国产精品成人网站/两攻一受3p双龙h调教/玩弄人妻少妇500系列/人妻换人妻仑乱/国产成人一区二区三区别

中文

全國熱線:138-9810-2027

您(nin)的位置: 首頁>>嫩江新聞動態>>行業動態

推薦資訊

全國服務熱線

138-9810-2027

嫩江電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動(dong)態 閱(yue)讀:109386 發布時間(jian):2019-07-05

導讀(du):由于生(sheng)(sheng)產(chan)(chan)銅(tong)(tong)桿(gan)(gan)(gan)的(de)兩者的(de)工藝不同,所(suo)生(sheng)(sheng)產(chan)(chan)的(de)銅(tong)(tong)桿(gan)(gan)(gan)中的(de)含(han)氧量(liang)及外觀就不同。上引生(sheng)(sheng)產(chan)(chan)的(de)銅(tong)(tong)桿(gan)(gan)(gan),工藝得(de)當氧含(han)量(liang)在10ppm以下,叫無(wu)氧銅(tong)(tong)桿(gan)(gan)(gan);連鑄連鑄生(sheng)(sheng)產(chan)(chan)的(de)銅(tong)(tong)桿(gan)(gan)(gan) 是(shi)在保護條(tiao)件下的(de)熱軋,氧含(han)量(liang)在200-500ppm范圍內,但有(you)(you)時也高達700ppm以上,一般情況下,此種方法生(sheng)(sheng)產(chan)(chan)的(de)銅(tong)(tong)外表光亮,低氧銅(tong)(tong)桿(gan)(gan)(gan),有(you)(you)時也叫光桿(gan)(gan)(gan)。

銅(tong)(tong)(tong)桿(gan)是電(dian)纜行(xing)(xing)業(ye)的(de)(de)主要原(yuan)料(liao),生產(chan)的(de)(de)方式(shi)(shi)主要有兩種——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)法和(he)上(shang)引連(lian)鑄(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)低(di)氧銅(tong)(tong)(tong)桿(gan)的(de)(de)生產(chan)方法較(jiao)多(duo),其(qi)特點(dian)是金(jin)屬在豎爐中(zhong)(zhong)融(rong)化(hua)(hua)后(hou),銅(tong)(tong)(tong)液通(tong)過(guo)保(bao)溫爐、溜槽、中(zhong)(zhong)間包,從澆管進入封(feng)閉的(de)(de)模腔內,采(cai)用(yong)較(jiao)大的(de)(de)冷卻(que)強度進行(xing)(xing)冷卻(que),形成鑄(zhu)(zhu)坯(pi),然后(hou)進行(xing)(xing)多(duo)道次軋(ya)制(zhi),生產(chan)的(de)(de)低(di)氧銅(tong)(tong)(tong)桿(gan)為熱加(jia)(jia)工(gong)組(zu)織(zhi),原(yuan)來的(de)(de)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)已經破碎(sui),含(han)氧量(liang)一般為200~400ppm之間。無(wu)(wu)氧銅(tong)(tong)(tong)桿(gan)國(guo)內基本(ben)全部采(cai)用(yong)上(shang)引連(lian)鑄(zhu)(zhu)法生產(chan),金(jin)屬在感(gan)應電(dian)爐中(zhong)(zhong)融(rong)化(hua)(hua)后(hou)通(tong)過(guo)石墨模進行(xing)(xing)上(shang)引連(lian)續鑄(zhu)(zhu)造(zao),之后(hou)進行(xing)(xing)冷軋(ya)或(huo)冷加(jia)(jia)工(gong),生產(chan)的(de)(de)無(wu)(wu)氧銅(tong)(tong)(tong)桿(gan)為鑄(zhu)(zhu)造(zao)組(zu)織(zhi),含(han)氧量(liang)一般在20ppm以下(xia)。由于制(zhi)造(zao)工(gong)藝(yi)的(de)(de)不(bu)同,所以在組(zu)織(zhi)結構、氧含(han)量(liang)分布(bu)、雜質的(de)(de)形式(shi)(shi)及分布(bu)等(deng)諸多(duo)方面有較(jiao)大差別。

一、拉制性能

銅(tong)(tong)桿的(de)拉制性能跟很多因素(su)有關,如(ru)雜質的(de)含量、氧含量及分布、工(gong)藝控制等。下面(mian)分別從(cong)以上幾(ji)個方(fang)面(mian)對銅(tong)(tong)桿的(de)拉制性能進行(xing)分析。

1、熔(rong)化方式對S等雜(za)質的影響

連鑄(zhu)(zhu)連軋生(sheng)產銅(tong)(tong)(tong)桿主要(yao)是通(tong)過氣體(ti)的(de)燃(ran)燒使銅(tong)(tong)(tong)桿熔(rong)(rong)化,在(zai)燃(ran)燒的(de)過程中,通(tong)過氧(yang)化和揮發作用(yong),可一(yi)(yi)定程度減少部分雜質進入銅(tong)(tong)(tong)液(ye),因此連鑄(zhu)(zhu)連軋法(fa)對原料要(yao)求相對低(di)一(yi)(yi)些。上引連鑄(zhu)(zhu)生(sheng)產無氧(yang)銅(tong)(tong)(tong)桿,由于(yu)是用(yong)感應(ying)電(dian)爐熔(rong)(rong)化,電(dian)解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基本都(dou)熔(rong)(rong)入到(dao)銅(tong)(tong)(tong)液(ye)中。其中熔(rong)(rong)入的(de)S對無氧(yang)銅(tong)(tong)(tong)桿塑性影響極大,會增加拉絲斷線率。

2、鑄造過程中雜質的進入

在生產過(guo)程(cheng)(cheng)中(zhong),連鑄連軋(ya)工(gong)(gong)藝需(xu)通(tong)(tong)過(guo)保溫爐、溜槽、中(zhong)間包轉運(yun)銅(tong)液,相對容易造成(cheng)(cheng)耐火(huo)材(cai)料的剝(bo)落,在軋(ya)制過(guo)程(cheng)(cheng)中(zhong)需(xu)要通(tong)(tong)過(guo)軋(ya)輥,造成(cheng)(cheng)鐵(tie)質(zhi)的脫(tuo)落,會(hui)給(gei)(gei)銅(tong)桿造成(cheng)(cheng)外部(bu)夾雜。而(er)熱軋(ya)中(zhong)皮上和皮下氧(yang)化(hua)物的軋(ya)入,會(hui)給(gei)(gei)低氧(yang)桿的拉絲(si)造成(cheng)(cheng)不利的影響(xiang)。上引連鑄法生產工(gong)(gong)藝流(liu)程(cheng)(cheng)較短,銅(tong)液是通(tong)(tong)過(guo)聯體爐內(nei)潛流(liu)式完成(cheng)(cheng),對耐火(huo)材(cai)料的沖擊不大,結晶是通(tong)(tong)過(guo)石墨模內(nei)進(jin)行,所(suo)以過(guo)程(cheng)(cheng)中(zhong)可(ke)能產生的污染源較少,雜質(zhi)進(jin)入的機會(hui)較少。

O、S、P是與銅(tong)會生產(chan)化合物的(de)(de)元素。在熔態銅(tong)中,氧可以(yi)溶解(jie)(jie)一部分,但(dan)當銅(tong)冷凝時,氧幾乎不溶解(jie)(jie)于(yu)銅(tong)中。熔態時所(suo)溶解(jie)(jie)的(de)(de)氧,以(yi)銅(tong)=氧化亞銅(tong)共(gong)晶體析出,分布(bu)在晶粒晶界(jie)處(chu)。銅(tong)-氧化亞銅(tong)共(gong)晶體的(de)(de)出現,顯(xian)著降低了(le)銅(tong)的(de)(de)塑(su)性。

硫可以溶(rong)解(jie)在(zai)熔體的銅(tong)(tong)中,但在(zai)室(shi)溫(wen)下(xia),其溶(rong)解(jie)度幾乎降(jiang)低到零(ling),它以硫化(hua)亞銅(tong)(tong)的形式出現在(zai)晶(jing)粒晶(jing)界處,會顯著降(jiang)低銅(tong)(tong)的塑(su)性(xing)。

3、氧(yang)(yang)在低(di)氧(yang)(yang)銅(tong)桿和無氧(yang)(yang)銅(tong)桿中分布(bu)形式及(ji)其(qi)影響

氧(yang)(yang)(yang)(yang)含量(liang)對低氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)的(de)(de)拉線性能(neng)有著明顯的(de)(de)影響。當氧(yang)(yang)(yang)(yang)含量(liang)增加(jia)到最佳值時,銅(tong)桿(gan)的(de)(de)斷線率最低。這是因為氧(yang)(yang)(yang)(yang)在與大(da)部分(fen)雜質反(fan)應的(de)(de)過程中都(dou)起到了清除(chu)器的(de)(de)作(zuo)用。適度的(de)(de)氧(yang)(yang)(yang)(yang)還有利于去(qu)除(chu)銅(tong)液中的(de)(de)氫,生成水蒸氣(qi)溢出,減少氣(qi)孔(kong)的(de)(de)形(xing)成。最佳的(de)(de)氧(yang)(yang)(yang)(yang)含量(liang)為拉線工藝提供(gong)了最好(hao)的(de)(de)條件(jian)。

低氧(yang)(yang)銅桿(gan)氧(yang)(yang)化(hua)物(wu)的分布:在連續(xu)澆鑄中(zhong)凝固的最(zui)初(chu)階段,散(san)熱(re)速(su)率和(he)(he)均勻(yun)冷卻是決定銅桿(gan)氧(yang)(yang)化(hua)物(wu)分布的主要因(yin)素。不均勻(yun)冷卻會引起銅桿(gan)內部結構本質上(shang)的差(cha)異,但后續(xu)的熱(re)加工,柱狀(zhuang)晶通常(chang)會遭(zao)到破壞,使氧(yang)(yang)化(hua)亞(ya)銅顆(ke)粒(li)細微(wei)化(hua)和(he)(he)均勻(yun)分布。氧(yang)(yang)化(hua)物(wu)顆(ke)粒(li)聚(ju)集而(er)產生(sheng)的典(dian)型情況是中(zhong)心爆裂(lie)。除氧(yang)(yang)化(hua)物(wu)顆(ke)粒(li)分布的影響外(wai),具有較小氧(yang)(yang)化(hua)物(wu)顆(ke)粒(li)的銅桿(gan)顯示出較好的拉線特性,較大(da)的Cu2O顆(ke)粒(li)容易造成應力集中(zhong)點而(er)斷裂(lie)。

無氧銅(tong)(tong)含氧量超標,銅(tong)(tong)桿(gan)(gan)變(bian)脆(cui),延伸(shen)率(lv)下降(jiang),拉伸(shen)式樣(yang)端口顯暗紅色(se),結晶(jing)組織(zhi)(zhi)疏松。當氧含量超出8ppm時,工藝(yi)性能(neng)變(bian)差,表現為鑄造(zao)及拉伸(shen)過程中斷(duan)桿(gan)(gan)及斷(duan)線率(lv)極(ji)具增高(gao)。這是由于氧能(neng)與銅(tong)(tong)生成(cheng)氧化亞銅(tong)(tong)脆(cui)性相,形(xing)成(cheng)銅(tong)(tong)-氧化亞銅(tong)(tong)共晶(jing)體,以(yi)網(wang)狀組織(zhi)(zhi)分布在(zai)(zai)境界(jie)上(shang)。這種(zhong)脆(cui)性相硬度高(gao),在(zai)(zai)冷(leng)變(bian)形(xing)時將會與銅(tong)(tong)機體脫離,導(dao)致銅(tong)(tong)桿(gan)(gan)的機械性能(neng)下降(jiang),在(zai)(zai)后續加工中容易造(zao)成(cheng)斷(duan)裂(lie)現象。氧含量高(gao)還能(neng)導(dao)致無氧銅(tong)(tong)桿(gan)(gan)導(dao)電率(lv)下降(jiang)。因此(ci),必須(xu)嚴格(ge)控制上(shang)引連鑄工藝(yi)及產(chan)品質量。

4、氫的影響

在上(shang)引(yin)連鑄中,氧(yang)含量控制(zhi)較(jiao)低,氧(yang)化物(wu)的(de)(de)副(fu)作用唄**降(jiang)低,但氫的(de)(de)影響成為較(jiao)顯(xian)著的(de)(de)問題。吸氣后熔體中存(cun)在平衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)(qi)體及疏松(song)是(shi)(shi)在(zai)(zai)(zai)(zai)結晶(jing)(jing)(jing)的(de)(de)(de)(de)過程(cheng)中(zhong),氫從過飽和(he)的(de)(de)(de)(de)溶液(ye)(ye)中(zhong)析出(chu)并聚(ju)集而形成(cheng)(cheng)的(de)(de)(de)(de)。在(zai)(zai)(zai)(zai)結晶(jing)(jing)(jing)前(qian)析出(chu)的(de)(de)(de)(de)氫又可還(huan)原氧化亞銅(tong)而生成(cheng)(cheng)水氣(qi)(qi)(qi)(qi)泡(pao)。由于上(shang)引鑄(zhu)造的(de)(de)(de)(de)特點(dian)是(shi)(shi)銅(tong)液(ye)(ye)自上(shang)而下的(de)(de)(de)(de)結晶(jing)(jing)(jing),形成(cheng)(cheng)的(de)(de)(de)(de)液(ye)(ye)**形狀近(jin)似錐型。銅(tong)液(ye)(ye)結晶(jing)(jing)(jing)前(qian)析出(chu)的(de)(de)(de)(de)氣(qi)(qi)(qi)(qi)體在(zai)(zai)(zai)(zai)上(shang)浮過程(cheng)中(zhong)被堵在(zai)(zai)(zai)(zai)凝固組織(zhi)內,結晶(jing)(jing)(jing)時在(zai)(zai)(zai)(zai)鑄(zhu)桿內形成(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔。上(shang)引的(de)(de)(de)(de)含氣(qi)(qi)(qi)(qi)量少時,析出(chu)的(de)(de)(de)(de)氫存在(zai)(zai)(zai)(zai)于晶(jing)(jing)(jing)界處,形成(cheng)(cheng)疏松(song);含氣(qi)(qi)(qi)(qi)量多時,則(ze)聚(ju)集成(cheng)(cheng)氣(qi)(qi)(qi)(qi)孔,因(yin)此(ci),氣(qi)(qi)(qi)(qi)孔和(he)疏松(song)是(shi)(shi)氫氣(qi)(qi)(qi)(qi)和(he)水蒸氣(qi)(qi)(qi)(qi)兩者(zhe)形成(cheng)(cheng)的(de)(de)(de)(de)。

氫來(lai)源于上引生產過(guo)程中的各個工藝環(huan)節,如(ru)原料電解(jie)銅的“銅綠(lv)”、輔料木炭**、氣候環(huan)境**、石墨結晶器未干燥(zao)等。因此,熔(rong)化爐中的銅液(ye)表面應覆蓋(gai)經(jing)烘烤的木炭,電解(jie)銅應盡量去除“銅綠(lv)”、“銅豆(dou)”“耳朵”,對提高(gao)無氧(yang)銅桿質量非常(chang)重(zhong)要。

在連鑄連軋工藝(yi)中,往往采(cai)用(yong)適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅液在(zai)鑄造過程中是自下而(er)上(shang)結晶(jing),銅液中的(de)氧和氫所產(chan)生的(de)水(shui)蒸(zheng)氣很容易上(shang)浮跑出,銅液中的(de)氫大(da)部分(fen)能(neng)被有效去(qu)除(chu),因(yin)而(er)對銅桿的(de)影響較小(xiao)。

二、表面質量

在生產(chan)電磁線等產(chan)品的(de)過程(cheng)中,對銅(tong)(tong)(tong)桿(gan)的(de)表(biao)(biao)面(mian)質(zhi)量也需提出要求。需要拉(la)制后(hou)的(de)銅(tong)(tong)(tong)絲表(biao)(biao)面(mian)無毛刺、銅(tong)(tong)(tong)粉少、無油污。并通(tong)過扭轉試驗(yan)測量表(biao)(biao)面(mian)銅(tong)(tong)(tong)粉的(de)質(zhi)量和(he)扭轉后(hou)觀察銅(tong)(tong)(tong)桿(gan)的(de)復原情況(kuang)來判(pan)定其好壞。

在連(lian)鑄連(lian)軋(ya)過(guo)程(cheng)(cheng)中,從鑄造(zao)到軋(ya)制前,溫度高(gao),完全暴露(lu)于(yu)空氣中,使(shi)鑄坯(pi)表(biao)面(mian)(mian)形成較(jiao)厚的氧(yang)(yang)化(hua)(hua)(hua)層,在軋(ya)制過(guo)程(cheng)(cheng)中,隨著軋(ya)輥的轉動,氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆粒(li)軋(ya)入(ru)銅(tong)(tong)線表(biao)面(mian)(mian)。由于(yu)氧(yang)(yang)化(hua)(hua)(hua)亞銅(tong)(tong)是高(gao)熔點(dian)脆性化(hua)(hua)(hua)合物(wu),對于(yu)軋(ya)入(ru)較(jiao)深的氧(yang)(yang)化(hua)(hua)(hua)亞銅(tong)(tong),當成條狀的聚(ju)集物(wu)遇模具拉伸時,就會是銅(tong)(tong)桿外表(biao)面(mian)(mian)產生毛刺,給后(hou)續(xu)的涂漆造(zao)成麻煩。

而上(shang)引連鑄工(gong)藝制造(zao)的無氧(yang)銅桿,由(you)于鑄造(zao)和冷卻完全(quan)與氧(yang)隔絕,后續亦(yi)無熱軋過程,銅桿表面無軋入表面的氧(yang)化(hua)物,質量較(jiao)好,拉(la)制后銅粉少,上(shang)述問(wen)題(ti)較(jiao)少存(cun)在。

無(wu)氧銅(tong)桿也(ye)分進口(kou)設(she)(she)(she)備(bei)做的(de)和(he)國(guo)產設(she)(she)(she)備(bei)做的(de),但目前(qian)進口(kou)產品已無(wu)明顯優勢,銅(tong)桿產品出來后區別不是很大(da),只要銅(tong)板選的(de)好,生產控(kong)制比較穩定,國(guo)產設(she)(she)(she)備(bei)也(ye)能產出可拉伸0.05的(de)銅(tong)桿.進口(kou)設(she)(she)(she)備(bei)一般是芬蘭奧托(tuo)昆(kun)普的(de)設(she)(she)(she)備(bei),國(guo)產設(she)(she)(she)備(bei)最好的(de)應該(gai)是上海的(de)海軍廠的(de)了(le),生產時間最長,軍工企業(ye),質量可靠。

低氧(yang)銅(tong)桿(gan)進口設(she)(she)備國(guo)際主(zhu)要有兩種,一種是美(mei)國(guo)南(nan)(nan)線(xian)設(she)(she)備,英(ying)文是SOUTHWIRE,國(guo)內廠(chang)家是南(nan)(nan)京(jing)華新,江(jiang)西銅(tong)業,另一種是德國(guo)CONTIROD設(she)(she)備,國(guo)內廠(chang)家是常州(zhou)金(jin)源,天津大無縫。

無(wu)(wu)(wu)氧(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)桿(gan)從含氧(yang)(yang)(yang)量上容易區別,無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)是(shi)含氧(yang)(yang)(yang)量在10-20個(ge)PPM以(yi)下(xia),但目(mu)前有(you)的(de)(de)(de)廠家只能做(zuo)到(dao)50個(ge)PPM以(yi)下(xia).低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)在 200-400個(ge)PPM,好(hao)的(de)(de)(de)桿(gan)子(zi)一般(ban)含氧(yang)(yang)(yang)量控制在250個(ge)PPM左右,無(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)一般(ban)采(cai)取(qu)的(de)(de)(de)是(shi)上引(yin)法,低(di)氧(yang)(yang)(yang)桿(gan)是(shi)連鑄連軋,兩種產品相(xiang)對(dui)而言低(di)氧(yang)(yang)(yang)桿(gan)對(dui)漆包線性 能更適應些(xie),如柔(rou)軟性,回(hui)彈角,繞線性能.但低(di)氧(yang)(yang)(yang)桿(gan)對(dui)拉絲條(tiao)(tiao)件相(xiang)對(dui)要(yao)苛刻些(xie),同樣(yang)拉伸0.2的(de)(de)(de)細(xi)絲,如果伸線條(tiao)(tiao)件不(bu)好(hao),普(pu)(pu)通(tong)的(de)(de)(de)無(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)可拉而好(hao)的(de)(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)就斷 線,但如果放在好(hao)的(de)(de)(de)伸線條(tiao)(tiao)件,同樣(yang)的(de)(de)(de)桿(gan)子(zi),低(di)氧(yang)(yang)(yang)桿(gan)說(shuo)不(bu)定就能拉到(dao)雙零(ling)五,而普(pu)(pu)通(tong)無(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)最多只能拉伸到(dao)0.1而已,當然做(zuo)的(de)(de)(de)最細(xi)的(de)(de)(de)如雙零(ling)二卻(que)非得依靠進(jin)口的(de)(de)(de) 無(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)了(le).目(mu)前有(you)企(qi)業嘗試用剝皮的(de)(de)(de)方式來處理(li)低(di)氧(yang)(yang)(yang)桿(gan)來伸0.03線.但有(you)關(guan)這方面(mian)的(de)(de)(de)內容我還(huan)不(bu)是(shi)很(hen)清楚。

音(yin)響線一般(ban)反而喜歡用(yong)無氧(yang)桿(gan),這和無氧(yang)桿(gan)是單(dan)晶銅,低氧(yang)桿(gan)是多晶銅有關。

氧(yang)銅桿和無氧(yang)銅桿由于制造方法的不(bu)同,致使存在差(cha)別,具有各自的特點(dian)。

一、關(guan)于氧的吸入和脫(tuo)去(qu)以(yi)及它(ta)的存在狀(zhuang)態

生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)含(han)氧(yang)(yang)量一般在10—50ppm,在常(chang)(chang)(chang)溫下(xia)(xia)氧(yang)(yang)在銅(tong)(tong)(tong)(tong)中的(de)(de)(de)固(gu)溶(rong)度約2ppm。低氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)含(han)氧(yang)(yang)量一般在200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)(de)進入是在銅(tong)(tong)(tong)(tong)的(de)(de)(de)液態(tai)下(xia)(xia)吸入的(de)(de)(de),而(er)上(shang)引法無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)相反,氧(yang)(yang)在液態(tai)銅(tong)(tong)(tong)(tong)下(xia)(xia)保(bao)持相當時間后,被還原而(er)脫去,通常(chang)(chang)(chang)這(zhe)種(zhong)桿(gan)(gan)的(de)(de)(de)含(han)氧(yang)(yang)量都在10—50ppm以(yi)(yi)下(xia)(xia),最低可(ke)達1-2ppm,從(cong)組(zu)織上(shang)看(kan),低氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang),以(yi)(yi)氧(yang)(yang)化銅(tong)(tong)(tong)(tong)狀(zhuang)態(tai),存在于晶粒邊界(jie)附(fu)近,這(zhe)對低氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)而(er)言可(ke)以(yi)(yi)說是常(chang)(chang)(chang)見的(de)(de)(de)但對無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)很(hen)少見。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形式在晶界(jie)出現對材(cai)料(liao)的(de)(de)(de)韌性(xing)產生負面影響(xiang)。而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)很(hen)低,所(suo)以(yi)(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)組(zu)織是均勻的(de)(de)(de)單相組(zu)織對韌性(xing)有(you)利。在無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)多孔性(xing)是不常(chang)(chang)(chang)見的(de)(de)(de),而(er)在低氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中則(ze)是常(chang)(chang)(chang)見的(de)(de)(de)一種(zhong)缺陷。

二、熱軋組(zu)織和(he)鑄(zhu)造組(zu)織的區(qu)別

低氧(yang)(yang)(yang)銅(tong)桿(gan)由于經(jing)過熱軋,所以(yi)其組(zu)(zu)(zu)(zu)織(zhi)屬熱加工(gong)組(zu)(zu)(zu)(zu)織(zhi),原來的(de)(de)(de)鑄(zhu)(zhu)造(zao)(zao)組(zu)(zu)(zu)(zu)織(zhi)已經(jing)破碎,在8mm的(de)(de)(de)桿(gan)時(shi)已有再(zai)結晶(jing)的(de)(de)(de)形式(shi)出現,而(er)無氧(yang)(yang)(yang)銅(tong)桿(gan)屬鑄(zhu)(zhu)造(zao)(zao)組(zu)(zu)(zu)(zu)織(zhi),晶(jing)粒粗(cu)大,這是為(wei)什么,無氧(yang)(yang)(yang)銅(tong)的(de)(de)(de)再(zai)結晶(jing)溫度較(jiao)(jiao)高(gao),需(xu)要較(jiao)(jiao)高(gao)退(tui)火溫度的(de)(de)(de)固有原因。這是因為(wei),再(zai)結晶(jing)發生在晶(jing)粒邊(bian)界(jie)附近,無氧(yang)(yang)(yang)銅(tong)桿(gan)組(zu)(zu)(zu)(zu)織(zhi)晶(jing)粒粗(cu)大,晶(jing)粒尺(chi)寸甚至能達(da)幾個毫(hao)米,因而(er)晶(jing)粒邊(bian)界(jie)少(shao),即使(shi)通過拉(la)制變形,但晶(jing)粒邊(bian)界(jie)相對低氧(yang)(yang)(yang)銅(tong)桿(gan)還是較(jiao)(jiao)少(shao),所以(yi)需(xu)要較(jiao)(jiao)高(gao)的(de)(de)(de)退(tui)火功(gong)率。對無氧(yang)(yang)(yang)銅(tong)成功(gong)的(de)(de)(de)退(tui)火要求是:由桿(gan)經(jing)拉(la)制,但尚未鑄(zhu)(zhu)造(zao)(zao)組(zu)(zu)(zu)(zu)織(zhi)的(de)(de)(de)線時(shi)的(de)(de)(de)第一次退(tui)火,其退(tui)火功(gong)率應比同樣情況的(de)(de)(de)低氧(yang)(yang)(yang)銅(tong)高(gao)10——15%。經(jing)繼(ji)續拉(la)制,在以(yi)后階段的(de)(de)(de)退(tui)火功(gong)率應留有足(zu)夠(gou)的(de)(de)(de)余量和對低氧(yang)(yang)(yang)銅(tong)和無氧(yang)(yang)(yang)銅(tong)切實區別(bie)執行不同的(de)(de)(de)退(tui)火工(gong)藝,以(yi)保證在制品和成品導(dao)線的(de)(de)(de)柔軟(ruan)性。

三、夾雜,氧(yang)含(han)量波(bo)動,表(biao)面氧(yang)化物和(he)可能存(cun)在的熱軋缺(que)陷(xian)的差(cha)別

無(wu)氧(yang)(yang)銅桿(gan)的可拉性在(zai)(zai)所(suo)有(you)線(xian)(xian)徑里與低氧(yang)(yang)銅桿(gan)相(xiang)比都(dou)是優越的,除上述組織原(yuan)因(yin)外,無(wu)氧(yang)(yang)銅桿(gan)夾雜少(shao),含(han)氧(yang)(yang)量穩定(ding),無(wu)熱(re)軋可能產(chan)生(sheng)的缺陷,桿(gan)表(biao)氧(yang)(yang)化物(wu)(wu)厚度可達≤15A。在(zai)(zai)連鑄連軋生(sheng)產(chan)過程中如果工(gong)藝(yi)不(bu)穩定(ding),對(dui)氧(yang)(yang)監控不(bu)嚴,含(han)氧(yang)(yang)量不(bu)穩定(ding)將直(zhi)接影響桿(gan)的性能。如果桿(gan)的表(biao)面氧(yang)(yang)化物(wu)(wu)能在(zai)(zai)后工(gong)序的連續清洗中得(de)以(yi)彌補(bu)外,但比較(jiao)麻煩的是有(you)相(xiang)當多的氧(yang)(yang)化物(wu)(wu)存(cun)在(zai)(zai)于“皮下”,對(dui)拉線(xian)(xian)斷線(xian)(xian)影響更直(zhi)接,故而(er)在(zai)(zai)拉制微細線(xian)(xian),超微細線(xian)(xian)時,為(wei)了(le)減少(shao)斷線(xian)(xian),有(you)時要對(dui)銅桿(gan)采取不(bu)得(de)已的辦法——剝皮,甚至二次(ci)剝皮的原(yuan)因(yin)所(suo)在(zai)(zai),目的要除去皮下氧(yang)(yang)化物(wu)(wu)。

四、低氧(yang)銅桿和無(wu)氧(yang)銅桿的韌性有差別

兩者都可(ke)以拉到0.015mm,但在低溫超導線中的低溫級無氧(yang)銅,其細絲間的間距只有0.001mm.

五、從(cong)制桿的(de)原材料到制線的(de)經濟性有(you)差別。

制造無氧(yang)銅(tong)桿(gan)要求質量較高(gao)的原材料。一(yi)般,拉制直徑>1mm的銅(tong)線時,低氧(yang)銅(tong)桿(gan)的優點比較明(ming)顯(xian),而無氧(yang)銅(tong)桿(gan)顯(xian)得更為優越的是拉制直徑<0.5mm的銅(tong)線。

六、低氧(yang)銅桿的制線工藝與(yu)無(wu)氧(yang)銅桿的有所不同(tong)。

低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)制(zhi)(zhi)線(xian)(xian)(xian)工藝不能照搬到無(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)制(zhi)(zhi)線(xian)(xian)(xian)工藝上來,至少兩者的(de)退火工藝是不同的(de)。因(yin)為(wei)線(xian)(xian)(xian)的(de)柔軟(ruan)性深(shen)受材(cai)料(liao)成份(fen)和(he)制(zhi)(zhi)桿(gan),制(zhi)(zhi)線(xian)(xian)(xian)和(he)退火工藝的(de)影(ying)響(xiang),不能簡(jian)單地說低(di)氧(yang)(yang)(yang)銅(tong)或無(wu)氧(yang)(yang)(yang)銅(tong)誰軟(ruan)誰硬。