熱(re)門關鍵(jian)詞:
來(lai)源:行(xing)業動態(tai) 閱(yue)讀:109406 發(fa)布(bu)時間(jian):2019-07-05
導讀:由于生(sheng)產(chan)銅(tong)桿的(de)(de)兩者的(de)(de)工藝不同,所生(sheng)產(chan)的(de)(de)銅(tong)桿中的(de)(de)含(han)氧量及外(wai)觀就不同。上引生(sheng)產(chan)的(de)(de)銅(tong)桿,工藝得當氧含(han)量在(zai)10ppm以下(xia),叫無氧銅(tong)桿;連鑄連鑄生(sheng)產(chan)的(de)(de)銅(tong)桿 是在(zai)保護條件下(xia)的(de)(de)熱軋,氧含(han)量在(zai)200-500ppm范圍內,但有時也高達700ppm以上,一般(ban)情況下(xia),此種方(fang)法生(sheng)產(chan)的(de)(de)銅(tong)外(wai)表光(guang)亮,低氧銅(tong)桿,有時也叫光(guang)桿。
銅(tong)(tong)(tong)桿是電纜行業的主(zhu)要(yao)原(yuan)料,生(sheng)(sheng)產的方式(shi)主(zhu)要(yao)有(you)兩(liang)種(zhong)——連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)(lian)(lian)軋(ya)法和上(shang)引(yin)連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)法。連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)(lian)(lian)軋(ya)低氧(yang)銅(tong)(tong)(tong)桿的生(sheng)(sheng)產方法較多(duo)(duo),其特點是金(jin)屬在(zai)(zai)豎爐(lu)中融化(hua)后,銅(tong)(tong)(tong)液通過保溫爐(lu)、溜槽(cao)、中間包(bao),從澆管進入封閉的模腔內,采用較大的冷(leng)卻強度進行冷(leng)卻,形(xing)成鑄(zhu)(zhu)坯(pi),然后進行多(duo)(duo)道次軋(ya)制,生(sheng)(sheng)產的低氧(yang)銅(tong)(tong)(tong)桿為(wei)熱加(jia)工組(zu)織,原(yuan)來的鑄(zhu)(zhu)造組(zu)織已經(jing)破碎,含(han)氧(yang)量(liang)一般為(wei)200~400ppm之(zhi)間。無氧(yang)銅(tong)(tong)(tong)桿國內基(ji)本全部采用上(shang)引(yin)連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)法生(sheng)(sheng)產,金(jin)屬在(zai)(zai)感應(ying)電爐(lu)中融化(hua)后通過石墨模進行上(shang)引(yin)連(lian)(lian)(lian)(lian)續鑄(zhu)(zhu)造,之(zhi)后進行冷(leng)軋(ya)或冷(leng)加(jia)工,生(sheng)(sheng)產的無氧(yang)銅(tong)(tong)(tong)桿為(wei)鑄(zhu)(zhu)造組(zu)織,含(han)氧(yang)量(liang)一般在(zai)(zai)20ppm以下(xia)。由(you)于制造工藝的不同,所以在(zai)(zai)組(zu)織結(jie)構、氧(yang)含(han)量(liang)分(fen)布、雜質的形(xing)式(shi)及(ji)分(fen)布等諸多(duo)(duo)方面有(you)較大差別。
一、拉制性能
銅桿(gan)(gan)的(de)(de)拉制(zhi)性能跟很多(duo)因素有關,如(ru)雜(za)質的(de)(de)含(han)量(liang)、氧含(han)量(liang)及分(fen)布、工藝控(kong)制(zhi)等(deng)。下面分(fen)別從(cong)以上幾個方面對銅桿(gan)(gan)的(de)(de)拉制(zhi)性能進行分(fen)析。
1、熔化(hua)方式對S等雜質的影響
連(lian)鑄(zhu)連(lian)軋(ya)生產銅(tong)桿(gan)主(zhu)要(yao)是通過(guo)(guo)氣體(ti)的燃(ran)燒使(shi)銅(tong)桿(gan)熔化,在燃(ran)燒的過(guo)(guo)程中,通過(guo)(guo)氧(yang)(yang)化和(he)揮發作用,可一定程度(du)減(jian)少(shao)部分雜質進入銅(tong)液,因(yin)此連(lian)鑄(zhu)連(lian)軋(ya)法對(dui)原料要(yao)求相對(dui)低一些。上引連(lian)鑄(zhu)生產無(wu)氧(yang)(yang)銅(tong)桿(gan),由于是用感應電爐熔化,電解銅(tong)表面的“銅(tong)綠”“銅(tong)豆”基本都熔入到銅(tong)液中。其中熔入的S對(dui)無(wu)氧(yang)(yang)銅(tong)桿(gan)塑性影(ying)響(xiang)極大,會(hui)增加拉絲(si)斷線率。
2、鑄造(zao)過程中雜質的進入
在生產過(guo)(guo)程(cheng)中(zhong),連鑄(zhu)連軋工(gong)藝需通過(guo)(guo)保溫爐、溜槽、中(zhong)間包轉運(yun)銅液(ye),相對容易造(zao)成(cheng)耐(nai)火(huo)材(cai)料(liao)的(de)(de)剝落,在軋制過(guo)(guo)程(cheng)中(zhong)需要(yao)通過(guo)(guo)軋輥,造(zao)成(cheng)鐵質的(de)(de)脫落,會給銅桿造(zao)成(cheng)外部夾雜。而熱(re)軋中(zhong)皮(pi)上和皮(pi)下氧(yang)化物的(de)(de)軋入,會給低氧(yang)桿的(de)(de)拉(la)絲造(zao)成(cheng)不利的(de)(de)影響。上引連鑄(zhu)法生產工(gong)藝流(liu)程(cheng)較短(duan),銅液(ye)是(shi)(shi)通過(guo)(guo)聯體爐內(nei)潛(qian)流(liu)式完成(cheng),對耐(nai)火(huo)材(cai)料(liao)的(de)(de)沖(chong)擊不大,結晶是(shi)(shi)通過(guo)(guo)石墨模內(nei)進(jin)行,所以過(guo)(guo)程(cheng)中(zhong)可能產生的(de)(de)污染源較少,雜質進(jin)入的(de)(de)機會較少。
O、S、P是與(yu)銅(tong)(tong)(tong)會生產化(hua)合物的元素。在(zai)熔(rong)(rong)態(tai)銅(tong)(tong)(tong)中,氧(yang)(yang)可以(yi)溶解(jie)一部分,但當銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)幾(ji)乎不溶解(jie)于(yu)銅(tong)(tong)(tong)中。熔(rong)(rong)態(tai)時所溶解(jie)的氧(yang)(yang),以(yi)銅(tong)(tong)(tong)=氧(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共晶(jing)體析出,分布在(zai)晶(jing)粒晶(jing)界(jie)處。銅(tong)(tong)(tong)-氧(yang)(yang)化(hua)亞銅(tong)(tong)(tong)共晶(jing)體的出現,顯著降低了(le)銅(tong)(tong)(tong)的塑(su)性。
硫可(ke)以溶解在熔體的銅中(zhong),但(dan)在室溫下,其(qi)溶解度幾乎(hu)降低(di)到零,它(ta)以硫化亞銅的形式出現在晶(jing)粒晶(jing)界(jie)處,會顯著(zhu)降低(di)銅的塑(su)性。
3、氧(yang)在低氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)中分布形式(shi)及(ji)其影響(xiang)
氧含(han)量(liang)對低氧銅桿的(de)拉線性(xing)能有著(zhu)明顯的(de)影(ying)響(xiang)。當氧含(han)量(liang)增加到(dao)最佳(jia)值時,銅桿的(de)斷線率(lv)最低。這是(shi)因為氧在與大(da)部分雜(za)質反應(ying)的(de)過程中都起到(dao)了清除器的(de)作用(yong)。適度的(de)氧還有利于去除銅液(ye)中的(de)氫,生成水蒸氣溢出,減(jian)少(shao)氣孔的(de)形成。最佳(jia)的(de)氧含(han)量(liang)為拉線工藝提供了最好的(de)條件(jian)。
低氧(yang)銅(tong)桿氧(yang)化(hua)物(wu)的(de)(de)分布(bu):在連(lian)續澆鑄中(zhong)凝固的(de)(de)最初階段,散(san)熱速(su)率和均(jun)勻(yun)冷卻是(shi)決定銅(tong)桿氧(yang)化(hua)物(wu)分布(bu)的(de)(de)主要(yao)因(yin)素。不均(jun)勻(yun)冷卻會引起銅(tong)桿內部結構本質上(shang)的(de)(de)差異,但(dan)后續的(de)(de)熱加工,柱狀晶通常會遭到破壞,使氧(yang)化(hua)亞銅(tong)顆粒細微化(hua)和均(jun)勻(yun)分布(bu)。氧(yang)化(hua)物(wu)顆粒聚集而產生的(de)(de)典(dian)型情況(kuang)是(shi)中(zhong)心(xin)爆裂(lie)。除(chu)氧(yang)化(hua)物(wu)顆粒分布(bu)的(de)(de)影響外,具(ju)有較小氧(yang)化(hua)物(wu)顆粒的(de)(de)銅(tong)桿顯示出較好的(de)(de)拉線(xian)特(te)性,較大的(de)(de)Cu2O顆粒容易造成應力集中(zhong)點而斷裂(lie)。
無氧(yang)(yang)(yang)銅(tong)(tong)(tong)含(han)氧(yang)(yang)(yang)量(liang)超(chao)標,銅(tong)(tong)(tong)桿(gan)(gan)變脆,延(yan)伸(shen)率(lv)下降(jiang),拉(la)伸(shen)式樣端口顯(xian)暗紅色,結晶組織疏松(song)。當氧(yang)(yang)(yang)含(han)量(liang)超(chao)出8ppm時,工藝性(xing)能變差,表現為鑄(zhu)造及(ji)拉(la)伸(shen)過程中斷桿(gan)(gan)及(ji)斷線率(lv)極具增高(gao)。這是由于氧(yang)(yang)(yang)能與銅(tong)(tong)(tong)生成氧(yang)(yang)(yang)化亞銅(tong)(tong)(tong)脆性(xing)相(xiang),形成銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化亞銅(tong)(tong)(tong)共晶體(ti),以網狀組織分(fen)布在(zai)(zai)境界上。這種脆性(xing)相(xiang)硬度高(gao),在(zai)(zai)冷變形時將會與銅(tong)(tong)(tong)機(ji)體(ti)脫(tuo)離,導(dao)致銅(tong)(tong)(tong)桿(gan)(gan)的機(ji)械性(xing)能下降(jiang),在(zai)(zai)后(hou)續加工中容易(yi)造成斷裂現象(xiang)。氧(yang)(yang)(yang)含(han)量(liang)高(gao)還能導(dao)致無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)導(dao)電率(lv)下降(jiang)。因此,必須嚴格(ge)控制上引連鑄(zhu)工藝及(ji)產品質量(liang)。
4、氫的影響
在(zai)上(shang)引連鑄中,氧含量控(kong)制較(jiao)低,氧化物的(de)副作用唄**降低,但(dan)氫(qing)的(de)影響(xiang)成(cheng)為較(jiao)顯著的(de)問(wen)題。吸氣后熔體(ti)中存在(zai)平衡反(fan)應:H2O(g)=[O]+2[H];
氣(qi)體及疏(shu)松是在結(jie)晶(jing)的(de)(de)(de)(de)(de)過(guo)程中(zhong)(zhong),氫(qing)從過(guo)飽和的(de)(de)(de)(de)(de)溶液(ye)中(zhong)(zhong)析(xi)(xi)(xi)(xi)出(chu)并聚集而(er)形(xing)成的(de)(de)(de)(de)(de)。在結(jie)晶(jing)前(qian)析(xi)(xi)(xi)(xi)出(chu)的(de)(de)(de)(de)(de)氫(qing)又可還原(yuan)氧化亞銅(tong)而(er)生成水氣(qi)泡(pao)。由于上引鑄(zhu)造的(de)(de)(de)(de)(de)特點是銅(tong)液(ye)自上而(er)下的(de)(de)(de)(de)(de)結(jie)晶(jing),形(xing)成的(de)(de)(de)(de)(de)液(ye)**形(xing)狀近似錐型。銅(tong)液(ye)結(jie)晶(jing)前(qian)析(xi)(xi)(xi)(xi)出(chu)的(de)(de)(de)(de)(de)氣(qi)體在上浮過(guo)程中(zhong)(zhong)被堵在凝(ning)固(gu)組織內,結(jie)晶(jing)時在鑄(zhu)桿內形(xing)成氣(qi)孔(kong)。上引的(de)(de)(de)(de)(de)含氣(qi)量少時,析(xi)(xi)(xi)(xi)出(chu)的(de)(de)(de)(de)(de)氫(qing)存在于晶(jing)界處,形(xing)成疏(shu)松;含氣(qi)量多時,則聚集成氣(qi)孔(kong),因此,氣(qi)孔(kong)和疏(shu)松是氫(qing)氣(qi)和水蒸氣(qi)兩(liang)者(zhe)形(xing)成的(de)(de)(de)(de)(de)。
氫來(lai)源(yuan)于上引生產過程中的各個工(gong)藝環節,如原(yuan)料電(dian)(dian)解銅(tong)的“銅(tong)綠(lv)”、輔料木炭**、氣候環境(jing)**、石墨結晶器未干燥(zao)等(deng)。因(yin)此,熔化爐中的銅(tong)液表面應(ying)(ying)覆蓋經烘烤的木炭,電(dian)(dian)解銅(tong)應(ying)(ying)盡量(liang)去除“銅(tong)綠(lv)”、“銅(tong)豆(dou)”“耳朵”,對提高無氧銅(tong)桿(gan)質量(liang)非常重(zhong)要。
在連(lian)鑄(zhu)連(lian)軋工藝中(zhong),往往采(cai)用適度控制氧含量來(lai)控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液(ye)(ye)在鑄造過程中(zhong)是自(zi)下而上結晶,銅(tong)液(ye)(ye)中(zhong)的氧和氫所產生的水(shui)蒸氣很(hen)容易上浮(fu)跑(pao)出,銅(tong)液(ye)(ye)中(zhong)的氫大部分能被有效去除,因(yin)而對銅(tong)桿的影響較小。
二、表面質量
在生(sheng)產電(dian)磁(ci)線(xian)等產品的過程中,對(dui)銅(tong)桿的表面質量(liang)也需(xu)提出要(yao)求(qiu)。需(xu)要(yao)拉制后(hou)的銅(tong)絲(si)表面無(wu)毛刺、銅(tong)粉少、無(wu)油污。并通(tong)過扭(niu)轉(zhuan)試驗測量(liang)表面銅(tong)粉的質量(liang)和扭(niu)轉(zhuan)后(hou)觀(guan)察(cha)銅(tong)桿的復原情況來(lai)判定其好壞。
在(zai)連(lian)鑄連(lian)軋(ya)(ya)(ya)過(guo)程(cheng)中(zhong)(zhong),從鑄造到(dao)軋(ya)(ya)(ya)制(zhi)前,溫度(du)高(gao)(gao),完全暴(bao)露于空氣中(zhong)(zhong),使鑄坯(pi)表面形成較(jiao)厚的氧(yang)化層,在(zai)軋(ya)(ya)(ya)制(zhi)過(guo)程(cheng)中(zhong)(zhong),隨著軋(ya)(ya)(ya)輥的轉動,氧(yang)化物(wu)顆粒軋(ya)(ya)(ya)入(ru)(ru)銅線表面。由(you)于氧(yang)化亞銅是高(gao)(gao)熔(rong)點(dian)脆性化合(he)物(wu),對于軋(ya)(ya)(ya)入(ru)(ru)較(jiao)深的氧(yang)化亞銅,當成條狀(zhuang)的聚集物(wu)遇模具拉伸時,就會是銅桿外表面產生毛(mao)刺,給后續的涂漆(qi)造成麻(ma)煩。
而上引連鑄工藝(yi)制造的(de)(de)無氧(yang)銅(tong)桿(gan)(gan),由于鑄造和冷卻(que)完全與氧(yang)隔絕(jue),后續(xu)亦無熱(re)軋過程,銅(tong)桿(gan)(gan)表面無軋入(ru)表面的(de)(de)氧(yang)化物(wu),質(zhi)量較好,拉制后銅(tong)粉少(shao),上述問題(ti)較少(shao)存在。
無氧銅桿(gan)(gan)也(ye)分進口設(she)(she)(she)備(bei)做(zuo)的和國(guo)產(chan)(chan)設(she)(she)(she)備(bei)做(zuo)的,但目前(qian)進口產(chan)(chan)品已無明顯(xian)優勢,銅桿(gan)(gan)產(chan)(chan)品出(chu)(chu)來后區別不是(shi)(shi)很大,只(zhi)要銅板選(xuan)的好(hao)(hao),生(sheng)產(chan)(chan)控制比較穩定(ding),國(guo)產(chan)(chan)設(she)(she)(she)備(bei)也(ye)能產(chan)(chan)出(chu)(chu)可(ke)拉(la)伸0.05的銅桿(gan)(gan).進口設(she)(she)(she)備(bei)一般是(shi)(shi)芬蘭奧(ao)托(tuo)昆(kun)普的設(she)(she)(she)備(bei),國(guo)產(chan)(chan)設(she)(she)(she)備(bei)最好(hao)(hao)的應該是(shi)(shi)上海的海軍(jun)廠的了,生(sheng)產(chan)(chan)時間最長,軍(jun)工(gong)企業,質(zhi)量可(ke)靠。
低氧銅桿進(jin)口設備國(guo)際主要有兩種,一種是美國(guo)南(nan)線設備,英文是SOUTHWIRE,國(guo)內廠(chang)家是南(nan)京(jing)華新,江西銅業,另(ling)一種是德國(guo)CONTIROD設備,國(guo)內廠(chang)家是常州金源(yuan),天(tian)津(jin)大無縫。
無(wu)(wu)氧(yang)(yang)(yang)及(ji)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)量上容(rong)易區別,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)是(shi)含(han)氧(yang)(yang)(yang)量在(zai)(zai)10-20個(ge)(ge)PPM以(yi)下,但(dan)(dan)目前有(you)的(de)(de)(de)(de)廠家只能(neng)做到50個(ge)(ge)PPM以(yi)下.低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)(ge)PPM,好(hao)(hao)的(de)(de)(de)(de)桿(gan)(gan)(gan)子(zi)一般含(han)氧(yang)(yang)(yang)量控制在(zai)(zai)250個(ge)(ge)PPM左右(you),無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)一般采取的(de)(de)(de)(de)是(shi)上引法,低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)連鑄連軋(ya),兩種產(chan)品相(xiang)對(dui)而言低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)漆包線性(xing) 能(neng)更適應些,如(ru)柔軟性(xing),回(hui)彈角,繞(rao)線性(xing)能(neng).但(dan)(dan)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)拉(la)(la)絲(si)條件(jian)相(xiang)對(dui)要苛(ke)刻些,同樣拉(la)(la)伸0.2的(de)(de)(de)(de)細(xi)絲(si),如(ru)果伸線條件(jian)不好(hao)(hao),普(pu)通的(de)(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)(la)而好(hao)(hao)的(de)(de)(de)(de)低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就斷 線,但(dan)(dan)如(ru)果放在(zai)(zai)好(hao)(hao)的(de)(de)(de)(de)伸線條件(jian),同樣的(de)(de)(de)(de)桿(gan)(gan)(gan)子(zi),低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不定就能(neng)拉(la)(la)到雙(shuang)零五,而普(pu)通無(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)最多只能(neng)拉(la)(la)伸到0.1而已,當(dang)然做的(de)(de)(de)(de)最細(xi)的(de)(de)(de)(de)如(ru)雙(shuang)零二卻非得依(yi)靠進(jin)口的(de)(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)了(le).目前有(you)企(qi)業嘗試用剝皮的(de)(de)(de)(de)方(fang)式來(lai)處理低(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來(lai)伸0.03線.但(dan)(dan)有(you)關這方(fang)面的(de)(de)(de)(de)內(nei)容(rong)我(wo)還不是(shi)很(hen)清楚。
音響線(xian)一(yi)般反而喜(xi)歡用無(wu)(wu)氧桿,這和無(wu)(wu)氧桿是單晶銅,低氧桿是多晶銅有關。
氧銅(tong)桿和無氧銅(tong)桿由于制造(zao)方法的(de)不同,致使存(cun)在差別(bie),具有各自的(de)特點。
一、關于氧的吸(xi)入和脫去以及它的存在(zai)狀態
生(sheng)產銅(tong)(tong)(tong)(tong)桿的(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)(liang)一(yi)般在(zai)10—50ppm,在(zai)常(chang)(chang)(chang)溫下(xia)氧(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)(de)固溶度(du)約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)(liang)一(yi)般在(zai)200(175)—400(450)ppm,因(yin)此(ci)氧(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)(de)進入(ru)是(shi)在(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)液態下(xia)吸(xi)入(ru)的(de)(de)(de)(de)(de)(de),而(er)(er)上引法無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿則(ze)相(xiang)(xiang)反,氧(yang)(yang)(yang)(yang)在(zai)液態銅(tong)(tong)(tong)(tong)下(xia)保(bao)持相(xiang)(xiang)當時間后,被還(huan)原而(er)(er)脫(tuo)去(qu),通常(chang)(chang)(chang)這種桿的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量(liang)(liang)都在(zai)10—50ppm以下(xia),最低(di)(di)(di)可(ke)達1-2ppm,從組織上看,低(di)(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態,存(cun)在(zai)于晶粒邊(bian)界附近,這對低(di)(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿而(er)(er)言可(ke)以說(shuo)是(shi)常(chang)(chang)(chang)見的(de)(de)(de)(de)(de)(de)但對無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿則(ze)很少(shao)見。氧(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以夾雜形式在(zai)晶界出現對材料的(de)(de)(de)(de)(de)(de)韌性(xing)(xing)產生(sheng)負面影響(xiang)。而(er)(er)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)很低(di)(di)(di),所以這種銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)組織是(shi)均勻的(de)(de)(de)(de)(de)(de)單相(xiang)(xiang)組織對韌性(xing)(xing)有(you)利。在(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)(de)多孔性(xing)(xing)是(shi)不常(chang)(chang)(chang)見的(de)(de)(de)(de)(de)(de),而(er)(er)在(zai)低(di)(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿中(zhong)(zhong)(zhong)則(ze)是(shi)常(chang)(chang)(chang)見的(de)(de)(de)(de)(de)(de)一(yi)種缺陷(xian)。
二、熱軋組(zu)織和鑄造(zao)組(zu)織的區別
低氧(yang)銅(tong)(tong)桿由(you)于經過熱(re)軋,所以(yi)其組織(zhi)(zhi)屬熱(re)加工(gong)組織(zhi)(zhi),原來的(de)(de)鑄(zhu)造(zao)組織(zhi)(zhi)已經破碎,在(zai)(zai)8mm的(de)(de)桿時已有(you)再(zai)(zai)結晶(jing)(jing)的(de)(de)形式出現,而(er)無(wu)(wu)氧(yang)銅(tong)(tong)桿屬鑄(zhu)造(zao)組織(zhi)(zhi),晶(jing)(jing)粒(li)粗大,這(zhe)是(shi)為什么,無(wu)(wu)氧(yang)銅(tong)(tong)的(de)(de)再(zai)(zai)結晶(jing)(jing)溫度較(jiao)高(gao),需(xu)要較(jiao)高(gao)退火(huo)(huo)(huo)溫度的(de)(de)固有(you)原因(yin)。這(zhe)是(shi)因(yin)為,再(zai)(zai)結晶(jing)(jing)發(fa)生在(zai)(zai)晶(jing)(jing)粒(li)邊界(jie)附近,無(wu)(wu)氧(yang)銅(tong)(tong)桿組織(zhi)(zhi)晶(jing)(jing)粒(li)粗大,晶(jing)(jing)粒(li)尺寸甚至(zhi)能(neng)達幾(ji)個毫米,因(yin)而(er)晶(jing)(jing)粒(li)邊界(jie)少,即使通過拉制變形,但(dan)晶(jing)(jing)粒(li)邊界(jie)相對低氧(yang)銅(tong)(tong)桿還是(shi)較(jiao)少,所以(yi)需(xu)要較(jiao)高(gao)的(de)(de)退火(huo)(huo)(huo)功率(lv)。對無(wu)(wu)氧(yang)銅(tong)(tong)成功的(de)(de)退火(huo)(huo)(huo)要求是(shi):由(you)桿經拉制,但(dan)尚(shang)未鑄(zhu)造(zao)組織(zhi)(zhi)的(de)(de)線時的(de)(de)第一次退火(huo)(huo)(huo),其退火(huo)(huo)(huo)功率(lv)應比同(tong)樣(yang)情況(kuang)的(de)(de)低氧(yang)銅(tong)(tong)高(gao)10——15%。經繼續拉制,在(zai)(zai)以(yi)后(hou)階段的(de)(de)退火(huo)(huo)(huo)功率(lv)應留有(you)足夠的(de)(de)余量和對低氧(yang)銅(tong)(tong)和無(wu)(wu)氧(yang)銅(tong)(tong)切實(shi)區別執行不同(tong)的(de)(de)退火(huo)(huo)(huo)工(gong)藝,以(yi)保證在(zai)(zai)制品和成品導線的(de)(de)柔軟性。
三、夾雜,氧含(han)量波動,表面氧化(hua)物(wu)和可能(neng)存在的熱軋缺(que)陷的差(cha)別
無(wu)氧(yang)銅(tong)桿(gan)(gan)的(de)(de)可拉性在(zai)(zai)所有線徑里與低氧(yang)銅(tong)桿(gan)(gan)相(xiang)比都(dou)是優越的(de)(de),除上述組(zu)織(zhi)原因外,無(wu)氧(yang)銅(tong)桿(gan)(gan)夾雜少,含(han)氧(yang)量穩(wen)定(ding),無(wu)熱軋可能(neng)(neng)(neng)產(chan)(chan)生的(de)(de)缺陷,桿(gan)(gan)表(biao)氧(yang)化物厚度可達≤15A。在(zai)(zai)連(lian)鑄連(lian)軋生產(chan)(chan)過程中(zhong)(zhong)如果(guo)工藝不穩(wen)定(ding),對(dui)氧(yang)監控不嚴,含(han)氧(yang)量不穩(wen)定(ding)將直接影(ying)響(xiang)桿(gan)(gan)的(de)(de)性能(neng)(neng)(neng)。如果(guo)桿(gan)(gan)的(de)(de)表(biao)面氧(yang)化物能(neng)(neng)(neng)在(zai)(zai)后工序的(de)(de)連(lian)續清洗中(zhong)(zhong)得以彌補(bu)外,但(dan)比較麻煩(fan)的(de)(de)是有相(xiang)當多的(de)(de)氧(yang)化物存在(zai)(zai)于“皮(pi)下”,對(dui)拉線斷(duan)線影(ying)響(xiang)更直接,故而在(zai)(zai)拉制微(wei)細(xi)線,超(chao)微(wei)細(xi)線時,為了減少斷(duan)線,有時要對(dui)銅(tong)桿(gan)(gan)采(cai)取不得已(yi)的(de)(de)辦(ban)法——剝皮(pi),甚(shen)至二(er)次剝皮(pi)的(de)(de)原因所在(zai)(zai),目的(de)(de)要除去皮(pi)下氧(yang)化物。
四、低氧(yang)銅桿和(he)無氧(yang)銅桿的(de)韌性(xing)有(you)差(cha)別
兩(liang)者都(dou)可(ke)以拉(la)到0.015mm,但在(zai)低(di)溫超導線中(zhong)的低(di)溫級無氧銅,其細絲間(jian)的間(jian)距只有0.001mm.
五、從(cong)制桿的原材料到制線(xian)的經濟性有差別。
制造無(wu)氧銅(tong)桿要求質量較高的(de)原材料。一般(ban),拉制直(zhi)徑(jing)>1mm的(de)銅(tong)線時,低(di)氧銅(tong)桿的(de)優(you)點比(bi)較明顯,而無(wu)氧銅(tong)桿顯得更(geng)為優(you)越的(de)是拉制直(zhi)徑(jing)<0.5mm的(de)銅(tong)線。
六、低氧銅桿(gan)的制線工藝(yi)與無氧銅桿(gan)的有(you)所不(bu)同。
低氧銅(tong)桿的(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)不能照(zhao)搬到無(wu)氧銅(tong)桿的(de)制(zhi)(zhi)線(xian)工(gong)(gong)藝(yi)上來,至少兩(liang)者的(de)退(tui)火(huo)工(gong)(gong)藝(yi)是不同的(de)。因為線(xian)的(de)柔軟性深受材料成(cheng)份和制(zhi)(zhi)桿,制(zhi)(zhi)線(xian)和退(tui)火(huo)工(gong)(gong)藝(yi)的(de)影響,不能簡單地說(shuo)低氧銅(tong)或無(wu)氧銅(tong)誰軟誰硬。
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