熱門關(guan)鍵(jian)詞:
來源:行業動態 閱讀:109537 發布時間(jian):2019-07-05
導讀:由(you)于生產(chan)銅(tong)桿(gan)(gan)的(de)兩者的(de)工藝(yi)不同,所生產(chan)的(de)銅(tong)桿(gan)(gan)中的(de)含氧量(liang)及外觀(guan)就不同。上引生產(chan)的(de)銅(tong)桿(gan)(gan),工藝(yi)得當氧含量(liang)在10ppm以(yi)下,叫無(wu)氧銅(tong)桿(gan)(gan);連鑄(zhu)連鑄(zhu)生產(chan)的(de)銅(tong)桿(gan)(gan) 是在保護條件(jian)下的(de)熱(re)軋,氧含量(liang)在200-500ppm范圍內(nei),但有時也(ye)高達(da)700ppm以(yi)上,一般情況下,此種方(fang)法生產(chan)的(de)銅(tong)外表光亮,低氧銅(tong)桿(gan)(gan),有時也(ye)叫光桿(gan)(gan)。
銅(tong)(tong)桿是(shi)電纜行(xing)業的(de)(de)(de)(de)(de)主要原(yuan)料,生(sheng)產(chan)的(de)(de)(de)(de)(de)方(fang)式主要有兩種——連(lian)(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)(lian)軋法和上引連(lian)(lian)(lian)鑄(zhu)(zhu)法。連(lian)(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)(lian)軋低氧(yang)銅(tong)(tong)桿的(de)(de)(de)(de)(de)生(sheng)產(chan)方(fang)法較多,其特(te)點是(shi)金屬在(zai)豎爐(lu)中(zhong)融(rong)化后(hou),銅(tong)(tong)液通過(guo)保溫爐(lu)、溜槽、中(zhong)間包,從澆(jiao)管進入(ru)封(feng)閉(bi)的(de)(de)(de)(de)(de)模腔內,采用較大的(de)(de)(de)(de)(de)冷(leng)卻強(qiang)度進行(xing)冷(leng)卻,形成鑄(zhu)(zhu)坯(pi),然后(hou)進行(xing)多道次軋制,生(sheng)產(chan)的(de)(de)(de)(de)(de)低氧(yang)銅(tong)(tong)桿為(wei)(wei)熱加(jia)工組(zu)織(zhi),原(yuan)來的(de)(de)(de)(de)(de)鑄(zhu)(zhu)造組(zu)織(zhi)已(yi)經破碎(sui),含(han)氧(yang)量一(yi)般為(wei)(wei)200~400ppm之間。無氧(yang)銅(tong)(tong)桿國內基本(ben)全(quan)部采用上引連(lian)(lian)(lian)鑄(zhu)(zhu)法生(sheng)產(chan),金屬在(zai)感應電爐(lu)中(zhong)融(rong)化后(hou)通過(guo)石墨模進行(xing)上引連(lian)(lian)(lian)續鑄(zhu)(zhu)造,之后(hou)進行(xing)冷(leng)軋或冷(leng)加(jia)工,生(sheng)產(chan)的(de)(de)(de)(de)(de)無氧(yang)銅(tong)(tong)桿為(wei)(wei)鑄(zhu)(zhu)造組(zu)織(zhi),含(han)氧(yang)量一(yi)般在(zai)20ppm以下。由于(yu)制造工藝的(de)(de)(de)(de)(de)不同,所以在(zai)組(zu)織(zhi)結構、氧(yang)含(han)量分(fen)(fen)布、雜質的(de)(de)(de)(de)(de)形式及分(fen)(fen)布等諸多方(fang)面有較大差別。
一、拉制性能
銅桿(gan)的拉制(zhi)(zhi)性能跟很多因(yin)素有關,如雜質的含(han)量(liang)、氧含(han)量(liang)及分布、工藝控制(zhi)(zhi)等。下面(mian)(mian)分別(bie)從(cong)以(yi)上幾個方面(mian)(mian)對(dui)銅桿(gan)的拉制(zhi)(zhi)性能進(jin)行(xing)分析(xi)。
1、熔化方式(shi)對S等雜質的影響
連鑄(zhu)連軋生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)主要(yao)是通(tong)過氣體(ti)的(de)(de)燃燒使銅(tong)(tong)(tong)(tong)桿(gan)(gan)熔(rong)化,在燃燒的(de)(de)過程中,通(tong)過氧(yang)化和揮發作用,可一定程度減少部(bu)分雜質(zhi)進入銅(tong)(tong)(tong)(tong)液,因(yin)此連鑄(zhu)連軋法(fa)對(dui)原料要(yao)求相對(dui)低一些(xie)。上引連鑄(zhu)生產無氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan),由于是用感(gan)應電爐熔(rong)化,電解銅(tong)(tong)(tong)(tong)表面的(de)(de)“銅(tong)(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)(tong)豆”基本都(dou)熔(rong)入到銅(tong)(tong)(tong)(tong)液中。其中熔(rong)入的(de)(de)S對(dui)無氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)塑性影響極(ji)大,會增加拉絲斷線率(lv)。
2、鑄造過程中雜質的(de)進入
在生(sheng)產過(guo)(guo)(guo)程中(zhong),連(lian)鑄(zhu)連(lian)軋(ya)工藝(yi)需通過(guo)(guo)(guo)保(bao)溫爐、溜槽(cao)、中(zhong)間包(bao)轉運銅(tong)液,相對容易造(zao)(zao)成(cheng)(cheng)耐(nai)火(huo)材(cai)(cai)料的(de)剝落(luo),在軋(ya)制過(guo)(guo)(guo)程中(zhong)需要通過(guo)(guo)(guo)軋(ya)輥,造(zao)(zao)成(cheng)(cheng)鐵(tie)質的(de)脫落(luo),會(hui)給銅(tong)桿(gan)造(zao)(zao)成(cheng)(cheng)外(wai)部夾雜(za)。而熱軋(ya)中(zhong)皮(pi)上和皮(pi)下氧(yang)化物的(de)軋(ya)入(ru),會(hui)給低氧(yang)桿(gan)的(de)拉絲(si)造(zao)(zao)成(cheng)(cheng)不利的(de)影響。上引連(lian)鑄(zhu)法生(sheng)產工藝(yi)流程較短(duan),銅(tong)液是(shi)通過(guo)(guo)(guo)聯體爐內潛流式完成(cheng)(cheng),對耐(nai)火(huo)材(cai)(cai)料的(de)沖擊不大,結(jie)晶是(shi)通過(guo)(guo)(guo)石墨模(mo)內進(jin)行(xing),所以(yi)過(guo)(guo)(guo)程中(zhong)可能產生(sheng)的(de)污染源較少,雜(za)質進(jin)入(ru)的(de)機會(hui)較少。
O、S、P是(shi)與銅(tong)(tong)(tong)(tong)會生(sheng)產化合物的(de)元素。在(zai)熔態銅(tong)(tong)(tong)(tong)中,氧(yang)(yang)可以(yi)溶(rong)解(jie)(jie)(jie)一(yi)部分(fen),但當銅(tong)(tong)(tong)(tong)冷(leng)凝時,氧(yang)(yang)幾乎不溶(rong)解(jie)(jie)(jie)于銅(tong)(tong)(tong)(tong)中。熔態時所溶(rong)解(jie)(jie)(jie)的(de)氧(yang)(yang),以(yi)銅(tong)(tong)(tong)(tong)=氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)(tong)共(gong)晶體(ti)析出(chu),分(fen)布在(zai)晶粒(li)晶界處。銅(tong)(tong)(tong)(tong)-氧(yang)(yang)化亞(ya)銅(tong)(tong)(tong)(tong)共(gong)晶體(ti)的(de)出(chu)現(xian),顯著降低了銅(tong)(tong)(tong)(tong)的(de)塑性。
硫可(ke)以溶解(jie)在熔體的銅中(zhong),但在室溫下,其溶解(jie)度幾乎(hu)降低到零,它以硫化亞(ya)銅的形式出(chu)現在晶粒(li)晶界處,會顯(xian)著降低銅的塑性。
3、氧在(zai)低氧銅(tong)桿和無(wu)氧銅(tong)桿中分布形式及(ji)其(qi)影響
氧(yang)(yang)含量(liang)對低氧(yang)(yang)銅(tong)(tong)桿的(de)(de)(de)(de)(de)拉線性能有著明顯的(de)(de)(de)(de)(de)影響。當氧(yang)(yang)含量(liang)增加到最(zui)佳值時,銅(tong)(tong)桿的(de)(de)(de)(de)(de)斷線率最(zui)低。這是(shi)因為氧(yang)(yang)在(zai)與大(da)部(bu)分(fen)雜質(zhi)反(fan)應的(de)(de)(de)(de)(de)過程中(zhong)都起(qi)到了清除器的(de)(de)(de)(de)(de)作用。適度(du)的(de)(de)(de)(de)(de)氧(yang)(yang)還有利于去除銅(tong)(tong)液中(zhong)的(de)(de)(de)(de)(de)氫(qing),生(sheng)成水蒸氣溢出,減少氣孔的(de)(de)(de)(de)(de)形成。最(zui)佳的(de)(de)(de)(de)(de)氧(yang)(yang)含量(liang)為拉線工藝(yi)提供了最(zui)好(hao)的(de)(de)(de)(de)(de)條件。
低氧(yang)(yang)(yang)銅桿氧(yang)(yang)(yang)化(hua)(hua)物(wu)的(de)(de)(de)分(fen)布:在連續(xu)澆鑄(zhu)中(zhong)凝(ning)固的(de)(de)(de)最初階(jie)段,散熱速率(lv)和均勻冷(leng)卻是(shi)決定(ding)銅桿氧(yang)(yang)(yang)化(hua)(hua)物(wu)分(fen)布的(de)(de)(de)主要(yao)因(yin)素。不均勻冷(leng)卻會引起銅桿內部結構本質上的(de)(de)(de)差(cha)異(yi),但后續(xu)的(de)(de)(de)熱加(jia)工,柱狀(zhuang)晶(jing)通常會遭到破壞,使氧(yang)(yang)(yang)化(hua)(hua)亞銅顆(ke)粒細微化(hua)(hua)和均勻分(fen)布。氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒聚集而產生的(de)(de)(de)典型(xing)情況是(shi)中(zhong)心爆裂(lie)。除(chu)氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒分(fen)布的(de)(de)(de)影響(xiang)外,具有較小氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒的(de)(de)(de)銅桿顯示(shi)出較好(hao)的(de)(de)(de)拉(la)線特(te)性,較大的(de)(de)(de)Cu2O顆(ke)粒容易(yi)造成應力(li)集中(zhong)點(dian)而斷裂(lie)。
無氧(yang)(yang)(yang)(yang)銅(tong)含(han)氧(yang)(yang)(yang)(yang)量(liang)超標,銅(tong)桿(gan)變脆,延伸率下降,拉伸式(shi)樣端口顯暗紅色(se),結晶組(zu)(zu)織疏松(song)。當氧(yang)(yang)(yang)(yang)含(han)量(liang)超出8ppm時,工(gong)(gong)藝性能(neng)變差,表現(xian)為鑄造及(ji)拉伸過程中(zhong)斷桿(gan)及(ji)斷線率極具增高(gao)。這(zhe)是由(you)于氧(yang)(yang)(yang)(yang)能(neng)與(yu)銅(tong)生成氧(yang)(yang)(yang)(yang)化(hua)亞(ya)銅(tong)脆性相(xiang),形(xing)(xing)成銅(tong)-氧(yang)(yang)(yang)(yang)化(hua)亞(ya)銅(tong)共晶體(ti),以網狀組(zu)(zu)織分(fen)布在(zai)境界上。這(zhe)種(zhong)脆性相(xiang)硬(ying)度高(gao),在(zai)冷變形(xing)(xing)時將會與(yu)銅(tong)機(ji)體(ti)脫(tuo)離,導(dao)致銅(tong)桿(gan)的機(ji)械性能(neng)下降,在(zai)后續加工(gong)(gong)中(zhong)容易造成斷裂現(xian)象。氧(yang)(yang)(yang)(yang)含(han)量(liang)高(gao)還能(neng)導(dao)致無氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)導(dao)電率下降。因(yin)此(ci),必須(xu)嚴格控制上引連鑄工(gong)(gong)藝及(ji)產品質量(liang)。
4、氫的影響
在(zai)上引連鑄中,氧含量控制較(jiao)低,氧化物(wu)的副作用唄**降低,但(dan)氫的影響成為較(jiao)顯(xian)著(zhu)的問題。吸氣后熔體中存(cun)在(zai)平(ping)衡反應:H2O(g)=[O]+2[H];
氣體及疏(shu)松(song)(song)是(shi)在(zai)結(jie)晶(jing)(jing)(jing)的(de)過程中(zhong)(zhong),氫(qing)從過飽(bao)和(he)的(de)溶液(ye)(ye)中(zhong)(zhong)析(xi)出(chu)并聚(ju)集而(er)(er)形(xing)成(cheng)的(de)。在(zai)結(jie)晶(jing)(jing)(jing)前析(xi)出(chu)的(de)氫(qing)又可還原氧化亞(ya)銅而(er)(er)生成(cheng)水氣泡。由于上引(yin)鑄造的(de)特(te)點是(shi)銅液(ye)(ye)自上而(er)(er)下的(de)結(jie)晶(jing)(jing)(jing),形(xing)成(cheng)的(de)液(ye)(ye)**形(xing)狀近似錐型。銅液(ye)(ye)結(jie)晶(jing)(jing)(jing)前析(xi)出(chu)的(de)氣體在(zai)上浮過程中(zhong)(zhong)被堵在(zai)凝固組織內,結(jie)晶(jing)(jing)(jing)時在(zai)鑄桿內形(xing)成(cheng)氣孔。上引(yin)的(de)含(han)氣量(liang)少時,析(xi)出(chu)的(de)氫(qing)存(cun)在(zai)于晶(jing)(jing)(jing)界處,形(xing)成(cheng)疏(shu)松(song)(song);含(han)氣量(liang)多時,則聚(ju)集成(cheng)氣孔,因此,氣孔和(he)疏(shu)松(song)(song)是(shi)氫(qing)氣和(he)水蒸氣兩者(zhe)形(xing)成(cheng)的(de)。
氫來源于上引生產過程(cheng)中的(de)(de)各個工藝環節,如(ru)原料電解(jie)銅的(de)(de)“銅綠(lv)”、輔料木炭**、氣候環境**、石(shi)墨結晶器未干燥等。因此,熔化爐(lu)中的(de)(de)銅液(ye)表面應覆蓋(gai)經烘烤的(de)(de)木炭,電解(jie)銅應盡(jin)量去除“銅綠(lv)”、“銅豆”“耳朵”,對提高無氧銅桿質量非常重要。
在連鑄(zhu)連軋工藝中,往(wang)往(wang)采(cai)用適(shi)度控制氧含量來(lai)控制氫。Cu2O+ H2= 2Cu+ H2O
由(you)于銅(tong)液(ye)在鑄造過(guo)程中(zhong)(zhong)是自下(xia)而上結晶(jing),銅(tong)液(ye)中(zhong)(zhong)的氧和氫(qing)所(suo)產(chan)生的水蒸(zheng)氣很容易上浮跑出,銅(tong)液(ye)中(zhong)(zhong)的氫(qing)大(da)部分能被有效去除,因而對銅(tong)桿的影響較小。
二、表面質量
在(zai)生(sheng)產(chan)(chan)電磁線等(deng)產(chan)(chan)品的(de)(de)過程中,對銅(tong)桿的(de)(de)表面質(zhi)量也(ye)需提出要(yao)求(qiu)。需要(yao)拉制后的(de)(de)銅(tong)絲表面無毛刺、銅(tong)粉少、無油污。并通過扭轉(zhuan)試驗測量表面銅(tong)粉的(de)(de)質(zhi)量和(he)扭轉(zhuan)后觀察銅(tong)桿的(de)(de)復原情況來判定其好壞。
在連(lian)鑄連(lian)軋過程中(zhong),從鑄造到(dao)軋制前,溫度高(gao),完全暴露(lu)于空氣中(zhong),使鑄坯表(biao)(biao)面(mian)形成較(jiao)(jiao)厚的氧(yang)化(hua)(hua)層,在軋制過程中(zhong),隨(sui)著軋輥的轉動,氧(yang)化(hua)(hua)物(wu)(wu)顆(ke)粒軋入銅(tong)線表(biao)(biao)面(mian)。由于氧(yang)化(hua)(hua)亞(ya)(ya)銅(tong)是(shi)高(gao)熔點脆性化(hua)(hua)合物(wu)(wu),對(dui)于軋入較(jiao)(jiao)深的氧(yang)化(hua)(hua)亞(ya)(ya)銅(tong),當(dang)成條狀(zhuang)的聚集物(wu)(wu)遇模(mo)具拉伸(shen)時,就會是(shi)銅(tong)桿外表(biao)(biao)面(mian)產生(sheng)毛(mao)刺,給后續的涂漆造成麻煩。
而(er)上引連鑄(zhu)(zhu)工藝制(zhi)造的無(wu)(wu)氧(yang)銅(tong)桿(gan),由于鑄(zhu)(zhu)造和冷卻完(wan)全(quan)與氧(yang)隔絕,后續亦(yi)無(wu)(wu)熱軋過程,銅(tong)桿(gan)表(biao)面無(wu)(wu)軋入(ru)表(biao)面的氧(yang)化物,質量較好,拉制(zhi)后銅(tong)粉少,上述問題較少存在。
無(wu)氧銅桿(gan)(gan)也(ye)分進口(kou)設(she)(she)(she)備(bei)做的(de)(de)和國(guo)產(chan)(chan)設(she)(she)(she)備(bei)做的(de)(de),但目前(qian)進口(kou)產(chan)(chan)品已無(wu)明顯優勢,銅桿(gan)(gan)產(chan)(chan)品出來后區別不是(shi)(shi)(shi)很大(da),只要(yao)銅板選的(de)(de)好,生產(chan)(chan)控制比較穩定,國(guo)產(chan)(chan)設(she)(she)(she)備(bei)也(ye)能(neng)產(chan)(chan)出可(ke)拉伸0.05的(de)(de)銅桿(gan)(gan).進口(kou)設(she)(she)(she)備(bei)一般是(shi)(shi)(shi)芬蘭奧托昆普的(de)(de)設(she)(she)(she)備(bei),國(guo)產(chan)(chan)設(she)(she)(she)備(bei)最好的(de)(de)應該是(shi)(shi)(shi)上海的(de)(de)海軍(jun)廠的(de)(de)了,生產(chan)(chan)時間最長,軍(jun)工(gong)企業,質量可(ke)靠。
低氧銅桿進(jin)口設備國際主要(yao)有(you)兩(liang)種(zhong),一種(zhong)是(shi)(shi)美國南(nan)線設備,英文是(shi)(shi)SOUTHWIRE,國內(nei)廠(chang)(chang)家是(shi)(shi)南(nan)京華新,江西銅業,另一種(zhong)是(shi)(shi)德國CONTIROD設備,國內(nei)廠(chang)(chang)家是(shi)(shi)常州金源(yuan),天津大無(wu)縫。
無(wu)(wu)氧及(ji)低(di)(di)氧桿(gan)(gan)從含氧量(liang)上容易區別(bie),無(wu)(wu)氧銅是(shi)含氧量(liang)在(zai)10-20個(ge)PPM以下,但(dan)(dan)目前(qian)有(you)的(de)廠(chang)家只(zhi)能(neng)(neng)做到50個(ge)PPM以下.低(di)(di)氧銅桿(gan)(gan)在(zai) 200-400個(ge)PPM,好的(de)桿(gan)(gan)子一(yi)般(ban)含氧量(liang)控(kong)制在(zai)250個(ge)PPM左右,無(wu)(wu)氧桿(gan)(gan)一(yi)般(ban)采取的(de)是(shi)上引法,低(di)(di)氧桿(gan)(gan)是(shi)連鑄連軋,兩種產品相(xiang)對而言低(di)(di)氧桿(gan)(gan)對漆包線(xian)(xian)(xian)性 能(neng)(neng)更適應些,如柔(rou)軟性,回彈(dan)角,繞(rao)線(xian)(xian)(xian)性能(neng)(neng).但(dan)(dan)低(di)(di)氧桿(gan)(gan)對拉(la)(la)絲條(tiao)(tiao)件相(xiang)對要苛刻些,同樣(yang)(yang)拉(la)(la)伸(shen)0.2的(de)細(xi)絲,如果(guo)伸(shen)線(xian)(xian)(xian)條(tiao)(tiao)件不好,普通的(de)無(wu)(wu)氧桿(gan)(gan)可拉(la)(la)而好的(de)低(di)(di)氧桿(gan)(gan)就(jiu)斷 線(xian)(xian)(xian),但(dan)(dan)如果(guo)放在(zai)好的(de)伸(shen)線(xian)(xian)(xian)條(tiao)(tiao)件,同樣(yang)(yang)的(de)桿(gan)(gan)子,低(di)(di)氧桿(gan)(gan)說不定就(jiu)能(neng)(neng)拉(la)(la)到雙(shuang)零(ling)五,而普通無(wu)(wu)氧桿(gan)(gan)最多只(zhi)能(neng)(neng)拉(la)(la)伸(shen)到0.1而已(yi),當然做的(de)最細(xi)的(de)如雙(shuang)零(ling)二卻非得依(yi)靠(kao)進(jin)口的(de) 無(wu)(wu)氧銅桿(gan)(gan)了.目前(qian)有(you)企(qi)業嘗(chang)試用剝皮的(de)方(fang)式(shi)來處理(li)低(di)(di)氧桿(gan)(gan)來伸(shen)0.03線(xian)(xian)(xian).但(dan)(dan)有(you)關這方(fang)面(mian)的(de)內容我還不是(shi)很清楚。
音響線一般反而喜歡用無氧(yang)桿,這(zhe)和無氧(yang)桿是(shi)單晶銅,低氧(yang)桿是(shi)多(duo)晶銅有(you)關(guan)。
氧銅(tong)(tong)桿和無氧銅(tong)(tong)桿由(you)于(yu)制造方法的不同,致使存在差(cha)別,具(ju)有各(ge)自的特點。
一、關于氧的吸入和脫去(qu)以及(ji)它的存在狀(zhuang)態
生(sheng)產(chan)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)含氧(yang)(yang)量一(yi)(yi)般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常溫下(xia)(xia)氧(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中(zhong)的(de)(de)固溶度約(yue)2ppm。低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)含氧(yang)(yang)量一(yi)(yi)般(ban)在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)進入是(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)液(ye)(ye)態(tai)下(xia)(xia)吸入的(de)(de),而(er)(er)上引(yin)法無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則(ze)相(xiang)反,氧(yang)(yang)在(zai)(zai)液(ye)(ye)態(tai)銅(tong)(tong)(tong)(tong)(tong)下(xia)(xia)保持相(xiang)當時間后,被還(huan)原而(er)(er)脫去,通(tong)常這(zhe)種(zhong)桿(gan)的(de)(de)含氧(yang)(yang)量都在(zai)(zai)10—50ppm以(yi)下(xia)(xia),最低(di)可達1-2ppm,從組織上看,低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang),以(yi)氧(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)狀(zhuang)態(tai),存在(zai)(zai)于晶粒邊界附近(jin),這(zhe)對(dui)(dui)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)而(er)(er)言可以(yi)說(shuo)是(shi)常見(jian)(jian)的(de)(de)但對(dui)(dui)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則(ze)很(hen)(hen)少見(jian)(jian)。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)晶界出現對(dui)(dui)材料的(de)(de)韌性產(chan)生(sheng)負面影響。而(er)(er)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)很(hen)(hen)低(di),所以(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)組織是(shi)均勻的(de)(de)單(dan)相(xiang)組織對(dui)(dui)韌性有利。在(zai)(zai)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中(zhong)的(de)(de)多(duo)孔性是(shi)不常見(jian)(jian)的(de)(de),而(er)(er)在(zai)(zai)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中(zhong)則(ze)是(shi)常見(jian)(jian)的(de)(de)一(yi)(yi)種(zhong)缺陷。
二、熱軋組織(zhi)和鑄(zhu)造組織(zhi)的(de)區別(bie)
低(di)氧(yang)銅(tong)(tong)桿(gan)由于經(jing)過熱軋,所以其(qi)組(zu)織(zhi)(zhi)(zhi)屬熱加工組(zu)織(zhi)(zhi)(zhi),原來的(de)(de)(de)(de)(de)鑄(zhu)造組(zu)織(zhi)(zhi)(zhi)已經(jing)破碎,在(zai)(zai)8mm的(de)(de)(de)(de)(de)桿(gan)時已有(you)再結晶(jing)(jing)的(de)(de)(de)(de)(de)形(xing)式出現(xian),而無氧(yang)銅(tong)(tong)桿(gan)屬鑄(zhu)造組(zu)織(zhi)(zhi)(zhi),晶(jing)(jing)粒粗大,這是為什么,無氧(yang)銅(tong)(tong)的(de)(de)(de)(de)(de)再結晶(jing)(jing)溫(wen)度(du)較(jiao)(jiao)高,需(xu)要(yao)較(jiao)(jiao)高退(tui)(tui)火溫(wen)度(du)的(de)(de)(de)(de)(de)固有(you)原因(yin)(yin)。這是因(yin)(yin)為,再結晶(jing)(jing)發(fa)生在(zai)(zai)晶(jing)(jing)粒邊(bian)界(jie)附近,無氧(yang)銅(tong)(tong)桿(gan)組(zu)織(zhi)(zhi)(zhi)晶(jing)(jing)粒粗大,晶(jing)(jing)粒尺寸甚至能(neng)達幾個毫米,因(yin)(yin)而晶(jing)(jing)粒邊(bian)界(jie)少(shao),即使(shi)通過拉制變(bian)形(xing),但晶(jing)(jing)粒邊(bian)界(jie)相對(dui)低(di)氧(yang)銅(tong)(tong)桿(gan)還是較(jiao)(jiao)少(shao),所以需(xu)要(yao)較(jiao)(jiao)高的(de)(de)(de)(de)(de)退(tui)(tui)火功(gong)(gong)率。對(dui)無氧(yang)銅(tong)(tong)成(cheng)功(gong)(gong)的(de)(de)(de)(de)(de)退(tui)(tui)火要(yao)求是:由桿(gan)經(jing)拉制,但尚未鑄(zhu)造組(zu)織(zhi)(zhi)(zhi)的(de)(de)(de)(de)(de)線時的(de)(de)(de)(de)(de)第一次退(tui)(tui)火,其(qi)退(tui)(tui)火功(gong)(gong)率應(ying)比同(tong)樣情況(kuang)的(de)(de)(de)(de)(de)低(di)氧(yang)銅(tong)(tong)高10——15%。經(jing)繼續拉制,在(zai)(zai)以后階段(duan)的(de)(de)(de)(de)(de)退(tui)(tui)火功(gong)(gong)率應(ying)留有(you)足夠(gou)的(de)(de)(de)(de)(de)余(yu)量和(he)對(dui)低(di)氧(yang)銅(tong)(tong)和(he)無氧(yang)銅(tong)(tong)切實區別(bie)執行不同(tong)的(de)(de)(de)(de)(de)退(tui)(tui)火工藝,以保證在(zai)(zai)制品和(he)成(cheng)品導線的(de)(de)(de)(de)(de)柔(rou)軟(ruan)性。
三、夾雜,氧含量波動,表面氧化物和(he)可能存在的(de)熱軋缺(que)陷的(de)差別
無(wu)氧(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)可拉(la)(la)性在(zai)所(suo)有線(xian)(xian)徑里(li)與低氧(yang)銅(tong)(tong)桿(gan)相(xiang)比(bi)都(dou)是(shi)優(you)越的(de)(de)(de),除(chu)上述組織原因(yin)外,無(wu)氧(yang)銅(tong)(tong)桿(gan)夾雜少,含(han)氧(yang)量穩定,無(wu)熱軋可能產(chan)生(sheng)的(de)(de)(de)缺陷,桿(gan)表氧(yang)化(hua)(hua)物厚度(du)可達(da)≤15A。在(zai)連(lian)鑄連(lian)軋生(sheng)產(chan)過程中(zhong)如果工(gong)(gong)藝不(bu)穩定,對(dui)氧(yang)監(jian)控不(bu)嚴(yan),含(han)氧(yang)量不(bu)穩定將直接影響桿(gan)的(de)(de)(de)性能。如果桿(gan)的(de)(de)(de)表面氧(yang)化(hua)(hua)物能在(zai)后工(gong)(gong)序的(de)(de)(de)連(lian)續(xu)清(qing)洗中(zhong)得以彌補外,但比(bi)較麻煩的(de)(de)(de)是(shi)有相(xiang)當多的(de)(de)(de)氧(yang)化(hua)(hua)物存(cun)在(zai)于“皮(pi)下”,對(dui)拉(la)(la)線(xian)(xian)斷線(xian)(xian)影響更直接,故而在(zai)拉(la)(la)制(zhi)微(wei)細線(xian)(xian),超(chao)微(wei)細線(xian)(xian)時,為了減少斷線(xian)(xian),有時要對(dui)銅(tong)(tong)桿(gan)采取不(bu)得已(yi)的(de)(de)(de)辦(ban)法——剝皮(pi),甚(shen)至(zhi)二(er)次(ci)剝皮(pi)的(de)(de)(de)原因(yin)所(suo)在(zai),目(mu)的(de)(de)(de)要除(chu)去皮(pi)下氧(yang)化(hua)(hua)物。
四、低氧銅桿(gan)和無氧銅桿(gan)的韌性有差別
兩者都可以(yi)拉(la)到0.015mm,但在低(di)溫超導(dao)線中的(de)低(di)溫級無氧銅,其(qi)細絲間的(de)間距(ju)只有0.001mm.
五、從(cong)制桿的原材料到制線的經(jing)濟性有差別。
制(zhi)造無氧(yang)銅桿要求(qiu)質(zhi)量(liang)較(jiao)高的原材料。一般,拉制(zhi)直徑(jing)>1mm的銅線時,低氧(yang)銅桿的優(you)點比較(jiao)明顯(xian),而無氧(yang)銅桿顯(xian)得更為優(you)越的是拉制(zhi)直徑(jing)<0.5mm的銅線。
六、低氧(yang)銅桿(gan)的制線工(gong)藝(yi)與無氧(yang)銅桿(gan)的有所不同。
低(di)氧(yang)銅桿的(de)(de)制線(xian)工(gong)藝(yi)不能(neng)照(zhao)搬到無氧(yang)銅桿的(de)(de)制線(xian)工(gong)藝(yi)上來,至少兩者的(de)(de)退火工(gong)藝(yi)是(shi)不同的(de)(de)。因為(wei)線(xian)的(de)(de)柔軟性深受材料(liao)成份和制桿,制線(xian)和退火工(gong)藝(yi)的(de)(de)影響,不能(neng)簡單地說低(di)氧(yang)銅或無氧(yang)銅誰軟誰硬。
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