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新城電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業(ye)動(dong)態 閱讀:109301 發(fa)布(bu)時間:2019-07-05

導讀(du):由(you)于生產(chan)銅桿的兩者的工藝不同(tong),所生產(chan)的銅桿中的含(han)氧(yang)量及外觀就不同(tong)。上引(yin)生產(chan)的銅桿,工藝得當氧(yang)含(han)量在10ppm以(yi)(yi)下,叫無氧(yang)銅桿;連鑄連鑄生產(chan)的銅桿 是在保護條件下的熱軋,氧(yang)含(han)量在200-500ppm范圍(wei)內,但有時也高達700ppm以(yi)(yi)上,一般情(qing)況下,此種方(fang)法生產(chan)的銅外表光亮,低(di)氧(yang)銅桿,有時也叫光桿。

銅(tong)桿是(shi)電(dian)(dian)纜行(xing)(xing)業的(de)(de)(de)(de)主要原料,生產的(de)(de)(de)(de)方(fang)式主要有(you)兩種——連(lian)鑄(zhu)連(lian)軋(ya)法和上引(yin)連(lian)鑄(zhu)法。連(lian)鑄(zhu)連(lian)軋(ya)低氧(yang)銅(tong)桿的(de)(de)(de)(de)生產方(fang)法較(jiao)多(duo),其特點是(shi)金(jin)屬(shu)在(zai)豎(shu)爐中融化(hua)后,銅(tong)液通(tong)過(guo)保溫爐、溜槽、中間包,從澆管(guan)進入封閉的(de)(de)(de)(de)模(mo)腔內,采(cai)用(yong)較(jiao)大(da)的(de)(de)(de)(de)冷卻強(qiang)度進行(xing)(xing)冷卻,形成鑄(zhu)坯,然后進行(xing)(xing)多(duo)道(dao)次(ci)軋(ya)制,生產的(de)(de)(de)(de)低氧(yang)銅(tong)桿為熱加(jia)工組織,原來的(de)(de)(de)(de)鑄(zhu)造(zao)組織已經破碎,含(han)氧(yang)量一般為200~400ppm之(zhi)間。無氧(yang)銅(tong)桿國內基本全部采(cai)用(yong)上引(yin)連(lian)鑄(zhu)法生產,金(jin)屬(shu)在(zai)感應電(dian)(dian)爐中融化(hua)后通(tong)過(guo)石墨模(mo)進行(xing)(xing)上引(yin)連(lian)續鑄(zhu)造(zao),之(zhi)后進行(xing)(xing)冷軋(ya)或冷加(jia)工,生產的(de)(de)(de)(de)無氧(yang)銅(tong)桿為鑄(zhu)造(zao)組織,含(han)氧(yang)量一般在(zai)20ppm以下(xia)。由于制造(zao)工藝的(de)(de)(de)(de)不同,所以在(zai)組織結構、氧(yang)含(han)量分布、雜質的(de)(de)(de)(de)形式及分布等諸多(duo)方(fang)面有(you)較(jiao)大(da)差(cha)別。

一、拉制性能

銅(tong)桿的(de)拉制(zhi)性能跟很多因(yin)素(su)有關,如(ru)雜(za)質的(de)含(han)量(liang)、氧含(han)量(liang)及分(fen)布、工藝控(kong)制(zhi)等。下面分(fen)別從以上幾個方面對銅(tong)桿的(de)拉制(zhi)性能進(jin)行分(fen)析。

1、熔化方(fang)式對S等雜質(zhi)的影響

連(lian)鑄(zhu)連(lian)軋生產銅(tong)桿主要是通過氣體的(de)燃(ran)燒(shao)使(shi)銅(tong)桿熔(rong)化(hua)(hua),在(zai)燃(ran)燒(shao)的(de)過程(cheng)中(zhong)(zhong),通過氧化(hua)(hua)和(he)揮發(fa)作用(yong),可(ke)一定(ding)程(cheng)度減(jian)少部分雜質進(jin)入銅(tong)液(ye),因此連(lian)鑄(zhu)連(lian)軋法對原料要求相對低一些。上(shang)引連(lian)鑄(zhu)生產無(wu)(wu)氧銅(tong)桿,由于(yu)是用(yong)感(gan)應(ying)電爐熔(rong)化(hua)(hua),電解銅(tong)表面的(de)“銅(tong)綠”“銅(tong)豆”基本都(dou)熔(rong)入到銅(tong)液(ye)中(zhong)(zhong)。其中(zhong)(zhong)熔(rong)入的(de)S對無(wu)(wu)氧銅(tong)桿塑性影響極大,會增加拉(la)絲斷線(xian)率。

2、鑄(zhu)造過(guo)程(cheng)中雜質的(de)進入

在(zai)生產過(guo)程中,連鑄連軋(ya)(ya)工藝需通(tong)過(guo)保溫爐、溜槽(cao)、中間包轉運銅液,相對(dui)容易造成耐火材(cai)料的(de)(de)剝落,在(zai)軋(ya)(ya)制過(guo)程中需要通(tong)過(guo)軋(ya)(ya)輥,造成鐵質的(de)(de)脫落,會(hui)(hui)給銅桿造成外部夾雜。而熱軋(ya)(ya)中皮上(shang)(shang)和皮下氧化物的(de)(de)軋(ya)(ya)入(ru),會(hui)(hui)給低氧桿的(de)(de)拉絲(si)造成不利的(de)(de)影響。上(shang)(shang)引(yin)連鑄法生產工藝流(liu)程較短,銅液是(shi)通(tong)過(guo)聯體爐內(nei)潛流(liu)式完成,對(dui)耐火材(cai)料的(de)(de)沖擊不大(da),結(jie)晶(jing)是(shi)通(tong)過(guo)石墨(mo)模內(nei)進(jin)行,所以過(guo)程中可能產生的(de)(de)污(wu)染源較少(shao),雜質進(jin)入(ru)的(de)(de)機會(hui)(hui)較少(shao)。

O、S、P是與銅(tong)(tong)(tong)(tong)會(hui)生產化合物的(de)元素。在熔態(tai)銅(tong)(tong)(tong)(tong)中,氧可(ke)以(yi)(yi)溶解(jie)一部分,但(dan)當(dang)銅(tong)(tong)(tong)(tong)冷凝時,氧幾乎不(bu)溶解(jie)于(yu)銅(tong)(tong)(tong)(tong)中。熔態(tai)時所溶解(jie)的(de)氧,以(yi)(yi)銅(tong)(tong)(tong)(tong)=氧化亞(ya)銅(tong)(tong)(tong)(tong)共晶體(ti)析(xi)出,分布在晶粒晶界(jie)處。銅(tong)(tong)(tong)(tong)-氧化亞(ya)銅(tong)(tong)(tong)(tong)共晶體(ti)的(de)出現,顯著(zhu)降低了銅(tong)(tong)(tong)(tong)的(de)塑性。

硫可以(yi)溶(rong)解(jie)在熔體的(de)銅(tong)中(zhong),但在室溫下,其溶(rong)解(jie)度幾(ji)乎降(jiang)低(di)到零,它以(yi)硫化亞(ya)銅(tong)的(de)形式出現在晶(jing)粒晶(jing)界處,會顯著降(jiang)低(di)銅(tong)的(de)塑(su)性(xing)。

3、氧(yang)在低(di)氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)中分布(bu)形式及其(qi)影(ying)響(xiang)

氧(yang)含量對(dui)低氧(yang)銅(tong)桿(gan)的(de)(de)拉(la)線性(xing)能有著(zhu)明(ming)顯(xian)的(de)(de)影響(xiang)。當氧(yang)含量增加到最(zui)(zui)佳值時(shi),銅(tong)桿(gan)的(de)(de)斷線率最(zui)(zui)低。這(zhe)是因為氧(yang)在(zai)與大部分雜質反應的(de)(de)過程中都起到了清除(chu)器(qi)的(de)(de)作用。適度的(de)(de)氧(yang)還有利(li)于(yu)去除(chu)銅(tong)液(ye)中的(de)(de)氫,生成水蒸氣(qi)溢出,減(jian)少氣(qi)孔(kong)的(de)(de)形成。最(zui)(zui)佳的(de)(de)氧(yang)含量為拉(la)線工藝提供了最(zui)(zui)好的(de)(de)條件(jian)。

低(di)氧(yang)(yang)銅(tong)桿氧(yang)(yang)化(hua)(hua)(hua)物(wu)的(de)(de)(de)分布(bu)(bu):在連續澆鑄中(zhong)凝固的(de)(de)(de)最初階(jie)段,散熱(re)速率和均勻(yun)冷(leng)卻是(shi)決(jue)定銅(tong)桿氧(yang)(yang)化(hua)(hua)(hua)物(wu)分布(bu)(bu)的(de)(de)(de)主要因素。不均勻(yun)冷(leng)卻會引起銅(tong)桿內(nei)部結構(gou)本(ben)質(zhi)上的(de)(de)(de)差(cha)異,但(dan)后續的(de)(de)(de)熱(re)加工,柱狀(zhuang)晶通常會遭到破壞,使(shi)氧(yang)(yang)化(hua)(hua)(hua)亞銅(tong)顆粒細(xi)微化(hua)(hua)(hua)和均勻(yun)分布(bu)(bu)。氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆粒聚集而(er)產生的(de)(de)(de)典型情況是(shi)中(zhong)心(xin)爆裂。除氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆粒分布(bu)(bu)的(de)(de)(de)影響(xiang)外,具有較小(xiao)氧(yang)(yang)化(hua)(hua)(hua)物(wu)顆粒的(de)(de)(de)銅(tong)桿顯(xian)示出較好的(de)(de)(de)拉線特性,較大的(de)(de)(de)Cu2O顆粒容易造成應力(li)集中(zhong)點而(er)斷裂。

無(wu)氧(yang)(yang)(yang)銅含氧(yang)(yang)(yang)量(liang)(liang)(liang)超標,銅桿變脆,延伸率(lv)(lv)下降,拉(la)伸式樣端口顯暗紅(hong)色(se),結晶組織(zhi)疏松。當氧(yang)(yang)(yang)含量(liang)(liang)(liang)超出8ppm時(shi),工(gong)藝性(xing)(xing)能(neng)變差(cha),表(biao)現為鑄造及(ji)(ji)拉(la)伸過程中(zhong)(zhong)斷(duan)桿及(ji)(ji)斷(duan)線(xian)率(lv)(lv)極(ji)具增(zeng)高。這(zhe)是(shi)由于氧(yang)(yang)(yang)能(neng)與(yu)銅生成(cheng)氧(yang)(yang)(yang)化(hua)亞銅脆性(xing)(xing)相,形(xing)成(cheng)銅-氧(yang)(yang)(yang)化(hua)亞銅共晶體,以(yi)網狀(zhuang)組織(zhi)分布(bu)在(zai)境(jing)界上。這(zhe)種脆性(xing)(xing)相硬度高,在(zai)冷變形(xing)時(shi)將會與(yu)銅機體脫離,導致(zhi)銅桿的機械性(xing)(xing)能(neng)下降,在(zai)后續加工(gong)中(zhong)(zhong)容(rong)易造成(cheng)斷(duan)裂現象。氧(yang)(yang)(yang)含量(liang)(liang)(liang)高還能(neng)導致(zhi)無(wu)氧(yang)(yang)(yang)銅桿導電(dian)率(lv)(lv)下降。因此,必須嚴格控制上引(yin)連(lian)鑄工(gong)藝及(ji)(ji)產品質量(liang)(liang)(liang)。

4、氫的影響

在(zai)上(shang)引連鑄中,氧(yang)含量控制較(jiao)低,氧(yang)化物的副作用唄**降低,但氫(qing)的影響成為較(jiao)顯著的問(wen)題。吸氣后熔體中存在(zai)平衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)體及疏松是在結晶(jing)(jing)(jing)的(de)(de)過(guo)程(cheng)中,氫從過(guo)飽和的(de)(de)溶液(ye)中析出(chu)并聚集而形(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)。在結晶(jing)(jing)(jing)前析出(chu)的(de)(de)氫又可還(huan)原氧化(hua)亞(ya)銅(tong)而生成(cheng)(cheng)(cheng)水氣(qi)(qi)(qi)泡。由于上(shang)(shang)(shang)引(yin)鑄造的(de)(de)特點是銅(tong)液(ye)自上(shang)(shang)(shang)而下的(de)(de)結晶(jing)(jing)(jing),形(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)液(ye)**形(xing)(xing)狀近似(si)錐型。銅(tong)液(ye)結晶(jing)(jing)(jing)前析出(chu)的(de)(de)氣(qi)(qi)(qi)體在上(shang)(shang)(shang)浮過(guo)程(cheng)中被堵在凝固組織內(nei),結晶(jing)(jing)(jing)時(shi)在鑄桿內(nei)形(xing)(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔。上(shang)(shang)(shang)引(yin)的(de)(de)含(han)氣(qi)(qi)(qi)量少時(shi),析出(chu)的(de)(de)氫存在于晶(jing)(jing)(jing)界處,形(xing)(xing)成(cheng)(cheng)(cheng)疏松;含(han)氣(qi)(qi)(qi)量多時(shi),則聚集成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)孔和疏松是氫氣(qi)(qi)(qi)和水蒸氣(qi)(qi)(qi)兩者形(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)。

氫來源于上引生產過程中的各個(ge)工藝環(huan)節,如原料電解銅(tong)的“銅(tong)綠(lv)”、輔料木(mu)炭**、氣候環(huan)境**、石墨結晶(jing)器未干燥等。因(yin)此,熔化爐中的銅(tong)液表面應(ying)覆蓋經烘烤的木(mu)炭,電解銅(tong)應(ying)盡量去(qu)除“銅(tong)綠(lv)”、“銅(tong)豆”“耳(er)朵”,對提高無(wu)氧銅(tong)桿質(zhi)量非常重要。

在連鑄連軋工藝中,往往采用適度控制氧含量(liang)來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于銅液在鑄造過程中(zhong)是自(zi)下(xia)而上結晶,銅液中(zhong)的氧和氫(qing)所產生的水蒸氣很容易上浮跑出,銅液中(zhong)的氫(qing)大部(bu)分能(neng)被有效去除,因而對銅桿的影(ying)響(xiang)較(jiao)小(xiao)。

二、表面質量

在生產電磁線等產品的(de)過程中,對(dui)銅(tong)(tong)桿的(de)表面質(zhi)量(liang)(liang)也需提出要求。需要拉制后(hou)的(de)銅(tong)(tong)絲(si)表面無(wu)毛刺、銅(tong)(tong)粉少(shao)、無(wu)油污。并通過扭轉試驗測(ce)量(liang)(liang)表面銅(tong)(tong)粉的(de)質(zhi)量(liang)(liang)和扭轉后(hou)觀察(cha)銅(tong)(tong)桿的(de)復原情況(kuang)來判定其好(hao)壞。

在連鑄(zhu)(zhu)連軋(ya)(ya)過(guo)程中,從鑄(zhu)(zhu)造到軋(ya)(ya)制(zhi)(zhi)前,溫度高(gao),完(wan)全暴露于(yu)空氣中,使鑄(zhu)(zhu)坯表面形成較厚的氧(yang)(yang)(yang)化(hua)(hua)層,在軋(ya)(ya)制(zhi)(zhi)過(guo)程中,隨著軋(ya)(ya)輥(gun)的轉動,氧(yang)(yang)(yang)化(hua)(hua)物(wu)顆(ke)粒軋(ya)(ya)入(ru)銅(tong)線表面。由于(yu)氧(yang)(yang)(yang)化(hua)(hua)亞銅(tong)是高(gao)熔點脆性化(hua)(hua)合物(wu),對于(yu)軋(ya)(ya)入(ru)較深(shen)的氧(yang)(yang)(yang)化(hua)(hua)亞銅(tong),當成條狀的聚集物(wu)遇(yu)模(mo)具拉伸時,就(jiu)會是銅(tong)桿外表面產生毛刺,給后續的涂漆造成麻煩(fan)。

而上引連(lian)鑄工藝制造的無氧(yang)銅桿,由(you)于鑄造和冷(leng)卻完(wan)全與氧(yang)隔絕,后續亦(yi)無熱(re)軋(ya)過程(cheng),銅桿表面無軋(ya)入(ru)表面的氧(yang)化物,質量較(jiao)好,拉制后銅粉少,上述問題較(jiao)少存在(zai)。

無(wu)(wu)氧銅桿(gan)也分進(jin)口(kou)(kou)設(she)備(bei)做的(de)和國產(chan)設(she)備(bei)做的(de),但目前(qian)進(jin)口(kou)(kou)產(chan)品(pin)已無(wu)(wu)明(ming)顯優勢,銅桿(gan)產(chan)品(pin)出(chu)來后區別不(bu)是很(hen)大,只要銅板選的(de)好(hao),生產(chan)控(kong)制(zhi)比較穩(wen)定,國產(chan)設(she)備(bei)也能產(chan)出(chu)可拉伸0.05的(de)銅桿(gan).進(jin)口(kou)(kou)設(she)備(bei)一般是芬蘭奧托(tuo)昆(kun)普(pu)的(de)設(she)備(bei),國產(chan)設(she)備(bei)最(zui)好(hao)的(de)應該是上海(hai)的(de)海(hai)軍廠的(de)了,生產(chan)時間(jian)最(zui)長(chang),軍工企(qi)業(ye),質量可靠。

低氧(yang)銅桿(gan)進口設(she)(she)備(bei)(bei)國際主要有(you)兩種,一種是(shi)(shi)美國南線設(she)(she)備(bei)(bei),英文是(shi)(shi)SOUTHWIRE,國內廠家是(shi)(shi)南京華新,江西銅業,另一種是(shi)(shi)德國CONTIROD設(she)(she)備(bei)(bei),國內廠家是(shi)(shi)常州金源(yuan),天(tian)津大無縫。

無(wu)氧(yang)(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從含氧(yang)(yang)(yang)(yang)量上容易區別,無(wu)氧(yang)(yang)(yang)(yang)銅是(shi)(shi)含氧(yang)(yang)(yang)(yang)量在10-20個(ge)PPM以(yi)下(xia),但(dan)(dan)(dan)目(mu)前有的(de)(de)廠家只能(neng)(neng)做到(dao)50個(ge)PPM以(yi)下(xia).低(di)(di)氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在 200-400個(ge)PPM,好的(de)(de)桿(gan)(gan)(gan)(gan)子(zi)(zi)一般含氧(yang)(yang)(yang)(yang)量控制在250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一般采取(qu)的(de)(de)是(shi)(shi)上引法,低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)(shi)連鑄連軋,兩種產(chan)品相對(dui)(dui)而(er)言低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)(dui)漆包線(xian)(xian)性 能(neng)(neng)更適應些(xie),如(ru)柔軟性,回彈角(jiao),繞線(xian)(xian)性能(neng)(neng).但(dan)(dan)(dan)低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)(dui)拉絲(si)條件相對(dui)(dui)要苛刻些(xie),同(tong)樣(yang)拉伸(shen)0.2的(de)(de)細絲(si),如(ru)果伸(shen)線(xian)(xian)條件不(bu)好,普通(tong)(tong)的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可拉而(er)好的(de)(de)低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷(duan) 線(xian)(xian),但(dan)(dan)(dan)如(ru)果放(fang)在好的(de)(de)伸(shen)線(xian)(xian)條件,同(tong)樣(yang)的(de)(de)桿(gan)(gan)(gan)(gan)子(zi)(zi),低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說不(bu)定就能(neng)(neng)拉到(dao)雙零五,而(er)普通(tong)(tong)無(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最多只能(neng)(neng)拉伸(shen)到(dao)0.1而(er)已,當然做的(de)(de)最細的(de)(de)如(ru)雙零二卻非得依靠進口的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了(le).目(mu)前有企業(ye)嘗試(shi)用剝皮的(de)(de)方式來處(chu)理低(di)(di)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來伸(shen)0.03線(xian)(xian).但(dan)(dan)(dan)有關(guan)這(zhe)方面的(de)(de)內(nei)容我還不(bu)是(shi)(shi)很清楚。

音響(xiang)線一(yi)般反(fan)而喜(xi)歡用無(wu)氧桿,這和無(wu)氧桿是單晶(jing)銅,低氧桿是多晶(jing)銅有關。

氧銅桿和無(wu)氧銅桿由于制造方法的不同,致使存(cun)在差別,具有各自(zi)的特點。

一、關于(yu)氧的吸入和(he)脫(tuo)去以及它的存在狀態

生產(chan)(chan)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)陰(yin)極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)(chang)溫(wen)下氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)固(gu)溶度(du)約(yue)2ppm。低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)液(ye)態(tai)(tai)下吸入的(de)(de)(de)(de)(de),而(er)上(shang)引(yin)法無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則相反(fan),氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)在(zai)(zai)(zai)液(ye)態(tai)(tai)銅(tong)(tong)(tong)(tong)下保持(chi)相當(dang)時間后,被還原而(er)脫去,通常(chang)(chang)這(zhe)種桿(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)(zai)10—50ppm以(yi)下,最低(di)(di)(di)可達1-2ppm,從組織(zhi)(zhi)上(shang)看,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態(tai)(tai),存在(zai)(zai)(zai)于晶(jing)粒邊界附近,這(zhe)對低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)而(er)言(yan)可以(yi)說(shuo)是常(chang)(chang)見(jian)(jian)的(de)(de)(de)(de)(de)但對無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則很少見(jian)(jian)。氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)晶(jing)界出現對材料的(de)(de)(de)(de)(de)韌(ren)性(xing)產(chan)(chan)生負面影響(xiang)。而(er)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)很低(di)(di)(di),所以(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)組織(zhi)(zhi)是均(jun)勻的(de)(de)(de)(de)(de)單相組織(zhi)(zhi)對韌(ren)性(xing)有利(li)。在(zai)(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)(de)(de)(de)多(duo)孔(kong)性(xing)是不常(chang)(chang)見(jian)(jian)的(de)(de)(de)(de)(de),而(er)在(zai)(zai)(zai)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中則是常(chang)(chang)見(jian)(jian)的(de)(de)(de)(de)(de)一(yi)種缺陷。

二、熱軋組織(zhi)和鑄(zhu)造組織(zhi)的區別

低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)由于經(jing)過(guo)熱軋,所(suo)以(yi)其(qi)組(zu)織屬熱加工組(zu)織,原來的(de)(de)鑄造(zao)組(zu)織已經(jing)破碎(sui),在(zai)8mm的(de)(de)桿(gan)(gan)時(shi)已有再(zai)結晶(jing)(jing)的(de)(de)形(xing)式(shi)出現,而無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)屬鑄造(zao)組(zu)織,晶(jing)(jing)粒(li)(li)粗大,這是(shi)為什么,無(wu)氧(yang)(yang)銅(tong)的(de)(de)再(zai)結晶(jing)(jing)溫度較高,需(xu)要(yao)較高退(tui)(tui)火溫度的(de)(de)固有原因(yin)。這是(shi)因(yin)為,再(zai)結晶(jing)(jing)發生在(zai)晶(jing)(jing)粒(li)(li)邊界附近(jin),無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)組(zu)織晶(jing)(jing)粒(li)(li)粗大,晶(jing)(jing)粒(li)(li)尺寸甚至能達幾個毫米,因(yin)而晶(jing)(jing)粒(li)(li)邊界少,即(ji)使通過(guo)拉制(zhi)變形(xing),但晶(jing)(jing)粒(li)(li)邊界相(xiang)對(dui)低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)還是(shi)較少,所(suo)以(yi)需(xu)要(yao)較高的(de)(de)退(tui)(tui)火功率。對(dui)無(wu)氧(yang)(yang)銅(tong)成功的(de)(de)退(tui)(tui)火要(yao)求(qiu)是(shi):由桿(gan)(gan)經(jing)拉制(zhi),但尚未(wei)鑄造(zao)組(zu)織的(de)(de)線時(shi)的(de)(de)第(di)一次(ci)退(tui)(tui)火,其(qi)退(tui)(tui)火功率應比同樣情況的(de)(de)低(di)氧(yang)(yang)銅(tong)高10——15%。經(jing)繼續拉制(zhi),在(zai)以(yi)后階(jie)段的(de)(de)退(tui)(tui)火功率應留有足(zu)夠的(de)(de)余(yu)量和(he)對(dui)低(di)氧(yang)(yang)銅(tong)和(he)無(wu)氧(yang)(yang)銅(tong)切(qie)實(shi)區別執行不同的(de)(de)退(tui)(tui)火工藝,以(yi)保證在(zai)制(zhi)品(pin)和(he)成品(pin)導線的(de)(de)柔軟性。

三、夾(jia)雜(za),氧含量波(bo)動,表(biao)面氧化物和可能存(cun)在的熱軋缺陷的差別

無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)可(ke)(ke)拉(la)(la)性在(zai)(zai)所(suo)有線(xian)(xian)徑(jing)里與低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)相比(bi)都是(shi)優越的(de)(de)(de),除(chu)上述組(zu)織(zhi)原(yuan)因外(wai),無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)夾雜少(shao),含氧(yang)(yang)(yang)(yang)量(liang)穩(wen)(wen)定(ding)(ding),無(wu)熱軋(ya)可(ke)(ke)能產生的(de)(de)(de)缺(que)陷(xian),桿(gan)(gan)(gan)表(biao)氧(yang)(yang)(yang)(yang)化(hua)物(wu)厚(hou)度可(ke)(ke)達≤15A。在(zai)(zai)連(lian)鑄連(lian)軋(ya)生產過程中(zhong)如(ru)果工(gong)藝不(bu)穩(wen)(wen)定(ding)(ding),對(dui)(dui)氧(yang)(yang)(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)(yang)(yang)量(liang)不(bu)穩(wen)(wen)定(ding)(ding)將直接(jie)影響桿(gan)(gan)(gan)的(de)(de)(de)性能。如(ru)果桿(gan)(gan)(gan)的(de)(de)(de)表(biao)面氧(yang)(yang)(yang)(yang)化(hua)物(wu)能在(zai)(zai)后工(gong)序的(de)(de)(de)連(lian)續清洗中(zhong)得以彌(mi)補外(wai),但比(bi)較(jiao)麻(ma)煩的(de)(de)(de)是(shi)有相當多的(de)(de)(de)氧(yang)(yang)(yang)(yang)化(hua)物(wu)存在(zai)(zai)于(yu)“皮(pi)下”,對(dui)(dui)拉(la)(la)線(xian)(xian)斷(duan)線(xian)(xian)影響更直接(jie),故而在(zai)(zai)拉(la)(la)制微細線(xian)(xian),超微細線(xian)(xian)時,為了減少(shao)斷(duan)線(xian)(xian),有時要(yao)對(dui)(dui)銅(tong)(tong)桿(gan)(gan)(gan)采(cai)取不(bu)得已的(de)(de)(de)辦法——剝皮(pi),甚至二次(ci)剝皮(pi)的(de)(de)(de)原(yuan)因所(suo)在(zai)(zai),目的(de)(de)(de)要(yao)除(chu)去(qu)皮(pi)下氧(yang)(yang)(yang)(yang)化(hua)物(wu)。

四、低氧銅桿和(he)無氧銅桿的(de)韌性有差別(bie)

兩(liang)者(zhe)都可以拉到0.015mm,但在低溫超(chao)導線(xian)中的低溫級無氧銅,其細絲間的間距(ju)只有0.001mm.

五、從制桿(gan)的原材料到制線的經濟性有差(cha)別。

制(zhi)(zhi)造無氧(yang)(yang)銅(tong)桿要求質量(liang)較高(gao)的(de)原材(cai)料。一般,拉制(zhi)(zhi)直徑>1mm的(de)銅(tong)線時(shi),低氧(yang)(yang)銅(tong)桿的(de)優(you)點比較明(ming)顯(xian),而無氧(yang)(yang)銅(tong)桿顯(xian)得(de)更為優(you)越的(de)是拉制(zhi)(zhi)直徑<0.5mm的(de)銅(tong)線。

六、低氧(yang)銅桿的(de)制線工藝與無氧(yang)銅桿的(de)有所不同。

低氧(yang)(yang)銅(tong)桿的(de)(de)制線(xian)(xian)工(gong)藝(yi)(yi)不(bu)(bu)能(neng)照搬到(dao)無氧(yang)(yang)銅(tong)桿的(de)(de)制線(xian)(xian)工(gong)藝(yi)(yi)上(shang)來,至少兩者的(de)(de)退火工(gong)藝(yi)(yi)是(shi)不(bu)(bu)同的(de)(de)。因為線(xian)(xian)的(de)(de)柔軟(ruan)性深受材(cai)料成份和制桿,制線(xian)(xian)和退火工(gong)藝(yi)(yi)的(de)(de)影響(xiang),不(bu)(bu)能(neng)簡單地說低氧(yang)(yang)銅(tong)或無氧(yang)(yang)銅(tong)誰軟(ruan)誰硬。