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元寶電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來(lai)源:行業動態(tai) 閱讀:109469 發布時間(jian):2019-07-05

導讀:由于生(sheng)(sheng)產(chan)(chan)銅(tong)(tong)桿(gan)的兩者的工(gong)藝不同,所生(sheng)(sheng)產(chan)(chan)的銅(tong)(tong)桿(gan)中的含氧(yang)量(liang)及外觀(guan)就(jiu)不同。上引生(sheng)(sheng)產(chan)(chan)的銅(tong)(tong)桿(gan),工(gong)藝得當氧(yang)含量(liang)在(zai)10ppm以(yi)下,叫無氧(yang)銅(tong)(tong)桿(gan);連鑄連鑄生(sheng)(sheng)產(chan)(chan)的銅(tong)(tong)桿(gan) 是(shi)在(zai)保護條(tiao)件下的熱軋(ya),氧(yang)含量(liang)在(zai)200-500ppm范圍(wei)內,但有時也(ye)(ye)高(gao)達700ppm以(yi)上,一般情況下,此種(zhong)方(fang)法生(sheng)(sheng)產(chan)(chan)的銅(tong)(tong)外表光亮,低氧(yang)銅(tong)(tong)桿(gan),有時也(ye)(ye)叫光桿(gan)。

銅(tong)桿(gan)(gan)是(shi)(shi)電纜行(xing)業(ye)的(de)(de)(de)主要(yao)(yao)原料,生產(chan)的(de)(de)(de)方(fang)式主要(yao)(yao)有兩(liang)種——連鑄(zhu)連軋法和上(shang)引(yin)連鑄(zhu)法。連鑄(zhu)連軋低氧銅(tong)桿(gan)(gan)的(de)(de)(de)生產(chan)方(fang)法較多,其特點(dian)是(shi)(shi)金屬在豎爐(lu)(lu)中融化后,銅(tong)液通過(guo)保溫爐(lu)(lu)、溜槽(cao)、中間包,從澆管進(jin)(jin)入封(feng)閉的(de)(de)(de)模腔(qiang)內,采用較大的(de)(de)(de)冷卻強度進(jin)(jin)行(xing)冷卻,形(xing)成鑄(zhu)坯,然(ran)后進(jin)(jin)行(xing)多道次軋制,生產(chan)的(de)(de)(de)低氧銅(tong)桿(gan)(gan)為熱加(jia)工(gong)組(zu)(zu)織(zhi),原來的(de)(de)(de)鑄(zhu)造(zao)(zao)組(zu)(zu)織(zhi)已經破(po)碎,含(han)(han)氧量(liang)一(yi)般(ban)為200~400ppm之間。無氧銅(tong)桿(gan)(gan)國內基(ji)本全部采用上(shang)引(yin)連鑄(zhu)法生產(chan),金屬在感應(ying)電爐(lu)(lu)中融化后通過(guo)石(shi)墨(mo)模進(jin)(jin)行(xing)上(shang)引(yin)連續鑄(zhu)造(zao)(zao),之后進(jin)(jin)行(xing)冷軋或(huo)冷加(jia)工(gong),生產(chan)的(de)(de)(de)無氧銅(tong)桿(gan)(gan)為鑄(zhu)造(zao)(zao)組(zu)(zu)織(zhi),含(han)(han)氧量(liang)一(yi)般(ban)在20ppm以下。由于(yu)制造(zao)(zao)工(gong)藝的(de)(de)(de)不同,所以在組(zu)(zu)織(zhi)結構、氧含(han)(han)量(liang)分布(bu)、雜(za)質的(de)(de)(de)形(xing)式及分布(bu)等諸多方(fang)面有較大差別。

一、拉制性能

銅(tong)桿的(de)(de)(de)拉制性(xing)(xing)能(neng)跟很多(duo)因素有(you)關,如雜質的(de)(de)(de)含(han)量(liang)、氧(yang)含(han)量(liang)及(ji)分布、工藝控制等。下面分別從以上(shang)幾(ji)個方面對銅(tong)桿的(de)(de)(de)拉制性(xing)(xing)能(neng)進行分析。

1、熔化方式(shi)對S等(deng)雜質的影響

連(lian)鑄(zhu)連(lian)軋生產(chan)銅桿(gan)主要(yao)是(shi)通過(guo)(guo)氣體(ti)的(de)燃燒(shao)(shao)使銅桿(gan)熔化(hua),在(zai)燃燒(shao)(shao)的(de)過(guo)(guo)程中,通過(guo)(guo)氧(yang)化(hua)和揮發作用,可一(yi)定程度減(jian)少部(bu)分(fen)雜質進入銅液,因此連(lian)鑄(zhu)連(lian)軋法對原料(liao)要(yao)求相對低一(yi)些(xie)。上引連(lian)鑄(zhu)生產(chan)無氧(yang)銅桿(gan),由(you)于(yu)是(shi)用感應(ying)電爐熔化(hua),電解銅表面(mian)的(de)“銅綠”“銅豆”基本都熔入到銅液中。其中熔入的(de)S對無氧(yang)銅桿(gan)塑性(xing)影響極(ji)大,會增加(jia)拉(la)絲斷線率。

2、鑄造過程(cheng)中雜(za)質的進入

在生產(chan)過(guo)程中(zhong),連(lian)鑄連(lian)軋(ya)工藝需(xu)通(tong)過(guo)保(bao)溫(wen)爐(lu)、溜槽、中(zhong)間包(bao)轉(zhuan)運(yun)銅液,相對(dui)容(rong)易造成(cheng)耐(nai)火材(cai)料的(de)剝(bo)落(luo),在軋(ya)制過(guo)程中(zhong)需(xu)要通(tong)過(guo)軋(ya)輥(gun),造成(cheng)鐵質的(de)脫(tuo)落(luo),會給(gei)銅桿造成(cheng)外部夾雜(za)。而熱軋(ya)中(zhong)皮(pi)上和皮(pi)下氧化物的(de)軋(ya)入,會給(gei)低氧桿的(de)拉絲造成(cheng)不利的(de)影(ying)響。上引連(lian)鑄法生產(chan)工藝流程較(jiao)短,銅液是通(tong)過(guo)聯(lian)體爐(lu)內潛流式(shi)完(wan)成(cheng),對(dui)耐(nai)火材(cai)料的(de)沖擊不大,結晶是通(tong)過(guo)石(shi)墨模內進(jin)行,所以過(guo)程中(zhong)可(ke)能產(chan)生的(de)污染(ran)源較(jiao)少,雜(za)質進(jin)入的(de)機會較(jiao)少。

O、S、P是(shi)與銅會生產化(hua)合(he)物(wu)的元素。在熔態(tai)銅中,氧可以(yi)溶解一部分(fen),但當銅冷(leng)凝時,氧幾乎不溶解于(yu)銅中。熔態(tai)時所溶解的氧,以(yi)銅=氧化(hua)亞(ya)銅共晶體析(xi)出(chu),分(fen)布在晶粒(li)晶界處(chu)。銅-氧化(hua)亞(ya)銅共晶體的出(chu)現(xian),顯著降低了(le)銅的塑性。

硫可以溶(rong)解在(zai)熔體的(de)銅中,但在(zai)室溫下,其(qi)溶(rong)解度(du)幾乎(hu)降低到零(ling),它以硫化(hua)亞銅的(de)形式出現在(zai)晶粒(li)晶界(jie)處(chu),會顯(xian)著降低銅的(de)塑性。

3、氧(yang)在低氧(yang)銅(tong)桿和(he)無氧(yang)銅(tong)桿中(zhong)分布形式(shi)及其影(ying)響

氧(yang)含量(liang)對低氧(yang)銅桿的(de)(de)拉線(xian)(xian)性能有(you)著明顯(xian)的(de)(de)影響。當氧(yang)含量(liang)增加(jia)到最(zui)佳值時,銅桿的(de)(de)斷線(xian)(xian)率最(zui)低。這(zhe)是因為氧(yang)在與大(da)部分雜質反應的(de)(de)過程(cheng)中(zhong)都起(qi)到了(le)清除(chu)器的(de)(de)作用。適度(du)的(de)(de)氧(yang)還有(you)利于去除(chu)銅液中(zhong)的(de)(de)氫,生成水蒸氣溢出,減(jian)少氣孔的(de)(de)形成。最(zui)佳的(de)(de)氧(yang)含量(liang)為拉線(xian)(xian)工藝(yi)提供了(le)最(zui)好的(de)(de)條(tiao)件。

低氧(yang)銅(tong)(tong)桿(gan)(gan)氧(yang)化(hua)物(wu)(wu)的(de)分(fen)布(bu)(bu):在連續澆(jiao)鑄(zhu)中凝固的(de)最初階(jie)段,散熱(re)速(su)率(lv)和(he)均(jun)勻冷(leng)(leng)卻是(shi)決定銅(tong)(tong)桿(gan)(gan)氧(yang)化(hua)物(wu)(wu)分(fen)布(bu)(bu)的(de)主要因素。不均(jun)勻冷(leng)(leng)卻會引起銅(tong)(tong)桿(gan)(gan)內部結構本(ben)質上的(de)差異,但后(hou)續的(de)熱(re)加(jia)工,柱狀晶通(tong)常會遭(zao)到破壞(huai),使氧(yang)化(hua)亞(ya)銅(tong)(tong)顆(ke)(ke)粒(li)細微(wei)化(hua)和(he)均(jun)勻分(fen)布(bu)(bu)。氧(yang)化(hua)物(wu)(wu)顆(ke)(ke)粒(li)聚集(ji)而產生的(de)典型情況是(shi)中心爆裂。除氧(yang)化(hua)物(wu)(wu)顆(ke)(ke)粒(li)分(fen)布(bu)(bu)的(de)影響外(wai),具(ju)有較小(xiao)氧(yang)化(hua)物(wu)(wu)顆(ke)(ke)粒(li)的(de)銅(tong)(tong)桿(gan)(gan)顯(xian)示出較好的(de)拉線特性(xing),較大的(de)Cu2O顆(ke)(ke)粒(li)容易造成應力集(ji)中點而斷(duan)裂。

無氧(yang)(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)(yang)量超(chao)標,銅(tong)(tong)(tong)桿(gan)變脆(cui),延伸(shen)率下降(jiang)(jiang),拉伸(shen)式樣端口顯暗(an)紅(hong)色,結(jie)晶組(zu)(zu)織疏松。當氧(yang)(yang)(yang)含量超(chao)出(chu)8ppm時(shi),工藝(yi)性能變差,表現為(wei)鑄(zhu)造及(ji)拉伸(shen)過程中(zhong)斷(duan)桿(gan)及(ji)斷(duan)線率極具(ju)增(zeng)高(gao)。這是由于(yu)氧(yang)(yang)(yang)能與銅(tong)(tong)(tong)生成氧(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)脆(cui)性相,形成銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)晶體,以網狀組(zu)(zu)織分(fen)布在境(jing)界上(shang)(shang)。這種脆(cui)性相硬度高(gao),在冷變形時(shi)將會與銅(tong)(tong)(tong)機體脫(tuo)離,導致銅(tong)(tong)(tong)桿(gan)的(de)機械(xie)性能下降(jiang)(jiang),在后(hou)續(xu)加(jia)工中(zhong)容易(yi)造成斷(duan)裂現象。氧(yang)(yang)(yang)含量高(gao)還能導致無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)導電率下降(jiang)(jiang)。因此(ci),必須嚴格控制(zhi)上(shang)(shang)引連鑄(zhu)工藝(yi)及(ji)產品質量。

4、氫的影響

在(zai)上引(yin)連(lian)鑄中,氧(yang)含(han)量控制較低(di),氧(yang)化物(wu)的副作用唄**降低(di),但氫的影響成為較顯著的問(wen)題。吸氣后熔體中存在(zai)平衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)體(ti)及(ji)疏松是在(zai)(zai)結晶的(de)(de)過(guo)程中(zhong)(zhong),氫從(cong)過(guo)飽和的(de)(de)溶液中(zhong)(zhong)析(xi)出(chu)并(bing)聚集(ji)而形成(cheng)的(de)(de)。在(zai)(zai)結晶前(qian)析(xi)出(chu)的(de)(de)氫又可還原氧化亞(ya)銅(tong)而生成(cheng)水(shui)氣(qi)(qi)泡(pao)。由(you)于上(shang)引(yin)鑄(zhu)造的(de)(de)特點是銅(tong)液自上(shang)而下的(de)(de)結晶,形成(cheng)的(de)(de)液**形狀近似錐(zhui)型。銅(tong)液結晶前(qian)析(xi)出(chu)的(de)(de)氣(qi)(qi)體(ti)在(zai)(zai)上(shang)浮過(guo)程中(zhong)(zhong)被堵在(zai)(zai)凝固組織內(nei),結晶時在(zai)(zai)鑄(zhu)桿內(nei)形成(cheng)氣(qi)(qi)孔。上(shang)引(yin)的(de)(de)含(han)(han)氣(qi)(qi)量少時,析(xi)出(chu)的(de)(de)氫存(cun)在(zai)(zai)于晶界(jie)處,形成(cheng)疏松;含(han)(han)氣(qi)(qi)量多時,則聚集(ji)成(cheng)氣(qi)(qi)孔,因此,氣(qi)(qi)孔和疏松是氫氣(qi)(qi)和水(shui)蒸氣(qi)(qi)兩(liang)者形成(cheng)的(de)(de)。

氫(qing)來源于上引生產過程中(zhong)的各個(ge)工藝環節,如原料(liao)電解銅(tong)的“銅(tong)綠(lv)”、輔料(liao)木炭**、氣候環境**、石(shi)墨結晶(jing)器(qi)未干燥(zao)等。因此,熔化(hua)爐中(zhong)的銅(tong)液表面應覆蓋(gai)經烘烤的木炭,電解銅(tong)應盡量(liang)去除“銅(tong)綠(lv)”、“銅(tong)豆”“耳(er)朵”,對提高(gao)無氧銅(tong)桿質量(liang)非常重要。

在連鑄連軋工(gong)藝中,往往采用適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由于銅液(ye)在鑄造(zao)過程(cheng)中(zhong)是自下而上(shang)結晶,銅液(ye)中(zhong)的(de)(de)氧和氫所產(chan)生的(de)(de)水蒸氣很容(rong)易上(shang)浮跑出(chu),銅液(ye)中(zhong)的(de)(de)氫大部分能被有(you)效去除,因(yin)而對銅桿的(de)(de)影響較(jiao)小。

二、表面質量

在生產(chan)電磁線等產(chan)品的(de)過(guo)程中,對銅桿的(de)表面質量也需提出要(yao)求。需要(yao)拉制后(hou)的(de)銅絲(si)表面無(wu)毛(mao)刺、銅粉少(shao)、無(wu)油污。并(bing)通(tong)過(guo)扭(niu)轉(zhuan)試驗(yan)測量表面銅粉的(de)質量和扭(niu)轉(zhuan)后(hou)觀察銅桿的(de)復原(yuan)情況來判(pan)定其好壞。

在連鑄連軋(ya)過(guo)(guo)程(cheng)中(zhong),從鑄造(zao)到軋(ya)制(zhi)前,溫(wen)度高(gao),完全暴露(lu)于空氣中(zhong),使鑄坯表面形(xing)成較厚的(de)(de)氧(yang)化(hua)層,在軋(ya)制(zhi)過(guo)(guo)程(cheng)中(zhong),隨(sui)著軋(ya)輥的(de)(de)轉(zhuan)動,氧(yang)化(hua)物顆粒軋(ya)入銅線表面。由于氧(yang)化(hua)亞(ya)(ya)銅是(shi)高(gao)熔點脆(cui)性化(hua)合物,對于軋(ya)入較深的(de)(de)氧(yang)化(hua)亞(ya)(ya)銅,當成條狀的(de)(de)聚集物遇模具拉伸時,就會是(shi)銅桿外表面產生毛刺(ci),給后(hou)續的(de)(de)涂(tu)漆造(zao)成麻煩。

而上引連鑄(zhu)(zhu)工藝(yi)制(zhi)造的無(wu)(wu)氧銅桿(gan)(gan),由于鑄(zhu)(zhu)造和冷(leng)卻完全與氧隔絕,后續亦無(wu)(wu)熱軋(ya)(ya)過程,銅桿(gan)(gan)表面(mian)無(wu)(wu)軋(ya)(ya)入表面(mian)的氧化物,質量較好(hao),拉制(zhi)后銅粉(fen)少(shao),上述問題較少(shao)存在(zai)。

無(wu)氧(yang)銅(tong)桿也分進(jin)口(kou)設(she)(she)(she)備做的(de)(de)(de)(de)和國產設(she)(she)(she)備做的(de)(de)(de)(de),但目前進(jin)口(kou)產品已(yi)無(wu)明顯(xian)優勢,銅(tong)桿產品出來后區別不是很(hen)大(da),只要(yao)銅(tong)板選(xuan)的(de)(de)(de)(de)好,生產控制比較穩定,國產設(she)(she)(she)備也能產出可拉伸0.05的(de)(de)(de)(de)銅(tong)桿.進(jin)口(kou)設(she)(she)(she)備一般是芬蘭奧托昆普的(de)(de)(de)(de)設(she)(she)(she)備,國產設(she)(she)(she)備最好的(de)(de)(de)(de)應該是上海的(de)(de)(de)(de)海軍廠的(de)(de)(de)(de)了,生產時間最長,軍工企(qi)業,質量可靠(kao)。

低氧(yang)銅桿進口設備國(guo)際(ji)主要有兩種,一種是(shi)(shi)美國(guo)南(nan)線設備,英(ying)文是(shi)(shi)SOUTHWIRE,國(guo)內(nei)廠家(jia)是(shi)(shi)南(nan)京華新,江西(xi)銅業,另一種是(shi)(shi)德國(guo)CONTIROD設備,國(guo)內(nei)廠家(jia)是(shi)(shi)常州(zhou)金(jin)源,天津大無(wu)縫。

無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)及(ji)低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從(cong)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)上容易區別,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅是含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)在10-20個(ge)(ge)PPM以下,但(dan)目前有的(de)廠家只能(neng)做(zuo)到(dao)50個(ge)(ge)PPM以下.低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在 200-400個(ge)(ge)PPM,好(hao)的(de)桿(gan)(gan)(gan)(gan)子(zi)一(yi)般含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)(liang)控制在250個(ge)(ge)PPM左(zuo)右(you),無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一(yi)般采取(qu)的(de)是上引法,低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是連(lian)鑄連(lian)軋,兩種產(chan)品(pin)相對(dui)而言低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)漆包線性 能(neng)更適應些,如(ru)柔軟性,回彈角,繞(rao)線性能(neng).但(dan)低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)拉絲(si)條(tiao)件(jian)(jian)相對(dui)要苛刻些,同樣(yang)拉伸(shen)0.2的(de)細(xi)絲(si),如(ru)果(guo)伸(shen)線條(tiao)件(jian)(jian)不(bu)好(hao),普通的(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可拉而好(hao)的(de)低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷 線,但(dan)如(ru)果(guo)放在好(hao)的(de)伸(shen)線條(tiao)件(jian)(jian),同樣(yang)的(de)桿(gan)(gan)(gan)(gan)子(zi),低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說(shuo)不(bu)定就能(neng)拉到(dao)雙(shuang)零(ling)五,而普通無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最多只能(neng)拉伸(shen)到(dao)0.1而已,當然做(zuo)的(de)最細(xi)的(de)如(ru)雙(shuang)零(ling)二卻非(fei)得依靠進口的(de) 無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了.目前有企(qi)業(ye)嘗試(shi)用剝皮(pi)的(de)方(fang)式(shi)來處理低氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來伸(shen)0.03線.但(dan)有關這(zhe)方(fang)面的(de)內(nei)容我(wo)還不(bu)是很清楚。

音響線一般(ban)反而喜歡用無(wu)氧(yang)桿,這和無(wu)氧(yang)桿是(shi)單晶銅,低氧(yang)桿是(shi)多晶銅有關。

氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)由(you)于制(zhi)造方法的不同,致使存在(zai)差(cha)別,具有各自(zi)的特點。

一、關于氧的(de)吸入和脫去以及(ji)它的(de)存在狀態(tai)

生產(chan)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量一般在(zai)10—50ppm,在(zai)常(chang)溫下氧(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)固(gu)溶(rong)度約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量一般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是在(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)液(ye)態下吸入的(de)(de)(de)(de)(de),而上引(yin)法無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)則相反(fan),氧(yang)(yang)(yang)在(zai)液(ye)態銅(tong)(tong)(tong)(tong)(tong)(tong)下保持相當時間后,被還(huan)原(yuan)而脫去,通常(chang)這種(zhong)桿(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量都在(zai)10—50ppm以(yi)(yi)下,最低(di)(di)(di)可達1-2ppm,從組(zu)織(zhi)(zhi)上看(kan),低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)(tong)狀(zhuang)態,存在(zai)于晶(jing)粒邊界(jie)附近,這對(dui)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)而言可以(yi)(yi)說是常(chang)見(jian)的(de)(de)(de)(de)(de)但對(dui)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)則很少見(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)(tong)(tong)以(yi)(yi)夾雜(za)形式在(zai)晶(jing)界(jie)出現(xian)對(dui)材料的(de)(de)(de)(de)(de)韌性(xing)產(chan)生負面影響。而無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)很低(di)(di)(di),所以(yi)(yi)這種(zhong)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)組(zu)織(zhi)(zhi)是均勻的(de)(de)(de)(de)(de)單相組(zu)織(zhi)(zhi)對(dui)韌性(xing)有利。在(zai)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)(de)多孔性(xing)是不(bu)常(chang)見(jian)的(de)(de)(de)(de)(de),而在(zai)低(di)(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)中則是常(chang)見(jian)的(de)(de)(de)(de)(de)一種(zhong)缺陷。

二、熱軋組(zu)織和(he)鑄造組(zu)織的區(qu)別

低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)由于經(jing)過熱軋(ya),所(suo)以(yi)其組(zu)(zu)織(zhi)屬熱加(jia)工(gong)組(zu)(zu)織(zhi),原來的(de)(de)(de)鑄造組(zu)(zu)織(zhi)已經(jing)破碎,在(zai)(zai)8mm的(de)(de)(de)桿(gan)(gan)時已有(you)再(zai)結晶(jing)(jing)(jing)的(de)(de)(de)形(xing)式(shi)出現,而(er)無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)屬鑄造組(zu)(zu)織(zhi),晶(jing)(jing)(jing)粒粗(cu)大,這是(shi)為什么(me),無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)的(de)(de)(de)再(zai)結晶(jing)(jing)(jing)溫度(du)較(jiao)高,需要(yao)較(jiao)高退(tui)(tui)(tui)火(huo)溫度(du)的(de)(de)(de)固(gu)有(you)原因(yin)(yin)(yin)。這是(shi)因(yin)(yin)(yin)為,再(zai)結晶(jing)(jing)(jing)發生在(zai)(zai)晶(jing)(jing)(jing)粒邊(bian)界(jie)附近,無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)組(zu)(zu)織(zhi)晶(jing)(jing)(jing)粒粗(cu)大,晶(jing)(jing)(jing)粒尺寸甚至能達(da)幾個毫米,因(yin)(yin)(yin)而(er)晶(jing)(jing)(jing)粒邊(bian)界(jie)少,即使(shi)通過拉制變形(xing),但晶(jing)(jing)(jing)粒邊(bian)界(jie)相對低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)還是(shi)較(jiao)少,所(suo)以(yi)需要(yao)較(jiao)高的(de)(de)(de)退(tui)(tui)(tui)火(huo)功率(lv)。對無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)成(cheng)功的(de)(de)(de)退(tui)(tui)(tui)火(huo)要(yao)求是(shi):由桿(gan)(gan)經(jing)拉制,但尚未鑄造組(zu)(zu)織(zhi)的(de)(de)(de)線時的(de)(de)(de)第一次退(tui)(tui)(tui)火(huo),其退(tui)(tui)(tui)火(huo)功率(lv)應(ying)比(bi)同樣(yang)情況的(de)(de)(de)低氧(yang)(yang)(yang)(yang)銅(tong)(tong)高10——15%。經(jing)繼續(xu)拉制,在(zai)(zai)以(yi)后階段(duan)的(de)(de)(de)退(tui)(tui)(tui)火(huo)功率(lv)應(ying)留有(you)足夠的(de)(de)(de)余量和(he)對低氧(yang)(yang)(yang)(yang)銅(tong)(tong)和(he)無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)切實(shi)區別執行(xing)不同的(de)(de)(de)退(tui)(tui)(tui)火(huo)工(gong)藝,以(yi)保證在(zai)(zai)制品和(he)成(cheng)品導線的(de)(de)(de)柔(rou)軟性。

三、夾(jia)雜(za),氧含量波動,表面氧化物(wu)和可能存在的熱軋缺陷的差別(bie)

無氧(yang)(yang)銅(tong)(tong)桿的(de)(de)可拉性在(zai)所有(you)線(xian)徑里與(yu)低氧(yang)(yang)銅(tong)(tong)桿相(xiang)比都是優越的(de)(de),除(chu)上述組織原因(yin)外,無氧(yang)(yang)銅(tong)(tong)桿夾雜(za)少,含氧(yang)(yang)量穩定(ding),無熱軋可能(neng)產(chan)生的(de)(de)缺陷,桿表(biao)氧(yang)(yang)化(hua)物(wu)厚度可達≤15A。在(zai)連鑄連軋生產(chan)過(guo)程中如果工藝(yi)不(bu)穩定(ding),對氧(yang)(yang)監控(kong)不(bu)嚴(yan),含氧(yang)(yang)量不(bu)穩定(ding)將直接影(ying)響桿的(de)(de)性能(neng)。如果桿的(de)(de)表(biao)面氧(yang)(yang)化(hua)物(wu)能(neng)在(zai)后工序的(de)(de)連續清洗(xi)中得以(yi)彌補外,但比較麻煩(fan)的(de)(de)是有(you)相(xiang)當多的(de)(de)氧(yang)(yang)化(hua)物(wu)存在(zai)于“皮(pi)下(xia)”,對拉線(xian)斷線(xian)影(ying)響更直接,故(gu)而在(zai)拉制微細(xi)線(xian),超微細(xi)線(xian)時,為(wei)了(le)減少斷線(xian),有(you)時要對銅(tong)(tong)桿采取不(bu)得已的(de)(de)辦法——剝皮(pi),甚至二次剝皮(pi)的(de)(de)原因(yin)所在(zai),目的(de)(de)要除(chu)去皮(pi)下(xia)氧(yang)(yang)化(hua)物(wu)。

四(si)、低氧(yang)(yang)銅桿和無(wu)氧(yang)(yang)銅桿的韌(ren)性有差(cha)別(bie)

兩者都可以(yi)拉(la)到0.015mm,但在低溫超導(dao)線中的低溫級(ji)無(wu)氧銅,其細絲間(jian)的間(jian)距只(zhi)有0.001mm.

五、從制桿的(de)原材(cai)料到制線(xian)的(de)經濟(ji)性有差別。

制(zhi)(zhi)造(zao)無氧銅(tong)(tong)桿要(yao)求質量較高的(de)原(yuan)材(cai)料。一般,拉制(zhi)(zhi)直(zhi)徑(jing)>1mm的(de)銅(tong)(tong)線時(shi),低氧銅(tong)(tong)桿的(de)優(you)(you)點(dian)比較明(ming)顯,而(er)無氧銅(tong)(tong)桿顯得(de)更為(wei)優(you)(you)越的(de)是(shi)拉制(zhi)(zhi)直(zhi)徑(jing)<0.5mm的(de)銅(tong)(tong)線。

六、低氧(yang)銅桿(gan)的制線工藝與(yu)無氧(yang)銅桿(gan)的有所不同。

低氧(yang)(yang)銅(tong)(tong)桿(gan)的(de)制(zhi)線(xian)工(gong)藝(yi)不能(neng)照搬到無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)的(de)制(zhi)線(xian)工(gong)藝(yi)上來,至少(shao)兩(liang)者的(de)退火(huo)工(gong)藝(yi)是不同的(de)。因為(wei)線(xian)的(de)柔軟性深受材料成份和制(zhi)桿(gan),制(zhi)線(xian)和退火(huo)工(gong)藝(yi)的(de)影響,不能(neng)簡(jian)單地(di)說低氧(yang)(yang)銅(tong)(tong)或(huo)無(wu)氧(yang)(yang)銅(tong)(tong)誰軟誰硬。