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盤錦電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業動態 閱讀:109569 發布(bu)時間:2019-07-05

導讀:由(you)于生(sheng)產(chan)(chan)(chan)銅(tong)桿(gan)的(de)兩者的(de)工藝(yi)不同(tong)(tong),所生(sheng)產(chan)(chan)(chan)的(de)銅(tong)桿(gan)中(zhong)的(de)含(han)氧(yang)量及外觀就不同(tong)(tong)。上引生(sheng)產(chan)(chan)(chan)的(de)銅(tong)桿(gan),工藝(yi)得當(dang)氧(yang)含(han)量在10ppm以下,叫無氧(yang)銅(tong)桿(gan);連(lian)鑄連(lian)鑄生(sheng)產(chan)(chan)(chan)的(de)銅(tong)桿(gan) 是在保護條件下的(de)熱軋,氧(yang)含(han)量在200-500ppm范圍內(nei),但(dan)有時也高達700ppm以上,一般情況下,此種方法生(sheng)產(chan)(chan)(chan)的(de)銅(tong)外表(biao)光(guang)亮,低氧(yang)銅(tong)桿(gan),有時也叫光(guang)桿(gan)。

銅(tong)桿(gan)是電(dian)纜行(xing)(xing)業的主(zhu)要原料,生(sheng)產(chan)(chan)的方(fang)式主(zhu)要有(you)兩種——連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)(lian)(lian)(lian)軋法和上引連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)法。連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)(lian)(lian)(lian)軋低(di)氧(yang)(yang)銅(tong)桿(gan)的生(sheng)產(chan)(chan)方(fang)法較多(duo),其特點(dian)是金屬在(zai)(zai)豎爐(lu)中(zhong)(zhong)融化后,銅(tong)液通(tong)過保溫爐(lu)、溜(liu)槽、中(zhong)(zhong)間(jian)包,從澆管進(jin)入封閉的模腔(qiang)內(nei),采用較大(da)的冷(leng)(leng)卻強(qiang)度進(jin)行(xing)(xing)冷(leng)(leng)卻,形成鑄(zhu)(zhu)(zhu)(zhu)坯(pi),然后進(jin)行(xing)(xing)多(duo)道次軋制,生(sheng)產(chan)(chan)的低(di)氧(yang)(yang)銅(tong)桿(gan)為(wei)(wei)熱(re)加工(gong)組(zu)織(zhi),原來的鑄(zhu)(zhu)(zhu)(zhu)造(zao)組(zu)織(zhi)已經破碎,含氧(yang)(yang)量(liang)一(yi)般為(wei)(wei)200~400ppm之間(jian)。無氧(yang)(yang)銅(tong)桿(gan)國內(nei)基本全部采用上引連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)法生(sheng)產(chan)(chan),金屬在(zai)(zai)感應電(dian)爐(lu)中(zhong)(zhong)融化后通(tong)過石墨模進(jin)行(xing)(xing)上引連(lian)(lian)(lian)(lian)續鑄(zhu)(zhu)(zhu)(zhu)造(zao),之后進(jin)行(xing)(xing)冷(leng)(leng)軋或冷(leng)(leng)加工(gong),生(sheng)產(chan)(chan)的無氧(yang)(yang)銅(tong)桿(gan)為(wei)(wei)鑄(zhu)(zhu)(zhu)(zhu)造(zao)組(zu)織(zhi),含氧(yang)(yang)量(liang)一(yi)般在(zai)(zai)20ppm以下。由于制造(zao)工(gong)藝的不同(tong),所以在(zai)(zai)組(zu)織(zhi)結構、氧(yang)(yang)含量(liang)分布、雜質的形式及分布等(deng)諸多(duo)方(fang)面(mian)有(you)較大(da)差(cha)別。

一、拉制性能

銅桿的拉制性能(neng)跟(gen)很多因素(su)有關,如(ru)雜質的含量、氧含量及分布、工(gong)藝控制等。下面分別從以上幾個方(fang)面對銅桿的拉制性能(neng)進行分析。

1、熔(rong)化方式對S等雜質的影響

連(lian)(lian)鑄(zhu)連(lian)(lian)軋生產(chan)銅(tong)(tong)桿(gan)(gan)主要(yao)是(shi)通過氣體的(de)燃燒使銅(tong)(tong)桿(gan)(gan)熔(rong)化(hua),在燃燒的(de)過程(cheng)(cheng)中(zhong),通過氧化(hua)和揮發作(zuo)用(yong),可一(yi)定程(cheng)(cheng)度減少部分雜質進(jin)入(ru)(ru)銅(tong)(tong)液(ye),因(yin)此連(lian)(lian)鑄(zhu)連(lian)(lian)軋法對(dui)原料(liao)要(yao)求相對(dui)低一(yi)些。上引(yin)連(lian)(lian)鑄(zhu)生產(chan)無(wu)氧銅(tong)(tong)桿(gan)(gan),由(you)于是(shi)用(yong)感應電(dian)爐熔(rong)化(hua),電(dian)解銅(tong)(tong)表(biao)面(mian)的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都熔(rong)入(ru)(ru)到銅(tong)(tong)液(ye)中(zhong)。其中(zhong)熔(rong)入(ru)(ru)的(de)S對(dui)無(wu)氧銅(tong)(tong)桿(gan)(gan)塑性影響極大,會增加拉絲斷線率。

2、鑄造過程(cheng)中雜質的(de)進入

在(zai)生產過(guo)(guo)(guo)(guo)程(cheng)中(zhong),連(lian)鑄(zhu)連(lian)軋(ya)工(gong)藝需(xu)通過(guo)(guo)(guo)(guo)保溫爐、溜槽、中(zhong)間包(bao)轉運銅液,相對(dui)容(rong)易造(zao)(zao)成(cheng)耐火(huo)材(cai)料的(de)剝落,在(zai)軋(ya)制過(guo)(guo)(guo)(guo)程(cheng)中(zhong)需(xu)要通過(guo)(guo)(guo)(guo)軋(ya)輥,造(zao)(zao)成(cheng)鐵質(zhi)的(de)脫(tuo)落,會給(gei)銅桿造(zao)(zao)成(cheng)外部夾雜。而熱軋(ya)中(zhong)皮上(shang)和皮下氧化物的(de)軋(ya)入(ru)(ru),會給(gei)低氧桿的(de)拉絲(si)造(zao)(zao)成(cheng)不(bu)利的(de)影響。上(shang)引連(lian)鑄(zhu)法(fa)生產工(gong)藝流(liu)程(cheng)較短,銅液是通過(guo)(guo)(guo)(guo)聯體(ti)爐內潛流(liu)式完成(cheng),對(dui)耐火(huo)材(cai)料的(de)沖擊不(bu)大,結晶是通過(guo)(guo)(guo)(guo)石墨(mo)模內進行,所以過(guo)(guo)(guo)(guo)程(cheng)中(zhong)可能產生的(de)污染源較少,雜質(zhi)進入(ru)(ru)的(de)機會較少。

O、S、P是與銅(tong)會生產化合物的(de)元素。在熔態(tai)銅(tong)中,氧(yang)可(ke)以(yi)溶(rong)解(jie)(jie)一部分(fen)(fen),但當銅(tong)冷(leng)凝時,氧(yang)幾乎(hu)不(bu)溶(rong)解(jie)(jie)于銅(tong)中。熔態(tai)時所溶(rong)解(jie)(jie)的(de)氧(yang),以(yi)銅(tong)=氧(yang)化亞銅(tong)共(gong)晶(jing)體(ti)析(xi)出,分(fen)(fen)布在晶(jing)粒晶(jing)界(jie)處。銅(tong)-氧(yang)化亞銅(tong)共(gong)晶(jing)體(ti)的(de)出現(xian),顯著降低了銅(tong)的(de)塑性。

硫(liu)可以(yi)溶解(jie)在熔體(ti)的(de)銅中,但在室(shi)溫(wen)下,其溶解(jie)度幾乎降低(di)到零,它以(yi)硫(liu)化亞銅的(de)形式出現在晶(jing)粒晶(jing)界處,會顯著(zhu)降低(di)銅的(de)塑性。

3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中分(fen)布形(xing)式及其影響(xiang)

氧(yang)含量對低(di)氧(yang)銅(tong)(tong)桿(gan)的(de)(de)拉(la)線性能有著明顯的(de)(de)影響。當(dang)氧(yang)含量增加到(dao)最佳值(zhi)時,銅(tong)(tong)桿(gan)的(de)(de)斷(duan)線率最低(di)。這是因為(wei)(wei)氧(yang)在與大部分雜質反應的(de)(de)過程中(zhong)都起到(dao)了(le)(le)清除(chu)器的(de)(de)作(zuo)用。適度的(de)(de)氧(yang)還有利于(yu)去除(chu)銅(tong)(tong)液(ye)中(zhong)的(de)(de)氫,生成(cheng)水蒸(zheng)氣溢出,減(jian)少氣孔(kong)的(de)(de)形成(cheng)。最佳的(de)(de)氧(yang)含量為(wei)(wei)拉(la)線工藝提供了(le)(le)最好的(de)(de)條件。

低氧(yang)(yang)銅(tong)桿氧(yang)(yang)化物(wu)的(de)分(fen)(fen)布(bu):在連續澆(jiao)鑄中凝固的(de)最(zui)初階段(duan),散(san)熱速(su)率和均勻(yun)冷卻是(shi)(shi)決定銅(tong)桿氧(yang)(yang)化物(wu)分(fen)(fen)布(bu)的(de)主要因素。不均勻(yun)冷卻會引起銅(tong)桿內部(bu)結構本質(zhi)上的(de)差(cha)異,但后續的(de)熱加工,柱(zhu)狀晶(jing)通常會遭到破壞,使氧(yang)(yang)化亞銅(tong)顆(ke)粒細微化和均勻(yun)分(fen)(fen)布(bu)。氧(yang)(yang)化物(wu)顆(ke)粒聚集而產生的(de)典(dian)型情況是(shi)(shi)中心爆(bao)裂(lie)。除氧(yang)(yang)化物(wu)顆(ke)粒分(fen)(fen)布(bu)的(de)影響(xiang)外,具(ju)有較小氧(yang)(yang)化物(wu)顆(ke)粒的(de)銅(tong)桿顯示(shi)出(chu)較好的(de)拉線特性(xing),較大的(de)Cu2O顆(ke)粒容易造(zao)成應力集中點而斷裂(lie)。

無(wu)氧(yang)(yang)銅(tong)含氧(yang)(yang)量(liang)超標,銅(tong)桿變脆(cui),延伸率下降,拉伸式樣端口顯暗紅色,結晶(jing)組織疏(shu)松。當(dang)氧(yang)(yang)含量(liang)超出8ppm時(shi),工(gong)(gong)藝性(xing)(xing)能(neng)變差,表現(xian)為鑄(zhu)造及拉伸過程中斷(duan)(duan)桿及斷(duan)(duan)線率極具(ju)增高(gao)。這是由于氧(yang)(yang)能(neng)與(yu)銅(tong)生成(cheng)氧(yang)(yang)化亞銅(tong)脆(cui)性(xing)(xing)相,形(xing)成(cheng)銅(tong)-氧(yang)(yang)化亞銅(tong)共晶(jing)體,以網狀(zhuang)組織分布在境界上。這種脆(cui)性(xing)(xing)相硬度高(gao),在冷變形(xing)時(shi)將(jiang)會與(yu)銅(tong)機體脫離(li),導(dao)致(zhi)銅(tong)桿的機械性(xing)(xing)能(neng)下降,在后續加工(gong)(gong)中容(rong)易(yi)造成(cheng)斷(duan)(duan)裂現(xian)象。氧(yang)(yang)含量(liang)高(gao)還能(neng)導(dao)致(zhi)無(wu)氧(yang)(yang)銅(tong)桿導(dao)電率下降。因此,必(bi)須嚴格控制上引連(lian)鑄(zhu)工(gong)(gong)藝及產品質(zhi)量(liang)。

4、氫的影響

在上引連鑄中,氧含量(liang)控制較低(di),氧化物的(de)副(fu)作(zuo)用唄**降低(di),但氫的(de)影響成為(wei)較顯著的(de)問題。吸氣后(hou)熔(rong)體中存(cun)在平(ping)衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)(qi)體及疏松(song)是在(zai)結(jie)(jie)(jie)晶的(de)(de)(de)(de)過程中,氫(qing)(qing)從過飽和的(de)(de)(de)(de)溶(rong)液中析出(chu)(chu)并聚(ju)集而形(xing)(xing)成(cheng)的(de)(de)(de)(de)。在(zai)結(jie)(jie)(jie)晶前(qian)析出(chu)(chu)的(de)(de)(de)(de)氫(qing)(qing)又(you)可還(huan)原氧化(hua)亞(ya)銅(tong)而生成(cheng)水氣(qi)(qi)(qi)(qi)泡(pao)。由(you)于(yu)上(shang)引(yin)鑄造(zao)的(de)(de)(de)(de)特點是銅(tong)液自上(shang)而下的(de)(de)(de)(de)結(jie)(jie)(jie)晶,形(xing)(xing)成(cheng)的(de)(de)(de)(de)液**形(xing)(xing)狀近似錐型。銅(tong)液結(jie)(jie)(jie)晶前(qian)析出(chu)(chu)的(de)(de)(de)(de)氣(qi)(qi)(qi)(qi)體在(zai)上(shang)浮(fu)過程中被堵(du)在(zai)凝固組(zu)織(zhi)內(nei),結(jie)(jie)(jie)晶時(shi)在(zai)鑄桿內(nei)形(xing)(xing)成(cheng)氣(qi)(qi)(qi)(qi)孔。上(shang)引(yin)的(de)(de)(de)(de)含氣(qi)(qi)(qi)(qi)量(liang)少時(shi),析出(chu)(chu)的(de)(de)(de)(de)氫(qing)(qing)存在(zai)于(yu)晶界處,形(xing)(xing)成(cheng)疏松(song);含氣(qi)(qi)(qi)(qi)量(liang)多時(shi),則聚(ju)集成(cheng)氣(qi)(qi)(qi)(qi)孔,因此(ci),氣(qi)(qi)(qi)(qi)孔和疏松(song)是氫(qing)(qing)氣(qi)(qi)(qi)(qi)和水蒸氣(qi)(qi)(qi)(qi)兩者形(xing)(xing)成(cheng)的(de)(de)(de)(de)。

氫來源于上引(yin)生(sheng)產過程中(zhong)(zhong)的各個工藝環節,如原(yuan)料電解銅(tong)的“銅(tong)綠”、輔料木炭**、氣候環境**、石墨結晶器未(wei)干(gan)燥(zao)等。因此,熔化爐中(zhong)(zhong)的銅(tong)液表面應(ying)覆蓋經烘烤的木炭,電解銅(tong)應(ying)盡量去(qu)除“銅(tong)綠”、“銅(tong)豆(dou)”“耳朵(duo)”,對提高無(wu)氧銅(tong)桿質量非常重(zhong)要。

在(zai)連(lian)鑄(zhu)連(lian)軋工(gong)藝(yi)中,往往采用適度控制氧(yang)含量來(lai)控制氫。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅(tong)液在鑄(zhu)造過(guo)程中是自(zi)下而(er)上(shang)結晶,銅(tong)液中的氧(yang)和氫(qing)所產生(sheng)的水蒸氣很容(rong)易上(shang)浮跑(pao)出,銅(tong)液中的氫(qing)大(da)部分能被有效去除(chu),因而(er)對銅(tong)桿的影(ying)響較小(xiao)。

二、表面質量

在生產電磁線等產品的(de)過程中,對銅桿的(de)表面質(zhi)量(liang)也(ye)需(xu)提出(chu)要(yao)求。需(xu)要(yao)拉制后的(de)銅絲表面無毛(mao)刺、銅粉少、無油污。并通過扭(niu)轉試驗測量(liang)表面銅粉的(de)質(zhi)量(liang)和扭(niu)轉后觀察銅桿的(de)復原情況來判定其好壞。

在(zai)連鑄連軋(ya)過程(cheng)中(zhong),從鑄造到軋(ya)制前,溫度高,完全暴露(lu)于(yu)空氣中(zhong),使(shi)鑄坯表面(mian)形成(cheng)較(jiao)厚的(de)(de)氧化(hua)(hua)(hua)層,在(zai)軋(ya)制過程(cheng)中(zhong),隨著軋(ya)輥的(de)(de)轉動,氧化(hua)(hua)(hua)物顆粒軋(ya)入銅(tong)線表面(mian)。由于(yu)氧化(hua)(hua)(hua)亞銅(tong)是高熔(rong)點脆性化(hua)(hua)(hua)合物,對于(yu)軋(ya)入較(jiao)深(shen)的(de)(de)氧化(hua)(hua)(hua)亞銅(tong),當成(cheng)條(tiao)狀的(de)(de)聚集物遇模具拉伸時,就(jiu)會是銅(tong)桿外(wai)表面(mian)產生(sheng)毛刺,給后續的(de)(de)涂漆造成(cheng)麻煩。

而上引連鑄(zhu)工藝制造的無氧銅桿,由于鑄(zhu)造和冷卻完全與氧隔(ge)絕,后續亦無熱軋(ya)過(guo)程,銅桿表(biao)面(mian)無軋(ya)入表(biao)面(mian)的氧化物,質量較(jiao)(jiao)好,拉制后銅粉少(shao),上述問(wen)題較(jiao)(jiao)少(shao)存在(zai)。

無氧銅桿也分(fen)進(jin)口(kou)設(she)備(bei)做(zuo)的(de)和國產(chan)設(she)備(bei)做(zuo)的(de),但目前進(jin)口(kou)產(chan)品已無明顯優勢,銅桿產(chan)品出來后區別不(bu)是很大,只要銅板選的(de)好(hao),生(sheng)產(chan)控制(zhi)比較穩定,國產(chan)設(she)備(bei)也能產(chan)出可(ke)拉伸0.05的(de)銅桿.進(jin)口(kou)設(she)備(bei)一般(ban)是芬蘭(lan)奧(ao)托(tuo)昆普(pu)的(de)設(she)備(bei),國產(chan)設(she)備(bei)最好(hao)的(de)應(ying)該是上海的(de)海軍廠的(de)了,生(sheng)產(chan)時間最長,軍工企業,質(zhi)量可(ke)靠。

低氧銅桿進口設備(bei)國際(ji)主要有兩種(zhong),一種(zhong)是(shi)美國南線(xian)設備(bei),英(ying)文是(shi)SOUTHWIRE,國內廠(chang)家是(shi)南京華新,江西銅業,另一種(zhong)是(shi)德國CONTIROD設備(bei),國內廠(chang)家是(shi)常州金源,天津大(da)無(wu)縫(feng)。

無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)及(ji)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從(cong)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)上(shang)容(rong)易區別,無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅是(shi)(shi)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)在(zai)10-20個(ge)PPM以(yi)下(xia),但(dan)(dan)目前有(you)的(de)(de)(de)(de)廠家(jia)只(zhi)能(neng)做到50個(ge)PPM以(yi)下(xia).低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好的(de)(de)(de)(de)桿(gan)(gan)(gan)(gan)子一般(ban)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)控制(zhi)在(zai)250個(ge)PPM左右,無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一般(ban)采取(qu)的(de)(de)(de)(de)是(shi)(shi)上(shang)引法,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)(shi)連鑄連軋,兩(liang)種產品相對(dui)而(er)言低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)漆包線(xian)性 能(neng)更適應(ying)些(xie)(xie),如(ru)柔軟性,回彈角,繞(rao)線(xian)性能(neng).但(dan)(dan)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)拉絲條件相對(dui)要苛刻些(xie)(xie),同樣拉伸(shen)0.2的(de)(de)(de)(de)細(xi)絲,如(ru)果伸(shen)線(xian)條件不(bu)好,普(pu)通(tong)的(de)(de)(de)(de)無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可(ke)拉而(er)好的(de)(de)(de)(de)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷 線(xian),但(dan)(dan)如(ru)果放在(zai)好的(de)(de)(de)(de)伸(shen)線(xian)條件,同樣的(de)(de)(de)(de)桿(gan)(gan)(gan)(gan)子,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說(shuo)不(bu)定就能(neng)拉到雙零五,而(er)普(pu)通(tong)無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最多只(zhi)能(neng)拉伸(shen)到0.1而(er)已,當然做的(de)(de)(de)(de)最細(xi)的(de)(de)(de)(de)如(ru)雙零二卻非(fei)得依靠進(jin)口的(de)(de)(de)(de) 無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了.目前有(you)企業嘗試用剝皮的(de)(de)(de)(de)方(fang)式(shi)來(lai)處理低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來(lai)伸(shen)0.03線(xian).但(dan)(dan)有(you)關這方(fang)面的(de)(de)(de)(de)內容(rong)我還(huan)不(bu)是(shi)(shi)很清楚(chu)。

音響線一般(ban)反(fan)而喜(xi)歡(huan)用無(wu)氧桿,這(zhe)和無(wu)氧桿是單晶(jing)銅,低氧桿是多晶(jing)銅有關。

氧銅(tong)桿(gan)和(he)無氧銅(tong)桿(gan)由(you)于(yu)制造方法的(de)不同,致使(shi)存在差別(bie),具有各自的(de)特點。

一、關(guan)于(yu)氧的吸入(ru)和(he)脫去以及它的存在狀態(tai)

生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)陰極銅(tong)(tong)(tong)(tong)的(de)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常溫下(xia)氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中的(de)固溶度(du)約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)(zai)200(175)—400(450)ppm,因(yin)此(ci)氧(yang)(yang)(yang)(yang)(yang)的(de)進入是(shi)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)液(ye)態下(xia)吸入的(de),而(er)上引法無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)相反,氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)液(ye)態銅(tong)(tong)(tong)(tong)下(xia)保(bao)持相當(dang)時間(jian)后,被還原而(er)脫(tuo)去,通常這(zhe)種桿(gan)(gan)的(de)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)(zai)10—50ppm以(yi)(yi)下(xia),最低(di)可達1-2ppm,從組織上看(kan),低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀(zhuang)態,存在(zai)(zai)(zai)于晶粒邊(bian)界(jie)附近,這(zhe)對(dui)(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)而(er)言可以(yi)(yi)說是(shi)常見的(de)但對(dui)(dui)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)很少見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形(xing)式在(zai)(zai)(zai)晶界(jie)出現(xian)對(dui)(dui)材(cai)料的(de)韌(ren)性產生負面(mian)影響。而(er)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所以(yi)(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)組織是(shi)均勻的(de)單(dan)相組織對(dui)(dui)韌(ren)性有利(li)。在(zai)(zai)(zai)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中的(de)多孔性是(shi)不常見的(de),而(er)在(zai)(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中則(ze)是(shi)常見的(de)一種缺陷。

二(er)、熱軋組織和鑄造組織的區別

低氧銅桿(gan)(gan)(gan)由于(yu)經過熱軋,所以其(qi)組(zu)織(zhi)(zhi)屬(shu)熱加工(gong)組(zu)織(zhi)(zhi),原(yuan)來(lai)的(de)(de)(de)(de)(de)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi)已(yi)經破碎(sui),在(zai)(zai)(zai)8mm的(de)(de)(de)(de)(de)桿(gan)(gan)(gan)時(shi)已(yi)有(you)再(zai)結晶(jing)(jing)的(de)(de)(de)(de)(de)形(xing)式(shi)出(chu)現,而無氧銅桿(gan)(gan)(gan)屬(shu)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi),晶(jing)(jing)粒(li)(li)粗(cu)大(da),這是(shi)為什么,無氧銅的(de)(de)(de)(de)(de)再(zai)結晶(jing)(jing)溫(wen)度較高(gao)(gao),需(xu)要較高(gao)(gao)退(tui)火溫(wen)度的(de)(de)(de)(de)(de)固有(you)原(yuan)因(yin)。這是(shi)因(yin)為,再(zai)結晶(jing)(jing)發生在(zai)(zai)(zai)晶(jing)(jing)粒(li)(li)邊(bian)界(jie)附近,無氧銅桿(gan)(gan)(gan)組(zu)織(zhi)(zhi)晶(jing)(jing)粒(li)(li)粗(cu)大(da),晶(jing)(jing)粒(li)(li)尺(chi)寸(cun)甚(shen)至能達幾個毫米(mi),因(yin)而晶(jing)(jing)粒(li)(li)邊(bian)界(jie)少,即(ji)使通過拉(la)(la)制(zhi)變形(xing),但晶(jing)(jing)粒(li)(li)邊(bian)界(jie)相對(dui)低氧銅桿(gan)(gan)(gan)還是(shi)較少,所以需(xu)要較高(gao)(gao)的(de)(de)(de)(de)(de)退(tui)火功率(lv)。對(dui)無氧銅成功的(de)(de)(de)(de)(de)退(tui)火要求(qiu)是(shi):由桿(gan)(gan)(gan)經拉(la)(la)制(zhi),但尚未(wei)鑄(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi)的(de)(de)(de)(de)(de)線時(shi)的(de)(de)(de)(de)(de)第(di)一次退(tui)火,其(qi)退(tui)火功率(lv)應比同樣情況(kuang)的(de)(de)(de)(de)(de)低氧銅高(gao)(gao)10——15%。經繼續拉(la)(la)制(zhi),在(zai)(zai)(zai)以后階(jie)段的(de)(de)(de)(de)(de)退(tui)火功率(lv)應留有(you)足(zu)夠的(de)(de)(de)(de)(de)余量和(he)(he)對(dui)低氧銅和(he)(he)無氧銅切實(shi)區別執行不同的(de)(de)(de)(de)(de)退(tui)火工(gong)藝(yi),以保證在(zai)(zai)(zai)制(zhi)品和(he)(he)成品導線的(de)(de)(de)(de)(de)柔軟(ruan)性。

三(san)、夾雜,氧含量波動,表(biao)面(mian)氧化物和可能(neng)存(cun)在(zai)的熱軋(ya)缺陷的差(cha)別

無(wu)(wu)氧(yang)(yang)(yang)銅桿的(de)可(ke)拉性在(zai)(zai)所(suo)(suo)有線(xian)(xian)徑里與低氧(yang)(yang)(yang)銅桿相比都是優越(yue)的(de),除(chu)上述組織原因外(wai),無(wu)(wu)氧(yang)(yang)(yang)銅桿夾雜(za)少(shao),含(han)氧(yang)(yang)(yang)量穩定(ding),無(wu)(wu)熱軋可(ke)能(neng)產(chan)生(sheng)的(de)缺陷,桿表(biao)氧(yang)(yang)(yang)化(hua)(hua)物厚度可(ke)達≤15A。在(zai)(zai)連(lian)鑄連(lian)軋生(sheng)產(chan)過(guo)程中如果工藝不(bu)(bu)穩定(ding),對氧(yang)(yang)(yang)監控(kong)不(bu)(bu)嚴(yan),含(han)氧(yang)(yang)(yang)量不(bu)(bu)穩定(ding)將直接影響桿的(de)性能(neng)。如果桿的(de)表(biao)面氧(yang)(yang)(yang)化(hua)(hua)物能(neng)在(zai)(zai)后工序的(de)連(lian)續清洗中得以(yi)彌補外(wai),但比較麻(ma)煩的(de)是有相當多的(de)氧(yang)(yang)(yang)化(hua)(hua)物存(cun)在(zai)(zai)于(yu)“皮(pi)下”,對拉線(xian)(xian)斷線(xian)(xian)影響更直接,故而在(zai)(zai)拉制微細線(xian)(xian),超(chao)微細線(xian)(xian)時(shi),為(wei)了(le)減少(shao)斷線(xian)(xian),有時(shi)要對銅桿采取不(bu)(bu)得已的(de)辦法(fa)——剝皮(pi),甚至二次剝皮(pi)的(de)原因所(suo)(suo)在(zai)(zai),目的(de)要除(chu)去皮(pi)下氧(yang)(yang)(yang)化(hua)(hua)物。

四、低(di)氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿的韌(ren)性有(you)差別

兩(liang)者都(dou)可以拉到0.015mm,但在低溫超導線中的低溫級無氧(yang)銅,其細絲(si)間的間距只有0.001mm.

五、從制桿的原材料到制線(xian)的經濟性有差(cha)別。

制(zhi)(zhi)造無(wu)氧銅(tong)(tong)桿(gan)要求(qiu)質(zhi)量較高的原材料。一(yi)般(ban),拉(la)(la)制(zhi)(zhi)直徑(jing)>1mm的銅(tong)(tong)線時,低氧銅(tong)(tong)桿(gan)的優點(dian)比(bi)較明顯(xian),而無(wu)氧銅(tong)(tong)桿(gan)顯(xian)得(de)更(geng)為(wei)優越的是拉(la)(la)制(zhi)(zhi)直徑(jing)<0.5mm的銅(tong)(tong)線。

六、低氧銅(tong)(tong)桿(gan)的制線工(gong)藝與無(wu)氧銅(tong)(tong)桿(gan)的有所(suo)不(bu)同。

低氧銅(tong)桿(gan)的(de)(de)制(zhi)(zhi)線(xian)工(gong)藝(yi)(yi)(yi)不能(neng)(neng)照(zhao)搬到(dao)無氧銅(tong)桿(gan)的(de)(de)制(zhi)(zhi)線(xian)工(gong)藝(yi)(yi)(yi)上來,至少兩者(zhe)的(de)(de)退火(huo)工(gong)藝(yi)(yi)(yi)是不同的(de)(de)。因(yin)為線(xian)的(de)(de)柔軟性深(shen)受材(cai)料成份和(he)制(zhi)(zhi)桿(gan),制(zhi)(zhi)線(xian)和(he)退火(huo)工(gong)藝(yi)(yi)(yi)的(de)(de)影響,不能(neng)(neng)簡(jian)單地說低氧銅(tong)或無氧銅(tong)誰(shui)軟誰(shui)硬(ying)。