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太平電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業動態 閱讀:109453 發布時間:2019-07-05

導讀:由于生產銅桿的兩者的工(gong)藝不同(tong),所生產的銅桿中(zhong)的含(han)氧量及外觀就不同(tong)。上(shang)引生產的銅桿,工(gong)藝得當氧含(han)量在10ppm以下(xia)(xia),叫無氧銅桿;連(lian)(lian)鑄連(lian)(lian)鑄生產的銅桿 是在保護條件(jian)下(xia)(xia)的熱軋,氧含(han)量在200-500ppm范圍內,但有時(shi)也(ye)高達700ppm以上(shang),一般情況(kuang)下(xia)(xia),此種方法生產的銅外表光(guang)亮,低氧銅桿,有時(shi)也(ye)叫光(guang)桿。

銅(tong)桿(gan)是(shi)電(dian)纜行(xing)(xing)(xing)業的(de)(de)(de)主(zhu)要原(yuan)料,生(sheng)產(chan)(chan)的(de)(de)(de)方(fang)式主(zhu)要有兩種(zhong)——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)法(fa)和上(shang)(shang)引(yin)連(lian)鑄(zhu)(zhu)法(fa)。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)低氧銅(tong)桿(gan)的(de)(de)(de)生(sheng)產(chan)(chan)方(fang)法(fa)較(jiao)多,其特點是(shi)金屬(shu)在(zai)豎爐中(zhong)融化后,銅(tong)液通過(guo)保溫(wen)爐、溜(liu)槽、中(zhong)間(jian)包,從澆(jiao)管(guan)進入封閉的(de)(de)(de)模腔內(nei),采(cai)用(yong)較(jiao)大(da)的(de)(de)(de)冷(leng)(leng)卻強(qiang)度進行(xing)(xing)(xing)冷(leng)(leng)卻,形成(cheng)鑄(zhu)(zhu)坯,然后進行(xing)(xing)(xing)多道(dao)次軋(ya)(ya)制,生(sheng)產(chan)(chan)的(de)(de)(de)低氧銅(tong)桿(gan)為熱加工組織,原(yuan)來(lai)的(de)(de)(de)鑄(zhu)(zhu)造(zao)組織已(yi)經(jing)破(po)碎(sui),含氧量一般為200~400ppm之間(jian)。無(wu)氧銅(tong)桿(gan)國(guo)內(nei)基本全部(bu)采(cai)用(yong)上(shang)(shang)引(yin)連(lian)鑄(zhu)(zhu)法(fa)生(sheng)產(chan)(chan),金屬(shu)在(zai)感應電(dian)爐中(zhong)融化后通過(guo)石(shi)墨(mo)模進行(xing)(xing)(xing)上(shang)(shang)引(yin)連(lian)續鑄(zhu)(zhu)造(zao),之后進行(xing)(xing)(xing)冷(leng)(leng)軋(ya)(ya)或冷(leng)(leng)加工,生(sheng)產(chan)(chan)的(de)(de)(de)無(wu)氧銅(tong)桿(gan)為鑄(zhu)(zhu)造(zao)組織,含氧量一般在(zai)20ppm以(yi)下。由(you)于制造(zao)工藝的(de)(de)(de)不同,所以(yi)在(zai)組織結構、氧含量分(fen)布(bu)、雜(za)質的(de)(de)(de)形式及分(fen)布(bu)等(deng)諸多方(fang)面有較(jiao)大(da)差別。

一、拉制性能

銅(tong)桿(gan)(gan)的(de)(de)拉制性(xing)能跟很多(duo)因素有(you)關(guan),如(ru)雜質(zhi)的(de)(de)含(han)量、氧含(han)量及分布、工藝(yi)控制等。下面(mian)分別從以上幾個方面(mian)對銅(tong)桿(gan)(gan)的(de)(de)拉制性(xing)能進行(xing)分析。

1、熔化方(fang)式對S等雜質的影響(xiang)

連(lian)鑄連(lian)軋生(sheng)產(chan)銅(tong)桿主要是通過(guo)氣體的(de)(de)燃(ran)燒(shao)使銅(tong)桿熔(rong)化(hua),在燃(ran)燒(shao)的(de)(de)過(guo)程中,通過(guo)氧化(hua)和揮發作(zuo)用,可一定程度減少部分(fen)雜(za)質(zhi)進入銅(tong)液,因此(ci)連(lian)鑄連(lian)軋法(fa)對(dui)原料(liao)要求相對(dui)低一些。上(shang)引(yin)連(lian)鑄生(sheng)產(chan)無氧銅(tong)桿,由于是用感應(ying)電(dian)爐熔(rong)化(hua),電(dian)解銅(tong)表面的(de)(de)“銅(tong)綠”“銅(tong)豆”基(ji)本都熔(rong)入到銅(tong)液中。其中熔(rong)入的(de)(de)S對(dui)無氧銅(tong)桿塑性影響極(ji)大,會(hui)增加拉絲斷線率。

2、鑄(zhu)造(zao)過程中雜(za)質的進入(ru)

在生產(chan)過(guo)程中(zhong)(zhong),連鑄(zhu)連軋(ya)(ya)工藝(yi)(yi)需通(tong)過(guo)保溫爐、溜槽(cao)、中(zhong)(zhong)間(jian)包轉運銅液,相對容易造(zao)成(cheng)耐火(huo)材料(liao)(liao)的(de)剝(bo)落,在軋(ya)(ya)制過(guo)程中(zhong)(zhong)需要通(tong)過(guo)軋(ya)(ya)輥,造(zao)成(cheng)鐵(tie)質的(de)脫落,會給銅桿造(zao)成(cheng)外部夾雜。而(er)熱(re)軋(ya)(ya)中(zhong)(zhong)皮(pi)上(shang)和皮(pi)下氧化物(wu)的(de)軋(ya)(ya)入(ru),會給低氧桿的(de)拉絲(si)造(zao)成(cheng)不利的(de)影響。上(shang)引連鑄(zhu)法生產(chan)工藝(yi)(yi)流程較(jiao)短,銅液是通(tong)過(guo)聯體(ti)爐內潛流式(shi)完成(cheng),對耐火(huo)材料(liao)(liao)的(de)沖擊不大,結(jie)晶是通(tong)過(guo)石墨模內進行,所(suo)以過(guo)程中(zhong)(zhong)可能產(chan)生的(de)污染源(yuan)較(jiao)少(shao),雜質進入(ru)的(de)機會較(jiao)少(shao)。

O、S、P是與銅(tong)(tong)(tong)會(hui)生產化合物的(de)元素。在熔態銅(tong)(tong)(tong)中,氧(yang)可(ke)以溶(rong)解一部分,但當銅(tong)(tong)(tong)冷凝時,氧(yang)幾乎不溶(rong)解于銅(tong)(tong)(tong)中。熔態時所溶(rong)解的(de)氧(yang),以銅(tong)(tong)(tong)=氧(yang)化亞銅(tong)(tong)(tong)共晶體(ti)析出(chu),分布在晶粒晶界處。銅(tong)(tong)(tong)-氧(yang)化亞銅(tong)(tong)(tong)共晶體(ti)的(de)出(chu)現(xian),顯著降低了銅(tong)(tong)(tong)的(de)塑性。

硫可以(yi)溶解在熔(rong)體的銅(tong)中,但在室溫(wen)下,其溶解度幾乎降(jiang)低到(dao)零,它(ta)以(yi)硫化亞銅(tong)的形式(shi)出現在晶(jing)粒晶(jing)界處(chu),會(hui)顯著(zhu)降(jiang)低銅(tong)的塑(su)性(xing)。

3、氧在低氧銅桿和無氧銅桿中分布(bu)形式及其影響

氧(yang)(yang)含量(liang)對低(di)氧(yang)(yang)銅桿的(de)(de)拉線性能有著明顯的(de)(de)影(ying)響。當氧(yang)(yang)含量(liang)增加到最(zui)佳值時,銅桿的(de)(de)斷線率最(zui)低(di)。這是(shi)因為氧(yang)(yang)在與(yu)大(da)部分雜質反應(ying)的(de)(de)過程(cheng)中都(dou)起到了清除器的(de)(de)作(zuo)用。適(shi)度的(de)(de)氧(yang)(yang)還(huan)有利于(yu)去除銅液(ye)中的(de)(de)氫,生成水蒸氣溢出,減少氣孔的(de)(de)形成。最(zui)佳的(de)(de)氧(yang)(yang)含量(liang)為拉線工藝提供了最(zui)好的(de)(de)條件。

低氧(yang)(yang)銅桿(gan)氧(yang)(yang)化(hua)物(wu)(wu)(wu)的(de)(de)(de)(de)分(fen)布:在連(lian)續澆鑄(zhu)中(zhong)凝固的(de)(de)(de)(de)最初階段,散熱速率和均(jun)勻冷(leng)卻是(shi)決定銅桿(gan)氧(yang)(yang)化(hua)物(wu)(wu)(wu)分(fen)布的(de)(de)(de)(de)主要因素。不均(jun)勻冷(leng)卻會引起銅桿(gan)內部結構本質上的(de)(de)(de)(de)差異,但后續的(de)(de)(de)(de)熱加工(gong),柱狀(zhuang)晶通(tong)常會遭(zao)到破壞,使氧(yang)(yang)化(hua)亞銅顆(ke)(ke)粒細微(wei)化(hua)和均(jun)勻分(fen)布。氧(yang)(yang)化(hua)物(wu)(wu)(wu)顆(ke)(ke)粒聚集(ji)而(er)產生的(de)(de)(de)(de)典型情況是(shi)中(zhong)心爆(bao)裂。除氧(yang)(yang)化(hua)物(wu)(wu)(wu)顆(ke)(ke)粒分(fen)布的(de)(de)(de)(de)影(ying)響外,具(ju)有較(jiao)小氧(yang)(yang)化(hua)物(wu)(wu)(wu)顆(ke)(ke)粒的(de)(de)(de)(de)銅桿(gan)顯(xian)示出(chu)較(jiao)好的(de)(de)(de)(de)拉線特性,較(jiao)大的(de)(de)(de)(de)Cu2O顆(ke)(ke)粒容(rong)易(yi)造成應力(li)集(ji)中(zhong)點而(er)斷裂。

無氧(yang)(yang)銅含氧(yang)(yang)量(liang)超(chao)標,銅桿(gan)變脆,延伸(shen)率下(xia)(xia)(xia)降(jiang),拉伸(shen)式樣端口(kou)顯暗(an)紅色,結晶組織(zhi)(zhi)疏松。當(dang)氧(yang)(yang)含量(liang)超(chao)出8ppm時,工(gong)(gong)藝性(xing)能變差,表現為(wei)鑄造(zao)及拉伸(shen)過程中斷桿(gan)及斷線(xian)率極(ji)具(ju)增高。這是(shi)由于氧(yang)(yang)能與(yu)銅生(sheng)成氧(yang)(yang)化亞(ya)(ya)銅脆性(xing)相,形成銅-氧(yang)(yang)化亞(ya)(ya)銅共晶體(ti),以網狀組織(zhi)(zhi)分布在(zai)境界上(shang)。這種(zhong)脆性(xing)相硬(ying)度高,在(zai)冷變形時將(jiang)會與(yu)銅機體(ti)脫離(li),導(dao)(dao)致(zhi)銅桿(gan)的機械(xie)性(xing)能下(xia)(xia)(xia)降(jiang),在(zai)后續加工(gong)(gong)中容易造(zao)成斷裂(lie)現象(xiang)。氧(yang)(yang)含量(liang)高還能導(dao)(dao)致(zhi)無氧(yang)(yang)銅桿(gan)導(dao)(dao)電率下(xia)(xia)(xia)降(jiang)。因此,必(bi)須嚴格控制上(shang)引(yin)連(lian)鑄工(gong)(gong)藝及產品質(zhi)量(liang)。

4、氫的影響

在上引連鑄中,氧(yang)含量(liang)控制較低,氧(yang)化物的副(fu)作用唄**降低,但氫的影(ying)響成(cheng)為較顯著的問題。吸氣后熔(rong)體中存在平衡反應(ying):H2O(g)=[O]+2[H];

氣(qi)體及疏(shu)松是在(zai)(zai)結(jie)晶(jing)的(de)過程中,氫(qing)從過飽和(he)的(de)溶液(ye)中析出(chu)并聚集而形成(cheng)的(de)。在(zai)(zai)結(jie)晶(jing)前析出(chu)的(de)氫(qing)又可還原氧化亞銅(tong)而生成(cheng)水(shui)氣(qi)泡。由于上(shang)(shang)引鑄造的(de)特點是銅(tong)液(ye)自上(shang)(shang)而下的(de)結(jie)晶(jing),形成(cheng)的(de)液(ye)**形狀近似錐型。銅(tong)液(ye)結(jie)晶(jing)前析出(chu)的(de)氣(qi)體在(zai)(zai)上(shang)(shang)浮過程中被堵在(zai)(zai)凝(ning)固(gu)組織內(nei),結(jie)晶(jing)時(shi)在(zai)(zai)鑄桿內(nei)形成(cheng)氣(qi)孔(kong)。上(shang)(shang)引的(de)含(han)氣(qi)量少時(shi),析出(chu)的(de)氫(qing)存在(zai)(zai)于晶(jing)界處(chu),形成(cheng)疏(shu)松;含(han)氣(qi)量多時(shi),則聚集成(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和(he)疏(shu)松是氫(qing)氣(qi)和(he)水(shui)蒸氣(qi)兩者形成(cheng)的(de)。

氫來源于上引生(sheng)產過程中的各個工藝環節,如原料電解(jie)銅(tong)(tong)的“銅(tong)(tong)綠”、輔料木(mu)炭(tan)**、氣候環境(jing)**、石(shi)墨結晶器未(wei)干燥等。因此,熔化(hua)爐中的銅(tong)(tong)液表面應覆蓋經烘烤(kao)的木(mu)炭(tan),電解(jie)銅(tong)(tong)應盡(jin)量(liang)去除“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳朵”,對提高無氧銅(tong)(tong)桿質量(liang)非常重要。

在連鑄連軋工(gong)藝(yi)中(zhong),往往采用適度控(kong)制(zhi)氧含量來控(kong)制(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅液(ye)在(zai)鑄造(zao)過程中(zhong)是(shi)自(zi)下而(er)上結晶,銅液(ye)中(zhong)的(de)氧和氫所(suo)產生的(de)水(shui)蒸氣(qi)很容易上浮跑出,銅液(ye)中(zhong)的(de)氫大部分(fen)能被有效(xiao)去除,因而(er)對銅桿(gan)的(de)影響較小。

二、表面質量

在(zai)生產電磁線等產品(pin)的過(guo)程中(zhong),對銅(tong)桿(gan)的表(biao)面(mian)(mian)質量(liang)也(ye)需提出(chu)要求。需要拉(la)制后的銅(tong)絲(si)表(biao)面(mian)(mian)無毛刺、銅(tong)粉少、無油污。并通過(guo)扭(niu)轉試驗測(ce)量(liang)表(biao)面(mian)(mian)銅(tong)粉的質量(liang)和扭(niu)轉后觀察(cha)銅(tong)桿(gan)的復原情(qing)況來(lai)判定其好壞。

在(zai)(zai)連(lian)(lian)鑄連(lian)(lian)軋(ya)(ya)(ya)過程中,從鑄造到軋(ya)(ya)(ya)制前,溫度(du)高,完(wan)全暴露于(yu)空氣中,使鑄坯表面(mian)(mian)形(xing)成(cheng)較厚(hou)的氧化層,在(zai)(zai)軋(ya)(ya)(ya)制過程中,隨著軋(ya)(ya)(ya)輥的轉動,氧化物顆粒軋(ya)(ya)(ya)入銅(tong)線(xian)表面(mian)(mian)。由于(yu)氧化亞銅(tong)是(shi)高熔點脆性化合物,對于(yu)軋(ya)(ya)(ya)入較深的氧化亞銅(tong),當成(cheng)條狀(zhuang)的聚集(ji)物遇模具(ju)拉伸時(shi),就會是(shi)銅(tong)桿外(wai)表面(mian)(mian)產生(sheng)毛刺,給后續的涂漆造成(cheng)麻(ma)煩。

而上引(yin)連鑄工藝制(zhi)造的(de)(de)無氧銅桿,由(you)于(yu)鑄造和(he)冷卻完全(quan)與氧隔(ge)絕(jue),后續亦(yi)無熱(re)軋過程(cheng),銅桿表面無軋入(ru)表面的(de)(de)氧化物,質量較(jiao)好(hao),拉制(zhi)后銅粉少,上述問(wen)題較(jiao)少存(cun)在。

無氧銅(tong)(tong)桿也(ye)分進(jin)口設(she)(she)備(bei)做(zuo)的(de)(de)(de)(de)(de)和國(guo)產(chan)設(she)(she)備(bei)做(zuo)的(de)(de)(de)(de)(de),但目前進(jin)口產(chan)品(pin)已無明顯優勢,銅(tong)(tong)桿產(chan)品(pin)出(chu)來后(hou)區別不是很(hen)大(da),只(zhi)要銅(tong)(tong)板選的(de)(de)(de)(de)(de)好,生產(chan)控(kong)制比較穩定,國(guo)產(chan)設(she)(she)備(bei)也(ye)能產(chan)出(chu)可拉(la)伸0.05的(de)(de)(de)(de)(de)銅(tong)(tong)桿.進(jin)口設(she)(she)備(bei)一般是芬蘭奧托昆普的(de)(de)(de)(de)(de)設(she)(she)備(bei),國(guo)產(chan)設(she)(she)備(bei)最(zui)好的(de)(de)(de)(de)(de)應該(gai)是上(shang)海的(de)(de)(de)(de)(de)海軍廠的(de)(de)(de)(de)(de)了,生產(chan)時間最(zui)長,軍工企業,質量可靠。

低氧(yang)銅桿進口設備(bei)國(guo)(guo)際主(zhu)要有兩(liang)種(zhong),一(yi)(yi)種(zhong)是美國(guo)(guo)南線設備(bei),英文是SOUTHWIRE,國(guo)(guo)內廠家是南京華(hua)新,江(jiang)西(xi)銅業,另一(yi)(yi)種(zhong)是德(de)國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內廠家是常州(zhou)金(jin)源(yuan),天津大無縫。

無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上容易(yi)區別,無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)是(shi)(shi)含氧(yang)(yang)(yang)量在(zai)(zai)10-20個PPM以(yi)下(xia),但(dan)(dan)目前(qian)有(you)的(de)(de)(de)(de)廠家只能做(zuo)(zuo)到50個PPM以(yi)下(xia).低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)在(zai)(zai) 200-400個PPM,好的(de)(de)(de)(de)桿(gan)(gan)(gan)子一般含氧(yang)(yang)(yang)量控制在(zai)(zai)250個PPM左(zuo)右,無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)一般采取(qu)的(de)(de)(de)(de)是(shi)(shi)上引法,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)是(shi)(shi)連鑄(zhu)連軋,兩種產品相對而(er)(er)言低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對漆包線(xian)性(xing) 能更適(shi)應些,如柔軟性(xing),回(hui)彈角,繞(rao)線(xian)性(xing)能.但(dan)(dan)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)對拉絲條(tiao)件相對要苛刻些,同樣(yang)拉伸(shen)0.2的(de)(de)(de)(de)細(xi)(xi)絲,如果伸(shen)線(xian)條(tiao)件不(bu)好,普通的(de)(de)(de)(de)無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)可拉而(er)(er)好的(de)(de)(de)(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)就斷(duan) 線(xian),但(dan)(dan)如果放在(zai)(zai)好的(de)(de)(de)(de)伸(shen)線(xian)條(tiao)件,同樣(yang)的(de)(de)(de)(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)說不(bu)定(ding)就能拉到雙零五(wu),而(er)(er)普通無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)最多只能拉伸(shen)到0.1而(er)(er)已(yi),當然做(zuo)(zuo)的(de)(de)(de)(de)最細(xi)(xi)的(de)(de)(de)(de)如雙零二卻非得依靠進口的(de)(de)(de)(de) 無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)了.目前(qian)有(you)企業嘗(chang)試(shi)用剝皮的(de)(de)(de)(de)方式來處(chu)理低(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)來伸(shen)0.03線(xian).但(dan)(dan)有(you)關這方面的(de)(de)(de)(de)內容我(wo)還不(bu)是(shi)(shi)很清楚。

音響線(xian)一般反而喜歡用無氧桿,這和(he)無氧桿是單晶銅(tong),低氧桿是多晶銅(tong)有關。

氧銅(tong)桿和無(wu)氧銅(tong)桿由于制(zhi)造(zao)方(fang)法的不同(tong),致使存在差別,具有各自的特點(dian)。

一、關于氧的吸入(ru)和(he)脫去以及它的存在(zai)狀態

生產銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一般在(zai)10—50ppm,在(zai)常(chang)溫(wen)下(xia)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一般在(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)進入是(shi)在(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)液(ye)態下(xia)吸入的(de)(de)(de),而(er)(er)(er)上引法無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則相(xiang)反,氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液(ye)態銅(tong)(tong)(tong)(tong)(tong)下(xia)保持相(xiang)當(dang)時間(jian)后,被還(huan)原而(er)(er)(er)脫去,通常(chang)這(zhe)種(zhong)桿(gan)(gan)(gan)的(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)量都在(zai)10—50ppm以下(xia),最低(di)可達1-2ppm,從(cong)組織(zhi)上看,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)狀態,存在(zai)于晶粒邊界(jie)附近,這(zhe)對低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)而(er)(er)(er)言可以說(shuo)是(shi)常(chang)見的(de)(de)(de)但(dan)對無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則很少見。氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)以夾雜形式在(zai)晶界(jie)出現對材(cai)料的(de)(de)(de)韌性產生負面影響。而(er)(er)(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)很低(di),所以這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)組織(zhi)是(shi)均勻的(de)(de)(de)單相(xiang)組織(zhi)對韌性有利。在(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中的(de)(de)(de)多孔性是(shi)不常(chang)見的(de)(de)(de),而(er)(er)(er)在(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中則是(shi)常(chang)見的(de)(de)(de)一種(zhong)缺陷(xian)。

二、熱軋(ya)組織(zhi)和鑄(zhu)造(zao)組織(zhi)的區別

低(di)氧銅桿(gan)由于經過熱(re)軋,所(suo)以(yi)(yi)其組織(zhi)屬(shu)熱(re)加工組織(zhi),原(yuan)來的(de)(de)鑄(zhu)造組織(zhi)已經破碎(sui),在(zai)8mm的(de)(de)桿(gan)時(shi)已有(you)再結(jie)晶的(de)(de)形式出現,而無氧銅桿(gan)屬(shu)鑄(zhu)造組織(zhi),晶粒(li)(li)(li)粗(cu)(cu)大(da),這是為什么,無氧銅的(de)(de)再結(jie)晶溫(wen)(wen)度較(jiao)(jiao)高,需(xu)要較(jiao)(jiao)高退(tui)火(huo)(huo)溫(wen)(wen)度的(de)(de)固有(you)原(yuan)因(yin)。這是因(yin)為,再結(jie)晶發生在(zai)晶粒(li)(li)(li)邊界(jie)附近(jin),無氧銅桿(gan)組織(zhi)晶粒(li)(li)(li)粗(cu)(cu)大(da),晶粒(li)(li)(li)尺(chi)寸甚至能達幾個毫(hao)米,因(yin)而晶粒(li)(li)(li)邊界(jie)少(shao),即使通過拉制(zhi)(zhi)變形,但(dan)(dan)晶粒(li)(li)(li)邊界(jie)相(xiang)對(dui)低(di)氧銅桿(gan)還是較(jiao)(jiao)少(shao),所(suo)以(yi)(yi)需(xu)要較(jiao)(jiao)高的(de)(de)退(tui)火(huo)(huo)功率。對(dui)無氧銅成功的(de)(de)退(tui)火(huo)(huo)要求是:由桿(gan)經拉制(zhi)(zhi),但(dan)(dan)尚(shang)未鑄(zhu)造組織(zhi)的(de)(de)線時(shi)的(de)(de)第一(yi)次(ci)退(tui)火(huo)(huo),其退(tui)火(huo)(huo)功率應比同樣情(qing)況的(de)(de)低(di)氧銅高10——15%。經繼續拉制(zhi)(zhi),在(zai)以(yi)(yi)后(hou)階(jie)段的(de)(de)退(tui)火(huo)(huo)功率應留(liu)有(you)足夠的(de)(de)余量(liang)和(he)對(dui)低(di)氧銅和(he)無氧銅切實區(qu)別執(zhi)行不同的(de)(de)退(tui)火(huo)(huo)工藝,以(yi)(yi)保證在(zai)制(zhi)(zhi)品和(he)成品導線的(de)(de)柔軟(ruan)性。

三、夾雜(za),氧含量波動,表(biao)面(mian)氧化物和可能存在的熱軋(ya)缺陷(xian)的差別

無(wu)(wu)氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)的(de)可拉(la)性在所有線(xian)徑(jing)里與低氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)相比都(dou)是優越的(de),除(chu)上述組織原(yuan)因(yin)外,無(wu)(wu)氧(yang)銅(tong)(tong)桿(gan)(gan)(gan)夾雜少,含氧(yang)量(liang)穩定,無(wu)(wu)熱軋可能(neng)產生(sheng)的(de)缺陷,桿(gan)(gan)(gan)表(biao)氧(yang)化(hua)(hua)物厚(hou)度可達(da)≤15A。在連鑄連軋生(sheng)產過程中(zhong)如(ru)果(guo)工(gong)藝不(bu)穩定,對(dui)(dui)氧(yang)監控不(bu)嚴,含氧(yang)量(liang)不(bu)穩定將直(zhi)(zhi)接(jie)影(ying)響桿(gan)(gan)(gan)的(de)性能(neng)。如(ru)果(guo)桿(gan)(gan)(gan)的(de)表(biao)面氧(yang)化(hua)(hua)物能(neng)在后工(gong)序的(de)連續清洗(xi)中(zhong)得(de)以彌補外,但比較麻煩(fan)的(de)是有相當多的(de)氧(yang)化(hua)(hua)物存在于“皮下”,對(dui)(dui)拉(la)線(xian)斷(duan)線(xian)影(ying)響更(geng)直(zhi)(zhi)接(jie),故而在拉(la)制(zhi)微細(xi)線(xian),超微細(xi)線(xian)時(shi),為了(le)減少斷(duan)線(xian),有時(shi)要(yao)對(dui)(dui)銅(tong)(tong)桿(gan)(gan)(gan)采(cai)取不(bu)得(de)已的(de)辦法——剝皮,甚(shen)至二次(ci)剝皮的(de)原(yuan)因(yin)所在,目的(de)要(yao)除(chu)去皮下氧(yang)化(hua)(hua)物。

四、低氧(yang)銅桿(gan)和無(wu)氧(yang)銅桿(gan)的(de)韌性有差別

兩(liang)者都可(ke)以(yi)拉(la)到0.015mm,但在(zai)低溫(wen)超導線中的(de)低溫(wen)級無(wu)氧銅,其細絲間(jian)的(de)間(jian)距(ju)只有0.001mm.

五(wu)、從制(zhi)桿的原材料到制(zhi)線的經濟性有差別(bie)。

制造(zao)無(wu)氧銅(tong)(tong)桿要求質量較(jiao)高的(de)原材料。一般(ban),拉(la)制直徑>1mm的(de)銅(tong)(tong)線時,低氧銅(tong)(tong)桿的(de)優點比較(jiao)明顯,而無(wu)氧銅(tong)(tong)桿顯得更為優越的(de)是(shi)拉(la)制直徑<0.5mm的(de)銅(tong)(tong)線。

六、低氧銅(tong)桿(gan)的制(zhi)線工藝與(yu)無氧銅(tong)桿(gan)的有所不同(tong)。

低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)制(zhi)線(xian)(xian)工(gong)藝(yi)不(bu)能照(zhao)搬到無氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)制(zhi)線(xian)(xian)工(gong)藝(yi)上(shang)來,至少兩者(zhe)的(de)(de)(de)(de)退火工(gong)藝(yi)是(shi)不(bu)同的(de)(de)(de)(de)。因為線(xian)(xian)的(de)(de)(de)(de)柔(rou)軟性深受材(cai)料成份(fen)和(he)制(zhi)桿(gan)(gan),制(zhi)線(xian)(xian)和(he)退火工(gong)藝(yi)的(de)(de)(de)(de)影響,不(bu)能簡(jian)單(dan)地說低(di)氧(yang)銅(tong)(tong)(tong)或無氧(yang)銅(tong)(tong)(tong)誰軟誰硬(ying)。