熱門關鍵詞:
來源:行(xing)業動態 閱讀:109327 發(fa)布(bu)時間:2019-07-05
導(dao)讀:由于(yu)生(sheng)(sheng)(sheng)產(chan)(chan)銅桿(gan)(gan)的兩者(zhe)的工藝不(bu)同,所生(sheng)(sheng)(sheng)產(chan)(chan)的銅桿(gan)(gan)中的含(han)氧(yang)(yang)量(liang)及外觀就不(bu)同。上引(yin)生(sheng)(sheng)(sheng)產(chan)(chan)的銅桿(gan)(gan),工藝得當氧(yang)(yang)含(han)量(liang)在10ppm以下,叫(jiao)無氧(yang)(yang)銅桿(gan)(gan);連鑄連鑄生(sheng)(sheng)(sheng)產(chan)(chan)的銅桿(gan)(gan) 是(shi)在保護條件下的熱軋,氧(yang)(yang)含(han)量(liang)在200-500ppm范圍(wei)內,但有時(shi)也高(gao)達700ppm以上,一般情況下,此種方法(fa)生(sheng)(sheng)(sheng)產(chan)(chan)的銅外表(biao)光(guang)(guang)亮,低氧(yang)(yang)銅桿(gan)(gan),有時(shi)也叫(jiao)光(guang)(guang)桿(gan)(gan)。
銅(tong)(tong)(tong)桿(gan)(gan)(gan)是(shi)電纜行(xing)業(ye)的(de)(de)(de)主(zhu)要原料,生(sheng)產的(de)(de)(de)方式主(zhu)要有兩種(zhong)——連(lian)鑄(zhu)連(lian)軋(ya)法和上(shang)引連(lian)鑄(zhu)法。連(lian)鑄(zhu)連(lian)軋(ya)低(di)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)生(sheng)產方法較多(duo),其特點是(shi)金屬在(zai)豎(shu)爐(lu)中融化(hua)后(hou)(hou),銅(tong)(tong)(tong)液通過保溫爐(lu)、溜槽、中間包(bao),從澆管進(jin)入(ru)封閉的(de)(de)(de)模腔內,采用(yong)較大的(de)(de)(de)冷卻(que)強度進(jin)行(xing)冷卻(que),形成鑄(zhu)坯,然后(hou)(hou)進(jin)行(xing)多(duo)道次軋(ya)制,生(sheng)產的(de)(de)(de)低(di)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)為(wei)(wei)熱加工(gong)組(zu)織(zhi),原來的(de)(de)(de)鑄(zhu)造(zao)(zao)組(zu)織(zhi)已(yi)經破碎(sui),含氧(yang)(yang)量(liang)一(yi)般(ban)為(wei)(wei)200~400ppm之(zhi)間。無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)國內基(ji)本全部(bu)采用(yong)上(shang)引連(lian)鑄(zhu)法生(sheng)產,金屬在(zai)感應(ying)電爐(lu)中融化(hua)后(hou)(hou)通過石墨模進(jin)行(xing)上(shang)引連(lian)續鑄(zhu)造(zao)(zao),之(zhi)后(hou)(hou)進(jin)行(xing)冷軋(ya)或冷加工(gong),生(sheng)產的(de)(de)(de)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)為(wei)(wei)鑄(zhu)造(zao)(zao)組(zu)織(zhi),含氧(yang)(yang)量(liang)一(yi)般(ban)在(zai)20ppm以下。由于(yu)制造(zao)(zao)工(gong)藝的(de)(de)(de)不同,所以在(zai)組(zu)織(zhi)結構、氧(yang)(yang)含量(liang)分布、雜(za)質(zhi)的(de)(de)(de)形式及分布等諸多(duo)方面有較大差別(bie)。
一、拉制性能
銅桿的拉制性能跟很多因素有關,如雜質(zhi)的含(han)量(liang)、氧含(han)量(liang)及(ji)分布(bu)、工藝控制等。下面(mian)(mian)分別從(cong)以上幾個方面(mian)(mian)對銅桿的拉制性能進(jin)行分析。
1、熔化方式對S等雜質的影響
連(lian)(lian)鑄連(lian)(lian)軋生(sheng)產銅(tong)桿主(zhu)要(yao)是通過氣體的(de)燃燒使(shi)銅(tong)桿熔(rong)化,在燃燒的(de)過程中(zhong),通過氧化和(he)揮發作用,可一(yi)定程度(du)減(jian)少部分雜質進入銅(tong)液,因此連(lian)(lian)鑄連(lian)(lian)軋法對(dui)原料要(yao)求相對(dui)低一(yi)些。上引連(lian)(lian)鑄生(sheng)產無(wu)氧銅(tong)桿,由(you)于是用感應電爐熔(rong)化,電解銅(tong)表面的(de)“銅(tong)綠(lv)”“銅(tong)豆”基本都熔(rong)入到銅(tong)液中(zhong)。其中(zhong)熔(rong)入的(de)S對(dui)無(wu)氧銅(tong)桿塑(su)性影(ying)響極大(da),會增(zeng)加拉絲(si)斷(duan)線率。
2、鑄造(zao)過程中雜質的進入
在生產過程(cheng)中(zhong)(zhong),連(lian)鑄連(lian)軋(ya)(ya)(ya)工(gong)藝需(xu)通過保溫爐、溜槽、中(zhong)(zhong)間包轉(zhuan)運銅(tong)(tong)液,相對(dui)容易造(zao)(zao)(zao)成(cheng)耐火材料(liao)的(de)剝落,在軋(ya)(ya)(ya)制過程(cheng)中(zhong)(zhong)需(xu)要(yao)通過軋(ya)(ya)(ya)輥,造(zao)(zao)(zao)成(cheng)鐵質(zhi)的(de)脫落,會(hui)給銅(tong)(tong)桿造(zao)(zao)(zao)成(cheng)外部夾雜。而熱(re)軋(ya)(ya)(ya)中(zhong)(zhong)皮上和皮下氧化物(wu)的(de)軋(ya)(ya)(ya)入,會(hui)給低氧桿的(de)拉絲造(zao)(zao)(zao)成(cheng)不利的(de)影響。上引連(lian)鑄法生產工(gong)藝流程(cheng)較(jiao)短,銅(tong)(tong)液是通過聯體爐內潛流式完成(cheng),對(dui)耐火材料(liao)的(de)沖擊不大,結晶是通過石(shi)墨模內進(jin)行,所以過程(cheng)中(zhong)(zhong)可(ke)能產生的(de)污染(ran)源較(jiao)少,雜質(zhi)進(jin)入的(de)機(ji)會(hui)較(jiao)少。
O、S、P是與銅(tong)(tong)會生(sheng)產化(hua)合(he)物的元素(su)。在(zai)熔態銅(tong)(tong)中(zhong),氧可以(yi)溶(rong)解一部分,但當(dang)銅(tong)(tong)冷凝(ning)時,氧幾乎不溶(rong)解于(yu)銅(tong)(tong)中(zhong)。熔態時所溶(rong)解的氧,以(yi)銅(tong)(tong)=氧化(hua)亞銅(tong)(tong)共晶(jing)(jing)體(ti)析出(chu),分布(bu)在(zai)晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)(tong)-氧化(hua)亞銅(tong)(tong)共晶(jing)(jing)體(ti)的出(chu)現,顯(xian)著降低(di)了銅(tong)(tong)的塑性。
硫可以溶解在熔(rong)體(ti)的銅中,但在室(shi)溫下,其溶解度幾乎降低到零,它以硫化亞(ya)銅的形式(shi)出現在晶粒晶界處,會顯著降低銅的塑性。
3、氧(yang)(yang)在低氧(yang)(yang)銅桿和無氧(yang)(yang)銅桿中分布形式及其影響(xiang)
氧(yang)含量(liang)對低(di)氧(yang)銅(tong)(tong)桿的(de)(de)拉(la)線(xian)性能有著明顯的(de)(de)影響(xiang)。當氧(yang)含量(liang)增加到最(zui)(zui)佳(jia)值時,銅(tong)(tong)桿的(de)(de)斷線(xian)率最(zui)(zui)低(di)。這是因(yin)為氧(yang)在與大部分雜質反(fan)應(ying)的(de)(de)過程中都起到了清除器的(de)(de)作用。適度的(de)(de)氧(yang)還有利(li)于(yu)去除銅(tong)(tong)液中的(de)(de)氫,生成(cheng)水(shui)蒸氣(qi)溢出,減少氣(qi)孔的(de)(de)形(xing)成(cheng)。最(zui)(zui)佳(jia)的(de)(de)氧(yang)含量(liang)為拉(la)線(xian)工(gong)藝提供了最(zui)(zui)好的(de)(de)條件。
低氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)(wu)的分布(bu):在連續(xu)澆鑄中(zhong)凝固的最初(chu)階(jie)段,散(san)熱速率和均(jun)(jun)勻(yun)冷卻是決定銅(tong)桿(gan)(gan)(gan)氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)(wu)分布(bu)的主(zhu)要因素(su)。不均(jun)(jun)勻(yun)冷卻會引起銅(tong)桿(gan)(gan)(gan)內部結構本質上的差(cha)異,但后續(xu)的熱加工(gong),柱狀晶(jing)通常會遭到(dao)破壞,使氧(yang)(yang)(yang)化(hua)(hua)(hua)亞銅(tong)顆(ke)粒細微化(hua)(hua)(hua)和均(jun)(jun)勻(yun)分布(bu)。氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)(wu)顆(ke)粒聚集而(er)產(chan)生(sheng)的典型情況是中(zhong)心爆裂。除氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)(wu)顆(ke)粒分布(bu)的影響外,具有較小氧(yang)(yang)(yang)化(hua)(hua)(hua)物(wu)(wu)顆(ke)粒的銅(tong)桿(gan)(gan)(gan)顯示出較好的拉線(xian)特性,較大的Cu2O顆(ke)粒容易造(zao)成應力集中(zhong)點而(er)斷(duan)裂。
無(wu)氧(yang)(yang)銅(tong)(tong)含氧(yang)(yang)量超(chao)標(biao),銅(tong)(tong)桿變脆,延伸率下降,拉伸式(shi)樣端口(kou)顯(xian)暗紅色,結晶組(zu)織(zhi)疏松(song)。當氧(yang)(yang)含量超(chao)出8ppm時(shi),工藝性(xing)能變差(cha),表現為鑄(zhu)造及(ji)拉伸過(guo)程中斷(duan)(duan)桿及(ji)斷(duan)(duan)線率極具增(zeng)高。這是由于氧(yang)(yang)能與銅(tong)(tong)生成氧(yang)(yang)化亞銅(tong)(tong)脆性(xing)相,形(xing)成銅(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)共晶體(ti),以網狀(zhuang)組(zu)織(zhi)分布在境(jing)界上。這種脆性(xing)相硬度(du)高,在冷變形(xing)時(shi)將會與銅(tong)(tong)機體(ti)脫離,導致銅(tong)(tong)桿的機械(xie)性(xing)能下降,在后續加(jia)工中容易造成斷(duan)(duan)裂現象。氧(yang)(yang)含量高還(huan)能導致無(wu)氧(yang)(yang)銅(tong)(tong)桿導電率下降。因此,必須嚴格控制上引連(lian)鑄(zhu)工藝及(ji)產品(pin)質量。
4、氫的影響
在(zai)上引(yin)連(lian)鑄中(zhong),氧含(han)量控(kong)制較低(di),氧化物的副作(zuo)用唄(bai)**降低(di),但(dan)氫的影響成為較顯著的問(wen)題。吸氣后熔體中(zhong)存(cun)在(zai)平衡反應:H2O(g)=[O]+2[H];
氣(qi)體及疏(shu)松(song)是在(zai)結(jie)晶(jing)的(de)(de)過程(cheng)中,氫(qing)(qing)從過飽和的(de)(de)溶液(ye)中析(xi)(xi)(xi)出(chu)并聚集而形(xing)(xing)成(cheng)的(de)(de)。在(zai)結(jie)晶(jing)前(qian)析(xi)(xi)(xi)出(chu)的(de)(de)氫(qing)(qing)又可還(huan)原氧化亞銅(tong)而生(sheng)成(cheng)水氣(qi)泡。由(you)于上(shang)引(yin)鑄(zhu)造(zao)的(de)(de)特點是銅(tong)液(ye)自上(shang)而下的(de)(de)結(jie)晶(jing),形(xing)(xing)成(cheng)的(de)(de)液(ye)**形(xing)(xing)狀近似錐型。銅(tong)液(ye)結(jie)晶(jing)前(qian)析(xi)(xi)(xi)出(chu)的(de)(de)氣(qi)體在(zai)上(shang)浮過程(cheng)中被堵在(zai)凝固組(zu)織內,結(jie)晶(jing)時在(zai)鑄(zhu)桿內形(xing)(xing)成(cheng)氣(qi)孔(kong)。上(shang)引(yin)的(de)(de)含(han)氣(qi)量(liang)少時,析(xi)(xi)(xi)出(chu)的(de)(de)氫(qing)(qing)存在(zai)于晶(jing)界處,形(xing)(xing)成(cheng)疏(shu)松(song);含(han)氣(qi)量(liang)多(duo)時,則(ze)聚集成(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和疏(shu)松(song)是氫(qing)(qing)氣(qi)和水蒸氣(qi)兩(liang)者形(xing)(xing)成(cheng)的(de)(de)。
氫來源于(yu)上引生(sheng)產過程中的各個工藝(yi)環節(jie),如原料電解銅的“銅綠”、輔料木(mu)炭**、氣候環境**、石墨結晶器未干燥(zao)等。因此,熔(rong)化爐(lu)中的銅液表面應(ying)覆(fu)蓋經烘烤(kao)的木(mu)炭,電解銅應(ying)盡量(liang)(liang)去(qu)除“銅綠”、“銅豆”“耳朵(duo)”,對(dui)提高無氧銅桿質(zhi)量(liang)(liang)非常重要。
在連鑄連軋工藝(yi)中,往往采用適度(du)控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅(tong)液在鑄造過程中是自下而上結晶,銅(tong)液中的氧和氫所產生的水(shui)蒸氣很(hen)容易上浮跑出,銅(tong)液中的氫大(da)部(bu)分能被(bei)有效去除,因而對(dui)銅(tong)桿的影響較小(xiao)。
二、表面質量
在生產(chan)電磁線等(deng)產(chan)品的(de)過(guo)程中,對銅桿的(de)表(biao)(biao)面(mian)質量(liang)也需(xu)提(ti)出要求(qiu)。需(xu)要拉制后的(de)銅絲表(biao)(biao)面(mian)無毛刺、銅粉(fen)少、無油(you)污。并通過(guo)扭轉試驗測(ce)量(liang)表(biao)(biao)面(mian)銅粉(fen)的(de)質量(liang)和(he)扭轉后觀察(cha)銅桿的(de)復原情況來判定其好壞。
在連(lian)鑄連(lian)軋(ya)過(guo)程中(zhong),從鑄造(zao)到軋(ya)制前,溫度高,完全暴露(lu)于(yu)空(kong)氣中(zhong),使鑄坯(pi)表面形成較(jiao)(jiao)厚的(de)氧(yang)化(hua)層(ceng),在軋(ya)制過(guo)程中(zhong),隨(sui)著(zhu)軋(ya)輥的(de)轉動,氧(yang)化(hua)物顆(ke)粒軋(ya)入銅(tong)(tong)線表面。由于(yu)氧(yang)化(hua)亞(ya)銅(tong)(tong)是(shi)高熔點脆(cui)性化(hua)合物,對于(yu)軋(ya)入較(jiao)(jiao)深的(de)氧(yang)化(hua)亞(ya)銅(tong)(tong),當成條狀(zhuang)的(de)聚集物遇(yu)模具拉伸時,就會是(shi)銅(tong)(tong)桿外(wai)表面產生毛刺,給后續的(de)涂漆(qi)造(zao)成麻(ma)煩。
而上引(yin)連鑄(zhu)工藝(yi)制造的(de)無(wu)氧(yang)銅(tong)桿,由(you)于鑄(zhu)造和(he)冷卻完全與氧(yang)隔絕,后續亦無(wu)熱軋過程,銅(tong)桿表面(mian)無(wu)軋入表面(mian)的(de)氧(yang)化(hua)物,質量較好,拉制后銅(tong)粉少,上述問題較少存在。
無氧銅桿(gan)也(ye)分進(jin)口設(she)備做的(de)和國(guo)產(chan)(chan)設(she)備做的(de),但目(mu)前(qian)進(jin)口產(chan)(chan)品已無明顯優(you)勢(shi),銅桿(gan)產(chan)(chan)品出(chu)來后區別不是很大,只(zhi)要銅板選的(de)好,生(sheng)產(chan)(chan)控制(zhi)比較穩定,國(guo)產(chan)(chan)設(she)備也(ye)能產(chan)(chan)出(chu)可拉伸(shen)0.05的(de)銅桿(gan).進(jin)口設(she)備一般是芬蘭(lan)奧(ao)托昆普的(de)設(she)備,國(guo)產(chan)(chan)設(she)備最(zui)好的(de)應該是上海的(de)海軍廠的(de)了,生(sheng)產(chan)(chan)時(shi)間最(zui)長,軍工企業(ye),質量可靠。
低氧銅桿進(jin)口設備國際主要有兩種(zhong),一種(zhong)是美國南(nan)線設備,英文是SOUTHWIRE,國內(nei)廠家是南(nan)京(jing)華新,江(jiang)西(xi)銅業,另一種(zhong)是德國CONTIROD設備,國內(nei)廠家是常州金源,天津大無縫。
無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)上(shang)(shang)容(rong)易區別,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅是含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)在(zai)10-20個(ge)PPM以下,但目(mu)前有(you)的(de)(de)(de)廠家只能(neng)做到(dao)50個(ge)PPM以下.低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子一(yi)(yi)般(ban)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)控制在(zai)250個(ge)PPM左(zuo)右,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)一(yi)(yi)般(ban)采取的(de)(de)(de)是上(shang)(shang)引法,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)是連(lian)鑄連(lian)軋,兩種產品相對而(er)言(yan)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對漆包線性 能(neng)更適應些,如(ru)(ru)柔(rou)軟(ruan)性,回彈角(jiao),繞線性能(neng).但低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對拉絲(si)條(tiao)(tiao)件(jian)相對要苛(ke)刻些,同(tong)(tong)樣(yang)拉伸(shen)0.2的(de)(de)(de)細(xi)絲(si),如(ru)(ru)果伸(shen)線條(tiao)(tiao)件(jian)不(bu)好,普(pu)通的(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)可拉而(er)好的(de)(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)就(jiu)斷(duan) 線,但如(ru)(ru)果放(fang)在(zai)好的(de)(de)(de)伸(shen)線條(tiao)(tiao)件(jian),同(tong)(tong)樣(yang)的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)說不(bu)定(ding)就(jiu)能(neng)拉到(dao)雙(shuang)(shuang)零五,而(er)普(pu)通無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)最多只能(neng)拉伸(shen)到(dao)0.1而(er)已,當然做的(de)(de)(de)最細(xi)的(de)(de)(de)如(ru)(ru)雙(shuang)(shuang)零二卻非得依靠進口的(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)(gan)了.目(mu)前有(you)企業嘗試(shi)用剝皮的(de)(de)(de)方(fang)式來處理低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)來伸(shen)0.03線.但有(you)關這方(fang)面的(de)(de)(de)內(nei)容(rong)我還不(bu)是很清楚(chu)。
音響(xiang)線(xian)一(yi)般反而喜歡用無氧(yang)桿(gan),這和無氧(yang)桿(gan)是單晶銅,低氧(yang)桿(gan)是多晶銅有關。
氧銅(tong)桿和無氧銅(tong)桿由于制造方法的不同,致使存在差別,具有各自的特點。
一、關于氧(yang)的吸入和脫(tuo)去以(yi)及它的存(cun)在狀態(tai)
生產(chan)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)陰(yin)極銅(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量一般在(zai)(zai)10—50ppm,在(zai)(zai)常溫(wen)下氧(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)固溶度約2ppm。低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量一般在(zai)(zai)200(175)—400(450)ppm,因此(ci)氧(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是在(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)(de)液態下吸入的(de)(de)(de)(de)(de),而(er)(er)(er)上引法無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)則相反,氧(yang)(yang)(yang)在(zai)(zai)液態銅(tong)(tong)下保持相當時間后(hou),被還原而(er)(er)(er)脫去(qu),通常這(zhe)種(zhong)桿(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量都(dou)在(zai)(zai)10—50ppm以(yi)(yi)(yi)下,最低(di)可(ke)達1-2ppm,從組(zu)織(zhi)上看,低(di)氧(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang),以(yi)(yi)(yi)氧(yang)(yang)(yang)化銅(tong)(tong)狀(zhuang)態,存在(zai)(zai)于晶粒邊界附近,這(zhe)對低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)而(er)(er)(er)言(yan)可(ke)以(yi)(yi)(yi)說是常見(jian)的(de)(de)(de)(de)(de)但對無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)則很少見(jian)。氧(yang)(yang)(yang)化銅(tong)(tong)以(yi)(yi)(yi)夾雜(za)形式在(zai)(zai)晶界出現對材料的(de)(de)(de)(de)(de)韌性產(chan)生負面影(ying)響。而(er)(er)(er)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)很低(di),所以(yi)(yi)(yi)這(zhe)種(zhong)銅(tong)(tong)的(de)(de)(de)(de)(de)組(zu)織(zhi)是均勻的(de)(de)(de)(de)(de)單相組(zu)織(zhi)對韌性有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)(de)(de)多(duo)孔(kong)性是不常見(jian)的(de)(de)(de)(de)(de),而(er)(er)(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)中(zhong)則是常見(jian)的(de)(de)(de)(de)(de)一種(zhong)缺陷。
二、熱軋組(zu)(zu)織(zhi)和鑄(zhu)造組(zu)(zu)織(zhi)的區別(bie)
低氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)由于經(jing)(jing)過熱軋,所(suo)以其(qi)組織屬熱加工(gong)組織,原來的(de)鑄造(zao)組織已經(jing)(jing)破碎,在(zai)(zai)8mm的(de)桿(gan)(gan)時(shi)已有(you)再結晶(jing)的(de)形式出現(xian),而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)屬鑄造(zao)組織,晶(jing)粒(li)(li)粗大(da)(da),這(zhe)是(shi)(shi)為(wei)什么,無(wu)氧(yang)(yang)銅(tong)(tong)(tong)的(de)再結晶(jing)溫(wen)度較(jiao)(jiao)高,需要較(jiao)(jiao)高退(tui)火(huo)溫(wen)度的(de)固有(you)原因(yin)。這(zhe)是(shi)(shi)因(yin)為(wei),再結晶(jing)發生在(zai)(zai)晶(jing)粒(li)(li)邊(bian)界(jie)附(fu)近(jin),無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)組織晶(jing)粒(li)(li)粗大(da)(da),晶(jing)粒(li)(li)尺(chi)寸甚至(zhi)能達幾個毫(hao)米,因(yin)而(er)晶(jing)粒(li)(li)邊(bian)界(jie)少,即使通(tong)過拉制變形,但晶(jing)粒(li)(li)邊(bian)界(jie)相對低氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)還是(shi)(shi)較(jiao)(jiao)少,所(suo)以需要較(jiao)(jiao)高的(de)退(tui)火(huo)功率(lv)。對無(wu)氧(yang)(yang)銅(tong)(tong)(tong)成功的(de)退(tui)火(huo)要求是(shi)(shi):由桿(gan)(gan)經(jing)(jing)拉制,但尚未鑄造(zao)組織的(de)線時(shi)的(de)第一次(ci)退(tui)火(huo),其(qi)退(tui)火(huo)功率(lv)應比(bi)同樣(yang)情(qing)況的(de)低氧(yang)(yang)銅(tong)(tong)(tong)高10——15%。經(jing)(jing)繼(ji)續拉制,在(zai)(zai)以后階段的(de)退(tui)火(huo)功率(lv)應留有(you)足夠(gou)的(de)余量和對低氧(yang)(yang)銅(tong)(tong)(tong)和無(wu)氧(yang)(yang)銅(tong)(tong)(tong)切實區別執行不同的(de)退(tui)火(huo)工(gong)藝,以保(bao)證在(zai)(zai)制品和成品導線的(de)柔軟性。
三、夾雜(za),氧含量波(bo)動,表(biao)面氧化物(wu)和(he)可能(neng)存在的熱(re)軋缺陷的差(cha)別
無氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)的(de)可(ke)拉性在(zai)(zai)(zai)所有線(xian)(xian)(xian)(xian)(xian)徑里與低氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)相(xiang)(xiang)比都是(shi)優越的(de),除上述組織原因(yin)外,無氧(yang)銅(tong)(tong)(tong)桿(gan)(gan)夾雜少,含氧(yang)量(liang)穩定,無熱軋可(ke)能(neng)產(chan)(chan)生(sheng)的(de)缺陷,桿(gan)(gan)表(biao)(biao)氧(yang)化(hua)(hua)(hua)物(wu)厚(hou)度(du)可(ke)達≤15A。在(zai)(zai)(zai)連(lian)鑄連(lian)軋生(sheng)產(chan)(chan)過(guo)程中如(ru)果工藝不(bu)穩定,對氧(yang)監控不(bu)嚴,含氧(yang)量(liang)不(bu)穩定將直接(jie)影響桿(gan)(gan)的(de)性能(neng)。如(ru)果桿(gan)(gan)的(de)表(biao)(biao)面氧(yang)化(hua)(hua)(hua)物(wu)能(neng)在(zai)(zai)(zai)后工序(xu)的(de)連(lian)續清洗中得以彌(mi)補外,但比較麻煩的(de)是(shi)有相(xiang)(xiang)當(dang)多的(de)氧(yang)化(hua)(hua)(hua)物(wu)存在(zai)(zai)(zai)于“皮(pi)(pi)下(xia)(xia)”,對拉線(xian)(xian)(xian)(xian)(xian)斷線(xian)(xian)(xian)(xian)(xian)影響更(geng)直接(jie),故而在(zai)(zai)(zai)拉制微(wei)(wei)細(xi)線(xian)(xian)(xian)(xian)(xian),超微(wei)(wei)細(xi)線(xian)(xian)(xian)(xian)(xian)時(shi),為了減(jian)少斷線(xian)(xian)(xian)(xian)(xian),有時(shi)要對銅(tong)(tong)(tong)桿(gan)(gan)采(cai)取(qu)不(bu)得已的(de)辦法——剝(bo)皮(pi)(pi),甚至二次剝(bo)皮(pi)(pi)的(de)原因(yin)所在(zai)(zai)(zai),目的(de)要除去皮(pi)(pi)下(xia)(xia)氧(yang)化(hua)(hua)(hua)物(wu)。
四、低氧(yang)(yang)銅桿和無氧(yang)(yang)銅桿的(de)韌性有差(cha)別
兩(liang)者都可以拉到0.015mm,但在低溫(wen)超導線(xian)中的低溫(wen)級(ji)無氧(yang)銅(tong),其細絲間(jian)的間(jian)距只有(you)0.001mm.
五、從制桿的原材料(liao)到制線的經(jing)濟性有差別。
制造無氧(yang)銅(tong)(tong)桿要求(qiu)質量較高的原材料。一般,拉(la)制直(zhi)徑(jing)>1mm的銅(tong)(tong)線時,低氧(yang)銅(tong)(tong)桿的優點比較明顯,而(er)無氧(yang)銅(tong)(tong)桿顯得更為優越的是拉(la)制直(zhi)徑(jing)<0.5mm的銅(tong)(tong)線。
六、低(di)氧(yang)銅桿(gan)的制(zhi)線工藝與無(wu)氧(yang)銅桿(gan)的有(you)所不同(tong)。
低氧(yang)銅(tong)(tong)桿(gan)的(de)(de)制(zhi)線(xian)工(gong)(gong)藝(yi)(yi)不能照搬(ban)到無氧(yang)銅(tong)(tong)桿(gan)的(de)(de)制(zhi)線(xian)工(gong)(gong)藝(yi)(yi)上來,至(zhi)少兩(liang)者的(de)(de)退(tui)火工(gong)(gong)藝(yi)(yi)是不同的(de)(de)。因為線(xian)的(de)(de)柔(rou)軟性深受材料(liao)成份(fen)和(he)制(zhi)桿(gan),制(zhi)線(xian)和(he)退(tui)火工(gong)(gong)藝(yi)(yi)的(de)(de)影響,不能簡(jian)單地說低氧(yang)銅(tong)(tong)或無氧(yang)銅(tong)(tong)誰(shui)軟誰(shui)硬(ying)。
上一條(tiao)興隆臺絕緣層厚度不合格對電線電纜有何影響