熱(re)門關鍵詞:
來(lai)源:行業動態 閱讀(du):109261 發布時間:2019-07-05
導讀:由于生(sheng)(sheng)產(chan)(chan)(chan)(chan)銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)兩者的(de)工藝不(bu)同,所(suo)生(sheng)(sheng)產(chan)(chan)(chan)(chan)的(de)銅(tong)(tong)(tong)桿(gan)(gan)(gan)中的(de)含(han)(han)(han)氧量(liang)及外觀就不(bu)同。上引生(sheng)(sheng)產(chan)(chan)(chan)(chan)的(de)銅(tong)(tong)(tong)桿(gan)(gan)(gan),工藝得當氧含(han)(han)(han)量(liang)在10ppm以下(xia),叫無氧銅(tong)(tong)(tong)桿(gan)(gan)(gan);連(lian)鑄連(lian)鑄生(sheng)(sheng)產(chan)(chan)(chan)(chan)的(de)銅(tong)(tong)(tong)桿(gan)(gan)(gan) 是(shi)在保(bao)護條件下(xia)的(de)熱軋(ya),氧含(han)(han)(han)量(liang)在200-500ppm范圍內(nei),但(dan)有(you)(you)時也高達700ppm以上,一般(ban)情況下(xia),此種方(fang)法生(sheng)(sheng)產(chan)(chan)(chan)(chan)的(de)銅(tong)(tong)(tong)外表光(guang)亮,低氧銅(tong)(tong)(tong)桿(gan)(gan)(gan),有(you)(you)時也叫光(guang)桿(gan)(gan)(gan)。
銅(tong)(tong)桿(gan)(gan)是電纜行業的(de)(de)主要(yao)原料(liao),生(sheng)(sheng)產(chan)的(de)(de)方式(shi)主要(yao)有(you)兩種(zhong)——連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)(ya)法和上引連(lian)(lian)鑄(zhu)(zhu)(zhu)法。連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)(ya)低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)(de)生(sheng)(sheng)產(chan)方法較(jiao)多,其特點是金屬在豎爐中融(rong)化后(hou),銅(tong)(tong)液通過(guo)保溫爐、溜(liu)槽、中間(jian)包,從澆(jiao)管進(jin)入(ru)封閉(bi)的(de)(de)模腔(qiang)內,采(cai)用較(jiao)大的(de)(de)冷(leng)(leng)卻(que)強度進(jin)行冷(leng)(leng)卻(que),形成鑄(zhu)(zhu)(zhu)坯,然后(hou)進(jin)行多道次(ci)軋(ya)(ya)制,生(sheng)(sheng)產(chan)的(de)(de)低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)為熱加工組織,原來的(de)(de)鑄(zhu)(zhu)(zhu)造(zao)組織已經破碎,含(han)氧(yang)(yang)量(liang)一(yi)般(ban)為200~400ppm之(zhi)間(jian)。無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)國內基本全部(bu)采(cai)用上引連(lian)(lian)鑄(zhu)(zhu)(zhu)法生(sheng)(sheng)產(chan),金屬在感(gan)應電爐中融(rong)化后(hou)通過(guo)石墨模進(jin)行上引連(lian)(lian)續(xu)鑄(zhu)(zhu)(zhu)造(zao),之(zhi)后(hou)進(jin)行冷(leng)(leng)軋(ya)(ya)或冷(leng)(leng)加工,生(sheng)(sheng)產(chan)的(de)(de)無氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)為鑄(zhu)(zhu)(zhu)造(zao)組織,含(han)氧(yang)(yang)量(liang)一(yi)般(ban)在20ppm以(yi)下。由(you)于制造(zao)工藝的(de)(de)不同(tong),所以(yi)在組織結構、氧(yang)(yang)含(han)量(liang)分布、雜(za)質(zhi)的(de)(de)形式(shi)及(ji)分布等諸多方面有(you)較(jiao)大差別。
一、拉制性能
銅桿的(de)拉(la)制(zhi)性能(neng)跟很多因素有(you)關,如雜質的(de)含量、氧含量及分(fen)布、工藝(yi)控(kong)制(zhi)等。下面分(fen)別從以(yi)上幾個方面對銅桿的(de)拉(la)制(zhi)性能(neng)進行分(fen)析。
1、熔化方(fang)式對S等雜質的影響(xiang)
連鑄(zhu)連軋生產銅(tong)(tong)桿主(zhu)要是通過氣(qi)體的(de)燃燒使銅(tong)(tong)桿熔化(hua),在燃燒的(de)過程中,通過氧化(hua)和揮(hui)發作用,可(ke)一定程度減少部(bu)分(fen)雜質進入(ru)銅(tong)(tong)液,因此連鑄(zhu)連軋法對原料要求相(xiang)對低一些。上引連鑄(zhu)生產無(wu)(wu)氧銅(tong)(tong)桿,由于是用感應電(dian)爐熔化(hua),電(dian)解銅(tong)(tong)表面的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都熔入(ru)到(dao)銅(tong)(tong)液中。其中熔入(ru)的(de)S對無(wu)(wu)氧銅(tong)(tong)桿塑性影響極(ji)大,會增加拉絲(si)斷(duan)線率。
2、鑄造過程中雜質的進入
在生產(chan)過(guo)程中,連(lian)鑄(zhu)連(lian)軋(ya)工(gong)藝(yi)需通(tong)(tong)(tong)(tong)過(guo)保溫爐、溜槽(cao)、中間包轉運(yun)銅(tong)液,相對容易造(zao)成耐火(huo)材料的(de)剝(bo)落(luo),在軋(ya)制(zhi)過(guo)程中需要通(tong)(tong)(tong)(tong)過(guo)軋(ya)輥,造(zao)成鐵質的(de)脫落(luo),會(hui)給(gei)銅(tong)桿造(zao)成外部(bu)夾(jia)雜。而熱軋(ya)中皮(pi)上和(he)皮(pi)下(xia)氧化物的(de)軋(ya)入(ru),會(hui)給(gei)低(di)氧桿的(de)拉(la)絲造(zao)成不利(li)的(de)影響。上引連(lian)鑄(zhu)法生產(chan)工(gong)藝(yi)流(liu)程較短,銅(tong)液是通(tong)(tong)(tong)(tong)過(guo)聯(lian)體爐內潛流(liu)式完成,對耐火(huo)材料的(de)沖擊不大,結(jie)晶是通(tong)(tong)(tong)(tong)過(guo)石墨(mo)模內進(jin)行,所以(yi)過(guo)程中可能產(chan)生的(de)污(wu)染(ran)源較少,雜質進(jin)入(ru)的(de)機(ji)會(hui)較少。
O、S、P是與銅(tong)(tong)會生產化合物的(de)元素。在(zai)熔態(tai)銅(tong)(tong)中,氧(yang)可以(yi)溶解一部分,但當銅(tong)(tong)冷凝時,氧(yang)幾乎不溶解于銅(tong)(tong)中。熔態(tai)時所溶解的(de)氧(yang),以(yi)銅(tong)(tong)=氧(yang)化亞銅(tong)(tong)共晶(jing)體析出(chu),分布在(zai)晶(jing)粒晶(jing)界(jie)處(chu)。銅(tong)(tong)-氧(yang)化亞銅(tong)(tong)共晶(jing)體的(de)出(chu)現,顯著降(jiang)低了銅(tong)(tong)的(de)塑性(xing)。
硫可以溶(rong)(rong)解(jie)在熔體的銅(tong)(tong)(tong)中(zhong),但在室(shi)溫下(xia),其溶(rong)(rong)解(jie)度幾乎降低(di)到零,它以硫化亞銅(tong)(tong)(tong)的形式出現在晶粒晶界處(chu),會顯(xian)著(zhu)降低(di)銅(tong)(tong)(tong)的塑性。
3、氧在低(di)氧銅桿和無氧銅桿中(zhong)分布形式及其影響
氧(yang)(yang)(yang)(yang)含(han)(han)量(liang)對低(di)氧(yang)(yang)(yang)(yang)銅(tong)桿的(de)拉(la)線性(xing)能有著明(ming)顯的(de)影響(xiang)。當氧(yang)(yang)(yang)(yang)含(han)(han)量(liang)增加到最佳(jia)值時,銅(tong)桿的(de)斷線率最低(di)。這是因為氧(yang)(yang)(yang)(yang)在與(yu)大部(bu)分(fen)雜質反應的(de)過(guo)程中都起(qi)到了清除器的(de)作用。適度的(de)氧(yang)(yang)(yang)(yang)還有利于(yu)去除銅(tong)液中的(de)氫,生成(cheng)水蒸氣溢出,減少氣孔的(de)形成(cheng)。最佳(jia)的(de)氧(yang)(yang)(yang)(yang)含(han)(han)量(liang)為拉(la)線工藝提供了最好的(de)條件。
低氧(yang)銅(tong)桿(gan)氧(yang)化(hua)物(wu)(wu)的(de)分(fen)(fen)布(bu):在連續(xu)澆(jiao)鑄中凝固的(de)最初階段,散熱(re)速率(lv)和(he)均(jun)勻(yun)冷卻是決定銅(tong)桿(gan)氧(yang)化(hua)物(wu)(wu)分(fen)(fen)布(bu)的(de)主要因素。不均(jun)勻(yun)冷卻會(hui)引起銅(tong)桿(gan)內部結構(gou)本質上的(de)差異,但后(hou)續(xu)的(de)熱(re)加工(gong),柱(zhu)狀晶通常(chang)會(hui)遭到破壞(huai),使氧(yang)化(hua)亞銅(tong)顆(ke)粒(li)(li)細微化(hua)和(he)均(jun)勻(yun)分(fen)(fen)布(bu)。氧(yang)化(hua)物(wu)(wu)顆(ke)粒(li)(li)聚(ju)集(ji)而產生的(de)典型情況是中心爆裂(lie)(lie)。除氧(yang)化(hua)物(wu)(wu)顆(ke)粒(li)(li)分(fen)(fen)布(bu)的(de)影響外,具有較小(xiao)氧(yang)化(hua)物(wu)(wu)顆(ke)粒(li)(li)的(de)銅(tong)桿(gan)顯示出較好的(de)拉線特性(xing),較大的(de)Cu2O顆(ke)粒(li)(li)容易造成應力集(ji)中點(dian)而斷裂(lie)(lie)。
無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)(yang)(yang)(yang)量(liang)超(chao)標(biao),銅(tong)(tong)(tong)桿變脆(cui),延伸率下(xia)降,拉伸式樣端口顯暗紅色,結晶(jing)組(zu)織疏松。當氧(yang)(yang)(yang)(yang)(yang)含量(liang)超(chao)出8ppm時,工藝(yi)性能(neng)(neng)(neng)變差,表(biao)現為鑄(zhu)造及拉伸過(guo)程中斷(duan)桿及斷(duan)線率極(ji)具增(zeng)高(gao)。這是(shi)由于氧(yang)(yang)(yang)(yang)(yang)能(neng)(neng)(neng)與銅(tong)(tong)(tong)生(sheng)成氧(yang)(yang)(yang)(yang)(yang)化亞銅(tong)(tong)(tong)脆(cui)性相,形成銅(tong)(tong)(tong)-氧(yang)(yang)(yang)(yang)(yang)化亞銅(tong)(tong)(tong)共(gong)晶(jing)體,以網狀組(zu)織分布在(zai)境界上。這種脆(cui)性相硬度高(gao),在(zai)冷變形時將會(hui)與銅(tong)(tong)(tong)機(ji)體脫離,導(dao)致銅(tong)(tong)(tong)桿的(de)機(ji)械性能(neng)(neng)(neng)下(xia)降,在(zai)后續加工中容易造成斷(duan)裂(lie)現象。氧(yang)(yang)(yang)(yang)(yang)含量(liang)高(gao)還能(neng)(neng)(neng)導(dao)致無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿導(dao)電(dian)率下(xia)降。因此(ci),必須嚴格控制上引連鑄(zhu)工藝(yi)及產品質量(liang)。
4、氫的影響
在上引(yin)連(lian)鑄中(zhong),氧含量控制較低,氧化(hua)物的副作(zuo)用唄**降低,但氫的影響成為(wei)較顯著的問題(ti)。吸氣后熔(rong)體中(zhong)存在平(ping)衡反應:H2O(g)=[O]+2[H];
氣(qi)體(ti)(ti)及疏(shu)松是(shi)在(zai)(zai)結晶(jing)的(de)(de)(de)過程中(zhong),氫(qing)從過飽和(he)的(de)(de)(de)溶液(ye)中(zhong)析出(chu)(chu)并聚(ju)集而形成(cheng)的(de)(de)(de)。在(zai)(zai)結晶(jing)前(qian)(qian)析出(chu)(chu)的(de)(de)(de)氫(qing)又(you)可還(huan)原氧化亞銅而生成(cheng)水氣(qi)泡。由(you)于上(shang)引(yin)鑄造的(de)(de)(de)特點是(shi)銅液(ye)自上(shang)而下的(de)(de)(de)結晶(jing),形成(cheng)的(de)(de)(de)液(ye)**形狀近似錐型。銅液(ye)結晶(jing)前(qian)(qian)析出(chu)(chu)的(de)(de)(de)氣(qi)體(ti)(ti)在(zai)(zai)上(shang)浮過程中(zhong)被堵(du)在(zai)(zai)凝固組織內(nei)(nei),結晶(jing)時(shi)在(zai)(zai)鑄桿內(nei)(nei)形成(cheng)氣(qi)孔(kong)。上(shang)引(yin)的(de)(de)(de)含氣(qi)量少時(shi),析出(chu)(chu)的(de)(de)(de)氫(qing)存在(zai)(zai)于晶(jing)界處,形成(cheng)疏(shu)松;含氣(qi)量多(duo)時(shi),則聚(ju)集成(cheng)氣(qi)孔(kong),因此(ci),氣(qi)孔(kong)和(he)疏(shu)松是(shi)氫(qing)氣(qi)和(he)水蒸氣(qi)兩者形成(cheng)的(de)(de)(de)。
氫來源于上引生產過程(cheng)中的各個工(gong)藝環(huan)節,如原(yuan)料電解銅(tong)(tong)(tong)(tong)的“銅(tong)(tong)(tong)(tong)綠”、輔(fu)料木炭(tan)**、氣候環(huan)境**、石墨結晶器未干燥等。因(yin)此(ci),熔化爐中的銅(tong)(tong)(tong)(tong)液表(biao)面應覆蓋經烘(hong)烤的木炭(tan),電解銅(tong)(tong)(tong)(tong)應盡量(liang)(liang)去(qu)除“銅(tong)(tong)(tong)(tong)綠”、“銅(tong)(tong)(tong)(tong)豆(dou)”“耳朵”,對提(ti)高無氧(yang)銅(tong)(tong)(tong)(tong)桿質量(liang)(liang)非常重要(yao)。
在連鑄連軋(ya)工藝中,往往采(cai)用(yong)適度(du)控制(zhi)氧(yang)含量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于銅液(ye)在鑄造過程(cheng)中(zhong)是自下而上結晶(jing),銅液(ye)中(zhong)的(de)氧和氫(qing)所產生的(de)水(shui)蒸(zheng)氣很(hen)容(rong)易(yi)上浮(fu)跑(pao)出,銅液(ye)中(zhong)的(de)氫(qing)大部分能被(bei)有(you)效(xiao)去除(chu),因而對銅桿的(de)影響較小。
二、表面質量
在(zai)生產電(dian)磁線等產品的(de)(de)(de)過(guo)程(cheng)中,對銅桿(gan)的(de)(de)(de)表(biao)(biao)面(mian)質量也需提出要(yao)求。需要(yao)拉制后(hou)的(de)(de)(de)銅絲表(biao)(biao)面(mian)無毛刺、銅粉(fen)(fen)少、無油污。并通過(guo)扭轉試驗測量表(biao)(biao)面(mian)銅粉(fen)(fen)的(de)(de)(de)質量和扭轉后(hou)觀察(cha)銅桿(gan)的(de)(de)(de)復原(yuan)情況來(lai)判定其(qi)好壞。
在(zai)(zai)連鑄(zhu)(zhu)連軋(ya)(ya)過(guo)程中(zhong),從鑄(zhu)(zhu)造到軋(ya)(ya)制前(qian),溫度(du)高(gao),完全暴露于(yu)空(kong)氣中(zhong),使鑄(zhu)(zhu)坯(pi)表(biao)面形成(cheng)較厚(hou)的氧(yang)(yang)(yang)(yang)化層,在(zai)(zai)軋(ya)(ya)制過(guo)程中(zhong),隨著軋(ya)(ya)輥的轉動,氧(yang)(yang)(yang)(yang)化物(wu)顆粒(li)軋(ya)(ya)入銅(tong)線(xian)表(biao)面。由于(yu)氧(yang)(yang)(yang)(yang)化亞銅(tong)是高(gao)熔點(dian)脆性化合物(wu),對于(yu)軋(ya)(ya)入較深的氧(yang)(yang)(yang)(yang)化亞銅(tong),當成(cheng)條狀的聚(ju)集物(wu)遇模(mo)具拉(la)伸時,就會是銅(tong)桿外表(biao)面產生毛刺,給后續(xu)的涂漆造成(cheng)麻煩。
而上(shang)引連鑄工(gong)藝制造(zao)的(de)(de)無氧銅(tong)桿,由于鑄造(zao)和(he)冷(leng)卻完全與氧隔絕,后續亦無熱(re)軋過程,銅(tong)桿表(biao)面無軋入表(biao)面的(de)(de)氧化物(wu),質量(liang)較(jiao)好(hao),拉制后銅(tong)粉少,上(shang)述(shu)問題較(jiao)少存在(zai)。
無氧銅桿也分(fen)進(jin)口設(she)(she)備做(zuo)的(de)和國產(chan)設(she)(she)備做(zuo)的(de),但目前進(jin)口產(chan)品已無明顯優勢,銅桿產(chan)品出來后區別不是很大,只要銅板(ban)選的(de)好(hao),生(sheng)產(chan)控制比較穩定(ding),國產(chan)設(she)(she)備也能產(chan)出可(ke)拉伸0.05的(de)銅桿.進(jin)口設(she)(she)備一(yi)般是芬蘭奧(ao)托昆普的(de)設(she)(she)備,國產(chan)設(she)(she)備最好(hao)的(de)應(ying)該是上海的(de)海軍(jun)廠的(de)了,生(sheng)產(chan)時間最長,軍(jun)工企業(ye),質量(liang)可(ke)靠。
低(di)氧銅桿進口(kou)設(she)備國際(ji)主(zhu)要有兩(liang)種(zhong),一種(zhong)是(shi)美國南線(xian)設(she)備,英文是(shi)SOUTHWIRE,國內廠家(jia)是(shi)南京華新,江西銅業,另一種(zhong)是(shi)德國CONTIROD設(she)備,國內廠家(jia)是(shi)常州金源,天津(jin)大無縫。
無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)從(cong)含氧(yang)(yang)(yang)(yang)(yang)量(liang)上(shang)容易區(qu)別,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅是含氧(yang)(yang)(yang)(yang)(yang)量(liang)在10-20個(ge)(ge)PPM以下,但目前(qian)有(you)的(de)廠家只能(neng)(neng)做到(dao)50個(ge)(ge)PPM以下.低(di)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)在 200-400個(ge)(ge)PPM,好(hao)的(de)桿(gan)(gan)(gan)子一(yi)般含氧(yang)(yang)(yang)(yang)(yang)量(liang)控制在250個(ge)(ge)PPM左右,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)一(yi)般采取的(de)是上(shang)引法,低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)是連鑄連軋,兩種產(chan)品相對(dui)而言低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)漆包(bao)線(xian)(xian)性 能(neng)(neng)更適應些(xie),如(ru)柔軟性,回(hui)彈角,繞線(xian)(xian)性能(neng)(neng).但低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)對(dui)拉(la)絲(si)條件(jian)相對(dui)要(yao)苛刻些(xie),同樣(yang)拉(la)伸(shen)0.2的(de)細絲(si),如(ru)果伸(shen)線(xian)(xian)條件(jian)不好(hao),普通(tong)(tong)的(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)可拉(la)而好(hao)的(de)低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)就斷(duan) 線(xian)(xian),但如(ru)果放在好(hao)的(de)伸(shen)線(xian)(xian)條件(jian),同樣(yang)的(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)說不定就能(neng)(neng)拉(la)到(dao)雙零(ling)五,而普通(tong)(tong)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)最(zui)多只能(neng)(neng)拉(la)伸(shen)到(dao)0.1而已(yi),當然做的(de)最(zui)細的(de)如(ru)雙零(ling)二卻非得依靠(kao)進口的(de) 無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)了(le).目前(qian)有(you)企業嘗試用剝皮的(de)方(fang)式來(lai)處理低(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)來(lai)伸(shen)0.03線(xian)(xian).但有(you)關這方(fang)面的(de)內容我還(huan)不是很清楚。
音響(xiang)線一(yi)般(ban)反而喜歡用無氧桿(gan),這和無氧桿(gan)是單(dan)晶銅,低氧桿(gan)是多晶銅有關。
氧銅桿和無氧銅桿由于(yu)制造方法的不(bu)同,致使存在差別,具有各自的特點。
一、關于氧(yang)的吸入和脫(tuo)去(qu)以(yi)及它的存在(zai)狀態
生產銅(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)陰極(ji)銅(tong)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)溫下氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)中的(de)(de)(de)(de)(de)固溶度約(yue)2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)量一般在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是在(zai)(zai)銅(tong)的(de)(de)(de)(de)(de)液態(tai)(tai)下吸入的(de)(de)(de)(de)(de),而(er)上引法(fa)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)則相反,氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態(tai)(tai)銅(tong)下保持(chi)相當時(shi)間(jian)后,被還原而(er)脫去,通常(chang)這(zhe)種(zhong)(zhong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)量都(dou)在(zai)(zai)10—50ppm以(yi)下,最(zui)低(di)可達1-2ppm,從組織(zhi)上看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)狀態(tai)(tai),存在(zai)(zai)于(yu)晶粒(li)邊界附(fu)近,這(zhe)對(dui)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)而(er)言可以(yi)說是常(chang)見的(de)(de)(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)則很少見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)以(yi)夾雜形式在(zai)(zai)晶界出現對(dui)材料的(de)(de)(de)(de)(de)韌性(xing)產生負面(mian)影響。而(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所以(yi)這(zhe)種(zhong)(zhong)銅(tong)的(de)(de)(de)(de)(de)組織(zhi)是均勻的(de)(de)(de)(de)(de)單相組織(zhi)對(dui)韌性(xing)有利(li)。在(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)中的(de)(de)(de)(de)(de)多孔性(xing)是不常(chang)見的(de)(de)(de)(de)(de),而(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)中則是常(chang)見的(de)(de)(de)(de)(de)一種(zhong)(zhong)缺陷。
二、熱軋(ya)組(zu)織和鑄造組(zu)織的區(qu)別
低(di)(di)氧(yang)(yang)銅(tong)桿由于經過(guo)熱軋,所以(yi)其組(zu)織(zhi)屬熱加工組(zu)織(zhi),原(yuan)來的(de)(de)鑄造(zao)組(zu)織(zhi)已(yi)經破碎,在8mm的(de)(de)桿時(shi)已(yi)有再(zai)(zai)結(jie)晶(jing)(jing)的(de)(de)形(xing)式(shi)出現,而(er)無(wu)氧(yang)(yang)銅(tong)桿屬鑄造(zao)組(zu)織(zhi),晶(jing)(jing)粒(li)(li)粗大,這是(shi)為什么,無(wu)氧(yang)(yang)銅(tong)的(de)(de)再(zai)(zai)結(jie)晶(jing)(jing)溫度(du)較高(gao)(gao),需(xu)要較高(gao)(gao)退(tui)火(huo)溫度(du)的(de)(de)固(gu)有原(yuan)因(yin)(yin)(yin)。這是(shi)因(yin)(yin)(yin)為,再(zai)(zai)結(jie)晶(jing)(jing)發生在晶(jing)(jing)粒(li)(li)邊(bian)(bian)界(jie)(jie)附(fu)近,無(wu)氧(yang)(yang)銅(tong)桿組(zu)織(zhi)晶(jing)(jing)粒(li)(li)粗大,晶(jing)(jing)粒(li)(li)尺寸(cun)甚至能達(da)幾個毫(hao)米(mi),因(yin)(yin)(yin)而(er)晶(jing)(jing)粒(li)(li)邊(bian)(bian)界(jie)(jie)少,即使通(tong)過(guo)拉(la)制(zhi)(zhi)變形(xing),但晶(jing)(jing)粒(li)(li)邊(bian)(bian)界(jie)(jie)相(xiang)對(dui)低(di)(di)氧(yang)(yang)銅(tong)桿還是(shi)較少,所以(yi)需(xu)要較高(gao)(gao)的(de)(de)退(tui)火(huo)功率。對(dui)無(wu)氧(yang)(yang)銅(tong)成功的(de)(de)退(tui)火(huo)要求(qiu)是(shi):由桿經拉(la)制(zhi)(zhi),但尚(shang)未鑄造(zao)組(zu)織(zhi)的(de)(de)線(xian)時(shi)的(de)(de)第一次退(tui)火(huo),其退(tui)火(huo)功率應比同樣情(qing)況的(de)(de)低(di)(di)氧(yang)(yang)銅(tong)高(gao)(gao)10——15%。經繼續(xu)拉(la)制(zhi)(zhi),在以(yi)后階段的(de)(de)退(tui)火(huo)功率應留有足夠的(de)(de)余量和對(dui)低(di)(di)氧(yang)(yang)銅(tong)和無(wu)氧(yang)(yang)銅(tong)切實區別執行不同的(de)(de)退(tui)火(huo)工藝,以(yi)保證在制(zhi)(zhi)品和成品導(dao)線(xian)的(de)(de)柔軟性。
三、夾雜,氧含量波動,表面(mian)氧化物(wu)和可(ke)能存在的熱軋(ya)缺陷(xian)的差別
無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)可拉(la)性在(zai)(zai)所有(you)(you)線(xian)(xian)徑里與低氧(yang)(yang)銅(tong)(tong)桿(gan)相比都(dou)是(shi)優越(yue)的(de)(de)(de)(de),除上述組(zu)織原因外,無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)夾雜(za)少(shao),含氧(yang)(yang)量(liang)穩(wen)定,無(wu)(wu)熱軋可能(neng)產生(sheng)的(de)(de)(de)(de)缺陷,桿(gan)表(biao)氧(yang)(yang)化(hua)物(wu)厚度可達≤15A。在(zai)(zai)連鑄連軋生(sheng)產過(guo)程中(zhong)如果(guo)工藝不穩(wen)定,對(dui)氧(yang)(yang)監(jian)控不嚴,含氧(yang)(yang)量(liang)不穩(wen)定將直接(jie)影響桿(gan)的(de)(de)(de)(de)性能(neng)。如果(guo)桿(gan)的(de)(de)(de)(de)表(biao)面氧(yang)(yang)化(hua)物(wu)能(neng)在(zai)(zai)后(hou)工序的(de)(de)(de)(de)連續(xu)清(qing)洗中(zhong)得以(yi)彌補外,但比較麻(ma)煩的(de)(de)(de)(de)是(shi)有(you)(you)相當(dang)多的(de)(de)(de)(de)氧(yang)(yang)化(hua)物(wu)存在(zai)(zai)于“皮(pi)(pi)下(xia)”,對(dui)拉(la)線(xian)(xian)斷線(xian)(xian)影響更直接(jie),故而在(zai)(zai)拉(la)制微細線(xian)(xian),超微細線(xian)(xian)時,為了(le)減少(shao)斷線(xian)(xian),有(you)(you)時要(yao)對(dui)銅(tong)(tong)桿(gan)采(cai)取不得已的(de)(de)(de)(de)辦法——剝皮(pi)(pi),甚至二(er)次剝皮(pi)(pi)的(de)(de)(de)(de)原因所在(zai)(zai),目的(de)(de)(de)(de)要(yao)除去皮(pi)(pi)下(xia)氧(yang)(yang)化(hua)物(wu)。
四(si)、低氧銅桿和無(wu)氧銅桿的韌性有差別
兩者(zhe)都可以(yi)拉到0.015mm,但在低溫超導線中的(de)低溫級(ji)無氧銅,其細絲間的(de)間距(ju)只(zhi)有(you)0.001mm.
五、從制(zhi)(zhi)桿的原(yuan)材(cai)料到制(zhi)(zhi)線(xian)的經濟性有差別。
制(zhi)造無(wu)氧銅(tong)桿(gan)要(yao)求(qiu)質量較高的(de)(de)原材料。一般,拉制(zhi)直徑(jing)>1mm的(de)(de)銅(tong)線(xian)時,低氧銅(tong)桿(gan)的(de)(de)優(you)點比較明顯,而無(wu)氧銅(tong)桿(gan)顯得更為優(you)越的(de)(de)是(shi)拉制(zhi)直徑(jing)<0.5mm的(de)(de)銅(tong)線(xian)。
六、低(di)氧(yang)銅(tong)桿(gan)的(de)制(zhi)線工藝(yi)與無(wu)氧(yang)銅(tong)桿(gan)的(de)有所(suo)不(bu)同。
低氧(yang)(yang)銅(tong)桿(gan)(gan)的制(zhi)(zhi)線(xian)工藝(yi)(yi)(yi)(yi)不能(neng)照搬到無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)的制(zhi)(zhi)線(xian)工藝(yi)(yi)(yi)(yi)上來(lai),至少兩者(zhe)的退火工藝(yi)(yi)(yi)(yi)是不同(tong)的。因為線(xian)的柔軟性深(shen)受(shou)材料成份和(he)制(zhi)(zhi)桿(gan)(gan),制(zhi)(zhi)線(xian)和(he)退火工藝(yi)(yi)(yi)(yi)的影響(xiang),不能(neng)簡(jian)單(dan)地(di)說低氧(yang)(yang)銅(tong)或無(wu)氧(yang)(yang)銅(tong)誰(shui)軟誰(shui)硬。
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