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來源:行業動(dong)態 閱讀:109302 發布時間:2019-07-05
導(dao)讀:由于生(sheng)產(chan)(chan)(chan)銅(tong)(tong)桿的(de)(de)兩者的(de)(de)工藝(yi)不(bu)同(tong),所生(sheng)產(chan)(chan)(chan)的(de)(de)銅(tong)(tong)桿中的(de)(de)含氧(yang)量及外觀就不(bu)同(tong)。上(shang)引生(sheng)產(chan)(chan)(chan)的(de)(de)銅(tong)(tong)桿,工藝(yi)得當氧(yang)含量在10ppm以下(xia),叫無(wu)氧(yang)銅(tong)(tong)桿;連鑄(zhu)連鑄(zhu)生(sheng)產(chan)(chan)(chan)的(de)(de)銅(tong)(tong)桿 是在保護條(tiao)件下(xia)的(de)(de)熱軋,氧(yang)含量在200-500ppm范圍內,但有時也(ye)高達700ppm以上(shang),一(yi)般情況下(xia),此種方法生(sheng)產(chan)(chan)(chan)的(de)(de)銅(tong)(tong)外表光亮(liang),低氧(yang)銅(tong)(tong)桿,有時也(ye)叫光桿。
銅(tong)桿(gan)是電(dian)纜行業的(de)(de)主要(yao)原料,生(sheng)(sheng)產(chan)的(de)(de)方(fang)式(shi)主要(yao)有(you)兩種——連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)(ya)(ya)法和上(shang)引連(lian)(lian)鑄(zhu)法。連(lian)(lian)鑄(zhu)連(lian)(lian)軋(ya)(ya)(ya)低氧(yang)(yang)銅(tong)桿(gan)的(de)(de)生(sheng)(sheng)產(chan)方(fang)法較多(duo)(duo),其特點是金屬在(zai)(zai)豎爐中融化后,銅(tong)液通(tong)過(guo)(guo)保溫爐、溜槽、中間包,從澆管(guan)進(jin)(jin)入(ru)封閉的(de)(de)模(mo)腔內(nei),采用(yong)較大的(de)(de)冷(leng)卻強度進(jin)(jin)行冷(leng)卻,形(xing)成鑄(zhu)坯,然后進(jin)(jin)行多(duo)(duo)道次軋(ya)(ya)(ya)制,生(sheng)(sheng)產(chan)的(de)(de)低氧(yang)(yang)銅(tong)桿(gan)為熱加(jia)工(gong)(gong)組(zu)織,原來的(de)(de)鑄(zhu)造(zao)組(zu)織已經(jing)破碎,含(han)氧(yang)(yang)量一(yi)般為200~400ppm之(zhi)間。無氧(yang)(yang)銅(tong)桿(gan)國內(nei)基本全部(bu)采用(yong)上(shang)引連(lian)(lian)鑄(zhu)法生(sheng)(sheng)產(chan),金屬在(zai)(zai)感應電(dian)爐中融化后通(tong)過(guo)(guo)石墨(mo)模(mo)進(jin)(jin)行上(shang)引連(lian)(lian)續(xu)鑄(zhu)造(zao),之(zhi)后進(jin)(jin)行冷(leng)軋(ya)(ya)(ya)或冷(leng)加(jia)工(gong)(gong),生(sheng)(sheng)產(chan)的(de)(de)無氧(yang)(yang)銅(tong)桿(gan)為鑄(zhu)造(zao)組(zu)織,含(han)氧(yang)(yang)量一(yi)般在(zai)(zai)20ppm以(yi)下(xia)。由于制造(zao)工(gong)(gong)藝(yi)的(de)(de)不同,所以(yi)在(zai)(zai)組(zu)織結構、氧(yang)(yang)含(han)量分布、雜質(zhi)的(de)(de)形(xing)式(shi)及分布等諸多(duo)(duo)方(fang)面(mian)有(you)較大差別。
一、拉制性能
銅桿的拉(la)制性能(neng)(neng)跟很(hen)多因素有(you)關,如雜(za)質的含(han)量(liang)、氧含(han)量(liang)及分布(bu)、工藝控制等。下面分別(bie)從以上幾個方面對銅桿的拉(la)制性能(neng)(neng)進(jin)行分析。
1、熔化方式對S等(deng)雜(za)質的影響
連(lian)鑄(zhu)連(lian)軋(ya)生(sheng)產銅(tong)(tong)桿(gan)(gan)主要是通過(guo)(guo)氣體的燃燒使銅(tong)(tong)桿(gan)(gan)熔(rong)化,在燃燒的過(guo)(guo)程中,通過(guo)(guo)氧化和揮(hui)發(fa)作用,可(ke)一定(ding)程度減少部分雜質進(jin)入銅(tong)(tong)液,因此連(lian)鑄(zhu)連(lian)軋(ya)法(fa)對原料要求相對低一些(xie)。上引(yin)連(lian)鑄(zhu)生(sheng)產無氧銅(tong)(tong)桿(gan)(gan),由于是用感應電爐(lu)熔(rong)化,電解銅(tong)(tong)表(biao)面的“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本都熔(rong)入到銅(tong)(tong)液中。其中熔(rong)入的S對無氧銅(tong)(tong)桿(gan)(gan)塑性影響極大(da),會增加拉絲斷線率。
2、鑄造(zao)過程(cheng)中雜質(zhi)的(de)進入(ru)
在生(sheng)產過程(cheng)(cheng)中,連(lian)鑄連(lian)軋工藝(yi)(yi)需通過保溫(wen)爐(lu)、溜槽(cao)、中間包轉運銅(tong)液,相對(dui)容(rong)易造(zao)成耐火(huo)材(cai)料的(de)剝(bo)落,在軋制(zhi)過程(cheng)(cheng)中需要(yao)通過軋輥,造(zao)成鐵質(zhi)的(de)脫落,會給銅(tong)桿造(zao)成外(wai)部夾雜(za)。而(er)熱軋中皮(pi)上和皮(pi)下氧化物的(de)軋入(ru),會給低氧桿的(de)拉絲造(zao)成不利的(de)影響。上引(yin)連(lian)鑄法生(sheng)產工藝(yi)(yi)流(liu)程(cheng)(cheng)較(jiao)短(duan),銅(tong)液是通過聯體爐(lu)內潛流(liu)式完成,對(dui)耐火(huo)材(cai)料的(de)沖擊不大,結晶(jing)是通過石墨(mo)模內進行,所以過程(cheng)(cheng)中可能產生(sheng)的(de)污(wu)染(ran)源(yuan)較(jiao)少(shao),雜(za)質(zhi)進入(ru)的(de)機會較(jiao)少(shao)。
O、S、P是與銅會生產(chan)化合物的(de)元素(su)。在熔態(tai)銅中,氧(yang)可以(yi)溶解(jie)一部分(fen),但當(dang)銅冷凝時,氧(yang)幾乎不(bu)溶解(jie)于(yu)銅中。熔態(tai)時所溶解(jie)的(de)氧(yang),以(yi)銅=氧(yang)化亞銅共晶(jing)體(ti)(ti)析(xi)出,分(fen)布在晶(jing)粒晶(jing)界處。銅-氧(yang)化亞銅共晶(jing)體(ti)(ti)的(de)出現,顯著降(jiang)低了銅的(de)塑性(xing)。
硫可以溶(rong)解(jie)在熔體的(de)銅(tong)中(zhong),但在室(shi)溫下,其溶(rong)解(jie)度幾乎降(jiang)低到零,它以硫化亞銅(tong)的(de)形式出現在晶(jing)粒(li)晶(jing)界處,會顯著降(jiang)低銅(tong)的(de)塑性。
3、氧(yang)在低氧(yang)銅(tong)桿和(he)無氧(yang)銅(tong)桿中分(fen)布形式及其影響(xiang)
氧含(han)量對低氧銅(tong)(tong)桿(gan)的(de)(de)(de)(de)拉線(xian)(xian)性能有著明顯的(de)(de)(de)(de)影響(xiang)。當氧含(han)量增加到最佳值(zhi)時,銅(tong)(tong)桿(gan)的(de)(de)(de)(de)斷線(xian)(xian)率(lv)最低。這是因為氧在與大部(bu)分雜質反(fan)應(ying)的(de)(de)(de)(de)過程中都起到了(le)清除器的(de)(de)(de)(de)作用。適度(du)的(de)(de)(de)(de)氧還有利于去除銅(tong)(tong)液中的(de)(de)(de)(de)氫(qing),生成水蒸氣溢出,減少氣孔的(de)(de)(de)(de)形成。最佳的(de)(de)(de)(de)氧含(han)量為拉線(xian)(xian)工藝提(ti)供了(le)最好(hao)的(de)(de)(de)(de)條件。
低氧銅桿(gan)氧化物的(de)分布(bu):在連續澆鑄中(zhong)凝(ning)固的(de)最(zui)初階段,散熱(re)速率和均勻冷(leng)卻(que)(que)是(shi)決(jue)定銅桿(gan)氧化物分布(bu)的(de)主(zhu)要因素。不均勻冷(leng)卻(que)(que)會(hui)引起銅桿(gan)內(nei)部結(jie)構本質上的(de)差異(yi),但后續的(de)熱(re)加工,柱狀晶通常會(hui)遭到破壞,使氧化亞銅顆(ke)(ke)粒(li)細微(wei)化和均勻分布(bu)。氧化物顆(ke)(ke)粒(li)聚集而(er)產生的(de)典型情況是(shi)中(zhong)心(xin)爆(bao)裂(lie)。除氧化物顆(ke)(ke)粒(li)分布(bu)的(de)影響外,具(ju)有較(jiao)(jiao)小氧化物顆(ke)(ke)粒(li)的(de)銅桿(gan)顯示(shi)出較(jiao)(jiao)好的(de)拉線特性(xing),較(jiao)(jiao)大的(de)Cu2O顆(ke)(ke)粒(li)容易(yi)造(zao)成應力集中(zhong)點而(er)斷裂(lie)。
無(wu)氧(yang)(yang)(yang)銅含(han)氧(yang)(yang)(yang)量超(chao)標,銅桿變(bian)(bian)脆(cui)(cui),延伸(shen)率(lv)下降,拉(la)伸(shen)式樣端口顯暗紅(hong)色,結晶(jing)組織(zhi)疏松。當氧(yang)(yang)(yang)含(han)量超(chao)出8ppm時,工(gong)藝性能變(bian)(bian)差,表現(xian)為鑄造(zao)及拉(la)伸(shen)過程中(zhong)斷桿及斷線率(lv)極具增高。這(zhe)是由(you)于(yu)氧(yang)(yang)(yang)能與銅生(sheng)成氧(yang)(yang)(yang)化(hua)亞(ya)銅脆(cui)(cui)性相(xiang),形成銅-氧(yang)(yang)(yang)化(hua)亞(ya)銅共晶(jing)體,以網狀組織(zhi)分布在境界上。這(zhe)種脆(cui)(cui)性相(xiang)硬度高,在冷變(bian)(bian)形時將會與銅機體脫離(li),導致(zhi)銅桿的機械性能下降,在后續加工(gong)中(zhong)容易造(zao)成斷裂現(xian)象(xiang)。氧(yang)(yang)(yang)含(han)量高還能導致(zhi)無(wu)氧(yang)(yang)(yang)銅桿導電率(lv)下降。因(yin)此,必須嚴格控(kong)制上引連(lian)鑄工(gong)藝及產品質量。
4、氫的影響
在上引連鑄中(zhong),氧含(han)量控制較低,氧化物的副作用唄**降低,但氫(qing)的影響成為較顯(xian)著的問題。吸氣后(hou)熔體中(zhong)存在平衡反應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)(qi)(qi)(qi)體(ti)(ti)及疏(shu)松是在(zai)結(jie)晶的(de)(de)過程中,氫(qing)(qing)從(cong)過飽和的(de)(de)溶(rong)液(ye)(ye)中析(xi)(xi)出并聚(ju)集而(er)形(xing)成(cheng)(cheng)(cheng)的(de)(de)。在(zai)結(jie)晶前析(xi)(xi)出的(de)(de)氫(qing)(qing)又可還原氧化亞(ya)銅(tong)(tong)而(er)生成(cheng)(cheng)(cheng)水氣(qi)(qi)(qi)(qi)(qi)(qi)泡。由于(yu)上引鑄造的(de)(de)特點是銅(tong)(tong)液(ye)(ye)自上而(er)下的(de)(de)結(jie)晶,形(xing)成(cheng)(cheng)(cheng)的(de)(de)液(ye)(ye)**形(xing)狀近(jin)似錐型(xing)。銅(tong)(tong)液(ye)(ye)結(jie)晶前析(xi)(xi)出的(de)(de)氣(qi)(qi)(qi)(qi)(qi)(qi)體(ti)(ti)在(zai)上浮過程中被(bei)堵(du)在(zai)凝(ning)固組織內,結(jie)晶時在(zai)鑄桿內形(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)(qi)(qi)(qi)孔(kong)。上引的(de)(de)含氣(qi)(qi)(qi)(qi)(qi)(qi)量少(shao)時,析(xi)(xi)出的(de)(de)氫(qing)(qing)存在(zai)于(yu)晶界處,形(xing)成(cheng)(cheng)(cheng)疏(shu)松;含氣(qi)(qi)(qi)(qi)(qi)(qi)量多時,則聚(ju)集成(cheng)(cheng)(cheng)氣(qi)(qi)(qi)(qi)(qi)(qi)孔(kong),因此,氣(qi)(qi)(qi)(qi)(qi)(qi)孔(kong)和疏(shu)松是氫(qing)(qing)氣(qi)(qi)(qi)(qi)(qi)(qi)和水蒸氣(qi)(qi)(qi)(qi)(qi)(qi)兩者形(xing)成(cheng)(cheng)(cheng)的(de)(de)。
氫來源于上(shang)引生產(chan)過程(cheng)中的各(ge)個工藝環節,如原料電解(jie)銅(tong)的“銅(tong)綠”、輔料木炭(tan)**、氣候環境(jing)**、石(shi)墨(mo)結晶(jing)器未(wei)干(gan)燥等。因此,熔(rong)化(hua)爐中的銅(tong)液表面應覆蓋經烘烤的木炭(tan),電解(jie)銅(tong)應盡(jin)量(liang)去除(chu)“銅(tong)綠”、“銅(tong)豆(dou)”“耳朵”,對(dui)提高無氧銅(tong)桿(gan)質量(liang)非(fei)常重(zhong)要。
在連鑄連軋工藝(yi)中,往往采用適度控制(zhi)氧(yang)含(han)量來控制(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由(you)于銅(tong)液(ye)在鑄造過程中(zhong)(zhong)是自下而上結晶,銅(tong)液(ye)中(zhong)(zhong)的(de)氧和氫所產生的(de)水蒸氣(qi)很容易上浮跑出(chu),銅(tong)液(ye)中(zhong)(zhong)的(de)氫大(da)部分能被有效(xiao)去除,因而對(dui)銅(tong)桿的(de)影響較小。
二、表面質量
在生(sheng)產電磁線等產品(pin)的過程中,對銅(tong)桿(gan)的表面質量也(ye)需(xu)(xu)提(ti)出(chu)要求(qiu)。需(xu)(xu)要拉制(zhi)后(hou)的銅(tong)絲表面無(wu)毛刺、銅(tong)粉少、無(wu)油污。并通過扭(niu)轉試(shi)驗測(ce)量表面銅(tong)粉的質量和扭(niu)轉后(hou)觀察(cha)銅(tong)桿(gan)的復原情況來(lai)判(pan)定其好壞(huai)。
在(zai)連鑄(zhu)連軋(ya)過程中(zhong)(zhong),從鑄(zhu)造到軋(ya)制前(qian),溫度(du)高,完全暴(bao)露于空氣中(zhong)(zhong),使鑄(zhu)坯表(biao)面(mian)形成較厚的(de)氧(yang)化層,在(zai)軋(ya)制過程中(zhong)(zhong),隨著軋(ya)輥的(de)轉動,氧(yang)化物顆粒軋(ya)入銅(tong)線(xian)表(biao)面(mian)。由于氧(yang)化亞(ya)銅(tong)是高熔點脆性化合(he)物,對于軋(ya)入較深的(de)氧(yang)化亞(ya)銅(tong),當成條狀的(de)聚集(ji)物遇模(mo)具(ju)拉伸時,就(jiu)會是銅(tong)桿外表(biao)面(mian)產(chan)生毛刺(ci),給后續的(de)涂漆(qi)造成麻(ma)煩。
而上(shang)(shang)引連鑄工藝制造的無(wu)氧(yang)銅(tong)(tong)桿,由于鑄造和冷卻完(wan)全(quan)與氧(yang)隔(ge)絕,后(hou)續亦無(wu)熱(re)軋過(guo)程,銅(tong)(tong)桿表(biao)面無(wu)軋入表(biao)面的氧(yang)化物(wu),質量(liang)較好,拉制后(hou)銅(tong)(tong)粉(fen)少,上(shang)(shang)述問題較少存在。
無氧(yang)銅(tong)桿也(ye)(ye)分進口(kou)設(she)備做的(de)和國(guo)(guo)產(chan)(chan)設(she)備做的(de),但目前(qian)進口(kou)產(chan)(chan)品已(yi)無明顯優(you)勢(shi),銅(tong)桿產(chan)(chan)品出來后區別不(bu)是很大,只要銅(tong)板選的(de)好,生產(chan)(chan)控(kong)制(zhi)比較穩定,國(guo)(guo)產(chan)(chan)設(she)備也(ye)(ye)能產(chan)(chan)出可拉伸0.05的(de)銅(tong)桿.進口(kou)設(she)備一般(ban)是芬蘭奧托昆普(pu)的(de)設(she)備,國(guo)(guo)產(chan)(chan)設(she)備最(zui)好的(de)應(ying)該是上海的(de)海軍廠的(de)了,生產(chan)(chan)時間最(zui)長,軍工企業,質(zhi)量可靠。
低(di)氧(yang)銅桿進口設備(bei)國(guo)(guo)際主要有兩種(zhong),一(yi)種(zhong)是(shi)(shi)美國(guo)(guo)南(nan)線設備(bei),英文是(shi)(shi)SOUTHWIRE,國(guo)(guo)內廠(chang)家是(shi)(shi)南(nan)京華(hua)新,江西銅業,另一(yi)種(zhong)是(shi)(shi)德國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內廠(chang)家是(shi)(shi)常州金源(yuan),天津大無縫。
無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從含(han)(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)上容(rong)易區別,無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅是(shi)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)PPM以下(xia),但目(mu)前有(you)(you)的(de)(de)廠(chang)家只(zhi)能(neng)做到50個(ge)PPM以下(xia).低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)桿(gan)(gan)(gan)(gan)子(zi)一(yi)般(ban)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個(ge)PPM左右,無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一(yi)般(ban)采取的(de)(de)是(shi)上引法(fa),低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)連鑄連軋,兩種產品相(xiang)對(dui)而言(yan)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)漆包線(xian)性 能(neng)更適應(ying)些,如(ru)柔軟性,回彈角,繞線(xian)性能(neng).但低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)拉(la)(la)絲(si)條件(jian)(jian)相(xiang)對(dui)要苛刻(ke)些,同(tong)樣拉(la)(la)伸0.2的(de)(de)細(xi)絲(si),如(ru)果伸線(xian)條件(jian)(jian)不(bu)好,普(pu)通的(de)(de)無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可(ke)拉(la)(la)而好的(de)(de)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就(jiu)斷(duan) 線(xian),但如(ru)果放在(zai)(zai)好的(de)(de)伸線(xian)條件(jian)(jian),同(tong)樣的(de)(de)桿(gan)(gan)(gan)(gan)子(zi),低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說不(bu)定就(jiu)能(neng)拉(la)(la)到雙(shuang)零五,而普(pu)通無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最多只(zhi)能(neng)拉(la)(la)伸到0.1而已,當然(ran)做的(de)(de)最細(xi)的(de)(de)如(ru)雙(shuang)零二卻(que)非得依靠進口的(de)(de) 無氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了.目(mu)前有(you)(you)企業嘗(chang)試用(yong)剝皮的(de)(de)方式來處理低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來伸0.03線(xian).但有(you)(you)關(guan)這方面(mian)的(de)(de)內(nei)容(rong)我還不(bu)是(shi)很清楚。
音響(xiang)線一般反而喜歡用(yong)無(wu)氧桿(gan)(gan),這和無(wu)氧桿(gan)(gan)是(shi)單晶銅(tong),低(di)氧桿(gan)(gan)是(shi)多晶銅(tong)有關。
氧銅桿和無氧銅桿由于制造(zao)方法的(de)不同,致使存在差(cha)別,具(ju)有各自的(de)特點。
一(yi)、關于氧(yang)的(de)吸入和脫去以及它的(de)存(cun)在狀態
生產(chan)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)(de)(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)量(liang)(liang)一般在(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)常溫(wen)下氧(yang)(yang)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)固溶度(du)約(yue)2ppm。低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)量(liang)(liang)一般在(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)(de)(de)(de)進入(ru)是(shi)(shi)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)液態(tai)下吸(xi)入(ru)的(de)(de)(de)(de)(de),而(er)上(shang)引法無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則(ze)(ze)相反,氧(yang)(yang)在(zai)(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)下保(bao)持相當時間后,被還原而(er)脫(tuo)去,通常這種桿(gan)(gan)(gan)(gan)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)量(liang)(liang)都在(zai)(zai)(zai)(zai)10—50ppm以(yi)下,最(zui)低(di)(di)(di)可達1-2ppm,從組(zu)織上(shang)看,低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang),以(yi)氧(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)(zai)于(yu)晶粒(li)邊界附近,這對(dui)低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)而(er)言可以(yi)說是(shi)(shi)常見(jian)(jian)的(de)(de)(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)則(ze)(ze)很少(shao)見(jian)(jian)。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形式(shi)在(zai)(zai)(zai)(zai)晶界出(chu)現對(dui)材料的(de)(de)(de)(de)(de)韌性(xing)產(chan)生負面影(ying)響。而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)很低(di)(di)(di),所(suo)以(yi)這種銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)組(zu)織是(shi)(shi)均勻的(de)(de)(de)(de)(de)單相組(zu)織對(dui)韌性(xing)有利。在(zai)(zai)(zai)(zai)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中(zhong)的(de)(de)(de)(de)(de)多孔性(xing)是(shi)(shi)不常見(jian)(jian)的(de)(de)(de)(de)(de),而(er)在(zai)(zai)(zai)(zai)低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)(gan)中(zhong)則(ze)(ze)是(shi)(shi)常見(jian)(jian)的(de)(de)(de)(de)(de)一種缺陷。
二、熱軋組(zu)織和鑄造(zao)組(zu)織的區別
低(di)氧(yang)(yang)銅(tong)(tong)桿由(you)于(yu)經過熱軋(ya),所(suo)以其組(zu)(zu)織(zhi)(zhi)(zhi)屬熱加工(gong)組(zu)(zu)織(zhi)(zhi)(zhi),原來(lai)的鑄造組(zu)(zu)織(zhi)(zhi)(zhi)已經破(po)碎,在(zai)(zai)8mm的桿時(shi)已有(you)(you)(you)再結晶的形式出現,而無(wu)氧(yang)(yang)銅(tong)(tong)桿屬鑄造組(zu)(zu)織(zhi)(zhi)(zhi),晶粒(li)(li)(li)粗大,這是為(wei)什(shen)么,無(wu)氧(yang)(yang)銅(tong)(tong)的再結晶溫度較高(gao),需(xu)要較高(gao)退(tui)火(huo)溫度的固(gu)有(you)(you)(you)原因(yin)。這是因(yin)為(wei),再結晶發生(sheng)在(zai)(zai)晶粒(li)(li)(li)邊界(jie)附近,無(wu)氧(yang)(yang)銅(tong)(tong)桿組(zu)(zu)織(zhi)(zhi)(zhi)晶粒(li)(li)(li)粗大,晶粒(li)(li)(li)尺寸甚(shen)至能達幾個毫(hao)米(mi),因(yin)而晶粒(li)(li)(li)邊界(jie)少,即使(shi)通(tong)過拉制變形,但晶粒(li)(li)(li)邊界(jie)相對(dui)低(di)氧(yang)(yang)銅(tong)(tong)桿還是較少,所(suo)以需(xu)要較高(gao)的退(tui)火(huo)功率(lv)(lv)。對(dui)無(wu)氧(yang)(yang)銅(tong)(tong)成功的退(tui)火(huo)要求是:由(you)桿經拉制,但尚未鑄造組(zu)(zu)織(zhi)(zhi)(zhi)的線時(shi)的第一次退(tui)火(huo),其退(tui)火(huo)功率(lv)(lv)應比同(tong)樣(yang)情況的低(di)氧(yang)(yang)銅(tong)(tong)高(gao)10——15%。經繼續拉制,在(zai)(zai)以后階段的退(tui)火(huo)功率(lv)(lv)應留有(you)(you)(you)足夠的余量和對(dui)低(di)氧(yang)(yang)銅(tong)(tong)和無(wu)氧(yang)(yang)銅(tong)(tong)切實(shi)區別(bie)執行不(bu)同(tong)的退(tui)火(huo)工(gong)藝,以保證(zheng)在(zai)(zai)制品和成品導線的柔軟性。
三、夾雜,氧含量(liang)波動,表面氧化物和可能存在(zai)的熱軋缺陷的差別
無氧銅桿(gan)(gan)(gan)的(de)(de)可(ke)拉(la)(la)性在(zai)(zai)(zai)所有線(xian)徑里與低氧銅桿(gan)(gan)(gan)相比都是優越的(de)(de),除上述組織原(yuan)(yuan)因外(wai)(wai),無氧銅桿(gan)(gan)(gan)夾雜少(shao)(shao),含(han)氧量穩定(ding),無熱軋可(ke)能(neng)(neng)(neng)產生(sheng)的(de)(de)缺陷,桿(gan)(gan)(gan)表(biao)氧化(hua)(hua)物厚度(du)可(ke)達(da)≤15A。在(zai)(zai)(zai)連鑄連軋生(sheng)產過程(cheng)中(zhong)如(ru)果工藝(yi)不穩定(ding),對氧監控不嚴,含(han)氧量不穩定(ding)將直接影響桿(gan)(gan)(gan)的(de)(de)性能(neng)(neng)(neng)。如(ru)果桿(gan)(gan)(gan)的(de)(de)表(biao)面(mian)氧化(hua)(hua)物能(neng)(neng)(neng)在(zai)(zai)(zai)后工序的(de)(de)連續清洗中(zhong)得以彌補外(wai)(wai),但比較麻煩的(de)(de)是有相當多的(de)(de)氧化(hua)(hua)物存在(zai)(zai)(zai)于“皮下”,對拉(la)(la)線(xian)斷(duan)線(xian)影響更直接,故而在(zai)(zai)(zai)拉(la)(la)制微細(xi)線(xian),超(chao)微細(xi)線(xian)時(shi),為了減(jian)少(shao)(shao)斷(duan)線(xian),有時(shi)要(yao)對銅桿(gan)(gan)(gan)采取不得已的(de)(de)辦(ban)法(fa)——剝皮,甚至二(er)次剝皮的(de)(de)原(yuan)(yuan)因所在(zai)(zai)(zai),目的(de)(de)要(yao)除去皮下氧化(hua)(hua)物。
四、低氧銅桿和無氧銅桿的(de)韌性有差別(bie)
兩者都(dou)可以拉到0.015mm,但在低(di)(di)溫超導線(xian)中的低(di)(di)溫級無氧銅,其細絲間的間距(ju)只(zhi)有(you)0.001mm.
五、從制(zhi)桿的(de)原(yuan)材料到制(zhi)線(xian)的(de)經(jing)濟性(xing)有差別。
制(zhi)造無(wu)氧銅桿(gan)要求質量較高的原材料。一般,拉制(zhi)直徑>1mm的銅線時,低氧銅桿(gan)的優點比(bi)較明顯(xian),而無(wu)氧銅桿(gan)顯(xian)得更為優越(yue)的是拉制(zhi)直徑<0.5mm的銅線。
六、低氧銅(tong)桿(gan)的制線工藝(yi)與無(wu)氧銅(tong)桿(gan)的有所不同。
低氧(yang)銅(tong)桿的(de)制線工藝不能(neng)照搬到無(wu)氧(yang)銅(tong)桿的(de)制線工藝上(shang)來(lai),至少兩者的(de)退火工藝是不同的(de)。因(yin)為(wei)線的(de)柔軟性深受材料成份和制桿,制線和退火工藝的(de)影響,不能(neng)簡單地說低氧(yang)銅(tong)或無(wu)氧(yang)銅(tong)誰軟誰硬。
下(xia)一條肇源如何分辨劣質線纜(電纜人必備)