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土默特右電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動(dong)態(tai) 閱讀:109382 發布時間:2019-07-05

導讀:由于生產(chan)銅(tong)桿(gan)(gan)的(de)(de)(de)兩(liang)者的(de)(de)(de)工藝(yi)不(bu)同,所(suo)生產(chan)的(de)(de)(de)銅(tong)桿(gan)(gan)中的(de)(de)(de)含(han)氧(yang)量及外觀(guan)就不(bu)同。上引(yin)生產(chan)的(de)(de)(de)銅(tong)桿(gan)(gan),工藝(yi)得當(dang)氧(yang)含(han)量在(zai)10ppm以下,叫無氧(yang)銅(tong)桿(gan)(gan);連(lian)鑄連(lian)鑄生產(chan)的(de)(de)(de)銅(tong)桿(gan)(gan) 是在(zai)保護(hu)條件下的(de)(de)(de)熱軋,氧(yang)含(han)量在(zai)200-500ppm范(fan)圍(wei)內,但有時也高(gao)達700ppm以上,一般情況下,此種方法生產(chan)的(de)(de)(de)銅(tong)外表光亮,低氧(yang)銅(tong)桿(gan)(gan),有時也叫光桿(gan)(gan)。

銅(tong)(tong)桿(gan)是電(dian)纜行業的(de)(de)主要原料,生(sheng)(sheng)產(chan)的(de)(de)方式主要有兩(liang)種——連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)法和上(shang)(shang)(shang)引(yin)(yin)連(lian)(lian)鑄(zhu)(zhu)法。連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)低(di)(di)氧(yang)銅(tong)(tong)桿(gan)的(de)(de)生(sheng)(sheng)產(chan)方法較多(duo),其(qi)特點(dian)是金(jin)屬在(zai)豎爐(lu)中融化后,銅(tong)(tong)液通過保溫爐(lu)、溜(liu)槽(cao)、中間包(bao),從澆管進(jin)入(ru)封閉的(de)(de)模(mo)腔內,采(cai)用較大(da)的(de)(de)冷卻(que)強(qiang)度(du)進(jin)行冷卻(que),形(xing)成鑄(zhu)(zhu)坯,然后進(jin)行多(duo)道次軋(ya)制,生(sheng)(sheng)產(chan)的(de)(de)低(di)(di)氧(yang)銅(tong)(tong)桿(gan)為熱加工組織,原來的(de)(de)鑄(zhu)(zhu)造(zao)組織已經破碎(sui),含(han)氧(yang)量一般為200~400ppm之間。無氧(yang)銅(tong)(tong)桿(gan)國內基本全(quan)部采(cai)用上(shang)(shang)(shang)引(yin)(yin)連(lian)(lian)鑄(zhu)(zhu)法生(sheng)(sheng)產(chan),金(jin)屬在(zai)感應電(dian)爐(lu)中融化后通過石墨(mo)模(mo)進(jin)行上(shang)(shang)(shang)引(yin)(yin)連(lian)(lian)續鑄(zhu)(zhu)造(zao),之后進(jin)行冷軋(ya)或冷加工,生(sheng)(sheng)產(chan)的(de)(de)無氧(yang)銅(tong)(tong)桿(gan)為鑄(zhu)(zhu)造(zao)組織,含(han)氧(yang)量一般在(zai)20ppm以(yi)下。由于制造(zao)工藝的(de)(de)不同,所(suo)以(yi)在(zai)組織結(jie)構、氧(yang)含(han)量分布、雜(za)質的(de)(de)形(xing)式及分布等(deng)諸多(duo)方面有較大(da)差別。

一、拉制性能

銅桿(gan)的(de)拉(la)制(zhi)性能跟很多(duo)因(yin)素有關(guan),如雜(za)質的(de)含量(liang)、氧(yang)含量(liang)及(ji)分布(bu)、工藝控制(zhi)等(deng)。下面(mian)分別從以上幾個方面(mian)對(dui)銅桿(gan)的(de)拉(la)制(zhi)性能進行分析。

1、熔化(hua)方式對S等雜質的影響

連鑄(zhu)連軋(ya)生產(chan)銅(tong)(tong)桿(gan)主要是(shi)通過(guo)(guo)氣體的燃(ran)燒使銅(tong)(tong)桿(gan)熔(rong)化(hua),在燃(ran)燒的過(guo)(guo)程中,通過(guo)(guo)氧化(hua)和揮(hui)發(fa)作用,可一(yi)定程度減少部(bu)分雜質進入(ru)銅(tong)(tong)液,因此連鑄(zhu)連軋(ya)法對原料要求(qiu)相(xiang)對低一(yi)些。上引(yin)連鑄(zhu)生產(chan)無氧銅(tong)(tong)桿(gan),由于是(shi)用感(gan)應電爐熔(rong)化(hua),電解銅(tong)(tong)表(biao)面的“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都(dou)熔(rong)入(ru)到銅(tong)(tong)液中。其中熔(rong)入(ru)的S對無氧銅(tong)(tong)桿(gan)塑(su)性(xing)影響(xiang)極大,會增(zeng)加(jia)拉絲(si)斷線率。

2、鑄造過程中雜(za)質的進入

在(zai)生產過(guo)程(cheng)(cheng)中(zhong),連(lian)鑄(zhu)連(lian)軋(ya)工(gong)藝需通(tong)(tong)過(guo)保溫爐、溜槽、中(zhong)間包轉運(yun)銅(tong)(tong)液,相對(dui)容易造(zao)(zao)成(cheng)耐(nai)火材料的(de)剝落,在(zai)軋(ya)制(zhi)過(guo)程(cheng)(cheng)中(zhong)需要通(tong)(tong)過(guo)軋(ya)輥,造(zao)(zao)成(cheng)鐵質的(de)脫落,會給(gei)銅(tong)(tong)桿(gan)造(zao)(zao)成(cheng)外部(bu)夾雜。而熱軋(ya)中(zhong)皮上和皮下氧(yang)(yang)化物的(de)軋(ya)入,會給(gei)低氧(yang)(yang)桿(gan)的(de)拉(la)絲造(zao)(zao)成(cheng)不(bu)(bu)利的(de)影(ying)響。上引連(lian)鑄(zhu)法生產工(gong)藝流程(cheng)(cheng)較短(duan),銅(tong)(tong)液是通(tong)(tong)過(guo)聯體爐內(nei)潛(qian)流式完成(cheng),對(dui)耐(nai)火材料的(de)沖(chong)擊不(bu)(bu)大(da),結(jie)晶是通(tong)(tong)過(guo)石(shi)墨模內(nei)進行,所以過(guo)程(cheng)(cheng)中(zhong)可能產生的(de)污染源較少,雜質進入的(de)機會較少。

O、S、P是(shi)與銅(tong)會(hui)生產化(hua)(hua)(hua)合物的(de)(de)元(yuan)素。在熔態(tai)(tai)銅(tong)中(zhong),氧(yang)可以溶(rong)解一部(bu)分,但當銅(tong)冷凝(ning)時,氧(yang)幾乎(hu)不溶(rong)解于銅(tong)中(zhong)。熔態(tai)(tai)時所溶(rong)解的(de)(de)氧(yang),以銅(tong)=氧(yang)化(hua)(hua)(hua)亞銅(tong)共(gong)晶(jing)體析出,分布在晶(jing)粒晶(jing)界處。銅(tong)-氧(yang)化(hua)(hua)(hua)亞銅(tong)共(gong)晶(jing)體的(de)(de)出現,顯著(zhu)降低了銅(tong)的(de)(de)塑性。

硫可以(yi)溶(rong)解在熔(rong)體的(de)銅(tong)中,但在室溫下,其溶(rong)解度幾乎降低到(dao)零,它以(yi)硫化亞銅(tong)的(de)形(xing)式出(chu)現(xian)在晶粒晶界處,會顯著降低銅(tong)的(de)塑性。

3、氧(yang)在低氧(yang)銅桿和無氧(yang)銅桿中(zhong)分(fen)布形式(shi)及其(qi)影響(xiang)

氧(yang)(yang)(yang)含量(liang)對低(di)氧(yang)(yang)(yang)銅(tong)桿(gan)的(de)拉(la)線(xian)(xian)性能有著明顯的(de)影響(xiang)。當氧(yang)(yang)(yang)含量(liang)增加到(dao)最(zui)(zui)佳值時,銅(tong)桿(gan)的(de)斷線(xian)(xian)率最(zui)(zui)低(di)。這是因(yin)為(wei)氧(yang)(yang)(yang)在(zai)與大部(bu)分雜質(zhi)反應的(de)過(guo)程中都起(qi)到(dao)了清除器的(de)作用。適度的(de)氧(yang)(yang)(yang)還有利(li)于(yu)去(qu)除銅(tong)液(ye)中的(de)氫,生成(cheng)水蒸(zheng)氣溢出,減少氣孔的(de)形成(cheng)。最(zui)(zui)佳的(de)氧(yang)(yang)(yang)含量(liang)為(wei)拉(la)線(xian)(xian)工(gong)藝提供了最(zui)(zui)好(hao)的(de)條件。

低氧(yang)(yang)銅(tong)(tong)桿氧(yang)(yang)化(hua)物(wu)(wu)的(de)(de)分(fen)布:在連續澆鑄(zhu)中(zhong)凝固的(de)(de)最初階(jie)段,散熱(re)速率和均(jun)勻(yun)冷(leng)卻是決定銅(tong)(tong)桿氧(yang)(yang)化(hua)物(wu)(wu)分(fen)布的(de)(de)主(zhu)要因素(su)。不(bu)均(jun)勻(yun)冷(leng)卻會引起銅(tong)(tong)桿內部結構本質上的(de)(de)差(cha)異,但后續的(de)(de)熱(re)加工,柱(zhu)狀晶通常會遭到破(po)壞,使氧(yang)(yang)化(hua)亞銅(tong)(tong)顆粒細微化(hua)和均(jun)勻(yun)分(fen)布。氧(yang)(yang)化(hua)物(wu)(wu)顆粒聚集而(er)產生的(de)(de)典(dian)型情況是中(zhong)心爆裂。除氧(yang)(yang)化(hua)物(wu)(wu)顆粒分(fen)布的(de)(de)影響外(wai),具有較(jiao)(jiao)小氧(yang)(yang)化(hua)物(wu)(wu)顆粒的(de)(de)銅(tong)(tong)桿顯(xian)示出較(jiao)(jiao)好的(de)(de)拉線(xian)特性,較(jiao)(jiao)大的(de)(de)Cu2O顆粒容易造成應力集中(zhong)點而(er)斷裂。

無氧(yang)(yang)銅(tong)(tong)含氧(yang)(yang)量(liang)超標,銅(tong)(tong)桿變(bian)脆(cui)(cui),延伸(shen)率下(xia)(xia)降,拉伸(shen)式樣端(duan)口顯(xian)暗紅色(se),結(jie)晶(jing)組(zu)織疏松。當氧(yang)(yang)含量(liang)超出8ppm時,工藝性(xing)能(neng)變(bian)差,表現(xian)為鑄造(zao)及拉伸(shen)過程(cheng)中(zhong)斷桿及斷線(xian)率極具(ju)增高(gao)。這是由于(yu)氧(yang)(yang)能(neng)與銅(tong)(tong)生成(cheng)(cheng)氧(yang)(yang)化亞銅(tong)(tong)脆(cui)(cui)性(xing)相,形(xing)(xing)成(cheng)(cheng)銅(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)共(gong)晶(jing)體(ti),以網狀組(zu)織分布(bu)在境界上。這種脆(cui)(cui)性(xing)相硬度高(gao),在冷(leng)變(bian)形(xing)(xing)時將會與銅(tong)(tong)機(ji)體(ti)脫離,導致銅(tong)(tong)桿的(de)機(ji)械性(xing)能(neng)下(xia)(xia)降,在后續(xu)加工中(zhong)容易造(zao)成(cheng)(cheng)斷裂現(xian)象。氧(yang)(yang)含量(liang)高(gao)還(huan)能(neng)導致無氧(yang)(yang)銅(tong)(tong)桿導電率下(xia)(xia)降。因此,必(bi)須嚴格(ge)控制上引連鑄工藝及產(chan)品質量(liang)。

4、氫的影響

在上引(yin)連(lian)鑄中,氧(yang)含量控(kong)制較(jiao)低,氧(yang)化物的(de)副作用唄**降低,但氫的(de)影響(xiang)成(cheng)為較(jiao)顯著的(de)問題。吸氣后熔(rong)體中存在平衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)體及(ji)疏(shu)松(song)(song)是在結晶(jing)(jing)的過(guo)程中,氫從過(guo)飽和的溶液中析出(chu)并聚集而(er)形成的。在結晶(jing)(jing)前析出(chu)的氫又(you)可還(huan)原(yuan)氧化亞(ya)銅而(er)生(sheng)成水(shui)(shui)氣(qi)(qi)泡。由于上引(yin)鑄造(zao)的特點是銅液自上而(er)下的結晶(jing)(jing),形成的液**形狀近似錐(zhui)型。銅液結晶(jing)(jing)前析出(chu)的氣(qi)(qi)體在上浮過(guo)程中被堵在凝固組織內(nei),結晶(jing)(jing)時在鑄桿(gan)內(nei)形成氣(qi)(qi)孔(kong)(kong)。上引(yin)的含氣(qi)(qi)量少時,析出(chu)的氫存在于晶(jing)(jing)界處,形成疏(shu)松(song)(song);含氣(qi)(qi)量多時,則聚集成氣(qi)(qi)孔(kong)(kong),因(yin)此(ci),氣(qi)(qi)孔(kong)(kong)和疏(shu)松(song)(song)是氫氣(qi)(qi)和水(shui)(shui)蒸氣(qi)(qi)兩者形成的。

氫來源于上引生產過程中的(de)各個工(gong)藝(yi)環節,如原(yuan)料電(dian)解銅(tong)的(de)“銅(tong)綠(lv)”、輔料木炭**、氣候環境**、石墨結晶器未干燥等。因(yin)此(ci),熔(rong)化(hua)爐中的(de)銅(tong)液表面應(ying)(ying)覆蓋經(jing)烘烤的(de)木炭,電(dian)解銅(tong)應(ying)(ying)盡量(liang)去除“銅(tong)綠(lv)”、“銅(tong)豆(dou)”“耳朵”,對提高無氧銅(tong)桿質量(liang)非(fei)常重(zhong)要。

在連鑄連軋工藝(yi)中,往往采(cai)用適度控(kong)制氧含量(liang)來控(kong)制氫。Cu2O+ H2= 2Cu+ H2O

由于銅液在(zai)鑄(zhu)造過程中是(shi)自(zi)下而(er)上結(jie)晶,銅液中的(de)(de)氧和氫所產生的(de)(de)水蒸氣很容易(yi)上浮跑出,銅液中的(de)(de)氫大部分能被有效去除,因而(er)對銅桿的(de)(de)影響較小。

二、表面質量

在生產電磁線(xian)等產品的過(guo)程(cheng)中,對銅(tong)桿(gan)的表面(mian)質(zhi)量也需提出要求。需要拉制后(hou)的銅(tong)絲表面(mian)無毛刺、銅(tong)粉少、無油污。并通過(guo)扭轉試驗測量表面(mian)銅(tong)粉的質(zhi)量和扭轉后(hou)觀察銅(tong)桿(gan)的復原情況來判定其好壞(huai)。

在連鑄連軋(ya)(ya)(ya)過程中(zhong)(zhong),從鑄造到軋(ya)(ya)(ya)制前(qian),溫度高,完(wan)全暴(bao)露于(yu)空(kong)氣中(zhong)(zhong),使鑄坯表(biao)面(mian)形(xing)成(cheng)較(jiao)厚(hou)的(de)(de)氧(yang)化層,在軋(ya)(ya)(ya)制過程中(zhong)(zhong),隨著軋(ya)(ya)(ya)輥的(de)(de)轉動,氧(yang)化物(wu)顆粒(li)軋(ya)(ya)(ya)入銅(tong)線表(biao)面(mian)。由于(yu)氧(yang)化亞銅(tong)是高熔點脆(cui)性化合物(wu),對于(yu)軋(ya)(ya)(ya)入較(jiao)深的(de)(de)氧(yang)化亞銅(tong),當成(cheng)條(tiao)狀的(de)(de)聚(ju)集物(wu)遇模具拉伸時,就會是銅(tong)桿(gan)外表(biao)面(mian)產生毛刺,給后續的(de)(de)涂漆(qi)造成(cheng)麻煩。

而上引連鑄工藝制造的無氧銅桿(gan),由(you)于(yu)鑄造和(he)冷卻完全與氧隔絕,后續亦無熱軋(ya)過程(cheng),銅桿(gan)表(biao)面無軋(ya)入表(biao)面的氧化物,質量較好,拉(la)制后銅粉(fen)少,上述(shu)問題(ti)較少存在。

無氧銅(tong)桿也分進口(kou)設(she)(she)備(bei)(bei)做(zuo)的(de)(de)(de)和(he)國產(chan)(chan)設(she)(she)備(bei)(bei)做(zuo)的(de)(de)(de),但目前進口(kou)產(chan)(chan)品(pin)(pin)已無明(ming)顯優勢(shi),銅(tong)桿產(chan)(chan)品(pin)(pin)出來后區別不是(shi)很大(da),只要銅(tong)板選的(de)(de)(de)好,生產(chan)(chan)控制比(bi)較穩定(ding),國產(chan)(chan)設(she)(she)備(bei)(bei)也能(neng)產(chan)(chan)出可拉伸(shen)0.05的(de)(de)(de)銅(tong)桿.進口(kou)設(she)(she)備(bei)(bei)一般是(shi)芬蘭奧托(tuo)昆普(pu)的(de)(de)(de)設(she)(she)備(bei)(bei),國產(chan)(chan)設(she)(she)備(bei)(bei)最(zui)(zui)好的(de)(de)(de)應該是(shi)上(shang)海的(de)(de)(de)海軍廠(chang)的(de)(de)(de)了,生產(chan)(chan)時間最(zui)(zui)長,軍工企業,質(zhi)量可靠。

低氧銅桿進口設備國(guo)(guo)際(ji)主要有兩(liang)種(zhong),一(yi)種(zhong)是(shi)(shi)美國(guo)(guo)南線設備,英文是(shi)(shi)SOUTHWIRE,國(guo)(guo)內廠家是(shi)(shi)南京華新(xin),江西銅業(ye),另(ling)一(yi)種(zhong)是(shi)(shi)德國(guo)(guo)CONTIROD設備,國(guo)(guo)內廠家是(shi)(shi)常州金源,天津大無縫。

無氧(yang)(yang)及(ji)低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)從(cong)含(han)氧(yang)(yang)量上容(rong)易區別,無氧(yang)(yang)銅(tong)(tong)是含(han)氧(yang)(yang)量在(zai)10-20個PPM以下,但(dan)目前有(you)的(de)(de)(de)廠家只能(neng)(neng)做到(dao)50個PPM以下.低(di)(di)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)(de)(de)桿(gan)(gan)(gan)子(zi)(zi)一般含(han)氧(yang)(yang)量控(kong)制在(zai)250個PPM左右,無氧(yang)(yang)桿(gan)(gan)(gan)一般采取的(de)(de)(de)是上引法,低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)是連(lian)鑄連(lian)軋,兩種(zhong)產(chan)品相對而(er)言低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)對漆包線(xian)性(xing) 能(neng)(neng)更適應些(xie),如(ru)(ru)柔軟性(xing),回彈角,繞線(xian)性(xing)能(neng)(neng).但(dan)低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)對拉(la)(la)(la)絲條件相對要苛刻些(xie),同(tong)(tong)樣(yang)拉(la)(la)(la)伸0.2的(de)(de)(de)細絲,如(ru)(ru)果(guo)伸線(xian)條件不好(hao),普通的(de)(de)(de)無氧(yang)(yang)桿(gan)(gan)(gan)可拉(la)(la)(la)而(er)好(hao)的(de)(de)(de)低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)就斷 線(xian),但(dan)如(ru)(ru)果(guo)放在(zai)好(hao)的(de)(de)(de)伸線(xian)條件,同(tong)(tong)樣(yang)的(de)(de)(de)桿(gan)(gan)(gan)子(zi)(zi),低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)說不定就能(neng)(neng)拉(la)(la)(la)到(dao)雙零(ling)五,而(er)普通無氧(yang)(yang)桿(gan)(gan)(gan)最多(duo)只能(neng)(neng)拉(la)(la)(la)伸到(dao)0.1而(er)已(yi),當(dang)然(ran)做的(de)(de)(de)最細的(de)(de)(de)如(ru)(ru)雙零(ling)二卻非得依(yi)靠進口的(de)(de)(de) 無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)了(le).目前有(you)企業嘗試(shi)用剝皮(pi)的(de)(de)(de)方(fang)式來(lai)處理(li)低(di)(di)氧(yang)(yang)桿(gan)(gan)(gan)來(lai)伸0.03線(xian).但(dan)有(you)關這方(fang)面的(de)(de)(de)內容(rong)我還(huan)不是很清楚。

音響(xiang)線一般反而(er)喜(xi)歡用無(wu)氧(yang)桿,這和無(wu)氧(yang)桿是單晶(jing)銅,低氧(yang)桿是多晶(jing)銅有關。

氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)由于制造方法(fa)的不(bu)同,致使存在差別(bie),具(ju)有各自(zi)的特點。

一(yi)、關于氧(yang)的(de)(de)吸入(ru)和(he)脫去以及它的(de)(de)存在狀態

生產銅(tong)(tong)桿(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)常(chang)(chang)(chang)溫下氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入(ru)是(shi)(shi)在(zai)(zai)(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)液(ye)態下吸入(ru)的(de)(de)(de)(de),而上(shang)引法(fa)無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)(ze)相反,氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)(zai)液(ye)態銅(tong)(tong)下保(bao)持相當時間后,被還原而脫去,通常(chang)(chang)(chang)這種(zhong)桿(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)量都(dou)在(zai)(zai)(zai)(zai)10—50ppm以(yi)下,最低(di)可達1-2ppm,從組(zu)織(zhi)上(shang)看,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)狀態,存在(zai)(zai)(zai)(zai)于晶(jing)粒邊界附近(jin),這對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)而言可以(yi)說是(shi)(shi)常(chang)(chang)(chang)見的(de)(de)(de)(de)但(dan)對(dui)無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)則(ze)(ze)很少見。氧(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)以(yi)夾雜(za)形式在(zai)(zai)(zai)(zai)晶(jing)界出現對(dui)材料的(de)(de)(de)(de)韌性(xing)產生負面影響。而無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)很低(di),所以(yi)這種(zhong)銅(tong)(tong)的(de)(de)(de)(de)組(zu)織(zhi)是(shi)(shi)均勻的(de)(de)(de)(de)單相組(zu)織(zhi)對(dui)韌性(xing)有利。在(zai)(zai)(zai)(zai)無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)(de)多孔性(xing)是(shi)(shi)不常(chang)(chang)(chang)見的(de)(de)(de)(de),而在(zai)(zai)(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)則(ze)(ze)是(shi)(shi)常(chang)(chang)(chang)見的(de)(de)(de)(de)一(yi)種(zhong)缺陷。

二、熱軋組織和鑄(zhu)造組織的區別

低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)由(you)于經(jing)過熱軋,所以(yi)其(qi)組(zu)織屬熱加工組(zu)織,原來的(de)(de)鑄(zhu)造組(zu)織已經(jing)破碎,在(zai)8mm的(de)(de)桿(gan)時(shi)已有(you)(you)再(zai)結(jie)晶(jing)的(de)(de)形(xing)式出(chu)現,而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)屬鑄(zhu)造組(zu)織,晶(jing)粒(li)(li)粗(cu)大(da),這是(shi)為什么,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)的(de)(de)再(zai)結(jie)晶(jing)溫度(du)較(jiao)(jiao)高,需要較(jiao)(jiao)高退火(huo)(huo)溫度(du)的(de)(de)固有(you)(you)原因(yin)。這是(shi)因(yin)為,再(zai)結(jie)晶(jing)發生在(zai)晶(jing)粒(li)(li)邊(bian)(bian)界(jie)附近,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)組(zu)織晶(jing)粒(li)(li)粗(cu)大(da),晶(jing)粒(li)(li)尺寸甚至能達幾個(ge)毫(hao)米,因(yin)而晶(jing)粒(li)(li)邊(bian)(bian)界(jie)少,即使(shi)通過拉制變形(xing),但(dan)晶(jing)粒(li)(li)邊(bian)(bian)界(jie)相對(dui)(dui)低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)還(huan)是(shi)較(jiao)(jiao)少,所以(yi)需要較(jiao)(jiao)高的(de)(de)退火(huo)(huo)功(gong)(gong)(gong)(gong)率。對(dui)(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)成功(gong)(gong)(gong)(gong)的(de)(de)退火(huo)(huo)要求是(shi):由(you)桿(gan)經(jing)拉制,但(dan)尚(shang)未鑄(zhu)造組(zu)織的(de)(de)線時(shi)的(de)(de)第一次退火(huo)(huo),其(qi)退火(huo)(huo)功(gong)(gong)(gong)(gong)率應比同(tong)樣情況的(de)(de)低氧(yang)(yang)(yang)銅(tong)(tong)高10——15%。經(jing)繼續拉制,在(zai)以(yi)后(hou)階(jie)段的(de)(de)退火(huo)(huo)功(gong)(gong)(gong)(gong)率應留有(you)(you)足夠的(de)(de)余量和(he)對(dui)(dui)低氧(yang)(yang)(yang)銅(tong)(tong)和(he)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)切實區(qu)別執行不同(tong)的(de)(de)退火(huo)(huo)工藝,以(yi)保證在(zai)制品和(he)成品導線的(de)(de)柔軟性。

三、夾(jia)雜,氧含(han)量波動,表面氧化物和可能(neng)存在的熱軋缺陷的差別(bie)

無(wu)氧(yang)(yang)(yang)銅桿的(de)可拉性(xing)在(zai)所(suo)有(you)線(xian)徑里與(yu)低氧(yang)(yang)(yang)銅桿相比(bi)都(dou)是(shi)優越的(de),除上述組(zu)織原因外,無(wu)氧(yang)(yang)(yang)銅桿夾雜少,含(han)氧(yang)(yang)(yang)量穩定(ding),無(wu)熱(re)軋可能(neng)產(chan)生的(de)缺陷,桿表氧(yang)(yang)(yang)化物(wu)厚度可達≤15A。在(zai)連(lian)鑄(zhu)連(lian)軋生產(chan)過程中如果工藝不穩定(ding),對氧(yang)(yang)(yang)監控不嚴,含(han)氧(yang)(yang)(yang)量不穩定(ding)將直接影響桿的(de)性(xing)能(neng)。如果桿的(de)表面氧(yang)(yang)(yang)化物(wu)能(neng)在(zai)后工序(xu)的(de)連(lian)續清洗中得以彌(mi)補外,但比(bi)較(jiao)麻煩的(de)是(shi)有(you)相當多的(de)氧(yang)(yang)(yang)化物(wu)存(cun)在(zai)于“皮(pi)下(xia)”,對拉線(xian)斷線(xian)影響更直接,故而在(zai)拉制微細線(xian),超(chao)微細線(xian)時(shi),為了(le)減(jian)少斷線(xian),有(you)時(shi)要對銅桿采取不得已的(de)辦法(fa)——剝皮(pi),甚至(zhi)二次剝皮(pi)的(de)原因所(suo)在(zai),目的(de)要除去皮(pi)下(xia)氧(yang)(yang)(yang)化物(wu)。

四、低氧(yang)銅桿(gan)和(he)無氧(yang)銅桿(gan)的韌性有(you)差別(bie)

兩者都可以拉到0.015mm,但在低溫(wen)超(chao)導線(xian)中(zhong)的(de)低溫(wen)級無氧銅,其細絲間(jian)(jian)的(de)間(jian)(jian)距只(zhi)有0.001mm.

五、從(cong)制桿的原材(cai)料(liao)到制線的經濟性有差別。

制造(zao)無氧(yang)銅(tong)桿(gan)要求(qiu)質量較高的(de)原材料。一般,拉(la)制直徑>1mm的(de)銅(tong)線時(shi),低(di)氧(yang)銅(tong)桿(gan)的(de)優點(dian)比(bi)較明顯,而無氧(yang)銅(tong)桿(gan)顯得更(geng)為優越的(de)是拉(la)制直徑<0.5mm的(de)銅(tong)線。

六(liu)、低氧銅(tong)桿的制線工藝與無氧銅(tong)桿的有(you)所不同(tong)。

低(di)氧(yang)銅(tong)桿(gan)的(de)(de)制(zhi)線(xian)工(gong)藝(yi)(yi)不(bu)能照搬到無氧(yang)銅(tong)桿(gan)的(de)(de)制(zhi)線(xian)工(gong)藝(yi)(yi)上來,至(zhi)少兩者的(de)(de)退(tui)火(huo)(huo)工(gong)藝(yi)(yi)是不(bu)同的(de)(de)。因為線(xian)的(de)(de)柔(rou)軟性深受材料(liao)成份和制(zhi)桿(gan),制(zhi)線(xian)和退(tui)火(huo)(huo)工(gong)藝(yi)(yi)的(de)(de)影響,不(bu)能簡(jian)單地說低(di)氧(yang)銅(tong)或無氧(yang)銅(tong)誰(shui)軟誰(shui)硬。