(shi)決定銅(tong)桿氧(yang)化物分(fen)布(bu)的(de)(de)(de)(de)主要因(yin)素(su)。不均勻冷卻會引起銅(tong)桿內部結構(gou)本質上(shang)的(de)(de)(de)(de)差異,但后續的(de)(de)(de)(de)熱加工,柱(zhu)狀晶通常(chang)會遭到破壞(huai),使氧(yang)化亞銅(tong)顆(ke)粒(li)細微化和(he)均勻分(fen)布(bu)。氧(yang)化物顆(ke)粒(li)聚集而產生的(de)(de)(de)(de)典型情況是(shi)中心爆裂(lie)。除氧(yang)化物顆(ke)粒(li)分(fen)布(bu)的(de)(de)(de)(de)影響外,具有較(jiao)小氧(yang)化物顆(ke)粒(li)的(de)(de)(de)(de)銅(tong)桿顯示(shi)出較(jiao)好(hao)的(de)(de)(de)(de)拉(la)線特性,較(jiao)大的(de)(de)(de)(de)Cu2O顆(ke)粒(li)容易造成應力集中點而斷(duan)裂(lie)。
無氧(yang)銅含氧(yang)量超(chao)標(biao),銅桿(gan)(gan)變脆(cui),延伸率(lv)(lv)(lv)下(xia)(xia)降,拉(la)伸式樣端口顯(xian)暗紅色(se),結晶組織(zhi)疏松(song)。當氧(yang)含量超(chao)出8ppm時(shi),工藝性(xing)能(neng)變差,表現為鑄造及(ji)拉(la)伸過程中斷桿(gan)(gan)及(ji)斷線率(lv)(lv)(lv)極具增高。這是由于氧(yang)能(neng)與(yu)銅生成(cheng)(cheng)氧(yang)化(hua)亞銅脆(cui)性(xing)相(xiang),形成(cheng)(cheng)銅-氧(yang)化(hua)亞銅共晶體(ti),以網(wang)狀(zhuang)組織(zhi)分布在境界上(shang)。這種脆(cui)性(xing)相(xiang)硬度高,在冷變形時(shi)將會與(yu)銅機體(ti)脫離,導(dao)致(zhi)銅桿(gan)(gan)的(de)機械性(xing)能(neng)下(xia)(xia)降,在后續加工中容易造成(cheng)(cheng)斷裂現象。氧(yang)含量高還能(neng)導(dao)致(zhi)無氧(yang)銅桿(gan)(gan)導(dao)電率(lv)(lv)(lv)下(xia)(xia)降。因此,必須嚴格控制上(shang)引連鑄工藝及(ji)產品質量。
4、氫的影響
在(zai)上引連鑄中(zhong),氧含量控制較低,氧化物的(de)副作(zuo)用(yong)唄(bai)**降低,但氫(qing)的(de)影響成為較顯著(zhu)的(de)問(wen)題。吸氣后熔體中(zhong)存在(zai)平衡反(fan)應(ying):H2O(g)=[O]+2[H];
氣(qi)(qi)體(ti)及疏(shu)松是在(zai)(zai)結晶(jing)的(de)過(guo)程中(zhong)(zhong),氫(qing)從過(guo)飽和(he)的(de)溶液(ye)中(zhong)(zhong)析(xi)(xi)(xi)出并聚集而(er)形(xing)成(cheng)(cheng)(cheng)的(de)。在(zai)(zai)結晶(jing)前(qian)析(xi)(xi)(xi)出的(de)氫(qing)又可還原(yuan)氧化(hua)亞銅而(er)生成(cheng)(cheng)(cheng)水氣(qi)(qi)泡。由于上引(yin)鑄造的(de)特點(dian)是銅液(ye)自上而(er)下的(de)結晶(jing),形(xing)成(cheng)(cheng)(cheng)的(de)液(ye)**形(xing)狀近似錐型。銅液(ye)結晶(jing)前(qian)析(xi)(xi)(xi)出的(de)氣(qi)(qi)體(ti)在(zai)(zai)上浮過(guo)程中(zhong)(zhong)被堵在(zai)(zai)凝固組織內,結晶(jing)時在(zai)(zai)鑄桿內形(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)孔(kong)。上引(yin)的(de)含氣(qi)(qi)量(liang)少(shao)時,析(xi)(xi)(xi)出的(de)氫(qing)存在(zai)(zai)于晶(jing)界(jie)處,形(xing)成(cheng)(cheng)(cheng)疏(shu)松;含氣(qi)(qi)量(liang)多時,則聚集成(cheng)(cheng)(cheng)氣(qi)(qi)孔(kong),因(yin)此(ci),氣(qi)(qi)孔(kong)和(he)疏(shu)松是氫(qing)氣(qi)(qi)和(he)水蒸氣(qi)(qi)兩者形(xing)成(cheng)(cheng)(cheng)的(de)。
氫來源于上引(yin)生產過(guo)程中的(de)各(ge)個工藝環節,如原料電解銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔(fu)料木(mu)炭(tan)**、氣候環境**、石(shi)墨結晶(jing)器未干燥(zao)等。因(yin)此(ci),熔化爐(lu)中的(de)銅(tong)(tong)液表(biao)面應覆蓋經烘烤的(de)木(mu)炭(tan),電解銅(tong)(tong)應盡量去除“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳朵”,對提(ti)高無氧銅(tong)(tong)桿(gan)質量非常重要。
在連鑄連軋(ya)工藝中,往往采(cai)用適度控制氧(yang)含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液(ye)在鑄(zhu)造(zao)過程(cheng)中是自(zi)下而上結晶,銅(tong)液(ye)中的(de)氧和氫(qing)所(suo)產生的(de)水蒸氣很(hen)容易(yi)上浮跑出(chu),銅(tong)液(ye)中的(de)氫(qing)大部(bu)分能被有(you)效去除,因而對銅(tong)桿的(de)影響較小。
二、表面質量
在生產電磁線(xian)等產品(pin)的(de)過程(cheng)中,對銅(tong)(tong)桿的(de)表面質(zhi)量(liang)也需提出要(yao)求。需要(yao)拉制后(hou)(hou)的(de)銅(tong)(tong)絲表面無(wu)毛刺、銅(tong)(tong)粉(fen)少、無(wu)油污。并通過扭轉(zhuan)試驗測量(liang)表面銅(tong)(tong)粉(fen)的(de)質(zhi)量(liang)和扭轉(zhuan)后(hou)(hou)觀察銅(tong)(tong)桿的(de)復原(yuan)情況來判(pan)定(ding)其(qi)好壞。
在連鑄(zhu)(zhu)連軋(ya)(ya)過程(cheng)中,從(cong)鑄(zhu)(zhu)造(zao)到軋(ya)(ya)制前,溫(wen)度高,完全暴(bao)露于(yu)空氣中,使鑄(zhu)(zhu)坯表(biao)面(mian)(mian)形成(cheng)較厚的(de)(de)氧化(hua)(hua)層,在軋(ya)(ya)制過程(cheng)中,隨著軋(ya)(ya)輥的(de)(de)轉動,氧化(hua)(hua)物(wu)顆粒(li)軋(ya)(ya)入(ru)銅(tong)(tong)線表(biao)面(mian)(mian)。由于(yu)氧化(hua)(hua)亞(ya)銅(tong)(tong)是(shi)高熔點(dian)脆性化(hua)(hua)合物(wu),對(dui)于(yu)軋(ya)(ya)入(ru)較深的(de)(de)氧化(hua)(hua)亞(ya)銅(tong)(tong),當成(cheng)條(tiao)狀(zhuang)的(de)(de)聚集物(wu)遇模具拉伸(shen)時,就會是(shi)銅(tong)(tong)桿外表(biao)面(mian)(mian)產生(sheng)毛(mao)刺,給后續的(de)(de)涂漆造(zao)成(cheng)麻(ma)煩。
而上(shang)(shang)引連鑄(zhu)工藝制(zhi)造(zao)(zao)的(de)無(wu)氧銅桿,由于(yu)鑄(zhu)造(zao)(zao)和(he)冷卻完(wan)全與氧隔絕,后(hou)續(xu)亦無(wu)熱(re)軋過程(cheng),銅桿表(biao)面無(wu)軋入表(biao)面的(de)氧化(hua)物,質量較好,拉制(zhi)后(hou)銅粉少,上(shang)(shang)述問題較少存在。
無氧銅(tong)桿(gan)也(ye)分進口設(she)備(bei)做的(de)(de)(de)和國(guo)產(chan)(chan)設(she)備(bei)做的(de)(de)(de),但目前(qian)進口產(chan)(chan)品已(yi)無明顯優(you)勢,銅(tong)桿(gan)產(chan)(chan)品出來后區別不是很大,只(zhi)要銅(tong)板(ban)選的(de)(de)(de)好,生產(chan)(chan)控制比(bi)較穩定,國(guo)產(chan)(chan)設(she)備(bei)也(ye)能產(chan)(chan)出可拉伸0.05的(de)(de)(de)銅(tong)桿(gan).進口設(she)備(bei)一般是芬(fen)蘭奧托(tuo)昆普的(de)(de)(de)設(she)備(bei),國(guo)產(chan)(chan)設(she)備(bei)最好的(de)(de)(de)應該是上海(hai)的(de)(de)(de)海(hai)軍廠(chang)的(de)(de)(de)了(le),生產(chan)(chan)時間(jian)最長,軍工企業,質量(liang)可靠。
低氧(yang)銅(tong)(tong)桿進口(kou)設備(bei)國際(ji)主要有兩種(zhong),一(yi)種(zhong)是(shi)(shi)美國南線設備(bei),英(ying)文是(shi)(shi)SOUTHWIRE,國內廠家是(shi)(shi)南京華(hua)新,江西銅(tong)(tong)業,另一(yi)種(zhong)是(shi)(shi)德國CONTIROD設備(bei),國內廠家是(shi)(shi)常州金源,天津大無縫。
無(wu)氧(yang)(yang)(yang)及(ji)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上容易區別,無(wu)氧(yang)(yang)(yang)銅是(shi)含氧(yang)(yang)(yang)量在10-20個PPM以下(xia),但目前有(you)的(de)(de)廠家只能做(zuo)(zuo)到(dao)50個PPM以下(xia).低(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在 200-400個PPM,好(hao)的(de)(de)桿(gan)(gan)(gan)(gan)子一般含氧(yang)(yang)(yang)量控制在250個PPM左右(you),無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一般采(cai)取的(de)(de)是(shi)上引法,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)連鑄(zhu)連軋,兩種產品相對而言低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對漆包線(xian)性(xing)(xing)(xing) 能更適應些(xie),如(ru)柔軟性(xing)(xing)(xing),回(hui)彈(dan)角,繞(rao)線(xian)性(xing)(xing)(xing)能.但低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對拉(la)絲條件相對要苛刻些(xie),同(tong)樣(yang)拉(la)伸(shen)0.2的(de)(de)細絲,如(ru)果(guo)伸(shen)線(xian)條件不好(hao),普(pu)通(tong)的(de)(de)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可拉(la)而好(hao)的(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷(duan) 線(xian),但如(ru)果(guo)放在好(hao)的(de)(de)伸(shen)線(xian)條件,同(tong)樣(yang)的(de)(de)桿(gan)(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說不定就能拉(la)到(dao)雙零五(wu),而普(pu)通(tong)無(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最(zui)多只能拉(la)伸(shen)到(dao)0.1而已,當然做(zuo)(zuo)的(de)(de)最(zui)細的(de)(de)如(ru)雙零二卻非得(de)依(yi)靠(kao)進(jin)口的(de)(de) 無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了(le).目前有(you)企業(ye)嘗試用剝皮的(de)(de)方(fang)式來處理低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來伸(shen)0.03線(xian).但有(you)關(guan)這方(fang)面的(de)(de)內(nei)容我(wo)還不是(shi)很清楚。
音(yin)響(xiang)線一(yi)般反而喜歡用無氧桿,這和無氧桿是(shi)單(dan)晶銅,低氧桿是(shi)多(duo)晶銅有關。
氧(yang)銅桿和(he)無氧(yang)銅桿由(you)于制(zhi)造方法(fa)的不同,致使存在差別,具有各自的特(te)點(dian)。
一(yi)、關于氧的吸入和脫去(qu)以及它的存在狀態
生產銅(tong)(tong)(tong)(tong)(tong)桿(gan)的陰極銅(tong)(tong)(tong)(tong)(tong)的含(han)氧(yang)(yang)(yang)量一般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下(xia)氧(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中的固(gu)溶(rong)度約2ppm。低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的含(han)氧(yang)(yang)(yang)量一般在(zai)(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)的進入是(shi)(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的液態下(xia)吸(xi)入的,而(er)上引法(fa)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則相反(fan),氧(yang)(yang)(yang)在(zai)(zai)液態銅(tong)(tong)(tong)(tong)(tong)下(xia)保持相當時間后,被還原而(er)脫(tuo)去,通常(chang)(chang)這種(zhong)桿(gan)的含(han)氧(yang)(yang)(yang)量都在(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低可(ke)達1-2ppm,從組(zu)織上看(kan),低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的氧(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)狀態,存在(zai)(zai)于(yu)晶(jing)粒邊界附近,這對(dui)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)而(er)言可(ke)以(yi)(yi)說是(shi)(shi)常(chang)(chang)見的但對(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則很少見。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)以(yi)(yi)夾雜(za)形式在(zai)(zai)晶(jing)界出現對(dui)材(cai)料(liao)的韌性產生負面(mian)影響。而(er)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的氧(yang)(yang)(yang)很低,所以(yi)(yi)這種(zhong)銅(tong)(tong)(tong)(tong)(tong)的組(zu)織是(shi)(shi)均勻的單相組(zu)織對(dui)韌性有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中的多(duo)孔性是(shi)(shi)不常(chang)(chang)見的,而(er)在(zai)(zai)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中則是(shi)(shi)常(chang)(chang)見的一種(zhong)缺陷。
二、熱軋組(zu)織(zhi)和(he)鑄(zhu)造組(zu)織(zhi)的區別(bie)
低(di)氧銅(tong)(tong)桿由于經(jing)過熱軋,所以(yi)其(qi)組(zu)(zu)織(zhi)屬熱加工組(zu)(zu)織(zhi),原(yuan)來的(de)(de)鑄造(zao)(zao)組(zu)(zu)織(zhi)已(yi)經(jing)破(po)碎,在(zai)8mm的(de)(de)桿時(shi)(shi)已(yi)有再(zai)結(jie)晶(jing)的(de)(de)形(xing)式出現,而無(wu)氧銅(tong)(tong)桿屬鑄造(zao)(zao)組(zu)(zu)織(zhi),晶(jing)粒(li)粗大,這(zhe)是(shi)(shi)(shi)為什么,無(wu)氧銅(tong)(tong)的(de)(de)再(zai)結(jie)晶(jing)溫(wen)度(du)較(jiao)高,需要較(jiao)高退(tui)(tui)火溫(wen)度(du)的(de)(de)固(gu)有原(yuan)因(yin)。這(zhe)是(shi)(shi)(shi)因(yin)為,再(zai)結(jie)晶(jing)發生在(zai)晶(jing)粒(li)邊(bian)界附(fu)近(jin),無(wu)氧銅(tong)(tong)桿組(zu)(zu)織(zhi)晶(jing)粒(li)粗大,晶(jing)粒(li)尺寸甚(shen)至(zhi)能(neng)達幾(ji)個(ge)毫米,因(yin)而晶(jing)粒(li)邊(bian)界少(shao),即(ji)使(shi)通過拉制(zhi)變形(xing),但(dan)晶(jing)粒(li)邊(bian)界相對低(di)氧銅(tong)(tong)桿還是(shi)(shi)(shi)較(jiao)少(shao),所以(yi)需要較(jiao)高的(de)(de)退(tui)(tui)火功率(lv)(lv)。對無(wu)氧銅(tong)(tong)成(cheng)功的(de)(de)退(tui)(tui)火要求是(shi)(shi)(shi):由桿經(jing)拉制(zhi),但(dan)尚未鑄造(zao)(zao)組(zu)(zu)織(zhi)的(de)(de)線時(shi)(shi)的(de)(de)第一次退(tui)(tui)火,其(qi)退(tui)(tui)火功率(lv)(lv)應比同樣情況的(de)(de)低(di)氧銅(tong)(tong)高10——15%。經(jing)繼續拉制(zhi),在(zai)以(yi)后階段(duan)的(de)(de)退(tui)(tui)火功率(lv)(lv)應留有足夠的(de)(de)余量和對低(di)氧銅(tong)(tong)和無(wu)氧銅(tong)(tong)切(qie)實(shi)區別(bie)執(zhi)行不同的(de)(de)退(tui)(tui)火工藝,以(yi)保證在(zai)制(zhi)品和成(cheng)品導(dao)線的(de)(de)柔軟性。
三(san)、夾雜,氧含量波動(dong),表面氧化(hua)物和可能存在的(de)熱軋(ya)缺陷的(de)差別
無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)可(ke)拉性在所(suo)有(you)線(xian)徑里與低氧(yang)(yang)(yang)銅(tong)桿(gan)相比都是優越的(de),除上述組織原因(yin)外,無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)夾雜少(shao),含氧(yang)(yang)(yang)量(liang)穩定(ding),無(wu)熱軋(ya)可(ke)能(neng)產生(sheng)的(de)缺陷,桿(gan)表氧(yang)(yang)(yang)化(hua)物(wu)厚度可(ke)達≤15A。在連鑄連軋(ya)生(sheng)產過程中如(ru)果(guo)(guo)工(gong)藝不(bu)穩定(ding),對氧(yang)(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)(yang)量(liang)不(bu)穩定(ding)將直接(jie)影(ying)(ying)響桿(gan)的(de)性能(neng)。如(ru)果(guo)(guo)桿(gan)的(de)表面氧(yang)(yang)(yang)化(hua)物(wu)能(neng)在后工(gong)序的(de)連續清洗(xi)中得以彌(mi)補外,但(dan)比較麻煩的(de)是有(you)相當多的(de)氧(yang)(yang)(yang)化(hua)物(wu)存在于“皮下”,對拉線(xian)斷線(xian)影(ying)(ying)響更直接(jie),故(gu)而在拉制(zhi)微細線(xian),超微細線(xian)時,為了減少(shao)斷線(xian),有(you)時要對銅(tong)桿(gan)采取不(bu)得已的(de)辦法——剝皮,甚(shen)至二次剝皮的(de)原因(yin)所(suo)在,目的(de)要除去(qu)皮下氧(yang)(yang)(yang)化(hua)物(wu)。
四、低氧銅桿(gan)和無氧銅桿(gan)的韌性有差別
兩(liang)者(zhe)都可以(yi)拉到(dao)0.015mm,但在低溫(wen)超(chao)導線(xian)中的低溫(wen)級無氧銅,其細絲間的間距只有(you)0.001mm.
五(wu)、從制桿的(de)(de)原材料到(dao)制線的(de)(de)經濟性有差別。
制造無氧(yang)(yang)銅(tong)桿要求質量較高(gao)的(de)(de)(de)原材料。一般,拉(la)制直徑(jing)>1mm的(de)(de)(de)銅(tong)線時,低氧(yang)(yang)銅(tong)桿的(de)(de)(de)優點(dian)比(bi)較明顯(xian),而(er)無氧(yang)(yang)銅(tong)桿顯(xian)得更(geng)為優越(yue)的(de)(de)(de)是拉(la)制直徑(jing)<0.5mm的(de)(de)(de)銅(tong)線。
六、低氧(yang)銅桿的(de)制線(xian)工(gong)藝與無氧(yang)銅桿的(de)有所不同。
低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)不能照搬(ban)到無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)上來,至少(shao)兩者的(de)退(tui)火(huo)工(gong)(gong)藝(yi)是不同的(de)。因為線(xian)的(de)柔軟性深(shen)受材料成份和制(zhi)(zhi)桿(gan)(gan),制(zhi)(zhi)線(xian)和退(tui)火(huo)工(gong)(gong)藝(yi)的(de)影響,不能簡單(dan)地說低氧(yang)(yang)銅(tong)(tong)或無(wu)氧(yang)(yang)銅(tong)(tong)誰(shui)軟誰(shui)硬(ying)。
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