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茄子河電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態 閱讀(du):109490 發布時間:2019-07-05

導讀:由于生(sheng)產銅(tong)(tong)(tong)桿(gan)(gan)的兩者的工藝(yi)不(bu)同,所生(sheng)產的銅(tong)(tong)(tong)桿(gan)(gan)中(zhong)的含(han)氧量及外觀(guan)就(jiu)不(bu)同。上(shang)引生(sheng)產的銅(tong)(tong)(tong)桿(gan)(gan),工藝(yi)得當(dang)氧含(han)量在(zai)10ppm以下(xia),叫無氧銅(tong)(tong)(tong)桿(gan)(gan);連鑄(zhu)連鑄(zhu)生(sheng)產的銅(tong)(tong)(tong)桿(gan)(gan) 是在(zai)保護條件下(xia)的熱軋,氧含(han)量在(zai)200-500ppm范(fan)圍內,但有時(shi)也高達700ppm以上(shang),一般情況下(xia),此(ci)種(zhong)方法生(sheng)產的銅(tong)(tong)(tong)外表光(guang)亮,低氧銅(tong)(tong)(tong)桿(gan)(gan),有時(shi)也叫光(guang)桿(gan)(gan)。

銅(tong)桿(gan)是(shi)電纜行業的(de)主要原料,生(sheng)產(chan)(chan)的(de)方(fang)式主要有(you)(you)兩種——連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)法和上引連(lian)(lian)鑄(zhu)(zhu)法。連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)低氧銅(tong)桿(gan)的(de)生(sheng)產(chan)(chan)方(fang)法較(jiao)多(duo),其特點是(shi)金屬在(zai)(zai)豎爐(lu)(lu)中融(rong)化后(hou),銅(tong)液通過保溫爐(lu)(lu)、溜槽、中間(jian)包,從澆管(guan)進(jin)(jin)入封閉的(de)模腔(qiang)內,采(cai)用(yong)較(jiao)大(da)的(de)冷卻強度進(jin)(jin)行冷卻,形成鑄(zhu)(zhu)坯,然后(hou)進(jin)(jin)行多(duo)道次軋(ya)制,生(sheng)產(chan)(chan)的(de)低氧銅(tong)桿(gan)為(wei)(wei)熱(re)加工組(zu)(zu)織(zhi),原來的(de)鑄(zhu)(zhu)造組(zu)(zu)織(zhi)已經破碎,含(han)氧量一般為(wei)(wei)200~400ppm之間(jian)。無(wu)氧銅(tong)桿(gan)國內基本全(quan)部采(cai)用(yong)上引連(lian)(lian)鑄(zhu)(zhu)法生(sheng)產(chan)(chan),金屬在(zai)(zai)感應電爐(lu)(lu)中融(rong)化后(hou)通過石墨模進(jin)(jin)行上引連(lian)(lian)續(xu)鑄(zhu)(zhu)造,之后(hou)進(jin)(jin)行冷軋(ya)或冷加工,生(sheng)產(chan)(chan)的(de)無(wu)氧銅(tong)桿(gan)為(wei)(wei)鑄(zhu)(zhu)造組(zu)(zu)織(zhi),含(han)氧量一般在(zai)(zai)20ppm以(yi)下。由(you)于(yu)制造工藝的(de)不同,所(suo)以(yi)在(zai)(zai)組(zu)(zu)織(zhi)結構、氧含(han)量分布(bu)、雜質(zhi)的(de)形式及分布(bu)等諸多(duo)方(fang)面有(you)(you)較(jiao)大(da)差別(bie)。

一、拉制性能

銅桿的拉制(zhi)性能跟(gen)很(hen)多因素有(you)關,如雜質的含量、氧含量及(ji)分布、工藝控制(zhi)等(deng)。下面分別(bie)從以上(shang)幾個方面對銅桿的拉制(zhi)性能進(jin)行分析。

1、熔化方式對(dui)S等雜質(zhi)的影響

連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)生產(chan)(chan)銅(tong)桿(gan)主要是通過(guo)氣(qi)體的燃(ran)燒(shao)使銅(tong)桿(gan)熔(rong)化,在燃(ran)燒(shao)的過(guo)程中(zhong)(zhong)(zhong),通過(guo)氧化和揮發作用,可一(yi)定程度減少部分雜質進入(ru)銅(tong)液,因此連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)法對原料(liao)要求相對低一(yi)些。上(shang)引連(lian)(lian)鑄(zhu)生產(chan)(chan)無(wu)氧銅(tong)桿(gan),由于是用感應電(dian)爐熔(rong)化,電(dian)解銅(tong)表面(mian)的“銅(tong)綠”“銅(tong)豆”基本都熔(rong)入(ru)到銅(tong)液中(zhong)(zhong)(zhong)。其中(zhong)(zhong)(zhong)熔(rong)入(ru)的S對無(wu)氧銅(tong)桿(gan)塑(su)性影(ying)響(xiang)極(ji)大(da),會增(zeng)加拉(la)絲斷(duan)線率(lv)。

2、鑄造過程中雜(za)質的進入

在生(sheng)(sheng)產(chan)過程中,連(lian)(lian)鑄連(lian)(lian)軋工藝需通(tong)(tong)過保溫爐、溜槽、中間包轉運銅(tong)液(ye)(ye),相對容易造成(cheng)耐(nai)火材料的剝落(luo),在軋制過程中需要通(tong)(tong)過軋輥,造成(cheng)鐵質的脫(tuo)落(luo),會(hui)給銅(tong)桿造成(cheng)外部夾雜(za)。而(er)熱軋中皮(pi)上和皮(pi)下氧化物的軋入,會(hui)給低氧桿的拉絲造成(cheng)不利的影響。上引連(lian)(lian)鑄法生(sheng)(sheng)產(chan)工藝流程較(jiao)短(duan),銅(tong)液(ye)(ye)是(shi)通(tong)(tong)過聯體爐內潛(qian)流式(shi)完(wan)成(cheng),對耐(nai)火材料的沖擊(ji)不大,結晶是(shi)通(tong)(tong)過石墨模內進行,所以過程中可(ke)能產(chan)生(sheng)(sheng)的污染源較(jiao)少,雜(za)質進入的機(ji)會(hui)較(jiao)少。

O、S、P是與銅會生(sheng)產化(hua)合物的元素。在熔態(tai)銅中,氧(yang)(yang)(yang)可以溶解(jie)一部分,但當銅冷凝時,氧(yang)(yang)(yang)幾乎不溶解(jie)于銅中。熔態(tai)時所(suo)溶解(jie)的氧(yang)(yang)(yang),以銅=氧(yang)(yang)(yang)化(hua)亞(ya)銅共晶體(ti)析出(chu),分布(bu)在晶粒晶界處。銅-氧(yang)(yang)(yang)化(hua)亞(ya)銅共晶體(ti)的出(chu)現,顯著降低了銅的塑性。

硫(liu)可以溶解在(zai)熔體的(de)銅(tong)中,但在(zai)室溫(wen)下,其溶解度幾乎降低到零,它(ta)以硫(liu)化亞銅(tong)的(de)形式出現在(zai)晶(jing)粒晶(jing)界(jie)處,會顯著降低銅(tong)的(de)塑性(xing)。

3、氧在(zai)低氧銅桿(gan)(gan)和無氧銅桿(gan)(gan)中(zhong)分(fen)布形式及(ji)其影響

氧(yang)(yang)(yang)含(han)(han)量(liang)對低氧(yang)(yang)(yang)銅桿的(de)拉線性能有(you)著明(ming)顯的(de)影響。當(dang)氧(yang)(yang)(yang)含(han)(han)量(liang)增加到最佳值時,銅桿的(de)斷線率最低。這(zhe)是因為氧(yang)(yang)(yang)在與大部分雜質反應(ying)的(de)過程中(zhong)都起到了清(qing)除(chu)器(qi)的(de)作用。適(shi)度的(de)氧(yang)(yang)(yang)還有(you)利于去除(chu)銅液中(zhong)的(de)氫,生成(cheng)水蒸氣(qi)溢出,減少(shao)氣(qi)孔的(de)形成(cheng)。最佳的(de)氧(yang)(yang)(yang)含(han)(han)量(liang)為拉線工藝提供了最好的(de)條(tiao)件。

低氧(yang)銅(tong)桿(gan)氧(yang)化物(wu)的(de)(de)分(fen)布:在(zai)連續澆鑄(zhu)中凝(ning)固的(de)(de)最初階段(duan),散熱速率(lv)和均(jun)勻冷卻(que)(que)是(shi)決定銅(tong)桿(gan)氧(yang)化物(wu)分(fen)布的(de)(de)主要(yao)因素。不(bu)均(jun)勻冷卻(que)(que)會引(yin)起(qi)銅(tong)桿(gan)內部(bu)結(jie)構本(ben)質(zhi)上的(de)(de)差(cha)異,但(dan)后續的(de)(de)熱加(jia)工,柱(zhu)狀晶通常會遭到破壞,使氧(yang)化亞銅(tong)顆(ke)粒細微化和均(jun)勻分(fen)布。氧(yang)化物(wu)顆(ke)粒聚集而產生的(de)(de)典型情況是(shi)中心爆裂。除氧(yang)化物(wu)顆(ke)粒分(fen)布的(de)(de)影響外,具有較(jiao)小氧(yang)化物(wu)顆(ke)粒的(de)(de)銅(tong)桿(gan)顯示(shi)出較(jiao)好的(de)(de)拉線特性,較(jiao)大的(de)(de)Cu2O顆(ke)粒容易造成應力集中點而斷(duan)裂。

無氧銅(tong)(tong)(tong)(tong)含氧量(liang)超(chao)標(biao),銅(tong)(tong)(tong)(tong)桿(gan)變(bian)脆,延伸(shen)率(lv)下(xia)(xia)降(jiang),拉伸(shen)式樣端口顯(xian)暗紅色,結晶(jing)組織疏松。當氧含量(liang)超(chao)出8ppm時,工藝性能變(bian)差,表現(xian)為鑄(zhu)(zhu)造(zao)及拉伸(shen)過程(cheng)中斷桿(gan)及斷線率(lv)極具(ju)增高。這是由于氧能與銅(tong)(tong)(tong)(tong)生成(cheng)氧化(hua)(hua)亞銅(tong)(tong)(tong)(tong)脆性相,形(xing)成(cheng)銅(tong)(tong)(tong)(tong)-氧化(hua)(hua)亞銅(tong)(tong)(tong)(tong)共(gong)晶(jing)體(ti),以網狀組織分布在(zai)境界上(shang)。這種(zhong)脆性相硬(ying)度高,在(zai)冷(leng)變(bian)形(xing)時將會與銅(tong)(tong)(tong)(tong)機(ji)(ji)體(ti)脫(tuo)離,導致銅(tong)(tong)(tong)(tong)桿(gan)的機(ji)(ji)械性能下(xia)(xia)降(jiang),在(zai)后續加工中容易造(zao)成(cheng)斷裂現(xian)象。氧含量(liang)高還能導致無氧銅(tong)(tong)(tong)(tong)桿(gan)導電率(lv)下(xia)(xia)降(jiang)。因此(ci),必(bi)須嚴(yan)格控制上(shang)引連鑄(zhu)(zhu)工藝及產(chan)品質量(liang)。

4、氫的影響

在上引連鑄中(zhong),氧(yang)含量(liang)控制較(jiao)低(di),氧(yang)化(hua)物的副作用唄(bai)**降低(di),但氫的影響成為較(jiao)顯著的問(wen)題。吸(xi)氣后熔體中(zhong)存在平衡反(fan)應:H2O(g)=[O]+2[H];

氣(qi)體及疏(shu)(shu)松(song)是(shi)在(zai)結(jie)(jie)晶(jing)(jing)(jing)的(de)(de)(de)(de)(de)過(guo)程中(zhong),氫(qing)從過(guo)飽和(he)(he)的(de)(de)(de)(de)(de)溶液(ye)中(zhong)析(xi)出(chu)并(bing)聚(ju)集而形(xing)成(cheng)(cheng)的(de)(de)(de)(de)(de)。在(zai)結(jie)(jie)晶(jing)(jing)(jing)前析(xi)出(chu)的(de)(de)(de)(de)(de)氫(qing)又可還原氧化亞銅(tong)(tong)而生(sheng)成(cheng)(cheng)水氣(qi)泡。由于上(shang)引鑄造的(de)(de)(de)(de)(de)特點是(shi)銅(tong)(tong)液(ye)自上(shang)而下的(de)(de)(de)(de)(de)結(jie)(jie)晶(jing)(jing)(jing),形(xing)成(cheng)(cheng)的(de)(de)(de)(de)(de)液(ye)**形(xing)狀近似錐型。銅(tong)(tong)液(ye)結(jie)(jie)晶(jing)(jing)(jing)前析(xi)出(chu)的(de)(de)(de)(de)(de)氣(qi)體在(zai)上(shang)浮(fu)過(guo)程中(zhong)被堵在(zai)凝(ning)固組織內,結(jie)(jie)晶(jing)(jing)(jing)時在(zai)鑄桿內形(xing)成(cheng)(cheng)氣(qi)孔(kong)。上(shang)引的(de)(de)(de)(de)(de)含氣(qi)量少時,析(xi)出(chu)的(de)(de)(de)(de)(de)氫(qing)存在(zai)于晶(jing)(jing)(jing)界處,形(xing)成(cheng)(cheng)疏(shu)(shu)松(song);含氣(qi)量多(duo)時,則聚(ju)集成(cheng)(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和(he)(he)疏(shu)(shu)松(song)是(shi)氫(qing)氣(qi)和(he)(he)水蒸氣(qi)兩者形(xing)成(cheng)(cheng)的(de)(de)(de)(de)(de)。

氫來源于上(shang)引生產過(guo)程中(zhong)的(de)(de)各個工藝環節,如原料電(dian)解銅(tong)的(de)(de)“銅(tong)綠”、輔料木(mu)炭(tan)(tan)**、氣候環境**、石(shi)墨(mo)結晶(jing)器未干(gan)燥等。因此,熔化爐中(zhong)的(de)(de)銅(tong)液(ye)表面應覆蓋經烘烤的(de)(de)木(mu)炭(tan)(tan),電(dian)解銅(tong)應盡(jin)量去除“銅(tong)綠”、“銅(tong)豆”“耳朵(duo)”,對提高無氧(yang)銅(tong)桿(gan)質量非常重(zhong)要。

在連鑄連軋工(gong)藝中,往往采用適度(du)控制(zhi)氧含(han)量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)液(ye)在鑄造過(guo)程中(zhong)(zhong)是自(zi)下而上結晶(jing),銅(tong)液(ye)中(zhong)(zhong)的(de)氧和氫所產生(sheng)的(de)水蒸氣很容易上浮跑出(chu),銅(tong)液(ye)中(zhong)(zhong)的(de)氫大部分能被有效(xiao)去除,因(yin)而對銅(tong)桿的(de)影響較小。

二、表面質量

在生產電磁線(xian)等產品的(de)(de)過程中,對銅(tong)(tong)桿的(de)(de)表(biao)面(mian)質量(liang)(liang)也(ye)需(xu)提出要求。需(xu)要拉(la)制后的(de)(de)銅(tong)(tong)絲表(biao)面(mian)無毛刺、銅(tong)(tong)粉(fen)少、無油污。并(bing)通過扭轉試驗(yan)測量(liang)(liang)表(biao)面(mian)銅(tong)(tong)粉(fen)的(de)(de)質量(liang)(liang)和扭轉后觀察銅(tong)(tong)桿的(de)(de)復原情況來判定其(qi)好壞。

在連鑄連軋(ya)(ya)過程中(zhong),從鑄造到軋(ya)(ya)制前,溫度高(gao),完全暴露于(yu)(yu)空氣(qi)中(zhong),使鑄坯(pi)表面形(xing)成較(jiao)厚的氧(yang)化層(ceng),在軋(ya)(ya)制過程中(zhong),隨著軋(ya)(ya)輥的轉動,氧(yang)化物(wu)顆粒軋(ya)(ya)入銅(tong)線(xian)表面。由于(yu)(yu)氧(yang)化亞銅(tong)是(shi)高(gao)熔點脆性化合(he)物(wu),對于(yu)(yu)軋(ya)(ya)入較(jiao)深(shen)的氧(yang)化亞銅(tong),當成條(tiao)狀的聚集物(wu)遇模(mo)具(ju)拉伸(shen)時,就會是(shi)銅(tong)桿(gan)外表面產生毛刺,給后續的涂漆造成麻煩(fan)。

而(er)上引(yin)連鑄工藝制造的無(wu)氧(yang)銅(tong)桿,由于鑄造和冷卻完(wan)全與氧(yang)隔(ge)絕,后續亦無(wu)熱軋(ya)過程,銅(tong)桿表面無(wu)軋(ya)入表面的氧(yang)化物(wu),質量(liang)較好,拉制后銅(tong)粉少(shao),上述問題(ti)較少(shao)存在。

無(wu)氧銅(tong)桿(gan)也(ye)分進口(kou)設(she)(she)備做的(de)(de)(de)和國產(chan)(chan)設(she)(she)備做的(de)(de)(de),但目(mu)前進口(kou)產(chan)(chan)品已無(wu)明顯(xian)優勢,銅(tong)桿(gan)產(chan)(chan)品出來后區別不(bu)是(shi)很(hen)大,只要(yao)銅(tong)板選的(de)(de)(de)好,生產(chan)(chan)控制比較(jiao)穩定,國產(chan)(chan)設(she)(she)備也(ye)能產(chan)(chan)出可(ke)拉伸0.05的(de)(de)(de)銅(tong)桿(gan).進口(kou)設(she)(she)備一般是(shi)芬(fen)蘭奧托昆普(pu)的(de)(de)(de)設(she)(she)備,國產(chan)(chan)設(she)(she)備最好的(de)(de)(de)應該是(shi)上海的(de)(de)(de)海軍廠的(de)(de)(de)了,生產(chan)(chan)時間最長,軍工企(qi)業,質量可(ke)靠。

低氧(yang)銅桿進口(kou)設備國際主要(yao)有兩種,一(yi)種是(shi)美國南線設備,英(ying)文是(shi)SOUTHWIRE,國內(nei)廠家(jia)是(shi)南京華(hua)新,江(jiang)西銅業,另一(yi)種是(shi)德(de)國CONTIROD設備,國內(nei)廠家(jia)是(shi)常州金源,天津大無縫。

無氧(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上容(rong)易區別,無氧(yang)(yang)(yang)銅(tong)是含氧(yang)(yang)(yang)量在(zai)(zai)10-20個(ge)PPM以下,但(dan)目(mu)前(qian)有的(de)(de)(de)廠家只能(neng)(neng)做(zuo)到(dao)50個(ge)PPM以下.低(di)(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)(de)桿(gan)(gan)(gan)子(zi)一(yi)(yi)般(ban)含氧(yang)(yang)(yang)量控制在(zai)(zai)250個(ge)PPM左右,無氧(yang)(yang)(yang)桿(gan)(gan)(gan)一(yi)(yi)般(ban)采取的(de)(de)(de)是上引法,低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是連鑄(zhu)連軋,兩種產品相對而言低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對漆包(bao)線性(xing) 能(neng)(neng)更適應(ying)些,如(ru)(ru)(ru)柔軟性(xing),回彈角,繞線性(xing)能(neng)(neng).但(dan)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對拉絲條件(jian)相對要苛(ke)刻些,同樣(yang)拉伸(shen)0.2的(de)(de)(de)細絲,如(ru)(ru)(ru)果伸(shen)線條件(jian)不好,普通的(de)(de)(de)無氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉而好的(de)(de)(de)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就斷(duan) 線,但(dan)如(ru)(ru)(ru)果放在(zai)(zai)好的(de)(de)(de)伸(shen)線條件(jian),同樣(yang)的(de)(de)(de)桿(gan)(gan)(gan)子(zi),低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不定(ding)就能(neng)(neng)拉到(dao)雙零(ling)五,而普通無氧(yang)(yang)(yang)桿(gan)(gan)(gan)最多(duo)只能(neng)(neng)拉伸(shen)到(dao)0.1而已,當然做(zuo)的(de)(de)(de)最細的(de)(de)(de)如(ru)(ru)(ru)雙零(ling)二(er)卻非(fei)得依(yi)靠進(jin)口的(de)(de)(de) 無氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)了(le).目(mu)前(qian)有企業嘗(chang)試用剝皮的(de)(de)(de)方式來處理低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)0.03線.但(dan)有關這方面(mian)的(de)(de)(de)內容(rong)我還不是很清楚(chu)。

音響線(xian)一(yi)般反而喜歡(huan)用無氧(yang)桿,這和無氧(yang)桿是單晶銅(tong),低氧(yang)桿是多晶銅(tong)有關。

氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿由于(yu)制造方法的不同,致使存在(zai)差別,具有各自(zi)的特點。

一(yi)、關于氧的吸入(ru)和脫(tuo)去以及它的存在狀態(tai)

生(sheng)(sheng)產銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)(tong)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般(ban)在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)溫下氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)固(gu)溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)一(yi)(yi)般(ban)在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入(ru)是(shi)(shi)在(zai)(zai)(zai)銅(tong)(tong)(tong)的(de)(de)(de)(de)液態(tai)(tai)下吸入(ru)的(de)(de)(de)(de),而上(shang)引法無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則相反,氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)液態(tai)(tai)銅(tong)(tong)(tong)下保持相當時間后(hou),被還原而脫去(qu),通常(chang)這(zhe)種(zhong)桿(gan)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)都(dou)在(zai)(zai)(zai)10—50ppm以(yi)下,最低(di)可(ke)達1-2ppm,從組織(zhi)上(shang)看(kan),低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)狀態(tai)(tai),存在(zai)(zai)(zai)于晶(jing)粒邊界附近,這(zhe)對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)而言可(ke)以(yi)說是(shi)(shi)常(chang)見的(de)(de)(de)(de)但對(dui)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則很(hen)少見。氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)晶(jing)界出現對(dui)材料的(de)(de)(de)(de)韌(ren)性產生(sheng)(sheng)負面(mian)影響。而無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)很(hen)低(di),所以(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)的(de)(de)(de)(de)組織(zhi)是(shi)(shi)均勻(yun)的(de)(de)(de)(de)單相組織(zhi)對(dui)韌(ren)性有利。在(zai)(zai)(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中(zhong)(zhong)的(de)(de)(de)(de)多孔(kong)性是(shi)(shi)不(bu)常(chang)見的(de)(de)(de)(de),而在(zai)(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中(zhong)(zhong)則是(shi)(shi)常(chang)見的(de)(de)(de)(de)一(yi)(yi)種(zhong)缺陷。

二、熱軋組織(zhi)和鑄造組織(zhi)的區別

低(di)氧(yang)銅(tong)(tong)桿(gan)(gan)由(you)于經(jing)(jing)過熱(re)軋,所以其組織屬熱(re)加工(gong)(gong)組織,原來的(de)(de)(de)(de)(de)鑄造組織已經(jing)(jing)破(po)碎,在(zai)8mm的(de)(de)(de)(de)(de)桿(gan)(gan)時(shi)(shi)已有再(zai)結(jie)晶(jing)(jing)(jing)的(de)(de)(de)(de)(de)形式出現,而無氧(yang)銅(tong)(tong)桿(gan)(gan)屬鑄造組織,晶(jing)(jing)(jing)粒(li)(li)(li)(li)粗(cu)大,這(zhe)是(shi)(shi)為什么,無氧(yang)銅(tong)(tong)的(de)(de)(de)(de)(de)再(zai)結(jie)晶(jing)(jing)(jing)溫度較高(gao)(gao),需要(yao)較高(gao)(gao)退火(huo)溫度的(de)(de)(de)(de)(de)固有原因。這(zhe)是(shi)(shi)因為,再(zai)結(jie)晶(jing)(jing)(jing)發生在(zai)晶(jing)(jing)(jing)粒(li)(li)(li)(li)邊(bian)(bian)界附近,無氧(yang)銅(tong)(tong)桿(gan)(gan)組織晶(jing)(jing)(jing)粒(li)(li)(li)(li)粗(cu)大,晶(jing)(jing)(jing)粒(li)(li)(li)(li)尺寸甚至能達(da)幾個毫米,因而晶(jing)(jing)(jing)粒(li)(li)(li)(li)邊(bian)(bian)界少(shao)(shao),即使通過拉制(zhi)變形,但(dan)晶(jing)(jing)(jing)粒(li)(li)(li)(li)邊(bian)(bian)界相對(dui)低(di)氧(yang)銅(tong)(tong)桿(gan)(gan)還是(shi)(shi)較少(shao)(shao),所以需要(yao)較高(gao)(gao)的(de)(de)(de)(de)(de)退火(huo)功(gong)(gong)率(lv)。對(dui)無氧(yang)銅(tong)(tong)成(cheng)功(gong)(gong)的(de)(de)(de)(de)(de)退火(huo)要(yao)求(qiu)是(shi)(shi):由(you)桿(gan)(gan)經(jing)(jing)拉制(zhi),但(dan)尚未鑄造組織的(de)(de)(de)(de)(de)線(xian)時(shi)(shi)的(de)(de)(de)(de)(de)第一次退火(huo),其退火(huo)功(gong)(gong)率(lv)應(ying)比同樣情況的(de)(de)(de)(de)(de)低(di)氧(yang)銅(tong)(tong)高(gao)(gao)10——15%。經(jing)(jing)繼續拉制(zhi),在(zai)以后階段的(de)(de)(de)(de)(de)退火(huo)功(gong)(gong)率(lv)應(ying)留有足夠的(de)(de)(de)(de)(de)余量(liang)和對(dui)低(di)氧(yang)銅(tong)(tong)和無氧(yang)銅(tong)(tong)切(qie)實(shi)區別執行不同的(de)(de)(de)(de)(de)退火(huo)工(gong)(gong)藝,以保證在(zai)制(zhi)品和成(cheng)品導線(xian)的(de)(de)(de)(de)(de)柔軟性。

三、夾(jia)雜,氧(yang)含量波動(dong),表面氧(yang)化物和可能存在的熱軋(ya)缺陷的差別

無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)可拉性(xing)在所有(you)線(xian)徑(jing)里與低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)相(xiang)比(bi)都是優越的(de)(de),除(chu)上述組織(zhi)原因外,無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)夾(jia)雜少,含(han)氧(yang)(yang)量(liang)穩定(ding),無(wu)熱軋可能產生的(de)(de)缺陷,桿(gan)(gan)表氧(yang)(yang)化物厚度可達≤15A。在連鑄連軋生產過程中如果(guo)工(gong)(gong)藝不(bu)穩定(ding),對(dui)氧(yang)(yang)監控不(bu)嚴,含(han)氧(yang)(yang)量(liang)不(bu)穩定(ding)將直接影(ying)響桿(gan)(gan)的(de)(de)性(xing)能。如果(guo)桿(gan)(gan)的(de)(de)表面氧(yang)(yang)化物能在后工(gong)(gong)序的(de)(de)連續清洗中得以彌(mi)補外,但(dan)比(bi)較麻(ma)煩的(de)(de)是有(you)相(xiang)當多的(de)(de)氧(yang)(yang)化物存在于“皮下”,對(dui)拉線(xian)斷線(xian)影(ying)響更(geng)直接,故而在拉制微(wei)細線(xian),超微(wei)細線(xian)時,為了減少斷線(xian),有(you)時要(yao)對(dui)銅(tong)桿(gan)(gan)采取不(bu)得已的(de)(de)辦法(fa)——剝皮,甚至二次剝皮的(de)(de)原因所在,目的(de)(de)要(yao)除(chu)去皮下氧(yang)(yang)化物。

四、低氧(yang)銅(tong)桿(gan)和(he)無氧(yang)銅(tong)桿(gan)的韌(ren)性有差別

兩者都可以(yi)拉(la)到0.015mm,但(dan)在低溫超導線中的(de)低溫級無氧(yang)銅,其(qi)細絲(si)間(jian)的(de)間(jian)距(ju)只有0.001mm.

五、從制桿的(de)原材料到制線的(de)經濟性(xing)有差別。

制(zhi)造無(wu)氧(yang)(yang)銅(tong)桿(gan)要求質量較高的(de)原材料(liao)。一般,拉(la)制(zhi)直(zhi)徑>1mm的(de)銅(tong)線時,低氧(yang)(yang)銅(tong)桿(gan)的(de)優點(dian)比較明顯,而無(wu)氧(yang)(yang)銅(tong)桿(gan)顯得更為優越的(de)是(shi)拉(la)制(zhi)直(zhi)徑<0.5mm的(de)銅(tong)線。

六、低氧銅桿的(de)(de)制線(xian)工藝與無氧銅桿的(de)(de)有(you)所不同。

低氧(yang)銅桿的(de)制線工藝不(bu)(bu)能照搬到無(wu)氧(yang)銅桿的(de)制線工藝上來,至少兩者的(de)退火(huo)(huo)工藝是不(bu)(bu)同的(de)。因為線的(de)柔軟性深受材料成份和制桿,制線和退火(huo)(huo)工藝的(de)影(ying)響,不(bu)(bu)能簡單(dan)地說(shuo)低氧(yang)銅或無(wu)氧(yang)銅誰(shui)(shui)軟誰(shui)(shui)硬。