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寧城電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱讀:109413 發布時(shi)間:2019-07-05

導讀:由(you)于(yu)生產銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)兩者(zhe)的(de)(de)工(gong)藝不同(tong),所生產的(de)(de)銅(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)含氧(yang)量及外觀就不同(tong)。上引生產的(de)(de)銅(tong)(tong)(tong)桿(gan)(gan),工(gong)藝得當氧(yang)含量在10ppm以下(xia),叫(jiao)無氧(yang)銅(tong)(tong)(tong)桿(gan)(gan);連(lian)鑄連(lian)鑄生產的(de)(de)銅(tong)(tong)(tong)桿(gan)(gan) 是(shi)在保護條件下(xia)的(de)(de)熱軋,氧(yang)含量在200-500ppm范圍內(nei),但有(you)時也高達700ppm以上,一般情況下(xia),此(ci)種(zhong)方法生產的(de)(de)銅(tong)(tong)(tong)外表光(guang)亮,低氧(yang)銅(tong)(tong)(tong)桿(gan)(gan),有(you)時也叫(jiao)光(guang)桿(gan)(gan)。

銅(tong)桿(gan)是電(dian)纜(lan)行(xing)業的(de)(de)主要(yao)原(yuan)料,生(sheng)產(chan)的(de)(de)方式主要(yao)有(you)兩種——連(lian)鑄(zhu)連(lian)軋法(fa)(fa)和(he)上(shang)(shang)引(yin)連(lian)鑄(zhu)法(fa)(fa)。連(lian)鑄(zhu)連(lian)軋低氧(yang)(yang)銅(tong)桿(gan)的(de)(de)生(sheng)產(chan)方法(fa)(fa)較(jiao)多(duo),其特點是金屬在(zai)(zai)豎爐(lu)中(zhong)融(rong)化后(hou),銅(tong)液通過保溫爐(lu)、溜槽、中(zhong)間(jian)(jian)包,從澆管進(jin)(jin)入封閉(bi)的(de)(de)模腔(qiang)內,采用較(jiao)大的(de)(de)冷(leng)卻(que)強度(du)進(jin)(jin)行(xing)冷(leng)卻(que),形(xing)成(cheng)鑄(zhu)坯,然后(hou)進(jin)(jin)行(xing)多(duo)道次軋制(zhi),生(sheng)產(chan)的(de)(de)低氧(yang)(yang)銅(tong)桿(gan)為(wei)(wei)熱(re)加工(gong)(gong)組織,原(yuan)來的(de)(de)鑄(zhu)造(zao)組織已(yi)經破碎,含(han)(han)氧(yang)(yang)量一般為(wei)(wei)200~400ppm之間(jian)(jian)。無氧(yang)(yang)銅(tong)桿(gan)國(guo)內基本全部采用上(shang)(shang)引(yin)連(lian)鑄(zhu)法(fa)(fa)生(sheng)產(chan),金屬在(zai)(zai)感應電(dian)爐(lu)中(zhong)融(rong)化后(hou)通過石墨模進(jin)(jin)行(xing)上(shang)(shang)引(yin)連(lian)續(xu)鑄(zhu)造(zao),之后(hou)進(jin)(jin)行(xing)冷(leng)軋或冷(leng)加工(gong)(gong),生(sheng)產(chan)的(de)(de)無氧(yang)(yang)銅(tong)桿(gan)為(wei)(wei)鑄(zhu)造(zao)組織,含(han)(han)氧(yang)(yang)量一般在(zai)(zai)20ppm以下。由于(yu)制(zhi)造(zao)工(gong)(gong)藝(yi)的(de)(de)不同,所以在(zai)(zai)組織結構(gou)、氧(yang)(yang)含(han)(han)量分布、雜質的(de)(de)形(xing)式及分布等諸多(duo)方面有(you)較(jiao)大差(cha)別。

一、拉制性能

銅(tong)桿(gan)的拉制性能跟(gen)很多因素有(you)關,如雜質的含(han)量、氧含(han)量及分布(bu)、工藝(yi)控制等(deng)。下面分別(bie)從以上幾個方面對銅(tong)桿(gan)的拉制性能進(jin)行分析。

1、熔化方式對S等雜質的影響

連(lian)(lian)(lian)(lian)鑄連(lian)(lian)(lian)(lian)軋生(sheng)產銅(tong)(tong)(tong)桿(gan)主要是(shi)(shi)通過氣體的(de)燃燒使銅(tong)(tong)(tong)桿(gan)熔(rong)化(hua),在燃燒的(de)過程中(zhong),通過氧(yang)化(hua)和揮(hui)發作用,可(ke)一(yi)定程度減少部分雜質進入銅(tong)(tong)(tong)液,因此連(lian)(lian)(lian)(lian)鑄連(lian)(lian)(lian)(lian)軋法對(dui)原料要求相對(dui)低一(yi)些。上引連(lian)(lian)(lian)(lian)鑄生(sheng)產無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan),由于是(shi)(shi)用感應電爐(lu)熔(rong)化(hua),電解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基本都熔(rong)入到銅(tong)(tong)(tong)液中(zhong)。其中(zhong)熔(rong)入的(de)S對(dui)無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)塑性影響(xiang)極(ji)大,會增加(jia)拉絲斷線率。

2、鑄造(zao)過程(cheng)中(zhong)雜質(zhi)的進入

在生(sheng)產過程(cheng)中,連鑄連軋工(gong)藝需通(tong)過保溫爐、溜槽、中間包轉運銅(tong)(tong)液,相(xiang)對容易造(zao)成(cheng)耐(nai)火(huo)材料(liao)(liao)的(de)(de)(de)剝落,在軋制(zhi)過程(cheng)中需要通(tong)過軋輥,造(zao)成(cheng)鐵質(zhi)的(de)(de)(de)脫落,會給銅(tong)(tong)桿造(zao)成(cheng)外部夾雜。而熱軋中皮上和(he)皮下氧化物的(de)(de)(de)軋入(ru),會給低氧桿的(de)(de)(de)拉絲造(zao)成(cheng)不利的(de)(de)(de)影響。上引連鑄法生(sheng)產工(gong)藝流程(cheng)較短(duan),銅(tong)(tong)液是通(tong)過聯體爐內潛流式完成(cheng),對耐(nai)火(huo)材料(liao)(liao)的(de)(de)(de)沖(chong)擊不大,結晶是通(tong)過石墨(mo)模內進(jin)行,所以過程(cheng)中可能產生(sheng)的(de)(de)(de)污染源較少(shao),雜質(zhi)進(jin)入(ru)的(de)(de)(de)機會較少(shao)。

O、S、P是與(yu)銅(tong)(tong)(tong)會生產化(hua)合物的元素。在(zai)熔(rong)態銅(tong)(tong)(tong)中,氧(yang)(yang)可以溶(rong)解(jie)(jie)一部分(fen),但當銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)幾(ji)乎(hu)不溶(rong)解(jie)(jie)于銅(tong)(tong)(tong)中。熔(rong)態時所(suo)溶(rong)解(jie)(jie)的氧(yang)(yang),以銅(tong)(tong)(tong)=氧(yang)(yang)化(hua)亞(ya)銅(tong)(tong)(tong)共晶體析出,分(fen)布在(zai)晶粒(li)晶界處。銅(tong)(tong)(tong)-氧(yang)(yang)化(hua)亞(ya)銅(tong)(tong)(tong)共晶體的出現,顯著降低了(le)銅(tong)(tong)(tong)的塑性。

硫(liu)可以(yi)溶解(jie)在熔體(ti)的(de)銅中,但在室溫下(xia),其溶解(jie)度幾乎降(jiang)低(di)到零,它以(yi)硫(liu)化亞銅的(de)形(xing)式出現在晶粒晶界處,會顯著(zhu)降(jiang)低(di)銅的(de)塑性。

3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中(zhong)分布(bu)形(xing)式及其影響

氧(yang)(yang)含(han)量對低(di)氧(yang)(yang)銅(tong)桿的拉線(xian)性能有著明顯的影響。當氧(yang)(yang)含(han)量增加到(dao)最(zui)佳值(zhi)時,銅(tong)桿的斷線(xian)率(lv)最(zui)低(di)。這是(shi)因為氧(yang)(yang)在(zai)與大部分雜質反應的過程中(zhong)都起到(dao)了清除器的作用。適度的氧(yang)(yang)還(huan)有利(li)于(yu)去(qu)除銅(tong)液(ye)中(zhong)的氫(qing),生(sheng)成水(shui)蒸氣溢出,減少氣孔的形成。最(zui)佳的氧(yang)(yang)含(han)量為拉線(xian)工藝提供了最(zui)好的條件。

低氧(yang)(yang)(yang)(yang)銅桿氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)(hua)物的(de)(de)(de)分(fen)(fen)布:在連續澆鑄中凝(ning)固的(de)(de)(de)最初階(jie)段,散熱速率和均勻冷卻是(shi)決(jue)定(ding)銅桿氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)(hua)物分(fen)(fen)布的(de)(de)(de)主(zhu)要因素(su)。不均勻冷卻會引起銅桿內(nei)部(bu)結構本質(zhi)上的(de)(de)(de)差異(yi),但后續的(de)(de)(de)熱加工,柱狀晶通(tong)常會遭到破壞,使氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)(hua)亞銅顆(ke)(ke)粒(li)(li)(li)細(xi)微(wei)化(hua)(hua)(hua)(hua)(hua)和均勻分(fen)(fen)布。氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)(hua)物顆(ke)(ke)粒(li)(li)(li)聚集而產生(sheng)的(de)(de)(de)典型(xing)情況是(shi)中心(xin)爆裂(lie)。除氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)(hua)物顆(ke)(ke)粒(li)(li)(li)分(fen)(fen)布的(de)(de)(de)影響外,具(ju)有較(jiao)小(xiao)氧(yang)(yang)(yang)(yang)化(hua)(hua)(hua)(hua)(hua)物顆(ke)(ke)粒(li)(li)(li)的(de)(de)(de)銅桿顯示(shi)出較(jiao)好的(de)(de)(de)拉線特性(xing),較(jiao)大的(de)(de)(de)Cu2O顆(ke)(ke)粒(li)(li)(li)容易造(zao)成應力(li)集中點而斷裂(lie)。

無氧(yang)(yang)銅(tong)(tong)含(han)氧(yang)(yang)量(liang)(liang)(liang)超標,銅(tong)(tong)桿(gan)變(bian)脆,延(yan)伸(shen)率(lv)下降(jiang),拉伸(shen)式樣端口(kou)顯暗(an)紅色,結晶組(zu)織疏松。當氧(yang)(yang)含(han)量(liang)(liang)(liang)超出8ppm時,工(gong)藝性(xing)能(neng)變(bian)差,表現(xian)(xian)為鑄造及拉伸(shen)過程中斷(duan)桿(gan)及斷(duan)線率(lv)極具(ju)增高。這(zhe)(zhe)是由于氧(yang)(yang)能(neng)與銅(tong)(tong)生成氧(yang)(yang)化(hua)亞銅(tong)(tong)脆性(xing)相,形成銅(tong)(tong)-氧(yang)(yang)化(hua)亞銅(tong)(tong)共晶體,以(yi)網狀組(zu)織分布在(zai)境界上(shang)。這(zhe)(zhe)種脆性(xing)相硬(ying)度高,在(zai)冷變(bian)形時將會與銅(tong)(tong)機體脫離,導(dao)致銅(tong)(tong)桿(gan)的機械性(xing)能(neng)下降(jiang),在(zai)后續加(jia)工(gong)中容易造成斷(duan)裂現(xian)(xian)象。氧(yang)(yang)含(han)量(liang)(liang)(liang)高還能(neng)導(dao)致無氧(yang)(yang)銅(tong)(tong)桿(gan)導(dao)電率(lv)下降(jiang)。因此,必須嚴格(ge)控制上(shang)引連鑄工(gong)藝及產(chan)品質量(liang)(liang)(liang)。

4、氫的影響

在上(shang)引連(lian)鑄中(zhong)(zhong),氧含量控制(zhi)較低,氧化物的副作用唄**降低,但氫的影響成為(wei)較顯著的問題。吸氣后(hou)熔體中(zhong)(zhong)存(cun)在平衡反應:H2O(g)=[O]+2[H];

氣(qi)體(ti)及疏松是在(zai)(zai)(zai)結晶(jing)(jing)的(de)(de)過(guo)程(cheng)中,氫(qing)從過(guo)飽和的(de)(de)溶液中析(xi)(xi)出(chu)并聚集(ji)(ji)而(er)(er)(er)形(xing)成(cheng)(cheng)(cheng)的(de)(de)。在(zai)(zai)(zai)結晶(jing)(jing)前析(xi)(xi)出(chu)的(de)(de)氫(qing)又可還原氧化亞銅而(er)(er)(er)生成(cheng)(cheng)(cheng)水(shui)氣(qi)泡。由于上引(yin)鑄(zhu)造的(de)(de)特點是銅液自上而(er)(er)(er)下的(de)(de)結晶(jing)(jing),形(xing)成(cheng)(cheng)(cheng)的(de)(de)液**形(xing)狀近(jin)似錐(zhui)型。銅液結晶(jing)(jing)前析(xi)(xi)出(chu)的(de)(de)氣(qi)體(ti)在(zai)(zai)(zai)上浮過(guo)程(cheng)中被堵(du)在(zai)(zai)(zai)凝(ning)固(gu)組織(zhi)內,結晶(jing)(jing)時在(zai)(zai)(zai)鑄(zhu)桿內形(xing)成(cheng)(cheng)(cheng)氣(qi)孔(kong)。上引(yin)的(de)(de)含氣(qi)量(liang)少時,析(xi)(xi)出(chu)的(de)(de)氫(qing)存在(zai)(zai)(zai)于晶(jing)(jing)界(jie)處,形(xing)成(cheng)(cheng)(cheng)疏松;含氣(qi)量(liang)多(duo)時,則聚集(ji)(ji)成(cheng)(cheng)(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和疏松是氫(qing)氣(qi)和水(shui)蒸氣(qi)兩者(zhe)形(xing)成(cheng)(cheng)(cheng)的(de)(de)。

氫(qing)來(lai)源于上引生(sheng)產(chan)過(guo)程中的(de)各個工藝環(huan)節,如原料(liao)電解銅(tong)(tong)的(de)“銅(tong)(tong)綠(lv)”、輔料(liao)木炭**、氣候環(huan)境**、石墨結晶(jing)器未干燥(zao)等。因(yin)此,熔化爐中的(de)銅(tong)(tong)液表面應覆蓋(gai)經烘烤的(de)木炭,電解銅(tong)(tong)應盡量去除“銅(tong)(tong)綠(lv)”、“銅(tong)(tong)豆”“耳朵”,對提高無(wu)氧銅(tong)(tong)桿質(zhi)量非常重要。

在(zai)連鑄連軋工藝中(zhong),往往采用適度控(kong)(kong)制(zhi)氧(yang)含量來控(kong)(kong)制(zhi)氫。Cu2O+ H2= 2Cu+ H2O

由(you)于銅(tong)(tong)液(ye)(ye)在鑄造過程中是自下而上結(jie)晶,銅(tong)(tong)液(ye)(ye)中的(de)(de)氧和氫(qing)所(suo)產生的(de)(de)水蒸氣很(hen)容易上浮跑出,銅(tong)(tong)液(ye)(ye)中的(de)(de)氫(qing)大部分(fen)能(neng)被(bei)有效(xiao)去除(chu),因而對銅(tong)(tong)桿的(de)(de)影(ying)響較小。

二、表面質量

在生產電磁線等(deng)產品的(de)過(guo)程(cheng)中(zhong),對銅(tong)桿(gan)的(de)表(biao)面(mian)質(zhi)量(liang)(liang)也需(xu)提出要求(qiu)。需(xu)要拉制后的(de)銅(tong)絲表(biao)面(mian)無(wu)毛刺、銅(tong)粉少(shao)、無(wu)油污。并通過(guo)扭(niu)轉試驗測量(liang)(liang)表(biao)面(mian)銅(tong)粉的(de)質(zhi)量(liang)(liang)和扭(niu)轉后觀察銅(tong)桿(gan)的(de)復(fu)原情況來(lai)判定其(qi)好壞。

在(zai)連鑄連軋(ya)(ya)(ya)過(guo)程中(zhong)(zhong),從鑄造到軋(ya)(ya)(ya)制前,溫度高(gao)(gao),完全(quan)暴露于(yu)空氣中(zhong)(zhong),使(shi)鑄坯表(biao)面形成(cheng)較厚(hou)的(de)氧(yang)化(hua)層,在(zai)軋(ya)(ya)(ya)制過(guo)程中(zhong)(zhong),隨著軋(ya)(ya)(ya)輥的(de)轉動,氧(yang)化(hua)物(wu)顆粒軋(ya)(ya)(ya)入(ru)銅線表(biao)面。由(you)于(yu)氧(yang)化(hua)亞(ya)(ya)銅是高(gao)(gao)熔點脆性化(hua)合物(wu),對于(yu)軋(ya)(ya)(ya)入(ru)較深的(de)氧(yang)化(hua)亞(ya)(ya)銅,當成(cheng)條狀的(de)聚(ju)集(ji)物(wu)遇模具(ju)拉伸時(shi),就會是銅桿外表(biao)面產生毛刺,給(gei)后續的(de)涂漆造成(cheng)麻煩。

而上引(yin)連鑄工藝制造的無氧(yang)銅(tong)桿(gan)(gan),由(you)于鑄造和(he)冷卻完全與氧(yang)隔絕,后續亦無熱軋(ya)過程,銅(tong)桿(gan)(gan)表面無軋(ya)入表面的氧(yang)化(hua)物,質量較(jiao)好(hao),拉制后銅(tong)粉少,上述問題較(jiao)少存(cun)在。

無氧銅桿也分(fen)進口(kou)設備(bei)(bei)(bei)做(zuo)(zuo)的(de)和(he)國(guo)產(chan)設備(bei)(bei)(bei)做(zuo)(zuo)的(de),但目前進口(kou)產(chan)品(pin)已(yi)無明顯優(you)勢,銅桿產(chan)品(pin)出來后區(qu)別(bie)不是很大(da),只要銅板選的(de)好,生產(chan)控制比(bi)較穩定(ding),國(guo)產(chan)設備(bei)(bei)(bei)也能產(chan)出可(ke)拉伸(shen)0.05的(de)銅桿.進口(kou)設備(bei)(bei)(bei)一般是芬蘭(lan)奧(ao)托昆(kun)普的(de)設備(bei)(bei)(bei),國(guo)產(chan)設備(bei)(bei)(bei)最好的(de)應該是上海的(de)海軍廠的(de)了,生產(chan)時間最長,軍工企業,質量可(ke)靠。

低氧銅桿(gan)進口設備國(guo)際主要有兩種,一種是(shi)美(mei)國(guo)南(nan)線(xian)設備,英文是(shi)SOUTHWIRE,國(guo)內廠家(jia)是(shi)南(nan)京華新,江西銅業,另一種是(shi)德國(guo)CONTIROD設備,國(guo)內廠家(jia)是(shi)常州金(jin)源,天(tian)津大無(wu)縫。

無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)上容易區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)是含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)在10-20個PPM以下,但(dan)目(mu)前有(you)(you)的(de)(de)廠家(jia)只能(neng)做到(dao)(dao)50個PPM以下.低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)在 200-400個PPM,好的(de)(de)桿(gan)(gan)(gan)子一般含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)控制(zhi)在250個PPM左右(you),無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)一般采取的(de)(de)是上引法,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)是連鑄連軋,兩種產品相(xiang)對(dui)(dui)(dui)而言低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)(dui)(dui)漆包(bao)線性(xing)(xing) 能(neng)更適(shi)應(ying)些,如(ru)(ru)柔(rou)軟性(xing)(xing),回彈角,繞(rao)線性(xing)(xing)能(neng).但(dan)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)(dui)(dui)拉(la)絲條(tiao)件相(xiang)對(dui)(dui)(dui)要(yao)苛(ke)刻些,同樣拉(la)伸(shen)(shen)0.2的(de)(de)細絲,如(ru)(ru)果伸(shen)(shen)線條(tiao)件不好,普通(tong)(tong)的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)可(ke)拉(la)而好的(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)就(jiu)斷 線,但(dan)如(ru)(ru)果放在好的(de)(de)伸(shen)(shen)線條(tiao)件,同樣的(de)(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)說不定就(jiu)能(neng)拉(la)到(dao)(dao)雙零五,而普通(tong)(tong)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)最多只能(neng)拉(la)伸(shen)(shen)到(dao)(dao)0.1而已(yi),當然做的(de)(de)最細的(de)(de)如(ru)(ru)雙零二卻非得(de)依靠進口的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)了.目(mu)前有(you)(you)企業(ye)嘗(chang)試用剝(bo)皮的(de)(de)方式來(lai)處理低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)來(lai)伸(shen)(shen)0.03線.但(dan)有(you)(you)關這方面的(de)(de)內容我還不是很清楚。

音響(xiang)線一(yi)般(ban)反而喜(xi)歡用無氧桿,這和無氧桿是單(dan)晶(jing)銅(tong),低氧桿是多晶(jing)銅(tong)有(you)關(guan)。

氧(yang)銅(tong)桿(gan)和(he)無(wu)氧(yang)銅(tong)桿(gan)由于制造方法的不同,致使存在(zai)差別,具有(you)各自的特點。

一、關于氧的吸入和脫去以(yi)及它(ta)的存(cun)在狀態

生產銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)一般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)固(gu)溶度約2ppm。低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)一般在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)(de)進入(ru)是(shi)(shi)在(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)(de)(de)液態(tai)下(xia)吸入(ru)的(de)(de)(de)(de)(de)(de),而(er)(er)上引法無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)相反,氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態(tai)銅(tong)(tong)下(xia)保持相當(dang)時(shi)間(jian)后,被(bei)還原而(er)(er)脫去(qu),通常(chang)(chang)這種(zhong)桿(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以(yi)下(xia),最低可達1-2ppm,從組織上看,低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)狀態(tai),存在(zai)(zai)于晶粒邊界附(fu)近(jin),這對(dui)低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)而(er)(er)言可以(yi)說是(shi)(shi)常(chang)(chang)見(jian)的(de)(de)(de)(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)很少見(jian)。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)以(yi)夾雜形(xing)式在(zai)(zai)晶界出現(xian)對(dui)材料的(de)(de)(de)(de)(de)(de)韌性產生負(fu)面影響。而(er)(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低,所以(yi)這種(zhong)銅(tong)(tong)的(de)(de)(de)(de)(de)(de)組織是(shi)(shi)均勻(yun)的(de)(de)(de)(de)(de)(de)單相組織對(dui)韌性有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)(de)(de)(de)多孔性是(shi)(shi)不常(chang)(chang)見(jian)的(de)(de)(de)(de)(de)(de),而(er)(er)在(zai)(zai)低氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)則(ze)是(shi)(shi)常(chang)(chang)見(jian)的(de)(de)(de)(de)(de)(de)一種(zhong)缺陷。

二、熱(re)軋組(zu)織和(he)鑄(zhu)造組(zu)織的區別

低(di)氧(yang)銅(tong)桿由于經過熱(re)軋(ya),所以(yi)(yi)其組織(zhi)(zhi)(zhi)屬熱(re)加工(gong)組織(zhi)(zhi)(zhi),原來的(de)鑄造(zao)組織(zhi)(zhi)(zhi)已(yi)經破碎,在(zai)(zai)8mm的(de)桿時(shi)已(yi)有再(zai)結(jie)晶(jing)(jing)(jing)的(de)形式出現(xian),而無氧(yang)銅(tong)桿屬鑄造(zao)組織(zhi)(zhi)(zhi),晶(jing)(jing)(jing)粒(li)粗大,這(zhe)是為什么,無氧(yang)銅(tong)的(de)再(zai)結(jie)晶(jing)(jing)(jing)溫(wen)度較(jiao)(jiao)(jiao)高(gao)(gao),需要較(jiao)(jiao)(jiao)高(gao)(gao)退火(huo)(huo)溫(wen)度的(de)固有原因。這(zhe)是因為,再(zai)結(jie)晶(jing)(jing)(jing)發(fa)生在(zai)(zai)晶(jing)(jing)(jing)粒(li)邊(bian)界(jie)附近,無氧(yang)銅(tong)桿組織(zhi)(zhi)(zhi)晶(jing)(jing)(jing)粒(li)粗大,晶(jing)(jing)(jing)粒(li)尺寸甚(shen)至(zhi)能達幾個(ge)毫米,因而晶(jing)(jing)(jing)粒(li)邊(bian)界(jie)少,即(ji)使通過拉(la)(la)制(zhi)變形,但(dan)晶(jing)(jing)(jing)粒(li)邊(bian)界(jie)相(xiang)對低(di)氧(yang)銅(tong)桿還是較(jiao)(jiao)(jiao)少,所以(yi)(yi)需要較(jiao)(jiao)(jiao)高(gao)(gao)的(de)退火(huo)(huo)功率(lv)(lv)。對無氧(yang)銅(tong)成(cheng)功的(de)退火(huo)(huo)要求是:由桿經拉(la)(la)制(zhi),但(dan)尚未鑄造(zao)組織(zhi)(zhi)(zhi)的(de)線時(shi)的(de)第一(yi)次退火(huo)(huo),其退火(huo)(huo)功率(lv)(lv)應(ying)比同樣情況的(de)低(di)氧(yang)銅(tong)高(gao)(gao)10——15%。經繼(ji)續拉(la)(la)制(zhi),在(zai)(zai)以(yi)(yi)后階段的(de)退火(huo)(huo)功率(lv)(lv)應(ying)留有足夠的(de)余量和(he)對低(di)氧(yang)銅(tong)和(he)無氧(yang)銅(tong)切實區別執行(xing)不同的(de)退火(huo)(huo)工(gong)藝,以(yi)(yi)保證在(zai)(zai)制(zhi)品(pin)和(he)成(cheng)品(pin)導線的(de)柔軟性。

三、夾雜,氧含量波(bo)動,表面氧化物和(he)可(ke)能存在的熱軋缺陷的差(cha)別

無氧(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)可(ke)拉性(xing)在(zai)所有線徑里與(yu)低氧(yang)(yang)銅(tong)桿(gan)(gan)相(xiang)比(bi)都(dou)是(shi)優越的(de)(de),除上(shang)述組織原(yuan)因(yin)外(wai),無氧(yang)(yang)銅(tong)桿(gan)(gan)夾雜少,含氧(yang)(yang)量穩(wen)定,無熱軋可(ke)能產(chan)生的(de)(de)缺陷,桿(gan)(gan)表(biao)氧(yang)(yang)化(hua)物厚度可(ke)達≤15A。在(zai)連鑄連軋生產(chan)過程中(zhong)(zhong)如果工(gong)藝(yi)不(bu)(bu)穩(wen)定,對(dui)(dui)氧(yang)(yang)監控不(bu)(bu)嚴,含氧(yang)(yang)量不(bu)(bu)穩(wen)定將直(zhi)接影(ying)響桿(gan)(gan)的(de)(de)性(xing)能。如果桿(gan)(gan)的(de)(de)表(biao)面(mian)氧(yang)(yang)化(hua)物能在(zai)后工(gong)序的(de)(de)連續清洗(xi)中(zhong)(zhong)得以(yi)彌補外(wai),但比(bi)較麻(ma)煩的(de)(de)是(shi)有相(xiang)當多的(de)(de)氧(yang)(yang)化(hua)物存在(zai)于“皮(pi)下(xia)”,對(dui)(dui)拉線斷線影(ying)響更(geng)直(zhi)接,故而在(zai)拉制微細線,超(chao)微細線時(shi),為了減少斷線,有時(shi)要對(dui)(dui)銅(tong)桿(gan)(gan)采取不(bu)(bu)得已的(de)(de)辦(ban)法(fa)——剝(bo)皮(pi),甚至二(er)次剝(bo)皮(pi)的(de)(de)原(yuan)因(yin)所在(zai),目的(de)(de)要除去皮(pi)下(xia)氧(yang)(yang)化(hua)物。

四、低氧銅桿(gan)和無氧銅桿(gan)的(de)韌性有差別(bie)

兩者(zhe)都(dou)可(ke)以(yi)拉到(dao)0.015mm,但在(zai)低溫(wen)超導線中的低溫(wen)級(ji)無氧銅,其細絲間的間距(ju)只有0.001mm.

五、從制桿的原材(cai)料到制線的經(jing)濟性有差別。

制(zhi)造無(wu)氧銅(tong)桿(gan)要求質量(liang)較高的(de)原材料。一般(ban),拉制(zhi)直徑>1mm的(de)銅(tong)線(xian)時,低氧銅(tong)桿(gan)的(de)優點比較明(ming)顯(xian),而無(wu)氧銅(tong)桿(gan)顯(xian)得(de)更為(wei)優越的(de)是(shi)拉制(zhi)直徑<0.5mm的(de)銅(tong)線(xian)。

六、低氧銅(tong)桿(gan)的制線工藝與無氧銅(tong)桿(gan)的有所不(bu)同。

低氧(yang)銅(tong)桿(gan)的制(zhi)線工藝(yi)(yi)不(bu)(bu)能(neng)照搬到(dao)無氧(yang)銅(tong)桿(gan)的制(zhi)線工藝(yi)(yi)上來,至少兩者的退(tui)(tui)火(huo)工藝(yi)(yi)是不(bu)(bu)同的。因為線的柔軟性深受材料(liao)成(cheng)份和(he)制(zhi)桿(gan),制(zhi)線和(he)退(tui)(tui)火(huo)工藝(yi)(yi)的影響(xiang),不(bu)(bu)能(neng)簡(jian)單(dan)地說(shuo)低氧(yang)銅(tong)或無氧(yang)銅(tong)誰軟誰硬(ying)。