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來(lai)源(yuan):行業動(dong)態 閱讀:109393 發布時(shi)間:2019-07-05
導讀:由于生(sheng)(sheng)產銅(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)兩者的(de)工藝(yi)不(bu)同,所生(sheng)(sheng)產的(de)銅(tong)(tong)桿(gan)(gan)(gan)(gan)中的(de)含(han)氧量(liang)(liang)及外觀就不(bu)同。上(shang)(shang)引生(sheng)(sheng)產的(de)銅(tong)(tong)桿(gan)(gan)(gan)(gan),工藝(yi)得當氧含(han)量(liang)(liang)在10ppm以下,叫無氧銅(tong)(tong)桿(gan)(gan)(gan)(gan);連鑄連鑄生(sheng)(sheng)產的(de)銅(tong)(tong)桿(gan)(gan)(gan)(gan) 是在保護條件下的(de)熱軋(ya),氧含(han)量(liang)(liang)在200-500ppm范圍內,但(dan)有(you)時也(ye)(ye)高達(da)700ppm以上(shang)(shang),一般情(qing)況下,此種方法生(sheng)(sheng)產的(de)銅(tong)(tong)外表光(guang)亮,低氧銅(tong)(tong)桿(gan)(gan)(gan)(gan),有(you)時也(ye)(ye)叫光(guang)桿(gan)(gan)(gan)(gan)。
銅桿(gan)是(shi)電(dian)纜(lan)行(xing)業的(de)(de)主要原料,生產的(de)(de)方(fang)式主要有兩種(zhong)——連鑄(zhu)連軋(ya)法和上(shang)引連鑄(zhu)法。連鑄(zhu)連軋(ya)低氧銅桿(gan)的(de)(de)生產方(fang)法較(jiao)(jiao)多(duo),其特點是(shi)金屬在(zai)豎(shu)爐(lu)中融(rong)化后(hou),銅液(ye)通(tong)過保(bao)溫爐(lu)、溜(liu)槽、中間包,從澆管進(jin)(jin)入封閉的(de)(de)模腔內,采用(yong)較(jiao)(jiao)大的(de)(de)冷卻(que)強(qiang)度進(jin)(jin)行(xing)冷卻(que),形成(cheng)鑄(zhu)坯,然后(hou)進(jin)(jin)行(xing)多(duo)道次軋(ya)制,生產的(de)(de)低氧銅桿(gan)為熱加(jia)工組(zu)(zu)織(zhi),原來的(de)(de)鑄(zhu)造(zao)組(zu)(zu)織(zhi)已(yi)經破碎,含(han)氧量一(yi)般為200~400ppm之間。無氧銅桿(gan)國(guo)內基本(ben)全部采用(yong)上(shang)引連鑄(zhu)法生產,金屬在(zai)感應電(dian)爐(lu)中融(rong)化后(hou)通(tong)過石墨模進(jin)(jin)行(xing)上(shang)引連續(xu)鑄(zhu)造(zao),之后(hou)進(jin)(jin)行(xing)冷軋(ya)或冷加(jia)工,生產的(de)(de)無氧銅桿(gan)為鑄(zhu)造(zao)組(zu)(zu)織(zhi),含(han)氧量一(yi)般在(zai)20ppm以(yi)下。由于制造(zao)工藝(yi)的(de)(de)不同,所以(yi)在(zai)組(zu)(zu)織(zhi)結構、氧含(han)量分布、雜質(zhi)的(de)(de)形式及分布等(deng)諸多(duo)方(fang)面(mian)有較(jiao)(jiao)大差別。
一、拉制性能
銅桿(gan)的拉制性能(neng)跟很多因素(su)有關,如雜質的含(han)量、氧含(han)量及分布、工藝控制等(deng)。下面分別從以(yi)上(shang)幾個方面對(dui)銅桿(gan)的拉制性能(neng)進行(xing)分析。
1、熔化方(fang)式對S等雜質的(de)影響
連(lian)鑄連(lian)軋生產銅(tong)(tong)(tong)桿(gan)主(zhu)要(yao)(yao)是通過氣體(ti)的(de)燃燒(shao)(shao)使銅(tong)(tong)(tong)桿(gan)熔(rong)化(hua),在燃燒(shao)(shao)的(de)過程(cheng)(cheng)中(zhong),通過氧(yang)(yang)化(hua)和揮發作用(yong),可一定程(cheng)(cheng)度減少部分雜質進入銅(tong)(tong)(tong)液(ye),因此連(lian)鑄連(lian)軋法對原(yuan)料要(yao)(yao)求相對低一些。上引連(lian)鑄生產無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan),由(you)于是用(yong)感(gan)應電爐熔(rong)化(hua),電解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基(ji)本都(dou)熔(rong)入到銅(tong)(tong)(tong)液(ye)中(zhong)。其中(zhong)熔(rong)入的(de)S對無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)塑性影響極大(da),會(hui)增加拉絲斷線率。
2、鑄造過程中雜質的進入
在生產(chan)過(guo)(guo)程(cheng)(cheng)中(zhong)(zhong),連鑄(zhu)連軋工(gong)藝需通過(guo)(guo)保溫爐、溜(liu)槽、中(zhong)(zhong)間(jian)包(bao)轉運(yun)銅液,相對容易造(zao)(zao)成(cheng)(cheng)耐火材料(liao)的(de)(de)剝落,在軋制過(guo)(guo)程(cheng)(cheng)中(zhong)(zhong)需要通過(guo)(guo)軋輥,造(zao)(zao)成(cheng)(cheng)鐵質的(de)(de)脫落,會(hui)(hui)給(gei)銅桿造(zao)(zao)成(cheng)(cheng)外(wai)部夾雜。而熱軋中(zhong)(zhong)皮上(shang)和皮下氧(yang)化(hua)物的(de)(de)軋入,會(hui)(hui)給(gei)低氧(yang)桿的(de)(de)拉(la)絲(si)造(zao)(zao)成(cheng)(cheng)不利的(de)(de)影(ying)響。上(shang)引連鑄(zhu)法生產(chan)工(gong)藝流(liu)程(cheng)(cheng)較短,銅液是(shi)通過(guo)(guo)聯體爐內(nei)潛流(liu)式完成(cheng)(cheng),對耐火材料(liao)的(de)(de)沖擊不大,結晶是(shi)通過(guo)(guo)石墨(mo)模內(nei)進行,所以過(guo)(guo)程(cheng)(cheng)中(zhong)(zhong)可能產(chan)生的(de)(de)污染源(yuan)較少(shao),雜質進入的(de)(de)機會(hui)(hui)較少(shao)。
O、S、P是與銅(tong)會生產化合物的元素。在熔態銅(tong)中,氧(yang)可以溶(rong)解(jie)一部分,但當銅(tong)冷凝時,氧(yang)幾乎不溶(rong)解(jie)于銅(tong)中。熔態時所溶(rong)解(jie)的氧(yang),以銅(tong)=氧(yang)化亞銅(tong)共晶體(ti)析出,分布在晶粒晶界處(chu)。銅(tong)-氧(yang)化亞銅(tong)共晶體(ti)的出現,顯著降低了銅(tong)的塑性。
硫可以(yi)溶解(jie)在熔體的銅(tong)(tong)中,但在室(shi)溫下,其溶解(jie)度幾乎降低到零,它以(yi)硫化亞銅(tong)(tong)的形式出(chu)現在晶(jing)粒晶(jing)界處,會顯著(zhu)降低銅(tong)(tong)的塑性(xing)。
3、氧在低(di)氧銅(tong)桿和無氧銅(tong)桿中分(fen)布形式及其影響(xiang)
氧(yang)(yang)含(han)量(liang)對(dui)低氧(yang)(yang)銅(tong)桿的(de)拉線性能有著明顯(xian)的(de)影(ying)響。當氧(yang)(yang)含(han)量(liang)增加(jia)到最佳值(zhi)時,銅(tong)桿的(de)斷線率最低。這是因為氧(yang)(yang)在(zai)與(yu)大部分(fen)雜質反應的(de)過程中都起到了清除(chu)器的(de)作用。適度(du)的(de)氧(yang)(yang)還有利于去(qu)除(chu)銅(tong)液中的(de)氫,生成水(shui)蒸氣溢出,減少氣孔的(de)形成。最佳的(de)氧(yang)(yang)含(han)量(liang)為拉線工藝提供(gong)了最好的(de)條(tiao)件。
低氧(yang)(yang)銅(tong)桿(gan)(gan)氧(yang)(yang)化(hua)(hua)(hua)物的分布:在連續(xu)澆鑄中凝固的最初階段,散熱速率和均(jun)勻(yun)冷卻是決(jue)定銅(tong)桿(gan)(gan)氧(yang)(yang)化(hua)(hua)(hua)物分布的主要(yao)因(yin)素(su)。不均(jun)勻(yun)冷卻會(hui)引(yin)起(qi)銅(tong)桿(gan)(gan)內(nei)部(bu)結構本質上的差(cha)異,但后續(xu)的熱加工,柱(zhu)狀晶通(tong)常會(hui)遭(zao)到(dao)破(po)壞,使氧(yang)(yang)化(hua)(hua)(hua)亞(ya)銅(tong)顆(ke)粒(li)(li)細微化(hua)(hua)(hua)和均(jun)勻(yun)分布。氧(yang)(yang)化(hua)(hua)(hua)物顆(ke)粒(li)(li)聚(ju)集而(er)(er)產生的典型情況是中心爆(bao)裂。除氧(yang)(yang)化(hua)(hua)(hua)物顆(ke)粒(li)(li)分布的影響外,具有較小氧(yang)(yang)化(hua)(hua)(hua)物顆(ke)粒(li)(li)的銅(tong)桿(gan)(gan)顯示出較好(hao)的拉線特性,較大的Cu2O顆(ke)粒(li)(li)容易造(zao)成應力集中點而(er)(er)斷(duan)裂。
無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)含(han)氧(yang)(yang)量(liang)超標,銅(tong)(tong)(tong)(tong)桿變(bian)脆(cui)(cui),延(yan)伸率(lv)下(xia)降,拉伸式樣端口顯暗(an)紅色,結晶組織疏松。當氧(yang)(yang)含(han)量(liang)超出(chu)8ppm時,工藝性(xing)(xing)能變(bian)差,表現(xian)為(wei)鑄(zhu)造及拉伸過程中(zhong)斷(duan)桿及斷(duan)線率(lv)極具增(zeng)高。這是(shi)由于氧(yang)(yang)能與(yu)銅(tong)(tong)(tong)(tong)生成(cheng)氧(yang)(yang)化亞銅(tong)(tong)(tong)(tong)脆(cui)(cui)性(xing)(xing)相(xiang),形成(cheng)銅(tong)(tong)(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)(tong)(tong)共(gong)晶體,以網狀組織分(fen)布在(zai)境界上。這種脆(cui)(cui)性(xing)(xing)相(xiang)硬度高,在(zai)冷變(bian)形時將會與(yu)銅(tong)(tong)(tong)(tong)機(ji)體脫離,導(dao)致銅(tong)(tong)(tong)(tong)桿的機(ji)械性(xing)(xing)能下(xia)降,在(zai)后續加(jia)工中(zhong)容易造成(cheng)斷(duan)裂現(xian)象(xiang)。氧(yang)(yang)含(han)量(liang)高還能導(dao)致無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿導(dao)電率(lv)下(xia)降。因(yin)此,必(bi)須(xu)嚴格控制上引連鑄(zhu)工藝及產品質(zhi)量(liang)。
4、氫的影響
在(zai)(zai)上引連鑄(zhu)中,氧(yang)含量控制較低(di),氧(yang)化(hua)物的副作用唄(bai)**降(jiang)低(di),但氫的影(ying)響成為較顯(xian)著的問題。吸氣后熔(rong)體中存(cun)在(zai)(zai)平(ping)衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)體及疏松(song)是在(zai)結(jie)(jie)(jie)晶(jing)(jing)的(de)(de)(de)過程中(zhong),氫從過飽和(he)的(de)(de)(de)溶液中(zhong)析(xi)(xi)出(chu)并聚(ju)集而(er)形(xing)成(cheng)(cheng)的(de)(de)(de)。在(zai)結(jie)(jie)(jie)晶(jing)(jing)前(qian)析(xi)(xi)出(chu)的(de)(de)(de)氫又可還原氧(yang)化亞銅而(er)生成(cheng)(cheng)水(shui)氣(qi)(qi)泡。由(you)于上引(yin)鑄造的(de)(de)(de)特(te)點是銅液自上而(er)下的(de)(de)(de)結(jie)(jie)(jie)晶(jing)(jing),形(xing)成(cheng)(cheng)的(de)(de)(de)液**形(xing)狀近似(si)錐型。銅液結(jie)(jie)(jie)晶(jing)(jing)前(qian)析(xi)(xi)出(chu)的(de)(de)(de)氣(qi)(qi)體在(zai)上浮過程中(zhong)被堵在(zai)凝固組織內(nei),結(jie)(jie)(jie)晶(jing)(jing)時(shi)(shi)在(zai)鑄桿內(nei)形(xing)成(cheng)(cheng)氣(qi)(qi)孔(kong)。上引(yin)的(de)(de)(de)含氣(qi)(qi)量少時(shi)(shi),析(xi)(xi)出(chu)的(de)(de)(de)氫存(cun)在(zai)于晶(jing)(jing)界處,形(xing)成(cheng)(cheng)疏松(song);含氣(qi)(qi)量多時(shi)(shi),則(ze)聚(ju)集成(cheng)(cheng)氣(qi)(qi)孔(kong),因此,氣(qi)(qi)孔(kong)和(he)疏松(song)是氫氣(qi)(qi)和(he)水(shui)蒸氣(qi)(qi)兩者(zhe)形(xing)成(cheng)(cheng)的(de)(de)(de)。
氫來源于上(shang)引(yin)生產過(guo)程中的(de)各(ge)個工藝環(huan)節,如原料(liao)電(dian)解(jie)銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔料(liao)木(mu)(mu)炭**、氣(qi)候環(huan)境(jing)**、石墨結(jie)晶器未(wei)干燥等。因此,熔化爐中的(de)銅(tong)(tong)液表面應覆(fu)蓋(gai)經烘烤的(de)木(mu)(mu)炭,電(dian)解(jie)銅(tong)(tong)應盡量(liang)去除(chu)“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳朵”,對(dui)提高無氧(yang)銅(tong)(tong)桿(gan)質量(liang)非(fei)常重要。
在連鑄(zhu)連軋工藝(yi)中,往往采用適(shi)度控制(zhi)氧含量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅(tong)液(ye)(ye)在鑄造過程中是自(zi)下而(er)上(shang)結晶,銅(tong)液(ye)(ye)中的(de)(de)氧和氫所產生的(de)(de)水(shui)蒸氣很容易上(shang)浮跑出(chu),銅(tong)液(ye)(ye)中的(de)(de)氫大部分能(neng)被有效(xiao)去除,因而(er)對銅(tong)桿的(de)(de)影響較(jiao)小(xiao)。
二、表面質量
在生產電磁線(xian)等產品的(de)過(guo)(guo)程中,對銅桿的(de)表(biao)(biao)面質量(liang)(liang)也需(xu)提出(chu)要求。需(xu)要拉制后的(de)銅絲表(biao)(biao)面無毛刺、銅粉少(shao)、無油(you)污。并通(tong)過(guo)(guo)扭轉試驗測量(liang)(liang)表(biao)(biao)面銅粉的(de)質量(liang)(liang)和扭轉后觀(guan)察銅桿的(de)復原情況(kuang)來判定其好壞。
在(zai)連(lian)鑄連(lian)軋(ya)過(guo)程中,從鑄造(zao)(zao)到軋(ya)制(zhi)前,溫度高,完(wan)全暴(bao)露于空氣中,使(shi)鑄坯(pi)表面(mian)形成(cheng)(cheng)較厚的(de)氧化(hua)(hua)層,在(zai)軋(ya)制(zhi)過(guo)程中,隨著軋(ya)輥的(de)轉動,氧化(hua)(hua)物(wu)(wu)顆粒軋(ya)入(ru)銅線表面(mian)。由于氧化(hua)(hua)亞銅是高熔點脆(cui)性化(hua)(hua)合(he)物(wu)(wu),對(dui)于軋(ya)入(ru)較深的(de)氧化(hua)(hua)亞銅,當(dang)成(cheng)(cheng)條狀(zhuang)的(de)聚集物(wu)(wu)遇(yu)模具拉伸時,就會是銅桿外(wai)表面(mian)產生(sheng)毛(mao)刺(ci),給后續的(de)涂(tu)漆造(zao)(zao)成(cheng)(cheng)麻煩。
而上(shang)引連(lian)鑄工藝(yi)制造的無氧(yang)(yang)(yang)銅桿(gan),由于鑄造和(he)冷卻(que)完全與氧(yang)(yang)(yang)隔絕(jue),后續亦(yi)無熱軋過程,銅桿(gan)表(biao)面(mian)無軋入(ru)表(biao)面(mian)的氧(yang)(yang)(yang)化物(wu),質(zhi)量較好(hao),拉(la)制后銅粉少,上(shang)述問題較少存在。
無氧銅(tong)桿(gan)(gan)也(ye)(ye)分進口(kou)設(she)備(bei)(bei)做的(de)(de)和(he)國(guo)產(chan)(chan)設(she)備(bei)(bei)做的(de)(de),但目前進口(kou)產(chan)(chan)品已無明顯優勢,銅(tong)桿(gan)(gan)產(chan)(chan)品出來后區別不是(shi)很大(da),只要銅(tong)板選(xuan)的(de)(de)好(hao),生產(chan)(chan)控制比較穩(wen)定,國(guo)產(chan)(chan)設(she)備(bei)(bei)也(ye)(ye)能產(chan)(chan)出可(ke)拉伸0.05的(de)(de)銅(tong)桿(gan)(gan).進口(kou)設(she)備(bei)(bei)一般(ban)是(shi)芬蘭奧托昆普的(de)(de)設(she)備(bei)(bei),國(guo)產(chan)(chan)設(she)備(bei)(bei)最好(hao)的(de)(de)應該是(shi)上海的(de)(de)海軍(jun)廠的(de)(de)了,生產(chan)(chan)時間最長,軍(jun)工(gong)企業,質量(liang)可(ke)靠。
低氧銅(tong)桿進口設(she)備國(guo)際主要有(you)兩(liang)種,一種是(shi)(shi)美國(guo)南線設(she)備,英文是(shi)(shi)SOUTHWIRE,國(guo)內廠家是(shi)(shi)南京華新,江西銅(tong)業,另(ling)一種是(shi)(shi)德國(guo)CONTIROD設(she)備,國(guo)內廠家是(shi)(shi)常州金源,天津大(da)無縫。
無(wu)(wu)(wu)氧(yang)(yang)及低(di)氧(yang)(yang)桿(gan)(gan)(gan)從含氧(yang)(yang)量上(shang)容(rong)(rong)易(yi)區別,無(wu)(wu)(wu)氧(yang)(yang)銅(tong)是(shi)含氧(yang)(yang)量在(zai)10-20個(ge)PPM以(yi)下(xia),但目前有(you)的(de)廠家(jia)只能做(zuo)到(dao)50個(ge)PPM以(yi)下(xia).低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好(hao)的(de)桿(gan)(gan)(gan)子一般(ban)含氧(yang)(yang)量控(kong)制在(zai)250個(ge)PPM左右,無(wu)(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)一般(ban)采取的(de)是(shi)上(shang)引法,低(di)氧(yang)(yang)桿(gan)(gan)(gan)是(shi)連鑄連軋,兩種產品相對(dui)而(er)(er)言低(di)氧(yang)(yang)桿(gan)(gan)(gan)對(dui)漆包線(xian)性 能更適(shi)應些,如(ru)(ru)(ru)柔軟性,回(hui)彈(dan)角,繞線(xian)性能.但低(di)氧(yang)(yang)桿(gan)(gan)(gan)對(dui)拉絲條(tiao)件相對(dui)要(yao)苛刻些,同樣(yang)(yang)拉伸(shen)0.2的(de)細絲,如(ru)(ru)(ru)果(guo)伸(shen)線(xian)條(tiao)件不好(hao),普通(tong)的(de)無(wu)(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)可拉而(er)(er)好(hao)的(de)低(di)氧(yang)(yang)桿(gan)(gan)(gan)就(jiu)斷 線(xian),但如(ru)(ru)(ru)果(guo)放在(zai)好(hao)的(de)伸(shen)線(xian)條(tiao)件,同樣(yang)(yang)的(de)桿(gan)(gan)(gan)子,低(di)氧(yang)(yang)桿(gan)(gan)(gan)說不定(ding)就(jiu)能拉到(dao)雙(shuang)零五,而(er)(er)普通(tong)無(wu)(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)最多只能拉伸(shen)到(dao)0.1而(er)(er)已,當(dang)然做(zuo)的(de)最細的(de)如(ru)(ru)(ru)雙(shuang)零二卻非得依靠進(jin)口(kou)的(de) 無(wu)(wu)(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)了.目前有(you)企業嘗試(shi)用剝皮的(de)方式來(lai)處理低(di)氧(yang)(yang)桿(gan)(gan)(gan)來(lai)伸(shen)0.03線(xian).但有(you)關(guan)這方面的(de)內容(rong)(rong)我還不是(shi)很清(qing)楚(chu)。
音響線一般反(fan)而(er)喜歡(huan)用無氧(yang)桿(gan),這和無氧(yang)桿(gan)是(shi)單晶銅,低(di)氧(yang)桿(gan)是(shi)多晶銅有關(guan)。
氧(yang)(yang)銅桿(gan)和無氧(yang)(yang)銅桿(gan)由于制造方法的不同,致使存在差別,具有(you)各自(zi)的特點。
一、關(guan)于(yu)氧的(de)吸(xi)入和脫去以及它的(de)存在狀(zhuang)態(tai)
生(sheng)產銅(tong)(tong)(tong)(tong)(tong)(tong)桿的(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)一般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常(chang)(chang)溫(wen)下(xia)氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)固溶(rong)度約(yue)2ppm。低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)一般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入(ru)(ru)是(shi)在(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)液態(tai)下(xia)吸(xi)入(ru)(ru)的(de)(de)(de)(de),而(er)(er)上引法無氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿則(ze)相反,氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)(tong)下(xia)保持相當時(shi)間后,被還原而(er)(er)脫去,通常(chang)(chang)這種桿的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)都(dou)在(zai)(zai)(zai)10—50ppm以(yi)下(xia),最低(di)(di)可達1-2ppm,從組織(zhi)上看,低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)(tong)狀(zhuang)態(tai),存在(zai)(zai)(zai)于晶(jing)粒邊界附近,這對(dui)低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿而(er)(er)言(yan)可以(yi)說是(shi)常(chang)(chang)見(jian)(jian)的(de)(de)(de)(de)但對(dui)無氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿則(ze)很(hen)少(shao)見(jian)(jian)。氧(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)晶(jing)界出現對(dui)材料的(de)(de)(de)(de)韌性(xing)產生(sheng)負面影響。而(er)(er)無氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)很(hen)低(di)(di),所以(yi)這種銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)(de)組織(zhi)是(shi)均勻(yun)的(de)(de)(de)(de)單相組織(zhi)對(dui)韌性(xing)有(you)利(li)。在(zai)(zai)(zai)無氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿中的(de)(de)(de)(de)多(duo)孔性(xing)是(shi)不常(chang)(chang)見(jian)(jian)的(de)(de)(de)(de),而(er)(er)在(zai)(zai)(zai)低(di)(di)氧(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿中則(ze)是(shi)常(chang)(chang)見(jian)(jian)的(de)(de)(de)(de)一種缺(que)陷。
二(er)、熱軋組(zu)織和鑄造組(zu)織的(de)區別
低(di)氧銅(tong)桿(gan)(gan)(gan)由于經(jing)(jing)過(guo)熱(re)(re)軋,所(suo)以(yi)(yi)其組(zu)織(zhi)屬熱(re)(re)加工組(zu)織(zhi),原來的(de)(de)(de)(de)鑄(zhu)造組(zu)織(zhi)已經(jing)(jing)破碎(sui),在(zai)8mm的(de)(de)(de)(de)桿(gan)(gan)(gan)時已有(you)再(zai)結晶(jing)(jing)(jing)的(de)(de)(de)(de)形式出(chu)現,而無(wu)(wu)氧銅(tong)桿(gan)(gan)(gan)屬鑄(zhu)造組(zu)織(zhi),晶(jing)(jing)(jing)粒粗大,這是為(wei)什(shen)么,無(wu)(wu)氧銅(tong)的(de)(de)(de)(de)再(zai)結晶(jing)(jing)(jing)溫(wen)度(du)較(jiao)高(gao)(gao),需(xu)要(yao)較(jiao)高(gao)(gao)退火(huo)(huo)溫(wen)度(du)的(de)(de)(de)(de)固(gu)有(you)原因。這是因為(wei),再(zai)結晶(jing)(jing)(jing)發生在(zai)晶(jing)(jing)(jing)粒邊(bian)界附(fu)近,無(wu)(wu)氧銅(tong)桿(gan)(gan)(gan)組(zu)織(zhi)晶(jing)(jing)(jing)粒粗大,晶(jing)(jing)(jing)粒尺寸甚(shen)至能(neng)達幾個毫米,因而晶(jing)(jing)(jing)粒邊(bian)界少,即使通過(guo)拉(la)制變形,但(dan)(dan)晶(jing)(jing)(jing)粒邊(bian)界相對低(di)氧銅(tong)桿(gan)(gan)(gan)還是較(jiao)少,所(suo)以(yi)(yi)需(xu)要(yao)較(jiao)高(gao)(gao)的(de)(de)(de)(de)退火(huo)(huo)功率。對無(wu)(wu)氧銅(tong)成(cheng)功的(de)(de)(de)(de)退火(huo)(huo)要(yao)求(qiu)是:由桿(gan)(gan)(gan)經(jing)(jing)拉(la)制,但(dan)(dan)尚未鑄(zhu)造組(zu)織(zhi)的(de)(de)(de)(de)線(xian)時的(de)(de)(de)(de)第一次退火(huo)(huo),其退火(huo)(huo)功率應(ying)比同樣情況(kuang)的(de)(de)(de)(de)低(di)氧銅(tong)高(gao)(gao)10——15%。經(jing)(jing)繼續(xu)拉(la)制,在(zai)以(yi)(yi)后(hou)階段的(de)(de)(de)(de)退火(huo)(huo)功率應(ying)留有(you)足(zu)夠的(de)(de)(de)(de)余量和(he)對低(di)氧銅(tong)和(he)無(wu)(wu)氧銅(tong)切實(shi)區別執行(xing)不同的(de)(de)(de)(de)退火(huo)(huo)工藝,以(yi)(yi)保(bao)證在(zai)制品和(he)成(cheng)品導線(xian)的(de)(de)(de)(de)柔(rou)軟性。
三、夾雜,氧含量波動,表面氧化(hua)物(wu)和可能存在的(de)熱(re)軋缺陷的(de)差別
無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)的(de)(de)可(ke)拉性在(zai)所(suo)有(you)(you)線(xian)(xian)(xian)徑里(li)與低氧(yang)(yang)(yang)銅桿(gan)(gan)相(xiang)比都是優越的(de)(de),除上(shang)述組織原因外,無(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)夾雜少,含(han)氧(yang)(yang)(yang)量(liang)穩(wen)(wen)定,無(wu)熱軋(ya)可(ke)能(neng)(neng)產(chan)生(sheng)(sheng)的(de)(de)缺陷(xian),桿(gan)(gan)表(biao)氧(yang)(yang)(yang)化(hua)(hua)物(wu)厚度可(ke)達≤15A。在(zai)連鑄連軋(ya)生(sheng)(sheng)產(chan)過程中如(ru)果(guo)工藝不(bu)穩(wen)(wen)定,對(dui)氧(yang)(yang)(yang)監(jian)控不(bu)嚴,含(han)氧(yang)(yang)(yang)量(liang)不(bu)穩(wen)(wen)定將直接影響桿(gan)(gan)的(de)(de)性能(neng)(neng)。如(ru)果(guo)桿(gan)(gan)的(de)(de)表(biao)面(mian)氧(yang)(yang)(yang)化(hua)(hua)物(wu)能(neng)(neng)在(zai)后工序的(de)(de)連續清洗中得以彌補外,但比較麻(ma)煩的(de)(de)是有(you)(you)相(xiang)當多(duo)的(de)(de)氧(yang)(yang)(yang)化(hua)(hua)物(wu)存在(zai)于(yu)“皮下”,對(dui)拉線(xian)(xian)(xian)斷線(xian)(xian)(xian)影響更直接,故而在(zai)拉制微(wei)細線(xian)(xian)(xian),超(chao)微(wei)細線(xian)(xian)(xian)時(shi)(shi),為了減少斷線(xian)(xian)(xian),有(you)(you)時(shi)(shi)要對(dui)銅桿(gan)(gan)采(cai)取不(bu)得已的(de)(de)辦法——剝皮,甚(shen)至二次剝皮的(de)(de)原因所(suo)在(zai),目的(de)(de)要除去皮下氧(yang)(yang)(yang)化(hua)(hua)物(wu)。
四(si)、低氧銅(tong)桿(gan)和(he)無氧銅(tong)桿(gan)的(de)韌性有差別
兩者都可(ke)以拉到0.015mm,但在低溫(wen)超(chao)導(dao)線中的低溫(wen)級無氧銅,其細絲間的間距只有0.001mm.
五、從(cong)制(zhi)桿的原材料到制(zhi)線的經濟性有(you)差(cha)別。
制(zhi)造無(wu)氧銅桿(gan)要求(qiu)質(zhi)量較(jiao)(jiao)高(gao)的(de)(de)(de)原材料。一般(ban),拉制(zhi)直徑>1mm的(de)(de)(de)銅線時,低氧銅桿(gan)的(de)(de)(de)優點比較(jiao)(jiao)明(ming)顯,而無(wu)氧銅桿(gan)顯得更為優越的(de)(de)(de)是拉制(zhi)直徑<0.5mm的(de)(de)(de)銅線。
六、低(di)氧(yang)銅(tong)桿的(de)制(zhi)線(xian)工藝與無氧(yang)銅(tong)桿的(de)有所(suo)不同。
低氧銅桿(gan)的(de)制(zhi)(zhi)線(xian)工(gong)藝(yi)(yi)不能照(zhao)搬(ban)到無氧銅桿(gan)的(de)制(zhi)(zhi)線(xian)工(gong)藝(yi)(yi)上來,至(zhi)少兩者的(de)退火(huo)工(gong)藝(yi)(yi)是不同的(de)。因為線(xian)的(de)柔軟(ruan)性深受材料成份和制(zhi)(zhi)桿(gan),制(zhi)(zhi)線(xian)和退火(huo)工(gong)藝(yi)(yi)的(de)影響,不能簡單地(di)說(shuo)低氧銅或無氧銅誰軟(ruan)誰硬(ying)。
上一條(tiao)扎賚特絕緣層厚度不合格對電線電纜有何影響